WO2018038189A1 - 1-フェニル-3-カルバモイル尿素化合物及びその用途 - Google Patents
1-フェニル-3-カルバモイル尿素化合物及びその用途 Download PDFInfo
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- WO2018038189A1 WO2018038189A1 PCT/JP2017/030247 JP2017030247W WO2018038189A1 WO 2018038189 A1 WO2018038189 A1 WO 2018038189A1 JP 2017030247 W JP2017030247 W JP 2017030247W WO 2018038189 A1 WO2018038189 A1 WO 2018038189A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/69—Two or more oxygen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Definitions
- Patent Document 1 describes N- [4-chloro-2-fluoro-5- ⁇ 2- (ethoxycarbonyl) methoxy-3-pyridyloxy ⁇ phenyl] acetamide.
- An object of the present invention is to provide a compound having an excellent control effect against plant diseases.
- the present inventor has found that the compound represented by the following formula (1) has an excellent control effect against plant diseases. That is, the present invention is as follows.
- Formula (1) (Hereinafter referred to as the present compound).
- a plant disease control agent containing the compound according to [1] (hereinafter also referred to as the present control agent).
- a method for controlling plant diseases comprising treating an effective amount of the compound according to [1] to a plant or soil for cultivating the plant.
- Use of the compound according to [1] for controlling plant diseases are examples of the compounds according to [1] for controlling plant diseases.
- plant diseases can be controlled.
- the control agent of the present invention is usually prepared by mixing the compound of the present invention with a solid carrier, liquid carrier, oil and / or surfactant, etc. Then, it is formulated into a wettable powder, granular wettable powder, flowable preparation, granule, dry flowable preparation, emulsion, aqueous liquid preparation, oil preparation, smoke preparation, aerosol preparation, microcapsule preparation and the like. These preparations contain the compound of the present invention in a weight ratio of usually 0.1 to 99%, preferably 0.2 to 90%.
- solid support examples include clays (for example, kaolin clay, diatomaceous earth, synthetic hydrous silicon oxide, fusami clay, bentonite, acidic clay), talc, and other inorganic minerals (for example, sericite, quartz powder, sulfur powder, activated carbon). , Calcium carbonate, hydrated silica) and the like.
- liquid carrier examples include water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), aromatic hydrocarbons (toluene, xylene, ethylbenzene, methylnaphthalene, etc.), aliphatic hydrocarbons ( Hexane, cyclohexane, kerosene, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, isobutylnitrile, etc.), ethers (diisopropyl ether, etc.), amides (dimethylformamide, dimethylacetamide, etc.), and sulfoxide (Dimethyl sulfoxide and the like).
- alcohols methanol, ethanol, etc.
- ketones acetone, methyl ethyl ketone, etc.
- aromatic hydrocarbons toluene, xylene
- Surfactants include, for example, alkyl sulfates, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and their polyoxyethylene compounds, polyoxyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohols. Derivatives.
- formulation adjuvants include, for example, fixing agents, dispersants, and stabilizers.
- casein gelatin, polysaccharides (eg, starch, arabic gum, cellulose derivatives, alginic acid), lignin derivatives, bentonite.
- Saccharides synthetic water-soluble polymers (eg, polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids), PAP (isopropyl acid phosphate), BHT (2,6-di-tert-butyl-4-methylphenol), BHA ( And a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol), vegetable oils, mineral oils, fatty acids and the like.
- Oils and surfactants that can be used in combination with the compounds of the present invention include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), and Silwet L-77 (registered trademark).
- BreakThru registered trademark
- Sundance II registered trademark
- Induce registered trademark
- Penetrator registered trademark
- AgriDex registered trademark
- Lutensol A8 registered trademark
- NP-7 registered trademark
- Triton registered trademark
- Nufilm Registered Trademark
- Emulator NP7 Registered Trademark
- Emulad Registered Trademark
- TRITON X 45 Registered Trademark
- AGRAL 90 Registered Trademark
- AGROTIN Registered Trademark
- ARPON Registered Trademark
- EnS ray N R
- BANOLE registered trademark
- the compound of the present invention is applied as the control agent of the present invention.
- the method of applying the present control agent is not particularly limited as long as the method of the present invention can be applied substantially, but for example, treatment of plants such as foliage spraying, soil treatment, etc.
- the treatment to the planting place of a plant, the treatment to seeds, such as seed disinfection, are mentioned.
- the treatment amount of the compound of the present invention in the control method of the present invention varies depending on the type of plant to be treated, the type and occurrence frequency of plant diseases to be controlled, the preparation form, the treatment time, the treatment method, the treatment place, the weather conditions, etc.
