WO2018182255A1 - Composition cosmétique anti-pollution comprenant une poudre sphérique - Google Patents

Composition cosmétique anti-pollution comprenant une poudre sphérique Download PDF

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Publication number
WO2018182255A1
WO2018182255A1 PCT/KR2018/003523 KR2018003523W WO2018182255A1 WO 2018182255 A1 WO2018182255 A1 WO 2018182255A1 KR 2018003523 W KR2018003523 W KR 2018003523W WO 2018182255 A1 WO2018182255 A1 WO 2018182255A1
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Prior art keywords
cosmetic composition
powder
group
pollution
weight
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PCT/KR2018/003523
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English (en)
Korean (ko)
Inventor
서호중
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(주)아모레퍼시픽
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Publication of WO2018182255A1 publication Critical patent/WO2018182255A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/025—Explicitly spheroidal or spherical shape
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • an anti-pollution cosmetic composition having an excellent dustproof effect against fine dust and the like.
  • the skin acts as a barrier between the organism and the environment in the outermost part of our body, which is in direct contact with dust, which often degrades when directly exposed to contamination.
  • the fine dust is 20 times smaller than the pores, so it can easily penetrate the skin.
  • air pollutants such as fine dust have been known to seriously affect skin health.
  • premature aging, lack of moisture, fine lines and wrinkles, and irreversible skin damage in the long run can lead to serious illnesses such as skin cancer, as the skin loses its ability to protect itself from environmental factors. .
  • the object of the present invention is to prevent contaminants from adhering to the skin.
  • an object of the present invention is to improve the bone repelling effect of the cosmetic composition by including a high content of spherical powder.
  • an object of the present invention is to prevent or minimize contamination of the skin due to fine dust.
  • the present invention in the anti-pollution cosmetic composition, provides an anti-pollution cosmetic composition comprising at least 20% by weight of the spherical powder based on the total weight of the total composition.
  • the anti-pollution cosmetic composition of the present invention can minimize the penetration of dust, in particular fine dust into the skin.
  • the spherical powder contained in a high content to improve the applicability of the formulation to help apply evenly on the surface of the skin, the effect of filling the bone of the skin surface is also excellent, the surface coated with particles in the spherical powder
  • the surface coated with particles in the spherical powder By forming three-dimensional fine protrusions on the surface, it is possible to minimize the adhesion of dust to the skin surface.
  • the plate-shaped powder it is possible to prevent the dust from sticking to the skin during application and preventing the dust from penetrating into the skin.
  • by preventing the penetration of fine dust it is possible to minimize the skin inflammation, heavy metal accumulation due to this, it is beneficial to skin health.
  • FIG. 1A is a SEM photograph of artificial leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention
  • FIG. 1B is a SEM photograph of artificial leather coated with the cosmetic composition of Comparative Example 1. Taken under a microscope).
  • Figure 2a is a photograph of the artificial leather surface coated with the anti-pollution cosmetic composition of Example 1 of the present invention with a digital camera
  • Figure 2b is a photograph of the artificial leather surface coated with the cosmetic composition of Comparative Example 1 with a digital camera It is.
  • 3A is a 3D scan photograph of a synthetic leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention, and magnified by 50 times, and shows the difference in height in color
  • FIG. 3B illustrates the cosmetic composition of Comparative Example 1
  • the coated artificial leather is magnified 50 times by 3D scan, and the difference in height is expressed in color.
  • Figure 4a is taken after 10 minutes convection of the artificial leather coated with oil and the anti-pollution cosmetic composition of Example 1 of the present invention in a fine dust convection box
  • Figure 4b is a fine dust convection of artificial leather coated with oil only After the convection in the box for 10 minutes, it is taken
  • Figs. 4c and 4d is taken after 10 minutes convection in artificial dust coated with the cosmetic composition of Comparative Examples 1 and 2 in a fine dust convection box.
  • the term “anti-pollution” refers to preventing or minimizing the adhesion of contaminants, such as dust, to the skin, or the removal of contaminants adhering to the skin from the skin to penetrate the skin. I mean. That is, when the anti-pollution cosmetic composition of the present disclosure is applied to the skin, it is possible to minimize the adhesion of contaminants to the skin due to the excellent bone repelling effect, and compared to the plate-like powder, the dust is less at the time of application It can prevent dust from penetrating the skin.
