CN110154466A - A kind of high barrier laser transfer membrane and its production technology - Google Patents
A kind of high barrier laser transfer membrane and its production technology Download PDFInfo
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- CN110154466A CN110154466A CN201810228534.8A CN201810228534A CN110154466A CN 110154466 A CN110154466 A CN 110154466A CN 201810228534 A CN201810228534 A CN 201810228534A CN 110154466 A CN110154466 A CN 110154466A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/12—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7244—Oxygen barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention discloses a kind of high barrier laser transfer membrane, including laser transfer membrane ontology, the laser transfer membrane ontology includes papery base, and papery base upper surface is set, and the seamless applying aluminium foil layer with papery base, and aluminium foil layer upper surface is set, and it is seamless applying with aluminium foil layer, it can prevent the barrier layer of aluminium foil layer oxidation corrosion, and barrier layer upper surface is set, and it is seamless applying with barrier layer, flexible layer for improving laser transfer membrane ontology flexibility He slowing down barrier layer internal stress, and flexible layer upper surface is set, and it is seamless applying with flexible layer, for improving the hardened layer of laser transfer membrane ontology hardness and anti-penetration performance；The laser transfer membrane by the way that hardened layer, flexible layer are integrated on barrier layer, enable to laser transfer membrane improve when in use it is scratch-resistant injure puncture-proof performance, and can guarantee stable high resistant oxidation susceptibility, be conducive to protect cigarette.
Description
Technical field
The present invention relates to a kind of high barrier laser transfer membrane and its production technologies.
Background technique
Radium-shine packaging is the segmented industry in packaging industry, achieves quick development, with its in packaging industry
He compares product, and radium-shine packaging material not only has novel, beautiful appearance, while also having high-tech antiforge function,
The technical products of forefront referred to as in world's packages printing industry.The application field of radium-shine material is very extensive, food,
The industries such as drug, daily chemical product, tobacco and wine, clothes, gift wrap and ornament materials are all promoted faster.From product composition
It is divided in composition, laser film product can be roughly divided into BOPP laser film, PET laser film and three kinds of PVC laser film.From technique
It is seen in technical level, the anti-counterfeit laser film product applied to label printing field belongs to the high-end product in the sector, production
Process is related to multiple sport technique segments such as laser anti-counterfeiting plate-making, membrane pressure, coating, transfer, product added value with higher.Also extensively
It applies in food packaging, commodity packaging, such as box for moon-cake, toothpaste box etc., and these fields can get over the utilization of radium-shine technology
Come more.
And after the completion of laser transfer membrane product plated film now, it generally all directly winds, barrier layer is not protected, wind
The inorganic barrier layer for causing barrier layer embrittlement, especially sputtering and technique for atomic layer deposition to be coated in the process；In addition, radium-shine transfer
Film product in volume Compound Machining, in transportation and handling procedure, easily damage by outer surface, in turn results in falling off and piercing through for barrier layer,
Barrier layer is caused integrally to block water the significant decrease of oxygen performance.
Summary of the invention
In view of this, it is an object of the present invention to provide one kind improve when in use it is scratch-resistant injure puncture-proof performance, and can protect
Demonstrate,prove the laser transfer membrane of stable high resistant oxidation susceptibility.
In order to solve the above-mentioned technical problem, the technical scheme is that
A kind of high barrier laser transfer membrane, including laser transfer membrane ontology, the laser transfer membrane ontology includes papery
Base, and aluminium foil layer papery base upper surface and seamless applying with papery base is set, and table is arranged on aluminium foil layer
Face and with aluminium foil layer it is seamless applying, can prevent the barrier layer of aluminium foil layer oxidation corrosion, and be arranged in barrier layer upper surface
And with barrier layer is seamless applying, flexibility for improving laser transfer membrane ontology flexibility and slowing down barrier layer internal stress
Layer, and be arranged in flexible layer upper surface and with flexible layer it is seamless applying, for improving laser transfer membrane ontology hardness and anti-
The hardened layer of penetration performance.
Further, the papery base is transfer paper layer.
Further, the barrier layer is PE film.
Further, the flexible layer is the cyano resin layer of softening.
Further, the hardened layer is the weather-proof paint layer after hardening.
