WO2018024181A1 - Procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux - Google Patents

Procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux Download PDF

Info

Publication number
WO2018024181A1
WO2018024181A1 PCT/CN2017/095363 CN2017095363W WO2018024181A1 WO 2018024181 A1 WO2018024181 A1 WO 2018024181A1 CN 2017095363 W CN2017095363 W CN 2017095363W WO 2018024181 A1 WO2018024181 A1 WO 2018024181A1
Authority
WO
WIPO (PCT)
Prior art keywords
titanium dioxide
foam
graphene
metal
foam metal
Prior art date
Application number
PCT/CN2017/095363
Other languages
English (en)
Chinese (zh)
Inventor
杨与畅
Original Assignee
福建新峰二维材料科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 福建新峰二维材料科技有限公司 filed Critical 福建新峰二维材料科技有限公司
Publication of WO2018024181A1 publication Critical patent/WO2018024181A1/fr

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/18—Electroplating using modulated, pulsed or reversing current
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/46—Electroplating: Baths therefor from solutions of silver
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/48—Electroplating: Baths therefor from solutions of gold
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48—After-treatment of electroplated surfaces
    • C25D5/50—After-treatment of electroplated surfaces by heat-treatment
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D9/00—Electrolytic coating other than with metals
    • C25D9/04—Electrolytic coating other than with metals with inorganic materials
    • C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes

Definitions

  • the invention relates to the field of photocatalysis technology, in particular to a method for preparing a graphene foam metal loaded with a titanium dioxide-precious metal film.
  • Titanium dioxide has the advantages of high photocatalytic activity, low cost and easy availability, good stability, non-toxicity and harmlessness, and is widely used in photocatalytic degradation of organic pollutants in air or sewage, sterilization, self-cleaning and the like.
  • the titanium dioxide powder is easy to aggregate in the suspension system and is difficult to separate and recycle, which hinders its application.
  • the use of catalyst immobilization is one of the effective ways to solve this problem, and is generally achieved by a method of preparing a photocatalytic film or coating.
  • the colloidal solution of TiO 2 is generally prepared by a sol-gel technique, and then the thickness of the film is quantitatively controlled by controlling the pulling speed and the number of times by using the immersion pulling method.
  • the method can form a film on both sides of the substrate, and is suitable for A variety of temperature-resistant substrate materials such as glass, ceramics, stainless steel, etc.
  • the TiO 2 colloidal solution may also be applied to the surface of the substrate material by brushing, dispensing, spin coating or the like. However, this method is more suitable for the surface material with a flat surface to obtain a TiO 2 film of a relatively uniform thickness.
  • the TiO 2 film can also be prepared by physical vapor deposition and chemical vapor deposition.
  • the coating equipment is complex, has certain requirements on the degree of vacuum, and requires strict control of deposition conditions, high cost and complicated process.
  • the object of the present invention is to overcome the defects of the prior art and provide a method for preparing a graphene foam metal loaded with a titanium dioxide-precious metal film, which has a simple process and is easy to perform large-area plating; the operation is easier and safer.
  • the present invention adopts the following technical scheme, a method for preparing a graphene foam metal loaded with a titanium dioxide-precious metal film, comprising the steps of: preparing an electrolyte containing butyl titanate; and cleaning the surface on which the electroplated surface is deposited with graphene.
  • Electrochemical deposition which is deposited by an electrochemical workstation comprising a working electrode, a counter electrode and a reference electrode, an electrolytic cell, the working electrode being a metal foam to be plated,
  • the electrode is a platinum electrode
  • the reference electrode is a saturated calomel electrode
  • the electrolyte is placed in an electrolytic cell; the electrochemically deposited graphitized foam metal loaded with a titanium dioxide-precious metal film is cleaned and dried; after cleaning and drying The graphene foam metal loaded with a titanium dioxide-precious metal film is sintered.
  • the electrolyte containing the butyl titanate is specifically prepared as follows: 20-120 ml of deionized water is placed in the No. 1 cup, and 15-100 ml of absolute ethanol is placed in the No. 2 cup; and 100-500 ul is taken. Concentrated nitric acid was dropped into the No. 1 cup, then covered with plastic wrap, ultrasonicated with an ultrasonic cleaner for 5-30 min; 100-500 ul of hydrogen peroxide was dropped into the No. 2 cup, and then 0.1-1 g of titanate was added dropwise. The ester was covered with plastic wrap. The No. 1 cup and the No. 2 cup were placed in an ultrasonic cleaner for 5-30 min. After the end of the ultrasound, the solution of the No.
  • the foam metal on which the surface to be electroplated is deposited with graphene is specifically: a metal foam having graphene deposited on the surface, and after being placed in an acetone solution, ultrasonicating for 5-30 min; taking out the foam metal and adding absolute ethanol Then perform ultrasonic for 5-30 min; remove the foam metal and place it in deionized water for 5-30 min.
  • the graphene foam metal is placed in the electrolyte for electrochemical deposition, specifically: the cleaned graphene foam metal is placed in the electrolyte, and the cyclic deposition is performed by electrochemical deposition.
  • the graphene foam metal cleaning and drying of the electrochemically deposited titanium dioxide-precious metal film is specifically: after the electrochemical deposition is completed, the graphene foam metal supporting the titanium dioxide-precious metal film is taken out and deionized. Rinse the surface with water and then dry in an oven at 50-100 °C.
  • the foamed metal after washing and drying is sintered to prepare a graphene foam metal supporting a titanium dioxide-precious metal film, specifically: heating the metal foam at a temperature of 300-600 ° C for 1-5 hours, and then heating The tempering was carried out for 1-5 hours, and after completion, the graphene foam metal supporting the titanium dioxide-precious metal film was taken out by cooling.
  • the metal foam is nickel foam, copper foam or aluminum foam.
  • the invention adopts the above technical solution to deposit a titanium dioxide-precious metal film on a foam metal on which graphene is deposited, which can be produced at normal temperature without residual thermal stress problem, and is beneficial to enhancing the bonding force between the substrate and the coating.
  • the process is simple, easy to carry out large-area plating; no need for high vacuum, no dangerous gas, etc.; operation is easier and safer; the surface of the foam metal can be uniformly deposited on the film, and the adhesion is good; the prepared titanium dioxide - The noble metal film is evenly distributed on the surface of the graphene in the metal foam, which not only improves the contact area, but also avoids the agglomeration of the self particles, effectively prolongs the carrier lifetime generated by the titanium dioxide-precious metal film, and prevents the recombination of holes and electrons.
  • the prepared titanium dioxide-precious metal film was used for the photocatalytic degradation test of Rhodamine B solution, and the results showed that the material has high photocatalytic activity.
  • Example 2 is a schematic view showing the degradation rate of the rhodamine B solution of the graphene foam metal loaded with titanium dioxide-precious metal film prepared in Example 1-3 of the present invention.
  • Supported titania of the present invention preparation of the noble metal thin film graphene metal foam, wherein the noble metal-modified TiO 2 TiO 2 is influenced by the surface properties of the electron distribution changes in the system, thereby improving the photocatalytic activity.
  • the work function of the noble metal is higher than the work function of TiO 2 .
  • the energy band of the semiconductor will bend upward toward the surface to form a lossy layer, forming a shallow well energy barrier that traps electrons at the noble metal-TiO 2 interface, further suppressing the recombination of photogenerated electrons and holes.
  • the deposition of noble metal on the surface of TiO 2 is generally carried out by an immersion reduction method in which TiO 2 is immersed in a solution containing a noble metal salt and then reduced at a high temperature. Due to the high porosity, good mechanical properties, structural uniformity and hydrodynamic properties of the metal foam material, the foam metal-supported photocatalyst has a higher contact surface, and the photocatalyst has a wider effective range, which can effectively improve the photocatalytic efficiency. A good substrate material for supporting photocatalysts.
  • the electrochemical deposition according to the present invention is a process in electrophoretic painting, in which a charged resin particle reaches a counter electrode under the action of a direct current electric field, and is deposited by discharging (or obtaining electrons) a water-insoluble paint film.
