WO2017179157A1 - オートサンプラ - Google Patents
オートサンプラ Download PDFInfo
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- WO2017179157A1 WO2017179157A1 PCT/JP2016/061929 JP2016061929W WO2017179157A1 WO 2017179157 A1 WO2017179157 A1 WO 2017179157A1 JP 2016061929 W JP2016061929 W JP 2016061929W WO 2017179157 A1 WO2017179157 A1 WO 2017179157A1
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- WIPO (PCT)
- Prior art keywords
- axis direction
- head
- arm
- obstacle
- unit
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/0099—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor comprising robots or similar manipulators
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/02—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor using a plurality of sample containers moved by a conveyor system past one or more treatment or analysis stations
- G01N35/04—Details of the conveyor system
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/24—Automatic injection systems
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/00584—Control arrangements for automatic analysers
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/10—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/10—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
- G01N35/1081—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices characterised by the means for relatively moving the transfer device and the containers in an horizontal plane
- G01N35/109—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices characterised by the means for relatively moving the transfer device and the containers in an horizontal plane with two horizontal degrees of freedom
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B19/00—Programme-control systems
- G05B19/02—Programme-control systems electric
- G05B19/18—Numerical control [NC], i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form
- G05B19/406—Numerical control [NC], i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form characterised by monitoring or safety
- G05B19/4061—Avoiding collision or forbidden zones
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/10—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
- G01N35/1009—Characterised by arrangements for controlling the aspiration or dispense of liquids
- G01N35/1011—Control of the position or alignment of the transfer device
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/10—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
- G01N35/1079—Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices with means for piercing stoppers or septums
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B2219/00—Program-control systems
- G05B2219/30—Nc systems
- G05B2219/49—Nc machine tool, till multiple
- G05B2219/49143—Obstacle, collision avoiding control, move so that no collision occurs
Definitions
- the present invention is used in, for example, a liquid chromatograph and a gas chromatograph, and a head having a function of sucking and discharging a sample or a reagent using a needle is driven in a horizontal plane, and is disposed within a moving range of the head.
- This relates to an autosampler that automatically accesses a container and an injection port.
- An autosampler used in a liquid chromatograph (LC), a gas chromatograph (GC), or a LC-MS or GC-MS in which a mass spectrometer (MS) is connected as a detector is perpendicular to the head in a horizontal plane. Drive in the direction.
- the head has a function of sucking and discharging a sample, a reagent or the like with a needle, for example.
- a sample container, a reagent container, a sample inlet, and the like are arranged in the moving range of the head.
- the autosampler automatically adjusts the sample and applies it to the chromatograph based on the analysis items set by the user. Perform operations such as injection.
- the autosampler can coexist with other devices such as auto injectors and detectors. That is, another autoinjector, detector, or the like can be arranged in the moving range of the head, and the adjusted sample can be introduced into another autoinjector or detector.
- the head movement path so that the head always moves along the path where the above problem hardly occurs.
- the moving distance of the head becomes longer than necessary and the moving time of the head becomes longer.
- an object of the present invention is to provide an autosampler that can prevent the head and arm from coming into contact with an obstacle without increasing the time required for the movement of the head.
- the autosampler includes a drive unit, an obstacle sensor, and a control unit.
- the drive unit includes a head, an arm extending in the Y-axis direction, which is one direction in the horizontal plane, holding the head on the tip side, and sliding in the Y-axis direction, and an X-axis orthogonal to the Y-axis direction in the horizontal plane
- An arm moving mechanism for moving the arm in the direction is provided.
- An obstacle sensor is provided in the drive unit and detects an obstacle on the movement path of the head and the arm.
- the control unit controls driving of the head by the driving unit, and includes a shortest route moving unit and an obstacle avoiding unit.
- the shortest route moving unit of the control unit is configured to drive the driving unit so that the head moves on the shortest route to the destination after the destination of the head is set.
- the obstacle avoiding unit is configured to execute a Y-axis direction avoiding operation and an X-axis direction avoiding operation.
- the Y-axis direction avoiding operation stops movement of the arm in the X-axis direction when the obstacle sensor detects an obstacle when the head is moved along the shortest route, and the arm is moved to the X-axis direction. This is an operation of moving the arm only in the Y-axis direction so that the head comes to a position in the Y-axis direction where the head and the arm do not come in contact with the obstacle even if the head is advanced in the direction.
- the X-axis direction avoiding operation is an operation for moving the arm only in the X-axis direction to a position where the head can be linearly moved in the destination direction after the Y-axis direction avoiding operation.
- the shortest route moving unit is configured to drive the driving unit so that the head moves along the shortest route from the position immediately after completion of the X-axis direction avoiding operation to the destination.
- the X-axis direction avoiding operation is completed simultaneously with the completion of the Y-axis direction avoiding operation.
- control unit further includes a warning generation unit that issues a warning to the user when the Y-axis direction avoidance operation is physically impossible. Then, the user can immediately know that the obstacle needs to be moved from the position.
- the shortest route moving unit moves the head to the destination in a state where the Y-axis direction avoidance position and the X-axis direction avoidance position are stored in the avoidance position storage unit.
- the drive unit is configured to control so that the head moves along the shortest route to the destination via the Y-axis direction avoidance position and the X-axis direction avoidance position. preferable.
- the Y stored in the avoidance position storage unit without performing the Y-axis direction avoiding operation and the X-axis direction avoiding operation using the obstacle sensor when the head moves to the destination after the second time.
- the avoidance position in the axial direction and the avoidance position in the X-axis direction the head can be moved to the destination by the shortest route while avoiding the obstacle.
