WO2018056732A3 - 수계 레독스 플로우 전지용 유기계 양극 활물질 - Google Patents

수계 레독스 플로우 전지용 유기계 양극 활물질 Download PDF

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Publication number
WO2018056732A3
WO2018056732A3 PCT/KR2017/010427 KR2017010427W WO2018056732A3 WO 2018056732 A3 WO2018056732 A3 WO 2018056732A3 KR 2017010427 W KR2017010427 W KR 2017010427W WO 2018056732 A3 WO2018056732 A3 WO 2018056732A3
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WIPO (PCT)
Prior art keywords
positive electrode
active material
electrode active
flow battery
redox flow
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PCT/KR2017/010427
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English (en)
French (fr)
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WO2018056732A2 (ko
Inventor
변수진
김성연
정봉현
노태근
이정배
강에스더
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주식회사 엘지화학
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Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to JP2018563894A priority Critical patent/JP6739810B2/ja
Priority to US16/308,092 priority patent/US20190221847A1/en
Priority to CN201780040304.2A priority patent/CN109417185B/zh
Priority to EP17853446.7A priority patent/EP3457481B1/en
Publication of WO2018056732A2 publication Critical patent/WO2018056732A2/ko
Publication of WO2018056732A3 publication Critical patent/WO2018056732A3/ko
Priority to US17/369,558 priority patent/US11621421B2/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
    • C07C205/20—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/21—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C205/22—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having one nitro groups bound to the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/74—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C215/76—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton of the same non-condensed six-membered aromatic ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/368—Liquid depolarisers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/08—Fuel cells with aqueous electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Fuel Cell (AREA)

Abstract

본 발명은 수계 레독스 플로우 전지용 유기계 양극 활물질에 관한 것으로, 보다 상세하게는 유기계 양극 활물질을 적용하여 종래의 수계 레독스 플로우 전지의 단점을 보완하는 기술에 관한 것이다. 본 발명에 따른 양극 활물질이 적용된 수계 레독스 플로우 전지는 금속 석출의 문제점이 없을 뿐만 아니라 용매에 따른 용해도 증가로 고농도 사용이 가능하여 고에너지 밀도를 달성할 수 있을 뿐만 아니라, 높은 작동전압을 얻을 수 있으며, 에너지 효율을 높일 수 있는 효과가 있다. 또한 고가의 유기 전해액을 적용하지 않아도 되므로 경제성이 우수하다.
PCT/KR2017/010427 2016-09-22 2017-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질 WO2018056732A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2018563894A JP6739810B2 (ja) 2016-09-22 2017-09-22 水系レドックスフロー電池用有機系正極活物質
US16/308,092 US20190221847A1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
CN201780040304.2A CN109417185B (zh) 2016-09-22 2017-09-22 用于水性氧化还原液流电池的有机正极活性材料
EP17853446.7A EP3457481B1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
US17/369,558 US11621421B2 (en) 2016-09-22 2021-07-07 Organic positive electrode active material for aqueous redox flow battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020160121644A KR102229442B1 (ko) 2016-09-22 2016-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질
KR10-2016-0121644 2016-09-22

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US16/308,092 A-371-Of-International US20190221847A1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
US17/369,558 Division US11621421B2 (en) 2016-09-22 2021-07-07 Organic positive electrode active material for aqueous redox flow battery

Publications (2)

Publication Number Publication Date
WO2018056732A2 WO2018056732A2 (ko) 2018-03-29
WO2018056732A3 true WO2018056732A3 (ko) 2018-07-12

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PCT/KR2017/010427 WO2018056732A2 (ko) 2016-09-22 2017-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질

Country Status (6)

Country Link
US (2) US20190221847A1 (ko)
EP (1) EP3457481B1 (ko)
JP (1) JP6739810B2 (ko)
KR (1) KR102229442B1 (ko)
CN (1) CN109417185B (ko)
WO (1) WO2018056732A2 (ko)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013232434A (ja) * 2013-07-11 2013-11-14 Sumitomo Electric Ind Ltd レドックスフロー電池用電解液、レドックスフロー電池、及びレドックスフロー電池の運転方法
KR20140071603A (ko) * 2012-12-04 2014-06-12 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
US20140370403A1 (en) * 2013-06-17 2014-12-18 University Of Southern California Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage
US20160043423A1 (en) * 2012-09-26 2016-02-11 President And Fellows Of Harvard College Small organic molecule based flow battery
KR101596218B1 (ko) * 2014-09-30 2016-02-22 한국에너지기술연구원 고용량 슬러리 전극 및 고용량 슬러리 전극 기반의 플로우 에너지 저장장치
WO2016086163A1 (en) * 2014-11-26 2016-06-02 Lockheed Martin Advanced Energy Storage, Llc Metal complexes of substituted catecholates and redox flow batteries containing the same

