CN105238298A - High-performance modified chloroprene rubber adhesive - Google Patents
High-performance modified chloroprene rubber adhesive Download PDFInfo
- Publication number
- CN105238298A CN105238298A CN201510623893.XA CN201510623893A CN105238298A CN 105238298 A CN105238298 A CN 105238298A CN 201510623893 A CN201510623893 A CN 201510623893A CN 105238298 A CN105238298 A CN 105238298A
- Authority
- CN
- China
- Prior art keywords
- parts
- chloroprene rubber
- resin
- performance modified
- rubber adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses a high-performance modified chloroprene rubber adhesive, wherein the raw materials comprise chloroprene rubber, cis-polybutadiene rubber, styrene-butadiene rubber, an alkyl benzoic acid resin, a p-tert-butyl phenol formaldehyde resin, a terpene resin, nanometer silica, nanometer alumina, organic bentonite, white carbon black, active magnesium oxide, polystyrene, ethylene thiourea, zinc oxide, ethyl acetate, cyclohexane, dimethyl carbonate, propylene glycol, methyl cyclopentane, 120# solvent oil, a resorcinol-formaldehyde resin, an anti-aging agent, cerium oxide, a silane coupling agent KH-560 and a plasticizer. According to the present invention, the high-performance modified chloroprene rubber adhesive has characteristics of high bonding strength, good low temperature resistance, good weather resistance, good heat resistance, good aging resistance, and excellent storage stability.
Description
Technical field
The present invention relates to chloroprene rubber adhesive technical field, particularly relate to a kind of high-performance modified chloroprene rubber adhesive.
Background technology
Chloroprene rubber is the body material of chloroprene rubber adhesive, its molecular structure is regular, molecular chain there is again the chlorine atom that polarity is large, this makes chloroprene rubber at room temperature also have higher cohesive strength and flame resistivity and ageing-resistant performance is better, the sizing agent be mixed with it can at room temperature cold-curing, initial bonding strength be very large, intensity is set up rapidly, bonding strength is higher, may be used for adhesive rubber, leather, fabric, leatheroid, plastics, timber, paper product, glass, pottery etc.But chloroprene rubber adhesive exists poor storage stability simultaneously, the defect that lower temperature resistance, weathering resistance and thermotolerance are undesirable, limits its range of application.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of high-performance modified chloroprene rubber adhesive, its cohesive strength is high, and lower temperature resistance, weathering resistance, thermotolerance and ageing resistance are good, and stable storing performance is excellent.
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 70-100 part, cis-1,4-polybutadiene rubber 5-15 part, styrene-butadiene rubber(SBR) 5-20 part, alkylphenyl acid resin 5-15 part, para-tert-butyl phenolic resin 3-10 part, terpine resin 2-5 part, nano silicon 1-5 part, nano aluminium oxide 1-5 part, organobentonite 2-8 part, white carbon black 5-12 part, activated magnesia 3-10 part, polystyrene 1-3.5 part, ethylene thiourea 1-5 part, zinc oxide 2-8 part, ethyl acetate 30-50 part, hexanaphthene 10-25 part, methylcarbonate 60-120 part, propylene glycol 10-30 part, methylcyclopentane 10-25 part, 120# solvent oil 10-35 part, resorcinol-formaldehyde resin 0.5-2 part, anti-aging agent 1-3.5 part, cerium oxide 2-5 part, silane coupling agent KH-5601-2.5 part, softening agent 3-5 part.
