WO2019114641A1 - 一种界面气泡率极低的覆膜铁及其制造方法 - Google Patents
一种界面气泡率极低的覆膜铁及其制造方法 Download PDFInfo
- Publication number
- WO2019114641A1 WO2019114641A1 PCT/CN2018/120006 CN2018120006W WO2019114641A1 WO 2019114641 A1 WO2019114641 A1 WO 2019114641A1 CN 2018120006 W CN2018120006 W CN 2018120006W WO 2019114641 A1 WO2019114641 A1 WO 2019114641A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- substrate
- coated iron
- extremely low
- interface bubble
- low interface
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title abstract description 15
- 229910000576 Laminated steel Inorganic materials 0.000 title abstract 5
- 239000000758 substrate Substances 0.000 claims abstract description 69
- 229920006267 polyester film Polymers 0.000 claims abstract description 35
- 229920003232 aliphatic polyester Polymers 0.000 claims abstract description 17
- 230000003746 surface roughness Effects 0.000 claims abstract description 14
- 238000010030 laminating Methods 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 10
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 5
- 238000012986 modification Methods 0.000 claims abstract description 5
- 230000004048 modification Effects 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 180
- 229910052742 iron Inorganic materials 0.000 claims description 90
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 12
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 230000006698 induction Effects 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000002356 single layer Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 239000000539 dimer Substances 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 abstract description 4
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 30
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000003475 lamination Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 229920002799 BoPET Polymers 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 235000019592 roughness Nutrition 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000000396 iron Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AXKZIDYFAMKWSA-UHFFFAOYSA-N 1,6-dioxacyclododecane-7,12-dione Chemical compound O=C1CCCCC(=O)OCCCCO1 AXKZIDYFAMKWSA-UHFFFAOYSA-N 0.000 description 1
- UKQJDWBNQNAJHB-UHFFFAOYSA-N 2-hydroxyethyl formate Chemical compound OCCOC=O UKQJDWBNQNAJHB-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000019587 texture Nutrition 0.000 description 1
- 238000009823 thermal lamination Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0046—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by constructional aspects of the apparatus
- B32B37/0053—Constructional details of laminating machines comprising rollers; Constructional features of the rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/27—Sprue channels ; Runner channels or runner nozzles
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/022—Mechanical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/06—Coating on the layer surface on metal layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Definitions
- the present invention relates to a material and a method of manufacturing the same, and more particularly to a coated iron and a method of manufacturing the same.
- the coated iron generally refers to a composite material obtained by directly laminating a polymer polyester film on a steel substrate by a method of heating and melting, and the coated iron can be used as a can body or a can lid material, and thus, a film is coated. Iron is suitable for the production of food cans, beverage cans, ordinary covers, and easy-open lids.
- the polymer polyester film composited with the steel substrate includes polypropylene (PP), polyethylene terephthalate (PET), polyethylene (PE), etc., wherein PET is the most common, which is PET is more commonly used because of its excellent formability, abrasion resistance, and printability.
- coated iron is mainly used to replace the traditional coating iron, because the coated iron production process is solvent-free and exhaust-free, and the subsequent processing is free of cleaning and coating, which improves efficiency, less environmental pollution and energy saving; Covered iron does not contain harmful chemicals to ensure food safety and human health.
- the thermoplastic resin film ie, the polymer polyester film
- the thermoplastic resin film is coated on at least one surface of the metal sheet by a pair of coating rolls. Therefore, in the laminating process, if the air between the polymer polyester film and the substrate is not discharged in time during the extrusion process of the coating roller, it is easy to form a large amount of uneven bubbles on the surface of the substrate and the film, and a large number of The formation of uniform bubbles affects the properties of the coated iron, such as adhesion and corrosion resistance. Especially after deep processing and filling of contents, film bubbling and detachment may occur during long-term shelf storage.
- the above-mentioned publication number is CN1201420, and the publication date is December 9, 1998.
- the Chinese patent document entitled "Manufacturing method and manufacturing equipment for laminated metal sheets” discloses the manufacture of a laminated metal sheet. method.
- the plastic film in the process of manufacturing a laminated laminated film, the plastic film is heated and the tension is applied to the metal film immediately after heating, and the layer is pressed to the metal plate to reduce the layer. The biting of the air at the time of pressing, thereby obtaining a laminated metal sheet having a small bubble ratio.