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3338806A (en) * 1961-08-21 1967-08-29 Continental Oil Co Process of preparing p-aminophenol by electrolytically reducing nitrobenzene
US4636286A (en) * 1983-03-25 1987-01-13 Ppg Industries, Inc. Electro organic method
KR910005058B1 (ko) * 1989-09-06 1991-07-22 한국과학기술 연구원 파라-아미노페놀의 제조방법
JPH09507950A (ja) 1993-11-17 1997-08-12 ユニサーチ リミテッド 安定電解液およびその製造方法と、レドックス電池の製造方法、および安定した電解液を含む電池
US5804329A (en) * 1995-12-28 1998-09-08 National Patent Development Corporation Electroconversion cell
JP2005303062A (ja) 2004-04-13 2005-10-27 Rubycon Corp 電解コンデンサ駆動用電解液及び電解コンデンサ
EP2735048A4 (en) 2011-07-21 2015-04-15 Univ Singapore REDOX FLOW BATTERY SYSTEM
US9660311B2 (en) 2011-08-19 2017-05-23 Polyplus Battery Company Aqueous lithium air batteries
US9300000B2 (en) 2012-02-28 2016-03-29 Uchicago Argonne, Llc Organic non-aqueous cation-based redox flow batteries
US8753761B2 (en) * 2012-07-27 2014-06-17 Sun Catalytix Corporation Aqueous redox flow batteries comprising metal ligand coordination compounds
KR102014987B1 (ko) * 2012-12-14 2019-08-27 삼성전자주식회사 레독스 플로우 전지
JP2014127358A (ja) * 2012-12-26 2014-07-07 Nihon Univ レドックスフロー電池
WO2014121276A2 (en) * 2013-02-04 2014-08-07 Massachusetts Institute Of Technology Metal sulfide electrodes and energy storage devices thereof
JP2014216203A (ja) * 2013-04-25 2014-11-17 住友電気工業株式会社 レドックスフロー電池用電解液、およびレドックスフロー電池
AU2014324647B2 (en) 2013-09-26 2018-12-20 President And Fellows Of Harvard College Quinone and hydroquinone based flow battery
KR101600141B1 (ko) 2013-10-11 2016-03-04 서울대학교산학협력단 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
WO2015126907A1 (en) 2014-02-18 2015-08-27 Massachusetts Institute Of Technology Materials for use with aqueous redox flow batteries and related methods and systems
KR101686127B1 (ko) 2014-09-23 2016-12-13 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 흐름전지
JP6621584B2 (ja) * 2015-02-27 2019-12-18 昭和電工株式会社 レドックスフロー電池用電解液およびレドックスフロー電池

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160043423A1 (en) * 2012-09-26 2016-02-11 President And Fellows Of Harvard College Small organic molecule based flow battery
KR20140071603A (ko) * 2012-12-04 2014-06-12 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
US20140370403A1 (en) * 2013-06-17 2014-12-18 University Of Southern California Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage
JP2013232434A (ja) * 2013-07-11 2013-11-14 Sumitomo Electric Ind Ltd レドックスフロー電池用電解液、レドックスフロー電池、及びレドックスフロー電池の運転方法
KR101596218B1 (ko) * 2014-09-30 2016-02-22 한국에너지기술연구원 고용량 슬러리 전극 및 고용량 슬러리 전극 기반의 플로우 에너지 저장장치
WO2016086163A1 (en) * 2014-11-26 2016-06-02 Lockheed Martin Advanced Energy Storage, Llc Metal complexes of substituted catecholates and redox flow batteries containing the same

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
SENTHIKUMAR, S. T.: "Redox additive/active electrolytes: a novel approach to enhance the performance of supercapacitors", JOURNAL OF MATERIALS CHEMISTRY A, vol. 1, no. 40, 2013, pages 12386 - 12394, XP055509559 *
WINSBERG, JAN ET AL.: "Redox-flow batteries: from metal to organic redox-active materials", ANGEWANDTE CHEMIE., vol. 56, no. 3, 16 January 2017 (2017-01-16), pages 686 - 711, XP055509401 *
XU, YAN: "Novel organic redox flow batteries using soluble quinoid com- pounds as positive materials", WORLD NON-GRID-CONNECTED WIND POWER AND ENERGY CONFERENCE, 2009. WNWEC 2009,, 24 September 2009 (2009-09-24), pages 1 - 4, XP031568418 *
ZHANG, ZHONG JIE: "Understanding the redox effects of amine and hydroxyl groups of p-aminophenol upon the capacitive performance in KOH and H2SO4 electrolyte", JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol. 778, 16 August 2016 (2016-08-16), pages 80 - 86, XP029733633 *

Also Published As

Publication number Publication date
CN109417185A (zh) 2019-03-01
US11621421B2 (en) 2023-04-04
EP3457481A4 (en) 2019-07-31
EP3457481B1 (en) 2020-11-04
KR20180032424A (ko) 2018-03-30
CN109417185B (zh) 2021-11-19
JP6739810B2 (ja) 2020-08-12
EP3457481A2 (en) 2019-03-20
WO2018056732A2 (ko) 2018-03-29
JP2019521480A (ja) 2019-07-25
US20210336264A1 (en) 2021-10-28
US20190221847A1 (en) 2019-07-18
KR102229442B1 (ko) 2021-03-17

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