CN110205038A - A kind of environment-friendly type aqueous gluing preparation process - Google Patents
A kind of environment-friendly type aqueous gluing preparation process Download PDFInfo
- Publication number
- CN110205038A CN110205038A CN201910528925.6A CN201910528925A CN110205038A CN 110205038 A CN110205038 A CN 110205038A CN 201910528925 A CN201910528925 A CN 201910528925A CN 110205038 A CN110205038 A CN 110205038A
- Authority
- CN
- China
- Prior art keywords
- parts
- added
- dimethylbenzene
- mixed
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a kind of environment-friendly type aqueous gluing preparation processes, it is made by the raw material of following parts by weight: 40~80 parts of benzoyl peroxide, 10~30 parts of isopropyl acrylate, 20~40 parts of butanediol water ester, 10~20 parts of toluene, 30~50 parts of epoxy resin, 30~60 parts of poly- isobutyl ester, 10-30 parts of polyvinyl alcohol, 12~24 parts of trimethylolpropane, 50~80 parts of isopropanol, 10~20 parts of acrylamide, 10~30 parts of ethylenediamine methylpropionate, 35~50 parts of dimethylbenzene, 20~30 parts of ethyl acetate, 15~30 parts of water, 10~20 parts of acetylbutyrylcellulose.The present invention has the beneficial effect that production is simple, using effect is good, environmentally friendly, is mainly used for the preparation of aqueous gluing.
Description
Technical field
The invention belongs to chemical article technical field more particularly to a kind of environment-friendly type aqueous gluing preparation processes.
Background technique
Gluing plays a very important role in production and life, and is widely used in vaerious fields, and the film that gluing is formed can be right
Object plays the role of decoration, protection and beautiful, although most of gluing production at present on the market is simple, price cheaply simultaneously
It with certain toxic side effect, will cause some harm to the human body as a household, and gluing function is relatively simple, be applicable in model
It encloses wideless, it is impossible to be used in many fields, limitation are very big.
Summary of the invention
The present invention provides a kind of environment-friendly type aqueous gluing preparation process, it is intended to solve above-mentioned in the presence of with certain secondary work of poison
With will cause some harm to the human body as a household, and gluing function is relatively simple, the scope of application is not wide, it is impossible to be used in
Many fields, the very big problem of limitation.
The invention is realized in this way a kind of environment-friendly type aqueous gluing preparation process, by the raw material production of following parts by weight
At:
40~80 parts of benzoyl peroxide, 10~30 parts of isopropyl acrylate, 20~40 parts of butanediol water ester, toluene 10~20
Part, 30~50 parts of epoxy resin, 30~60 parts of poly- isobutyl ester is 10-30 parts of polyvinyl alcohol, 12~24 parts of trimethylolpropane, different
50~80 parts of propyl alcohol, 10~20 parts of acrylamide, 10~30 parts of ethylenediamine methylpropionate, 35~50 parts of dimethylbenzene, acetic acid second
20~30 parts of ester, 15~30 parts of water, 10~20 parts of acetylbutyrylcellulose;
Its specific preparation the following steps are included:
It is mixed Step 1: being put into reaction kettle with ethyl acetate for the 80% of dimethylbenzene total amount, ethylenediamine methylpropionate and third is added
Isopropyl gadoleate;Water is mixed with the 50% of isopropanol total amount again, is then added into reaction kettle mixing, and be gradually heated up
Heating;Control speed of agitator is 110r/min, and heating rate is 3 DEG C/min, rises to 50~55 DEG C of stopping heatings to temperature, keeps
The temperature stirs 30~50min;
Step 2: first mixing the 60% of poly- isobutyl ester total amount with butanediol water ester, then the mixture of the two is slowly added to react
In kettle, speed of agitator 90r/min is maintained in adition process, then reacts 15~30min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining isopropanol is then dissolved into acrylamide, and be added
Into reaction kettle, 80~110min is reacted, maintains speed of agitator 90r/min;
Step 4: reactor temperature is cooled to 40~45 DEG C, remaining dimethylbenzene is mixed with trimethylolpropane, is used for
Dissolved epoxy;Remaining poly- isobutyl ester is dissolved into acetylbutyrylcellulose again, by dissolved epoxy resin and acetic acid fourth
Acid cellulose is separately added into reaction kettle, stirs 55~80min, and stop heating, temperature is made to be down to room temperature naturally;By phenol with
Benzoyl peroxide is mixed, and polyvinyl alcohol is added, and finally the mixture of polyvinyl alcohol is added in reaction kettle, stirs
It is uniformly mixed to each component to get finished product;
Wherein, the acetylbutyrylcellulose uses CAB 381-20.