- the Chinese Patent Publication No. Publication No. CN1212651A published on March 31, 1999, entitled "Manufacturing Apparatus for Laminated Metal Sheets” discloses a manufacturing apparatus for laminated metal sheets.
- the technical solution disclosed in the patent document proposes that the resin film is thinner than the metal plate, and the resin film is pulled to lamination to cause wrinkles.
- the bubble generation is more due to the fact that the melt-softened resin is not completely buried in the metal plate.
- a support roller for imparting tension to the film is provided during the film supply of the film film to the laminating roller to improve the bubble rate.
- One of the objects of the present invention is to provide a coated iron having an extremely low interface bubble ratio, which is coated with a substrate having a very low substrate roughness and a thermally laminated modified flexible polyester film covering the substrate.
- the medium interface bubble rate is low, and the obtained coating iron adhesion performance is good.
- the present invention provides a coated iron having an extremely low interface bubble ratio, comprising: a substrate having a surface roughness of 0.15 to 0.25 ⁇ m; and a modified flexible polyester film thermally bonded to the surface of the substrate;
- the modified flexible polyester film is obtained by copolymerization modification of a low molecular aliphatic polyester to ethylene terephthalate.
- the actual surface has microscopic unevenness, that is, surface roughness.
- the inventor of the present invention found through a lot of experimental research that since the surface of the strip is copied by the roll, as the surface roughness of the strip or roll increases, the surface parameters change accordingly, resulting in peaks and peaks of the grinding marks. The increase in depth.
- bubble defects will occur on the surface of the coated iron, that is, the deeper the peak-to-valley depth, the more air is present in the peak-valley position, the more It is not easy to be extruded during the lamination process and eventually causes a large amount of bubble defects to be generated on the surface of the coated iron.
- the substrate may be a strip with a plating layer, that is, a tin-plated steel sheet or a chrome-plated steel sheet may be used, but since the plating layer is thin (for example, the amount of chromium plating is generally 100 mg/m 2 , that is, the thickness is on the order of 10 nm), the plating layer is The influence on the surface roughness of the substrate is small.
- the coated iron adopts a substrate having a very low roughness (for example, a roughness of 0.15 to 0.25) so that the air in the peak-to-valley position is more easily discharged, thereby reducing the interface bubble rate and improving the present invention. The quality of the coated iron surface.
- the modified flexible polyester film coated on the substrate having extremely low surface roughness has a remarkable effect on reducing the interface bubble rate and improving the surface quality of the coated iron according to the present invention.
- the modified flexible polyester film is obtained by copolymerizing a low molecular weight aliphatic polyester with ethylene terephthalate. This is because the PET film obtained by conventional means (ie, polyester film), although PET has good mechanical properties and heat resistance, but due to the symmetry of the molecular structure of PET itself and the rigid benzene ring, PET cohesion It can be relatively large, has a high melting point, and has melt adhesion and poor melt flowability.
- the PET film obtained by conventional means is difficult to completely fill the gully on the surface of the substrate during the thermal lamination of the substrate, and thus it is difficult Achieve close adhesion between the interfaces, thereby affecting the adhesion of the product.
- the hard texture of the PET film obtained by conventional means may cause the coated iron to be easily formed in the case where the substrate is poorly bonded during the lamination, and the PET film and the substrate may be detached in the subsequent process such as press forming.
- the inventors have improved the flexibility of the rigid chain of PET by means of chemical modification, and the mobility of the segment is enhanced, so that the modified polyester has a good low melting point.
- the coated iron of the present invention has an extremely low bubble rate during the film coating process.
- the coated iron according to the present invention uses a substrate having a very low surface roughness and a modified flexible polyester film thermally bonded to the surface of the substrate to make the interface bubble rate of the coated iron extremely low, and the surface quality of the product. high.
- the molar percentage of the low molecular aliphatic polyester is 6-17%.
- the low molecular weight aliphatic polyester has a molecular weight of 500 to 3,000.
- the low molecular aliphatic polyester is a low molecular aliphatic polyester which is terminated with a hydroxyl group.
- the low molecular aliphatic polyester is obtained from an aliphatic diol and an aliphatic dibasic acid.
- the aliphatic diol is selected from the group consisting of propylene glycol, butylene glycol, pentanediol, hexanediol, and neopentyl glycol. one.
