WO2018030624A1 - 고내열성 방향제 조성물 - Google Patents
고내열성 방향제 조성물 Download PDFInfo
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- WO2018030624A1 WO2018030624A1 PCT/KR2017/005865 KR2017005865W WO2018030624A1 WO 2018030624 A1 WO2018030624 A1 WO 2018030624A1 KR 2017005865 W KR2017005865 W KR 2017005865W WO 2018030624 A1 WO2018030624 A1 WO 2018030624A1
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- Prior art keywords
- fragrance
- wax
- present
- composition
- melting point
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/044—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of an organic compound other than a macromolecular compound
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Definitions
- the characteristics of the scent varies depending on the solvent used, there is a limit in delivering the inherent sensitivity.
- plug-in or auto-injection type is most representative.
- the fragrance of the plug-in changes with use time due to the heating of the contents including the fragrance by electricity.
- the self-injection type when the fragrance is filled in the filled cans and dispersed in the space in the form of aerosol, there is a limiting factor in the enhancement of the sensitivity due to the noise and instant strong odor.
- problems such as leakage and melting due to the leakage of the interior of the vehicle and the rise of the temperature of the vehicle in the summer are required.
- the main limitation of the fragrance in the appearance of stable fragrance is the change in intrinsic fragrance by the base including the fragrance according to the external temperature change, the change of the fragrance and a solvent designed to deliver the fragrance.
- the problem to be solved by the present invention is to provide a fragrance composition that can be stably scented from the fragrance without deformation or melting even at high temperatures.
- the present invention includes a microcrystalline wax, provides a perfume composition characterized in that the melting point is 90 to 125 °C.
- the melting point may be 90 to 125 ° C, preferably 93 to 120 ° C, more preferably 95 to 115 ° C.
- the present inventors have completed the present invention by confirming that the fragrance composition according to the present invention does not leak or melt at a high temperature, and includes a fragrance containing a large amount of fragrance components, while having a stable at high temperature and excellent fragrance. Experimentally confirmed to complete the present invention.
- the fragrance composition according to the invention comprises microcrystal waxes and exerts an excellent effect when the melting point of the composition is from 90 to 125 ° C.
- the composition according to the invention further comprises natural waxes, paraffin waxes or both. It may include.
- the present inventors have experimentally confirmed that the fragrance composition having a melting point of 90 to 125 ° C. shows an excellent effect when the microcrystalline wax is included, and further includes natural wax, paraffin wax, or both. It was experimentally confirmed that more significant effects were exerted.
- the "microcrystalline wax” is characterized by having a predetermined crystallinity and strong hardness, is a wax obtained by refining and separating the remaining asphalt (Asphalt) after refining crude oil, C 25 to C 80 , preferably C 31 to C 70 is a hydrocarbon mixture mainly composed of isoparaffins having a molecular weight of 300 to 1500, preferably of a molecular weight of 400 to 1200, more preferably of a molecular weight of 450 to 1000.
- microcrystal waxes that can be used in the present invention are commercially available microcrystal waxes, for example, but not limited to, the multi-wax trade name Multi wax W-445 (Sonneborn), Hi wax (Hi). wax 400P, Hi wax 410P (Mitsui), Kahl Wax, and the like.
- Microcrystalline waxes contain large amounts of branched alkyl hydrocarbons, so they generally dissolve at higher temperatures than paraffin waxes, and have high hardness and viscous properties. Have In addition, the ability to absorb oil is greater than paraffin wax, which is advantageous for impregnating fragrances, and the purification method is also different.
- the microcrystalline wax may be included in 10 to 90% by weight, preferably 20 to 85% by weight, more preferably 30 to 80% by weight relative to the total weight of the composition.
- the "natural wax” includes both an animal natural wax and a vegetable natural wax, and the animal natural wax is not limited thereto, but a wax obtained from bees wax (wax wax), wool wax, whale, etc. And shellac obtained from insects.
