WO2017201792A1 - Waterproof and mildewproof coating adhesive - Google Patents

Waterproof and mildewproof coating adhesive Download PDF

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Publication number
WO2017201792A1
WO2017201792A1 PCT/CN2016/086979 CN2016086979W WO2017201792A1 WO 2017201792 A1 WO2017201792 A1 WO 2017201792A1 CN 2016086979 W CN2016086979 W CN 2016086979W WO 2017201792 A1 WO2017201792 A1 WO 2017201792A1
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WO
WIPO (PCT)
Prior art keywords
parts
waterproof
butanediol
acrylate
coating adhesive
Prior art date
Application number
PCT/CN2016/086979
Other languages
French (fr)
Chinese (zh)
Inventor
黄金生
Original Assignee
黄金生
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 黄金生 filed Critical 黄金生
Publication of WO2017201792A1 publication Critical patent/WO2017201792A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

Definitions

  • the invention relates to the technical field of chemical products, in particular to waterproof and mildew resistant glue.
  • Gluing has a very large role in production and life. It is widely used in various fields.
  • the coating film formed by gluing can play a role in decoration, protection and labeling.
  • Most of the coatings on the market are simple to make and sell. It is cheap but has certain toxic and side effects. As a household, it will cause certain harm to the human body.
  • the glue application function is relatively simple, and the scope of application is not wide. It cannot be used in many fields, and its limitations are very large.
  • the waterproof mildew-resistant coating comprises the following components by weight: 40-80 parts of isopropyl acrylate, 12-16 parts of epoxy resin, 40-50 parts of ethylene glycol monopropyl ether, acrylic acid Ethyl ester 20-40 parts, benzoyl peroxide 12-24 parts, dibutyl phthalate 10-20 parts, polyester 8-16 parts, butanediol acrylate 20-30 parts, trimethylol 4 to 6 parts of propane, 10 to 20 parts of butanediol, 10 to 20 parts of methoxyphenol, 8 to 12 parts of acrylamide, and 10 to 20 parts of styrene.
  • the waterproof and mildew-proof coating provided by the invention is simple to manufacture, and the raw materials used are non-toxic, the use effect is good, and the environment is environmentally friendly, and the surface coating of the leather can form a strong bright coating film.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

A waterproof and mildewproof coating adhesive, comprising the following components in parts by weight: 40-80 parts of isopropyl acrylate, 12-16 parts of epoxy resin, 40-50 parts of ethylene glycol monopropyl ether, 20-40 parts of ethyl acrylate, 12-24 parts of benzoyl peroxide, 10-20 parts of dibutyl phthalate, 8-16 parts of polyester, 20-30 parts of butanediol acrylic acid ester, 4-6 parts of trimethylolpropane, 10-20 parts of butanediol, 10-20 parts of methoxyphenol, 8-12 parts of acrylamide, and 10-20 parts of styrene. The waterproof and mildewproof coating adhesive can form a firm and bright film when coated on a leather surface.

