WO2017201867A1 - Coating adhesive for plastic products - Google Patents

Coating adhesive for plastic products Download PDF

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Publication number
WO2017201867A1
WO2017201867A1 PCT/CN2016/092308 CN2016092308W WO2017201867A1 WO 2017201867 A1 WO2017201867 A1 WO 2017201867A1 CN 2016092308 W CN2016092308 W CN 2016092308W WO 2017201867 A1 WO2017201867 A1 WO 2017201867A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
plastic products
coating adhesive
butanediol
methoxyphenol
Prior art date
Application number
PCT/CN2016/092308
Other languages
French (fr)
Chinese (zh)
Inventor
范红梅
Original Assignee
范红梅
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 范红梅 filed Critical 范红梅
Publication of WO2017201867A1 publication Critical patent/WO2017201867A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

Definitions

  • the invention relates to the technical field of chemical products, in particular to the coating of plastic products.
  • Gluing has a very large role in production and life. It is widely used in various fields.
  • the coating film formed by gluing can play a role in decoration, protection and labeling.
  • Most of the coatings on the market are simple to make and sell. It is cheap but has certain toxic and side effects. As a household, it will cause certain harm to the human body.
  • the glue application function is relatively simple, and the scope of application is not wide. It cannot be used in many fields, and its limitations are very large.
  • the plastic product is coated with glue, 40-60 parts of methacrylic acid, 80-120 parts of methyl methacrylate, 40-60 parts of lauryl methacrylate, 40-60 parts of polyester, and diced. 20-40 parts of alcohol acrylate, 40-60 parts of trimethylolpropane, 10-30 parts of butanediol, 20-40 parts of methoxyphenol, 8-12 parts of acrylamide, 10-20 parts of styrene, ethanol 12 to 24 parts, and 10 to 18 parts of xylene.
  • glue 40-60 parts of methacrylic acid, 80-120 parts of methyl methacrylate, 40-60 parts of lauryl methacrylate, 40-60 parts of polyester, and diced. 20-40 parts of alcohol acrylate, 40-60 parts of trimethylolpropane, 10-30 parts of butanediol, 20-40 parts of methoxyphenol, 8-12 parts of acrylamide, 10-20 parts of styrene, ethanol 12 to 24 parts, and 10 to 18 parts of x
  • the plastic product provided by the invention is simple in coating, the raw material used is non-toxic, the use effect is good, and the environment is environmentally friendly, and the surface coating of the leather can form a strong bright coating film.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

A coating adhesive for plastic products, comprising: 40-60 parts of methacrylic acid, 80-120 parts of methyl methacrylate, 40-60 parts of lauryl methacrylate, 40-60 parts of polyester, 20-40 parts of butylene glycol acrylate, 40-60 parts of trimethylolpropane, 10-30 parts of butylene glycol, 20-40 parts of methoxyphenol, 8-12 parts of acrylamide, 10-20 parts of styrene, 12-24 parts of ethanol, and 10-18 parts of xylene. The coating adhesive for plastic products is easy to manufacture, uses non-toxic raw materials for production, and has a good application effect, is environmentally friendly, and can form a strong and bright film when applied to a leather surface.