The raw material by weight, each component are as follows: 45 parts of benzoyl peroxide, 16 parts of isopropyl acrylate, fourth two
30 parts of alcohol water ester, 12 parts of toluene, 45 parts of epoxy resin, 30 parts of poly- isobutyl ester, 20 parts of polyvinyl alcohol, 15 parts of trimethylolpropane,
64 parts of isopropanol, 12 parts of acrylamide, 15 parts of ethylenediamine methylpropionate, 40 parts of dimethylbenzene, 23 parts of ethyl acetate, 20 parts of water,
13 parts of acetylbutyrylcellulose.
Mode is slowly added to by the way of being at the uniform velocity added dropwise in the step 2, rate of addition 5ml/min.
The epoxy resin is dissolved in the process of dimethylbenzene and trimethylolpropane mixture using ultrasonic treatment, ultrasonic function
Rate is 300~400W, and ultrasonic time is 5~10min.
Compared with prior art, the beneficial effects of the present invention are: production is simple, the raw materials for production of use select non-toxic
, the using effect of gluing is good, and environmental protection can enhance the storage stability of product.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work
Every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment one
The present invention provides a kind of technical solution: a kind of environment-friendly type aqueous gluing preparation process, is made by the raw material of following parts by weight
It forms:
40~80 parts of benzoyl peroxide, 10~30 parts of isopropyl acrylate, 20~40 parts of butanediol water ester, toluene 10~20
Part, 30~50 parts of epoxy resin, 30~60 parts of poly- isobutyl ester is 10-30 parts of polyvinyl alcohol, 12~24 parts of trimethylolpropane, different
50~80 parts of propyl alcohol, 10~20 parts of acrylamide, 10~30 parts of ethylenediamine methylpropionate, 35~50 parts of dimethylbenzene, acetic acid second
20~30 parts of ester, 15~30 parts of water, 10~20 parts of acetylbutyrylcellulose;
Its specific preparation the following steps are included:
It is mixed Step 1: being put into reaction kettle with ethyl acetate for the 80% of dimethylbenzene total amount, ethylenediamine methylpropionate and third is added
Isopropyl gadoleate;Water is mixed with the 50% of isopropanol total amount again, is then added into reaction kettle mixing, and be gradually heated up
Heating;Control speed of agitator is 110r/min, and heating rate is 3 DEG C/min, rises to 50~55 DEG C of stopping heatings to temperature, keeps
The temperature stirs 30~50min;
Step 2: first mixing the 60% of poly- isobutyl ester total amount with butanediol water ester, then the mixture of the two is slowly added to react
In kettle, speed of agitator 90r/min is maintained in adition process, then reacts 15~30min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining isopropanol is then dissolved into acrylamide, and be added
Into reaction kettle, 80~110min is reacted, maintains speed of agitator 90r/min;
Step 4: reactor temperature is cooled to 40~45 DEG C, remaining dimethylbenzene is mixed with trimethylolpropane, is used for
Dissolved epoxy;Remaining poly- isobutyl ester is dissolved into acetylbutyrylcellulose again, by dissolved epoxy resin and acetic acid fourth
Acid cellulose is separately added into reaction kettle, stirs 55~80min, and stop heating, temperature is made to be down to room temperature naturally;By phenol with
Benzoyl peroxide is mixed, and polyvinyl alcohol is added, and finally the mixture of polyvinyl alcohol is added in reaction kettle, stirs
It is uniformly mixed to each component to get finished product;
Wherein, the acetylbutyrylcellulose uses CAB 381-20.