Further, the paint vehicle that the hardened layer uses is made of raw material from the following weight: epoxy modified silicone tree
20-30 parts of rouge, 15-17 parts of polyaryl sulphone, 11-15 parts of non-isocyanate polyurethane, 9-13 parts of soybean alkyd, floating type aluminium
11-16 parts of powder, 6-8 parts of anatase titanium dioxide, 5-7 parts of aluminum phosphate, 9-12 parts of cobalt iso-octoate, 8-12 parts of zinc tetroxy chromate,
8-10 parts of chrome green, 4-6 parts of diacetone alcohol, 4-5 parts of phthalate anhydride, 9-11 parts of cyclohexanone, 8-10 parts of ethanol amine, tung oil
12-16 parts, 3-4 parts of curing agent and 3-6 parts of anti-cracking agent.
Further, the curing agent is vinyl triamine DETA, aminoethyl piperazine AE, m-phenylene diamine (MPD) and diamino hexichol
The mixture of one or more of methylmethane.
Further, the anti-cracking agent is phenyl-β-naphthylamine, N, N- diphenyl-para-phenylene diamine and N- phenyl N '-isopropyl
The mixture of one or more of p-phenylenediamine.
Another technical problem to be solved by the invention is to provide a kind of preparation method of paint vehicle, comprising the following steps:
A kind of preparation method of laser transfer membrane paint vehicle, comprising the following steps:
1) 20-30 parts of epoxy modified silicone resin, 15-17 parts of polyaryl sulphone, non-isocyanate polyurethane 11-15 are taken
Part is put into reaction kettle with soybean alkyd 9-13 parts, in the item that the revolving speed of reaction kettle is 25r/pm, temperature is 110-120 DEG C
Under part, agitating and heating 20-30min, so that epoxy modified silicone resin, polyaryl sulphone, non-isocyanate polyurethane and beans
Oil alkyd resin melting mixing at high temperature, is then allowed to stand cooling 10-15min, and mixed solution is made, spare；
2) it takes in 12-16 parts of reaction kettles being added in step 1) of tung oil, and the revolving speed for controlling reaction kettle drops to 20r/
Pm is stirred to react under the conditions of temperature is 50-70 DEG C with obtained mixed solution, spare；
3) 11-16 parts of floating type aluminium powder, 6-8 parts of anatase titanium dioxide, 5-7 parts of aluminum phosphate, 9-12 parts of cobalt iso-octoate, four are taken
8-12 parts of alkali zinc chromate and chrome green 8-10 parts are added in agitator to be dispersed with stirring in advance, is stirred under the low speed of 20r/pm
It mixes to being uniformly mixed, filler is made, it is spare；
4) filler made from step 3) is transferred in the reaction kettle of step 2), is turned with mixed solution obtained in 20r/pm
It is uniformly mixed under speed, adds 4-6 parts of diacetone alcohol, 4-5 parts of phthalate anhydride, 9-11 parts of cyclohexanone, ethanol amine 8-10
Part, 3-4 parts of curing agent and 3-6 parts of anti-cracking agent, the revolving speed for adjusting reaction kettle is improved by 20r/pm to 50r/pm, and stirs 8-10 points
Clock, so that the adjuvant of addition is stirred evenly with mixed solution, it is spare；
5) mixed solution made from step 4) is transferred in high speed disperser, by high speed disperser with 300r/pm's
Revolving speed carries out high speed rotation and stirs 2-4 hours, and paint vehicle is obtained after standing；It is spare；
6) use of paint vehicle: by paint vehicle made from step 5) through coater on cyano resin layer, then by nitrile
Base resin layer is combined to PE film by compounding machine, then carries out rewinding by rewinding machine, carries out cutting processing using cutting machine,
To obtain the final product.
The technology of the present invention effect major embodiment is in the following areas: the laser transfer membrane is by by hardened layer, flexible layer combination
Onto barrier layer, enable to laser transfer membrane improve when in use it is scratch-resistant injure puncture-proof performance, and can guarantee stable
High resistant oxidation susceptibility is conducive to protect cigarette, in addition, hardened layer is with epoxy modified silicone resin, polyaryl sulphone, non-isocyanide
Acid esters polyurethane and soybean alkyd as main glue, addition by floating type aluminium powder, anatase titanium dioxide, aluminum phosphate,
Filler made of cobalt iso-octoate, zinc tetroxy chromate and chrome green, and diacetone alcohol, phthalic acid are added upon mixing
Acid anhydride, cyclohexanone, ethanol amine, tung oil, curing agent and anti-cracking agent, paint vehicle obtained can not only rapid curing, and be applied to
Antioxidant effect can be improved on laser transfer membrane, avoid the destruction of barrier layer.
