WO2022088119A1 - Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau - Google Patents
Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau Download PDFInfo
- Publication number
- WO2022088119A1 WO2022088119A1 PCT/CN2020/125600 CN2020125600W WO2022088119A1 WO 2022088119 A1 WO2022088119 A1 WO 2022088119A1 CN 2020125600 W CN2020125600 W CN 2020125600W WO 2022088119 A1 WO2022088119 A1 WO 2022088119A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- parts
- water
- based paint
- acrylic resin
- plastic board
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 142
- 239000003973 paint Substances 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 title abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000002131 composite material Substances 0.000 title abstract description 4
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 49
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 49
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 39
- 238000003756 stirring Methods 0.000 claims abstract description 31
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 26
- 239000013530 defoamer Substances 0.000 claims abstract description 24
- 229920001225 polyester resin Polymers 0.000 claims abstract description 24
- 239000004645 polyester resin Substances 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000000080 wetting agent Substances 0.000 claims abstract description 23
- 238000001816 cooling Methods 0.000 claims abstract 2
- 239000004033 plastic Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 40
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 239000012855 volatile organic compound Substances 0.000 description 10
- 230000009286 beneficial effect Effects 0.000 description 7
- 238000000576 coating method Methods 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003471 anti-radiation Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
Definitions
- the invention relates to the technical field of environmental protection coatings, in particular to a water-based paint for high-imitation aluminum-plastic panels and a preparation method thereof.
- Water-based paint also known as water-based anti-rust paint, water-based steel structure paint, water-based floor paint, water-based wood paint, is harmless to the human body and does not pollute the environment. , anti-aging, anti-yellowing, fast drying, easy to use and so on. Water-based paint can effectively reduce the VOC content in the atmosphere by replacing paint with water-based paint, thereby improving haze weather.
- the purpose of the present invention is to provide a high-imitation aluminum-plastic board water-based paint and a preparation method thereof to solve the deficiencies in the prior art.
- a high-imitation water-based paint for aluminum-plastic panels comprising the following raw materials in parts by weight: 15-20 parts of water-based fluorocarbon modified acrylic resin, 45-50 parts of water-based saturated polyester resin, 15-20 parts of water-based silicone acrylic resin, and color paste 15-20 parts, defoamer 3-5 parts, leveling agent 2-5 parts, wetting agent 2-10 parts, dispersant 5-15 parts and adhesion promoter 2-10 parts;
- 16-18 parts of water-based fluorocarbon modified acrylic resin 46-48 parts of water-based saturated polyester resin, 16-18 parts of water-based silicone acrylic resin, 16-18 parts of color paste, 4-5 parts of defoamer, 3-5 parts of leveling agent, 4-8 parts of wetting agent, 8-13 parts of dispersant and 4-8 parts of adhesion promoter.
- the beneficial effects of the present invention are that the water-based fluorocarbon modified acrylic resin has excellent weather resistance, corrosion resistance, stain resistance, heat resistance, chemical resistance, hydrophobicity and oleophobicity, insulation and low coefficient of friction; Saturated polyester resin has many physical and chemical characteristics such as good adhesion, toughness, high fullness and high gloss; water-based silicone acrylic resin takes into account the super weather resistance of special silicone resins and the high decorative properties of acrylic resins, with excellent fullness and protection. Good light and color retention effect, durability, excellent weather resistance, no discoloration, compatible with water in any proportion, low viscosity, high solid content, low odor, good leveling, safety and environmental protection.
- the water-based paint prepared from the above-mentioned raw materials in the present invention has moderate viscosity, uniform dispersion of raw materials, good adhesion, fast drying, good film-forming, leveling, anti-corrosion, and strong operability, and can be sprayed, brushed or electrostatically sprayed. It can meet the required transparency and anti-corrosion performance standards; and the product is odorless, non-polluting, non-flammable and non-explosive.
- the above-mentioned color paste is a metallic color paste.
- the metal color paste of the present invention is natural and environmentally friendly, high-quality and healthy, soft in color, beautiful in decoration, strong in weather resistance, superior in rationality, strong in waterproof and moisture-proof, and ventilated and dry.
- the above-mentioned antifoaming agent is a nonionic silicone antifoaming agent.
