WO2017201882A1 - Environment-friendly mildew-proof coating adhesive - Google Patents

Environment-friendly mildew-proof coating adhesive Download PDF

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Publication number
WO2017201882A1
WO2017201882A1 PCT/CN2016/094005 CN2016094005W WO2017201882A1 WO 2017201882 A1 WO2017201882 A1 WO 2017201882A1 CN 2016094005 W CN2016094005 W CN 2016094005W WO 2017201882 A1 WO2017201882 A1 WO 2017201882A1
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WO
WIPO (PCT)
Prior art keywords
parts
environment
proof coating
coating adhesive
friendly
Prior art date
Application number
PCT/CN2016/094005
Other languages
French (fr)
Chinese (zh)
Inventor
陈金才
Original Assignee
陈金才
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 陈金才 filed Critical 陈金才
Publication of WO2017201882A1 publication Critical patent/WO2017201882A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters

Definitions

  • the invention relates to the technical field of chemical products, in particular to an environmentally friendly mildew-proof coating.
  • Gluing has a very large role in production and life. It is widely used in various fields.
  • the coating film formed by gluing can play the role of decoration, protection and adhesion to objects, and the adhesion between objects and objects is very large.
  • the role of most of the current coatings on the market although simple to manufacture, cheap, but at the same time the function is relatively simple, can only be used as a decoration, and will be degummed after long-term use, and in some special working environment In the simple application of glue, it does not meet people's needs.
  • An environmentally friendly mold-proof coating according to the present invention comprising the following components by weight,
  • the invention provides an environmentally-friendly mildew-proof glue, which is simple to manufacture, adopts non-toxic production raw materials, has good use effect of coating, is environmentally friendly, is applied to the surface of metal or plastic products, prevents mildew on metal surface, and can enhance products. Storage stability.
  • An environmentally friendly mold-proof coating comprising the following components by weight, 20 parts of titanium tetraisopropoxide, 10 parts of phenol, 40 parts of talc, 40 parts of polyisobutyl ester, 20 parts of aluminum hydroxide, and a phosphate triester. 12 copies, 80 parts of isopropyl alcohol, 10 parts of polyvinyl alcohol, 10 parts of zirconium tetrapropoxide, and 10 parts of ethylenediamine methyl propionate were mixed and heated at 80 ° C for 2 hours. After cooling, the product was obtained by mixing and stirring.
  • An environmentally friendly mold-proof coating comprising the following components by weight, 30 parts of titanium tetraisopropoxide, 15 parts of phenol, 50 parts of talc, 50 parts of polyisobutyl ester, 30 parts of aluminum hydroxide, and a phosphate triester. 18 parts, 90 parts of isopropanol, 15 parts of polyvinyl alcohol, 15 parts of tetrapropoxy zirconium, 20 parts of ethylenediamine methyl propionate, mixed and heated at 80 ° C for 3 hours, cooled and mixed. product.
  • An environmentally friendly mold-proof coating comprising the following components by weight, 40 parts of titanium tetraisopropoxide, 20 parts of phenol, 60 parts of talc, 60 parts of polyisobutyl ester, 40 parts of aluminum hydroxide, and a phosphate triester. 24 parts, 100 parts of isopropanol, 20 parts of polyvinyl alcohol, 20 parts of tetrapropoxy zirconium, 30 parts of ethylenediamine methyl propionate, mixed and heated at 80 ° C for 4 hours, cooled and mixed. product.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Disclosed is an environment-friendly mildew-proof coating adhesive, comprising the following components in parts by weight: 20-40 parts of titanium tetraisopropoxide, 10-20 parts of phenol, 40-60 parts of talcum powder, 40-60 parts of polyisobutyl ester, 20-40 parts of aluminum hydroxide, 12-24 parts of phosphotriester, 80-100 parts of isopropyl alcohol, 10-20 parts of polyvinyl alcohol, 10-20 parts of zirconium tetrapropoxide, and 10-30 parts of ethylenediamine methyl propionate. The environment-friendly mildew-proof coating adhesive provided by the present invention is easy to prepare and environment-friendly, uses non-toxic raw materials for production, has a good utilization effect, and can be coated on the surface of a metal or plastic product to prevent mildewing of the metal surface and enhance the storage stability of the product.