- the vegetable natural wax includes, but is not limited to, Soy wax, Carnauba wax, Candelilla wax, and the like.
- the natural wax includes not only natural wax collected directly from nature, but also all commercially available natural waxes.
- bees wax is also referred to as beeswax and beeswax, but is not limited to, for example, by the enzymatic action of biochemical processes of sugar collected from flowers naturally It is a yellow substance that is made in the body and secreted by the lower abdominal glands of worker bees, and materials that make up the honeycomb can be used.
- the beeswax used in the composition according to the present invention may preferably be processed by filtering out bead wax with a filter to remove impurities.
- the beeswax in the present invention may contain 40 to 90% by weight wax ester, 1 to 30% by weight free fatty acid, 0.1 to 5% by weight free alcohol or a mixture of two or more thereof, based on the total weight of the beeswax. It may contain 62 to 75 weight percent wax ester, 5 to 16 weight percent free fatty acid, 1 to 2 weight percent free alcohol, or a mixture of two or more thereof, more preferably a mixture of both. In addition, it may contain 10 to 20% by weight of C 20 to C 40 hydrocarbons or 2 to 5% by weight of glycerides (C 14 , C 16 or C 18 ).
- the "paraffin wax” is a crude oil wax (Crude Wax) containing a high boiling point component of the crude oil (Crude Wax) is purified by excluding oil components such as lubricating oil, and is a linear hydrocarbon (Linear alkyl hydrocarbon) in the molecular structure, It is a mixture of hydrocarbon molecules which are generally alkanes (alkanes) hydrocarbons represented by the formula CnH 2n + 2 ( n ⁇ 19) and consist of 20 to 40 carbon molecules.
- the paraffin wax may have a melting point of 40 to 90 °C.
- the paraffin wax may be classified into a high melting point paraffin wax and a low melting point paraffin wax, and the high melting point paraffin wax means a paraffin wax having a melting point of 60 to 90 ° C, preferably 65 to 85 ° C.
- the low melting point paraffin wax means a paraffin wax having a melting point of 40 to 60 °C, preferably 45 to 55 °C.
- the composition according to the present invention may further comprise a natural wax, paraffin wax or both in addition to the microcrystalline wax, the natural wax, paraffin wax or both are 1 to 20% by weight relative to the total weight of the composition, preferably Preferably 5 to 15% by weight.
- the present inventors have experimentally confirmed that in addition to the microcrystalline wax, natural wax, paraffin wax, or both of them further included in the composition to exert more excellent effects. That is, the present invention preferably provides a fragrance composition excellent in fragrance and stable even at high temperature, including not only microcrystalline wax, but also natural wax, paraffin wax or both.
- the perfume composition according to the present invention may include a perfume.
- the fragrance is not limited thereto, but general fragrances, deodorants, fragrance products, as well as shampoos, body wash products such as body washes, detergents, softeners such as laundry products, perfumes that can be used in cosmetics, such as perfumes. .
- the fragrance is included in the wax structure to form a stable composition.
- the stable composition of the present invention provides a sensational quality of good fragrance, which provides a fresh feeling by continuously supplying the incense fragrance while maintaining a stable form in a closed space.
- Perfume in the present invention may preferably provide a lasting aroma.
- the fragrance may be included in an amount of 1 to 50% by weight, preferably 5 to 40% by weight, and more preferably 10 to 30% by weight, based on the total weight of the composition.
- the present invention may add fragrances to eliminate odors and to maintain the odor on the surface for longer.
- the composition according to the present invention can use all the usual fragrance and the fragrance component can be used both hydrophobic (Hydrophobicity) or hydrophilic (Hydrophilicity) fragrance.
- the fragrance may exhibit hydrophobicity as logP, the log value of the octanol / water partition coefficient, and the larger the value, the greater the hydrophobicity. At this time, the greater the hydrophobicity is, the better the reverberation is.
