WO2019214228A1 - 一种气体传感器、传感器的制备方法及传感器阵列 - Google Patents
一种气体传感器、传感器的制备方法及传感器阵列 Download PDFInfo
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- WO2019214228A1 WO2019214228A1 PCT/CN2018/120547 CN2018120547W WO2019214228A1 WO 2019214228 A1 WO2019214228 A1 WO 2019214228A1 CN 2018120547 W CN2018120547 W CN 2018120547W WO 2019214228 A1 WO2019214228 A1 WO 2019214228A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/122—Circuits particularly adapted therefor, e.g. linearising circuits
- G01N27/123—Circuits particularly adapted therefor, e.g. linearising circuits for controlling the temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B3/00—Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
- B81B3/0035—Constitution or structural means for controlling the movement of the flexible or deformable elements
- B81B3/0037—For increasing stroke, i.e. achieve large displacement of actuated parts
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/128—Microapparatus
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00134—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems comprising flexible or deformable structures
- B81C1/0015—Cantilevers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2201/00—Specific applications of microelectromechanical systems
- B81B2201/02—Sensors
- B81B2201/0214—Biosensors; Chemical sensors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2203/00—Basic microelectromechanical structures
- B81B2203/01—Suspended structures, i.e. structures allowing a movement
- B81B2203/0118—Cantilevers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2203/00—Basic microelectromechanical structures
- B81B2203/04—Electrodes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0101—Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
- B81C2201/0102—Surface micromachining
- B81C2201/0105—Sacrificial layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0101—Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
- B81C2201/0128—Processes for removing material
- B81C2201/013—Etching
- B81C2201/0132—Dry etching, i.e. plasma etching, barrel etching, reactive ion etching [RIE], sputter etching or ion milling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0101—Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
- B81C2201/0128—Processes for removing material
- B81C2201/013—Etching
- B81C2201/0133—Wet etching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0174—Manufacture or treatment of microstructural devices or systems in or on a substrate for making multi-layered devices, film deposition or growing
- B81C2201/0176—Chemical vapour Deposition
Definitions
- the invention belongs to the field of microelectronic mechanical systems and gas detection technologies, and particularly relates to a gas sensor, a method for preparing the sensor and a sensor array.
- MEMS microelectromechanical systems
- MOS metal oxide semiconductor
- MEMS MOS gas sensors are mainly based on the research of suspension-type micro-heaters.
- the sensors of this structure have low power consumption, generally as low as 20 mW, as provided by the utility model patent No. 201520759054.6.
- a resistive gas sensor having a four-supported cantilever four-layer structure having a silicon substrate frame, a heating film layer, a heating electrode layer and a sensitive film layer arranged in this order from bottom to top, wherein the heating film layer comprises a heating film region, The heated film zone is connected to the silicon substrate frame by four cantilevers.
- Another example is a utility model patent with the patent number CN201520759055.0, which provides a resistive gas sensor with two supporting cantilever four-layer structure, the sensor also includes a silicon substrate frame, a heating film layer and a heating layer arranged from bottom to top. An electrode layer and a sensitive film layer, wherein the heated film layer comprises a heated film region connected to the silicon substrate frame by two cantilever beams.
- These multi-cantilever gas sensors have low power consumption, but with the rapid development of mobile and IoT applications, they are no longer sufficient. At the same time, when the multi-cantilever gas sensor is prepared, there are problems of complicated process, difficult positioning, and low efficiency.
- the technical problem to be solved by the present invention is how to further reduce the power consumption of the cantilever type gas sensor.
