WO2019080475A1 - Revêtement mural extérieur, procédé de préparation et agent mouillant associé - Google Patents

Revêtement mural extérieur, procédé de préparation et agent mouillant associé

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Publication number
WO2019080475A1
WO2019080475A1 PCT/CN2018/086075 CN2018086075W WO2019080475A1 WO 2019080475 A1 WO2019080475 A1 WO 2019080475A1 CN 2018086075 W CN2018086075 W CN 2018086075W WO 2019080475 A1 WO2019080475 A1 WO 2019080475A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
parts
exterior wall
content
agent
Prior art date
Application number
PCT/CN2018/086075
Other languages
English (en)
Chinese (zh)
Inventor
魏红岩
邢静
秦东杰
Original Assignee
北新集团建材股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 北新集团建材股份有限公司 filed Critical 北新集团建材股份有限公司
Publication of WO2019080475A1 publication Critical patent/WO2019080475A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Definitions

  • the present application relates to, but is not limited to, the field of coatings, and in particular, but not limited to, an exterior wall coating, a method of preparing the same, and a wetting agent.
  • the main function of the exterior latex paint is to decorate and protect the facade of the building, to make the appearance of the building clean and beautiful, to achieve the purpose of beautifying the urban environment, and at the same time to protect the external wall of the building and prolong the service life of the building. .
  • the inventor of the present application found that when the colored exterior latex paint is actually used, it often encounters the problem of floating color and blooming of the paint film, affecting the aesthetics of the wall surface, and the engineering cannot be normally accepted. In order to avoid such phenomena, it is necessary to improve the color development performance of the color paste in the latex paint.
  • the present application provides an exterior wall coating, a preparation method thereof and a wetting agent.
  • the exterior wall coating prepared by using the wetting agent has good color development performance, has no color difference, improves the decorative effect of the wall surface, and can effectively solve the problem.
  • the problem caused by the failure of the project due to the floating color of the paint film is not acceptable.
  • the application provides a wetting agent.
  • the wetting agent provided by the present application includes a nonionic surfactant and an anionic phosphate surfactant, and the weight ratio of the nonionic surfactant to the anionic phosphate surfactant is ( 3 to 5): (1 to 3).
  • the weight ratio of the nonionic surfactant to the anionic phosphate surfactant may be 3:2.
  • the nonionic surfactant may be a nonionic surfactant having an HLB value of from 17 to 18, for example, commercially available from Clariant LCN407 and Dow Chemical DB-40. All products are available.
  • the anionic phosphate surfactant may be Dispersogen LFH of Clariant.
  • the application also provides an exterior wall coating.
  • the exterior wall coatings provided herein include a wetting agent as described above.
  • the exterior wall paint may further include a cellulose ether, a dispersant, a titanium dioxide, a heavy calcium carbonate, a pH adjuster, an antifoaming agent, a styrene-acrylic emulsion, a film forming auxiliary, and an antifreezing agent. , preservatives, thickeners and water.
  • the nonionic surfactant may be included in an amount of 0.2 parts by weight to 0.3 parts by weight based on 100 parts by weight of the total amount of the exterior wall coating material, and the content of the cellulose ether. It may be 0.2 parts by weight to 0.3 parts by weight, the dispersant may be included in an amount of 1 part by weight to 1.1 parts by weight, and the titanium white powder may be contained in an amount of 10 parts by weight to 15 parts by weight, the content of the heavy calcium carbonate.
  • the pH adjusting agent may be included in an amount of 0.2 parts by weight to 0.3 parts by weight
  • the antifoaming agent may be contained in an amount of 0.5 parts by weight to 0.8 parts by weight, of the styrene-acrylic emulsion
  • the content may be from 25 parts by weight to 35 parts by weight
  • the film forming aid may be included in an amount of from 1.6 parts by weight to 2.5 parts by weight
  • the antifreeze agent may be contained in an amount of from 0.8 part by weight to 1 part by weight of the preservative.
  • the content may be from 0.1 part by weight to 0.3 part by weight
  • the thickener may be contained in an amount of from 0.5 part by weight to 0.8 part by weight, the content of the water being the balance.
  • the cellulose ether may be a cellulose ether commonly used in the art.
  • the cellulose ether may be a hydroxyethyl cellulose ether, for example, commercially available hydroxyethyl cellulose such as HBR-250 from Asialon, EBM 3000 from AkzoNobel.