In a particular embodiment, the high-performance modified chloroprene rubber adhesive of one that the present invention proposes, in its raw material, the weight part of chloroprene rubber can be 70,72,73,74.6,77,78,82,83,85.6,87,89,92,93,94.6,96,97,98,99.2,100 parts; The weight part of cis-1,4-polybutadiene rubber can be 5,6,7,8,8.6,9,9.2,10,11,11.5,12,12.6,13,13.5,14,14.6,15 parts; The weight part of styrene-butadiene rubber(SBR) can be 5,6,7,8,8.6,9,9.7,10,12,13,14.5,16,17,17.6,18,18.6,19,19.3,20 parts; The weight part of alkylphenyl acid resin can be 5,6,7,8,8.6,9,10,11,11.5,12,12.5,13,13.6,14,14.6,15 parts; The weight part of para-tert-butyl phenolic resin can be 3,4,5,6,6.7,7,7.5,8,9,9.5,10 parts; The weight part of terpine resin can be 2,2.4,2.8,3,3.2,3.8,4,4.6,5 parts; The weight part of nano silicon can be 1,1.5,1.8,2,2.5,3,3.4,3.8,4,4.3,4.8,5 part; The weight part of nano aluminium oxide can be 1,1.2,1.8,2,2.5,3,3.4,3.8,4,4.4,5 part; Bentonite weight part can be 2,3,4,5,5.6,6,6.4,7,7.5,8 parts; The weight part of white carbon black can be 5,6,7,8,8.7,9,10,11,11.5,12 parts; The weight part of activated magnesia can be 3,4,5,6,6.5,7,8,8.6,9,9.7,10 parts; The weight part of polystyrene can be 1,1.2,1.6,2,2.3,2.8,3,3.2,3.4,3.5 part; The weight part of ethylene thiourea can be 1,1.2,1.5,1.8,2,2.4,2.7,3,3.4,3.8,4,4.3,4.8,5 part; The weight part of zinc oxide can be 2,2.3,2.8,3,4,5,5.3,6,6.5,7,7.6,8 parts; The weight part of ethyl acetate can be 30,32,35,37,39,43,47,47.8,49,49.4,50 parts; The weight part of hexanaphthene can be 10,12,14,16,17.6,19,21,21.6,23,23.6,24,24.6,25 parts; The weight part of methylcarbonate can be 60,65,68,69,72,75,78.6,83,87,93,95.7,99,102,107,112,116,118.6,120 parts; The weight part of propylene glycol can be 10,12,15,16,17,18.6,19,21,24,25,26,26.7,28,29.3,30 parts; The weight part of methylcyclopentane can be 10,12,15,16,17.4,19,21,22.5,23,24.5,25 parts; The weight part of 120# solvent oil can be 10,12,14,16,17,18.5,21,24,26,27,28,29.6,31,32,33,33.6,35 parts; The weight part of resorcinol-formaldehyde resin can be 0.5,0.6,0.7,0.9,1,1.2,1.5,1.6,1.78,1.9,2 part; The weight part of anti-aging agent can be 1,1.2,1.5,1.6,1.8,2,2.3,2.5,2.7,2.9,3,3.2,3.3,3.4,3.5 part; The weight part of cerium oxide can be 2,2.3,2.6,2.8,3,3.2,3.6,3.8,4,4.3,4.7,4.8,5 parts; The weight part of silane coupling agent KH-560 can be 1,1.2,1.4,1.6,1.8,2,2.1,2.2,2.3,2.46,2.5 part; The weight part of softening agent can be 3,3.2,3.5,3.8,4,4.3,4.4,4.7,4.8,5 parts.
Preferably, in its raw material, the weight ratio of chloroprene rubber, cis-1,4-polybutadiene rubber, styrene-butadiene rubber(SBR), alkylphenyl acid resin, para-tert-butyl phenolic resin, terpine resin is 87-94:8-13:9-16:9-12:5-8:3-3.8.
Preferably, in its raw material, the weight ratio of ethyl acetate, hexanaphthene, methylcarbonate, propylene glycol, methylcyclopentane, 120# solvent oil is 38-43:16-21:86-92:19-25:17-22:19-26.