Detailed description of the invention
Fig. 1 is a kind of cross-sectional view of high barrier laser transfer membrane of the present invention.
Specific embodiment
Below in conjunction with attached drawing, a specific embodiment of the invention is described in further detail, so that technical solution of the present invention is more
It should be readily appreciated that and grasp.
In embodiment, it is to be understood that term " centre ", "upper", "lower", " top ", " right side ", " left end ", " on
Side ", " back side ", " middle part ", etc. instructions orientation or positional relationship be based on the orientation or positional relationship shown in the drawings, be only for
Convenient for the description present invention, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific
Orientation construction and operation, therefore be not considered as limiting the invention.
Embodiment 1
A kind of high barrier laser transfer membrane, including laser transfer membrane ontology 1, the laser transfer membrane ontology 1 include paper
Matter base 11, and aluminium foil layer 12 that is that 11 upper surface of papery base is set and being bonded with papery base 11 by composite seamless,
And 12 upper surface of aluminium foil layer is set and be bonded with aluminium foil layer 12 by composite seamless, can prevent aluminium foil layer 12 from aoxidizing corruption
The barrier layer 13 of erosion, and 13 upper surface of barrier layer is set and be bonded with barrier layer 13 by composite seamless, for improving
1 flexibility of laser transfer membrane ontology and the flexible layer 14 for slowing down 13 internal stress of barrier layer, and be arranged in 14 upper surface of flexible layer,
And hardening be bonded with flexible layer 14 by composite seamless, for improving laser transfer membrane ontology 1 hardness and anti-penetration performance
Layer 15.In the present embodiment, the papery base 11 is transfer paper layer.The barrier layer 13 is PE film.The flexible layer 14
For the cyano resin layer of softening.The hardened layer 15 is the weather-proof paint layer after hardening.
The paint vehicle that the hardened layer uses is made of raw material from the following weight: 30 parts of epoxy modified silicone resin gathers
15 parts of fragrant sulphone resin, 11 parts of non-isocyanate polyurethane, 9 parts of soybean alkyd, floating 11 parts of type aluminium powder, anatase titanium dioxide
6 parts, 5 parts of aluminum phosphate, 9 parts of cobalt iso-octoate, 8 parts of zinc tetroxy chromate, 8 parts of chrome green, 4 parts of diacetone alcohol, phthalic acid
4 parts of acid anhydride, 9 parts of cyclohexanone, 8 parts of ethanol amine, 12 parts of tung oil, 3 parts of curing agent and 3 parts of anti-cracking agent.
A kind of preparation method of laser transfer membrane paint vehicle, comprising the following steps:
1) 30 parts of epoxy modified silicone resin, 15 parts of polyaryl sulphone, 11 parts of non-isocyanate polyurethane and soya-bean oil are taken
9 parts of alkyd resin are put into reaction kettle, under conditions of the revolving speed of reaction kettle is 25r/pm, temperature is 110 DEG C, agitating and heating
20min, so that epoxy modified silicone resin, polyaryl sulphone, non-isocyanate polyurethane and soybean alkyd are in high temperature
Lower melting mixing, is then allowed to stand cooling 10min, and mixed solution is made, spare；
2) it takes in 12 parts of reaction kettles being added in step 1) of tung oil, and the revolving speed for controlling reaction kettle drops to 20r/pm,
It is stirred to react under the conditions of temperature is 50 DEG C with obtained mixed solution, it is spare；
3) 11 parts of floating type aluminium powder, 6 parts of anatase titanium dioxide, 5 parts of aluminum phosphate, 9 parts of cobalt iso-octoate, zinc tetroxy chromate are taken
8 parts and 8 parts of chrome green are added in agitator to be dispersed with stirring in advance, and stirring is to being uniformly mixed under the low speed of 20r/pm, system
Filler is obtained, it is spare；
4) filler made from step 3) is transferred in the reaction kettle of step 2), is turned with mixed solution obtained in 20r/pm
It is uniformly mixed under speed, adds 4 parts of diacetone alcohol, 4 parts of phthalate anhydride, 9 parts of cyclohexanone, 8 parts of ethanol amine, curing agent 3
Part and 3 parts of anti-cracking agent, adjust the revolving speed of reaction kettle and improved by 20r/pm to 50r/pm, and stir 8 minutes, so that the adjuvant of addition
It is stirred evenly with mixed solution, it is spare；
5) mixed solution made from step 4) is transferred in high speed disperser, by high speed disperser with 300r/pm's
Revolving speed carries out high speed rotation and stirs 2 hours, and paint vehicle is obtained after standing；It is spare；
6) use of paint vehicle: by paint vehicle made from step 5) through coater on cyano resin layer, then by nitrile
Base resin layer is combined to PE film by compounding machine, then carries out rewinding by rewinding machine, carries out cutting processing using cutting machine,
To obtain the final product.