Description

塑料制品用涂胶Glue for plastic products 技术领域Technical field
本发明涉及一种化学用品的技术领域，具体涉及塑料制品用涂胶。The invention relates to the technical field of chemical products, in particular to the coating of plastic products.
背景技术Background technique
涂胶在生产和生活中的作用非常大，广泛应用与各个领域，涂胶形成的涂膜可对物体起到装饰、保护和标致作用，目前市面上的大部分涂胶虽然制作简单、售价便宜但同时带有一定的毒副作用，作为家用的话会对人体产生一定危害，且涂胶功能比较单一，适用范围不广，不能用于很多领域，局限性很大。Gluing has a very large role in production and life. It is widely used in various fields. The coating film formed by gluing can play a role in decoration, protection and labeling. Most of the coatings on the market are simple to make and sell. It is cheap but has certain toxic and side effects. As a household, it will cause certain harm to the human body. The glue application function is relatively simple, and the scope of application is not wide. It cannot be used in many fields, and its limitations are very large.
发明内容Summary of the invention
本发明的目的提供塑料制品用涂胶，解决上述现有技术问题中的一个或者多个。It is an object of the present invention to provide a glue for plastic articles that addresses one or more of the above prior art problems.
根据本发明的一个方面，塑料制品用涂胶，甲基丙烯酸40～60份，甲基丙烯酸甲酯80～120份，甲基丙烯酸月桂酯40～60份，聚酯40～60份，丁二醇丙烯酸酯20～40份，三羟甲基丙烷40～60份，丁二醇10～30份，甲氧基苯酚20～40份，丙烯酰胺8～12份，苯乙烯10～20份，乙醇12～24份，二甲苯10～18份。According to one aspect of the invention, the plastic product is coated with glue, 40-60 parts of methacrylic acid, 80-120 parts of methyl methacrylate, 40-60 parts of lauryl methacrylate, 40-60 parts of polyester, and diced. 20-40 parts of alcohol acrylate, 40-60 parts of trimethylolpropane, 10-30 parts of butanediol, 20-40 parts of methoxyphenol, 8-12 parts of acrylamide, 10-20 parts of styrene, ethanol 12 to 24 parts, and 10 to 18 parts of xylene.
本发明提供的塑料制品用涂胶，制作简单，采用的生产原料选择无毒性的，的使用效果好，环保，作用于皮革表面涂饰可形成坚固的光亮涂膜。The plastic product provided by the invention is simple in coating, the raw material used is non-toxic, the use effect is good, and the environment is environmentally friendly, and the surface coating of the leather can form a strong bright coating film.
具体实施方式detailed description
实施例1Example 1
将甲基丙烯酸40份，甲基丙烯酸甲酯80份，甲基丙烯酸月桂酯40份，聚酯40份，丁二醇丙烯酸酯20份，三羟甲基丙烷40份，丁二醇10份，甲氧基苯酚20份，丙烯酰胺8份，苯乙烯10份，乙醇12份，二甲苯10～18 份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。40 parts of methacrylic acid, 80 parts of methyl methacrylate, 40 parts of lauryl methacrylate, 40 parts of polyester, 20 parts of butanediol acrylate, 40 parts of trimethylolpropane and 10 parts of butanediol. 20 parts of methoxyphenol, 8 parts of acrylamide, 10 parts of styrene, 12 parts of ethanol, 10 to 18 of xylene The mixture was placed in a reactor, continuously stirred, heated to 65 ° C after completion of the mixture, and passed through a reaction at a speed of 16 m/min under a UV lamp of 200 W/cm twice to obtain a product.
实施例2Example 2
将甲基丙烯酸50份，甲基丙烯酸甲酯100份，甲基丙烯酸月桂酯50份，聚酯50份，丁二醇丙烯酸酯30份，三羟甲基丙烷50份，丁二醇20份，甲氧基苯酚30份，丙烯酰胺10份，苯乙烯15份，乙醇18份，二甲苯14份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。50 parts of methacrylic acid, 100 parts of methyl methacrylate, 50 parts of lauryl methacrylate, 50 parts of polyester, 30 parts of butanediol acrylate, 50 parts of trimethylolpropane, 20 parts of butanediol, 30 parts of methoxyphenol, 10 parts of acrylamide, 15 parts of styrene, 18 parts of ethanol, 14 parts of xylene were placed in the reactor, stirring was continued, and after mixing, it was heated to 65 ° C at a speed of 16 m/min at 200 W. After passing the reaction twice under the UV lamp of /cm, the product is obtained.
实施例3Example 3
将甲基丙烯酸60份，甲基丙烯酸甲酯120份，甲基丙烯酸月桂酯60份，聚酯60份，丁二醇丙烯酸酯40份，三羟甲基丙烷60份，丁二醇30份，甲氧基苯酚40份，丙烯酰12份，苯乙烯20份，乙醇24份，二甲苯18份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。60 parts of methacrylic acid, 120 parts of methyl methacrylate, 60 parts of lauryl methacrylate, 60 parts of polyester, 40 parts of butanediol acrylate, 60 parts of trimethylolpropane, 30 parts of butanediol, 40 parts of methoxyphenol, 12 parts of acryloyl group, 20 parts of styrene, 24 parts of ethanol, 18 parts of xylene were placed in the reactor, stirring was continued, and after mixing, it was heated to 65 ° C at a speed of 16 m/min at 200 W. After passing the reaction twice under the UV lamp of /cm, the product is obtained.
以上所述仅是本发明的优选方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。 The above is only a preferred mode of the present invention, and it should be noted that various similar modifications and improvements can be made by those skilled in the art without departing from the inventive concept. Within the scope of protection of the present invention.

Claims (1)

  1. 塑料制品用涂胶，其特征在于：包括如下重量份的组分，甲基丙烯酸40～60份，甲基丙烯酸甲酯80～120份，甲基丙烯酸月桂酯40～60份，聚酯40～60份，丁二醇丙烯酸酯20～40份，三羟甲基丙烷40～60份，丁二醇10～30份，甲氧基苯酚20～40份，丙烯酰胺8～12份，苯乙烯10～20份，乙醇12～24份，二甲苯10～18份。 Gluing for plastic products, comprising: the following components by weight, 40-60 parts of methacrylic acid, 80-120 parts of methyl methacrylate, 40-60 parts of lauryl methacrylate, polyester 40~ 60 parts, 20-40 parts of butanediol acrylate, 40-60 parts of trimethylolpropane, 10-30 parts of butanediol, 20-40 parts of methoxyphenol, 8-12 parts of acrylamide, styrene 10 ～20 parts, 12 to 24 parts of ethanol, and 10 to 18 parts of xylene.
PCT/CN2016/092308 2016-05-21 2016-07-29 Coating adhesive for plastic products WO2017201867A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610343872.7A CN105754392A (en) 2016-05-21 2016-05-21 Glue for plastic products
CN201610343872.7 2016-05-21

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WO2017201867A1 true WO2017201867A1 (en) 2017-11-30

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WO (1) WO2017201867A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105754392A (en) * 2016-05-21 2016-07-13 范红梅 Glue for plastic products

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130092075A (en) * 2012-02-10 2013-08-20 재단법인 포항산업과학연구원 Acryl resin, preparing method thereof and coating composition comprising the same
CN105086849A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Antistatic environment-friendly glue
CN105086847A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Environment-friendly nontoxic glue
CN105754393A (en) * 2016-05-21 2016-07-13 黄金生 Waterproof coating adhesive
CN105754392A (en) * 2016-05-21 2016-07-13 范红梅 Glue for plastic products

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559378A (en) * 2014-12-23 2015-04-29 姜云华 Water-based paint for leather

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130092075A (en) * 2012-02-10 2013-08-20 재단법인 포항산업과학연구원 Acryl resin, preparing method thereof and coating composition comprising the same
CN105086849A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Antistatic environment-friendly glue
CN105086847A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Environment-friendly nontoxic glue
CN105754393A (en) * 2016-05-21 2016-07-13 黄金生 Waterproof coating adhesive
CN105754392A (en) * 2016-05-21 2016-07-13 范红梅 Glue for plastic products

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