- the fragrance for fragrance is preferred to have a low fragrance rather than a high hydrophobic fragrance in order to excellent fragrance, which has the disadvantage that the designed fragrance is not kept constant, and high hydrophobic fragrance has a weak fragrance.
- Log P the logarithm of the octanol / water partition coefficient
- the basis for hydrophobicity of the perfume used in the present invention is log P 3.
- the inventors have found that when the fragrance has a log P value of about 3 or more, preferably about 3.1 or more, and most preferably about 3.2 or more, desirable reverberation characteristics are exhibited.
- the flavor must have at least partial hydrophobicity and a relatively high boiling point in order to last longer. That is, the fragrance may have a log value of octanol / water partition coefficient of 3 to 8, and a boiling point of 200 to 500 ° C., preferably, a log value of octanol / water partition coefficient of 3.2 to 8, and a boiling point of 220 to 500 ° C.
- the properties of the fragrance components are also various isomers and have a large influence on the material present in the surrounding, it is not easy to clearly distinguish the physical properties such as logP. Therefore, the numerical values described above should be flexibly interpreted in the numerical range analysis as an approximate value for indicating the properties of the perfume.
- the hydrophobic fragrance may be included 5 to 80% by weight relative to the total weight of the fragrance, preferably 10 to 60% by weight may be included, more preferably 15 to 50% by weight.
- Table 1 shows the results of evaluating the molecular weight, boiling point and logP values for some of the various fragrances that can be used in the present invention and the degree of reverberation after 3 hours at 90 ° C. when included in the fragrance composition according to the present invention. Table.
- the fragrance that can be used in the present invention is not limited thereto, but is not limited thereto, oranthiol (Aurantiol), amyl cinnamate (Amyl cinnamate), Bacdanol (Cashmeran), Cervolide (Cervolide), Cinnamic cinnamate, Ethylene brassylate, Galaxolide, Helvetolide, Hexadecanolide, Hexyl Salicylate, Iso -E Super, Isopropyl myristate, Methyl dihydrojasmonate, Phenylethyl phenylacetate, Romandolide, Tonalid ), Trisamber or mixtures of two or more thereof can be used.
- the composition according to the present invention may further include a polymer, and the polymer may improve usability by increasing the reverberation of an additional fragrance.
- the said polymer is oil-absorbing as a nonionic polymer. That is, the polymer may be a nonionic oil-absorbing polymer, but is not limited thereto, and may include, for example, copolymers of polyethyleneglycol, polyoxyethylene, and polyoxypropylene. Commercially available products may include PEG 400, Poloxamer or Pluronics.
- the polymer may be included in an amount of 0.01 to 20% by weight based on the total weight of the composition, preferably 0.05 to 15% by weight, and more preferably 0.1 to 10% by weight.
- the composition according to the present invention may further include a surfactant, and the surfactant may help the mixing of the wax and the fragrance, and the cracking may occur due to uneven distribution of the fragrance in the wax as the fragrance is released during use. Prevent and increase the reverberation of the fragrance can have excellent usability.
- the surfactant may be included in an amount of 0.5 to 15% by weight relative to the total weight of the composition, preferably 1 to 10% by weight, and more preferably 2 to 7% by weight.
- the present invention also provides a fragrance comprising the composition.
- the fragrance is not limited to any form, but may preferably be in solid form.
- the fragrance composition according to the present invention is stable even at a high temperature and has an effect of excellent fragrance, and has excellent fragrance even in a space with high temperature rise, such as a car and a wardrobe.
- the present inventors prepared the fragrance composition which has a composition as shown in Table 3 using the fragrance as shown in Table 2 below.
- the fragrance composition according to the present invention consists of paraffin wax, microcrystalline wax, perfume and other ingredients
- the fragrance is stably dispersed in the high melting point wax in the production process of the fragrance composition and is present in the composition during the molding and cooling process. It is important. In order to maintain the fragrance in the high melting point wax, it must be first combined and melted according to the characteristics of the wax, and after injecting the fragrance, the fragrance is evenly dispersed in the wax, and then formed and hardened without bending or cracking. Functionally functioning compositions could be maintained.