In the present embodiment, the curing agent is vinyl triamine DETA.The anti-cracking agent is phenyl-β-naphthylamine.
Embodiment 2
A kind of high barrier laser transfer membrane, including laser transfer membrane ontology 1, the laser transfer membrane ontology 1 include paper
Matter base 11, and aluminium foil layer 12 that is that 11 upper surface of papery base is set and being bonded with papery base 11 by composite seamless,
And 12 upper surface of aluminium foil layer is set and be bonded with aluminium foil layer 12 by composite seamless, can prevent aluminium foil layer 12 from aoxidizing corruption
The barrier layer 13 of erosion, and 13 upper surface of barrier layer is set and be bonded with barrier layer 13 by composite seamless, for improving
1 flexibility of laser transfer membrane ontology and the flexible layer 14 for slowing down 13 internal stress of barrier layer, and be arranged in 14 upper surface of flexible layer,
And hardening be bonded with flexible layer 14 by composite seamless, for improving laser transfer membrane ontology 1 hardness and anti-penetration performance
Layer 15.In the present embodiment, the papery base 11 is transfer paper layer.The barrier layer 13 is PE film.The flexible layer 14
For the cyano resin layer of softening.The hardened layer 15 is the weather-proof paint layer after hardening.
The paint vehicle that the hardened layer uses is made of raw material from the following weight: 20 parts of epoxy modified silicone resin gathers
17 parts of fragrant sulphone resin, 15 parts of non-isocyanate polyurethane, 13 parts of soybean alkyd, floating 16 parts of type aluminium powder, Detitanium-ore-type titanium white
8 parts of powder, 7 parts of aluminum phosphate, 12 parts of cobalt iso-octoate, 12 parts of zinc tetroxy chromate, 10 parts of chrome green, 6 parts of diacetone alcohol, benzene two
5 parts of formic anhydride, 11 parts of cyclohexanone, 10 parts of ethanol amine, 16 parts of tung oil, 4 parts of curing agent and 6 parts of anti-cracking agent.
A kind of preparation method of laser transfer membrane paint vehicle, comprising the following steps:
1) 20 parts of epoxy modified silicone resin, 17 parts of polyaryl sulphone, 15 parts of non-isocyanate polyurethane and soya-bean oil are taken
13 parts of alkyd resin are put into reaction kettle, under conditions of the revolving speed of reaction kettle is 25r/pm, temperature is 120 DEG C, agitating and heating
20-30min, so that epoxy modified silicone resin, polyaryl sulphone, non-isocyanate polyurethane and soybean alkyd are in height
The lower melting mixing of temperature, is then allowed to stand cooling 15min, mixed solution is made, spare；
2) it takes in 16 parts of reaction kettles being added in step 1) of tung oil, and the revolving speed for controlling reaction kettle drops to 20r/pm,
It is stirred to react under the conditions of temperature is 70 DEG C with obtained mixed solution, it is spare；
3) 16 parts of floating type aluminium powder, 8 parts of anatase titanium dioxide, 7 parts of aluminum phosphate, 12 parts of cobalt iso-octoate, four alkali chromic acid are taken
12 parts of zinc and 10 parts of chrome green are added in agitator to be dispersed with stirring in advance, and stirring is equal to mixing under the low speed of 20r/pm
It is even, filler is made, it is spare；
4) filler made from step 3) is transferred in the reaction kettle of step 2), is turned with mixed solution obtained in 20r/pm
It is uniformly mixed under speed, adds 6 parts of diacetone alcohol, 5 parts of phthalate anhydride, 11 parts of cyclohexanone, 10 parts of ethanol amine, curing agent
4 parts and 6 parts of anti-cracking agent, the revolving speed for adjusting reaction kettle is improved by 20r/pm to 50r/pm, and is stirred 10 minutes, so that addition is auxiliary
Agent is stirred evenly with mixed solution, spare；
5) mixed solution made from step 4) is transferred in high speed disperser, by high speed disperser with 300r/pm's
Revolving speed carries out high speed rotation and stirs 4 hours, and paint vehicle is obtained after standing；It is spare；
6) use of paint vehicle: by paint vehicle made from step 5) through coater on cyano resin layer, then by nitrile
Base resin layer is combined to PE film by compounding machine, then carries out rewinding by rewinding machine, carries out cutting processing using cutting machine,
To obtain the final product.