  • dust refers to particulates mixed in the air, and refers to suspended solids having a particle diameter of usually 10 mm or less. Particularly, when the particle diameter is 10 ⁇ m or less, it is also referred to as fine dust and when it is 0.1 ⁇ m or less, it is also referred to as ultra fine dust. Dust is a material including materials derived from nature such as sand, soil and pollen, or materials derived from industrial processes such as carbon, carbon combusted products, metal salts and heavy metals, and the like. The presence of dust can be fume, mist, smoke, steam or mist.
  • particle group means a collection of single particles.
  • particle diameter refers to a particle diameter
  • average particle diameter of the first particle group to the second particle group refers to the diameter of each single particle belonging to the first particle group to the second particle group.
  • the mean value, and the "average particle diameter" of the plate-shaped powder means the average value of the diagonal length of the widest cross section of the particle.
  • the term “thickness” refers to the thickness of the vertical cross-section perpendicular to the widest cross-section of the particles of the plate-shaped powder, and refers to the shortest diameter.
  • the present invention is an anti-pollution cosmetic composition comprising at least 20% by weight of spherical powder, based on the total weight of the total composition.
  • Spherical powder is a powder that forms a spherical shape, it is included in the powder cosmetic composition to give a smooth and light texture.
  • Spherical powder has the effect of diffusing light in all directions, and excellent effect of concealing the defects of the skin such as pores and acne traces compared to the flake powder.
  • the powder cosmetic composition having a high proportion of spherical powder is effective for natural skin production, and has an effect of improving the holding force of the cosmetic film, and is suitable for fixing the cosmetic film and correcting makeup.
  • the present inventors in the case of a cosmetic composition containing a large amount of spherical powder, to improve the applicability of the formulation to be uniformly applied on the surface of the skin, excellent effect of bridging the bone of the skin surface, the particles in the spherical powder It was confirmed that the anti-pollution effect is excellent by forming fine protrusions to prevent fine dust adhesion.
  • the content of the spherical powder may be 20% by weight or more, for example, 25% by weight, 30% by weight, 35% by weight, 40% by weight, or 45% by weight or more, 50% by weight It may be less than or equal to%.
  • the content is less than 20% by weight, the bone glendal effect is insignificant, the micro-protrusion is not sufficient enough that the anti-pollution effect may be insignificant, when the content is greater than 50% by weight due to the voids and repulsive force between the powder particles during manufacture It can be difficult to prepare with compressed powder formulations.
  • the spherical powder includes a first particle group having an average particle diameter of less than 5 ⁇ m and a second particle group of 5 ⁇ m or more, and a weight ratio of the first particle group and the second particle group is 1: 1.1 to 1. May be eight.
  • the weight ratio is within the above range, it helps the particles of different sizes to be applied uniformly and densely, and also has the effect of filling the bones on the surface of the skin, and forms fine protrusions on the surface of the applied skin to prevent adsorption of contaminants. It protects the skin.
  • the particle size of the second particle group may be 50 ⁇ m or less, 45 ⁇ m or less, 40 ⁇ m or less, 35 ⁇ m or less, or 30 ⁇ m or less. If the particle size of the second particle group is out of the above range, there is a difficulty in compression molding, a problem may occur in the formulation stability, such as the formulation is broken when falling.
  • the weight ratio is 1: 1.1 to 1: 7.6, 1: 1.2 to 1: 7.2, 1: 1.3 to 1: 6.8, 1: 1.4 to 1: 6.4, 1: 1.5 to 1: 6, 1: 1.6 to 1. : 5.6, 1: 1.7 to 1: 5.2, 1: 1.8 to 1: 4.8, 1: 1.9 to 1: 4.4, or 1: 2 to 1: 4, but is not limited thereto.
  • the spherical powder includes a first particle group having an average particle diameter of less than 5 ⁇ m, a 2-1 particle group having a particle size of 5 ⁇ m or more and less than 10 ⁇ m, and a second particle group having a particle size of 10 ⁇ m or more.
  • the weight ratio of the first particle group, the 2-1 particle group, and the 2-2 particle group may be 1: 0.6: 0.5 to 1: 3: 5.
  • the particle diameter of the 2-2 particle group may be 50 ⁇ m or less, 45 ⁇ m or less, 40 ⁇ m or less, 35 ⁇ m or less, or 30 ⁇ m or less.
  • the weight ratio is 1: 0.6: 0.5 to 1: 2.8: 4.8, 1: 0.65: 0.55 to 1: 2.6: 4.6, 1: 0.7: 0.6 to 1: 2.4: 4.4, 1: 0.75: 0.65 to 1: 2.2 : 4.2, 1: 0.8: 0.7 to 1: 2: 2: 4, 1: 0.85: 0.75 to 1: 1.8: 3.8, 1: 0.9: 0.8 to 1: 1.6: 3.6, 1: 0.95: 0.85 to 1: 1.4: 3.4 , 1: 1: 0.9 to 1: 1.2: 3.2, or 1: 1.05: 0.95 to 1: 1: 3, but is not limited thereto.
  • the spherical powder may include one or more selected from the group consisting of inorganic particles, organic particles, and organic-inorganic composite particles.
