WO2018094766A1 - 植物纤维混纺亲肤面料及其加工方法 - Google Patents

植物纤维混纺亲肤面料及其加工方法 Download PDF

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Publication number
WO2018094766A1
WO2018094766A1 PCT/CN2016/108434 CN2016108434W WO2018094766A1 WO 2018094766 A1 WO2018094766 A1 WO 2018094766A1 CN 2016108434 W CN2016108434 W CN 2016108434W WO 2018094766 A1 WO2018094766 A1 WO 2018094766A1
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essential oil
fabric
lavender essential
gum arabic
parts
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PCT/CN2016/108434
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English (en)
French (fr)
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徐晓晔
孙俊河
王娟娟
郭岭岭
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江苏悦达家纺有限公司
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Priority to KR1020177037712A priority Critical patent/KR20190086600A/ko
Publication of WO2018094766A1 publication Critical patent/WO2018094766A1/zh

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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/233—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads protein-based, e.g. wool or silk
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8214—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/10—After-treatment with compounds containing metal
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation

Definitions

  • the invention relates to a fabric, in particular to a plant fiber blended skin-friendly fabric and a processing method thereof.
  • Warmth Although the warmth is closely related to the thickness of the fabric, but the user does not like the bedding such as quilt is too thick, so it is necessary to keep warm and light to become the basic requirements of the current bedding.
  • the most common method for achieving this requirement is to make the inside of the polyester fiber into a porous hollow shape, so that the fiber contains a large amount of non-circulating air, and the outer portion is spirally curled to maintain the bulkiness, so that the texture can be ensured under the premise of ensuring the lightness of the texture. Play a good thermal insulation effect.
  • Antibacterial, deodorizing Because bedding is easy to breed bacteria, it requires better antibacterial performance. At present, some antibacterial fabrics have limited technology for fixing antibacterial agents, and the antibacterial properties of antibacterial agents are not good enough. Some, after dozens of times, disappear completely.
  • Static electricity becomes a problem every time the moisture is easily volatilized and the environment is relatively dry. Static electricity generally makes home textiles easy to pilling, easy to contaminate dust and dirt, and close to the skin with electric shock.
  • the best antistatic fabrics are woven from natural fibers, but even in the case of natural fiber fabrics, static electricity is produced in the very dry environment due to the lack of water molecules.
  • the object of the present invention is to provide a plant fiber blended skin-friendly fabric and a processing method thereof for the above problems, and the obtained fabric has good thermal insulation property, antibacterial deodorizing property and antistatic property.
  • a method for processing a plant fiber blended skin-friendly fabric comprising the steps of:
  • Preparation of corn fiber yarn 90-100 parts of corn fiber is added to 0.1-5.0 parts of multi-functional polycarbodiimide according to parts by weight, mixed uniformly, and then melt-blended and granulated to obtain a master batch, which is obtained.
  • the masterbatch is vacuum dried, and then added 1-8 parts of fatty acid amide and 1-8 parts of glycidyl ester epoxy compound component, and melt-spun to form a corn fiber yarn with a fineness of 2.67 dtex;
  • the corn fiber yarn obtained in the step (1) is used as a warp yarn, and the lavender essential oil sustained release-soybean protein fiber obtained in the step (3) is used as a weft yarn, and the fabric is formed by a conventional weaving method;
  • the method for processing the vegetable fiber blended skin-friendly fabric, and the method for preparing the lavender essential oil microcapsule by the complex coacervation method described in the step (3) comprises the following steps:
  • the lavender essential oil-arabend latex obtained in the step 3 is added dropwise to the gelatin solution prepared in the step 2, and uniformly stirred at 40 to 60 ° C to obtain a mixed solution;
  • nano-scale fine ceramic powder containing 25-40% of the total mass of gum arabic to the microcapsule suspension prepared in step 5, cooling to 9-12 ° C, then adding TG enzyme as curing agent, curing 1 ⁇ 6h, then adding polyvinyl alcohol solution to make the concentration of polyvinyl alcohol in the system 0.8% to 1.2%, reacting for 1 ⁇ 2h to obtain the microcapsule suspension after curing, and collecting the microcapsules after microfiltration of the microcapsule suspension, micro The capsule is washed 1 to 3 times with water, and dried to obtain lavender essential oil microcapsules.
