WO2018056732A3 - 수계 레독스 플로우 전지용 유기계 양극 활물질 - Google Patents

수계 레독스 플로우 전지용 유기계 양극 활물질 Download PDF

Info

Publication number
WO2018056732A3
WO2018056732A3 PCT/KR2017/010427 KR2017010427W WO2018056732A3 WO 2018056732 A3 WO2018056732 A3 WO 2018056732A3 KR 2017010427 W KR2017010427 W KR 2017010427W WO 2018056732 A3 WO2018056732 A3 WO 2018056732A3
Authority
WO
WIPO (PCT)
Prior art keywords
positive electrode
active material
electrode active
flow battery
redox flow
Prior art date
Application number
PCT/KR2017/010427
Other languages
English (en)
French (fr)
Other versions
WO2018056732A2 (ko
Inventor
변수진
김성연
정봉현
노태근
이정배
강에스더
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to US16/308,092 priority Critical patent/US20190221847A1/en
Priority to CN201780040304.2A priority patent/CN109417185B/zh
Priority to EP17853446.7A priority patent/EP3457481B1/en
Priority to JP2018563894A priority patent/JP6739810B2/ja
Publication of WO2018056732A2 publication Critical patent/WO2018056732A2/ko
Publication of WO2018056732A3 publication Critical patent/WO2018056732A3/ko
Priority to US17/369,558 priority patent/US11621421B2/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/60Selection of substances as active materials, active masses, active liquids of organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/13Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
    • C07C205/20Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/21Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C205/22Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having one nitro groups bound to the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/74Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C215/76Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton of the same non-condensed six-membered aromatic ring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/368Liquid depolarisers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/08Fuel cells with aqueous electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184Regeneration by electrochemical means
    • H01M8/188Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/20Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0002Aqueous electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Fuel Cell (AREA)

Abstract

본 발명은 수계 레독스 플로우 전지용 유기계 양극 활물질에 관한 것으로, 보다 상세하게는 유기계 양극 활물질을 적용하여 종래의 수계 레독스 플로우 전지의 단점을 보완하는 기술에 관한 것이다. 본 발명에 따른 양극 활물질이 적용된 수계 레독스 플로우 전지는 금속 석출의 문제점이 없을 뿐만 아니라 용매에 따른 용해도 증가로 고농도 사용이 가능하여 고에너지 밀도를 달성할 수 있을 뿐만 아니라, 높은 작동전압을 얻을 수 있으며, 에너지 효율을 높일 수 있는 효과가 있다. 또한 고가의 유기 전해액을 적용하지 않아도 되므로 경제성이 우수하다.
PCT/KR2017/010427 2016-09-22 2017-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질 WO2018056732A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US16/308,092 US20190221847A1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
CN201780040304.2A CN109417185B (zh) 2016-09-22 2017-09-22 用于水性氧化还原液流电池的有机正极活性材料
EP17853446.7A EP3457481B1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
JP2018563894A JP6739810B2 (ja) 2016-09-22 2017-09-22 水系レドックスフロー電池用有機系正極活物質
US17/369,558 US11621421B2 (en) 2016-09-22 2021-07-07 Organic positive electrode active material for aqueous redox flow battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0121644 2016-09-22
KR1020160121644A KR102229442B1 (ko) 2016-09-22 2016-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US16/308,092 A-371-Of-International US20190221847A1 (en) 2016-09-22 2017-09-22 Organic positive electrode active material for aqueous redox flow battery
US17/369,558 Division US11621421B2 (en) 2016-09-22 2021-07-07 Organic positive electrode active material for aqueous redox flow battery

Publications (2)

Publication Number Publication Date
WO2018056732A2 WO2018056732A2 (ko) 2018-03-29
WO2018056732A3 true WO2018056732A3 (ko) 2018-07-12

Family

ID=61690548

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2017/010427 WO2018056732A2 (ko) 2016-09-22 2017-09-22 수계 레독스 플로우 전지용 유기계 양극 활물질

Country Status (6)