Embodiment two
By weight, each raw material component are as follows: 45 parts of benzoyl peroxide, 16 parts of isopropyl acrylate, 30 parts of butanediol water ester,
12 parts of toluene, 45 parts of epoxy resin, 30 parts of poly- isobutyl ester, 20 parts of polyvinyl alcohol, 15 parts of trimethylolpropane, 64 parts of isopropanol,
12 parts of acrylamide, 15 parts of ethylenediamine methylpropionate, 40 parts of dimethylbenzene, 23 parts of ethyl acetate, 20 parts of water, acetate butyrate fiber
14 parts of element is backed up;
Its specific preparation the following steps are included:
It is mixed Step 1: 32 parts of dimethylbenzene are put into reaction kettle with 23 ethyl acetate, is added 15 into the mixture of reaction kettle
Part ethylenediamine methylpropionate and 16 parts of isopropyl acrylates;20 parts of water are mixed with 32 parts of isopropanols again, are then added into
Reaction kettle is mixed, and is gradually heated up heating, that is to say, that by the dimethylbenzene to mix and ethyl acetate and the ethylenediamine to mix
After methylpropionate is mutually fused with isopropyl acrylate, mixed with the water for being dissolved in n-butanol;Control speed of agitator is 110r/min,
Heating rate is 3 DEG C/min, rises to 50~55 DEG C of stopping heatings to temperature, the temperature is kept to stir 40min;By by ethylenediamine
Methylpropionate, isopropyl acrylate and water are mixed with coordinative solvent respectively, then the stirring that heats up, and are conducive to these three ingredients mixed
It is better dispersed in bonding solvent, keeps its reaction more thorough;
Step 2: first mixing 18 parts of poly- isobutyl esters with 30 parts of butanediol water esters, then the mixture of the two is slowly added to react
In kettle, speed of agitator 90r/min is maintained in adition process, then reacts 23min;Being slowly added to here can be using can control
The feeder of liquid feeding speed processed, is at the uniform velocity added dropwise, and control rate of addition is 5ml/min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining 32 parts of isopropanols are then dissolved into 12 parts of acryloyls
Amine, and be added in reaction kettle, 90min is reacted, speed of agitator 90r/min is maintained;
Step 4: reactor temperature is cooled to 40~45 DEG C, 8 parts of dimethylbenzene are mixed with 15 parts of trimethylolpropanes, is used
In 45 parts of epoxy resin of dissolution;13 parts of acetylbutyrylcelluloses are dissolved with 12 parts of poly- isobutyl esters again, by dissolved epoxy resin,
14 parts of acetylbutyrylcelluloses are separately added into reaction kettle, stir 70min, and stop heating, temperature is made to be down to room temperature naturally;Such as
Fruit epoxy resin is difficult to quickly dissolve, and can carry out at ultrasound to epoxy resin and the mixture of dimethylbenzene and trimethylolpropane
12 parts of phenol and 45 parts of benzoyl peroxides are mixed, and are added by reason, ultrasonic power 350W, ultrasonic time 8min
The mixture of polyvinyl alcohol, is finally added in reaction kettle by 20 parts of polyvinyl alcohol, stirring to each component be uniformly mixed to get at
Product.