- the aliphatic dibasic acid is selected from the group consisting of oxalic acid, succinic acid, adipic acid, sebacic acid, and decanedicarboxylic acid.
- oxalic acid succinic acid
- adipic acid succinic acid
- sebacic acid sebacic acid
- decanedicarboxylic acid One of maleic acid, fumaric acid and dimer acid.
- the substrate is a tin-plated substrate or a chrome-plated substrate.
- the interfacial bubble ratio of the coated iron is 2-7%.
- the modified flexible polyester film has a single layer structure or a multilayer structure.
- the modified flexible polyester film preferably adopts a single layer structure or more. Layer structure.
- the surface tension of the surface of the modified flexible polyester film and the substrate is ⁇ 45 dynes.
- Another object of the present invention is to provide a method for producing a coated iron having an extremely low interface bubble ratio as described above, which has wide applicability and can achieve an extremely low interface bubble rate at a high speed operation of a production line.
- Membrane iron
- the present invention provides a method for producing a coated iron having an extremely low interface bubble ratio, comprising the steps of:
- the modified flexible polyester film is thermally laminated on the substrate. Further, the modified flexible polyester film has a high surface activation energy and a surface layer covering the substrate is a flexible polyester. Therefore, in the present case, the film opening does not require heating, and the film is opened at room temperature. After the modified flexible polyester film is coated on the substrate, it is cooled and squeezed to obtain the final coated iron.
- squeezing may employ a squeeze roller to remove moisture from the surface of the coated iron.
- the substrate in the step (1), is preheated to 60-80% of the target film temperature by using an induction heater, and then the substrate is heated to the target by the induction heating roller. Film temperature.
- the target coating temperature is 180 to 270 °C.
- the angle at which the modified flexible polyester film enters the roll gap of the coating roll is controlled to be 30-70.
- the film speed is controlled to be ⁇ 150 m/min.
- the coated iron spray water is rapidly cooled, and then the coated iron is immersed in a water quenching tank to be cooled.
- the coating iron with extremely low interface bubble rate according to the invention has extremely low bubble rate at the interface and has excellent adhesion performance, and is suitable for deep-drawn container processing and molding, especially under the high-speed coating film with a coating speed of ⁇ 150 m/min.
- a coated iron having an interface bubble ratio of 2-7% was obtained.
- the coated iron having an extremely low interface bubble ratio according to the present invention does not reduce the interface bubble rate by using an improvement of the production equipment, but reduces the interface bubble rate by using a substrate having an extremely low surface roughness. Therefore, the present invention
- the coated iron can be applied to the prior art production line and has universal applicability to the equipment.
- the coated iron having an extremely low interface bubble ratio according to the present invention has a high surface tension due to the modified flexible polyester film, and thus the coated iron according to the present invention is compared with the prior art.
- the air can be expelled quickly and in a timely manner during the lamination process, maintaining a long-lasting effective bond between the substrate and the film.
- the manufacturing method of the present invention also has the above advantages.
- coated iron having a very low interface bubble ratio and the method for manufacturing the same according to the present invention will be further explained and explained below with reference to specific embodiments. However, the explanation and description do not unduly limit the technical solution of the present invention.
- Table 1 lists the types of substrates and surface roughnesses of the coated irons having extremely low interface bubble ratios of Examples 1-6 and Comparative coated irons of Comparative Examples 1-4.
- Example 1 0.186 Chrome plated substrate
- Example 2 0.232 Chrome plated substrate
- Example 3 0.186 Chrome plated substrate
- Example 4 0.232 Chrome plated substrate
- Example 5 0.186 Tin plated substrate
- Example 6 0.232 Tin plated substrate Comparative example 1 0.261 Chrome plated substrate Comparative example 2 0.365 Chrome plated substrate Comparative example 3 0.281 Chrome plated substrate Comparative example 4 0.375 Tin plated substrate
- the flexible polyester film used in the coated iron having the extremely low interface bubble ratio of Examples 1-6 was obtained by copolymerization modification of a low molecular aliphatic polyester and ethylene terephthalate, and Comparative Examples 1-4
- the coating used for the coated iron is a single-layer polyester flexible film which is composed of a hydroxyl terminated butylene adipate (molecular weight of 1000, which is the same as the flexible polyester film used in Example 2) and terephthalic acid. It is obtained by copolymerization of ethylene glycol formate.