Country Link
US (2) US20190221847A1 (ko)
EP (1) EP3457481B1 (ko)
JP (1) JP6739810B2 (ko)
KR (1) KR102229442B1 (ko)
CN (1) CN109417185B (ko)
WO (1) WO2018056732A2 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118610535B (zh) * 2024-08-08 2024-10-01 天津泰然储能科技有限公司 一种用于全钒液流电池的电极活性原位监测装置及方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013232434A (ja) * 2013-07-11 2013-11-14 Sumitomo Electric Ind Ltd レドックスフロー電池用電解液、レドックスフロー電池、及びレドックスフロー電池の運転方法
KR20140071603A (ko) * 2012-12-04 2014-06-12 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
US20140370403A1 (en) * 2013-06-17 2014-12-18 University Of Southern California Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage
US20160043423A1 (en) * 2012-09-26 2016-02-11 President And Fellows Of Harvard College Small organic molecule based flow battery
KR101596218B1 (ko) * 2014-09-30 2016-02-22 한국에너지기술연구원 고용량 슬러리 전극 및 고용량 슬러리 전극 기반의 플로우 에너지 저장장치
WO2016086163A1 (en) * 2014-11-26 2016-06-02 Lockheed Martin Advanced Energy Storage, Llc Metal complexes of substituted catecholates and redox flow batteries containing the same

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3338806A (en) * 1961-08-21 1967-08-29 Continental Oil Co Process of preparing p-aminophenol by electrolytically reducing nitrobenzene
US4636286A (en) * 1983-03-25 1987-01-13 Ppg Industries, Inc. Electro organic method
KR910005058B1 (ko) * 1989-09-06 1991-07-22 한국과학기술 연구원 파라-아미노페놀의 제조방법
EP0729648B1 (en) 1993-11-17 2003-04-02 Pinnacle VRB Stabilised electrolyte solutions, methods of preparation thereof and redox cells and batteries containing stabilised electrolyte solutions
US5804329A (en) * 1995-12-28 1998-09-08 National Patent Development Corporation Electroconversion cell
JP2005303062A (ja) 2004-04-13 2005-10-27 Rubycon Corp 電解コンデンサ駆動用電解液及び電解コンデンサ
JP6077537B2 (ja) 2011-07-21 2017-02-08 ナショナル ユニヴァーシティー オブ シンガポール レドックスフロー電池システム
US9660311B2 (en) 2011-08-19 2017-05-23 Polyplus Battery Company Aqueous lithium air batteries
US9300000B2 (en) 2012-02-28 2016-03-29 Uchicago Argonne, Llc Organic non-aqueous cation-based redox flow batteries
US8753761B2 (en) 2012-07-27 2014-06-17 Sun Catalytix Corporation Aqueous redox flow batteries comprising metal ligand coordination compounds
KR102014987B1 (ko) * 2012-12-14 2019-08-27 삼성전자주식회사 레독스 플로우 전지
JP2014127358A (ja) * 2012-12-26 2014-07-07 Nihon Univ レドックスフロー電池
US9583779B2 (en) * 2013-02-04 2017-02-28 Massachusetts Institute Of Technology Metal sulfide electrodes and energy storage devices thereof
JP2014216203A (ja) * 2013-04-25 2014-11-17 住友電気工業株式会社 レドックスフロー電池用電解液、およびレドックスフロー電池
EP3050151B1 (en) 2013-09-26 2021-12-15 President and Fellows of Harvard College Quinone and hydroquinone based flow battery
KR101600141B1 (ko) 2013-10-11 2016-03-04 서울대학교산학협력단 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
WO2015126907A1 (en) 2014-02-18 2015-08-27 Massachusetts Institute Of Technology Materials for use with aqueous redox flow batteries and related methods and systems
KR101686127B1 (ko) 2014-09-23 2016-12-13 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 흐름전지
JP6621584B2 (ja) * 2015-02-27 2019-12-18 昭和電工株式会社 レドックスフロー電池用電解液およびレドックスフロー電池

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160043423A1 (en) * 2012-09-26 2016-02-11 President And Fellows Of Harvard College Small organic molecule based flow battery
KR20140071603A (ko) * 2012-12-04 2014-06-12 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 플로우 전지용 전해액 및 이를 포함하는 레독스 플로우 전지
US20140370403A1 (en) * 2013-06-17 2014-12-18 University Of Southern California Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage
JP2013232434A (ja) * 2013-07-11 2013-11-14 Sumitomo Electric Ind Ltd レドックスフロー電池用電解液、レドックスフロー電池、及びレドックスフロー電池の運転方法
KR101596218B1 (ko) * 2014-09-30 2016-02-22 한국에너지기술연구원 고용량 슬러리 전극 및 고용량 슬러리 전극 기반의 플로우 에너지 저장장치
WO2016086163A1 (en) * 2014-11-26 2016-06-02 Lockheed Martin Advanced Energy Storage, Llc Metal complexes of substituted catecholates and redox flow batteries containing the same