  • the titanium dioxide may be titanium white powder commonly used in the art.
  • the titanium dioxide may be rutile type titanium dioxide.
  • the ground calcium carbonate may be heavy calcium carbonate commonly used in the art.
  • the ground calcium carbonate may be a heavy calcium carbonate particle having a particle size of from 700 mesh to 800 mesh.
  • the pH adjusting agent may be a pH adjusting agent commonly used in the art.
  • the pH adjusting agent may be selected from an organic amine pH adjusting agent such as AMP-95 from Angus.
  • the antifoaming agent may be an antifoaming agent commonly used in the art.
  • the antifoaming agent may be selected from a mineral oil defoaming agent or a silicone defoaming agent, for example, NXZ mineral oil defoaming agent produced by Nopko Corporation, Nopco Corporation Commercially available defoamers such as SN-154 are acceptable.
  • the film forming aid may be a film forming aid commonly used in the art.
  • the coalescent may be a dodecyl ester, such as Texanol from Eastman.
  • the antifreeze agent may be an antifreeze agent commonly used in the art.
  • the antifreeze agent may be one or both of propylene glycol and ethylene glycol.
  • the preservative may be a preservative commonly used in the art.
  • the preservative may be an isothiazolinone.
  • the thickener may be a thickener commonly used in the art.
  • the thickener may be selected from one or more of an alkali swellable thickener and a polyurethane thickener, for example, DR-72, DR- produced by Dow Chemical. 73, TT-935 and other alkali-swelling thickeners and polyurethane thickeners such as SCT-275.
  • an alkali swellable thickener and a polyurethane thickener for example, DR-72, DR- produced by Dow Chemical. 73, TT-935 and other alkali-swelling thickeners and polyurethane thickeners such as SCT-275.
  • the exterior wall paint may further include talc powder, and the talc may be contained in an amount of 4 parts by weight to 8 parts by weight relative to 100 parts by weight of the exterior wall paint.
  • the talc may be a talc powder commonly used in the art.
  • the talc may have a particle size of from 325 mesh to 400 mesh.
  • the water may be tap water or purified water.
  • cellulose ether, dispersant, pH adjuster, antifoaming agent, film forming aid, antifreeze, preservative, thickener and water used in the exterior wall coating are not limited to the specific materials listed above. Materials capable of effecting the various reagents can be used in the preparation of the exterior wall coatings of the present application, and the specific materials listed above are not intended to be any form or substantial limitation to the application.
  • the intermediate wall coating may have a medium shear viscosity at 25 ° C of 110 KU to 120 KU.
  • the exterior wall paint may further include a color paste, and the color paste may be included in an amount of 2% to 10% of the total weight of the other components of the exterior wall paint.
  • the color paste may be any color paste commercially available for use in aqueous latex paints.
  • the present application further provides a method of making an exterior wall coating as described above.
  • the method for preparing the exterior wall coating as described above provided by the present application includes:
  • Shear dispersion to the fineness of the system is less than 60 ⁇ m;
  • a color paste is added.
  • the antifoaming agent is added in two parts, but the ratio of the first partial defoaming agent to the second partial defoaming agent has no influence on the color development performance of the prepared exterior wall coating, so there is no need to limit between them. proportion.
  • the content of the first partial antifoaming agent may be greater than 50% of the total content of the antifoaming agent.
  • the inventors of the present application have unexpectedly discovered that when a conventional nonionic surfactant wetting agent is used, an anionic phosphate surfactant is introduced, and the optimum ratio of the two surfactants is determined, which is effective Control the color difference to a certain range.
  • the inventors' analysis may be due to the introduction of a specific amount of anionic phosphate surfactant, which effectively improves the dispersion stability of the color paste in the exterior wall coating, and avoids the floating color of the coloring agent due to improper selection of the thickener. The problem is to ensure the color uniformity of the paint during the painting process.
  • the wetting agent of the present application when used as a component of the exterior wall coating, there is no limitation in selecting a thickener for the exterior wall coating, when an alkali-swelling thickener, a polyurethane thickener or a combination thereof is selected.
  • a thickener for the exterior wall coating when an alkali-swelling thickener, a polyurethane thickener or a combination thereof is selected.