  • the method for processing the vegetable fiber blended skin-friendly fabric, the dyeing method described in the step (5) is: putting the fabric prepared in the step (4) into a dyeing machine, running at 36-40 ° C for 5 min, adding 0.8g/L glacial acetic acid and 3.2-3.6g/L yuan powder, run for 8-12min, add dye, start heating after 10-12min, the heating rate is 1.2°C/min, stop heating when the temperature reaches 50-65°C , heat preservation operation 40-50min, draining, bath ratio 1:40
  • the processing method of the plant fiber blended skin-friendly fabric, the post-dyeing treatment described in the step (6) is to put the fabric dyed by the step (5) into the soap liquid of 8% fabric weight percentage, 45- Treated at 55 ° C for 50 min, then placed in a 3% fabric weight percent glacial acetic acid bath at 35-40 ° C for 10-15 min, bath ratio: 1:40
  • a plant fiber blended skin-friendly fabric obtained by the above method obtained by the above method.
  • the invention starts from the selection of materials, adopts corn fiber, soybean fiber and lavender essential oil with sustained release property.
  • the corn fiber is light and smooth, strong in strength, moisture absorbing and breathable, and the processed product has silky luster and comfortable skin touch and feel. , good drape, good resistance Heat and anti-ultraviolet function, soy fiber has a cashmere-like soft hand, silky soft luster, cotton warmth and good skin-friendly properties, as well as obvious antibacterial function, while lavender essential oil has remarkable Anti-collision and anti-anxiety effect
  • the invention encapsulates lavender essential oil into sustained-release microcapsules, and the fabric is used as a bedding product, and the fabric is subjected to friction and extrusion to release the essential oil, corn fiber, soybean fiber and lavender essential oil with sustained release property.
  • the combination of the fabrics is not only warm, antibacterial, deodorizing and antistatic, but also soft and comfortable, able to resist anxiety and promote sleep, very suitable for use as bedding.
  • the lavender essential oil microcapsule of the invention is added with nano-scale fine ceramic powder in the preparation process, and has good antibacterial property and skin-friendly comfort after being made into a fabric.
  • the fabric of the invention opens up a new situation of bedding fabrics, which greatly meets the needs of people's lives.
  • a method for processing a plant fiber blended skin-friendly fabric comprising the steps of:
  • Preparation of corn fiber yarn 90-100 parts of corn fiber is added to 0.1-5.0 parts of multi-functional polycarbodiimide according to parts by weight, mixed uniformly, and then melt-blended and granulated to obtain a master batch, which is obtained.
  • the masterbatch is vacuum dried, and then added 1-8 parts of fatty acid amide and 1-8 parts of glycidyl ester epoxy compound component, and melt-spun to form a corn fiber yarn with a fineness of 2.67 dtex;
  • the corn fiber yarn obtained in the step (1) is used as a warp yarn, and the lavender essential oil sustained release-soybean protein fiber obtained in the step (3) is used as a weft yarn, and the fabric is formed by a conventional weaving method;
  • a plant fiber blended skin-friendly fabric obtained by the above method is formed. It is warm, antibacterial, deodorizing and antistatic, and it is supple and comfortable. It is anti-anxiety and promotes sleep. It is very suitable for bedding.