- the fragrance composition according to the present invention consists of paraffin wax, microcrystalline wax, perfume and other ingredients, it is desirable to ensure that the fragrance is stably dispersed in the high melting wax in the production process of the composition and present in the composition during the molding and cooling process. It is important. In order to maintain the fragrance in the high melting point wax, it must be first combined and melted according to the characteristics of the wax, and after injecting the fragrance, the fragrance is evenly dispersed in the wax, and then formed and hardened without bending or cracking. Functionally functioning compositions could be maintained.
- Example 7 One Natural wax Soy wax 20 - 10 - - - - - - - 5 2 Beads wax 50 - - - - - - - - 3 Paraffin wax Low melting point paraffin wax - 35 10 - - - - - 10 - 4 High melting point paraffin wax - 35 50 - - - - - 5 5 Microcrystalline Wax Multi wax W-445 - - - 70 - - 40 10 15 15 6 Hi wax 410P - - - - 70 - 20 20 25 25 7 Hi wax 400P - - - - - - 70 10 40 20 20 8 Copolymerized polymer EMA 1605 5 5 5 5 5 5 5 5 5 9 Surfactants Sorbitan monostearate 5 5 5 5 5 5 5 5 10 Spices Compound fragrance of table 2 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20
- the wax used in the present invention was used in Comparative Examples and Examples by arranging commercially used raw materials, which can be replaced with raw materials having similar properties at the same level.
- the wax used in the comparative example used Soy wax and Beads wax as natural waxes most commonly used in general candles.
- paraffin wax was used as a petroleum wax widely used in the manufacture of candles, and the melting point of general paraffin wax is present between 47 ° C and 60 ° C.
- the paraffin wax is divided into a low melting point and a high melting point according to the melting point.
- the melting point of the paraffin wax is about 50 ° C.
- the high melting point paraffin wax is used at about 70 ° C.
- the microcrystalline wax increases the melting point of the wax, solidifies the properties of the formulation, and affects the degree of impregnation of the fragrance.
- W-445 wax having a melting point of 82 ° C. was used in Sonneborn's wax.
- Mitsui company completed the invention by mixing Hi wax 410P with melting point of 125 ° C and Hi wax 400P with 115 ° C.
- a polymer and a surfactant were further used to complete the formulations of the comparative examples and examples.
- the inventors of the present invention to determine the high temperature of the fragrance composition according to the present invention it was determined to melt or warp by leaving in a high temperature oven at 90 °C for 3 hours and the degree of reverberation of the initial fragrance was 5 points and after 3 hours at room temperature After cooling, the intensity of incense was evaluated from 1 to 5 points to evaluate relative reverberation. Evaluation criteria were based on the standard shown in Table 4 based on the room temperature standard.
- Comparative Examples 1 to 3 are combinations of waxes generally used in fragrance candles. As a result of evaluating at high temperature for Comparative Examples 1 to 3, it was confirmed that all the downflow occurred and the degree of downflow improved as the amount of petroleum-based high melting point paraffin wax was increased. It was judged to be due to the high content of wax with low melting point such as Soy wax, and Comparative Example 2 with high melting point paraffin wax was maintained more stable than Comparative Example 1, but it was bent or melted than Comparative Example 3 with higher melting point paraffin wax The falling phenomenon is more severe.
- Example 1 In the present invention it was confirmed that the higher the melting point in Examples 1 to 3 with high melting point microcrystalline wax is better in high temperature stability. However, in Example 1 to which the multi-wax with low melting point was applied, it was confirmed that deformation occurred at 90 ° C. In addition, Examples 2 and 3 in which the melting point was applied to the wax of 110 ° C or more, the surface was not good after appearance and cracking of the surface after high temperature aging. This is because wax having a high melting point lowers the penetration rate of the liquid fragrance.