  • the inorganic particles preferably use silica.
  • the silica is a porous spherical powder, has a high oil absorption, has an effect of maintaining the persistence of the makeup film, has a low refractive index, high transparency, and has the advantage of uniformly applying other powders.
  • compression molding is difficult when using a high content of silica, it is preferable to use within 30% by weight of the total weight of the cosmetic composition, and more preferably within 20% by weight because it may dry the skin.
  • the organic particles are, for example, polystyrene, polymethyl methacrylate, polyethylene, nylon 6, nylon 12, ethylene / acrylic acid copolymer, polymethyl methacrylate / ethylene glycol dimethacrylate copolymer, polyallyl methacrylate / Ethylene glycol dimethacrylate copolymer, ethylene glycol dimethacrylate / lauryl methacrylate copolymer, crosslinked acrylate / ethylhexyl acrylate copolymer, polyurethane, and combinations thereof.
  • polymethylmethacrylate and ethylene / acrylic acid copolymers are preferable in terms of formability, light spreadability, and a boosting effect of the cosmetic film.
  • the organic-inorganic composite particles may be, for example, polymethylsilsesquioxane, silicone resin powder, organic silicon particles, silica surface-treated with an organic material, and combinations thereof.
  • the silicone resin powder may be specifically an organopolysiloxane elastomer powder coated with a silicone resin such as silsesquioxane resin, and more specifically, may be vinyl dimethicone / methicone silsesquioxane crosspolymer.
  • the organic silicon particles may be, for example, methylsilanol / silicate crosspolymers, and the silica surface treated with the organic material may be, for example, silica coated with polydimethylsiloxane, but is not limited thereto.
  • the spherical powder is used by mixing one or more kinds, the combination is not limited and may be various, but preferably includes one or more of inorganic particles, one or more of organic particles.
  • the inorganic particles are preferably contained in 10 to 30% by weight, the organic particles in 5 to 20% by weight in the total composition.
  • the above numerical range is satisfied, it can be molded into compressed powder formulations without wet molding and exhibits excellent drop stability.
  • by including the inorganic and organic particles in the above numerical range can satisfy the weight ratio of the first particle group to the second particle group of the spherical powder.
  • the spherical powder comprises inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be an ethylene / acrylic acid copolymer.
  • the spherical powder includes inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be a combination of polymethylmethacrylate and ethylene / acrylic acid copolymer.
  • the spherical powder may include one or more selected from the group consisting of silica, polymethylmethacrylate, and ethylene / acrylic acid copolymer.
  • the cosmetic composition may further comprise a plate-like powder and an oil binder.
  • the plate-shaped powder is to impart compression moldability, coverage, skin adhesion and adhesion properties
  • the type of the plate-shaped powder is not particularly limited in the present invention may be used a plate-shaped powder commonly used in the art.
  • the plate-shaped powder has an average thickness of 0.1 to 1.0 ⁇ m, an average particle diameter of 1 to 100 ⁇ m, and an aspect ratio obtained by dividing the average particle diameter by the average thickness is 10 or more, in terms of compression moldability, coverage, skin adhesion and usability. Do.
  • the plate-like powder is talc, mica, boron nitride, barium sulfate, alumina sericite, kaolin, and Synthetic Fluorphlogopite may be one or more selected from the group consisting of, preferably talc is used.
  • Talc has no elasticity and almost all kinds can be molded when the average particle size is less than 10 ⁇ m. Since talc has low powder blowing and strong drop stability after molding, it is suitable for implementing compressed powder formulations. The larger the size of the talc powder, the less dense the moldability is, and therefore, talc powder having an average particle size of 4 to 9 ⁇ m, more preferably 6 to 7 ⁇ m, is used.
  • the content of the plate-like powder may be 40% by weight or more and less than 80% by weight based on the total weight of the total composition.
  • the content of the plate-shaped powder is less than 40% by weight, it is difficult to be formulated into compressed powder, and when the content is 80% by weight or more, the content of the spherical powder is lowered, so that a cosmetic composition with less agglomeration can not be obtained. do.
  • the oil binder is to increase the binding force between the powder particles
  • the kind of the oil binder is not particularly limited in the present invention may be a plate-like powder commonly used in the art.
  • the oil binder is hexyl laurate, dicaprylyl carbonate, diisostearyl malate, butylene glycol dicaprylate / dicaprate dicaprylate / dicaprate, Cetyl ethylhexanoate, Triethylhexanoin, Dicetearyl dimer dilinoleate, Caprylic / Capric triglyceride Triglyceride), ester-based oil selected from the group consisting of Polyglyceryl-2 Triisostearate and Pentaerythrityl Tetraisostearate; Hydrocarbon-based oils selected from the group consisting of polybutene, hydrogenated polyisobutene and phytosqualane; It may be at least one selected from the group consisting of silicone-based oils selected from the group consisting of phenyl trimethicone (Phenyl trimethicone) and dimethicone (Dimethicone). Among them, diisostearyl
