CN105820775A - Anti-aging binding agent for corrugated carton box - Google Patents
Anti-aging binding agent for corrugated carton box Download PDFInfo
- Publication number
- CN105820775A CN105820775A CN201610290650.3A CN201610290650A CN105820775A CN 105820775 A CN105820775 A CN 105820775A CN 201610290650 A CN201610290650 A CN 201610290650A CN 105820775 A CN105820775 A CN 105820775A
- Authority
- CN
- China
- Prior art keywords
- parts
- binding agent
- potato starch
- aging
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Dental Preparations (AREA)
Abstract
The invention provides an anti-aging binding agent for a corrugated carton box. The anti-aging binding agent is prepared from, by weight, 25-35 parts of potato starch, 15-30 parts of sweet potato starch, 5-10 parts of chlorosulfonated polyethylene rubber, 5-10 parts of nitrile butadiene rubber, 8-9 parts of nanometer graphene, 10-12 parts of talcum powder, 7-14 parts of aluminum acetylacetonate, 7-14 parts of glycidol phenyl ether, 7-14 parts of N-tertiary butyl-2-benzothiazole sulfonamide, 0.5-1.5 parts of cyclohexanone-oxime, 6-7 parts of linoleic acid, 45-62 parts of water and 20-26 parts of a modified anti-aging agent. The binding agent has very good anti-aging performance and does not degrade in an oxygen-enriched environment, ungluing is avoided under strong ultraviolet irradiation, the service life is longer than that of a common binding agent by 40-50%, metal ions and function groups in the components form strong ionic bonds, and cohesiveness is higher.
Description
Technical field
The present invention relates to amylum adhesive technical field, be specifically related to a kind of corrugated case anti-aging and bond
Agent.
Background technology
Corrugated board makes corrugated case through cross cutting, impression, nail case or stick box.Corrugated case is a kind of
Most widely used packing articles, consumption is always first of various packing articles.Corrugated case is moulded including calcium.
Since over half a century, corrugated case gradually replaces with its superior serviceability and good processing characteristics
The transportation package holdses such as wooden case, become the main force of transportation and packing.It is except protecting commodity, being easy to storehouse
Outside storage, transport, also act as and beautify commodity, the effect of publicity commodity.Corrugated case belongs to environmental protection
Product, it is beneficial to environmental protection, is beneficial to load and unload transport.
Needing during corrugated case stick box to use binding agent, binding agent is to have sticking material, glues by it
The material that two kinds separate is linked together by performance.The kind of binding agent is a lot.Mostly use starch at present
Binding agent, but always there are some problems in amylum adhesive at present, drastically influence corrugated case stick box.
Summary of the invention
The technical problem to be solved is to provide a kind of age inhibiting corrugated case binding agent.
The technical problem to be solved realizes by the following technical solutions:
A kind of corrugated case anti-aging binding agent, is made up of the raw material of following weight portion: potato starch
25-35 part, sweet potato starch 15-30 part, CSM 5-10 part, nitrile rubber 5-10 part,
Nano-graphene 8-9 part, Pulvis Talci 10-12 part, praseodynium aluminum 7-14 part, expoxy propane phenyl ether
7-14 part, the N-tert-butyl group-2-benzothiazole sulfonamide 7-14 part, cyclohexanone-oxime 0.5-1.5 part, sub-oil
Acid 6-7 part, water 45-62 part, modified age resistor 20-26 part；
Described modified age resistor is made up of the raw material of following weight portion: N-phenyl-N '-isopropyl is to benzene two
Amine 2-3.2 part, N-cyclohexyl-4-aminodiphenylamine 4-7 part, N, N-dimethyl open-chain crown ether 4-7 part,
To Chlorobenzoic Acid 8-15 part, 2.2-dimethyl benzyl 2.5-3 part, tartaric acid 4-5.5 part, periodic acid ammonium
4-6 part, N-vinylcaprolactam 4-4.5 part, ferrous perchlorate's 2-3 part, nickel nitrate 0.02-0.1 part,
Dexol 0.02-0.1 part, cerous nitrate 0.02-0.1 part, distilled water 70-80 part；Preparation method be by
Each raw material is sufficiently mixed prepared.