- the beneficial effect of adopting the above-mentioned further technical scheme is that the nonionic silicone defoamer of the present invention has excellent stability, is easy to disperse in water, and is compatible with the foaming medium in the system.
- adhesion promoter is a polyether compound.
- the adhesion promoter of the present invention can obviously improve the bonding force between the resin and various substrates, has high adhesion force, adhesive force and bonding force, and can greatly improve the paint finish and primer.
- the interlayer adhesion between paints significantly improves the moisture resistance, salt spray resistance and heat resistance of the coating film, and has excellent storage stability and long-term durability in paint and coating systems.
- a preparation method of high imitation aluminum-plastic board water-based paint specifically comprising the following steps:
- the beneficial effect of the present invention is that the preparation method has a simple process and is suitable for large-scale production.
- the stirring speed is 1200-1600r/min, preferably 1500r/min; the time is 15-25min, preferably 20min.
- the stirring speed is 100-300r/min, preferably 200r/min; the time is 5-10min, preferably 8min; naturally cooled to 20-30°C, preferably 25°C.
- the water-based paint of the present invention uses water as a solvent, which saves a lot of resources, is odorless, non-flammable and non-explosive, and does not contain VOC harmful substances such as benzene, xylene, ethane, formaldehyde, etc., eliminates fire hazards during construction and storage, reduces In order to avoid the pollution to the atmosphere, the construction can be carried out as usual in a closed environment;
- the water-based paint of the present invention has strong adhesion on the exterior wall surface, strong weather resistance, excellent anti-corrosion performance, anti-radiation, and simple operation performance. injury to construction workers;
- the water-based paint of the present invention can be directly stirred without any grinding procedure, and the preparation method is simple and reliable.
- model of each raw material and its manufacturer information are as follows:
- Water-based fluorocarbon modified acrylic resin model SN-3760, the manufacturer is Shanghai Shenzhu Chemical Technology Co., Ltd.;
- the model is TSA-10A, the manufacturer is Jiangsu Tengda Auxiliary Co., Ltd.;
- Leveling agent the model is AFCONA-3777, the manufacturer is Haimen Efcona Co., Ltd.;
- wetting agent the model is SINPOLS 530, the manufacturer is Shanghai Zhongjihang Chemical Co., Ltd.;
- Dispersant the model is XN 3800, the manufacturer is Shanghai Zhongjixing Chemical Co., Ltd.;
- Adhesion promoter the model is TL-BPA, and the manufacturer is Okter Chemical Co., Ltd.
- High imitation aluminum-plastic board water-based paint including the following raw materials: 15kg of water-based fluorocarbon modified acrylic resin, 45kg of water-based saturated polyester resin, 15kg of water-based silicone acrylic resin, 15kg of metal color paste, and 3kg of non-ionic silicone defoamer , 2kg of leveling agent, 2kg of wetting agent, 5kg of dispersant and 2kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- High imitation aluminum-plastic board water-based paint including the following raw materials: water-based fluorocarbon modified acrylic resin 16kg, water-based saturated polyester resin 4kg, water-based silicone acrylic resin 16kg, metal color paste 16kg, non-ionic silicone defoamer 4kg , 3kg of leveling agent, 4kg of wetting agent, 8kg of dispersant and 4kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- High imitation aluminum-plastic board water-based paint including the following raw materials: 16kg of water-based fluorocarbon modified acrylic resin, 46kg of water-based saturated polyester resin, 16kg of water-based silicone acrylic resin, 18kg of metal color paste, and 5kg of non-ionic silicone defoamer , 5kg of leveling agent, 8kg of wetting agent, 13kg of dispersant and 8kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- High imitation aluminum-plastic board water-based paint including the following raw materials: water-based fluorocarbon modified acrylic resin 18kg, water-based saturated polyester resin 48kg, water-based silicone acrylic resin 18kg, metal color paste 18kg, non-ionic silicone defoamer 5kg , 5kg of leveling agent, 8kg of wetting agent, 13kg of dispersant and 8kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- High imitation aluminum-plastic board water-based paint including the following raw materials: water-based fluorocarbon modified acrylic resin 20kg, water-based saturated polyester resin 50kg, water-based silicone acrylic resin 20kg, metal color paste 20kg, non-ionic silicone defoamer 5kg , 5kg of leveling agent, 10kg of wetting agent, 15kg of dispersant and 10kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- High imitation aluminum-plastic board water-based paint including the following raw materials: water-based fluorocarbon modified acrylic resin 16kg, water-based saturated polyester resin 46kg, water-based silicone acrylic resin 16kg, metal color paste 16kg, non-ionic silicone defoamer 4kg , 4kg of leveling agent, 5kg of wetting agent, 10kg of dispersant and 5kg of polyether compound adhesion promoter;
- the preparation method of the above-mentioned high imitation aluminum-plastic board water-based paint specifically comprises the following steps:
- the water-based paint of the present invention is a uniform and non-hard-block water-based liquid product with low fineness, high gloss and hardness, and excellent blocking resistance, scratch resistance, water resistance, alkali resistance and solvent resistance.