  • the method for processing the plant fiber blended skin-friendly fabric and the method for preparing the lavender essential oil microcapsule by the complex coacervation method described in the step (3) comprises the following steps:
  • the lavender essential oil-arabend latex obtained in the step 3 is added dropwise to the gelatin solution prepared in the step 2, and uniformly stirred at 40 to 60 ° C to obtain a mixed solution;
  • nano-scale fine ceramic powder containing 25-40% of the total mass of gum arabic to the microcapsule suspension prepared in step 5, cooling to 9-12 ° C, then adding TG enzyme as curing agent, curing 1 ⁇ 6h, then adding polyvinyl alcohol solution to make the concentration of polyvinyl alcohol in the system 0.8% to 1.2%, reacting for 1 ⁇ 2h to obtain the microcapsule suspension after curing, and collecting the microcapsules after microfiltration of the microcapsule suspension, micro The capsule is washed 1 to 3 times with water, and dried to obtain lavender essential oil microcapsules.
  • the difference between the embodiment and the embodiment 1 is that the method for processing the vegetable fiber blended skin-friendly fabric, the dyeing method described in the step (5) is: putting the fabric prepared in the step (4) into In the dyeing machine, run at 36-40 °C for 5 min, add 0.8g/L glacial acetic acid and 3.2-3.6g/L yuan powder, run for 8-12min, add dye, start heating after 10-12min, heating rate is 1.2°C /min, when the temperature reaches 50-65 °C, the temperature is stopped, the heat preservation operation is 40-50min, the liquid is rinsed, and the bath ratio is 1:40.