- a gas sensor having a base structure and a cantilever structure, including the following parts stacked in order from bottom to top
- the detecting electrode includes a first base, one side of the first base is provided with a first cantilever that is upwardly warped, and the free end of the first cantilever is provided with a first curling portion; the first base is away from the first cantilever a first window is disposed on one side, and a second window is disposed on the first cantilever, the second window extends along the first cantilever to the first curling portion, and divides the first curling portion, the second window and the first window Unicom, dividing the detecting electrode into two parts; the first base is respectively provided with a first lead at a position on both sides of the first window;
- the first isolating film which is a silicon nitride layer, includes a second base portion, one side of the second base portion is provided with a second cantilever that is upwardly warped, and the free end of the second cantilever is provided with a second curling portion;
- the second base portion is provided with a first through hole corresponding to the position of the first lead, and the first lead is exposed through the first through hole;
- a heating resistor comprising a third base, a third cantilever of the third base is provided with an upwardly warped third cantilever, a free end of the third cantilever is provided with a third curling portion; and a third base is facing away from the third cantilever a third window is disposed on one side, and a fourth window is disposed on the third cantilever, the fourth window extends along the third cantilever to the third curling portion, the fourth window is in communication with the third window, and the third base is located in the third a second lead is respectively disposed at a position on both sides of the window; the thickness of the heating resistor is smaller than the thickness of the first isolation film, and the heating resistor does not cover the first base;
- the second isolation film which is a silicon nitride layer, includes a fourth base portion, a fourth cantilevered arm is provided on one side of the fourth base portion, and a fourth cantilever is disposed at a free end of the fourth cantilever; a second transmission hole is disposed at a position corresponding to the second lead on the fourth base portion; and the fourth base portion does not cover the first transmission hole;
- the first base, the second base, the third base, and the fourth base are correspondingly disposed to form the base structure; the first cantilever, the second cantilever, the third cantilever, and the fourth cantilever are correspondingly disposed, and the first The curling portion, the second curling portion, the third curling portion and the fourth curling portion are sequentially disposed from the inside to the outside to form the cantilever structure;
- the first curling portion is wrapped with a gas sensing material.
- the horizontal projections of the first cantilever, the second cantilever, the third cantilever and the fourth cantilever are rectangular.
- the horizontal projections of the first cantilever, the second cantilever, the third cantilever, and the fourth cantilever are in an isosceles trapezoid, and the first is in a direction away from the base structure, the first The widths of the cantilever, the second cantilever, the third cantilever, and the fourth cantilever gradually increase.
- the first isolation film is provided with a first hole, and the first hole extends from an end of the second cantilever adjacent to the second base to the second curling portion.
- the second isolation film is provided with a second hole, and the second hole of the second hole extends near the fourth base to the fourth curl, and One hole corresponds to the setting.
- the third base portion and the fourth base portion are on a side of the first through hole facing the second cantilever; or the third base portion is located at the first through hole away from the second One side of the cantilever is disposed between the two first transmission holes, and a third transmission hole is disposed at a position corresponding to the first transmission hole on the fourth base.
- the thickness of the detecting electrode, the first isolation film, the heating resistor, and the second isolation film are both
- the present invention provides a gas sensor array characterized in that it is composed of a plurality of gas sensors as described above.
- the invention also provides a method for preparing a gas sensor for preparing the gas sensor described above, comprising the steps of:
- preparing a second isolation film preparing a silicon nitride layer by plasma using plasma enhanced chemical vapor deposition, and then etching the isolation film by reactive ion etching or ion beam etching to expose a heating resistor;
- (6) releasing the film firstly etching by reactive ion etching or ion beam etching to expose the silicon substrate to form a film release window, and then etching the sacrificial layer by a wet etching process to form a cantilever structure having a curled structure;
- a gas sensitive material is taken up at the end of the cantilever structure, and the gas sensitive material is wrapped to wrap the first curled portion.
- the thickness of the sacrificial layer is 2 um.
- the technical scheme of the invention adopts a single cantilever structure, and the effective area is arranged at the end of the cantilever beam, and the power consumption of the sensor is reduced to 1 milliwatt by reducing the effective area and reducing the number of cantilever beams; the curl structure of the sensor is smaller than the plane of the same area
- the structure is loaded with more sensitive materials, which is beneficial to provide sensitivity and stability of the sensor; the heating resistor is located inside the crimped structure and is heated from the inside to the outside, which is beneficial to improve heating efficiency and temperature uniformity; the detecting electrode is located in the crimped structure.