- Table 2 lists the specific parameters of the modified flexible polyester film used in the coated iron having an extremely low interface bubble ratio of Examples 1-6.
- the low molecular aliphatic polyesters in Table 2 all use hydroxyl terminated low molecular aliphatic polyesters.
- the method for producing the coated iron having an extremely low interface bubble ratio of Examples 1-6 and the comparative coated iron of Comparative Examples 1-4 comprises the following steps:
- Cooling and squeezing When cooling, the coated iron spray water is rapidly cooled, and then the coated iron is immersed in a water quenching tank for cooling.
- Table 3 lists the specific process parameters of the coated iron having an extremely low interface bubble ratio of Examples 1-6 and the comparative coated iron of Comparative Examples 1-4.
- Example 1 180 30 150 80
- Example 2 210 50 150 80 Example 3 225 50 180 80
- Example 4 225 50 180 80 Example 5 225 60 200 80
- Example 6 270 70 200
- Comparative example 1 210 50 150 80 Comparative example 2 210 50 150 80 Comparative example 3 210 50 200 80 Comparative example 4 210 50 200 80
- Interface bubble rate a high-resolution metal microscope was used to observe the laminate, and the bubble-like portion was bubbled, and the area ratio of the bubble per unit area was calculated;
- the adhesion after deformation was measured by a cross-cut cup tape peeling method. Take 10cm ⁇ 10cm coated iron sample, draw “well” on the plate at intervals of 3mm, scratch the film (be careful not to cut the substrate), then use the cup to change shape, keep the highest point of the cup in the word “well” Middle area. Then, the special tape is tightly adhered to the cup-scratching area, and the tape is quickly peeled off at the end of the tape, and the degree of peeling of the film is observed to evaluate the surface adhesion property of the film;
- Acid resistance After coating iron cans (tank type 691), the evaluation of corrosion resistance was performed to evaluate the corrosion resistance.
- the film-filled tank was filled with 1.5% citric acid solution, and then capped and cooked at 121 ° C for 30 min. After cooling, the sample was taken out to observe the surface to produce acidified spots, thereby evaluating the acid resistance of the coated iron. performance.
- the interface bubble ratio of the coated iron in each embodiment of the present invention is 2-7%, which is significantly lower than that of the comparative coating iron of each comparative example, thereby illustrating the interface of the coated iron of each embodiment of the present invention.
- the bubble rate is extremely low.
- the coated iron of each embodiment of the present invention has a high surface performance due to an extremely low interface bubble ratio, and in particular, the surface adhesion property and the acid resistance performance are superior to those of the comparative comparative coating iron. Performance, this is because the substrate of the embodiment with very low roughness can maintain the interface bubble rate between 2% and 7% under the high speed film. Therefore, at the same speed, the surface roughness is higher than that of the embodiment.
- the bubble ratio of the coated iron in each proportion of the degree is obviously improved, and at the same time, with the increase of the interface bubble rate, the surface adhesion performance of the comparative coated iron of each comparative layer under high deformation gradually deteriorates. Because, under high deformation, the bubble will be stretched with the deformation, that is, the defect is enlarged, and in the acid resistance test, the screening of the simulation is more strict, and the discrimination of the defect is more strict, from Table 4 It can be seen that as the surface bubble rate increases, the acid resistance of the comparative coated iron of each comparative ratio gradually deteriorates, which indicates that in the case of high deformation, in order to obtain a coated iron with better performance, it is required to be more stringent.