  • the processing method of the plant fiber blended skin-friendly fabric, the post-dyeing treatment described in the step (6) is to place the fabric dyed by the step (5). 8% fabric weight percentage of soap solution, 45-55 ° C treatment for 50min, and then placed in 3% fabric weight percentage of glacial acetic acid bath 35-40 ° C treatment 10-15min, bath ratio: 1:40
  • the technical means disclosed in the solution of the present invention is not limited to the technical means disclosed by the above technical means, and includes a technical solution composed of the above technical features equivalent replacement.
  • the unsolved matters of the present invention are common knowledge of those skilled in the art.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Botany (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

一种植物纤维混纺亲肤面料及其加工方法，包括如下步骤：(1)制备玉米纤维纱线；(2)用复凝聚法制备薰衣草精油微囊；(3)制作薰衣草精油缓释-大豆蛋白纤维；(4)织布：采用步骤(1)制得的玉米纤维纱线作经线，步骤(3)制得的薰衣草精油缓释-大豆蛋白纤维作纬线，采用常规的织布方法织布形成面料；(5)染色；(6)染色后处理。本方法制备的面料面料保暖性、抗菌除臭性和抗静电性好。

Description

植物纤维混纺亲肤面料及其加工方法 技术领域
本发明涉及一种面料，具体涉及一种植物纤维混纺亲肤面料及其加工方法。
背景技术
家用纺织品早期使用的面料除了内在质量要求外，只对缩水率和色牢度有一定的要求。随着国内家纺市场的迅速发展，对家纺面料的功能型有了更高的要求。用户对家用纺织品的要求也较为苛刻：对床上用品而言，在追求保暖性的同时，又不能太过厚重；任何一种单一的天然或化学纤维都无法达到这些要求，只能通过多种纤维的复合以及多途径化学整理来尽量达到这些功能。一般的床上用品需要具有以下
保暖性：虽然保暖性是与织物厚度密切相关的，但是使用者又不喜欢被子等床上用品过于厚重，因此既要保暖又要轻便成为目前床上用品的基本要求。目前为了达到这种要求最常见的方法是把涤纶纤维内部做成多孔空心状、使纤维内包含大量不流通空气，外部做成螺旋卷曲状以保持蓬松性，因此能在保证质地轻盈的前提下起到良好的保温作用。
抗菌、除臭性：由于床上用品容易滋生细菌，因此要求抗菌性能要好，目前的一些抗菌面料，目前固定抗菌剂的技术有限，抗菌剂的耐洗性还不够好，每洗涤一次抗菌性能就下降一些，一般几十次之后就完全消失。
抗静电性：目前的家用纺织品基本都是化学纤维面料制成，每当水分易于挥发，环境比较干燥的季节，静电就成了问题。静电一般会让家用纺织品易起毛起球、容易沾染灰尘污垢、贴近皮肤有电击感等。最好的抗静电面料是天然纤维织成的，但是目前就算是天然纤维面料，在非常干燥的环境下也会因为缺乏水分子而产生静电现象。
目前的面料难以在以上性能上都达到较好的效果，无法满足人民日益增长的物质文化需求。
发明内容
本发明的目的是针对上述存在的问题提供一种植物纤维混纺亲肤面料及其加工方法，制得的面料保暖性、抗菌除臭性和抗静电性好。
上述的目的通过以下的技术方案实现：
植物纤维混纺亲肤面料的加工方法，该方法包括如下步骤：
(1)制备玉米纤维纱线：按照重量份数将玉米纤维90-100份加入多功能聚碳化二亚胺0.1～5.0份混合，混合均匀后进行熔融共混造粒得母粒，将所得到的母粒经真空干燥后加入1-8份脂肪酸酰胺以及1-8份缩水甘油酯类环氧化合物成分，经熔融纺丝延伸制成玉米纤维纱线，细度2.67dtex；
(2)用复凝聚法制备薰衣草精油微囊；