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
SENTHIKUMAR, S. T.: "Redox additive/active electrolytes: a novel approach to enhance the performance of supercapacitors", JOURNAL OF MATERIALS CHEMISTRY A, vol. 1, no. 40, 2013, pages 12386 - 12394, XP055509559 *
WINSBERG, JAN ET AL.: "Redox-flow batteries: from metal to organic redox-active materials", ANGEWANDTE CHEMIE., vol. 56, no. 3, 16 January 2017 (2017-01-16), pages 686 - 711, XP055509401 *
XU, YAN: "Novel organic redox flow batteries using soluble quinoid com- pounds as positive materials", WORLD NON-GRID-CONNECTED WIND POWER AND ENERGY CONFERENCE, 2009. WNWEC 2009,, 24 September 2009 (2009-09-24), pages 1 - 4, XP031568418 *
ZHANG, ZHONG JIE: "Understanding the redox effects of amine and hydroxyl groups of p-aminophenol upon the capacitive performance in KOH and H2SO4 electrolyte", JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol. 778, 16 August 2016 (2016-08-16), pages 80 - 86, XP029733633 *

Also Published As

Publication number Publication date
CN109417185B (zh) 2021-11-19
EP3457481A2 (en) 2019-03-20
WO2018056732A2 (ko) 2018-03-29
JP6739810B2 (ja) 2020-08-12
CN109417185A (zh) 2019-03-01
US20210336264A1 (en) 2021-10-28
US20190221847A1 (en) 2019-07-18
EP3457481B1 (en) 2020-11-04
JP2019521480A (ja) 2019-07-25
KR20180032424A (ko) 2018-03-30
US11621421B2 (en) 2023-04-04
KR102229442B1 (ko) 2021-03-17
EP3457481A4 (en) 2019-07-31

Similar Documents

Publication Publication Date Title
MX2018008225A (es) Metodo para preparar catodo para bateria secundaria.
WO2017176936A8 (en) Lithium metal electrodes and batteries thereof
PH12017500654A1 (en) Electrochemical cells having semi-solid electrodes and methods of manufacturing the same
MY191555A (en) Method for recycling lithium-ion battery
JP2017528885A5 (ko)
EA201790554A1 (ru) Электрохимическая ячейка на основе галогенида цинка
WO2014189503A3 (en) In-situ electrolyte preparation in flow battery
JP2013229309A5 (ja) 蓄電素子および蓄電素子の作製方法
JP2015088482A5 (ko)
EA201891852A1 (ru) Способ получения графеновых материалов
WO2015073745A8 (en) Battery
WO2015017429A8 (en) Seal configuration for electrochemical cell
WO2016100204A3 (en) Catalyst system for advanced metal-air batteries
SG10201901001YA (en) A battery system
JP2016521442A5 (ko)
JP2014241304A5 (ja) 二次電池及びその製造方法
JP2019067768A5 (ko)
WO2015025211A3 (en) Film formation system and film formation method for forming metal film
WO2018191303A3 (en) High capacity batteries and components thereof
CA3047220C (en) Bipolar secondary battery with intermediate electrode between cathode and anode
WO2018056732A3 (ko) 수계 레독스 플로우 전지용 유기계 양극 활물질
JP2016072129A5 (ko)
WO2014174301A3 (en) Operation of a fuel cell system
TH173104B (th) เซลล์เคมีไฟฟ้าซึ่งมีขั้วไฟฟ้ากึ่งของแข็งและวิธีการผลิตสิ่งเดียวกันนี้
BR112014032572A2 (pt) dispositivos de armazenamento de energia e método de operação do dispositivo

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17853446

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2018563894

Country of ref document: JP

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2017853446

Country of ref document: EP

Effective date: 20181212

NENP Non-entry into the national phase

Ref country code: DE