- Examples 4 and 5 showed better results in surface cracking and aging stability when mixed with various types of microcrystal waxes, and especially in the case of using a lot of waxes with high melting points as in Example 5 It was confirmed that the appearance quality is good at the content of.
- Example 6 and Example 7 were better in maintaining the appearance of cracks, fractures, warpage and the like when using petroleum waxes other than natural waxes, which are known to be compatible with fragrances, and smelled. It was also confirmed that the characteristics of. In addition, it was found that the smoothness of the surface and the like was the best when Soywax excellent in compatibility with the fragrance is applied. When the wax having excellent compatibility for fragrance was also used in the fragrance characteristic, the fragrance of the fragrance was reduced even in the long-term room temperature fragrance evaluation.
- the inventors left the room at room temperature after 1 day, after 7 days so that the natural odor in the 4.5m 3 space, the intensity of the fragrance present in the space It evaluated by the 5-point evaluation method.
- a total of 10 evaluators were trained for clarity. The evaluation was conducted one by one in a standalone evaluation booth with forced ventilation, and three or more evaluations were limited at one time to increase the accuracy of the evaluation.
- Table 6 below is a criterion for evaluating fragrance in space.
- the present inventors confirmed that the difference in the odor according to room temperature with time is maintained as the appearance quality is maintained at 90 ° C. and 3 hours at high temperature, and there is no crack or breakage.
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Abstract
Description
향료명 | CAS No. | 분자량 | 끓는점(℃) | logP | 잔향 정도 |
오란티올(Aurantiol) | 89-43-0 | 305 | 450 | 4.2 | O |
아밀 시나메이트(Amyl cinnamate) | 3487-99-8 | 218 | 312 | 3.8 | O |
박다놀(Bacdanol) | 28219-61-6 | 208 | 287 | 4.3 | O |
캐쉬메란(Cashmeran) | 33704-61-9 | 206 | 285 | 4.5 | O |
세르볼라이드(Cervolide) | 6707-60-4 | 256 | 409 | 3.7 | O |
시나밀 시나메이트(Cinnamyl cinnamate) | 122-69-0 | 264 | 370 | 5.5 | O |
시트랄(Citral) | 5392-40-5 | 152 | 103 | 3.4 | X |
디하이드로미르세놀(Dihydromyrcenol) | 18479-58-8 | 156 | 196 | 3.0 | X |
에틸렌 브라실레이트(Ethylene brassylate) | 105-95-3 | 270 | 332 | 4.6 | O |
갈락솔라이드(Galaxolide) | 1222-05-5 | 258 | 326 | 5.3 | O |
헬베톨라이드(Helvetolide) | 141773-73-1 | 284 | 346 | 4.7 | O |
헥사데카놀라이드(Hexadecanolide) | 109-29-5 | 254 | 358 | 6.7 | O |
헥실 살리실레이트(Hexyl Salicylate) | 6259-76-3 | 222 | 290 | 5.1 | O |
이소-E 슈퍼(Iso-E Super) | 54464-57-2 | 234 | 312. | 3.6 | O |