Preferably, its raw material comprises following component by weight: chloroprene rubber 90-93 part, cis-1,4-polybutadiene rubber 9-12 part, styrene-butadiene rubber(SBR) 11-14 part, alkylphenyl acid resin 10-11 part, para-tert-butyl phenolic resin 6-7.5 part, terpine resin 3.2-3.5 part, nano silicon 3.8-4.2 part, nano aluminium oxide 3.5-3.9 part, organobentonite 5.2-6 part, white carbon black 7-10 part, activated magnesia 5.8-7 part, polystyrene 1.9-2.6 part, ethylene thiourea 3.2-4 part, zinc oxide 5.2-6 part, ethyl acetate 40-42 part, hexanaphthene 18-20 part, methylcarbonate 89-91 part, propylene glycol 21-24 part, methylcyclopentane 19-21 part, 120# solvent oil 21-25 part, resorcinol-formaldehyde resin 1.1-1.6 part, anti-aging agent 1.8-2.3 part, cerium oxide 3.5-4 part, silane coupling agent KH-5601.6-2 part, softening agent 3.9-4.5 part.
Preferably, its raw material comprises following component by weight: chloroprene rubber 92 parts, cis-1,4-polybutadiene rubber 10 parts, 12 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 10.6 parts, para-tert-butyl phenolic resin 7.2 parts, terpine resin 3.3 parts, nano silicon 4 parts, nano aluminium oxide 3.6 parts, organobentonite 5.5 parts, white carbon black 8 parts, activated magnesia 6 parts, polystyrene 2.1 parts, ethylene thiourea 3.5 parts, 5.5 parts, zinc oxide, ethyl acetate 41 parts, hexanaphthene 18 parts, methylcarbonate 90 parts, propylene glycol 22 parts, methylcyclopentane 20 parts, 120# solvent oil 23.5 parts, resorcinol-formaldehyde resin 1.4 parts, 2 parts, anti-aging agent, cerium oxide 3.6 parts, silane coupling agent KH-5601.8 part, 4.2 parts, softening agent.
Preferably, the median size of described nano silicon is 15-25nm; The median size of described nano aluminium oxide is 20-35nm.
Preferably, the properties-correcting agent that described organobentonite uses is lauric acid, the mixture of a kind of in hexamethyldisilazane or two kinds.
Preferably, described anti-aging agent is one or more the mixture in antioxidant A W, anti-aging agent RD, antioxidant H, antioxidant 4010NA, antioxidant 4020.
Preferably, described softening agent is one or more the mixture in Octyl adipate, dioctyl sebacate, butyl oleate, trioctyl phosphate, epoxyoleic acid butyl ester, hexanodioic acid two (Butoxyethoxy second) ester, Viscoat 295.
Preferably, described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is stearic acid, one or more mixture in lauric acid, vinylformic acid, Sodium dodecylbenzene sulfonate, hexamethyldisilazane, vinyltriethoxysilane.
High-performance modified chloroprene rubber adhesive of the present invention can chloroprene rubber adhesive preparation technology conveniently be prepared from.
In the present invention, have selected cis-1,4-polybutadiene rubber, styrene-butadiene rubber(SBR), alkylphenyl acid resin, para-tert-butyl phenolic resin and terpine resin carry out modification to chloroprene rubber, improve the weathering resistance of chloroprene rubber adhesive, thermotolerance, lower temperature resistance, ageing resistance, adhesive property and processing characteristics, wherein, cis-1,4-polybutadiene rubber winter hardiness is good, silane coupling agent KH-560 auxiliary under, good with the consistency of system, improve the lower temperature resistance of chloroprene rubber, styrene-butadiene rubber(SBR) adds in system, be conducive to intermolecular cross-linking and form stable reticulated structure, with anti-aging agent, cerium oxide coordinates the ageing-resistant performance that improve sizing agent, alkylphenyl acid resin, para-tert-butyl phenolic resin and terpine resin coordinate and add in system, and Efficient Adhesive Promotion is good, improves sizing agent to the wettability of base material, tack and cohesive force, activated magnesia, ethylene thiourea coordinate with zinc oxide and have collaborative crosslinked action, improve the crosslinking degree of system, coordinate with nano silicon, nano aluminium oxide, organobentonite, white carbon black, activated magnesia, polystyrene, there is synergy, improve the hardness of sizing agent, thermotolerance, winter hardiness, cohesive strength, water-fast moistureproofness, package stability and the feature of environmental protection, have selected methylcarbonate coordinates as solvent with ethyl acetate, hexanaphthene, methylcarbonate, propylene glycol, methylcyclopentane, 120# solvent oil, by regulating its content, while not affecting sizing agent performance, improve the stability in storage of sizing agent, Low-temperature antifreeze, reduces the toxicity of sizing agent, resorcinol-formaldehyde resin adds in system, coordinates the bond strength of the system of further increasing with silane coupling agent KH-560.