  • the prepared exterior wall paint can fully meet the performance requirements of the latex paint, such as: gloss, water resistance, leveling, film fullness, splash resistance, etc.
  • the external wall coating provided by the present application is With excellent color development performance, you can get the best product quality.
  • the exterior wall paint of the present application improves the decorative effect of the wall surface, avoids the failure of the project to be properly accepted due to the floating color, and saves the cost incurred in the later repair, and has extensive economic and social benefits.
  • the prepared exterior wall coating has a low shear viscosity of 25000-30000 centipoise at 25 ° C, a medium shear viscosity of 110-120 KU, and a high shear viscosity of 0.9-1.1 ICI.
  • fibroin retinoic acid 1.0kg of copolymer ammonium salt dispersant, 0.25kg of nonionic surfactant with HLB value of 17 to 18, 0.25kg of anionic phosphate surfactant, 0.3kg of antifoaming agent, 11kg Rutile titanium dioxide, 23kg 700 mesh heavy calcium carbonate, 8kg 400 mesh talc, 0.3kg pH adjuster added to the balance (ie 25.85kg) of purified water, high speed shear dispersion to the system fineness less than 60 ⁇ m;
  • the prepared exterior wall coating has a low shear viscosity of 27,000 to 30,000 centipoise at 25 ° C, a medium shear viscosity of 115 to 120 KU, and a high shear viscosity of 0.9 to 1.0 I CI.
  • 0.3 kg of fibroin retinoic acid 1.0 kg of copolymer ammonium salt dispersant, 0.3 kg of nonionic surfactant having a HLB value of 17 to 18, 0.2 kg of an anionic phosphate surfactant, 0.3 kg of antifoaming agent, 13 kg Rutile titanium dioxide, 24kg 700 mesh heavy calcium carbonate, 4kg 400 mesh talc, 0.3kg pH adjuster added to the balance (ie 25.6kg) of purified water, high speed shear dispersion to the system fineness less than 60 ⁇ m;
  • the prepared exterior wall coating has a low shear viscosity of 25000-30000 centipoise at 25 ° C, a medium shear viscosity of 110-120 KU, and a high shear viscosity of 0.9-1.1 ICI.
  • fibroin retinoic acid 1.0 kg of copolymer ammonium salt dispersant, 0.3 kg of nonionic surfactant having a HLB value of 17 to 18, 0.2 kg of an anionic phosphate surfactant, 0.3 kg of antifoaming agent, 13 kg Rutile titanium dioxide, 24kg 700 mesh heavy calcium carbonate, 5kg 400 mesh talc, 0.3kg pH adjuster added to the balance (ie 19.5kg) of purified water, high speed shear dispersion to the system fineness less than 60 ⁇ m;
  • the prepared exterior wall coating has a low shear viscosity of 25000-30000 centipoise at 25 ° C, a medium shear viscosity of 110-120 KU, and a high shear viscosity of 0.9-1.2 ICI.
  • fibroin retinoic acid 1.0 kg of copolymer ammonium salt dispersant, 0.3 kg of nonionic surfactant having a HLB value of 17 to 18, 0.2 kg of an anionic phosphate surfactant, 0.3 kg of antifoaming agent, 15 kg Rutile titanium dioxide, 22kg 700 mesh heavy calcium carbonate, 4kg 400 mesh talc, 0.3kg pH adjuster added to the balance (ie 19.2kg) of purified water, high speed shear dispersion to the system fineness less than 60 ⁇ m;
  • the prepared exterior wall coating has a low shear viscosity of 25000-30000 centipoise at 25 ° C, a medium shear viscosity of 110-120 KU, and a high shear viscosity of 1.0-1.1 ICI.
  • a color model (Lab) is used that describes all the colors that a person with normal vision can see.
  • Simple Lab is an absolute value. These three values can be used to accurately represent a point of a color in a three-dimensional view. The relative value can be used to obtain a difference from the reference point for correction.
  • ⁇ E ( ⁇ L 2 + ⁇ a 2 + ⁇ b 2 ) 1/2 ;
  • ⁇ a a means pre-study- a refers to post-study ;
  • L lightness, indicating the range from white to black
  • Example 1 0.3 0.22 0.90
  • Example 2 0.25 0.16 0.65
  • Example 3 0.6 0.23 0.79
  • Example 4 0.55 0.46 0.85
  • Example 5 0.79 0.25 0.88
  • the exterior wall paint provided by the application improves the decorative effect of the wall surface, avoids the failure of the project to be properly accepted due to the floating color, and saves the cost incurred in the later repair, and has extensive economic and social benefits.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne un revêtement mural extérieur et un agent mouillant associé. L'agent mouillant comprend un tensioactif non ionique et un tensioactif ester de phosphate anionique, et le rapport en poids du tensioactif non ionique au tensioactif ester de phosphate anionique est (3-5)/(1-3). Le revêtement mural extérieur comprend ledit agent mouillant. La présente invention concerne également un procédé de préparation dudit revêtement mural extérieur.
PCT/CN2018/086075 2017-10-23 2018-05-08 Revêtement mural extérieur, procédé de préparation et agent mouillant associé WO2019080475A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710995126.0 2017-10-23
CN201710995126.0A CN109694604A (zh) 2017-10-23 2017-10-23 一种外墙涂料及其制备方法和润湿剂