- the gas sensing material attached to the outside of the electrode is directly detected, and the contact area with the gas is large, which is advantageous for improving sensitivity and response speed;
- the crimped single cantilever type sensor has smaller size, higher integration, and more integration than existing ones.
- the cantilever structure is increased by an order of magnitude;
- the preparation method of the crimped single cantilever type gas sensor proposed by the invention is simple in process, easy to locate, effectively improves production efficiency, and is also easier to prepare a gas sensing material having a composite structure of temperament materials.
- FIG. 1 is a schematic structural view of a gas sensor according to Embodiment 1 of the present invention.
- Figure 2 is a schematic exploded view of Figure 1;
- Figure 3 is an enlarged schematic view of a portion A in Figure 2;
- Figure 4 is an enlarged schematic view of a portion B in Figure 2;
- FIG. 5 is a schematic exploded view of a gas sensor according to Embodiment 2 of the present invention.
- FIG. 6 is a schematic exploded view of a gas sensor according to Embodiment 3 of the present invention.
- FIG. 7 is a schematic structural diagram of a gas sensor array according to Embodiment 4 of the present invention.
- a gas sensor provided by the embodiment includes a silicon substrate 1, a detecting electrode 2, a first isolation film 3, a heating resistor 4, a second isolation film 5, and a gas sensing material 6.
- the sensor has a base structure and a cantilever structure.
- the base structure is rectangular, and the cantilever structure is disposed in the middle of a long side of the base structure. Therefore, the horizontal projection of the sensor is "T" type.
- the silicon substrate 1, the detecting electrode 2, the first isolation film 3, the heating resistor 4, and the second isolation film 5 are stacked in this order from bottom to top.
- the specific structure of the sensor is as follows:
- the silicon substrate 1 has a rectangular shape on both the upper and lower end faces thereof;
- the detecting electrode 2 is generally a noble metal material electrode such as metal platinum or gold.
- the detecting electrode 2 includes a first base portion 21 having a rectangular shape, a middle portion of a long side of the first base portion 21 is provided with a first cantilever 22 that is upwardly warped, and a first end of the first cantilever 22 is provided with a first end.
- a curling portion 23 a first window 24 is disposed on a side of the first base portion 21 away from the first cantilever 22, and a second window 25 is disposed on the first cantilever 22, the second window 25 extending along the first cantilever 22 to the first a curling portion 23, and dividing the first curling portion 23, the second window 25 is in communication with the first window 24, and the detecting electrode 2 is divided into two parts; the first base portion 21 is located at a position on both sides of the first window 24 There is a first lead (not shown).
- the first isolation film 3 is a silicon nitride layer, and is disposed to electrically isolate the detection electrode 2 and the heating electrode 4.
- the second isolation film 3 includes a second base portion 31, a second side of the long side of the second base portion 31 is provided with a second cantilever 32, the second cantilever 32 is provided with a second curling portion 33;
- the second base portion 32 is provided with a first through hole 34 corresponding to the position of the first lead, and the first lead is exposed through the first through hole 34;
- the heating resistor 4 is made of a metal material, typically metal platinum, for heating the detecting electrode 2 to obtain the temperature required for operation.
- the heating resistor 4 includes a third base portion 41, and a third side of the long side of the third base portion 41 is provided with a third cantilever 42 that is upwardly warped, and a free end of the third cantilever 42 is provided with a third curling portion 43;
- a third window 44 is disposed on a side of the base 41 facing away from the third cantilever 42.
- the third cantilever 42 is provided with a fourth window 45 extending along the third cantilever 42 to the third curling portion 43.
- the fourth window 45 is in communication with the third window 44; the third base portion 41 is respectively provided with a second lead (not shown) at a position on both sides of the third window 44; the thickness of the heating resistor 4 is smaller than the first isolation film 3 thickness, and the heating resistor 4 does not cover the first base portion 21;
- the second isolation film 5 is a silicon nitride layer which is covered on the heating resistor 4 to prevent the heating resistor 4 from being in contact with the outside.