Performance Detection is carried out to high-performance modified chloroprene rubber adhesive of the present invention, its non-volatile content is 22-21.5%, viscosity is 3550-3700mPa.s, just glutinous shearing resistance is 1.2-1.45MPa, shearing resistance is 1.85-2.1MPa, and its properties meets HG/T3738-2004 standard, its harmful substance contents meets GB18583-2008 standard.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 70 parts, cis-1,4-polybutadiene rubber 15 parts, 5 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 15 parts, para-tert-butyl phenolic resin 3 parts, terpine resin 5 parts, nano silicon 1 part, nano aluminium oxide 5 parts, organobentonite 2 parts, white carbon black 12 parts, activated magnesia 3 parts, polystyrene 3.5 parts, ethylene thiourea 1 part, 8 parts, zinc oxide, ethyl acetate 30 parts, hexanaphthene 25 parts, methylcarbonate 60 parts, propylene glycol 30 parts, methylcyclopentane 10 parts, 120# solvent oil 35 parts, resorcinol-formaldehyde resin 0.5 part, 3.5 parts, anti-aging agent, cerium oxide 2 parts, silane coupling agent KH-5602.5 part, 3 parts, softening agent.
Embodiment 2
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 100 parts, cis-1,4-polybutadiene rubber 5 parts, 20 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 5 parts, para-tert-butyl phenolic resin 10 parts, terpine resin 2 parts, nano silicon 5 parts, nano aluminium oxide 1 part, organobentonite 8 parts, white carbon black 5 parts, activated magnesia 10 parts, polystyrene 1 part, ethylene thiourea 5 parts, 2 parts, zinc oxide, ethyl acetate 50 parts, hexanaphthene 10 parts, methylcarbonate 120 parts, propylene glycol 10 parts, methylcyclopentane 25 parts, 120# solvent oil 10 parts, resorcinol-formaldehyde resin 2 parts, anti-aging agent RD 1 part, cerium oxide 5 parts, silane coupling agent KH-5601 part, dioctyl sebacate 3 parts, butyl oleate 2 parts,
Wherein, described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is stearic acid, lauric acid, vinylformic acid, Sodium dodecylbenzene sulfonate, hexamethyldisilazane, vinyltriethoxysilane be by the mixture of any weight ratio.
Embodiment 3
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 90 parts, cis-1,4-polybutadiene rubber 12 parts, 11 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 11 parts, para-tert-butyl phenolic resin 6 parts, terpine resin 3.5 parts, nano silicon 3.8 parts, nano aluminium oxide 3.9 parts, organobentonite 5.2 parts, white carbon black 10 parts, activated magnesia 5.8 parts, polystyrene 2.6 parts, ethylene thiourea 3.2 parts, 6 parts, zinc oxide, ethyl acetate 40 parts, hexanaphthene 20 parts, methylcarbonate 89 parts, propylene glycol 24 parts, methylcyclopentane 19 parts, 120# solvent oil 25 parts, resorcinol-formaldehyde resin 1.1 parts, antioxidant A W0.2 part, anti-aging agent RD 0.3 part, antioxidant H 0.2 part, antioxidant 4010NA 0.5 part, antioxidant 4020 1.1 parts, cerium oxide 3.5 parts, silane coupling agent KH-5602 part, Octyl adipate 0.5 part, dioctyl sebacate 0.6 part, butyl oleate 0.3 part, trioctyl phosphate 0.6 part, epoxyoleic acid butyl ester 0.2 part, hexanodioic acid two (Butoxyethoxy second) ester 1 part, in Viscoat 295 0.4 part,
Wherein, the median size of described nano silicon is 15nm; The median size of described nano aluminium oxide is 35nm; The properties-correcting agent that described organobentonite uses is lauric acid, hexamethyldisilazane is the mixture of 3:2 by weight; Described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is hexamethyldisilazane.