  • the content of the oil binder may be 5 to 20% by weight based on the total weight of the total composition, more preferably contained in 5 to 10% by weight. If the content of the oil binder is less than 5% by weight dry compression molding is difficult, there is a problem that the drop stability, the powder blowing phenomenon occurs, and if the content of the oil binder exceeds 20% by weight because the agglomeration of powder occurs Adjust appropriately within the range.
  • the cosmetic composition according to the present invention may further comprise a pigment in order to compensate for the skin defects and give a bright color.
  • a pigment in order to compensate for the skin defects and give a bright color.
  • the kind of such pigments is not particularly limited, and white or colored inorganic or organic particles can be used as those commonly used in the art.
  • Inorganic pigments include, for example, titanium dioxide, zirconium oxide or cerium oxide, surface treated or untreated, zinc oxide, iron oxide (black, yellow, or red), chromium oxide, manganese violet, ultramarine blue, chromium hydroxide hydrate ( chromium hydrate and ferric blue, aluminum powder and copper powder may be used.
  • organic pigments examples include cochinyl extract dyes, azo dyes, anthraquinone dyes, indigo dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes, and fluorane dyes.
  • the content of such pigments is not particularly limited in the present invention, but may preferably be included in the range of 0.1 to 10% by weight of the total weight of the composition.
  • the cosmetic composition is an oil and fat component, moisturizer, softener, surfactant, organic and inorganic pigment, organic powder, ultraviolet absorbent, preservative, thickener, fungicide, antioxidant, plant extract, pH adjuster, alcohol, pigment, flavoring, blood circulation It may further include any one or more of an accelerator, a cooling agent, a restriction agent.
  • cosmetics may refer to any material that may have a medical function in addition to the cosmetic function.
  • the cosmetic composition may be a compressed powder formulation, more specifically powder pact, foundation, two-way cake, eyebrow, eyeshadow ), A blusher, a highlighter, a concealer and other cosmetics with other functions.
  • the particle diameter can be dust-proof fine dust 10 ⁇ m or less.
  • the particle size is not limited and may be 100 ⁇ m or less, 90 ⁇ m or less, 70 ⁇ m or less, 50 ⁇ m or less, 30 ⁇ m or less, 20 ⁇ m or less, 15 ⁇ m or less, or 10 ⁇ m or less.
  • the cosmetic composition according to the present invention is spherical powder of various sizes is smoothly applied on the skin to be excellent in bone repellent effect to dust the fine dust, it is possible to prevent the attachment of fine dust by forming a fine projection.
  • the anti-pollution cosmetic composition of the present invention is prepared through mixing, grinding, filtration, and compression molding of raw materials.
  • Mixing and pulverization is not particularly limited, and a general method used in the art may be used, and for example, a 'mixer for mixing contents using high speed rotation of an impeller' such as a food mixer or Henschel mixer may be used.
  • a ball mill, a disintegrator in a crusher, a screen mill in an crusher, an atomizer; a hammer mill, a pin mill And it may be performed using any one selected from the group comprising an air jet mill (Air Jet Mill).
  • the compression molding method is not particularly limited, and a general method used in the art can be used, and can be molded using, for example, a press machine.
  • the cosmetic composition prepared by the above method may measure the hardness using a Teclock type A hardness meter. At this time, the cosmetic composition preferably has a hardness of 10 to 60, more preferably 30 to 50.
  • Example 1 The cosmetic composition of Example 1, Example 2, Comparative Example 1 and Comparative Example 2 was prepared using the prescription of Table 1, and the particle groups of the spherical powder according to the formulation of Table 1 were analyzed, and the results were as shown in Table 2. .
  • Prescription spherical powder content (% by weight) Spherical powder particle group (wt%) First particle group 2-1 particle group 2-2 particle group
  • Example 1 After applying the cosmetic composition of Example 1 and the comparative example 1 to artificial leather, the surface was image
  • White artificial leather was attached to the slide glass with a double-sided tape, and according to the content of Table 3 below, evenly spreading the artificial sebum or cosmetic composition with a spatula to prepare a skin replica test body.
  • the artificial leather was placed in a fine dust convection box (75 cm X 75 cm X 100 cm), 0.5 g of carbon black was weighed into a convection box, and convection was performed for 10 minutes. Thereafter, the samples were taken out and surface blown, and the states before and after the convection test were compared.