A kind of corrugated case anti-aging binding agent, preparation method is as follows:
(1) potato starch, sweet potato starch and water are mixed, be slowly added and be evenly stirred until creamy paste
Liquid；
(2) by linoleic acid and modified age resistor mixing；
(3) step (1) gained serosity is heated to 70 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds CSM, nitrile rubber, nano-graphene, Talcum
Powder, praseodynium aluminum, expoxy propane phenyl ether, the N-tert-butyl group-2-benzothiazole sulfonamide, hexamethylene
Ketoxime, gets product.
The invention has the beneficial effects as follows: invention adhesives has extraordinary anti ageing property, oxygen-enriched
In environment non-degradable, will not come unglued under strong ultraviolet radiation, service life is longer than common adhesive
40-50%, and metal ion and the functional group in composition forms powerful ionic bond so that its bonding
Property is higher.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from
Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of corrugated case anti-aging binding agent, is made up of the raw material of following weight portion: potato starch 30
Part, sweet potato starch 22 parts, CSM 8 parts, nitrile rubber 8 parts, nano-graphene 8 parts,
Pulvis Talci 11 parts, 10 parts of praseodynium aluminum, expoxy propane phenyl ether 10 parts, the N-tert-butyl group-2-benzene a pair of horses going side by side thiophene
Azoles sulfenamide 10 parts, cyclohexanone-oxime 1 part, linoleic acid 6 parts, 55 parts of water, modified 23 parts of age resistor；
Described modified age resistor is made up of the raw material of following weight portion: N-phenyl-N '-isopropyl is to benzene two
Amine 3 parts, N-cyclohexyl-4-aminodiphenylamine 5 parts, N, N-dimethyl open-chain crown ether 5 parts, to chloro
12 parts of benzoic acid, 2.2-dimethyl benzyl 2.5 parts, 5 parts of tartaric acid, periodic acid ammonium 5 parts, N-acetyl group are own
4 parts of lactams, ferrous perchlorate 2 parts, nickel nitrate 0.06 part, Dexol 0.06 part, cerous nitrate 0.06
Part, distilled water 75 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case anti-aging binding agent, preparation method is as follows:
(1) potato starch, sweet potato starch and water are mixed, be slowly added and be evenly stirred until creamy paste
Liquid；
(2) by linoleic acid and modified age resistor mixing；
(3) step (1) gained serosity is heated to 70 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds CSM, nitrile rubber, nano-graphene, Talcum
Powder, praseodynium aluminum, expoxy propane phenyl ether, the N-tert-butyl group-2-benzothiazole sulfonamide, hexamethylene
Ketoxime, gets product.
Embodiment 2
A kind of corrugated case anti-aging binding agent, is made up of the raw material of following weight portion: potato starch 25
Part, sweet potato starch 15 parts, CSM 5 parts, nitrile rubber 5 parts, nano-graphene 8 parts,
Pulvis Talci 10 parts, 7 parts of praseodynium aluminum, expoxy propane phenyl ether 7 parts, the N-tert-butyl group-2-benzothiazole
Sulfenamide 7 parts, cyclohexanone-oxime 0.5 part, linoleic acid 6 parts, 45 parts of water, modified 20 parts of age resistor；
Described modified age resistor is made up of the raw material of following weight portion: N-phenyl-N '-isopropyl is to benzene two
Amine 2 parts, N-cyclohexyl-4-aminodiphenylamine 4 parts, N, N-dimethyl open-chain crown ether 4 parts, to chloro
8 parts of benzoic acid, 2.2-dimethyl benzyl 2.5 parts, 4 parts of tartaric acid, periodic acid ammonium 4 parts, N-acetyl group are own
4 parts of lactams, ferrous perchlorate 2 parts, nickel nitrate 0.02 part, Dexol 0.02 part, cerous nitrate 0.02
Part, distilled water 70 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case anti-aging binding agent, preparation method is as follows:
(1) potato starch, sweet potato starch and water are mixed, be slowly added and be evenly stirred until creamy paste
Liquid；
(2) by linoleic acid and modified age resistor mixing；
(3) step (1) gained serosity is heated to 70 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds CSM, nitrile rubber, nano-graphene, Talcum
Powder, praseodynium aluminum, expoxy propane phenyl ether, the N-tert-butyl group-2-benzothiazole sulfonamide, hexamethylene
Ketoxime, gets product.