Embodiment 4
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 93 parts, cis-1,4-polybutadiene rubber 9 parts, 14 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 10 parts, para-tert-butyl phenolic resin 7.5 parts, terpine resin 3.2 parts, nano silicon 4.2 parts, nano aluminium oxide 3.5 parts, hexamethyldisilazane modified alta-mud 6 parts, white carbon black 7 parts, activated magnesia 7 parts, polystyrene 1.9 parts, ethylene thiourea 4 parts, 5.2 parts, zinc oxide, ethyl acetate 42 parts, hexanaphthene 18 parts, methylcarbonate 91 parts, propylene glycol 21 parts, methylcyclopentane 21 parts, 120# solvent oil 21 parts, resorcinol-formaldehyde resin 1.6 parts, antioxidant 4010NA 1.8 parts, cerium oxide 4 parts, silane coupling agent KH-5601.6 part, Octyl adipate 1 part, dioctyl sebacate 2 parts, butyl oleate 1.5 parts,
Wherein, the median size of described nano silicon is 25nm; The median size of described nano aluminium oxide is 20nm; Described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is stearic acid, lauric acid, vinylformic acid, Sodium dodecylbenzene sulfonate, hexamethyldisilazane, vinyltriethoxysilane be by the mixture of any weight ratio.
Embodiment 5
The high-performance modified chloroprene rubber adhesive of one that the present invention proposes, its raw material comprises following component by weight: chloroprene rubber 92 parts, cis-1,4-polybutadiene rubber 10 parts, 12 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 10.6 parts, para-tert-butyl phenolic resin 7.2 parts, terpine resin 3.3 parts, nano silicon 4 parts, nano aluminium oxide 3.6 parts, lauric acid modified alta-mud 5.5 parts, white carbon black 8 parts, activated magnesia 6 parts, polystyrene 2.1 parts, ethylene thiourea 3.5 parts, 5.5 parts, zinc oxide, ethyl acetate 41 parts, hexanaphthene 18 parts, methylcarbonate 90 parts, propylene glycol 22 parts, methylcyclopentane 20 parts, 120# solvent oil 23.5 parts, resorcinol-formaldehyde resin 1.4 parts, antioxidant A W1 part, anti-aging agent RD 1 part, cerium oxide 3.6 parts, silane coupling agent KH-5601.8 part, epoxyoleic acid butyl ester 3 parts, adipic acid two (Butoxyethoxy second) ester 1.2 parts,
Wherein, the median size of described nano silicon is 20nm; The median size of described nano aluminium oxide is 28nm; Described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is stearic acid, lauric acid, vinylformic acid are the mixture of 2:4:3 by weight.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. a high-performance modified chloroprene rubber adhesive, it is characterized in that, its raw material comprises following component by weight: chloroprene rubber 70-100 part, cis-1,4-polybutadiene rubber 5-15 part, styrene-butadiene rubber(SBR) 5-20 part, alkylphenyl acid resin 5-15 part, para-tert-butyl phenolic resin 3-10 part, terpine resin 2-5 part, nano silicon 1-5 part, nano aluminium oxide 1-5 part, organobentonite 2-8 part, white carbon black 5-12 part, activated magnesia 3-10 part, polystyrene 1-3.5 part, ethylene thiourea 1-5 part, zinc oxide 2-8 part, ethyl acetate 30-50 part, hexanaphthene 10-25 part, methylcarbonate 60-120 part, propylene glycol 10-30 part, methylcyclopentane 10-25 part, 120# solvent oil 10-35 part, resorcinol-formaldehyde resin 0.5-2 part, anti-aging agent 1-3.5 part, cerium oxide 2-5 part, silane coupling agent KH-5601-2.5 part, softening agent 3-5 part.