Description

一种环保防霉涂胶An environmentally friendly mildew resistant glue 技术领域Technical field
本发明涉及一种化学用品的技术领域，具体涉及一种环保防霉涂胶。The invention relates to the technical field of chemical products, in particular to an environmentally friendly mildew-proof coating.
背景技术Background technique
涂胶在生产和生活中的作用非常大，广泛应用与各个领域，涂胶形成的涂膜可对物体起到装饰、保护和黏贴的作用，在物体与物体之间的固接有很大的作用，目前市面上的大部分涂胶虽然制作简单、售价便宜但同时功能比较单一，只能简单的作为装饰之用，且长久使用后会产生脱胶的情况，而在一些特殊的作业环境中，简单的涂胶的并不能满足人们的所需。Gluing has a very large role in production and life. It is widely used in various fields. The coating film formed by gluing can play the role of decoration, protection and adhesion to objects, and the adhesion between objects and objects is very large. The role of most of the current coatings on the market, although simple to manufacture, cheap, but at the same time the function is relatively simple, can only be used as a decoration, and will be degummed after long-term use, and in some special working environment In the simple application of glue, it does not meet people's needs.
发明内容Summary of the invention
本发明的目的提供一种环保防霉涂胶，解决上述现有技术问题中的一个或者多个。It is an object of the present invention to provide an environmentally friendly mildew resistant glue that addresses one or more of the above prior art problems.
根据本发明的一种环保防霉涂胶，包括如下重量份的组分，An environmentally friendly mold-proof coating according to the present invention, comprising the following components by weight,
四异丙氧基钛20～40份，苯酚10～20份，滑石粉40～60份，聚异丁酯40～60份，氢氧化铝20～40份，磷酸三酯12～24份，异丙醇80～100份，聚乙烯醇10～20份，四丙氧基锆10～20份，乙二胺甲基丙酸酯10～30份。20 to 40 parts of titanium tetraisopropoxide, 10 to 20 parts of phenol, 40 to 60 parts of talc, 40 to 60 parts of polyisobutyl ester, 20 to 40 parts of aluminum hydroxide, and 12 to 24 parts of phosphate triester. 80 to 100 parts of propanol, 10 to 20 parts of polyvinyl alcohol, 10 to 20 parts of tetrapropoxy zirconium, and 10 to 30 parts of ethylenediamine methylpropionate.
本发明提供的一种环保防霉涂胶，制作简单，采用的生产原料选择无毒性的，涂胶的使用效果好，环保，涂抹于金属或塑料制品表面，防止金属表面霉变，能增强产品的贮存稳定性。The invention provides an environmentally-friendly mildew-proof glue, which is simple to manufacture, adopts non-toxic production raw materials, has good use effect of coating, is environmentally friendly, is applied to the surface of metal or plastic products, prevents mildew on metal surface, and can enhance products. Storage stability.
具体实施方式detailed description
实施例1Example 1
一种环保防霉涂胶，包括如下重量份的组分，四异丙氧基钛20份，苯酚10份，滑石粉40份，聚异丁酯40份，氢氧化铝20份，磷酸三酯12份， 异丙醇80份，聚乙烯醇10份，四丙氧基锆10份，乙二胺甲基丙酸酯10份混合后加热只80℃并回流2小时，降温后混合搅拌即得产品。An environmentally friendly mold-proof coating comprising the following components by weight, 20 parts of titanium tetraisopropoxide, 10 parts of phenol, 40 parts of talc, 40 parts of polyisobutyl ester, 20 parts of aluminum hydroxide, and a phosphate triester. 12 copies, 80 parts of isopropyl alcohol, 10 parts of polyvinyl alcohol, 10 parts of zirconium tetrapropoxide, and 10 parts of ethylenediamine methyl propionate were mixed and heated at 80 ° C for 2 hours. After cooling, the product was obtained by mixing and stirring.
实施例2Example 2
一种环保防霉涂胶，包括如下重量份的组分，四异丙氧基钛30份，苯酚15份，滑石粉50份，聚异丁酯50份，氢氧化铝30份，磷酸三酯18份，异丙醇90份，聚乙烯醇15份，四丙氧基锆15份，乙二胺甲基丙酸酯20份混合后加热只80℃并回流3小时，降温后混合搅拌即得产品。An environmentally friendly mold-proof coating comprising the following components by weight, 30 parts of titanium tetraisopropoxide, 15 parts of phenol, 50 parts of talc, 50 parts of polyisobutyl ester, 30 parts of aluminum hydroxide, and a phosphate triester. 18 parts, 90 parts of isopropanol, 15 parts of polyvinyl alcohol, 15 parts of tetrapropoxy zirconium, 20 parts of ethylenediamine methyl propionate, mixed and heated at 80 ° C for 3 hours, cooled and mixed. product.
实施例3Example 3
一种环保防霉涂胶，包括如下重量份的组分，四异丙氧基钛40份，苯酚20份，滑石粉60份，聚异丁酯60份，氢氧化铝40份，磷酸三酯24份，异丙醇100份，聚乙烯醇20份，四丙氧基锆20份，乙二胺甲基丙酸酯30份混合后加热只80℃并回流4小时，降温后混合搅拌即得产品。An environmentally friendly mold-proof coating comprising the following components by weight, 40 parts of titanium tetraisopropoxide, 20 parts of phenol, 60 parts of talc, 60 parts of polyisobutyl ester, 40 parts of aluminum hydroxide, and a phosphate triester. 24 parts, 100 parts of isopropanol, 20 parts of polyvinyl alcohol, 20 parts of tetrapropoxy zirconium, 30 parts of ethylenediamine methyl propionate, mixed and heated at 80 ° C for 4 hours, cooled and mixed. product.
以上所述仅是本发明的优选方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。 The above is only a preferred mode of the present invention, and it should be noted that various similar modifications and improvements can be made by those skilled in the art without departing from the inventive concept. Within the scope of protection of the present invention.

