CN106700983A - Processing technique for glue - Google Patents
Processing technique for glue Download PDFInfo
- Publication number
- CN106700983A CN106700983A CN201710011007.7A CN201710011007A CN106700983A CN 106700983 A CN106700983 A CN 106700983A CN 201710011007 A CN201710011007 A CN 201710011007A CN 106700983 A CN106700983 A CN 106700983A
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- CN
- China
- Prior art keywords
- parts
- glue
- temperature
- butyl
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003292 glue Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 51
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 50
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 48
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 34
- 150000003505 terpenes Chemical class 0.000 claims abstract description 28
- 235000007586 terpenes Nutrition 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 16
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims abstract description 13
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 13
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 10
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 9
- WYNCHZVNFNFDNH-UHFFFAOYSA-N Oxazolidine Chemical compound C1COCN1 WYNCHZVNFNFDNH-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004246 zinc acetate Substances 0.000 claims abstract description 8
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 21
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 15
- 239000000376 reactant Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
- 229910000077 silane Inorganic materials 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 8
- 230000008878 coupling Effects 0.000 claims description 7
- 238000010168 coupling process Methods 0.000 claims description 7
- 238000005859 coupling reaction Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 3
- -1 silicon Alkane Chemical class 0.000 claims description 3
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 231100000419 toxicity Toxicity 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 5
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 abstract 1
- 238000003889 chemical engineering Methods 0.000 abstract 1
- USUBUUXHLGKOHN-UHFFFAOYSA-N methyl 2-methylidenehexanoate Chemical compound CCCCC(=C)C(=O)OC USUBUUXHLGKOHN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 17
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000002904 solvent Substances 0.000 description 7
- 235000013904 zinc acetate Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000002917 oxazolidines Chemical class 0.000 description 2
- KILURZWTCGSYRE-LNTINUHCSA-K (z)-4-bis[[(z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one Chemical compound CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O KILURZWTCGSYRE-LNTINUHCSA-K 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical class OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to the technical field of chemical engineering and aims at providing a processing technique with the advantages of little influence from temperature and humidity environments and good levelling property for glue. The processing technique for the glue is prepared from the following raw materials in parts by weight: 50 to 60 parts of methylbutyl acrylate, 3 to 6 parts of acrylic acid, 15 to 25 parts of butyl acetate, 8 to 12 parts of hydroxypropyl acrylate, 1 to 3 parts of oxazolidine, 4 to 6 parts of a silane coupling agent A-151, 15 to 20 parts of terpene resin, 3 to 8 parts of cellulose acetate butyrate, 4 to 6 parts of tert-butyl peroxybenzoate, 3 to 5 parts of benzoyl peroxide, 1 to 3 parts of zinc acetate, 20 to 30 parts of ethyl acetate, 72 to 78 parts of dimethylbenzene, 12 to 22 parts of dichloromethane and 10 to 20 parts of normal butanol. According to the processing technique disclosed by the invention, the toxicity of the glue is effectively reduced, the influence from the ambient temperature and humidity in a production process is little and the leveling property of the glue is remarkably enhanced; the glue can be produced in most areas.
Description
Technical field
The invention belongs to chemical technology field, and in particular to glue processing technology.
Background technology
Glue includes water-base cement and oily gum, and water-base cement is by special using water as solvent by acrylic acid or polyurethane resin
The emulsifying device of door, emulsification is formed, and this kind of glue is cheap, more environmental protection, but the film forming of water-base cement is poor, washing fastness
Difference.Oily gum is based on oil-based solvent, acrylic acid or polyurethane dissolving to be formed, and this kind of glue good film-forming property, fastness are good,
Using more universal, but this kind of glue feature of environmental protection difference, it is necessary to using some solvents with toxicity.In the prior art, it is enhancing
The bonding force of glue, or some characteristic effects are reached, the reduction glue thickness such as on the premise of cohesive force is ensured needs more
Using toxic solvents such as toluene, be so unfavorable for producing glue workman it is healthy, also result in glue production condition more
Plus it is strict.