이소프로필 미리스테이트(Isopropyl myristate) | 110-27-0 | 271 | 320 | 7.2 | O |
리모넨(Limonene) | 5989-27-5 | 136 | 176 | 4.6 | X |
라이랄(Lyral) | 31906-04-4 | 210 | 319 | 2.1 | X |
메틸 디하이드로자스모네이트(Methyl dihydrojasmonate) | 24851-98-7 | 226 | 308 | 2.7 | O |
페닐에틸 페닐아세테이트(Phenylethyl phenylacetate) | 102-20-5 | 240 | 325 | 3.8 | O |
로만돌라이드(Romandolide) | 236391-76-7 | 270 | 308 | 4.6 | O |
토날리드(Tonalid) | 1506-02-1 | 258 | 393 | 5.1 | O |
트리샘버(Trisamber) | 338735-71-0 | 250 | 263 | 6.2+ | O |
No. | 향료명 | CAS No. | 함량(중량%) |
1 | 오란티올(Aurantiol) | 89-43-0 | 10.0 |
2 | 박다놀(Bacdanol) | 28219-61-6 | 10.0 |
3 | 시트랄(Citral) | 5392-40-5 | 10.0 |
4 | 에틸렌 브라실레이트(Ethylene brassylate) | 105-95-3 | 5.0 |
5 | 갈락솔라이드(Galaxolide) | 1222-05-5 | 5.0 |
6 | 헥실 살리실레이트(Hexyl Salicylate) | 6259-76-3 | 5.0 |
7 | 이소-E 슈퍼(Iso-E Super) | 54464-57-2 | 5.0 |
8 | 라이랄(Lyral) | 31906-04-4 | 30.0 |
9 | 메틸 디하이드로자스모네이트(Methyl dihydrojasmonate) | 24851-98-7 | 10.0 |
10 | 페닐에틸 페닐아세테이트(Phenylethyl phenylacatete) | 102-20-5 | 5.0 |
11 | 트리샘버(Trisamber) | 338735-71-0 | 5.0 |
합계 | 100.0 |
no. | 구분 | 성분(중량%) | 비교예1 | 비교예2 | 비교예3 | 실시예1 | 실시예2 | 실시예3 | 실시예4 | 실시예5 | 실시예6 | 실시예7 |
1 | 천연 왁스 | 소이왁스(Soy wax) | 20 | - | 10 | - | - | - | - | - | - | 5 |
2 | 비즈 왁스(Bees wax) | 50 | - | - | - | - | - | - | - | - | - | |
3 | 파라핀 왁스 | 저융점 파라핀 왁스 | - | 35 | 10 | - | - | - | - | - | 10 | - |
4 | 고융점 파라핀 왁스 | - | 35 | 50 | - | - | - | - | - | 5 | ||
5 | 마이크로크리스탈린 왁스 | 멀티 왁스(Multi wax) W-445 | - | - | - | 70 | - | - | 40 | 10 | 15 | 15 |
6 | 하이 왁스(Hi wax) 410P | - | - | - | - | 70 | - | 20 | 20 | 25 | 25 | |
7 | 하이 왁스(Hi wax) 400P | - | - | - | - | - | 70 | 10 | 40 | 20 | 20 | |
8 | 공중합 폴리머 | EMA 1605 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
9 | 계면활성제 | 소르비탄 모노스테아레이트(Sorbitan monostearate) | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
10 | 향료 | 표 2의 복합 향료 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 |
합계 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | ||
융점(℃) | 50 | 60 | 60 | 80 | 95 | 105 | 100 | 110 | 105 | 100 |
점수 | 평가 내용 |
1점 | 향취 없음 |
2점 | 표준품보다 향취가 매우 약함 |
3점 | 표준품보다 향취가 약함 |
4점 | 표준품보다 향취가 조금 약함 |
5점 | 표준품과 같이 향취가 같음 |
비교예 1 | 비교예 2 | 비교예 3 | 실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | |
평균 | 0.8 | 1.1 | 1.5 | 2.7 | 2.9 | 2.9 | 3.5 | 4.0 | 4.0 | 4.1 |
점수 | 평가 내용 |
1점 | 향이 매우 좋지 않음 |
2점 | 향이 좋지 않음 |
3점 | 향이 보통임 |
4점 | 향이 좋음 |
5점 | 향이 매우 좋음 |
비교예 1 | 비교예 2 | 비교예 3 | 실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | |
1일 후 | 4.3 | 4.2 | 4.3 | 4.3 | 4.2 | 4.2 | 4.4 | 4.5 | 4.5 | 4.5 |
7일 후 | 2.2 | 2.1 | 2.2 | 2.8 | 3.0 | 3.0 | 3.4 | 3.5 | 3.7 | 3.9 |
Claims (7)
- 마이크로크리스탈린 왁스를 포함하며, 융점이 90 내지 125℃인 것을 특징으로 하는 방향제 조성물.