- VOC Volatile organic compound
- MDL means detection limit
- ND means not detected.
- the water-based paint of the present invention does not contain soluble heavy metal elements such as lead, palladium, cadmium, chromium and mercury, nor does it contain soluble pollution elements such as arsenic and selenium. It shows that the water-based paint of the present invention is safe, environmentally friendly, and pollution-free.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Peinture à base d'eau imitant fortement un panneau composite d'aluminium, et procédé de préparation de la peinture à base d'eau. La peinture comprend les matières premières suivantes en parties en poids : de 15 à 20 parties d'une résine acrylique modifiée par un fluorocarbone à l'eau, de 45 à 50 parties d'une résine de polyester saturé à l'eau, de 15 à 20 parties d'une résine acrylique de silicone à l'eau, de 15 à 20 parties d'une pâte de couleur, de 3 à 5 parties d'un agent antimousse, de 2 à 5 parties d'un agent d'étalement, de 2 à 10 parties d'un agent mouillant, de 5 à 15 parties d'un dispersant et de 2 à 10 parties d'un promoteur d'adhésion. Le procédé de préparation consiste à : (1) peser les matières premières ; (2) mélanger et agiter la résine acrylique modifiée par un fluorocarbone à l'eau, la résine de polyester saturé à l'eau et la résine acrylique de silicone à l'eau ; (3) ajouter ledit mélange à la pâte de couleur, agiter et refroidir de façon naturelle ; et (4), dans des conditions d'agitation, séquentiellement ajouter l'agent antimousse, l'agent d'étalement, l'agent mouillant, l'agent dispersant et le promoteur d'adhésion pour obtenir la peinture. La peinture permet d'obtenir une dispersion uniforme des matières premières, présente une viscosité modérée, une bonne adhésion, un taux de séchage élevé, une bonne propriété de formation de film, une propriété d'étalement, une résistance à la corrosion, et une facilité d'application élevée, peut complètement remplacer des panneaux composites d'aluminium, et permet d'économiser des ressources.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2020/125600 WO2022088119A1 (fr) | 2020-10-30 | 2020-10-30 | Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2020/125600 WO2022088119A1 (fr) | 2020-10-30 | 2020-10-30 | Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022088119A1 true WO2022088119A1 (fr) | 2022-05-05 |
Family
ID=81383519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2020/125600 WO2022088119A1 (fr) | 2020-10-30 | 2020-10-30 | Peinture à base d'eau imitant fortement un panneau composite d'aluminium et procédé de préparation de la peinture à base d'eau |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2022088119A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115340793A (zh) * | 2022-08-11 | 2022-11-15 | 广东镭宝光电科技有限公司 | 一种水性乳液及其在镭射全息电化铝烫印膜中的应用 |
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- 2020-10-30 WO PCT/CN2020/125600 patent/WO2022088119A1/fr active Application Filing
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|---|---|---|---|---|
| CN115340793A (zh) * | 2022-08-11 | 2022-11-15 | 广东镭宝光电科技有限公司 | 一种水性乳液及其在镭射全息电化铝烫印膜中的应用 |
| CN115340793B (zh) * | 2022-08-11 | 2023-07-14 | 广东镭宝光电科技有限公司 | 一种水性乳液及其在镭射全息电化铝烫印膜中的应用 |
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