(3)制作薰衣草精油缓释-大豆蛋白纤维：将大豆蛋白、尿素、亚硫酸钠、蒸馏水加入带有搅拌器的反应釜中在50℃下处理2h；然后升温至85℃处理1h；调节温度到70℃，加入过氧化氢2～6份，引发10min后，加入丙烯酸10～80份在50～90℃下反应1～5h，得到纺丝 原液；向所述的纺丝原液中加入其重量25-40％的薰衣草精油微囊搅拌均匀再喷丝，采用直径为0.1mm～0.5mm的喷丝头喷入燥介质中使其凝固成型，用水淋洗后，在50～70℃下干燥而得薰衣草精油缓释-大豆蛋白纤维，细度4.35dtex；
(4)织布：采用步骤(1)制得的玉米纤维纱线作经线，步骤(3)制得的薰衣草精油缓释-大豆蛋白纤维作纬线，采用常规的织布方法织布形成面料；
(5)染色；
(6)染色后处理。
所述的植物纤维混纺亲肤面料的加工方法，步骤(3)中所述的复凝聚法制备薰衣草精油微囊的具体方法包括如下步骤：
①将阿拉伯胶加入水中，放置7～10小时自然溶胀后，加热至70～90℃使其完全溶解形成固含量为1％～40％的阿拉伯胶溶液；
②按照阿拉伯胶与明胶的质量比为1：1的比例将明胶加入水中，放置7～10小时自然溶胀后，加热至40～60℃使明胶完全溶解形成固含量为1％～40％的明胶溶液；
③按照阿拉伯胶与薰衣草精油的质量比为1：1的比例将薰衣草精油加入到步骤①的阿拉伯胶溶液中，进行乳化、均质后得到薰衣草精油-阿拉伯胶乳剂；
④把步骤③得到的薰衣草精油-阿拉伯胶乳剂滴加到步骤②中制得的明胶溶液中，在40～60℃下恒温搅拌均匀，得到混合液；
⑤向步骤④中的混合液中加入酸度调节剂，调至混合液pH＝4， 然后再加水稀释1～2倍，搅拌均匀后得到微囊混悬液；
⑥向步骤⑤中制得的微囊混悬液中加入占阿拉伯胶总质量25-40％的纳米级的微细陶瓷粉末，降温至9～12℃后再加入TG酶作为固化剂，固化1～6h，然后加入聚乙烯醇溶液使体系中聚乙烯醇质量浓度为0.8％～1.2％，反应1～2h得到固化后的微囊混悬液，微囊混悬液抽滤后收集微囊，微囊经水洗涤1～3次，干燥后得到薰衣草精油微囊。
所述的植物纤维混纺亲肤面料的加工方法，步骤(5)中所述的染色的方法为：将步骤(4)中制得的面料投入染色机中，在36-40℃运行5min，加入0.8g/L冰醋酸和3.2-3.6g/L元明粉，运行8-12min，加入染料，运行10-12min后开始升温，升温速率1.2℃/min，当温度达到50-65℃时停止升温，保温运行40-50min，排液冲洗，浴比1:40
所述的植物纤维混纺亲肤面料的加工方法，步骤(6)中所述的染色后处理是将经过步骤(5)染色后的面料置于8％面料重量百分比的皂洗液中，45-55℃处理50min，然后再置于3％面料重量百分比的冰醋酸浴中35-40℃处理10-15min，浴比：1:40
一种用上述方法制得的植物纤维混纺亲肤面料。
有益效果：
1、本发明从选材开始，采用玉米纤维、大豆纤维以及具有缓释性能的薰衣草精油，玉米纤维轻柔滑顺，强度大，吸湿透气，加工的产品有丝绸般的光泽及舒适的肌肤触感和手感，悬垂性佳，良好的耐 热性及抗紫外线功能，大豆纤维有着羊绒般的柔软手感，蚕丝般的柔和光泽，棉的保暖性和良好的亲肤性等优良性能，还有明显的抑菌功能，而薰衣草精油具有显著的抗冲突抗焦虑的效果，本发明将薰衣草精油包裹成缓释微囊，作为床上用品使用的过程中面料收到摩擦挤压缓慢释放精油，玉米纤维、大豆纤维以及具有缓释性能的薰衣草精油三者的结合制得的面料不仅保暖性、抗菌除臭性和抗静电性好，并且柔顺舒适，能够抗焦虑和促进睡眠，非常适合用作床上用品。
2.本发明的薰衣草精油微囊在制备的过程中加入纳米级的微细陶瓷粉末，制成面料以后其抗菌性能好，亲肤舒适。
3.本发明的面料开启了床上用品面料的新境地，极大满足人民生活的需要。
具体实施方式
实施例1：
植物纤维混纺亲肤面料的加工方法，该方法包括如下步骤：
(1)制备玉米纤维纱线：按照重量份数将玉米纤维90-100份加入多功能聚碳化二亚胺0.1～5.0份混合，混合均匀后进行熔融共混造粒得母粒，将所得到的母粒经真空干燥后加入1-8份脂肪酸酰胺以及1-8份缩水甘油酯类环氧化合物成分，经熔融纺丝延伸制成玉米纤维纱线，细度2.67dtex；
(2)用复凝聚法制备薰衣草精油微囊；