- 제1항에 있어서,상기 조성물은 천연 왁스, 파라핀 왁스 또는 이들 모두를 더 포함하는 것을 특징으로 하는 방향제 조성물.
- 제1항에 있어서,상기 조성물은 향료를 조성물 총 중량 대비 1 내지 50 중량% 포함하는 것을 특징으로 하는 방향제 조성물.
- 제3항에 있어서,상기 향료는 옥탄올/물 분배 계수의 로그 값이 3 내지 8, 및 끓는점이 200 내지 500℃인 향료를 향료 총 중량 대비 5 내지 80 중량% 포함하는 것을 특징으로 하는 방향제 조성물.
- 제1항에 있어서,상기 마이크로크리스탈린 왁스는 조성물 총 중량 대비 10 내지 90 중량% 포함되는 것을 특징으로 하는 방향제 조성물.
- 제2항에 있어서,상기 파라핀 왁스는 융점이 40 내지 90℃인 것을 특징으로 하는 방향제 조성물.
- 제1항 내지 제6항 중 어느 한 항에 따른 조성물을 포함하는 방향제.
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JP2019507172A JP7217067B2 (ja) | 2016-08-10 | 2017-06-05 | 高耐熱性芳香剤組成物 |
CN201780048519.9A CN109562198B (zh) | 2016-08-10 | 2017-06-05 | 高耐热性芳香剂组合物 |
JP2022015627A JP7301451B2 (ja) | 2016-08-10 | 2022-02-03 | 高耐熱性芳香剤組成物 |
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KR20160049513A (ko) * | 2016-04-14 | 2016-05-09 | 주식회사 불스원 | 훈증형 조성물 및 이를 포함하는 가열 증산장치 |
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JP5507790B2 (ja) | 2006-11-29 | 2014-05-28 | ペガサス・キャンドル株式会社 | 薄片状芳香剤 |
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JP2014094929A (ja) * | 2012-10-09 | 2014-05-22 | Pola Chem Ind Inc | 毛穴隠しに好適な化粧方法およびその化粧料 |
KR20160042586A (ko) | 2014-10-10 | 2016-04-20 | 박흥순 | 방향제 조성물 및 이를 이용한 방향제 제품 |
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US20050124530A1 (en) * | 2002-04-03 | 2005-06-09 | Serge Creutz | Fragrance compositions |
US20050086853A1 (en) * | 2003-10-23 | 2005-04-28 | Hudson Carl W. | Wax blends for candles with improved properties |
US8426352B2 (en) * | 2010-04-23 | 2013-04-23 | The Procter & Gamble Company | Scenting composition |
KR20160029807A (ko) * | 2013-07-09 | 2016-03-15 | 닛산 가가쿠 고교 가부시키 가이샤 | 분산액 및 하이드로겔 형성방법 |
KR20160049513A (ko) * | 2016-04-14 | 2016-05-09 | 주식회사 불스원 | 훈증형 조성물 및 이를 포함하는 가열 증산장치 |
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JP7217067B2 (ja) | 2023-02-02 |
KR20210084402A (ko) | 2021-07-07 |
KR102433106B1 (ko) | 2022-08-18 |
JP7301451B2 (ja) | 2023-07-03 |
JP2022051827A (ja) | 2022-04-01 |
JP2019531110A (ja) | 2019-10-31 |
KR20180017707A (ko) | 2018-02-21 |
KR102273880B1 (ko) | 2021-07-05 |
CN109562198A (zh) | 2019-04-02 |
CN109562198B (zh) | 2022-09-02 |
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