Description

防水防霉涂胶Waterproof and mildew resistant glue 技术领域Technical field
本发明涉及一种化学用品的技术领域，具体涉及防水防霉涂胶。The invention relates to the technical field of chemical products, in particular to waterproof and mildew resistant glue.
背景技术Background technique
涂胶在生产和生活中的作用非常大，广泛应用与各个领域，涂胶形成的涂膜可对物体起到装饰、保护和标致作用，目前市面上的大部分涂胶虽然制作简单、售价便宜但同时带有一定的毒副作用，作为家用的话会对人体产生一定危害，且涂胶功能比较单一，适用范围不广，不能用于很多领域，局限性很大。Gluing has a very large role in production and life. It is widely used in various fields. The coating film formed by gluing can play a role in decoration, protection and labeling. Most of the coatings on the market are simple to make and sell. It is cheap but has certain toxic and side effects. As a household, it will cause certain harm to the human body. The glue application function is relatively simple, and the scope of application is not wide. It cannot be used in many fields, and its limitations are very large.
发明内容Summary of the invention
本发明的目的提供防水防霉涂胶，解决上述现有技术问题中的一个或者多个。It is an object of the present invention to provide a water and mildew resistant glue that addresses one or more of the above prior art problems.
根据本发明的一个方面，防水防霉涂胶，包括如下重量份的组分，丙烯酸异丙酯40～80份，环氧树脂12～16份，乙二醇单丙醚40～50份，丙烯酸乙酯20～40份，过氧化苯甲酰12～24份，邻苯二甲酸二丁酯10～20份，聚酯8～16份，丁二醇丙烯酸酯20～30份，三羟甲基丙烷4～6份，丁二醇10～20份，甲氧基苯酚10～20份，丙烯酰胺8～12份，苯乙烯10～20份。According to one aspect of the invention, the waterproof mildew-resistant coating comprises the following components by weight: 40-80 parts of isopropyl acrylate, 12-16 parts of epoxy resin, 40-50 parts of ethylene glycol monopropyl ether, acrylic acid Ethyl ester 20-40 parts, benzoyl peroxide 12-24 parts, dibutyl phthalate 10-20 parts, polyester 8-16 parts, butanediol acrylate 20-30 parts, trimethylol 4 to 6 parts of propane, 10 to 20 parts of butanediol, 10 to 20 parts of methoxyphenol, 8 to 12 parts of acrylamide, and 10 to 20 parts of styrene.
本发明提供的防水防霉涂胶，制作简单，采用的生产原料选择无毒性的，的使用效果好，环保，作用于皮革表面涂饰可形成坚固的光亮涂膜。The waterproof and mildew-proof coating provided by the invention is simple to manufacture, and the raw materials used are non-toxic, the use effect is good, and the environment is environmentally friendly, and the surface coating of the leather can form a strong bright coating film.
具体实施方式detailed description
实施例1Example 1
将丙烯酸异丙酯40份，环氧树脂12份，乙二醇单丙醚40份，丙烯酸乙酯20份，过氧化苯甲酰12份，邻苯二甲酸二丁酯10份，聚酯8份，丁二醇丙烯酸酯20份，三羟甲基丙烷4份，丁二醇10份，甲氧基苯酚10份， 丙烯酰胺8份，苯乙烯10份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。40 parts of isopropyl acrylate, 12 parts of epoxy resin, 40 parts of ethylene glycol monopropyl ether, 20 parts of ethyl acrylate, 12 parts of benzoyl peroxide, 10 parts of dibutyl phthalate, polyester 8 Parts, 20 parts of butanediol acrylate, 4 parts of trimethylolpropane, 10 parts of butanediol, 10 parts of methoxyphenol, 8 parts of acrylamide, 10 parts of styrene were placed in the reactor, stirring was continued, and after mixing, the mixture was heated to 65 ° C, and the reaction was carried out twice at a speed of 16 m/min under a UV lamp of 200 W/cm to obtain a product.
实施例2Example 2
将丙烯酸异丙酯60份，环氧树脂14份，乙二醇单丙醚45份，丙烯酸乙酯30份，过氧化苯甲酰18份，邻苯二甲酸二丁酯15份，聚酯12份，丁二醇丙烯酸酯25份，三羟甲基丙烷5份，丁二醇15份，甲氧基苯酚15份，丙烯酰胺10份，苯乙烯15份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。60 parts of isopropyl acrylate, 14 parts of epoxy resin, 45 parts of ethylene glycol monopropyl ether, 30 parts of ethyl acrylate, 18 parts of benzoyl peroxide, 15 parts of dibutyl phthalate, polyester 12 Parts, 25 parts of butanediol acrylate, 5 parts of trimethylolpropane, 15 parts of butanediol, 15 parts of methoxyphenol, 10 parts of acrylamide, 15 parts of styrene were placed in the reactor, stirring was continued, mixing After completely heating to 65 ° C and passing through the reaction twice at a speed of 16 m/min under a UV lamp of 200 W/cm, the product was obtained.
实施例3Example 3
将丙烯酸异丙酯80份，环氧树脂16份，乙二醇单丙醚50份，丙烯酸乙酯40份，过氧化苯甲酰24份，邻苯二甲酸二丁酯20份，聚酯16份，丁二醇丙烯酸酯30份，三羟甲基丙烷6份，丁二醇20份，甲氧基苯酚10～20份，丙烯酰胺12份，苯乙烯20份放入反应器中，不断搅拌，混合完全后加热至65℃，以16m/min的速度在200W/cm的紫外灯下通过反应两次后，即得产品。80 parts of isopropyl acrylate, 16 parts of epoxy resin, 50 parts of ethylene glycol monopropyl ether, 40 parts of ethyl acrylate, 24 parts of benzoyl peroxide, 20 parts of dibutyl phthalate, polyester 16 Parts, 30 parts of butanediol acrylate, 6 parts of trimethylolpropane, 20 parts of butanediol, 10-20 parts of methoxyphenol, 12 parts of acrylamide, 20 parts of styrene were placed in the reactor, stirring constantly After the mixture was completely heated to 65 ° C and passed through a reaction at a speed of 16 m/min under a UV lamp of 200 W/cm twice, the product was obtained.
以上所述仅是本发明的优选方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。 The above is only a preferred mode of the present invention, and it should be noted that various similar modifications and improvements can be made by those skilled in the art without departing from the inventive concept. Within the scope of protection of the present invention.