- the second isolation film includes a fourth base portion 51, a fourth side of the long side of the fourth base portion 51 is provided with a fourth cantilever 52 that is upwardly warped, and a fourth end of the fourth cantilever 52 is provided with a fourth curling portion 53.
- a second through hole 54 is disposed at a position corresponding to the second lead on the fourth base portion 51; and the fourth base portion 51 does not cover the first through hole 34;
- the first base portion 21, the second base portion 31, the third base portion 41, and the fourth base portion 51 are correspondingly disposed to form the base structure;
- the first cantilever 22, the second cantilever 32, the third cantilever 42 and the fourth cantilever 52 Correspondingly, the first curling portion 23, the second curling portion 33, the third curling portion 43, and the fourth curling portion 53 are sequentially disposed from the inside to the outside to form the cantilever structure;
- the gas sensing material 6 is composed of a metal oxide semiconductor material at a nanometer scale, such as tin dioxide, zinc oxide or other oxides. It is wrapped outside the first curling portion 23, thereby being electrically connected to the detecting electrode 2. When the gas sensitive material 6 adsorbs a specific gas molecule, its electrical resistance changes, thereby achieving the purpose of detecting the gas.
- the core portion of the gas sensor is a cantilever structure having a crimped structure for loading the active area of the gas sensitive material only at the end of the cantilever structure away from the base mechanism.
- the heat loss caused by heat convection and heat radiation is reduced by reducing the area of the effective area, and on the other hand, the cantilever structure is thin and long, and warps upward, avoiding contact with the silicon substrate 1, and greatly reducing heat conduction.
- the heat loss in the process, so the sensor has very low power consumption; on the other hand, the heating resistor 4 is located inside the sensor, while reducing the heat loss, the heating of the detecting electrode is more uniform, and the detecting electrode 2 is located outside the sensor.
- the gas sensing material 6 is wrapped around the first curling portion 23, and has a large contact area with the gas to be detected and the detecting electrode 2, and has a faster response speed.
- the base structure is rectangular and the cantilever structure is disposed at the middle of the long side of the rectangular base structure, but this is not a strict regulation.
- the basic structure of the base structure And the setting position of the cantilever structure is set as needed.
- the horizontal projections of the first cantilever 22, the second cantilever 32, the third cantilever 42 and the fourth cantilever 52 are rectangular.
- first isolation film 3 is provided with a first hole 35 extending from an end of the second cantilever 32 adjacent to the second base 31 to the second curling portion 33.
- the second isolation film 5 is provided with a second hole 55 extending from one end of the fourth cantilever 52 near the fourth base portion 51 to the fourth curling portion 53. Only the first hole 35 may be provided on the sensor, or only the second hole 55 may be provided, or the first hole 35 and the second hole 55 may be simultaneously provided. It should be noted that the positions of the first hole 35, the second hole 55, the second window 24, and the fourth window 45 should correspond. The heat loss during heat transfer is further reduced by providing the elongated first hole 35 and/or the second hole 55.
- the third base portion 41 and the fourth base portion 41 are located on the side of the first through hole 34 facing the second cantilever 32.
- the thicknesses of the detecting electrode 2, the first isolation film 3, the heating resistor 4, and the second isolation film 5 described in this embodiment are both
- the first window 24 may be a symmetrical structure, and the detecting electrode 2 is divided into two parts by symmetry by providing the first window 24 and the second window 25; the third window 44 is a symmetrical structure, and passes through the third window 44 and the The four windows 45 form the heating resistor 4 into a symmetrical structure. It should be noted that, in actual production, the first window 24 and the third window 44 may also have an asymmetrical structure as needed, and the detecting electrode 2 and the heating resistor 4 are also asymmetric structures.