- the compound of the present invention is usually 1 to 500 g per 1000 m 2 .
- Emulsions, wettable powders, flowables and the like are usually treated by diluting with water and spraying.
- the concentration of the compound of the present invention is usually 0.0005 to 2% by weight. Powders, granules, etc. are usually processed without dilution.
- the compound of the present invention can be used as a plant disease control agent in agricultural land such as fields, paddy fields, lawns, orchards.
- Rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solani), idiot seedling (Gibberella fujikuroi), yellow dwarf (Sclerophthora macrospora); wheat powdery mildew (Blumeriagraminis) ), Red mold (Fusarium graminearum, Fusarium avenaceum, Fusarium culmorum, Microdochium nivale), yellow rust (Puccinia striiformis), black rust (Puccinia graminis), red rust (Puccinia recondita), red snow rot (Microdochium nival) Microdochium majus), Snow rot microbe nuclei (Typhula incarnata, Typhula ishikariensis), Bare smut (Ustilago tritici), Buffalo scab (Tilletia caries
- Rice seedling blight (Burkholderia plantarii); cucumber gray plague (Phytophthora capsici), seedling blight (Pythium ultimum) and spotted bacterial disease (Pseudomonas syringae pv. Lachrymans); eggplant blight (Ralstonia solanacearum) Citrus canker (Xanthomonas citiri); Chinese cabbage soft rot (Erwinia carotovora), etc.
- Test Example 1 Control Test against Phytophthora capsici Dilute 4.5 mg of the compound of the present invention with 100 ⁇ L of dimethyl sulfoxide. After 1 ⁇ L of the diluted solution was dispensed into a titer plate (96 well), 150 ⁇ L of a potato broth liquid medium (PDB medium) containing zoospores of Phytophthora capsici was dispensed. After culturing this plate at 27 ° C. for 3 days to propagate the cucumber gray plague, the absorbance at 600 nm of each well of the titer plate was measured to determine the growth of the cucumber gray plague.
- PDB medium potato broth liquid medium
- the efficacy of the compound of the present invention was 80% or more.
- "Formula 1" Efficacy 100 ⁇ (XY) / X X: Growth rate of fungus in untreated group
- Y Growth degree of fungus in treated group
- the untreated group in this test example refers to dispensing dimethyl sulfoxide instead of the dimethyl sulfoxide dilution containing the compound of the present invention. Except for the test plots, the test plots are the same as the treatment plots.
- the compound of the present invention has a controlling effect against plant diseases and is useful as an active ingredient of a plant disease controlling agent.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Description
本発明は1-フェニル-3-カルバモイル尿素化合物及びその用途に関する。
液体担体としては、例えば、水、アルコール類(メタノール、エタノール等)、ケトン類(アセトン、メチルエチルケトン等)、芳香族炭化水素類(トルエン、キシレン、エチルベンゼン、メチルナフタレン等)、脂肪族炭化水素類(ヘキサン、シクロヘキサン、灯油等)、エステル類(酢酸エチル、酢酸ブチル等)、ニトリル類(アセトニトリル、イソブチルニトリル等)、エーテル類(ジイソプロピルエーテル等)、アミド類(ジメチルホルムアミド、ジメチルアセトアミド等)、及びスルホキシド類(ジメチルスルホキシド等)が挙げられる。
本発明の防除方法における本発明化合物の処理量は、処理する植物の種類、防除対象である植物病害の種類や発生頻度、製剤形態、処理時期、処理方法、処理場所、気象条件等によっても異なるが、植物の茎葉に処理する場合又は植物を栽培する土壌に処理する場合は、本発明化合物は、1000m2あたり、通常1~500gである。
乳剤、水和剤、フロアブル剤等は通常水で希釈して散布することにより処理する。この場合、本発明化合物の濃度は、通常0.0005~2重量%である。粉剤、粒剤等は通常希釈することなくそのまま処理する。
Aspergillus属、Penicillium属、Fusarium属、Gibberella属、Tricoderma属、Thielaviopsis属、Rhizopus属、Mucor属、Corticium属、Phoma属、Rhizoctonia属、及びDiplodia属菌等によって引き起こされる、各種作物の種子病害又は生育初期の病害。Polymixa属又はOlpidium属等によって媒介される各種作物のウイルス病。
イネの苗立枯細菌病(Burkholderia plantarii);キュウリの灰色疫病(Phytophthora capsici)、苗立枯病(Pythium ultimum)および斑点細菌病(Pseudomonas syringae pv. Lachrymans);ナスの青枯病(Ralstonia solanacearum);カンキツのかいよう病(Xanthomonas citiri);ハクサイの軟腐病(Erwinia carotovora)等。
1H-NMR (CDCl3) δ (ppm): 9.30 (1H, s), 7.88 (1H, d, J = 7.6 Hz), 7.85 (1H, dd, J = 5.2, 1.6 Hz), 7.22 (1H, d, J = 10.0 Hz), 7.06 (1H, dd, J = 7.8, 1.6 Hz), 6.87 (1H, dd, J = 7.8, 5.2 Hz), 4.96 (2H, s), 4.21 (2H, q, J = 6.4 Hz) , 1.26 (3H, t, J = 7.2 Hz).