And oily gum is in process of production it is noted that avoid the incorporation of moisture, moisture can reduce the bonding effect of glue, especially
It easily has moisture to be condensed in the equipment of glue in humid environment, the area of high humidity, will result in moisture and penetrates into glue
In.Accordingly, it would be desirable to limit the humiture environment of production glue, to ensure the final product quality of glue, this is just proposed to power house environment
Requirements at the higher level, increased production cost.Additionally, in the larger area of the temperature difference, the use of glue can also be affected, for example,
Under low temperature environment, sticky, the levelability that glue can become decline so that glue is solidified into the shape of out-of-flatness, shadow in body surface
Ring appearance.
The content of the invention
It is an object of the invention to provide a kind of by humiture ambient influnence is small, good leveling property glue processing technology.
For achieving the above object, the technical solution adopted in the present invention is：A kind of glue processing technology, raw material is by weight
Gauge includes：
50~60 parts of butyl methacrylate, 3~6 parts of acrylic acid, 15~25 parts of butyl acetate, 8~12 parts of hydroxypropyl acrylate,
1~3 part of oxazolidine, 4~6 parts of silane coupling A -151,15~20 parts of terpene resin, 3~8 parts of acetylbutyrylcellulose, mistake
4~6 parts of t-butyl perbenzoate of oxidation, 3~5 parts of benzoyl peroxide, 1~3 part of zinc acetate, 20~30 parts of ethyl acetate, diformazan
72~78 parts of benzene, 12~22 parts of dichloromethane, 10~20 parts of n-butanol.
Preferably：Described raw material includes by weight：
55 parts of butyl methacrylate, 5 parts of acrylic acid, 20 parts of butyl acetate, 10 parts of hydroxypropyl acrylate, 2 parts of oxazolidine, silane
5 parts of coupling agent A-151,18 parts of terpene resin, 5 parts of acetylbutyrylcellulose, 5 parts of peroxidized t-butyl perbenzoate, benzoyl peroxide
4 parts of formyl, 2 parts of zinc acetate, 25 parts of ethyl acetate, 75 parts of dimethylbenzene, 18 parts of dichloromethane, 15 parts of n-butanol.
Preferably：Described acetylbutyrylcellulose uses CAB 381-20.
Preferably：Described glue processing technology is comprised the following steps：
1）, the 80% of dimethylbenzene total amount is mixed with ethyl acetate, add butyl methacrylate and hydroxypropyl acrylate；Again will
Acrylic acid mixes with the 50% of n-butanol total amount, and then both mix, and gradually heat up；It is 110r/ to control speed of agitator
Min, programming rate is 3 DEG C/min, treats that temperature rises to 50~55 DEG C and stops heating up, and keeps the temperature to stir 30~50min.
2）, first by the 60% of butyl acetate total amount and peroxidized t-butyl perbenzoate mix, be then slowly added into step 1）'s
In reactant, speed of agitator 90r/min is maintained in adition process, then react 15~30min.
3）, temperature is risen to 75~80 DEG C, then with remaining n-Butanol soluble benzoyl peroxide, and add reactant
In, 80~110min is reacted, maintain speed of agitator 90r/min.
4）, temperature is down to 40~45 DEG C, remaining dimethylbenzene and dichloromethane are mixed, for dissolving terpene resin；
Acetylbutyrylcellulose is dissolved with remaining butyl acetate again, the terpene resin and acetylbutyrylcellulose after dissolving are added respectively
Enter step 3）Reactant in, stir 55~80min, and stop heating, temperature is down to room temperature naturally；It is subsequently adding oxazole
Alkane, silane coupling A -151 and zinc acetate, stirring are well mixed to each component, obtain final product.
Preferably：Described is slowly added to mode to be at the uniform velocity added dropwise, and rate of addition is 5ml/min.