Embodiment 3
A kind of corrugated case anti-aging binding agent, is made up of the raw material of following weight portion: potato starch 35
Part, sweet potato starch 30 parts, CSM 10 parts, nitrile rubber 10 parts, nano-graphene 9 parts,
Pulvis Talci 12 parts, 14 parts of praseodynium aluminum, expoxy propane phenyl ether 14 parts, the N-tert-butyl group-2-benzene a pair of horses going side by side thiophene
Azoles sulfenamide 14 parts, cyclohexanone-oxime 1.5 parts, linoleic acid 7 parts, 62 parts of water, modified 26 parts of age resistor；
Described modified age resistor is made up of the raw material of following weight portion: N-phenyl-N '-isopropyl is to benzene two
Amine 3.2 parts, N-cyclohexyl-4-aminodiphenylamine 7 parts, N, N-dimethyl open-chain crown ether 7 parts, to chlorine
For 15 parts of benzoic acid, 2.2-dimethyl benzyl 3 parts, 5.5 parts of tartaric acid, periodic acid ammonium 6 parts, N-acetyl group
Caprolactam 4.5 parts, ferrous perchlorate 3 parts, nickel nitrate 0.1 part, Dexol 0.1 part, cerous nitrate
0.1 part, distilled water 80 parts；Preparation method is to be sufficiently mixed prepared by each raw material.
A kind of corrugated case anti-aging binding agent, preparation method is as follows:
(1) potato starch, sweet potato starch and water are mixed, be slowly added and be evenly stirred until creamy paste
Liquid；
(2) by linoleic acid and modified age resistor mixing；
(3) step (1) gained serosity is heated to 70 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds CSM, nitrile rubber, nano-graphene, Talcum
Powder, praseodynium aluminum, expoxy propane phenyl ether, the N-tert-butyl group-2-benzothiazole sulfonamide, hexamethylene
Ketoxime, gets product.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession
Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation
The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention,
The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model
In enclosing.Claimed scope is defined by appending claims and equivalent thereof.
Claims (2)
1. a corrugated case anti-aging binding agent, it is characterised in that by the raw material system of following weight portion
Become: potato starch 25-35 part, sweet potato starch 15-30 part, CSM 5-10 part, butyronitrile
Rubber 5-10 part, nano-graphene 8-9 part, Pulvis Talci 10-12 part, praseodynium aluminum 7-14 part, ring
Ethylene Oxide phenyl ether 7-14 part, the N-tert-butyl group-2-benzothiazole sulfonamide 7-14 part, cyclohexanone-oxime
0.5-1.5 part, linoleic acid 6-7 part, water 45-62 part, modified age resistor 20-26 part；
Described modified age resistor is made up of the raw material of following weight portion: N-phenyl-N '-isopropyl is to benzene two
Amine 2-3.2 part, N-cyclohexyl-4-aminodiphenylamine 4-7 part, N, N-dimethyl open-chain crown ether 4-7 part,
To Chlorobenzoic Acid 8-15 part, 2.2-dimethyl benzyl 2.5-3 part, tartaric acid 4-5.5 part, periodic acid ammonium
4-6 part, N-vinylcaprolactam 4-4.5 part, ferrous perchlorate's 2-3 part, nickel nitrate 0.02-0.1 part,
Dexol 0.02-0.1 part, cerous nitrate 0.02-0.1 part, distilled water 70-80 part；Preparation method be by
Each raw material is sufficiently mixed prepared.
