CN105820774A - Environment-friendly binding agent for corrugated carton box - Google Patents
Environment-friendly binding agent for corrugated carton box Download PDFInfo
- Publication number
- CN105820774A CN105820774A CN201610290648.6A CN201610290648A CN105820774A CN 105820774 A CN105820774 A CN 105820774A CN 201610290648 A CN201610290648 A CN 201610290648A CN 105820774 A CN105820774 A CN 105820774A
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- China
- Prior art keywords
- parts
- binding agent
- potato starch
- raw material
- acid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides an environment-friendly binding agent for a corrugated carton box. The binding agent is prepared from, by weight, 25-30 parts of corn starch, 25-30 parts of potato starch, 10-15 parts of sweet potato starch, 15-20 parts of butadiene rubber, 15-20 parts of polyurethane rubber, 10-12 parts of sodium hydroxide, 20-25 parts of dibutyltin dilaurate, 5-7.5 parts of 8-hydroxyquinoline, 18.5-22 parts of linoleic acid, 50-60 parts of water and 18-26 parts of modified oxidizing agent. The binding agent is safe, environmentally friendly, free of toxic and side effects, good in flexibility, excellent in mechanical performance and resistant to high temperature and low temperature, does not stimulate the respiratory tract or the skin and has ideal shock resistance; the flowing property is improved by 10-20% compared with a common binding agent, mould breeding can be prevented, aging resistance is good, and the binding service life is prolonged by 45-50%. Moreover, the binding agent has a certain flame retardant property, and surface tension of the binding agent and surface tension of the corrugated carton box are larger.
Description
Technical field
The present invention relates to amylum adhesive technical field, be specifically related to a kind of corrugated case environment-friendly adhesive.
Background technology
Corrugated board makes corrugated case through cross cutting, impression, nail case or stick box.Corrugated case is a kind of
Most widely used packing articles, consumption is always first of various packing articles.Corrugated case is moulded including calcium.
Since over half a century, corrugated case gradually replaces with its superior serviceability and good processing characteristics
The transportation package holdses such as wooden case, become the main force of transportation and packing.It is except protecting commodity, being easy to storehouse
Outside storage, transport, also act as and beautify commodity, the effect of publicity commodity.Corrugated case belongs to environmental protection
Product, it is beneficial to environmental protection, is beneficial to load and unload transport.
Needing during corrugated case stick box to use binding agent, binding agent is to have sticking material, glues by it
The material that two kinds separate is linked together by performance.The kind of binding agent is a lot.Mostly use starch at present
Binding agent, but always there are some problems in amylum adhesive at present, drastically influence corrugated case stick box.
Summary of the invention
The technical problem to be solved is to provide a kind of safety and environmental protection, no side effects, no
Stimulate respiratory tract and skin, flexible, excellent in mechanical performance, high temperature resistant, cold-resistant, have preferably
Shock resistance, can mould proof grow, and ageing resistace is good, but also there is certain fire resistance
Corrugated case environment-friendly adhesive.
The technical problem to be solved realizes by the following technical solutions:
A kind of corrugated case environment-friendly adhesive, is made up of the raw material of following weight portion: corn starch 25-30
Part, potato starch 25-30 part, sweet potato starch 10-15 part, butadiene rubber 15-20 part, polyurethane rubber 15-20
Part, sodium hydroxide 10-12.5 part, dibutyl tin laurate 20-25 part, 8-hydroxyquinoline 5-7.5 part,
Linoleic acid 18.5-22 part, water 50-60 part, modified oxidized dose of 18-26 part；
It is made up of the raw material of following weight portion for described modified oxidized dose: potassium hyperchlorate 5-6 part, peroxidating ten
Two acyl 10-17 parts, the 5-tert-butyl group-1,3-M-phthalic acid 10-17 part, BOC anhydride 22.2-23.2 part, do not have
Gallate-based 1.5-2.5 part, tartaric acid 1.5-2.5 part, 2-methyl isophthalic acid, 5-pentanediamine 4-6 part, N-acetyl group
Caprolactam 4-6 part, boron trifluoride complex 12-15 part, distilled water 38-48 part；Preparation method is by respectively
Raw material is sufficiently mixed prepared.
A kind of corrugated case environment-friendly adhesive, preparation method is as follows:
(1) corn starch, potato starch, sweet potato starch and water are mixed, be slowly added and stir
To milky serosity；
(2) by linoleic acid and modified oxidized dose of mixing；
(3) step (1) gained serosity is heated to 60 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds butadiene rubber, polyurethane rubber, sodium hydroxide, tin dilaurate two fourth
Ji Xi, 8-hydroxyquinoline, get product.