Publications (1)

Publication Number Publication Date
WO2019080475A1 true WO2019080475A1 (fr) 2019-05-02

Family

ID=66225983

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2018/086075 WO2019080475A1 (fr) 2017-10-23 2018-05-08 Revêtement mural extérieur, procédé de préparation et agent mouillant associé

Country Status (2)

Country Link
CN (1) CN109694604A (fr)
WO (1) WO2019080475A1 (fr)

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WO2022088119A1 (fr) * 2020-10-30 2022-05-05 河北比尔尼克新材料科技股份有限公司 Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau

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CN113913044A (zh) * 2021-10-21 2022-01-11 雅士利涂料（苏州）有限公司 一种复配型润湿剂及其制备方法和应用

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CN102321417A (zh) * 2011-08-16 2012-01-18 河南城建学院 一种外墙防火乳胶漆
CN104302717A (zh) * 2012-05-23 2015-01-21 塞拉尼斯乳液有限公司 含水胶乳基涂料组分
CN103626914A (zh) * 2013-11-29 2014-03-12 中国石油天然气股份有限公司 一种降凝降粘剂及其制备方法
CN105297057A (zh) * 2015-11-09 2016-02-03 广东新球清洗科技股份有限公司 一种碳氢除油除锈清洗剂
CN105557717A (zh) * 2016-03-03 2016-05-11 江苏丰山集团股份有限公司 一种双氟磺草胺悬浮剂及其制备方法
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022088119A1 (fr) * 2020-10-30 2022-05-05 河北比尔尼克新材料科技股份有限公司 Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau

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