Embodiment three
50 parts of benzoyl peroxide, 10 parts of isopropyl acrylate, 20 parts of butanediol water ester, 10 parts of toluene, 35 parts of epoxy resin,
42 parts of poly- isobutyl ester, 12 parts of polyvinyl alcohol, 14 parts of trimethylolpropane, 54 parts of isopropanol, 10 parts of acrylamide, ethylenediamine methyl
12 parts of propionic ester, 35 parts of dimethylbenzene, 20 parts of ethyl acetate, 15 parts of water, 12 parts of acetylbutyrylcellulose;
Its specific preparation the following steps are included:
It is mixed Step 1: 28 parts of dimethylbenzene are put into reaction kettle with 20 ethyl acetate, is added 12 into the mixture of reaction kettle
Part ethylenediamine methylpropionate and 10 parts of isopropyl acrylates;15 parts of water are mixed with 27 parts of isopropanols again, are then added into
Reaction kettle is mixed, and is gradually heated up heating;Control speed of agitator is 110r/min, and heating rate is 3 DEG C/min, to temperature
50~55 DEG C of stopping heatings being risen to, the temperature is kept to stir 30min;By by ethylenediamine methylpropionate, isopropyl acrylate
It is mixed respectively with coordinative solvent with water, then the stirring that heats up, is conducive to these three ingredients and is better dispersed in the mixed solvent, make it
It reacts more thorough;
Step 2: first mixing 25.2 parts of poly- isobutyl esters with 20 parts of butanediol water esters, then the mixture of the two is slowly added to instead
It answers in kettle, speed of agitator 90r/min is maintained in adition process, then reacts 16min;Being slowly added to here can be using can
The feeder for controlling liquid feeding speed, is at the uniform velocity added dropwise, and control rate of addition is 5ml/min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining 27 parts of isopropanols are then dissolved into 10 parts of acryloyls
Amine, and be added in reaction kettle, 90min is reacted, speed of agitator 90r/min is maintained;
Step 4: reactor temperature is cooled to 40~45 DEG C, 7 parts of dimethylbenzene are mixed with 14 parts of trimethylolpropanes, is used
In 35 parts of epoxy resin of dissolution;12 parts of acetylbutyrylcelluloses are dissolved with 16.8 parts of poly- isobutyl esters again, by dissolved asphalt mixtures modified by epoxy resin
Rouge and acetylbutyrylcellulose are separately added into reaction kettle, stir 55min, and stop heating, temperature is made to be down to room temperature naturally;Such as
Fruit epoxy resin is difficult to quickly dissolve, and can carry out at ultrasound to epoxy resin and the mixture of dimethylbenzene and trimethylolpropane
Reason, ultrasonic power 350W, ultrasonic time are that 10 parts of phenol and 50 parts of benzoyl peroxides are mixed 6min, and are added
The mixture of polyvinyl alcohol, is finally added in reaction kettle by 12 parts of polyvinyl alcohol, stirring to each component be uniformly mixed to get at
Product.
Example IV
70 parts of benzoyl peroxide, 25 parts of isopropyl acrylate, 38 parts of butanediol water ester, 48 parts of epoxy resin, gathers by 20 parts of toluene
60 parts of isobutyl ester, 30 parts of polyvinyl alcohol, 22 parts of trimethylolpropane, 75 parts of isopropanol, 18 parts of acrylamide, ethylenediamine methyl-prop
30 parts of acid esters, 46 parts of dimethylbenzene, 26 parts of ethyl acetate, 25 parts of water, 18 parts of acetylbutyrylcellulose;
Its specific preparation the following steps are included:
It mixes Step 1: 36.8 parts of dimethylbenzene are put into reaction kettle with 26 ethyl acetate, is added into the mixture of reaction kettle
30 parts of ethylenediamine methylpropionates and 25 parts of isopropyl acrylates;25 parts of water are mixed with 37.5 parts of isopropanols again, then by it
Reaction kettle is added to be mixed, and is gradually heated up heating;Control speed of agitator is 110r/min, and heating rate is 3 DEG C/min, to
Temperature rises to 50~55 DEG C of stopping heatings, and the temperature is kept to stir 50min;By the way that ethylenediamine methylpropionate, acrylic acid is different
Propyl ester and water are mixed with coordinative solvent respectively, then the stirring that heats up, and are conducive to these three ingredients and are better dispersed in the mixed solvent,
Keep its reaction more thorough;
Step 2: first mixing 36 parts of poly- isobutyl esters with 38 parts of butanediol water esters, then the mixture of the two is slowly added to react
In kettle, speed of agitator 90r/min is maintained in adition process, then reacts 28min;Being slowly added to here can be using can control