ESI-MS(posi):427[M+H]+
本発明化合物4.5mgをジメチルスルホキシド100μLで希釈した。希釈液1μLをタイタープレート(96ウェル)に分注したのち、キュウリ灰色疫病菌(Phytophthora capsici)の遊走子を含むジャガイモ煎汁液体培地(PDB培地)を150μL分注した。このプレートを3日間、27℃で培養してキュウリ灰色疫病菌を増殖させたのち、タイタープレートの各ウェルの600nmの吸光度を測定し、キュウリ灰色疫病菌の生育度とした。その生育度をもとに、「式1」を用いて効力を算出したところ、本発明化合物の効力は80%以上であった。
「式1」
効力=100×(X-Y)/X
X:無処理区の菌の生育度
Y:処理区の菌の生育度
なお、本試験例における無処理区とは、本発明化合物を含有するジメチルスルホキシド希釈液の代わりにジメチルスルホキシドを分注する以外は処理区と同じ条件で行った試験区を表す。
一方、欧州特許第1122244号明細書に記載のN-[4-クロロ-2-フルオロ-5-{2-(エトキシカルボニル)メトキシ-3-ピリジルオキシ}フェニル]アセトアミドを用いて同じ試験を行った結果、その効力は50%未満であった。
Claims (4)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/328,041 US10844019B2 (en) | 2016-08-26 | 2017-08-24 | 1-phenyl-3-carbamoyl urea compound, and use thereof |
CA3035003A CA3035003A1 (en) | 2016-08-26 | 2017-08-24 | 1-phenyl-3-carbamoyl urea compound, and use thereof |
BR112019002344-5A BR112019002344B1 (pt) | 2016-08-26 | 2017-08-24 | Composto de 1-fenil-3-carbamoilureia, seu uso, agente e método para controlar uma doença de planta |
CN201780051320.1A CN109641842B (zh) | 2016-08-26 | 2017-08-24 | 1-苯基-3-氨基甲酰基脲化合物及其用途 |
MX2019002234A MX2019002234A (es) | 2016-08-26 | 2017-08-24 | Compuesto de 1-fenil-3-carbamoil urea y uso del mismo. |
JP2018535749A JP6898332B2 (ja) | 2016-08-26 | 2017-08-24 | 1−フェニル−3−カルバモイル尿素化合物及びその用途 |
DE112017004274.7T DE112017004274T5 (de) | 2016-08-26 | 2017-08-24 | 1-phenyl-3-carbamoylharnstoff-verbindung und deren verwendung |
AU2017316908A AU2017316908B2 (en) | 2016-08-26 | 2017-08-24 | 1-phenyl-3-carbamoyl urea compound, and use thereof |
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JP2016165423 | 2016-08-26 | ||
JP2016-165423 | 2016-08-26 |
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WO2018038189A1 true WO2018038189A1 (ja) | 2018-03-01 |
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PCT/JP2017/030247 WO2018038189A1 (ja) | 2016-08-26 | 2017-08-24 | 1-フェニル-3-カルバモイル尿素化合物及びその用途 |
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US (1) | US10844019B2 (ja) |
JP (1) | JP6898332B2 (ja) |
CN (1) | CN109641842B (ja) |
AR (1) | AR109406A1 (ja) |
AU (1) | AU2017316908B2 (ja) |
BR (1) | BR112019002344B1 (ja) |
CA (1) | CA3035003A1 (ja) |
DE (1) | DE112017004274T5 (ja) |
MX (1) | MX2019002234A (ja) |
WO (1) | WO2018038189A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10624343B2 (en) * | 2016-08-26 | 2020-04-21 | Sumitomo Chemical Company, Limited | Phenyl urea compound, and use thereof |
WO2021117394A1 (ja) * | 2019-12-11 | 2021-06-17 | 住友化学株式会社 | ピリジルオキシ酢酸化合物及びその用途 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001519783A (ja) * | 1997-03-14 | 2001-10-23 | アイ・エス・ケー アメリカズ インコーポレイティド | ジアリールエーテルおよびその製造法ならびにそれらを含有する除草および乾燥組成物 |
CN1325849A (zh) * | 2000-05-30 | 2001-12-12 | 沈阳化工研究院 | 具有除草活性的2-(硫代)-4,5-咪唑啉三酮类化合物 |
JP2002155061A (ja) * | 2000-02-04 | 2002-05-28 | Sumitomo Chem Co Ltd | ウラシル化合物及びその用途 |
JP2004262934A (ja) * | 2003-02-13 | 2004-09-24 | Sankyo Agro Kk | 3−フェノキシ−4−ピリダジノール誘導体を含有する除草性組成物 |
