WO2017201883A1 - Environment-friendly mildew-proof coating adhesive - Google Patents

Environment-friendly mildew-proof coating adhesive Download PDF

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Publication number
WO2017201883A1
WO2017201883A1 PCT/CN2016/094013 CN2016094013W WO2017201883A1 WO 2017201883 A1 WO2017201883 A1 WO 2017201883A1 CN 2016094013 W CN2016094013 W CN 2016094013W WO 2017201883 A1 WO2017201883 A1 WO 2017201883A1
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WO
WIPO (PCT)
Prior art keywords
parts
environment
proof coating
coating adhesive
friendly
Prior art date
Application number
PCT/CN2016/094013
Other languages
French (fr)
Chinese (zh)
Inventor
陈金才
Original Assignee
陈金才
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Publication of WO2017201883A1 publication Critical patent/WO2017201883A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

Definitions

  • the invention relates to the technical field of chemical products, in particular to a green environmental protection mildew-proof coating.
  • Gluing has a very large role in production and life. It is widely used in various fields.
  • the coating film formed by gluing can play the role of decoration, protection and adhesion to objects, and the adhesion between objects and objects is very large.
  • the role of most of the current coatings on the market although simple to manufacture, cheap, but at the same time the function is relatively simple, can only be used as a decoration, and will be degummed after long-term use, and in some special working environment In the simple application of glue, it does not meet people's needs.
  • a green environmentally-friendly mold-proof coating according to the present invention comprising the following components by weight,
  • the invention provides a green environmental protection mildew-proof coating glue, which is simple to manufacture, adopts non-toxic production raw materials, has good use effect of coating glue, is environmentally friendly, is applied to the surface of metal or plastic products, prevents mildew on metal surface, can enhance Storage stability of the product.
  • a green environmentally-friendly mold-proof coating comprising the following components by weight, 40 parts of benzoyl peroxide, 10 parts of isopropyl acrylate, 20 parts of titanium tetraisopropoxide, 10 parts of phenol, 40 parts of talc, and poly different 40 parts of butyl ester, 20 parts of aluminum hydroxide, 12 parts of phosphate triester, 80 parts of isopropanol, 10 parts of polyvinyl alcohol, 10 parts of zirconium tetrapropoxide, and 10 parts of ethylenediamine methyl propionate are heated and mixed. Only 80 ° C and reflux for 2 hours, after cooling, mixing and stirring to obtain the product.
  • a green environmentally friendly mold-proof coating comprising the following components by weight, 60 parts of benzoyl peroxide, 20 parts of isopropyl acrylate, 30 parts of titanium tetraisopropoxide, 15 parts of phenol, 50 parts of talc, and poly 50 parts of isobutyl ester, 30 parts of aluminum hydroxide, 18 parts of phosphate triester, 90 parts of isopropanol, 15 parts of polyvinyl alcohol, 15 parts of tetrapropoxy zirconium, 20 parts of ethylenediamine methyl propionate The mixture was heated at 80 ° C and refluxed for 3 hours. After cooling, the product was obtained by mixing and stirring.
  • a green environmentally friendly mold-proof coating comprising the following components by weight, 80 parts of benzoyl peroxide, 30 parts of isopropyl acrylate, 40 parts of titanium tetraisopropoxide, 20 parts of phenol, 60 parts of talc, and poly 60 parts of isobutyl ester, 40 parts of aluminum hydroxide, 24 parts of phosphate triester, 100 parts of isopropanol, 20 parts of polyvinyl alcohol, 20 parts of tetrapropoxy zirconium, 30 parts of ethylenediamine methyl propionate The mixture was heated at 80 ° C and refluxed for 4 hours. After cooling, the product was obtained by mixing and stirring.

Abstract

An environment-friendly mildew-proof coating adhesive, comprising the following components in parts by weight: 40-80 parts of benzoyl peroxide, 10-30 parts of isopropyl acrylate, 20-40 parts of titanium tetraisopropoxide, 10-20 parts of phenol, 40-60 parts of talc powder, 40-60 parts of polyisobutyl ester, 20-40 parts of aluminum hydroxide, 12-24 parts of phosphotriester, 80-100 parts of isopropyl alcohol, 10-20 parts of polyvinyl alcohol, 10-20 parts of zirconium tetrapropoxide, and 10-30 parts of ethylenediamine methyl propionate. The environment-friendly mildew-proof coating adhesive is easy to prepare, is prepared by using nontoxic raw materials, has good effects in use, is environment-friendly, and can be applied to the surface of a metal or plastic product to prevent the metal surface from mildewing, thereby enhancing the storage stability of the product.

