CN105199651A - Oxidation-resistant high-strength binder and preparation method thereof - Google Patents
Oxidation-resistant high-strength binder and preparation method thereof Download PDFInfo
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- CN105199651A CN105199651A CN201510706566.0A CN201510706566A CN105199651A CN 105199651 A CN105199651 A CN 105199651A CN 201510706566 A CN201510706566 A CN 201510706566A CN 105199651 A CN105199651 A CN 105199651A
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Abstract
The invention discloses an oxidation-resistant high-strength binder and a preparation method thereof. The binder is prepared from the following raw materials by weight: 60 to 80 parts of polyurethane resin, 27 to 40 parts of methyl etherified amino resin, 18 to 25 parts of rosin pentaerythritol ester, 5 to 12 parts of vinyl chloride-vinyl acetate resin, 8 to 18 parts of tetraethylenepentamine, 6 to 13 parts of an anti-oxidant, 4 to 10 parts of a light stabilizing agent, 8 to 17 parts of fluorite powder, 6 to 14 parts of alumina, 5 to 11 parts of calcium persulfate, 2 to 6 parts of Tween-85, 25 to 40 parts of acetic ester, 12 to 26 parts of cyclohexanone and 8 to 16 parts of propylene glycol. The binder prepared in the invention has high tensile bonding strength and maintains good tensile bonding strength after thermal ageing at 136 DEG C for 168 h, showing good overall performance.
Description
Technical field
The invention belongs to Material Field, particularly high-strength binding agent of a kind of resistance to oxidation and preparation method thereof.
Background technology
Binding agent is also called binding agent, tackiness agent, is two or more homogeneity or heterogeneous object (or material) to be closely glued together, and has the material of sufficient intensity after solidification in junction.The application of binding agent has been goed deep in the middle of the life of people, is one of indispensable important source material of all trades and professions.
Along with the development of industrial economy, the performance requriements of people to binding agent is more and more higher.Traditional binder component is single, and special performance cannot be provided to meet the application demand of special occasions and environment, such as, to resistance to ultraviolet, and the performance such as resistance to oxidation, high bond strength, high abrasion, high tenacity, environmental protection.Therefore, in order to make up the defect of some binding agents in performance and deficiency, be badly in need of developing novel functional binding agent.
Summary of the invention
The technical problem solved is: in order to solve not resistance to oxidation, cohesive strength at least one technical problem not high of conventional binders, provide high-strength binding agent of a kind of resistance to oxidation and preparation method thereof.
Technical scheme: in order to solve the problem, the invention provides the high-strength binding agent of resistance to oxidation, is prepared from, counts by weight by following raw material:
Urethane resin 60 ~ 80 parts, 27 ~ 40 parts, methyl-etherified aminoresin, pentalyn 18 ~ 25 parts, vinyl chloride-vinyl acetate resin 5 ~ 12 parts, tetraethylene pentamine 8 ~ 18 parts, 6 ~ 13 parts, oxidation inhibitor, photostabilizer 4 ~ 10 parts, Fluorspar Powder 8 ~ 17 parts, 6 ~ 14 parts, aluminum oxide, persulfuric acid calcium 5 ~ 11 parts, polysorbate85 2 ~ 6 parts, vinyl acetic monomer 25 ~ 40 parts, pimelinketone 12 ~ 26 parts and propylene glycol 8 ~ 16 parts.
Preferably, the high-strength binding agent of described resistance to oxidation, is prepared from by following raw material, counts by weight:
Urethane resin 64 ~ 80 parts, 27 ~ 35 parts, methyl-etherified aminoresin, pentalyn 20 ~ 25 parts, vinyl chloride-vinyl acetate resin 6 ~ 12 parts, tetraethylene pentamine 10 ~ 18 parts, 6 ~ 13 parts, oxidation inhibitor, photostabilizer 4 ~ 10 parts, Fluorspar Powder 9 ~ 17 parts, 7 ~ 14 parts, aluminum oxide, persulfuric acid calcium 5 ~ 9 parts, polysorbate85 3 ~ 6 parts, vinyl acetic monomer 28 ~ 40 parts, pimelinketone 15 ~ 26 parts and propylene glycol 8 ~ 14 parts.