Preferably：Described terpene resin is dissolved in the process of dimethylbenzene and dichloromethane mixture using ultrasonically treated, surpasses
Acoustical power is 300~400W, and ultrasonic time is 5~10min.
The invention has the advantages that：Glue toxicity is effectively reduced, and ambient temperature and humidity shadow is received in production process
Sound is small, can realize production in most of areas, hence it is evident that enhance the levelability of glue.Specifically, the present invention have adjusted glue
The composition of water, using dimethylbenzene as solvent, each composition can well dissolve, be well mixed in making glue, and dimethylbenzene
Toxicity is less than toluene, this reduces the toxicity using solvent, is conducive to improving the workshop condition of production glue, is also beneficial to
Staff's is healthy, is easy to reduce the control to working condition.Meanwhile, added in the production technology that the present invention is provided
Oxazolidine, the composition is extremely sensitive to water, and meeting very first time when moisture is run into decomposes, to remove the moisture being mixed into glue,
Moisture is avoided to impact the cohesive force of glue.Accordingly even when in the larger area of humidity, it is not required that special configuration is controlled
The equipment of workshop humidity, effectively reduces the production cost of glue, expands the scope that can be used as grown place.
Additionally, the not good phenomenon of levelability often occurs in use in glue, this can cause glue to solidify not in body surface
Smooth phenomenon occurs, and outward appearance is had undesirable effect.And levelability it is not good the reason for, mainly too low with glue temperature, glue
Caused by becoming sticky, and with glue temperature be on the one hand environment temperature influence, on the other hand also with the acetic acid second that contains in glue
Ester is relevant.Ethyl acetate highly volatile, and this physical process of volatilizing can absorb heat, and cause glue temperature further to reduce, therefore
The consumption of ethyl acetate is reduced in the present invention, and increased the amount of butyl acetate and n-butanol, to ensure each composition in glue
Can well dissolve, mix.And acetylbutyrylcellulose is added in the present invention, the composition can improve the levelling of glue
Property, the cohesive force without influenceing glue.
Specific embodiment
Lower mask body provides preferred embodiment so that those skilled in the art more understand technical scheme and
Effect.
Embodiment one
1）, by weight, 60 parts of dimethylbenzene are mixed with 25 parts of ethyl acetate, in mixture add 55 parts of methacrylic acid fourths
Ester and 10 parts of hydroxypropyl acrylates；5 parts of acrylic acid are mixed with 7.5 parts of n-butanols again, then both mix, and gradually rise
Temperature.That is, the butyl methacrylate and hydroxypropyl acrylate of dimethylbenzene and ethyl acetate will be dissolved in and n-butanol is dissolved in
Acrylic acid mixing.Control speed of agitator for 110r/min, programming rate is 3 DEG C/min, treats that temperature rises to 50~55 DEG C of stoppings
Heat up, keep the temperature to stir 40min.By by butyl methacrylate, hydroxypropyl acrylate and acrylic acid respectively with accordingly
Solvent mixes, then the stirring that heats up, and is conducive to these three compositions preferably to disperse in mixed solvent, makes its reaction more thorough.
2）, first 12 parts of butyl acetates and 5 parts of peroxidized t-butyl perbenzoates are mixed, be then slowly added into step 1）It is anti-
Answer in thing, speed of agitator 90r/min is maintained in adition process, then react 25min.Being slowly added to here can be using can
The feeder of liquid feeding speed is controlled, is at the uniform velocity added dropwise, it is 5ml/min to control rate of addition.
3）, temperature is risen to 75~80 DEG C, then with 7.5 parts of n-Butanol solubles, 4 parts of benzoyl peroxides, and add reaction
In thing, 95min is reacted, maintain speed of agitator 90r/min.Reactant further reacts in stirring, temperature higher and slower
Mixing speed be conducive to reaction carrying out.