  • the surface of the coating is first carried out at a site where the power line density is particularly high (such as the edge edges and tips of the object to be coated). Once the deposition occurs, the object to be coated has a certain degree of insulation, and the electrodeposition gradually moves to a portion where the power line density is low. Until finally a completely uniform coating is obtained.
  • the preparation method of the graphene foam metal loaded with the titanium dioxide-precious metal film according to the present invention is as follows:
  • the metal foam is nickel foam, and the specific steps are as follows:
  • the foamed nickel to be plated is placed in an acetone solution for 5 min, then ultrasonicated with absolute ethanol for 5 min, and finally ultrasonicated for 5 min with deionized water to wash the foamed nickel on which the graphene is deposited on the surface to be electroplated;
  • the cleaned foamed nickel is connected to the working electrode of the electrochemical workstation, and the platinum counter electrode and the saturated calomel reference electrode are connected, and the electrodes are placed together in the prepared electrolyte; the scanning speed is 50 mV/s, and the voltage range is -0.1-0.5V, the scanning cycle is 500 times for cyclic electrochemical deposition, wherein the object to be coated in the electrochemical deposition in this embodiment is foamed nickel with graphene, and the coating is titanium dioxide-precious metal. In the example, it is titanium dioxide-gold.
  • the graphene foamed nickel coated with the titanium dioxide-precious metal film is taken out, the surface is rinsed with deionized water, and then dried in an oven at 100 ° C; then the nickel foam is placed in a muffle furnace and heated at 500 ° C. After 3 hours, the temperature was kept for 5 hours, and after completion, the graphene foamed nickel supporting the titanium dioxide-precious metal film was taken out by cooling.
  • the photocatalytic test and photoelectrocatalytic test of the titanium dioxide-precious metal film prepared by the invention are carried out:
  • Rhodamine B solution was prepared by: pour 100ml of 10mg/L Rhodamine B solution into the culture dish and submerge the foamed nickel; place the culture dish in the photochemical reactor for photocatalytic reaction; sample every 5 minutes, and measure the absorbance of the solution by UV-visible spectrophotometry. The photodegradation rate of Rhodamine B solution was calculated.
  • the graphene foamed nickel loaded with the titanium dioxide-precious metal film prepared above was first ultrasonicated with acetone for 5 min, then ultrasonicated with absolute ethanol for 5 min, and finally ultrasonicated with deionized water for 5 min; 100 ml of a NaOH solution having a concentration of 0.1 mol/L was placed.
  • test electrolyte Into the beaker, as the test electrolyte; connect the foamed nickel to the working electrode of the electrochemical workstation, and connect the platinum counter electrode and the saturated calomel reference electrode, set the voltage to 0.5V; then start the test, after testing 600S, turn on the xenon light source, Irradiation on the working electrode, according to the cycle 100S, Break the light source and observe the change of current before and after the light source.
  • test results are shown in Figure 2.
  • the photocatalytic degradation of rhodamine B solution by the graphene foam nickel supported on the titanium dioxide-precious metal film obtained in the first embodiment has a degradation rate of 100% in 35 minutes, and the photocatalytic result is that the current of the xenon lamp source is increased from 11 mA to 14 mA, and the photocatalytic effect is obvious. .
  • the foam metal in the embodiment is foamed copper.
  • 50 ml of deionized water is placed in the beaker No. 1, 200 ul of concentrated nitric acid is added, and the plastic wrap is covered with ultrasonic for 10 min; Put the beaker into 50ml of absolute ethanol, add 200ul of hydrogen peroxide, place the beaker on the balance and add 0.2g of butyl titanate, cover the plastic wrap; and sonicate with the No. 1 solution for 10min, then open the wrap film after the end The No. 2 solution was dropped into the No.
  • the foamed copper to be plated was placed in acetone solution for 20 min, then ultrasonicated with absolute ethanol for 20 min, and finally ultrasonicated with deionized water for 20 min; the cleaned foamed copper was connected to the working electrode of the electrochemical workstation, and platinum was connected.
  • the counter electrode and the saturated calomel reference electrode are placed in the prepared electrolyte together; the electrochemical deposition is performed at a scanning speed of 50 mV/s, a voltage range of -0.1-0.5 V, and a scanning period of 200 times, wherein
  • the object to be coated is foamed copper with graphene, and the coating layer is titanium dioxide-precious metal.
  • the copper oxide coated with the titanium dioxide-precious metal film was taken out, the surface was rinsed with deionized water, and then dried in an oven at 100 ° C; then the copper foam was placed in a muffle furnace and heated at 500 ° C for 3 hours. After 5 hours of heat retention, after completion, the graphene foam copper loaded with the titanium dioxide-precious metal film was taken out by cooling.
  • the photocatalytic test and the photoelectrocatalytic test procedure were the same as those in Example 1, and the test results are shown in FIG.
  • the photocatalytic degradation of rhodamine B solution of graphene foam copper loaded with titanium dioxide-precious metal film obtained in the second embodiment has a degradation rate of 100% in 35 minutes, and the photocatalytic result is that the current of the xenon lamp source is increased from 11 mA to 14 mA, and the photocatalytic effect is obvious. .
  • the foam metal in the embodiment is aluminum foam.
  • 100 ml of deionized water is placed in a beaker No. 1, 500 ul of concentrated nitric acid is added, and the plastic wrap is covered with ultrasonic for 20 min;
  • the beaker was placed in 100 ml of absolute ethanol, 500 ul of hydrogen peroxide was added dropwise, and the beaker was placed on the balance with 0.5 g of butyl titanate, and the plastic wrap was covered; the same solution was used for 20 min, and the plastic wrap was opened after the end.
  • the No. 2 solution was dropped into the No. 1 solution, and the solution was again ultrasonicated for 20 minutes to allow the solution to be thoroughly mixed;
  • the plastic wrap was again poured into 500 ul of silver nitrate, and the wrap film was ultrasonicated for 30 min to obtain the electrolytic solution of Example 3.
  • the foamed aluminum to be plated was ultrasonicated in acetone solution for 20 min, then ultrasonicated with absolute ethanol for 20 min, and finally ultrasonicated with deionized water for 20 min; the cleaned aluminum foam was connected to the working electrode of the electrochemical workstation, and platinum was connected at the same time.
  • the counter electrode and the saturated calomel reference electrode are placed together in the prepared electrolyte; the electrochemical deposition is performed at a scanning speed of 50 mV/s, a voltage range of -0.1 to 0.5 V, and a scanning period of 500 times, wherein
  • the object to be coated is aluminum oxide with graphene, and the coating layer is titanium dioxide-precious metal, which is titanium dioxide-silver in this embodiment.
  • the graphene aluminum foam coated with the titanium dioxide-precious metal film is taken out, the surface is rinsed with deionized water, and then dried in an oven at 100 ° C; then the aluminum foam is placed in a muffle furnace and heated at 500 ° C. After 3 hours, the temperature was kept for 5 hours. After the end, the graphene foam aluminum loaded with the titanium dioxide-precious metal film was taken out by cooling.
  • the graphene foam aluminum loaded with the titanium dioxide-precious metal film obtained in the third embodiment was photocatalyzed to degrade the rhodamine B solution, and the test results are shown in FIG. 2 .
  • the degradation rate reached 100% in 30min.
  • the photocatalytic result was that the xenon lamp source was irradiated with 100S current from 11mA to 16mA, and the photocatalytic effect was obvious.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