Preferably, the high-strength binding agent of described resistance to oxidation, is prepared from by following raw material, counts by weight:
Urethane resin 73 parts, 30 parts, methyl-etherified aminoresin, pentalyn 24 parts, vinyl chloride-vinyl acetate resin 10 parts, tetraethylene pentamine 13 parts, 11 parts, oxidation inhibitor, photostabilizer 9 parts, Fluorspar Powder 14 parts, 12 parts, aluminum oxide, persulfuric acid calcium 8 parts, polysorbate85 4 parts, vinyl acetic monomer 36 parts, pimelinketone 18 parts and propylene glycol 13 parts.
Preferably, described oxidation inhibitor is oxidation inhibitor 5057.
Preferably, described photostabilizer is photostabilizer 622.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of certainweight number, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 ~ 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
The present invention has following beneficial effect: the binding agent prepared by the present invention has higher stretching adhesive strength, and still keeps good through 136 DEG C × 168h thermal ageing back draft adhesive strength, shows good over-all properties.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, invention preferred embodiment is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
Embodiment 1
The high-strength binding agent of resistance to oxidation, is prepared from by following raw material, is by weight:
Urethane resin 60 kilograms, 27 kilograms, methyl-etherified aminoresin, pentalyn 18 kilograms, vinyl chloride-vinyl acetate resin 5 kilograms, tetraethylene pentamine 8 kilograms, 6 kilograms, oxidation inhibitor, photostabilizer 4 kilograms, Fluorspar Powder 8 kilograms, 6 kilograms, aluminum oxide, persulfuric acid calcium 5 kilograms, polysorbate85 2 kilograms, vinyl acetic monomer 25 kilograms, pimelinketone 12 kilograms and propylene glycol 8 kilograms.Described oxidation inhibitor is irgasfos 168; Described photostabilizer is photostabilizer 770.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of above-mentioned weight, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
Embodiment 2
The high-strength binding agent of resistance to oxidation, is prepared from by following raw material, is by weight:
Urethane resin 80 kilograms, 40 kilograms, methyl-etherified aminoresin, pentalyn 25 kilograms, vinyl chloride-vinyl acetate resin 12 kilograms, tetraethylene pentamine 18 kilograms, 13 kilograms, oxidation inhibitor, photostabilizer 10 kilograms, Fluorspar Powder 17 kilograms, 14 kilograms, aluminum oxide, persulfuric acid calcium 11 kilograms, polysorbate85 6 kilograms, vinyl acetic monomer 40 kilograms, pimelinketone 26 kilograms and propylene glycol 16 kilograms.Described oxidation inhibitor is antioxidant 264; Described photostabilizer is photostabilizer 622.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of above-mentioned weight, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
Embodiment 3
The high-strength binding agent of resistance to oxidation, is prepared from by following raw material, is by weight:
Urethane resin 70 kilograms, 33 kilograms, methyl-etherified aminoresin, pentalyn 21 kilograms, vinyl chloride-vinyl acetate resin 8 kilograms, tetraethylene pentamine 13 kilograms, 9 kilograms, oxidation inhibitor, photostabilizer 7 kilograms, Fluorspar Powder 13 kilograms, 10 kilograms, aluminum oxide, persulfuric acid calcium 8 kilograms, polysorbate85 4 kilograms, vinyl acetic monomer 32 kilograms, pimelinketone 19 kilograms and propylene glycol 12 kilograms.Described oxidation inhibitor is oxidation inhibitor 5057; Described photostabilizer is photostabilizer 622.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of above-mentioned weight, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 ~ 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
Embodiment 4
The high-strength binding agent of resistance to oxidation, is prepared from by following raw material, is by weight:
Urethane resin 73 kilograms, 30 kilograms, methyl-etherified aminoresin, pentalyn 24 kilograms, vinyl chloride-vinyl acetate resin 10 kilograms, tetraethylene pentamine 13 kilograms, 11 kilograms, oxidation inhibitor, photostabilizer 9 kilograms, Fluorspar Powder 14 kilograms, 12 kilograms, aluminum oxide, persulfuric acid calcium 8 kilograms, polysorbate85 4 kilograms, vinyl acetic monomer 36 kilograms, pimelinketone 18 kilograms and propylene glycol 13 kilograms.Described oxidation inhibitor is oxidation inhibitor 5057; Described photostabilizer is photostabilizer 622.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of above-mentioned weight, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 ~ 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
Embodiment 5
The high-strength binding agent of resistance to oxidation, is prepared from by following raw material, is by weight:
Urethane resin 64 kilograms, 35 kilograms, methyl-etherified aminoresin, pentalyn 20 kilograms, vinyl chloride-vinyl acetate resin 6 kilograms, tetraethylene pentamine 10 kilograms, 8 kilograms, oxidation inhibitor, photostabilizer 7 kilograms, Fluorspar Powder 9 kilograms, 7 kilograms, aluminum oxide, persulfuric acid calcium 9 kilograms, polysorbate85 3 kilograms, vinyl acetic monomer 28 kilograms, pimelinketone 15 kilograms and propylene glycol 14 kilograms.Described oxidation inhibitor is oxidation inhibitor 5057; Described photostabilizer is photostabilizer 622.
The preparation method of the high-strength binding agent of described resistance to oxidation, comprises the steps:
Take the urethane resin of above-mentioned weight, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 ~ 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
After testing, the performance test results of the binding agent prepared by each embodiment is as following table:
As seen from the above table, the binding agent prepared by the present invention has more excellent stretching adhesive strength, and still keeps good through 136 DEG C × 168h thermal ageing back draft adhesive strength, shows good over-all properties.
Claims (6)
1. the high-strength binding agent of resistance to oxidation, is characterized in that, is prepared from, counts by weight by following raw material:
Urethane resin 60 ~ 80 parts, 27 ~ 40 parts, methyl-etherified aminoresin, pentalyn 18 ~ 25 parts, vinyl chloride-vinyl acetate resin 5 ~ 12 parts, tetraethylene pentamine 8 ~ 18 parts, 6 ~ 13 parts, oxidation inhibitor, photostabilizer 4 ~ 10 parts, Fluorspar Powder 8 ~ 17 parts, 6 ~ 14 parts, aluminum oxide, persulfuric acid calcium 5 ~ 11 parts, polysorbate85 2 ~ 6 parts, vinyl acetic monomer 25 ~ 40 parts, pimelinketone 12 ~ 26 parts and propylene glycol 8 ~ 16 parts.
2. the high-strength binding agent of resistance to oxidation according to claim 1, is characterized in that, is prepared from, counts by weight by following raw material:
Urethane resin 64 ~ 80 parts, 27 ~ 35 parts, methyl-etherified aminoresin, pentalyn 20 ~ 25 parts, vinyl chloride-vinyl acetate resin 6 ~ 12 parts, tetraethylene pentamine 10 ~ 18 parts, 6 ~ 13 parts, oxidation inhibitor, photostabilizer 4 ~ 10 parts, Fluorspar Powder 9 ~ 17 parts, 7 ~ 14 parts, aluminum oxide, persulfuric acid calcium 5 ~ 9 parts, polysorbate85 3 ~ 6 parts, vinyl acetic monomer 28 ~ 40 parts, pimelinketone 15 ~ 26 parts and propylene glycol 8 ~ 14 parts.
3. the high-strength binding agent of resistance to oxidation according to claim 1, is characterized in that, is prepared from, counts by weight by following raw material:
Urethane resin 73 parts, 30 parts, methyl-etherified aminoresin, pentalyn 24 parts, vinyl chloride-vinyl acetate resin 10 parts, tetraethylene pentamine 13 parts, 11 parts, oxidation inhibitor, photostabilizer 9 parts, Fluorspar Powder 14 parts, 12 parts, aluminum oxide, persulfuric acid calcium 8 parts, polysorbate85 4 parts, vinyl acetic monomer 36 parts, pimelinketone 18 parts and propylene glycol 13 parts.