2. high-performance modified chloroprene rubber adhesive according to claim 1, it is characterized in that, in its raw material, the weight ratio of chloroprene rubber, cis-1,4-polybutadiene rubber, styrene-butadiene rubber(SBR), alkylphenyl acid resin, para-tert-butyl phenolic resin, terpine resin is 87-94:8-13:9-16:9-12:5-8:3-3.8.
3. high-performance modified chloroprene rubber adhesive according to claim 1 or 2, it is characterized in that, in its raw material, the weight ratio of ethyl acetate, hexanaphthene, methylcarbonate, propylene glycol, methylcyclopentane, 120# solvent oil is 38-43:16-21:86-92:19-25:17-22:19-26.
4. high-performance modified chloroprene rubber adhesive according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: chloroprene rubber 90-93 part, cis-1,4-polybutadiene rubber 9-12 part, styrene-butadiene rubber(SBR) 11-14 part, alkylphenyl acid resin 10-11 part, para-tert-butyl phenolic resin 6-7.5 part, terpine resin 3.2-3.5 part, nano silicon 3.8-4.2 part, nano aluminium oxide 3.5-3.9 part, organobentonite 5.2-6 part, white carbon black 7-10 part, activated magnesia 5.8-7 part, polystyrene 1.9-2.6 part, ethylene thiourea 3.2-4 part, zinc oxide 5.2-6 part, ethyl acetate 40-42 part, hexanaphthene 18-20 part, methylcarbonate 89-91 part, propylene glycol 21-24 part, methylcyclopentane 19-21 part, 120# solvent oil 21-25 part, resorcinol-formaldehyde resin 1.1-1.6 part, anti-aging agent 1.8-2.3 part, cerium oxide 3.5-4 part, silane coupling agent KH-5601.6-2 part, softening agent 3.9-4.5 part.
5. high-performance modified chloroprene rubber adhesive according to any one of claim 1-4, it is characterized in that, its raw material comprises following component by weight: chloroprene rubber 92 parts, cis-1,4-polybutadiene rubber 10 parts, 12 parts, styrene-butadiene rubber(SBR), alkylphenyl acid resin 10.6 parts, para-tert-butyl phenolic resin 7.2 parts, terpine resin 3.3 parts, nano silicon 4 parts, nano aluminium oxide 3.6 parts, organobentonite 5.5 parts, white carbon black 8 parts, activated magnesia 6 parts, polystyrene 2.1 parts, ethylene thiourea 3.5 parts, 5.5 parts, zinc oxide, ethyl acetate 41 parts, hexanaphthene 18 parts, methylcarbonate 90 parts, propylene glycol 22 parts, methylcyclopentane 20 parts, 120# solvent oil 23.5 parts, resorcinol-formaldehyde resin 1.4 parts, 2 parts, anti-aging agent, cerium oxide 3.6 parts, silane coupling agent KH-5601.8 part, 4.2 parts, softening agent.
6. high-performance modified chloroprene rubber adhesive according to any one of claim 1-5, is characterized in that, the median size of described nano silicon is 15-25nm; The median size of described nano aluminium oxide is 20-35nm.
7. high-performance modified chloroprene rubber adhesive according to any one of claim 1-6, is characterized in that, the properties-correcting agent that described organobentonite uses is lauric acid, the mixture of a kind of in hexamethyldisilazane or two kinds.
8. high-performance modified chloroprene rubber adhesive according to any one of claim 1-7, is characterized in that, described anti-aging agent is one or more the mixture in antioxidant A W, anti-aging agent RD, antioxidant H, antioxidant 4010NA, antioxidant 4020.
9. high-performance modified chloroprene rubber adhesive according to any one of claim 1-8, it is characterized in that, described softening agent is one or more the mixture in Octyl adipate, dioctyl sebacate, butyl oleate, trioctyl phosphate, epoxyoleic acid butyl ester, hexanodioic acid two (Butoxyethoxy second) ester, Viscoat 295.