The invention has the beneficial effects as follows: invention adhesives safety and environmental protection, no side effects, do not stimulate
Respiratory tract and skin, flexible, excellent in mechanical performance, high temperature resistant, cold-resistant, there is preferable anti-impact
Hitting performance, mobile performance improves 10-20% than common adhesive, can mould proof grow, and ageing resistace is good,
It bonds life 45-50%, but also has certain fire resistance, itself and the surface of corrugated case
Tension force is bigger.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from
Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of corrugated case environment-friendly adhesive, is made up of the raw material of following weight portion: corn starch 28 parts,
Potato starch 28 parts, sweet potato starch 12 parts, butadiene rubber 18 parts, polyurethane rubber 18 parts, sodium hydroxide
11 parts, dibutyl tin laurate 22 parts, 8-hydroxyquinoline 6 parts, linoleic acid 20 parts, 55 parts of water, modified
Oxidant 22 parts；
It is made up of the raw material of following weight portion for described modified oxidized dose: potassium hyperchlorate 5 parts, peroxidating 12
Acyl 14 parts, the 5-tert-butyl group-1,3-M-phthalic acid 14 parts, 27 parts of BOC anhydride, gallic acid 2 parts, winestone
Acid 2 parts, 2-methyl isophthalic acid, 5-pentanediamine 5 parts, N-vinylcaprolactam 5 parts, boron trifluoride complex 14
Part, distilled water 43 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case environment-friendly adhesive, preparation method is as follows:
(1) corn starch, potato starch, sweet potato starch and water are mixed, be slowly added and stir
To milky serosity；
(2) by linoleic acid and modified oxidized dose of mixing；
(3) step (1) gained serosity is heated to 60 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds butadiene rubber, polyurethane rubber, sodium hydroxide, tin dilaurate two fourth
Ji Xi, 8-hydroxyquinoline, get product.
Embodiment 2
A kind of corrugated case environment-friendly adhesive, is made up of the raw material of following weight portion: corn starch 25 parts,
Potato starch 25 parts, sweet potato starch 10 parts, butadiene rubber 15 parts, polyurethane rubber 15 parts, sodium hydroxide
10 parts, dibutyl tin laurate 20 parts, 8-hydroxyquinoline 5 parts, linoleic acid 18.5 parts, 50 parts of water, change
Property oxidant 18 parts；
It is made up of the raw material of following weight portion for described modified oxidized dose: potassium hyperchlorate 5 parts, peroxidating 12
Acyl 10 parts, the 5-tert-butyl group-1,3-M-phthalic acid 10 parts, 22.2 parts of BOC anhydride, gallic acid 1.5 parts,
1.5 parts of tartaric acid, 2-methyl isophthalic acid, 5-pentanediamine 4 parts, N-vinylcaprolactam 4 parts, boron trifluoride network
Compound 12 parts, distilled water 38 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case environment-friendly adhesive, preparation method is as follows:
(1) corn starch, potato starch, sweet potato starch and water are mixed, be slowly added and stir
To milky serosity；
(2) by linoleic acid and modified oxidized dose of mixing；
(3) step (1) gained serosity is heated to 60 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds butadiene rubber, polyurethane rubber, sodium hydroxide, tin dilaurate two fourth
Ji Xi, 8-hydroxyquinoline, get product.
Embodiment 3
A kind of corrugated case environment-friendly adhesive, is made up of the raw material of following weight portion: corn starch 30 parts,
Potato starch 30 parts, sweet potato starch 15 parts, butadiene rubber 20 parts, polyurethane rubber 20 parts, sodium hydroxide
12.5 parts, dibutyl tin laurate 25 parts, 8-hydroxyquinoline 7.5 parts, linoleic acid 22 parts, 60 parts of water,
Modified oxidized dose 26 parts；
It is made up of the raw material of following weight portion for described modified oxidized dose: potassium hyperchlorate 6 parts, peroxidating 12
Acyl 17 parts, the 5-tert-butyl group-1,3-M-phthalic acid 17 parts, 23.2 parts of BOC anhydride, gallic acid 2.5 parts,
2.5 parts of tartaric acid, 2-methyl isophthalic acid, 5-pentanediamine 6 parts, N-vinylcaprolactam 6 parts, boron trifluoride network
Compound 15 parts, distilled water 48 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case environment-friendly adhesive, preparation method is as follows:
(1) corn starch, potato starch, sweet potato starch and water are mixed, be slowly added and stir
To milky serosity；
(2) by linoleic acid and modified oxidized dose of mixing；
(3) step (1) gained serosity is heated to 60 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds butadiene rubber, polyurethane rubber, sodium hydroxide, tin dilaurate two fourth
Ji Xi, 8-hydroxyquinoline, get product.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession
Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation
The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention,
The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model
In enclosing.Claimed scope is defined by appending claims and equivalent thereof.