- the bubble rate at the interface of the coated iron is controlled, and the iron of the coated iron of the examples of the present invention has an extremely low interface bubble rate and high surface properties.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
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- Laminated Bodies (AREA)
Abstract
Description
表面粗糙度(μm) | 基板类型 | |
实施例1 | 0.186 | 镀铬基板 |
实施例2 | 0.232 | 镀铬基板 |
实施例3 | 0.186 | 镀铬基板 |
实施例4 | 0.232 | 镀铬基板 |
实施例5 | 0.186 | 镀锡基板 |
实施例6 | 0.232 | 镀锡基板 |
对比例1 | 0.261 | 镀铬基板 |
对比例2 | 0.365 | 镀铬基板 |
对比例3 | 0.281 | 镀铬基板 |
对比例4 | 0.375 | 镀锡基板 |
目标覆膜温度(℃) | 进入覆膜辊辊缝角度(°) | 覆膜速度(m/min) | 终冷温度(℃) | |
实施例1 | 180 | 30 | 150 | 80 |
实施例2 | 210 | 50 | 150 | 80 |
实施例3 | 225 | 50 | 180 | 80 |
实施例4 | 225 | 50 | 180 | 80 |
实施例5 | 225 | 60 | 200 | 80 |
实施例6 | 270 | 70 | 200 | 80 |
对比例1 | 210 | 50 | 150 | 80 |
对比例2 | 210 | 50 | 150 | 80 |
对比例3 | 210 | 50 | 200 | 80 |
对比例4 | 210 | 50 | 200 | 80 |
界面气泡率(%) | 表面附着性能 | 抗酸性能 | |
实施例1 | 2 | ◎ | ◎ |
实施例2 | 5 | ◎ | ◎ |
实施例3 | 3 | ◎ | ◎ |
实施例4 | 6 | ◎ | ○ |
实施例5 | 5 | ◎ | ○ |
实施例6 | 7 | ○ | ○ |
对比例1 | 10 | △ | △ |
对比例2 | 13 | △ | △ |
对比例3 | 18 | △ | ╳ |
对比例4 | 20 | ╳ | ╳ |
Claims (17)
- 一种界面气泡率极低的覆膜铁,其特征在于,包括:表面粗糙度为0.15-0.25μm的基板以及热覆合于基板表面的改性的柔性聚酯薄膜;其中所述改性的柔性聚酯薄膜由低分子脂肪族聚酯对对苯二甲酸乙二醇酯进行共聚改性得到。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述低分子脂肪族聚酯的摩尔百分比为6-17%。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述低分子脂肪族聚酯的分子量为500-3000。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述低分子脂肪族聚酯为采用羟基封端的低分子脂肪族聚酯。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述低分子脂肪族聚酯由脂肪族二元醇和脂肪族二元酸制得。
- 如权利要求5所述的界面气泡率极低的覆膜铁,其特征在于,所述脂肪族二元醇选自:丙二醇、丁二醇、戊二醇、己二醇和新戊二醇的其中之一。
- 如权利要求5所述的界面气泡率极低的覆膜铁,其特征在于,所述脂肪族二元酸选自:草酸、琥珀酸、己二酸、癸二酸、癸烷二羧酸、马来酸、富马酸和二聚酸的其中之一。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述基板为镀锡基板或镀铬基板。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述覆膜铁的界面气泡率为2-7%。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述改性的柔性聚酯薄膜为单层结构或多层结构。
- 如权利要求1所述的界面气泡率极低的覆膜铁,其特征在于,所述改性的柔性聚酯薄膜与基板覆合的面的表面张力≥45达因。
- 如权利要求1-11中任意一项所述的界面气泡率极低的覆膜铁的制造方法,其特征在于,包括步骤:(1)对基板进行预热,然后进行加热;(2)常温开膜,然后将改性的柔性聚酯薄膜热覆合于基板上;(3)冷却和挤干。
- 如权利要求12所述的制造方法,其特征在于,所述步骤(1)中先采用感应加热器将基板预热到目标覆膜温度的60-80%,然后采用感应加热辊将基板加热到目标覆膜温度。
- 如权利要求13所述的制造方法,其特征在于,所述目标覆膜温度为180-270℃。
- 如权利要求12所述的制造方法,其特征在于,在所述步骤(2)中,控制改性的柔性聚酯薄膜进入覆膜辊辊缝的角度为30-70°。
- 如权利要求12所述的制造方法,其特征在于,在所述步骤(2)中,控制覆膜速度≥150m/min。
- 如权利要求12所述的制造方法,其特征在于,在所述步骤(3)中,冷却时,先对覆膜铁喷水进行快速冷却,然后将覆膜铁浸入水淬槽中冷却。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/771,933 US11760064B2 (en) | 2017-12-13 | 2018-12-10 | Laminated steel having extremely low interface bubble rate and method for manufacturing same |
EP18889607.0A EP3725518A4 (en) | 2017-12-13 | 2018-12-10 | STRUCTURAL STEEL WITH EXTREMELY LOW INTERFACE BUBBLE RATE AND METHOD FOR MANUFACTURING IT |
BR112020010488-4A BR112020010488B1 (pt) | 2017-12-13 | 2018-12-10 | Aço laminado tendo taxa de bolha de interface extremamente baixa e método para produção do mesmo |