4. the high-strength binding agent of resistance to oxidation according to claim 1, is characterized in that, described oxidation inhibitor is oxidation inhibitor 5057.
5. the high-strength binding agent of resistance to oxidation according to claim 1, is characterized in that, described photostabilizer is photostabilizer 622.
6. the preparation method of the high-strength binding agent of resistance to oxidation as claimed in claim 1, is characterized in that, comprise the steps:
Take the urethane resin of certainweight number, methyl-etherified aminoresin, pentalyn, vinyl chloride-vinyl acetate resin, tetraethylene pentamine, oxidation inhibitor, photostabilizer, Fluorspar Powder, aluminum oxide, persulfuric acid calcium, polysorbate85, vinyl acetic monomer, pimelinketone and propylene glycol, then all raw materials are placed in container, at 45 ~ 50 DEG C, with the rotating speed mixing and stirring of 220rpm, can pack after crossing 150 mesh sieves after cooling.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510706566.0A CN105199651B (en) | 2015-10-27 | 2015-10-27 | High-strength binding agent of resistance to oxidation and preparation method thereof |
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| CN201510706566.0A CN105199651B (en) | 2015-10-27 | 2015-10-27 | High-strength binding agent of resistance to oxidation and preparation method thereof |
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| CN105199651A true CN105199651A (en) | 2015-12-30 |
| CN105199651B CN105199651B (en) | 2017-11-28 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109352539A (en) * | 2018-10-15 | 2019-02-19 | 昆山佳研磨具科技有限公司 | Nonwoven abrasive article and its application |
| CN114836087A (en) * | 2022-03-09 | 2022-08-02 | 安丹达工业技术(上海)有限公司 | Composition for welding PVC (polyvinyl chloride) film and TPU (thermoplastic polyurethane) film, preparation method and welding method |
Citations (4)
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| CN101701143A (en) * | 2009-09-23 | 2010-05-05 | 上海鼎道科技发展有限公司 | Ultraviolet light curing adhesive and preparation method thereof |
| CN102796482A (en) * | 2012-08-30 | 2012-11-28 | 郑州辰龙铝箔有限公司 | High-temperature-resistant heat-seal adhesive applied to medicinal aluminum foil packaging |
| CN102965035A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Calcium sulfate crystal whisker modified adhesive for packaging |
| CN104164207A (en) * | 2014-07-23 | 2014-11-26 | 安徽雪峰木业有限公司 | Fast-cured hot melt adhesive for pencil rod preparation |
-
2015
- 2015-10-27 CN CN201510706566.0A patent/CN105199651B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701143A (en) * | 2009-09-23 | 2010-05-05 | 上海鼎道科技发展有限公司 | Ultraviolet light curing adhesive and preparation method thereof |
| CN102796482A (en) * | 2012-08-30 | 2012-11-28 | 郑州辰龙铝箔有限公司 | High-temperature-resistant heat-seal adhesive applied to medicinal aluminum foil packaging |
| CN102965035A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Calcium sulfate crystal whisker modified adhesive for packaging |
| CN104164207A (en) * | 2014-07-23 | 2014-11-26 | 安徽雪峰木业有限公司 | Fast-cured hot melt adhesive for pencil rod preparation |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109352539A (en) * | 2018-10-15 | 2019-02-19 | 昆山佳研磨具科技有限公司 | Nonwoven abrasive article and its application |
| CN114836087A (en) * | 2022-03-09 | 2022-08-02 | 安丹达工业技术(上海)有限公司 | Composition for welding PVC (polyvinyl chloride) film and TPU (thermoplastic polyurethane) film, preparation method and welding method |
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| CN105199651B (en) | 2017-11-28 |
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