4）, temperature is down to 40~45 DEG C, 15 parts of dimethylbenzene and 18 parts of dichloromethane are mixed, for dissolving 18 parts of terpenes
Resin；5 parts of CAB 381-20 are dissolved with 8 parts of butyl acetates again, the terpene resin after dissolving and acetylbutyrylcellulose are distinguished
Add step 3）Reactant in, stir 70min, and stop heating, temperature is down to room temperature naturally.Because terpene resin is two
Solubility in chloromethanes is better than the solubility in dimethylbenzene, and dichloromethane has volatility, two as ethyl acetate
The content of chloromethanes is larger to be easily caused glue temperature is relatively low and influence levelability when in use, therefore uses dimethylbenzene and dichloromethane
The mixture of alkane dissolves terpene resin.If terpene resin is difficult to quick dissolving, can be to terpene resin and dimethylbenzene and dichloro
The mixture of methane carries out ultrasonically treated, and ultrasonic power is 350W, and ultrasonic time is 8min.Be eventually adding 2 parts of oxazolidines, 5 parts
Silane coupling A -151 and 2 parts of zinc acetates, stirring are well mixed to each component, obtain final product.
Embodiment two
1）, by weight, 62 parts of dimethylbenzene are mixed with 26 parts of ethyl acetate, in mixture add 56 parts of methacrylic acid fourths
Ester and 11 parts of hydroxypropyl acrylates；5 parts of acrylic acid are mixed with 8 parts of n-butanols again, then both mix, and gradually rise
Temperature.Control speed of agitator for 110r/min, programming rate is 3 DEG C/min, treat that temperature rises to 50~55 DEG C and stops heating up, keeping should
Temperature stirs 43min.
2）, first 13.2 parts of butyl acetates and 5 parts of peroxidized t-butyl perbenzoates are mixed, be then slowly added into step 1）'s
In reactant, speed of agitator 90r/min is maintained in adition process, then react 23min.Being slowly added to here can use energy
The feeder of liquid feeding speed is enough controlled, is at the uniform velocity added dropwise, it is 5ml/min to control rate of addition.
3）, temperature is risen to 75~80 DEG C, then with 8 parts of n-Butanol solubles, 4 parts of benzoyl peroxides, and add reactant
In, 100min is reacted, maintain speed of agitator 90r/min.
4）, temperature is down to 40~45 DEG C, 15.5 parts of dimethylbenzene and 17 parts of dichloromethane are mixed, for dissolving 17 parts of terpenes
Olefine resin；6 parts of CAB 381-20 are dissolved with 8.8 parts of butyl acetates again, by terpene resin and acetylbutyrylcellulose after dissolving
It is separately added into step 3）Reactant in, stir 65min, and stop heating, temperature is down to room temperature naturally.If terpene resin
Quick dissolving is difficult to, terpene resin and the mixture of dimethylbenzene and dichloromethane can be carried out ultrasonically treated, ultrasonic power is
350W, ultrasonic time is 7min.2.2 parts of oxazolidines, 5 parts of silane coupling As -151 and 2.1 parts of zinc acetates are eventually adding, are stirred
It is well mixed to each component, obtain final product.
Embodiment three
1）, by weight, 57.6 parts of dimethylbenzene are mixed with 20 parts of ethyl acetate, in mixture add 50 parts of methacrylic acids
Butyl ester and 8 parts of hydroxypropyl acrylates；3 parts of acrylic acid are mixed with 5 parts of n-butanols again, then both mix, and gradually rise
Temperature.Control speed of agitator for 110r/min, programming rate is 3 DEG C/min, treat that temperature rises to 50~55 DEG C and stops heating up, keeping should
Temperature stirs 30min.