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  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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Abstract

L'invention concerne une composition cosmétique anti-pollution. La composition cosmétique anti-pollution comprend au moins 20 % en poids de poudre sphérique par rapport au poids total de la composition. La composition cosmétique comprend une teneur élevée de poudre sphérique de façon à améliorer la propriété de couverture de la préparation et d'aider la préparation à recouvrir la surface de la peau de façon uniforme, se révèle extrêmement efficace en matière de comblement des rides à la surface de la peau, et forme des micro-protubérances à la surface de la peau, ce qui est à l'origine d'un excellent effet anti-pollution.
PCT/KR2018/003523 2017-03-31 2018-03-26 Composition cosmétique anti-pollution comprenant une poudre sphérique WO2018182255A1 (fr)

Applications Claiming Priority (2)

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KR10-2017-0041950 2017-03-31
KR1020170041950A KR102262308B1 (ko) 2017-03-31 2017-03-31 구상 파우더를 포함하는 안티-폴루션 화장료 조성물

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KR102151859B1 (ko) 2018-12-17 2020-09-03 한국세라믹기술원 표면개질된 TiO2 및 ZnO를 함유하는 미세먼지 세정용 화장료 조성물의 제조방법
KR102127053B1 (ko) 2018-12-17 2020-06-25 한국세라믹기술원 표면개질된 TiO2 및 ZnO를 함유하는 미세먼지 차단용 화장료 조성물의 제조방법
KR102145941B1 (ko) * 2019-09-05 2020-08-19 주식회사 코스메카코리아 해양유래소재 파우더를 포함하는 미세먼지 부착방지용 화장료 조성물
KR102462752B1 (ko) * 2020-07-22 2022-11-04 주식회사 코스메카코리아 폴리우레탄 분산액을 포함하는 미세먼지 부착방지용 화장료 조성물

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KR20130055333A (ko) * 2011-11-18 2013-05-28 (주)아모레퍼시픽 메이크업 수정용 화장료 조성물 및 제조 방법
JP2014152157A (ja) * 2013-02-13 2014-08-25 Nippon Menaade Keshohin Kk 被覆粉体及びこれを含有するメイクアップ化粧料
WO2014136993A2 (fr) * 2014-04-24 2014-09-12 株式会社 資生堂 Produit cosmétique pour le soin de la peau
KR20160030615A (ko) * 2014-09-11 2016-03-21 조영태 초미세먼지 차단용 기능성 크림
KR101653755B1 (ko) * 2016-01-06 2016-09-02 주식회사 씨앤피코스메틱스 미세먼지 차단용 화장료 조성물
KR20180006536A (ko) * 2016-07-07 2018-01-18 코스맥스 주식회사 미세돌기 구조 형성에 의한 미세먼지 흡착방지용 화장료 조성물

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