Cette invention concerne un procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux. Le procédé comprend : la préparation d'un électrolyte contenant du dioxyde de titane ; le nettoyage d'une mousse métallique destinée à subir un dépôt électrolytique, présentant sur sa surface un dépôt de graphène ; le positionnement de la mousse métallique au graphène dans l'électrolyte pour effectuer un dépôt électrochimique, le dépôt électrochimique étant effectué à l'aide d'un poste de travail électrochimique, le poste de travail électrochimique comprenant une électrode de travail, une contre-électrode, une électrode de référence et une cellule électrolytique, l'électrode de travail étant une mousse métallique destinée à subir un dépôt électrolytique, la contre-électrode étant une électrode en platine, l'électrode de référence étant une électrode de calomel saturé, et l'électrolyte étant placé dans la cellule électrolytique ; le nettoyage et le séchage de la mousse métallique au graphène ayant subi le dépôt électrolytique pour le support d'un film mince en dioxyde de titane/métal précieux ; et le frittage de la mousse métallique au graphène nettoyée et séchée pour le support d'un film mince en dioxyde de titane/métal précieux. La mousse métallique au graphène destinée à supporter un film mince en dioxyde de titane/métal précieux préparée à l'aide du procédé prolonge efficacement la durée de vie d'un support généré à l'aide d'un film photocatalytique, et empêche la recombinaison d'un trou et d'électrons.
PCT/CN2017/095363 2016-08-01 2017-08-01 Procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux WO2018024181A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610619640.XA CN107675219A (zh) 2016-08-01 2016-08-01 负载二氧化钛‑贵金属薄膜的石墨烯泡沫金属的制备方法
CN201610619640.X 2016-08-01