2）, first 9 parts of butyl acetates and 4 parts of peroxidized t-butyl perbenzoates are mixed, be then slowly added into step 1）It is anti-
Answer in thing, speed of agitator 90r/min is maintained in adition process, then react 15min.Being slowly added to here can be using can
The feeder of liquid feeding speed is controlled, is at the uniform velocity added dropwise, it is 5ml/min to control rate of addition.
3）, temperature is risen to 75~80 DEG C, then with 5 parts of n-Butanol solubles, 3 parts of benzoyl peroxides, and add reactant
In, 80min is reacted, maintain speed of agitator 90r/min.
4）, temperature is down to 40~45 DEG C, 14.4 parts of dimethylbenzene and 12 parts of dichloromethane are mixed, for dissolving 15 parts of terpenes
Olefine resin；3 parts of CAB 381-20 are dissolved with 6 parts of butyl acetates again, by the terpene resin and acetylbutyrylcellulose after dissolving point
Jia Ru not step 3）Reactant in, stir 55min, and stop heating, temperature is down to room temperature naturally.If terpene resin is difficult
Quickly to dissolve, terpene resin and the mixture of dimethylbenzene and dichloromethane can be carried out ultrasonically treated, ultrasonic power is 400W,
Ultrasonic time is 5min.1 part of oxazolidine, 4 parts of silane coupling As -151 and 1 part of zinc acetate are eventually adding, stirring is mixed to each component
Close uniform, obtain final product.
Example IV
1）, by weight, 62.4 parts of dimethylbenzene are mixed with 30 parts of ethyl acetate, in mixture add 60 parts of methacrylic acids
Butyl ester and 12 parts of hydroxypropyl acrylates；6 parts of acrylic acid are mixed with 10 parts of n-butanols again, then both mix, and gradually
Heat up.Control speed of agitator for 110r/min, programming rate is 3 DEG C/min, treat that temperature rises to 50~55 DEG C and stops heating up, keep
The temperature stirs 50min.
2）, 15 parts of butyl acetates and 6 parts of peroxidized t-butyl perbenzoates are mixed, be slowly added to step 1）Reactant
In, speed of agitator 90r/min is maintained in adition process, then react 30min.
3）, temperature is risen to 75~80 DEG C, then with 10 parts of n-Butanol solubles, 5 parts of benzoyl peroxides, and add reaction
In thing, 110min is reacted, maintain speed of agitator 90r/min.
4）, temperature is down to 40~45 DEG C, 15.6 parts of dimethylbenzene and 22 parts of dichloromethane are mixed, for dissolving 20 parts of terpenes
Olefine resin；8 parts of CAB 381-20 are dissolved with 10 parts of butyl acetates again, by the terpene resin and acetylbutyrylcellulose after dissolving point
Jia Ru not step 3）Reactant in, stir 80min, and stop heating, temperature is down to room temperature naturally.It is eventually adding 3 parts of evils
Oxazolidine, 6 parts of silane coupling As -151 and 3 parts of zinc acetates, stirring are well mixed to each component, obtain final product.
Comparative example one
Glue production is now carried out according to prior art, product glue is obtained as a comparison case.
1）, by weight, by 35 parts of butyl acrylates, 10 parts of 2-EHAs, 0.5 part of acrylic acid, 1 part of propylene
Sour hydroxyl ethyl ester, 30 parts of ethyl acetate and 60 parts of toluene are fitted into three neck round bottom, then three neck round bottom is connected respectively stir
Device, thermometer and condenser are mixed, and the raw material added by the above is stirred by agitator, while will be former above by water-bath
Material heating.
2）, to be heated to 85 DEG C, while stirring add 0.3 part of benzoyl peroxide.
3）, after the benzoyl peroxide temperature that is added is raised, maintain 85 DEG C of reaction 1h, add 0.5 part of peroxidating
Benzoyl and 4 parts of ethyl acetate, continue to react.
4）, after reaction 0.5h, add the double lauroyl of 2 parts of peroxidating and 5 parts of vinylacetates, and lower the temperature again after constant temperature 2h.