Claims (1)

  1. 防水防霉涂胶，其特征在于：包括如下重量份的组分，丙烯酸异丙酯40～80份，环氧树脂12～16份，乙二醇单丙醚40～50份，丙烯酸乙酯20～40份，过氧化苯甲酰12～24份，邻苯二甲酸二丁酯10～20份，聚酯8～16份，丁二醇丙烯酸酯20～30份，三羟甲基丙烷4～6份，丁二醇10～20份，甲氧基苯酚10～20份，丙烯酰胺8～12份，苯乙烯10～20份。 Waterproof and mildew resistant glue, characterized in that it comprises the following components by weight, 40-80 parts of isopropyl acrylate, 12-16 parts of epoxy resin, 40-50 parts of ethylene glycol monopropyl ether, and ethyl acrylate 20 ～40 parts, 12 to 24 parts of benzoyl peroxide, 10 to 20 parts of dibutyl phthalate, 8 to 16 parts of polyester, 20 to 30 parts of butanediol acrylate, and 3 to 3 parts of trimethylolpropane 6 parts, 10 to 20 parts of butanediol, 10 to 20 parts of methoxyphenol, 8 to 12 parts of acrylamide, and 10 to 20 parts of styrene.
PCT/CN2016/086979 2016-05-21 2016-06-24 Waterproof and mildewproof coating adhesive WO2017201792A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610340499.X 2016-05-21
CN201610340499.XA CN105778697A (en) 2016-05-21 2016-05-21 Fireproof mould-proof coating rubber

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105754393A (en) * 2016-05-21 2016-07-13 黄金生 Waterproof coating adhesive
WO2020019163A1 (en) * 2018-07-24 2020-01-30 江苏科力斯通新材料有限公司 Novel composite material

Citations (10)

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CN1083842A (en) * 1993-07-22 1994-03-16 浙江大学 Emulsion type adhesive for sticking paper to plastics and preparation method thereof
CN103224756A (en) * 2013-04-22 2013-07-31 苏州凹凸彩印厂 Glue used for hot-stamping printing
CN103571406A (en) * 2013-10-25 2014-02-12 北京天山新材料技术股份有限公司 High-elasticity room temperature rapidly cured acrylic ester structure adhesive and preparation method thereof
CN104212391A (en) * 2014-08-26 2014-12-17 安徽神舟飞船胶业有限公司 Formula and preparation method of epoxy resin-acrylate copolymerized adhesive
CN105062376A (en) * 2015-08-20 2015-11-18 巢湖子阳电器有限公司 Glue for assembling main air chamber of bubble generator of washing machine
CN105086847A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Environment-friendly nontoxic glue
CN105086907A (en) * 2015-09-30 2015-11-25 佛山市日丰企业有限公司 Mildew-proof sealant and preparation method thereof
CN105086842A (en) * 2015-08-10 2015-11-25 张相蓉 High-temperature-resistant epoxy sealant
CN105086849A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Antistatic environment-friendly glue
CN105419659A (en) * 2015-12-21 2016-03-23 青岛精石通精密机械制造有限公司 High-efficient environment-friendly glue

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CN1083842A (en) * 1993-07-22 1994-03-16 浙江大学 Emulsion type adhesive for sticking paper to plastics and preparation method thereof
CN103224756A (en) * 2013-04-22 2013-07-31 苏州凹凸彩印厂 Glue used for hot-stamping printing
CN103571406A (en) * 2013-10-25 2014-02-12 北京天山新材料技术股份有限公司 High-elasticity room temperature rapidly cured acrylic ester structure adhesive and preparation method thereof
CN104212391A (en) * 2014-08-26 2014-12-17 安徽神舟飞船胶业有限公司 Formula and preparation method of epoxy resin-acrylate copolymerized adhesive
CN105086842A (en) * 2015-08-10 2015-11-25 张相蓉 High-temperature-resistant epoxy sealant
CN105062376A (en) * 2015-08-20 2015-11-18 巢湖子阳电器有限公司 Glue for assembling main air chamber of bubble generator of washing machine
CN105086847A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Environment-friendly nontoxic glue
CN105086849A (en) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 Antistatic environment-friendly glue
CN105086907A (en) * 2015-09-30 2015-11-25 佛山市日丰企业有限公司 Mildew-proof sealant and preparation method thereof
CN105419659A (en) * 2015-12-21 2016-03-23 青岛精石通精密机械制造有限公司 High-efficient environment-friendly glue

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