Publications (1)

Publication Number Publication Date
WO2018024181A1 true WO2018024181A1 (fr) 2018-02-08

Family

ID=61072480

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/095363 WO2018024181A1 (fr) 2016-08-01 2017-08-01 Procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux

Country Status (2)

Country Link
CN (1) CN107675219A (fr)
WO (1) WO2018024181A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112374767A (zh) * 2019-11-07 2021-02-19 陕西彩虹新材料有限公司 一种光伏玻璃用功能涂层的制备方法
CN113856757A (zh) * 2021-11-04 2021-12-31 广东工业大学 一种聚多巴胺修饰氮化碳/二氧化钛负载泡沫镍复合光催化剂及其制备方法和应用
CN113979514A (zh) * 2021-10-22 2022-01-28 周口师范学院 一种Ni基CuFe2O4尖晶石涂层电极材料的制备方法
CN114411205A (zh) * 2022-01-21 2022-04-29 中国人民解放军陆军勤务学院 一种石墨烯负载镍颗粒复合粉末的制备方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114373938B (zh) * 2021-01-15 2024-02-02 西安石油大学 一种镍基三维有序二氧化钛/石墨烯复合材料的制备方法及其在锂离子电池中的应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101757902A (zh) * 2010-01-12 2010-06-30 海盐华强树脂有限公司 一种含活性炭涂层复合型光催化剂的制备方法
EP2647430A1 (fr) * 2012-04-05 2013-10-09 Commissariat à l'Énergie Atomique et aux Énergies Alternatives Procédé de préparation d'un catalyseur pour la évolution de H2, ledit catalyseur et utilisations associées
US20140346408A1 (en) * 2013-05-23 2014-11-27 Electronics And Telecommunications Research Institute Method of manufacturing graphene hybrid material and graphene hybrid material manufactured by the method
CN104588021A (zh) * 2014-12-31 2015-05-06 浙江大学 一种二氧化钛光催化涂层的制备方法及用途
CN105671611A (zh) * 2016-02-05 2016-06-15 浙江大学 一种石墨烯表面直接负载纳米氧化物的方法
CN106140127A (zh) * 2015-05-15 2016-11-23 蓝石科技(开曼)有限公司 一种复合可见光催化材料及其制备方法
CN106140126A (zh) * 2015-05-15 2016-11-23 蓝石科技(开曼)有限公司 一种粉末状复合光催化材料及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101608330B (zh) * 2009-07-14 2010-10-13 华中科技大学 一种二氧化钛镀膜的低温制备方法
CN106129329A (zh) * 2016-07-08 2016-11-16 中国工程物理研究院材料研究所 一种石墨烯基锂离子电池负极用复合电极及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101757902A (zh) * 2010-01-12 2010-06-30 海盐华强树脂有限公司 一种含活性炭涂层复合型光催化剂的制备方法
EP2647430A1 (fr) * 2012-04-05 2013-10-09 Commissariat à l'Énergie Atomique et aux Énergies Alternatives Procédé de préparation d'un catalyseur pour la évolution de H2, ledit catalyseur et utilisations associées
US20140346408A1 (en) * 2013-05-23 2014-11-27 Electronics And Telecommunications Research Institute Method of manufacturing graphene hybrid material and graphene hybrid material manufactured by the method
CN104588021A (zh) * 2014-12-31 2015-05-06 浙江大学 一种二氧化钛光催化涂层的制备方法及用途
CN106140127A (zh) * 2015-05-15 2016-11-23 蓝石科技(开曼)有限公司 一种复合可见光催化材料及其制备方法
CN106140126A (zh) * 2015-05-15 2016-11-23 蓝石科技(开曼)有限公司 一种粉末状复合光催化材料及其制备方法
CN105671611A (zh) * 2016-02-05 2016-06-15 浙江大学 一种石墨烯表面直接负载纳米氧化物的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHANG, XINYUAN: "Study on the Preparation of Modified Foam Nickel Material and its Catalysis Performance", SCIENCE -ENGINEERING (A), CHINA MASTER'S THESES FULL-TEXT DATABASE, 15 May 2014 (2014-05-15), pages 10, ISSN: 1674-0246 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112374767A (zh) * 2019-11-07 2021-02-19 陕西彩虹新材料有限公司 一种光伏玻璃用功能涂层的制备方法
CN113979514A (zh) * 2021-10-22 2022-01-28 周口师范学院 一种Ni基CuFe2O4尖晶石涂层电极材料的制备方法
CN113979514B (zh) * 2021-10-22 2023-04-28 周口师范学院 一种Ni基CuFe2O4尖晶石涂层电极材料的制备方法
CN113856757A (zh) * 2021-11-04 2021-12-31 广东工业大学 一种聚多巴胺修饰氮化碳/二氧化钛负载泡沫镍复合光催化剂及其制备方法和应用
CN113856757B (zh) * 2021-11-04 2023-08-22 广东工业大学 一种聚多巴胺修饰氮化碳/二氧化钛负载泡沫镍复合光催化剂及其制备方法和应用
CN114411205A (zh) * 2022-01-21 2022-04-29 中国人民解放军陆军勤务学院 一种石墨烯负载镍颗粒复合粉末的制备方法
CN114411205B (zh) * 2022-01-21 2023-10-27 中国人民解放军陆军勤务学院 一种石墨烯负载镍颗粒复合粉末的制备方法