5）, after room temperature is cooled to, add 10 parts of terpene phenol resins, 0.3 part of aluminium acetylacetonate, mix to each component
It is well mixed, obtain final product.
Product checking
Further to verify beneficial effects of the present invention, respectively under normal humidity environment（Medial humidity 55%）And wet environment
Under（Medial humidity 85%）The embodiment one to four of production and the product of comparative example one are detected.Detection content include viscosity,
PH value, 23 DEG C of shear strengths, 70 DEG C of shear strengths, levelability, heat resistance and cold resistance.Detection method is as follows：
Viscosity：（23±2℃）Under the conditions of, determine the product of embodiment one to four and comparative example one respectively with rotational viscometer.
PH value：（23±2℃）Under the conditions of, embodiment one to four is determined respectively with the Numerical pH-meter of precision≤0.1
With the product of comparative example one.
23 DEG C of shear strengths：（23 ± 2 DEG C, humidity 45%~55%）Under the conditions of, respectively with embodiment one to four and contrast
The product of example one is glued the same metal sheet of surfacing, is made sample.With the length of gage measuring sample faying surface
And width, it is accurate to 0.05mm；Sample is symmetrically clipped in upper and lower holder, the distance of holding position to bond end is（50±
1）mm；Testing machine is started,（5±1）In mm/min, loaded with stabilized speed, record the peak load of sample failure by shear, meter
Calculate shear strength.The computing formula of shear strength τ is as follows：
（F is failure by shear peak load；B and l are respectively that faying surface is wide, length）
70 DEG C of shear strengths：（70 ± 2 DEG C, humidity 45%~55%）Under the conditions of detected, detection method is strong with 23 DEG C of shearings
Degree.
Levelability：（23 ± 2 DEG C, humidity 45%~55%）Under the conditions of, by embodiment one to four and the product of comparative example one
On a glass, coating duration is not more than 20s for coating, determines glue surface and reaches uniform, smooth, wrinkle-free state required time.
Heat resistance：The product 100ml for distinguishing Example one to four and comparative example one with graduated cylinder moves into 250ml tool plug tapers
In bottle, sealed after cleaning bottleneck, in temperature（50±2）Continue 5h under the conditions of DEG C, visually inspected immediately after taking-up, glue is without knot
The significant changes such as block, layering are qualified.
Cold resistance：The product of embodiment one to four and comparative example one to test tube is added in having ground glass stopper test tube respectively
1/3rd at, clean it is closed after bottleneck, in temperature（-15±3）Under the conditions of DEG C, continue 5h, treated after taking-up glue recover to
Normal temperature（20±15）DEG C, after being stirred with glass bar, put upside down and just put each 3 times.Visually inspect, glue without caking, mobility without
Significant change is qualified.
Obtain testing result as shown in the table：
Product checking result is produced under the normal humidity environment of table 1
| Project | Embodiment one | Embodiment two | Embodiment three | Example IV | Comparative example one |
| Viscosity（Pa·s） | 3.6 | 3.7 | 3.5 | 3.8 | 2.8 |
| PH value | 6.5 | 6.5 | 6.4 | 6.5 | 6.8 |
| 23 DEG C of shear strengths（MPa） | 30 | 31 | 29 | 28 | 26 |
| 70 DEG C of shear strengths（MPa） | 31 | 30 | 22 | 23 | 15 |
| Levelability（s） | 42 | 45 | 48 | 36 | It is unable to reach levelling state |
| Heat resistance | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
| Cold resistance | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
Product checking result is produced under the wet environment of table 2
| Project | Embodiment one | Embodiment two | Embodiment three | Example IV | Comparative example one |
| Viscosity（Pa·s） | 3.2 | 3.3 | 3.1 | 3.5 | 0.9 |
| PH value | 6.7 | 6.7 | 6.5 | 6.6 | 6.3 |
| 23 DEG C of shear strengths（MPa） | 28 | 28 | 27 | 26 | 19 |
| 70 DEG C of shear strengths（MPa） | 30 | 27 | 20 | 19 | 10 |
| Levelability（s） | 45 | 47 | 43 | 38 | It is unable to reach levelling state |
| Heat resistance | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
| Cold resistance | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
Understood with reference to Tables 1 and 2, the glue bonding effect of present invention production is good, the product for either being produced under normal humidity environment
The product produced under product or wet environment, the shear strength for detecting at nominal room temperature and under the conditions of 70 DEG C is all higher than existing skill
Art level.The present invention is hardly influenceed by ambient humidity, and the product viscosity for producing in wet condition is good, outclass existing skill
The product that art is produced in wet condition.And compared to prior art, present invention improves the levelability of product, using
Cheng Zhong, ensure that pasted material, especially relatively thin material appearance is smooth, attractive in appearance, it is to avoid prior art production
Glue is frozen into the phenomenon of roughness in body surface.