In the present embodiment, the curing agent is the mixed of aminoethyl piperazine AE, m-phenylene diamine (MPD) and diaminodiphenyl-methane
Close object.The anti-cracking agent is N, N- diphenyl-para-phenylene diamine and N- phenyl N '-isopropyl p-phenylenediamine mixture.
Embodiment 3
A kind of high barrier laser transfer membrane, including laser transfer membrane ontology 1, the laser transfer membrane ontology 1 include paper
Matter base 11, and aluminium foil layer 12 that is that 11 upper surface of papery base is set and being bonded with papery base 11 by composite seamless,
And 12 upper surface of aluminium foil layer is set and be bonded with aluminium foil layer 12 by composite seamless, can prevent aluminium foil layer 12 from aoxidizing corruption
The barrier layer 13 of erosion, and 13 upper surface of barrier layer is set and be bonded with barrier layer 13 by composite seamless, for improving
1 flexibility of laser transfer membrane ontology and the flexible layer 14 for slowing down 13 internal stress of barrier layer, and be arranged in 14 upper surface of flexible layer,
And hardening be bonded with flexible layer 14 by composite seamless, for improving laser transfer membrane ontology 1 hardness and anti-penetration performance
Layer 15.In the present embodiment, the papery base 11 is transfer paper layer.The barrier layer 13 is PE film.The flexible layer 14
For the cyano resin layer of softening.The hardened layer 15 is the weather-proof paint layer after hardening.
The paint vehicle that the hardened layer uses is made of raw material from the following weight: 25 parts of epoxy modified silicone resin gathers
16 parts of fragrant sulphone resin, 13 parts of non-isocyanate polyurethane, 11 parts of soybean alkyd, floating 13.5 parts of type aluminium powder, Detitanium-ore-type titanium
7 parts of white powder, 6 parts of aluminum phosphate, 10.5 parts of cobalt iso-octoate, 10 parts of zinc tetroxy chromate, 9 parts of chrome green, 5 parts of diacetone alcohol,
4.5 parts of phthalate anhydride, 10 parts of cyclohexanone, 9 parts of ethanol amine, 14 parts of tung oil, 3.5 parts of curing agent and 4.5 parts of anti-cracking agent.