10. high-performance modified chloroprene rubber adhesive according to any one of claim 1-9, is characterized in that, described cerium oxide is modified oxidized cerium; The properties-correcting agent that described modified oxidized cerium uses is stearic acid, one or more mixture in lauric acid, vinylformic acid, Sodium dodecylbenzene sulfonate, hexamethyldisilazane, vinyltriethoxysilane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510623893.XA CN105238298A (en) | 2015-09-25 | 2015-09-25 | High-performance modified chloroprene rubber adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510623893.XA CN105238298A (en) | 2015-09-25 | 2015-09-25 | High-performance modified chloroprene rubber adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105238298A true CN105238298A (en) | 2016-01-13 |
Family
ID=55036132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510623893.XA Pending CN105238298A (en) | 2015-09-25 | 2015-09-25 | High-performance modified chloroprene rubber adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105238298A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108115957A (en) * | 2016-11-29 | 2018-06-05 | 江苏天凌体育用品有限公司 | A kind of fissureless machine patch basketball preparation method of not degumming |
| CN108192528A (en) * | 2017-11-23 | 2018-06-22 | 吉安迅达科技有限公司 | A kind of environmental protection one side glue and preparation method thereof |
| CN108929647A (en) * | 2018-08-02 | 2018-12-04 | 界首市盛泽鞋业有限公司 | A kind of low temperature resistant snow boot adhesive preparation method |
| CN109266270A (en) * | 2017-07-17 | 2019-01-25 | 中国石油天然气股份有限公司 | A kind of adhesive and preparation method and application |
| CN109971393A (en) * | 2019-03-26 | 2019-07-05 | 福清市南宾树脂有限公司 | A kind of neoprene glue spraying and preparation method thereof that the high temperature resistant operating time is long |
| CN110982016A (en) * | 2019-12-18 | 2020-04-10 | 广东裕田霸力科技股份有限公司 | Environment-friendly high-performance hydrolysis-resistant and aging-resistant TPR (thermal Plastic rubber) treating agent grafted through composite |
| CN113136152A (en) * | 2021-03-26 | 2021-07-20 | 湖南浩森胶业有限公司 | High-stability electronic adhesive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101990A (en) * | 2010-11-04 | 2011-06-22 | 博野县华月输送带产业科技发展有限公司 | Special adhesive layer and preparation method thereof |
| CN102492382A (en) * | 2011-11-16 | 2012-06-13 | 北京天山新材料技术股份有限公司 | Environmentally-friendly double-component high temperature-resistant conveyer belt bonding agent and preparation method thereof |
| CN103265911A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing ultra-fine aluminum silicate for packaging and preparation method thereof |
| CN103992764A (en) * | 2014-04-29 | 2014-08-20 | 天长永泰密封材料有限公司 | High viscosity rapid room temperature curing sealant |
-
2015
- 2015-09-25 CN CN201510623893.XA patent/CN105238298A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101990A (en) * | 2010-11-04 | 2011-06-22 | 博野县华月输送带产业科技发展有限公司 | Special adhesive layer and preparation method thereof |
| CN102492382A (en) * | 2011-11-16 | 2012-06-13 | 北京天山新材料技术股份有限公司 | Environmentally-friendly double-component high temperature-resistant conveyer belt bonding agent and preparation method thereof |
| CN103265911A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing ultra-fine aluminum silicate for packaging and preparation method thereof |
| CN103992764A (en) * | 2014-04-29 | 2014-08-20 | 天长永泰密封材料有限公司 | High viscosity rapid room temperature curing sealant |
Non-Patent Citations (2)
| Title |
|---|
| 凌辉等: "烷基苯酸树脂在氯丁型胶粘剂中的应用", 《粘接》 * |
| 孙传尧主编: "《选矿工程师手册》", 31 March 2015, 冶金工业出版社 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108115957A (en) * | 2016-11-29 | 2018-06-05 | 江苏天凌体育用品有限公司 | A kind of fissureless machine patch basketball preparation method of not degumming |