2. a kind of corrugated case anti-aging binding agent as claimed in claim 1, it is characterised in that system
Preparation Method is as follows:
(1) potato starch, sweet potato starch and water are mixed, be slowly added and be evenly stirred until creamy paste
Liquid；
(2) by linoleic acid and modified age resistor mixing；
(3) step (1) gained serosity is heated to 70 DEG C and is subsequently adding step (2) gained mixture,
It is subsequently cooled to 50 DEG C, adds CSM, nitrile rubber, nano-graphene, Talcum
Powder, praseodynium aluminum, expoxy propane phenyl ether, the N-tert-butyl group-2-benzothiazole sulfonamide, hexamethylene
Ketoxime, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610290650.3A CN105820775A (en) | 2016-04-29 | 2016-04-29 | Anti-aging binding agent for corrugated carton box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610290650.3A CN105820775A (en) | 2016-04-29 | 2016-04-29 | Anti-aging binding agent for corrugated carton box |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105820775A true CN105820775A (en) | 2016-08-03 |
Family
ID=56528919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610290650.3A Pending CN105820775A (en) | 2016-04-29 | 2016-04-29 | Anti-aging binding agent for corrugated carton box |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105820775A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325751A (en) * | 2017-08-07 | 2017-11-07 | 安徽凤凰松包装有限公司 | A kind of corrugated paper anti-aging amylum adhesive |
| CN107337823A (en) * | 2017-08-07 | 2017-11-10 | 安徽凤凰松包装有限公司 | A kind of age inhibiting abrasive rubber |
| CN107418472A (en) * | 2017-08-07 | 2017-12-01 | 安徽凤凰松包装有限公司 | A kind of anti-aging corrugated paper print paste |
| CN107503233A (en) * | 2017-08-07 | 2017-12-22 | 安徽凤凰松包装有限公司 | A kind of immersion corrugated paper waterproofing agent |
| CN108264952A (en) * | 2017-12-30 | 2018-07-10 | 安徽大地节能科技有限公司 | A kind of preparation method of biomass granule fuel binding agent |
| CN118290893A (en) * | 2024-06-03 | 2024-07-05 | 上海宝新特种沥青混凝土有限公司 | Low-temperature anti-cracking colored emulsified asphalt and preparation method thereof |
-
2016
- 2016-04-29 CN CN201610290650.3A patent/CN105820775A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325751A (en) * | 2017-08-07 | 2017-11-07 | 安徽凤凰松包装有限公司 | A kind of corrugated paper anti-aging amylum adhesive |
| CN107337823A (en) * | 2017-08-07 | 2017-11-10 | 安徽凤凰松包装有限公司 | A kind of age inhibiting abrasive rubber |
| CN107418472A (en) * | 2017-08-07 | 2017-12-01 | 安徽凤凰松包装有限公司 | A kind of anti-aging corrugated paper print paste |
| CN107503233A (en) * | 2017-08-07 | 2017-12-22 | 安徽凤凰松包装有限公司 | A kind of immersion corrugated paper waterproofing agent |
| CN108264952A (en) * | 2017-12-30 | 2018-07-10 | 安徽大地节能科技有限公司 | A kind of preparation method of biomass granule fuel binding agent |
| CN118290893A (en) * | 2024-06-03 | 2024-07-05 | 上海宝新特种沥青混凝土有限公司 | Low-temperature anti-cracking colored emulsified asphalt and preparation method thereof |
| CN118290893B (en) * | 2024-06-03 | 2024-10-01 | 上海宝新特种沥青混凝土有限公司 | Low-temperature anti-cracking colored emulsified asphalt and preparation method thereof |
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Application publication date: 20160803 |
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| WD01 | Invention patent application deemed withdrawn after publication |