- the difference between this embodiment and the first embodiment is that the horizontal projections of the first cantilever 22, the second cantilever 32, the third cantilever 42 and the fourth cantilever 52 are isosceles trapezoidal and are away from the base structure. In the direction, the widths of the first cantilever 22, the second cantilever 32, the third cantilever 42 and the fourth cantilever 52 are gradually increased. By widening the connection width of the cantilever structure and the base structure, while maintaining the low power consumption characteristics of the single cantilever structure, the mechanical strength of the entire sensor is also improved.
- the difference between the embodiment and the second embodiment is that the third base portion 41 is located on a side of the first through hole 34 facing away from the second cantilever 32 , and the third cantilever 42 is located at the two first through holes 34 .
- a third through hole 56 is defined in the fourth base portion 51 corresponding to the first through hole 34 for the first lead to pass through.
- the integration constitutes a sensor array.
- the present embodiment provides a sensor array which is tiled by the above-described single cantilever sensor having a crimped structure, wherein the cantilever structures of the respective sensors are located on the same side of the base structure.
- the cantilever structure of each sensor can also be distributed on both sides of the base structure or in other arrangements as needed.
- the embodiment provides a gas sensor manufacturing method for preparing the gas sensor of the first embodiment to the fourth embodiment, including the following steps:
- a silicon nitride layer is prepared by plasma enhanced chemical vapor deposition using a plasma, and the layer thickness is Then etching the isolation film by reactive ion etching or ion beam etching to expose the heating resistor 4;
- Release film firstly etched by reactive ion etching or ion beam etching to expose the silicon substrate 1 to form a film release window, and then the sacrificial layer is etched by a wet etching process due to tensile stress of the silicon nitride layer. Acting, the warp of the cantilever structure, and its free end is curved;
- the silicon substrate 1 in this embodiment may also select a double-throwing silicon wafer, and the crystal orientation thereof is also not strictly required; the detecting electrode 2, the first isolation film 3, the heating resistor 4, and the second isolation The thickness of the film 5 is as needed in Adjustment within the scope.
- the present embodiment provides a method for preparing a gas sensor for preparing the gas sensor of the first embodiment to the fourth embodiment, including the following steps:
- the top silicon is used as a sacrificial layer, the thickness of the top silicon is 2 um;
- a silicon nitride layer is prepared by plasma enhanced chemical vapor deposition using a plasma, and the layer thickness is Then etching the isolation film by reactive ion etching or ion beam etching to expose the heating resistor 4;
- Release film firstly etched by reactive ion etching or ion beam etching to expose the silicon substrate 1 to form a film release window, and then the sacrificial layer is etched by a wet etching process due to tensile stress of the silicon nitride layer. Acting, the warp of the cantilever structure, and its free end is curved;
- the method for preparing the sensor into the sensor array is basically the same as the gas sensor preparation process of the fifth embodiment and the sixth embodiment, and only needs to set the etching conditions in the step (6) to form a plurality of matrix structures after releasing the film.
- each base structure has a sensor array with a cantilever structure; then, at the end of each cantilever structure, the same or different formulations of the dioxide gas sensing material are respectively taken up to form a gas sensor array.