(3)制作薰衣草精油缓释-大豆蛋白纤维：将大豆蛋白、尿素、亚硫酸钠、蒸馏水加入带有搅拌器的反应釜中在50℃下处理2h；然 后升温至85℃处理1h；调节温度到70℃，加入过氧化氢2～6份，引发10min后，加入丙烯酸10～80份在50～90℃下反应1～5h，得到纺丝原液；向所述的纺丝原液中加入其重量25-40％的薰衣草精油微囊搅拌均匀再喷丝，采用直径为0.1mm～0.5mm的喷丝头喷入燥介质中使其凝固成型，用水淋洗后，在50～70℃下干燥而得薰衣草精油缓释-大豆蛋白纤维，细度4.35dtex；
(4)织布：采用步骤(1)制得的玉米纤维纱线作经线，步骤(3)制得的薰衣草精油缓释-大豆蛋白纤维作纬线，采用常规的织布方法织布形成面料；
(5)染色；
(6)染色后处理。
最终形成一种用上述方法制得的植物纤维混纺亲肤面料。其保暖性、抗菌除臭性和抗静电性好，并且柔顺舒适，能够抗焦虑和促进睡眠，非常适合用作床上用品。
实施例2：
本实施例与实施例1的不同之处在于：所述的植物纤维混纺亲肤面料的加工方法，步骤(3)中所述的复凝聚法制备薰衣草精油微囊的具体方法包括如下步骤：
①将阿拉伯胶加入水中，放置7～10小时自然溶胀后，加热至70～90℃使其完全溶解形成固含量为1％～40％的阿拉伯胶溶液；
②按照阿拉伯胶与明胶的质量比为1：1的比例将明胶加入水中，放置7～10小时自然溶胀后，加热至40～60℃使明胶完全溶解形成 固含量为1％～40％的明胶溶液；
③按照阿拉伯胶与薰衣草精油的质量比为1：1的比例将薰衣草精油加入到步骤①的阿拉伯胶溶液中，进行乳化、均质后得到薰衣草精油-阿拉伯胶乳剂；
④把步骤③得到的薰衣草精油-阿拉伯胶乳剂滴加到步骤②中制得的明胶溶液中，在40～60℃下恒温搅拌均匀，得到混合液；
⑤向步骤④中的混合液中加入酸度调节剂，调至混合液pH＝4，然后再加水稀释1～2倍，搅拌均匀后得到微囊混悬液；
⑥向步骤⑤中制得的微囊混悬液中加入占阿拉伯胶总质量25-40％的纳米级的微细陶瓷粉末，降温至9～12℃后再加入TG酶作为固化剂，固化1～6h，然后加入聚乙烯醇溶液使体系中聚乙烯醇质量浓度为0.8％～1.2％，反应1～2h得到固化后的微囊混悬液，微囊混悬液抽滤后收集微囊，微囊经水洗涤1～3次，干燥后得到薰衣草精油微囊。
实施例3：
本实施例与实施例1的不同之处在于：所述的植物纤维混纺亲肤面料的加工方法，步骤(5)中所述的染色的方法为：将步骤(4)中制得的面料投入染色机中，在36-40℃运行5min，加入0.8g/L冰醋酸和3.2-3.6g/L元明粉，运行8-12min，加入染料，运行10-12min后开始升温，升温速率1.2℃/min，当温度达到50—65℃时停止升温，保温运行40-50min，排液冲洗，浴比1:40
实施例4：
本实施例与实施例1的不同之处在于：所述的植物纤维混纺亲肤面料的加工方法，步骤(6)中所述的染色后处理是将经过步骤(5)染色后的面料置于8％面料重量百分比的皂洗液中，45-55℃处理50min，然后再置于3％面料重量百分比的冰醋酸浴中35-40℃处理10-15min，浴比：1:40
本发明方案所公开的技术手段不仅限于上述技术手段所公开的技术手段，还包括由以上技术特征等同替换所组成的技术方案。本发明的未尽事宜，属于本领域技术人员的公知常识。

Claims (5)

  1. 一种植物纤维混纺亲肤面料的加工方法，其特征在于，该方法包括如下步骤：
    (1)制备玉米纤维纱线：按照重量份数将玉米纤维90-100份加入多功能聚碳化二亚胺0.1～5.0份混合，混合均匀后进行熔融共混造粒得母粒，将所得到的母粒经真空干燥后加入1-8份脂肪酸酰胺以及1-8份缩水甘油酯类环氧化合物成分，经熔融纺丝延伸制成玉米纤维纱线，细度2.67dtex；
    (2)用复凝聚法制备薰衣草精油微囊；
    (3)制作薰衣草精油缓释-大豆蛋白纤维：将大豆蛋白、尿素、亚硫酸钠、蒸馏水加入带有搅拌器的反应釜中在50℃下处理2h；然后升温至85℃处理1h；调节温度到70℃，加入过氧化氢2～6份，引发10min后，加入丙烯酸10～80份在50～90℃下反应1～5h，得到纺丝原液；向所述的纺丝原液中加入其重量25-40％的薰衣草精油微囊搅拌均匀再喷丝，采用直径为0.1mm～0.5mm的喷丝头喷入燥介质中使其凝固成型，用水淋洗后，在50～70℃下干燥而得薰衣草精油缓释-大豆蛋白纤维，细度4.35dtex；