A kind of preparation method of laser transfer membrane paint vehicle, comprising the following steps:
1) 25 parts of epoxy modified silicone resin, 16 parts of polyaryl sulphone, 13 parts of non-isocyanate polyurethane and soya-bean oil are taken
11 parts of alkyd resin are put into reaction kettle, under conditions of the revolving speed of reaction kettle is 25r/pm, temperature is 115 DEG C, agitating and heating
25min, so that epoxy modified silicone resin, polyaryl sulphone, non-isocyanate polyurethane and soybean alkyd are in high temperature
Lower melting mixing, is then allowed to stand cooling 13min, and mixed solution is made, spare；
2) it takes in 14 parts of reaction kettles being added in step 1) of tung oil, and the revolving speed for controlling reaction kettle drops to 20r/pm,
It is stirred to react under the conditions of temperature is 60 DEG C with obtained mixed solution, it is spare；
3) 13.5 parts of floating type aluminium powder, 7 parts of anatase titanium dioxide, 6 parts of aluminum phosphate, 10.5 parts of cobalt iso-octoate, four alkali are taken
10 parts of zinc chromate and 9 parts of chrome green are added in agitator to be dispersed with stirring in advance, and stirring is to mixing under the low speed of 20r/pm
Uniformly, filler is made, it is spare；
4) filler made from step 3) is transferred in the reaction kettle of step 2), is turned with mixed solution obtained in 20r/pm
It is uniformly mixed under speed, adds 5 parts of diacetone alcohol, 4.5 parts of phthalate anhydride, 10 parts of cyclohexanone, 9 parts of ethanol amine, solidification
3.5 parts and 4.5 parts of anti-cracking agent of agent, the revolving speed for adjusting reaction kettle is improved by 20r/pm to 50r/pm, and is stirred 9 minutes, so that adding
The adjuvant added is stirred evenly with mixed solution, spare；
5) mixed solution made from step 4) is transferred in high speed disperser, by high speed disperser with 300r/pm's
Revolving speed carries out high speed rotation and stirs 3 hours, and paint vehicle is obtained after standing；It is spare；
6) use of paint vehicle: by paint vehicle made from step 5) through coater on cyano resin layer, then by nitrile
Base resin layer is combined to PE film by compounding machine, then carries out rewinding by rewinding machine, carries out cutting processing using cutting machine,
To obtain the final product.
In the present embodiment, the curing agent is vinyl triamine DETA, aminoethyl piperazine AE, m-phenylene diamine (MPD) and diamino
The mixture of diphenyl methane.The anti-cracking agent is phenyl-β-naphthylamine, N, N- diphenyl-para-phenylene diamine and N- phenyl N '-isopropyl
The mixture of base p-phenylenediamine.
Experimental example:
Pitch paint vehicle as a control group one is chosen, organic siliconresin paint vehicle as a control group two and the application is chosen
Paint vehicle is as experimental group.
Following table is the measuring method and standard of three groups of paint vehicles:
| Adhesive force | The cross cut test GB/T9286-1998 of paint and varnish paint film |
| Fineness | Colored paint, varnish and the measurement ISO1524-2013 for printing ink fineness of grind |
| Drying time | Paint film, putty membrane drying time measuring method GB/T1728-1979 |
| Weatherability | Paint and varnish artificial weathering aging and man-made radiation's exposure GB/T1865-1997 |
| Viscosity | Paint and varnish measures delivery time GB/T6753.4-1988 with outflow cup |
| Coloring | It is index by absorptivity of the paint vehicle to paint ink |
Experimental subjects chooses three pieces area, material and the identical PE film of specification.
Requirement of experiment: it is painted respectively using above-mentioned three groups of paint vehicles to PE film, specific detection data is as follows:
Following table is the experimental result of three groups of paint vehicles:
In conjunction with upper table, compares control group one, control group two and experimental group, paint vehicle of the invention and surveyed as experimental group
The data obtained are superior to control group one and control group two, and therefore, compared to than control group one and control group two, the paint vehicle of the application is more
Add and is suitble to be applied in laser transfer membrane as tobacco paper.
The technology of the present invention effect major embodiment is in the following areas: the laser transfer membrane is by by hardened layer, flexible layer combination
Onto barrier layer, enable to laser transfer membrane improve when in use it is scratch-resistant injure puncture-proof performance, and can guarantee stable
High resistant oxidation susceptibility is conducive to protect cigarette, in addition, hardened layer is with epoxy modified silicone resin, polyaryl sulphone, non-isocyanide
Acid esters polyurethane and soybean alkyd as main glue, addition by floating type aluminium powder, anatase titanium dioxide, aluminum phosphate,
Filler made of cobalt iso-octoate, zinc tetroxy chromate and chrome green, and diacetone alcohol, phthalic acid are added upon mixing
Acid anhydride, cyclohexanone, ethanol amine, tung oil, curing agent and anti-cracking agent, paint vehicle obtained can not only rapid curing, and be applied to
Antioxidant effect can be improved on laser transfer membrane, avoid the destruction of barrier layer.
Certainly, above is representative instance of the invention, and in addition to this, the present invention can also have other a variety of specific implementations
Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.