The feeder of liquid feeding speed processed, is at the uniform velocity added dropwise, and control rate of addition is 5ml/min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining 37.5 parts of isopropanols are then dissolved into 18 parts of propylene
Amide, and be added in reaction kettle, 110min is reacted, speed of agitator 90r/min is maintained;
Step 4: reactor temperature is cooled to 40~45 DEG C, 9.2 parts of dimethylbenzene are mixed with 22 parts of trimethylolpropanes,
For dissolving 48 parts of epoxy resin;18 parts of acetylbutyrylcelluloses are dissolved with 24 parts of poly- isobutyl esters again, by dissolved asphalt mixtures modified by epoxy resin
Rouge and acetylbutyrylcellulose are separately added into reaction kettle, stir 77min, and stop heating, temperature is made to be down to room temperature naturally;Such as
Fruit epoxy resin is difficult to quickly dissolve, and can carry out at ultrasound to epoxy resin and the mixture of dimethylbenzene and trimethylolpropane
Reason, ultrasonic power 350W, ultrasonic time are that 20 parts of phenol and 70 parts of benzoyl peroxides are mixed 10min, and are added
The mixture of polyvinyl alcohol, is finally added in reaction kettle by 30 parts of polyvinyl alcohol, stirring to each component be uniformly mixed to get at
Product.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (4)
1. a kind of environment-friendly type aqueous gluing preparation process, which is characterized in that be made by the raw material of following parts by weight:
40~80 parts of benzoyl peroxide, 10~30 parts of isopropyl acrylate, 20~40 parts of butanediol water ester, toluene 10~20
Part, 30~50 parts of epoxy resin, 30~60 parts of poly- isobutyl ester is 10-30 parts of polyvinyl alcohol, 12~24 parts of trimethylolpropane, different
50~80 parts of propyl alcohol, 10~20 parts of acrylamide, 10~30 parts of ethylenediamine methylpropionate, 35~50 parts of dimethylbenzene, acetic acid second
20~30 parts of ester, 15~30 parts of water, 10~20 parts of acetylbutyrylcellulose;
Its specific preparation the following steps are included:
It is mixed Step 1: being put into reaction kettle with ethyl acetate for the 80% of dimethylbenzene total amount, ethylenediamine methylpropionate and third is added
Isopropyl gadoleate;Water is mixed with the 50% of isopropanol total amount again, is then added into reaction kettle mixing, and be gradually heated up
Heating;Control speed of agitator is 110r/min, and heating rate is 3 DEG C/min, rises to 50~55 DEG C of stopping heatings to temperature, keeps
The temperature stirs 30~50min;
Step 2: first mixing the 60% of poly- isobutyl ester total amount with butanediol water ester, then the mixture of the two is slowly added to react
In kettle, speed of agitator 90r/min is maintained in adition process, then reacts 15~30min;
Step 3: reactor temperature is warming up to 75~80 DEG C, remaining isopropanol is then dissolved into acrylamide, and be added
Into reaction kettle, 80~110min is reacted, maintains speed of agitator 90r/min;
Step 4: reactor temperature is cooled to 40~45 DEG C, remaining dimethylbenzene is mixed with trimethylolpropane, is used for
Dissolved epoxy;Remaining poly- isobutyl ester is dissolved into acetylbutyrylcellulose again, by dissolved epoxy resin and acetic acid fourth
Acid cellulose is separately added into reaction kettle, stirs 55~80min, and stop heating, temperature is made to be down to room temperature naturally;By phenol with
Benzoyl peroxide is mixed, and polyvinyl alcohol is added, and finally the mixture of polyvinyl alcohol is added in reaction kettle, stirs
It is uniformly mixed to each component to get finished product;
Wherein, the acetylbutyrylcellulose uses CAB 381-20.
2. a kind of environment-friendly type aqueous gluing preparation process according to claim 1, it is characterised in that: the raw material is by weight
Measure part meter, each component are as follows: 45 parts of benzoyl peroxide, 16 parts of isopropyl acrylate, 30 parts of butanediol water ester, 12 parts of toluene, ring
45 parts of oxygen resin, 30 parts of poly- isobutyl ester, 20 parts of polyvinyl alcohol, 15 parts of trimethylolpropane, 64 parts of isopropanol, acrylamide 12
Part, 15 parts of ethylenediamine methylpropionate, 40 parts of dimethylbenzene, 23 parts of ethyl acetate, 20 parts of water, 13 parts of acetylbutyrylcellulose.
3. a kind of environment-friendly type aqueous gluing preparation process according to claim 1, it is characterised in that: in the step 2
Mode is slowly added to by the way of being at the uniform velocity added dropwise, rate of addition 5ml/min.