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Abstract
Description
Claims (10)
- 一种气体传感器,其特征在于,具有基体结构和悬梁结构,包括自下而上依次层叠设置的如下各部分硅衬底;检测电极,包括第一基部,所述第一基部的一侧边设有向上翘曲的第一悬臂,所述第一悬臂的自由端设有第一卷曲部;第一基部远离第一悬臂的一侧设有第一窗口,所述第一悬臂上设有第二窗口,该第二窗口沿第一悬臂延伸至第一卷曲部,并将第一卷曲部分割,第二窗口与第一窗口联通,将检测电极分割为两部分;第一基部位于第一窗口两侧的位置处分别设有第一引线;第一隔离膜,为氮化硅层,包括第二基部,所述第二基部的一侧边设有向上翘曲的第二悬臂,所述第二悬臂的自由端设有第二卷曲部;第二基部对应于第一引线的位置设有第一透过孔,所述第一引线穿过第一透过孔暴露在外;加热电阻,包括第三基部,所述第三基部的一侧边设有向上翘曲的第三悬臂,所述第三悬臂的自由端设有第三卷曲部;第三基部背离第三悬臂的一侧设有第三窗口,所述第三悬臂上设有第四窗口,该第四窗口沿第三悬臂延伸至第三卷曲部,第四窗口与第三窗口联通;第三基部位于第三窗口两侧的位置处分别设有第二引线;所述加热电阻的厚度小于第一隔离膜的厚度,且加热电阻不覆盖第一基部;第二隔离膜,为氮化硅层,包括第四基部,所述第四基部的一侧边设有向上翘曲的第四悬臂,所述第四悬臂的自由端设有第四卷曲部;第四基部上对应于第二引线的位置设有第二透过孔;且第四基部不遮盖第一透过孔;所述第一基部、第二基部、第三基部和第四基部对应设置形成所述基体结构;所述第一悬臂、第二悬臂、第三悬臂和第四悬臂对应设置,且所述第一卷曲部、第二卷曲部、第三卷曲部及第四卷曲部由内至外依次设置形成所述悬梁结构;所述第一卷曲部外包裹有气敏材料。
- 根据权利要求1所述的一种气体传感器,其特征在于,所述第一悬臂、第二悬臂、第三悬臂和第四悬臂的水平投影呈矩形。
- 根据权利要求1所述的一种气体传感器,其特征在于,所述第一悬臂、第二悬臂、第三悬臂和第四悬臂的水平投影呈等腰梯形,且沿远离基体结构的方向,所述第一悬臂、第二悬臂、第三悬臂和第四悬臂的宽度逐渐增大。
- 根据权利要求1-3任一项所述的一种气体传感器,其特征在于,所述第一隔离膜上设有第一孔,所述第一孔自第二悬臂靠近第二基部的一端延伸至第二卷曲部。
- 根据权利要求4所述的一种气体传感器,其特征在于,所述第二隔离膜上设有第二孔,所述第二孔子第四悬臂靠近第四基部的一端延伸至第四卷曲部,并与第一孔对应设置。
- 根据权利要求1所述的一种气体传感器,其特征在于,所述第三基部、第四基部位于第一透过孔朝向第二悬臂的一侧;或第三基部位于第一透过孔背离第二悬臂的一侧,且第四基部上对应于第一透过孔设置有第三透过孔,第三悬臂位于两个第一透过孔之间,。
- 一种气体传感器阵列,其特征在于,由多个如权利要求1-7任一项所述的一种气体传感器构成。
- 一种气体传感器的制备方法,用以制备如权利要求1-7任一项所述的一种气体传感器,包括以下步骤:(1)选择硅衬底和牺牲层:当采用单抛或双抛硅片作为衬底时,通过热氧化法在衬底上形成一氧化硅层作为牺牲层;当采用SOI硅片作为衬底时,其顶层硅作为牺牲层;(2)制作检测电极:采用剥离工艺制备;(3)制作第一隔离膜:采用等离子采用等离子增强化学气相沉积法制备氮化硅层,然后利用反应离子刻蚀或离子束刻蚀刻蚀隔离膜,形成第一透过孔露出检测电极;(4)制作加热电阻:采用剥离工艺制备;(5)制备第二隔离膜:采用等离子采用等离子增强化学气相沉积法制备氮化硅层,然后利用反应离子刻蚀或离子束刻蚀刻蚀隔离膜,露出加热电阻;(6)释放薄膜:先利用反应离子刻蚀或离子束刻蚀彻底刻蚀,露出硅衬底形成薄膜释放窗口,然后利用湿法腐蚀工艺刻蚀牺牲层,形成具有卷曲结构的悬梁结构;(7)气敏材料的加载:在所述悬梁结构的端部沾取气敏材料,经烧结使气敏材料包裹第一卷曲部。
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