PH12020550865A PH12020550865A1 (en) | 2017-12-13 | 2020-06-11 | Laminated steel having extremely low interface bubble rate and method for manufacturing same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN201711324503.4 | 2017-12-13 | ||
CN201711324503.4A CN109910402B (zh) | 2017-12-13 | 2017-12-13 | 一种界面气泡率极低的覆膜铁及其制造方法 |
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WO2019114641A1 true WO2019114641A1 (zh) | 2019-06-20 |
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US (1) | US11760064B2 (zh) |
EP (1) | EP3725518A4 (zh) |
CN (1) | CN109910402B (zh) |
PH (1) | PH12020550865A1 (zh) |
WO (1) | WO2019114641A1 (zh) |
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CN1201420A (zh) | 1995-11-02 | 1998-12-09 | 东洋钢钣株式会社 | 层压金属板的制造方法及制造设备 |
CN1212651A (zh) | 1996-03-04 | 1999-03-31 | 东洋钢钣株式会社 | 层压金属板的制造设备 |
CN101142277A (zh) * | 2005-03-16 | 2008-03-12 | 帝人化成株式会社 | 树脂组合物 |
US20120082844A1 (en) * | 2010-09-30 | 2012-04-05 | Tdk Corporation | Powder magnetic core |
CN102431269A (zh) * | 2011-09-29 | 2012-05-02 | 上海联净环保科技有限公司 | 一种覆膜铁加工工艺及设备 |
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CA2068829C (en) * | 1991-05-17 | 1998-12-15 | Yashichi Ooyagi | Steel strip for three-piece can body, production process thereof and resistance seam welded three-piece can body |
WO2005115744A1 (ja) | 2004-05-31 | 2005-12-08 | Jfe Steel Corporation | 樹脂被覆金属板 |
WO2013157379A1 (ja) | 2012-04-19 | 2013-10-24 | Jfeスチール株式会社 | ラミネート金属板および食品用缶詰容器 |
JP5874659B2 (ja) | 2013-02-28 | 2016-03-02 | Jfeスチール株式会社 | 2ピース缶用ラミネート金属板および2ピースラミネート缶体 |
CN104448726B (zh) * | 2014-11-10 | 2016-08-24 | 哈尔滨工业大学无锡新材料研究院 | 一种覆膜铁用聚酯薄膜增韧的生产方法 |
-
2017
- 2017-12-13 CN CN201711324503.4A patent/CN109910402B/zh active Active
-
2018
- 2018-12-10 WO PCT/CN2018/120006 patent/WO2019114641A1/zh unknown
- 2018-12-10 EP EP18889607.0A patent/EP3725518A4/en active Pending
- 2018-12-10 US US16/771,933 patent/US11760064B2/en active Active
-
2020
- 2020-06-11 PH PH12020550865A patent/PH12020550865A1/en unknown
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CN1201420A (zh) | 1995-11-02 | 1998-12-09 | 东洋钢钣株式会社 | 层压金属板的制造方法及制造设备 |
CN1212651A (zh) | 1996-03-04 | 1999-03-31 | 东洋钢钣株式会社 | 层压金属板的制造设备 |
CN101142277A (zh) * | 2005-03-16 | 2008-03-12 | 帝人化成株式会社 | 树脂组合物 |
US20120082844A1 (en) * | 2010-09-30 | 2012-04-05 | Tdk Corporation | Powder magnetic core |
CN102431269A (zh) * | 2011-09-29 | 2012-05-02 | 上海联净环保科技有限公司 | 一种覆膜铁加工工艺及设备 |
Non-Patent Citations (1)
Title |
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See also references of EP3725518A4 |
Also Published As
Publication number | Publication date |
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CN109910402A (zh) | 2019-06-21 |
CN109910402B (zh) | 2021-08-13 |
US11760064B2 (en) | 2023-09-19 |
EP3725518A4 (en) | 2021-07-21 |
PH12020550865A1 (en) | 2021-05-17 |
BR112020010488A2 (pt) | 2020-11-10 |
EP3725518A1 (en) | 2020-10-21 |
US20200391481A1 (en) | 2020-12-17 |
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