4. a kind of environment-friendly type aqueous gluing preparation process according to claim 1, it is characterised in that: the epoxy resin
The process of dimethylbenzene and trimethylolpropane mixture is dissolved in using ultrasonic treatment, and ultrasonic power is 300~400W, ultrasonic time
For 5~10min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910528925.6A CN110205038A (en) | 2019-06-19 | 2019-06-19 | A kind of environment-friendly type aqueous gluing preparation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910528925.6A CN110205038A (en) | 2019-06-19 | 2019-06-19 | A kind of environment-friendly type aqueous gluing preparation process |
Publications (1)
Publication Number | Publication Date |
---|---|
CN110205038A true CN110205038A (en) | 2019-09-06 |
Family
ID=67793352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910528925.6A Withdrawn CN110205038A (en) | 2019-06-19 | 2019-06-19 | A kind of environment-friendly type aqueous gluing preparation process |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110205038A (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010522798A (en) * | 2007-04-27 | 2010-07-08 | ヤング−ウー ケミテック カンパニーリミテッド | Acrylic ester copolymer composition and redispersible powder |
CN105754393A (en) * | 2016-05-21 | 2016-07-13 | 黄金生 | Waterproof coating adhesive |
CN106009815A (en) * | 2016-05-21 | 2016-10-12 | 陈金才 | Environment-friendly mildew-proof rubber coating |
CN106700983A (en) * | 2017-01-06 | 2017-05-24 | 昆明和裕胶粘制品有限公司 | Processing technique for glue |
-
2019
- 2019-06-19 CN CN201910528925.6A patent/CN110205038A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010522798A (en) * | 2007-04-27 | 2010-07-08 | ヤング−ウー ケミテック カンパニーリミテッド | Acrylic ester copolymer composition and redispersible powder |
CN105754393A (en) * | 2016-05-21 | 2016-07-13 | 黄金生 | Waterproof coating adhesive |
CN106009815A (en) * | 2016-05-21 | 2016-10-12 | 陈金才 | Environment-friendly mildew-proof rubber coating |
CN106700983A (en) * | 2017-01-06 | 2017-05-24 | 昆明和裕胶粘制品有限公司 | Processing technique for glue |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3264245A (en) | Preparation of an aqueous polyvinyl alcohol composition | |
US9546143B2 (en) | Method for preparing high-quality epoxidized fatty acid ester with micro-reaction device | |
CN101265398B (en) | Environment-friendly type white emulsion glue | |
CN100453596C (en) | Water-absorbing resin composition | |
CN102559108A (en) | Preparation method for water-fast starch adhesive with high initial adhesion | |
CN106700983B (en) | A kind of glue processing technology | |
CN102326848A (en) | Food preservative and preparation method thereof | |
CN102120792A (en) | Preparation method of maleic anhydride-(meth)acrylic acid dispersant | |
CN103642425A (en) | Production technology for starch adhesive | |
CN110205038A (en) | A kind of environment-friendly type aqueous gluing preparation process | |
CN102329573B (en) | Formula for production of non-setting adhesive and preparation method thereof | |
CN101869084A (en) | Preparation method for magnetic pearl nucleus | |
CN102453455A (en) | Environment-friendly emulsion paint used for glued board | |
CN104693371A (en) | New acrylic acid modified resin for water-based two-component polyurethane coating | |
CN104710578A (en) | Novel acrylic acid modified resin for waterborne double-component polyurethane adhesive and polyurethane adhesive comprising resin | |
CN108219725A (en) | A kind of wet-heat resisting shock resistance adhesive | |
CN108822766A (en) | Low solid high adhesive aggregation acetate emulsion and preparation method thereof | |
CN110218523A (en) | A kind of anti-fouling type aqueous gluing production technology | |
CN102732075B (en) | Wood putty and preparation method thereof | |
CN109574743A (en) | A kind of Water Soluble Compound fertilizer anti-caking agent and preparation method thereof | |
CN103122050A (en) | Synthetic resin for water-soluble printing ink and preparation method thereof | |
CN109266261A (en) | A kind of student's environmentally protective glue and preparation method thereof | |
JPH07278225A (en) | Water absorbent and its production | |
CN107629568A (en) | A kind of PVC coating and its preparation technology | |
CN104745139A (en) | Boiling-resistant aqueous polyurethane composite adhesive preparation process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190906 |
|
WW01 | Invention patent application withdrawn after publication |