Claims (1)

  1. 一种环保防霉涂胶，其特征在于：包括如下重量份的组分，An environmentally friendly mold-proof coating characterized by comprising the following components by weight,
    四异丙氧基钛20～40份，苯酚10～20份，滑石粉40～60份，聚异丁酯40～60份，氢氧化铝20～40份，磷酸三酯12～24份，异丙醇80～100份，聚乙烯醇10～20份，四丙氧基锆10～20份，乙二胺甲基丙酸酯10～30份。 20 to 40 parts of titanium tetraisopropoxide, 10 to 20 parts of phenol, 40 to 60 parts of talc, 40 to 60 parts of polyisobutyl ester, 20 to 40 parts of aluminum hydroxide, and 12 to 24 parts of phosphate triester. 80 to 100 parts of propanol, 10 to 20 parts of polyvinyl alcohol, 10 to 20 parts of tetrapropoxy zirconium, and 10 to 30 parts of ethylenediamine methylpropionate.
PCT/CN2016/094005 2016-05-21 2016-08-08 Environment-friendly mildew-proof coating adhesive WO2017201882A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610341274.6 2016-05-21
CN201610341274.6A CN105950074A (en) 2016-05-21 2016-05-21 Environment-friendly mould-proof adhesive

Publications (1)

Publication Number Publication Date
WO2017201882A1 true WO2017201882A1 (en) 2017-11-30

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117447942A (en) * 2023-12-22 2024-01-26 汕头市炜星工艺实业有限公司 Modified polyvinyl alcohol mildew-proof adhesive, preparation method thereof and application thereof in paper product processing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108230A (en) * 1986-12-15 1988-06-29 上海无线电六厂 Electronic ceramic binder for film formation by flow and expansion
CN103865442A (en) * 2012-12-18 2014-06-18 青岛海芬海洋生物科技有限公司 Mouldproof and environmentally-friendly glass adhesive
CN104927678A (en) * 2015-07-09 2015-09-23 常州百富电子有限公司 Environment-friendly tackiness agent and preparation method thereof
CN104946140A (en) * 2015-07-09 2015-09-30 常州汇森电子有限公司 Anti-mould corrosion-resistant flame-retardant polyethylene adhesive and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559369A (en) * 2014-12-23 2015-04-29 姜云华 Mildew-resistant paint and preparation method thereof
CN105086848A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Mould-proof glue
CN105086846A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Waterproof glue

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108230A (en) * 1986-12-15 1988-06-29 上海无线电六厂 Electronic ceramic binder for film formation by flow and expansion
CN103865442A (en) * 2012-12-18 2014-06-18 青岛海芬海洋生物科技有限公司 Mouldproof and environmentally-friendly glass adhesive
CN104927678A (en) * 2015-07-09 2015-09-23 常州百富电子有限公司 Environment-friendly tackiness agent and preparation method thereof
CN104946140A (en) * 2015-07-09 2015-09-30 常州汇森电子有限公司 Anti-mould corrosion-resistant flame-retardant polyethylene adhesive and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117447942A (en) * 2023-12-22 2024-01-26 汕头市炜星工艺实业有限公司 Modified polyvinyl alcohol mildew-proof adhesive, preparation method thereof and application thereof in paper product processing
CN117447942B (en) * 2023-12-22 2024-03-26 汕头市炜星工艺实业有限公司 Modified polyvinyl alcohol mildew-proof adhesive, preparation method thereof and application thereof in paper product processing

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