Claims (6)
1. a kind of glue processing technology, it is characterised in that：Raw material includes by weight：
50~60 parts of butyl methacrylate, 3~6 parts of acrylic acid, 15~25 parts of butyl acetate, 8~12 parts of hydroxypropyl acrylate,
1~3 part of oxazolidine, 4~6 parts of silane coupling A -151,15~20 parts of terpene resin, 3~8 parts of acetylbutyrylcellulose, mistake
4~6 parts of t-butyl perbenzoate of oxidation, 3~5 parts of benzoyl peroxide, 1~3 part of zinc acetate, 20~30 parts of ethyl acetate, diformazan
72~78 parts of benzene, 12~22 parts of dichloromethane, 10~20 parts of n-butanol.
2. glue processing technology according to claim 1, it is characterised in that：Described raw material includes by weight：
55 parts of butyl methacrylate, 5 parts of acrylic acid, 20 parts of butyl acetate, 10 parts of hydroxypropyl acrylate, 2 parts of oxazolidine, silane
5 parts of coupling agent A-151,18 parts of terpene resin, 5 parts of acetylbutyrylcellulose, 5 parts of peroxidized t-butyl perbenzoate, benzoyl peroxide
4 parts of formyl, 2 parts of zinc acetate, 25 parts of ethyl acetate, 75 parts of dimethylbenzene, 18 parts of dichloromethane, 15 parts of n-butanol.
3. glue processing technology according to claim 1, it is characterised in that：Described acetylbutyrylcellulose uses CAB
381-20。
4. glue processing technology according to claim 1 and 2, it is characterised in that：Described glue processing technology include with
Lower step：
1）, the 80% of dimethylbenzene total amount is mixed with ethyl acetate, add butyl methacrylate and hydroxypropyl acrylate；Again will
Acrylic acid mixes with the 50% of n-butanol total amount, and then both mix, and gradually heat up；It is 110r/ to control speed of agitator
Min, programming rate is 3 DEG C/min, treats that temperature rises to 50~55 DEG C and stops heating up, and keeps the temperature to stir 30~50min；
2）, first by the 60% of butyl acetate total amount and peroxidized t-butyl perbenzoate mix, be then slowly added into step 1）Reaction
In thing, speed of agitator 90r/min is maintained in adition process, then react 15~30min；
3）, temperature is risen to 75~80 DEG C, then with remaining n-Butanol soluble benzoyl peroxide, and add reactant,
80~110min of reaction, maintains speed of agitator 90r/min；
4）, temperature is down to 40~45 DEG C, remaining dimethylbenzene and dichloromethane are mixed, for dissolving terpene resin；Use again
Remaining butyl acetate dissolves acetylbutyrylcellulose, and the terpene resin and acetylbutyrylcellulose after dissolving are separately added into step
Rapid 3）Reactant in, stir 55~80min, and stop heating, temperature is down to room temperature naturally；It is subsequently adding oxazolidine, silicon
Alkane coupling agent A-151 and zinc acetate, stirring are well mixed to each component, obtain final product.