Also Published As

Publication number Publication date
CN107675219A (zh) 2018-02-09

Similar Documents

Publication Publication Date Title
WO2018024181A1 (fr) Procédé de préparation d'une mousse métallique au graphène pour le support d'un film mince en dioxyde de titane/métal précieux
CN101872862B (zh) 燃料电池板的表面的涂覆方法
Pyeon et al. Critical role and modification of surface states in hematite films for enhancing oxygen evolution activity
WO2003078694A1 (fr) Electrode utilisee pour la production d'hydrogene
CN108217852B (zh) 在电催化污水处理中用作阳极的二氧化铅电极及其制备方法
JP2016540118A (ja) グラフェンで覆われた電極を含む電気化学セル
JP2005240074A (ja) 導電性ダイヤモンド電極及びその製造方法
CN108597886B (zh) 一种用于改性氧化铁光阳极的有机溶液及其应用
Gowthaman et al. Modification of a glassy carbon electrode with gold–platinum core–shell nanoparticles by electroless deposition and their electrocatalytic activity
JP2012517532A (ja) 酸化物材料を調製するための溶液をベースとする非真空法および装置
WO2017192057A4 (fr) Revêtements poreux modifiés et dispositif modulaire pour le traitement de l'air contenant des revêtements poreux modifiés
CN103159299A (zh) 一种多孔钛膜光电催化废水反应装置
CN106048690A (zh) 一种钛基二氧化钛纳米管复合阳极及其制备方法
CN109589993A (zh) 电化学改性的钒酸铋-硫化钼-四氧化三钴催化电极及其制备方法和应用
CN104047043A (zh) TiO2/SnO2半导体双层复合膜光阳极的制备方法
US20220341027A1 (en) Method for preparing bismuth oxide nanowire films by heating in upside down position
CN111068639A (zh) 氧化锌掺杂混合晶型二氧化钛纳米管光催化复合材料
CN102534725A (zh) 一种制备Ag2S掺杂TiO2纳米管电极的方法
CN102534718B (zh) 一种制备PbO2修饰TiO2纳米管电极的方法
US20030098236A1 (en) Electrophoretically deposited hydrophilic coatings for fuel cell diffuser/current collector
CN111003759A (zh) 含亚氧化钛中间层的涂层电极及其制备方法与应用以及电化学水处理设备
CN101396651B (zh) 一种纳米有序构造的光电转换复合薄膜及其制备方法
CN106967979A (zh) 一种磷酸钴助催化剂改性BiFeO3薄膜光电极及其制备方法
CN101956194A (zh) 一种TiO2薄膜修饰的钛基β-PbO2光电极的制备方法
CN110330078B (zh) 一种高效长寿命的三维结构锑掺杂氧化锡电极

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17836363

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17836363

Country of ref document: EP

Kind code of ref document: A1