    (4)织布：采用步骤(1)制得的玉米纤维纱线作经线，步骤(3)制得的薰衣草精油缓释-大豆蛋白纤维作纬线，采用常规的织布方法织布形成面料；
    (5)染色；
    (6)染色后处理。
  2. 根据权利要求1所述的植物纤维混纺亲肤面料的加工方法，其特征在于，步骤(3)中所述的复凝聚法制备薰衣草精油微囊的具体方法包括如下步骤：
    ①将阿拉伯胶加入水中，放置7～10小时自然溶胀后，加热至70～90℃使其完全溶解形成固含量为1％～40％的阿拉伯胶溶液；
    ②按照阿拉伯胶与明胶的质量比为1：1的比例将明胶加入水中，放置7～10小时自然溶胀后，加热至40～60℃使明胶完全溶解形成固含量为1％～40％的明胶溶液；
    ③按照阿拉伯胶与薰衣草精油的质量比为1：1的比例将薰衣草精油加入到步骤①的阿拉伯胶溶液中，进行乳化、均质后得到薰衣草精油-阿拉伯胶乳剂；
    ④把步骤③得到的薰衣草精油-阿拉伯胶乳剂滴加到步骤②中制得的明胶溶液中，在40～60℃下恒温搅拌均匀，得到混合液；
    ⑤向步骤④中的混合液中加入酸度调节剂，调至混合液pH＝4，然后再加水稀释1～2倍，搅拌均匀后得到微囊混悬液；
    ⑥向步骤⑤中制得的微囊混悬液中加入占阿拉伯胶总质量25-40％的纳米级的微细陶瓷粉末，降温至9～12℃后再加入TG酶作为固化剂，固化1～6h，然后加入聚乙烯醇溶液使体系中聚乙烯醇质量浓度为0.8％～1.2％，反应1～2h得到固化后的微囊混悬液，微囊混悬液抽滤后收集微囊，微囊经水洗涤1～3次，干燥后得到薰衣草精油微囊。
  3. 根据权利要求1或2所述的植物纤维混纺亲肤面料的加工方法，其特征在于，步骤(5)中所述的染色的方法为：将步骤(4)中制得 的面料投入染色机中，在36-40℃运行5min，加入0.8g/L冰醋酸和3.2-3.6g/L元明粉，运行8—12min，加入染料，运行10-12min后开始升温，升温速率1.2℃/min，当温度达到50—65℃时停止升温，保温运行40-50min，排液冲洗，浴比1:40。
  4. 根据权利要求1或2所述的植物纤维混纺亲肤面料的加工方法，其特征在于，步骤(6)中所述的染色后处理是将经过步骤(5)染色后的面料置于8％面料重量百分比的皂洗液中，45-55℃处理50min，然后再置于3％面料重量百分比的冰醋酸浴中35-40℃处理10-15min，浴比：1:40。
  5. 一种用上述方法制得的植物纤维混纺亲肤面料。
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CN109554914B (zh) * 2018-10-04 2023-12-01 江苏品创纺织科技有限公司 吸湿排汗棉织物的制备方法
CN109757788A (zh) * 2019-01-28 2019-05-17 开放工场(深圳)科技有限公司 一种无毒海绵文胸
CN109757788B (zh) * 2019-01-28 2023-10-03 开放工场(深圳)科技有限公司 一种无毒海绵文胸
CN110616494A (zh) * 2019-09-30 2019-12-27 天津百益尔康保健用品有限公司 一种薰衣草纤维混纺面料
CN111335044A (zh) * 2020-03-31 2020-06-26 武汉中科先进技术研究院有限公司 缓释微胶囊及其制备方法和含有该缓释微胶囊的整理剂及其制备方法和应用
CN111335044B (zh) * 2020-03-31 2022-11-11 武汉中科先进材料科技有限公司 缓释微胶囊及其制备方法和含有该缓释微胶囊的整理剂及其制备方法和应用
CN114717733A (zh) * 2022-04-24 2022-07-08 郁飞 一种抗菌透气针织面料及其制备方法
CN114717733B (zh) * 2022-04-24 2023-08-15 普宁市乐乐兴服饰有限公司 一种抗菌透气针织面料及其制备方法

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