Description

一种绿色环保防霉涂胶Green environmental protection mildew coating 技术领域Technical field
本发明涉及一种化学用品的技术领域，具体涉及一种绿色环保防霉涂胶。The invention relates to the technical field of chemical products, in particular to a green environmental protection mildew-proof coating.
背景技术Background technique
涂胶在生产和生活中的作用非常大，广泛应用与各个领域，涂胶形成的涂膜可对物体起到装饰、保护和黏贴的作用，在物体与物体之间的固接有很大的作用，目前市面上的大部分涂胶虽然制作简单、售价便宜但同时功能比较单一，只能简单的作为装饰之用，且长久使用后会产生脱胶的情况，而在一些特殊的作业环境中，简单的涂胶的并不能满足人们的所需。Gluing has a very large role in production and life. It is widely used in various fields. The coating film formed by gluing can play the role of decoration, protection and adhesion to objects, and the adhesion between objects and objects is very large. The role of most of the current coatings on the market, although simple to manufacture, cheap, but at the same time the function is relatively simple, can only be used as a decoration, and will be degummed after long-term use, and in some special working environment In the simple application of glue, it does not meet people's needs.
发明内容Summary of the invention
本发明的目的提供一种绿色环保防霉涂胶，解决上述现有技术问题中的一个或者多个。It is an object of the present invention to provide a green environmentally friendly mold-resistant coating that addresses one or more of the above prior art problems.
根据本发明的一种绿色环保防霉涂胶，包括如下重量份的组分，A green environmentally-friendly mold-proof coating according to the present invention, comprising the following components by weight,
氧化苯甲酰40～80份，丙烯酸异丙酯10～30份，四异丙氧基钛20～40份，苯酚10～20份，滑石粉40～60份，聚异丁酯40～60份，氢氧化铝20～40份，磷酸三酯12～24份，异丙醇80～100份，聚乙烯醇10～20份，四丙氧基锆10～20份，乙二胺甲基丙酸酯10～30份。40 to 80 parts of benzoyl peroxide, 10 to 30 parts of isopropyl acrylate, 20 to 40 parts of titanium tetraisopropoxide, 10 to 20 parts of phenol, 40 to 60 parts of talc, and 40 to 60 parts of polyisobutylate. 20-40 parts of aluminum hydroxide, 12-24 parts of phosphate triester, 80-100 parts of isopropyl alcohol, 10-20 parts of polyvinyl alcohol, 10-20 parts of tetrapropoxy zirconium, ethylenediamine methylpropionic acid The ester is 10 to 30 parts.
本发明提供的一种绿色环保防霉涂胶，制作简单，采用的生产原料选择无毒性的，涂胶的使用效果好，环保，涂抹于金属或塑料制品表面，防止金属表面霉变，能增强产品的贮存稳定性。The invention provides a green environmental protection mildew-proof coating glue, which is simple to manufacture, adopts non-toxic production raw materials, has good use effect of coating glue, is environmentally friendly, is applied to the surface of metal or plastic products, prevents mildew on metal surface, can enhance Storage stability of the product.
具体实施方式detailed description
实施例1Example 1
一种绿色环保防霉涂胶，包括如下重量份的组分，氧化苯甲酰40份，丙烯酸异丙酯10份，四异丙氧基钛20份，苯酚10份，滑石粉40份，聚异 丁酯40份，氢氧化铝20份，磷酸三酯12份，异丙醇80份，聚乙烯醇10份，四丙氧基锆10份，乙二胺甲基丙酸酯10份混合后加热只80℃并回流2小时，降温后混合搅拌即得产品。A green environmentally-friendly mold-proof coating comprising the following components by weight, 40 parts of benzoyl peroxide, 10 parts of isopropyl acrylate, 20 parts of titanium tetraisopropoxide, 10 parts of phenol, 40 parts of talc, and poly different 40 parts of butyl ester, 20 parts of aluminum hydroxide, 12 parts of phosphate triester, 80 parts of isopropanol, 10 parts of polyvinyl alcohol, 10 parts of zirconium tetrapropoxide, and 10 parts of ethylenediamine methyl propionate are heated and mixed. Only 80 ° C and reflux for 2 hours, after cooling, mixing and stirring to obtain the product.
实施例2Example 2
一种绿色环保防霉涂胶，包括如下重量份的组分，氧化苯甲酰60份，丙烯酸异丙酯20份，四异丙氧基钛30份，苯酚15份，滑石粉50份，聚异丁酯50份，氢氧化铝30份，磷酸三酯18份，异丙醇90份，聚乙烯醇15份，四丙氧基锆15份，乙二胺甲基丙酸酯20份混合后加热只80℃并回流3小时，降温后混合搅拌即得产品。A green environmentally friendly mold-proof coating comprising the following components by weight, 60 parts of benzoyl peroxide, 20 parts of isopropyl acrylate, 30 parts of titanium tetraisopropoxide, 15 parts of phenol, 50 parts of talc, and poly 50 parts of isobutyl ester, 30 parts of aluminum hydroxide, 18 parts of phosphate triester, 90 parts of isopropanol, 15 parts of polyvinyl alcohol, 15 parts of tetrapropoxy zirconium, 20 parts of ethylenediamine methyl propionate The mixture was heated at 80 ° C and refluxed for 3 hours. After cooling, the product was obtained by mixing and stirring.
实施例3Example 3
一种绿色环保防霉涂胶，包括如下重量份的组分，氧化苯甲酰80份，丙烯酸异丙酯30份，四异丙氧基钛40份，苯酚20份，滑石粉60份，聚异丁酯60份，氢氧化铝40份，磷酸三酯24份，异丙醇100份，聚乙烯醇20份，四丙氧基锆20份，乙二胺甲基丙酸酯30份混合后加热只80℃并回流4小时，降温后混合搅拌即得产品。A green environmentally friendly mold-proof coating comprising the following components by weight, 80 parts of benzoyl peroxide, 30 parts of isopropyl acrylate, 40 parts of titanium tetraisopropoxide, 20 parts of phenol, 60 parts of talc, and poly 60 parts of isobutyl ester, 40 parts of aluminum hydroxide, 24 parts of phosphate triester, 100 parts of isopropanol, 20 parts of polyvinyl alcohol, 20 parts of tetrapropoxy zirconium, 30 parts of ethylenediamine methyl propionate The mixture was heated at 80 ° C and refluxed for 4 hours. After cooling, the product was obtained by mixing and stirring.
以上所述仅是本发明的优选方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。 The above is only a preferred mode of the present invention, and it should be noted that various similar modifications and improvements can be made by those skilled in the art without departing from the inventive concept. Within the scope of protection of the present invention.

