CN103865442A - Mouldproof and environmentally-friendly glass adhesive - Google Patents
Mouldproof and environmentally-friendly glass adhesive Download PDFInfo
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- CN103865442A CN103865442A CN201210550581.7A CN201210550581A CN103865442A CN 103865442 A CN103865442 A CN 103865442A CN 201210550581 A CN201210550581 A CN 201210550581A CN 103865442 A CN103865442 A CN 103865442A
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- glass adhesive
- environmentally
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- mouldproof
- friendly
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Abstract
The invention discloses a mouldproof and environmentally-friendly glass adhesive and a preparation method thereof, and the formula is selected as follows: the mouldproof and environmentally-friendly glass adhesive comprises, by weight, 70-72 parts of polyacrylate emulsion, 10 parts of a marine biological sterilization agent, 0.2-5 parts of a coupling agent, 17 parts of silica sol and 0.1-1 part of ammonia water. According to the invention, the sterilization agent is creatively infused in the glass adhesive, so that the glass adhesive has long-acting antibacterial properties, and puts an end to blacking or discoloration phenomena caused by moulding, VOC (volatile organic compound) emission is zero, and the glass adhesive is in accordance with the green and environmentally-friendly requirements, has extremely-high adhesion and waterproof function, and can replace a traditional glass adhesive.
Description
Technical field
The present invention relates to glass cement, relate in particular to a kind of mildew-resistant containing degerming composition, environmental protection glass cement and preparation method thereof.
Background technology
Glass cement is requisite articles for use in decorations, and chemical name is: CALCIUM ACRYLATE emulsion adhesive.Be usually used in the gluing of kitchen, toilet article, still, glass cement in use for some time, tend to blackening or variable color, this is due to kitchen, environment of toilet humidity, easily grows mould, after going mouldy, there is the place of glass cement will turn black or variable color, affect attractive in appearance.At present, common glass cement does not have degerming, antipathogenic composition.
Chinese patent: 200710086432.9, announce a kind of " environment-friendly universal glass glue ", the present invention improves and forms on this patent basis.
Summary of the invention
Main points of the present invention are to select suitable degerming antibacterial components, a kind of novel mildew-resistant that contains degerming composition that forms with other composition rational mixtures, environmental protection glass cement and preparation method thereof.
The present invention develops on Chinese invention patent CN200810083601 " environment-friendly universal glass glue " basis.
The formula following (component and weight percent % thereof) that the present invention selects,
Polyacrylic acid fat liquor 70-72, marine organisms degerming agent 10, coupling agent 0.2-5, silicon sol 17, ammoniacal liquor 0.1-1,
The described degerming agent of formula is cm-chitosan 6%, Sargassum polysaccharides 1.5, cecropin 8.0 and pure water 84.5% is composite forms.
The described coupling agent of formula is: 3-glycidoxypropyltrime,hoxysilane
The preparation method of " environment-friendly universal glass glue " of the present invention comprises the following steps:
One, the preparation of degerming agent
Preparation method is as follows:
(1) required pure water is heated to 30-35 degree Celsius.
(2) press proportioning by described component cm-chitosan 6%, Sargassum polysaccharides 1.5%, cecropin 8.2, adds in the above-mentioned aqueous solution and stirs 15 minutes and get final product.Control temperature and be no more than 35 degrees Celsius;
It is the cecropin described in CN101104637B that described cecropin can adopt notification number, can certainly adopt other cecropin.
Two, weigh
By formula rate, polyacrylic acid fat liquor, coupling agent (3-glycidoxypropyltrime,hoxysilane), silicon sol and degerming agent are accurately weighed.
Three, stir and first polyacrylic acid fat liquor is put in stirring tank, in the situation that stirring, add successively degerming agent, coupling agent, silicon sol.Stirring velocity is controlled at 500 and turns-700 revs/min.
Four, adjust pH value, with ammoniacal liquor, pH value is adjusted into 8.
Five, de-bubble is filling after leaving standstill open bubble being pumped to latter standing 72 hours.
The effect that the present invention is useful is: creationary degerming agent is incorporated in glass cement, make glass cement have long-acting bacteriostasis property, can stop the blackout or the metachromatism that produce because going mouldy after use; VOC discharge is zero, meets the requirement of environmental protection; There are high bonding force and water-proof function, can substitute traditional glass cement.
embodiment: below in conjunction with embodiment, the present invention is described in further detail:
Be configured according to following table institute column data (weight percent %) and described step thereof:
Formula one:
Polyacrylic acid fat liquor 70
Degerming agent 10,
Coupling agent 3,
Silicon sol 17,
Ammoniacal liquor is appropriate
Formula two:
Polyacrylic acid fat liquor 71,
Degerming agent 10,
Coupling agent 2,
Silicon sol 17,
Ammoniacal liquor is appropriate
Formula three:
Polyacrylic acid fat liquor 72,
Degerming agent 10,
Coupling agent 1,
Silicon sol 17,
Ammoniacal liquor is appropriate
Check:
1, fungistatic effect prison detects:
According to Ministry of Health of the People's Republic of China " disinfection technology standard ", adopt neutralizing agent qualification test, test flora is Candida albicans, fungi, streptococcus aureus, substratum is husky fort nutrient agar, at 20 ℃--23 ℃ of repetition tests 3 times, act on respectively 2min, 5min, 10min, average bacteriostasis rate is respectively: 99.25%; 99.46%.