JP2006515884A (ja) * | 2003-01-14 | 2006-06-08 | サイトキネティクス・インコーポレーテッド | 化合物、組成物および方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4376646A (en) * | 1980-03-18 | 1983-03-15 | Ciba-Geigy Corporation | Herbicidal N-[4-(3'-alkoxyphenoxy)-phenyl]-N'-methylureas |
DE3418532A1 (de) * | 1983-12-01 | 1985-06-13 | Basf Ag, 6700 Ludwigshafen | Chinolinoxyphenylharnstoffe, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
BR0117036A (pt) * | 2001-05-31 | 2004-07-27 | Sumitomo Chemical Co | Dissecante de caule/folha |
UY30117A1 (es) | 2006-01-31 | 2007-06-29 | Tanabe Seiyaku Co | Compuesto amina trisustituido |
JP6487728B2 (ja) | 2015-03-10 | 2019-03-20 | 富士フイルム株式会社 | 計測システム、計測方法及び計測プログラム |
-
2017
- 2017-08-24 WO PCT/JP2017/030247 patent/WO2018038189A1/ja active Application Filing
- 2017-08-24 DE DE112017004274.7T patent/DE112017004274T5/de active Pending
- 2017-08-24 MX MX2019002234A patent/MX2019002234A/es unknown
- 2017-08-24 CA CA3035003A patent/CA3035003A1/en active Pending
- 2017-08-24 CN CN201780051320.1A patent/CN109641842B/zh active Active
- 2017-08-24 BR BR112019002344-5A patent/BR112019002344B1/pt active IP Right Grant
- 2017-08-24 US US16/328,041 patent/US10844019B2/en active Active
- 2017-08-24 AU AU2017316908A patent/AU2017316908B2/en active Active
- 2017-08-24 JP JP2018535749A patent/JP6898332B2/ja active Active
- 2017-08-24 AR ARP170102343A patent/AR109406A1/es active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001519783A (ja) * | 1997-03-14 | 2001-10-23 | アイ・エス・ケー アメリカズ インコーポレイティド | ジアリールエーテルおよびその製造法ならびにそれらを含有する除草および乾燥組成物 |
JP2002155061A (ja) * | 2000-02-04 | 2002-05-28 | Sumitomo Chem Co Ltd | ウラシル化合物及びその用途 |
CN1325849A (zh) * | 2000-05-30 | 2001-12-12 | 沈阳化工研究院 | 具有除草活性的2-(硫代)-4,5-咪唑啉三酮类化合物 |
JP2006515884A (ja) * | 2003-01-14 | 2006-06-08 | サイトキネティクス・インコーポレーテッド | 化合物、組成物および方法 |
JP2004262934A (ja) * | 2003-02-13 | 2004-09-24 | Sankyo Agro Kk | 3−フェノキシ−4−ピリダジノール誘導体を含有する除草性組成物 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10624343B2 (en) * | 2016-08-26 | 2020-04-21 | Sumitomo Chemical Company, Limited | Phenyl urea compound, and use thereof |
WO2021117394A1 (ja) * | 2019-12-11 | 2021-06-17 | 住友化学株式会社 | ピリジルオキシ酢酸化合物及びその用途 |
CN114787131A (zh) * | 2019-12-11 | 2022-07-22 | 住友化学株式会社 | 吡啶氧基乙酸化合物及其用途 |
Also Published As
Publication number | Publication date |
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US20190202787A1 (en) | 2019-07-04 |
AR109406A1 (es) | 2018-11-28 |
AU2017316908A1 (en) | 2019-02-21 |
CN109641842B (zh) | 2021-12-07 |
BR112019002344B1 (pt) | 2022-10-18 |
MX2019002234A (es) | 2019-06-17 |
BR112019002344A2 (pt) | 2019-06-18 |
DE112017004274T5 (de) | 2019-05-16 |
JPWO2018038189A1 (ja) | 2019-06-24 |
JP6898332B2 (ja) | 2021-07-07 |
AU2017316908B2 (en) | 2020-11-19 |
CN109641842A (zh) | 2019-04-16 |
US10844019B2 (en) | 2020-11-24 |
CA3035003A1 (en) | 2018-03-01 |
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