Claims (1)

  1. 一种绿色环保防霉涂胶，其特征在于：包括如下重量份的组分，A green environmentally-friendly mold-proof coating, characterized in that it comprises the following components by weight,
    过氧化苯甲酰40～80份，丙烯酸异丙酯10～30份，四异丙氧基钛20～40份，苯酚10～20份，滑石粉40～60份，聚异丁酯40～60份，氢氧化铝20～40份，磷酸三酯12～24份，异丙醇80～100份，聚乙烯醇10～20份，四丙氧基锆10～20份，乙二胺甲基丙酸酯10～30份。 40 to 80 parts of benzoyl peroxide, 10 to 30 parts of isopropyl acrylate, 20 to 40 parts of titanium tetraisopropoxide, 10 to 20 parts of phenol, 40 to 60 parts of talc, and 40 to 60 parts of polyisobutylate. Parts, 20-40 parts of aluminum hydroxide, 12-24 parts of phosphate triester, 80-100 parts of isopropyl alcohol, 10-20 parts of polyvinyl alcohol, 10-20 parts of tetrapropoxy zirconium, ethylenediamine methyl propyl 10 to 30 parts of the acid ester.
PCT/CN2016/094013 2016-05-21 2016-08-08 Environment-friendly mildew-proof coating adhesive WO2017201883A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610341750.4A CN106009815A (en) 2016-05-21 2016-05-21 Environment-friendly mildew-proof rubber coating
CN201610341750.4 2016-05-21

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WO2017201883A1 true WO2017201883A1 (en) 2017-11-30

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* Cited by examiner, † Cited by third party
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CN110205038A (en) * 2019-06-19 2019-09-06 浙江安吉朝辉新材料有限公司 A kind of environment-friendly type aqueous gluing preparation process

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050133069A1 (en) * 2003-12-13 2005-06-23 Man Roland Druckmaschinen Ag Gumming medium
US20100028582A1 (en) * 2006-05-19 2010-02-04 Basf Coatings Ag Powder coating materials with high-functionality, highly or hyper-branched polycarbonates
CN102391741A (en) * 2011-08-01 2012-03-28 中山市丽莎涂料有限公司 Ammonia-removing and formaldehyde-removing paint
CN103374275A (en) * 2012-04-23 2013-10-30 周家欣 Waterproof and heat-resistant curtain coating glue
CN103602176A (en) * 2013-10-21 2014-02-26 青岛海伴诚远塑业有限公司 Novel building interior wall waterproof coating
CN104530794A (en) * 2014-12-23 2015-04-22 姜云华 Non-intumescent latex fireproof paint
CN104559369A (en) * 2014-12-23 2015-04-29 姜云华 Mildew-resistant paint and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050133069A1 (en) * 2003-12-13 2005-06-23 Man Roland Druckmaschinen Ag Gumming medium
US20100028582A1 (en) * 2006-05-19 2010-02-04 Basf Coatings Ag Powder coating materials with high-functionality, highly or hyper-branched polycarbonates
CN102391741A (en) * 2011-08-01 2012-03-28 中山市丽莎涂料有限公司 Ammonia-removing and formaldehyde-removing paint
CN103374275A (en) * 2012-04-23 2013-10-30 周家欣 Waterproof and heat-resistant curtain coating glue
CN103602176A (en) * 2013-10-21 2014-02-26 青岛海伴诚远塑业有限公司 Novel building interior wall waterproof coating
CN104530794A (en) * 2014-12-23 2015-04-22 姜云华 Non-intumescent latex fireproof paint
CN104559369A (en) * 2014-12-23 2015-04-29 姜云华 Mildew-resistant paint and preparation method thereof

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