Claims (8)
1. a kind of high barrier laser transfer membrane, including laser transfer membrane ontology, it is characterised in that: the laser transfer membrane ontology
Including papery base, and aluminium foil layer papery base upper surface and seamless applying with papery base is set, and is arranged in aluminium
Layers of foil upper surface and with aluminium foil layer it is seamless applying, can prevent the barrier layer of aluminium foil layer oxidation corrosion, and be arranged in barrier layer
Upper surface and with barrier layer it is seamless applying, for improving laser transfer membrane ontology flexibility and slowing down barrier layer internal stress
Flexible layer, and flexible layer upper surface is set and it is seamless applying, hard for improving laser transfer membrane ontology with flexible layer
The hardened layer of degree and anti-penetration performance.
2. a kind of high barrier laser transfer membrane as described in claim 1, it is characterised in that: the papery base is transfer paper
Layer.
3. a kind of high barrier laser transfer membrane as described in claim 1, it is characterised in that: the barrier layer is PE film.
4. a kind of high barrier laser transfer membrane as described in claim 1, it is characterised in that: the flexible layer is the nitrile of softening
Base resin layer.
5. a kind of high barrier laser transfer membrane as described in claim 1, it is characterised in that: the hardened layer is after hardening
Weather-proof paint layer.
6. a kind of high barrier laser transfer membrane as claimed in claim 5, it is characterised in that: the paint vehicle that the hardened layer uses
It is made of raw material from the following weight: 20-30 parts of epoxy modified silicone resin, 15-17 parts of polyaryl sulphone, non-isocyanate
11-15 parts of polyurethane, 9-13 parts of soybean alkyd, floating 11-16 parts of type aluminium powder, 6-8 parts of anatase titanium dioxide, aluminum phosphate 5-
7 parts, 9-12 parts of cobalt iso-octoate, 8-12 parts of zinc tetroxy chromate, 8-10 parts of chrome green, 4-6 parts of diacetone alcohol, phthalic acid
4-5 parts of acid anhydride, 9-11 parts of cyclohexanone, 8-10 parts of ethanol amine, 12-16 parts of tung oil, 3-4 parts of curing agent and 3-6 parts of anti-cracking agent.
7. a kind of high barrier laser transfer membrane as claimed in claim 6, it is characterised in that: the curing agent is vinyl three
The mixture of one or more of amine DETA, aminoethyl piperazine AE, m-phenylene diamine (MPD) and diaminodiphenyl-methane.
8. a kind of high barrier laser transfer membrane as claimed in claim 6, it is characterised in that: the anti-cracking agent is phenyl-β-
The mixture of one or more of naphthylamines, N, N- diphenyl-para-phenylene diamine and N- phenyl N '-isopropyl p-phenylenediamine.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111251740A (en) * | 2020-01-19 | 2020-06-09 | 上海美美尚隽印刷有限公司 | Laser transfer film and preparation method thereof |
| CN113478995A (en) * | 2021-07-02 | 2021-10-08 | 浙江春宇包装材料有限公司 | Laser transfer film and production process thereof |
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| CN104861866A (en) * | 2015-05-30 | 2015-08-26 | 张家港市山牧新材料技术开发有限公司 | Heat-resistant paint and preparation method thereof |
| CN205130674U (en) * | 2015-11-12 | 2016-04-06 | 宿迁市金田塑业有限公司 | Radium -shine transfer base film |
| CN206186461U (en) * | 2016-11-15 | 2017-05-24 | 深圳市东冠包装印刷纸品有限公司 | Radium -shine transfer card of PET band light beam and processingequipment thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861866A (en) * | 2015-05-30 | 2015-08-26 | 张家港市山牧新材料技术开发有限公司 | Heat-resistant paint and preparation method thereof |
| CN205130674U (en) * | 2015-11-12 | 2016-04-06 | 宿迁市金田塑业有限公司 | Radium -shine transfer base film |
| CN206186461U (en) * | 2016-11-15 | 2017-05-24 | 深圳市东冠包装印刷纸品有限公司 | Radium -shine transfer card of PET band light beam and processingequipment thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111251740A (en) * | 2020-01-19 | 2020-06-09 | 上海美美尚隽印刷有限公司 | Laser transfer film and preparation method thereof |
| CN111251740B (en) * | 2020-01-19 | 2021-06-25 | 上海美美尚隽印刷有限公司 | Laser transfer film and preparation method thereof |
| CN113478995A (en) * | 2021-07-02 | 2021-10-08 | 浙江春宇包装材料有限公司 | Laser transfer film and production process thereof |
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