Claims (1)
1. mildew-resistant, an environmental protection glass cement, is characterized in that (component and weight percent % thereof): polyacrylic acid fat liquor 70-72, marine organisms degerming agent 10, coupling agent 0.2-5, silicon sol 17, ammoniacal liquor 0.1-1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210550581.7A CN103865442A (en) | 2012-12-18 | 2012-12-18 | Mouldproof and environmentally-friendly glass adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210550581.7A CN103865442A (en) | 2012-12-18 | 2012-12-18 | Mouldproof and environmentally-friendly glass adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103865442A true CN103865442A (en) | 2014-06-18 |
Family
ID=50904474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210550581.7A Pending CN103865442A (en) | 2012-12-18 | 2012-12-18 | Mouldproof and environmentally-friendly glass adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN103865442A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327773A (en) * | 2014-10-30 | 2015-02-04 | 哈尔滨幻石科技发展有限公司 | Glass sealant based on hylocereus undatus emulsion and preparation method thereof |
| CN104327770A (en) * | 2014-10-30 | 2015-02-04 | 哈尔滨幻石科技发展有限公司 | Aluminum alloy glue based on Hylocereus undatus fallen leaves and seed shells and preparation method of aluminum alloy glue |
| WO2017201882A1 (en) * | 2016-05-21 | 2017-11-30 | 陈金才 | Environment-friendly mildew-proof coating adhesive |
| CN108130031A (en) * | 2018-01-29 | 2018-06-08 | 佛山市三水永发洁具有限公司 | A kind of glass high intensity, high-temperature-resistant adhesive |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070458A (en) * | 2006-05-10 | 2007-11-14 | 许昌南 | Adhesive special for heat-insulation sound-absorbing heat-isolation fiber coating and preparing method |
| CN101525526A (en) * | 2007-03-09 | 2009-09-09 | 金朝绪 | Environment-friendly universal glass glue |
| CN102417775A (en) * | 2011-11-18 | 2012-04-18 | 肇庆千江高新材料科技有限公司 | Silicasol-acrylate emulsion compound primer |
| CN102511507A (en) * | 2011-12-16 | 2012-06-27 | 青岛海芬海洋生物科技有限公司 | Marine bios sterilization solution |
| CN102604586A (en) * | 2012-03-15 | 2012-07-25 | 威海成景有机硅科技有限公司 | Method for producing mildew-resistant silicone sealing adhesive of hollow glass |
-
2012
- 2012-12-18 CN CN201210550581.7A patent/CN103865442A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070458A (en) * | 2006-05-10 | 2007-11-14 | 许昌南 | Adhesive special for heat-insulation sound-absorbing heat-isolation fiber coating and preparing method |
| CN101525526A (en) * | 2007-03-09 | 2009-09-09 | 金朝绪 | Environment-friendly universal glass glue |
| CN102417775A (en) * | 2011-11-18 | 2012-04-18 | 肇庆千江高新材料科技有限公司 | Silicasol-acrylate emulsion compound primer |
| CN102511507A (en) * | 2011-12-16 | 2012-06-27 | 青岛海芬海洋生物科技有限公司 | Marine bios sterilization solution |
| CN102604586A (en) * | 2012-03-15 | 2012-07-25 | 威海成景有机硅科技有限公司 | Method for producing mildew-resistant silicone sealing adhesive of hollow glass |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327773A (en) * | 2014-10-30 | 2015-02-04 | 哈尔滨幻石科技发展有限公司 | Glass sealant based on hylocereus undatus emulsion and preparation method thereof |
| CN104327770A (en) * | 2014-10-30 | 2015-02-04 | 哈尔滨幻石科技发展有限公司 | Aluminum alloy glue based on Hylocereus undatus fallen leaves and seed shells and preparation method of aluminum alloy glue |
| CN104327770B (en) * | 2014-10-30 | 2016-09-21 | 青岛橡胶谷知识产权有限公司 | A kind of based on keel flower fallen leaves and the aluminium alloy glue of melon-seed hull and preparation method |
| CN104327773B (en) * | 2014-10-30 | 2016-09-21 | 王林云 | A kind of glass cement based on keel flower emulsion and preparation method |
| WO2017201882A1 (en) * | 2016-05-21 | 2017-11-30 | 陈金才 | Environment-friendly mildew-proof coating adhesive |
| CN108130031A (en) * | 2018-01-29 | 2018-06-08 | 佛山市三水永发洁具有限公司 | A kind of glass high intensity, high-temperature-resistant adhesive |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140618 |