Claims (2)
1. a corrugated case environment-friendly adhesive, it is characterised in that be made up of the raw material of following weight portion:
Corn starch 25-30 part, potato starch 25-30 part, sweet potato starch 10-15 part, butadiene rubber 15-20 part,
Polyurethane rubber 15-20 part, sodium hydroxide 10-12.5 part, dibutyl tin laurate 20-25 part, 8-hydroxyl
Base quinoline 5-7.5 part, linoleic acid 18.5-22 part, water 50-60 part, modified oxidized dose of 18-26 part；
It is made up of the raw material of following weight portion for described modified oxidized dose: potassium hyperchlorate 5-6 part, peroxidating ten
Two acyl 10-17 parts, the 5-tert-butyl group-1,3-M-phthalic acid 10-17 part, BOC anhydride 22.2-23.2 part, do not have
Gallate-based 1.5-2.5 part, tartaric acid 1.5-2.5 part, 2-methyl isophthalic acid, 5-pentanediamine 4-6 part, N-acetyl group
Caprolactam 4-6 part, boron trifluoride complex 12-15 part, distilled water 38-48 part；Preparation method is by respectively
Raw material is sufficiently mixed prepared.
2. a kind of corrugated case environment-friendly adhesive as claimed in claim 1, it is characterised in that preparation
Method is as follows:
(1) corn starch, potato starch, sweet potato starch and water are mixed, be slowly added and stir
To milky serosity；
(2) by linoleic acid and modified oxidized dose of mixing；
(3) step (1) gained serosity is heated to 60 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds butadiene rubber, polyurethane rubber, sodium hydroxide, tin dilaurate two fourth
Ji Xi, 8-hydroxyquinoline, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610290648.6A CN105820774A (en) | 2016-04-29 | 2016-04-29 | Environment-friendly binding agent for corrugated carton box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610290648.6A CN105820774A (en) | 2016-04-29 | 2016-04-29 | Environment-friendly binding agent for corrugated carton box |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105820774A true CN105820774A (en) | 2016-08-03 |
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ID=56528201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610290648.6A Pending CN105820774A (en) | 2016-04-29 | 2016-04-29 | Environment-friendly binding agent for corrugated carton box |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105820774A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325751A (en) * | 2017-08-07 | 2017-11-07 | 安徽凤凰松包装有限公司 | A kind of corrugated paper anti-aging amylum adhesive |
| CN107502228A (en) * | 2017-08-18 | 2017-12-22 | 佛山市永恒达新材料科技有限公司 | The preparation method of Natural anti-mildew adhesive |
| CN108329866A (en) * | 2018-02-06 | 2018-07-27 | 罗绍庆 | A kind of Starch Gum for Corrugated Paper and preparation method thereof |
| CN111844920A (en) * | 2018-12-18 | 2020-10-30 | 福建省文松彩印有限公司 | Environment-friendly compression-resistant waterproof corrugated carton and manufacturing method thereof |
-
2016
- 2016-04-29 CN CN201610290648.6A patent/CN105820774A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325751A (en) * | 2017-08-07 | 2017-11-07 | 安徽凤凰松包装有限公司 | A kind of corrugated paper anti-aging amylum adhesive |
| CN107502228A (en) * | 2017-08-18 | 2017-12-22 | 佛山市永恒达新材料科技有限公司 | The preparation method of Natural anti-mildew adhesive |
| CN108329866A (en) * | 2018-02-06 | 2018-07-27 | 罗绍庆 | A kind of Starch Gum for Corrugated Paper and preparation method thereof |
| CN108329866B (en) * | 2018-02-06 | 2020-01-17 | 平湖市申丰纸业有限公司 | Starch adhesive for corrugated paper and preparation method thereof |
| CN111844920A (en) * | 2018-12-18 | 2020-10-30 | 福建省文松彩印有限公司 | Environment-friendly compression-resistant waterproof corrugated carton and manufacturing method thereof |
| CN111844920B (en) * | 2018-12-18 | 2021-12-14 | 福建省文松彩印有限公司 | Environment-friendly compression-resistant waterproof corrugated carton and manufacturing method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160803 |