| CN109266270A (en) * | 2017-07-17 | 2019-01-25 | 中国石油天然气股份有限公司 | A kind of adhesive and preparation method and application |
| CN109266270B (en) * | 2017-07-17 | 2021-08-03 | 中国石油天然气股份有限公司 | Adhesive, preparation method and application |
| CN108192528A (en) * | 2017-11-23 | 2018-06-22 | 吉安迅达科技有限公司 | A kind of environmental protection one side glue and preparation method thereof |
| CN108929647A (en) * | 2018-08-02 | 2018-12-04 | 界首市盛泽鞋业有限公司 | A kind of low temperature resistant snow boot adhesive preparation method |
| CN108929647B (en) * | 2018-08-02 | 2020-09-08 | 界首市盛泽鞋业有限公司 | Preparation method of adhesive for low-temperature-resistant snowfield shoes |
| CN109971393A (en) * | 2019-03-26 | 2019-07-05 | 福清市南宾树脂有限公司 | A kind of neoprene glue spraying and preparation method thereof that the high temperature resistant operating time is long |
| CN110982016A (en) * | 2019-12-18 | 2020-04-10 | 广东裕田霸力科技股份有限公司 | Environment-friendly high-performance hydrolysis-resistant and aging-resistant TPR (thermal Plastic rubber) treating agent grafted through composite |
| CN110982016B (en) * | 2019-12-18 | 2020-09-25 | 广东裕田霸力科技股份有限公司 | Environment-friendly high-performance hydrolysis-resistant and aging-resistant TPR (thermal Plastic rubber) treating agent grafted through composite |
| CN113136152A (en) * | 2021-03-26 | 2021-07-20 | 湖南浩森胶业有限公司 | High-stability electronic adhesive |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105238298A (en) | High-performance modified chloroprene rubber adhesive | |
| CN101967354B (en) | Low whitening alpha-cyanoacrylate adhesive | |
| CN101967256B (en) | Environment-friendly aqueous sealant for container | |
| CN105238299A (en) | Weather-resistance and low-temperature-resistance chloroprene rubber adhesive | |
| EP3854610B1 (en) | Pneumatic tire | |
| CN103435858B (en) | Tyre inner liner rubber and preparation method thereof | |
| CN102911625B (en) | Thermoplastic spacing bar and preparation method thereof | |
| CN106634769A (en) | High-intensity transparent bonding agent and preparation method thereof | |
| CN105111533A (en) | Anti-aging, oil resistant and high strength composite cable material | |
| JP2019172957A (en) | Rubber composition for tire tread and tire including the same | |
| KR101182208B1 (en) | Tread rubber composition and tire manufactured by using the same | |
| JP2008285626A (en) | Rubber composition for tire and pneumatic tire using the same | |
| JP2012201858A5 (en) | ||
| CN103602285B (en) | oil-resistant liquid sealant and preparation method thereof | |
| KR20130075243A (en) | Tread rubber composition and tire manufactured by using the same | |
| JP5687661B2 (en) | Rubber composition for tire and pneumatic tire | |
| JP5662388B2 (en) | Rubber composition for tire and studless tire | |
| KR101153384B1 (en) | Rubber composition for tire tread and tire manufactured by using the same | |
| KR101709217B1 (en) | Rubber composition for tire tread and tire manufactured by using the same | |
| CN105295795A (en) | Antistatic nano rubber solution | |
| JP6046213B2 (en) | Rubber composition for tire tread and tire produced therefrom | |
| KR101692858B1 (en) | Rubber composition for tire tread and tire manufactured by using the same | |
| JP4823882B2 (en) | Rubber composition for inner liner and tire having inner liner using the same | |
| CN105199651A (en) | Oxidation-resistant high-strength binder and preparation method thereof | |
| KR100477432B1 (en) | Tire under tread rubber composition involving the function of the cap ply |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160113 |