5. glue processing technology according to claim 4, it is characterised in that：Described is slowly added to mode at the uniform velocity to drip
Plus, rate of addition is 5ml/min.
6. glue processing technology according to claim 4, it is characterised in that：Described terpene resin is dissolved in dimethylbenzene and two
The process of chloromethane mixture uses ultrasonically treated, and ultrasonic power is 300~400W, and ultrasonic time is 5~10min.
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| CN109266261A (en) * | 2018-09-06 | 2019-01-25 | 喻泰阁 | A kind of student's environmentally protective glue and preparation method thereof |
| CN110205038A (en) * | 2019-06-19 | 2019-09-06 | 浙江安吉朝辉新材料有限公司 | A kind of environment-friendly type aqueous gluing preparation process |
| CN110283536A (en) * | 2019-06-19 | 2019-09-27 | 浙江安吉朝辉新材料有限公司 | A kind of process for producing of novel glue |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110218523A (en) * | 2019-06-19 | 2019-09-10 | 浙江安吉朝辉新材料有限公司 | A kind of anti-fouling type aqueous gluing production technology |
| CN112980358A (en) * | 2021-03-04 | 2021-06-18 | 吉安迅达科技有限公司 | Environment-friendly energy-saving adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798491A (en) * | 2010-02-25 | 2010-08-11 | 北京高盟新材料股份有限公司 | Pressure sensitive adhesive for protective film and preparation method thereof |
| CN101864257A (en) * | 2010-05-26 | 2010-10-20 | 北京高盟新材料股份有限公司 | Adhesive for automobile adhesive film and preparation method thereof |
| CN105602492A (en) * | 2015-12-30 | 2016-05-25 | 安徽明讯新材料科技股份有限公司 | Application method of solvent type polymethacrylate pressure-sensitive adhesive |
| US20160177145A1 (en) * | 2014-12-19 | 2016-06-23 | Samsung Sdi Co., Ltd. | Adhesive composition for polarizing plate, polarizing plate including the same and optical display including the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003041220A (en) * | 2001-07-27 | 2003-02-13 | Toagosei Co Ltd | Adhesive composition |
-
2017
- 2017-01-06 CN CN201710011007.7A patent/CN106700983B/en active Active
- 2017-01-06 CN CN201810203989.4A patent/CN108329871B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798491A (en) * | 2010-02-25 | 2010-08-11 | 北京高盟新材料股份有限公司 | Pressure sensitive adhesive for protective film and preparation method thereof |
| CN101864257A (en) * | 2010-05-26 | 2010-10-20 | 北京高盟新材料股份有限公司 | Adhesive for automobile adhesive film and preparation method thereof |
| US20160177145A1 (en) * | 2014-12-19 | 2016-06-23 | Samsung Sdi Co., Ltd. | Adhesive composition for polarizing plate, polarizing plate including the same and optical display including the same |
| CN105602492A (en) * | 2015-12-30 | 2016-05-25 | 安徽明讯新材料科技股份有限公司 | Application method of solvent type polymethacrylate pressure-sensitive adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 刘益军: "噁唑烷在聚氨酯中的应用", 《聚氨酯工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109266261A (en) * | 2018-09-06 | 2019-01-25 | 喻泰阁 | A kind of student's environmentally protective glue and preparation method thereof |
| CN110205038A (en) * | 2019-06-19 | 2019-09-06 | 浙江安吉朝辉新材料有限公司 | A kind of environment-friendly type aqueous gluing preparation process |
| CN110283536A (en) * | 2019-06-19 | 2019-09-27 | 浙江安吉朝辉新材料有限公司 | A kind of process for producing of novel glue |
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| CN108329871A (en) | 2018-07-27 |
| CN106700983B (en) | 2018-05-29 |
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