- the control unit that controls driving of the head by the driving unit includes a shortest route moving unit and an obstacle avoiding unit, and the obstacle avoiding unit performs the Y-axis direction avoiding operation and the X-axis direction avoiding. Since the operation is executed, the shortest route moving unit is configured to drive the driving unit so that the head moves the shortest route from the position immediately after the completion of the X-axis direction avoiding operation to the destination. It is possible to prevent the head and the arm from coming into contact with an obstacle without moving the head along a movement path longer than necessary.
- the head 2 is attached to the tip of the arm 4.
- the head 2 holds, for example, a needle whose tip is directed vertically downward, and has a function of sucking and discharging liquid from the tip of the needle.
- the arm 4 is disposed so as to extend in the Y-axis direction (vertical direction in the drawing) which is one direction in the horizontal plane.
- the arm 4 is held by an arm moving mechanism 6.
- the arm moving mechanism 6 can move in the X-axis direction along the guide rail 8 arranged so as to extend in the X-axis direction (left-right direction in the drawing) orthogonal to the Y-axis direction in the horizontal plane.
- the arm moving mechanism 6 slides the arm 4 in the Y-axis direction.
- the head 2, the arm 4 and the arm moving mechanism 6 constitute a drive unit in claim 1 of the present application.
- the right direction in the X-axis direction is defined as a positive direction
- the left direction is defined as a negative direction
- the upper direction in the Y-axis direction is defined as a negative direction
- the lower direction is defined as a positive direction.
- a rack gear provided so as to extend in the X-axis direction along the guide rail 8 and the arm moving mechanism 6 are provided.
- a mechanism including a pinion gear that meshes with the rack gear.
- the pinion gear provided in the arm moving mechanism 6 is rotated by the stepping motor, and the position of the head 4 in the X-axis direction can be controlled by the number of rotations of the stepping motor.
- a rack gear provided so as to extend in the Y-axis direction along the arm 4 and an arm 4 provided in the arm moving mechanism 6 are provided.
- a mechanism including a pinion gear meshing with the rack gear.
- the pinion gear provided in the arm moving mechanism 6 is rotated by the stepping motor, and the position of the head 4 in the Y-axis direction can be controlled by the number of rotations of the stepping motor.
- Obstacle sensors 10 and 12 are provided on the side surface of the head 2 on the X axis direction plus side (right side in the figure) and the side surface on the Y axis direction plus side (lower side in the figure), respectively.
- Obstacle sensors 14 are provided at a plurality of positions (three locations in the figure) on the side surface of the arm 4 on the plus side in the X-axis direction (right side in the figure). These obstacle sensors 10, 12, and 14 detect the presence of an obstacle when the obstacles approach each other within a certain distance in the direction in which each sensor faces (X-axis direction plus side or Y-axis direction plus side). Is.
- a photomicro sensor, an area sensor, a photoelectric sensor, a proximity sensor, and a laser sensor can be used as the obstacle sensors 10, 12, and 14, for example.
- the detection distance of the obstacle sensors 10, 12, and 14 is about 10 mm.
- the movement of the head 2, that is, the operation of the arm moving mechanism 6 is controlled by the control unit 16.
- the control unit 16 includes a shortest route moving unit 18, an obstacle avoiding unit 20, an avoidance position storage unit 22, and a warning generating unit 24 as functions for moving the head 2 to the destination G. Detection signals from the obstacle sensors 10, 12 and 14 are taken into the control unit 16.
- the control unit 16 controls the operation of the arm moving mechanism 6 so that the head 2 and the arm 4 do not contact the obstacle based on the signals from the obstacle sensors 10, 12, and 14.
- the control unit 16 can be realized by a computer dedicated to the autosampler or a general-purpose personal computer.
- the shortest route moving unit 18, the obstacle avoiding unit 20, and the warning generating unit 24 are functions obtained when the arithmetic processing unit executes a program stored in the computer that forms the control unit 16.
- the avoidance position storage unit 22 is realized by a storage device provided in the control unit 16.
- the avoidance position storage unit 22 may be realized by a storage device provided independently from the control unit 16.
- the shortest route moving unit 18 is configured to calculate the shortest route for moving the head 2 to the destination G and to control the arm moving mechanism 6 so that the head 2 moves to the shortest route. Furthermore, when the avoidance position storage unit 22 stores an X-axis direction avoidance position and a Y-axis direction avoidance position, which will be described later, the shortest route moving unit 18 reaches the destination in the shortest way through these avoidance positions. The shortest route for moving the head 2 is calculated, and the arm moving mechanism 6 is controlled so that the head 2 moves along the shortest route.
- the obstacle avoiding unit 20 is configured to control the arm moving mechanism 6 so that the head 2 and the arm 4 avoid the obstacle when there is an obstacle on the moving path of the head 2 or the arm 4. Has been. The details of the obstacle avoiding operation for avoiding the obstacle will be described later.
- the obstacle avoiding operation mainly includes an X axis direction avoiding operation and a Y axis direction avoiding operation, and each avoiding operation avoids the obstacle. X-axis direction avoidance position and Y-axis direction avoidance position are obtained.
- the obstacle avoidance operation may be always performed during the normal operation, but it is preferable to perform the obstacle avoidance operation during teaching for registering the destination G and the position of the obstacle in the control unit 16.
- the X-axis direction avoidance position and the Y-axis direction avoidance position are acquired by the X-axis direction avoidance operation and the Y-axis direction avoidance operation, and are stored in the avoidance position storage unit 22.
- the head 2 can be moved by the shortest route via the X-axis direction avoidance position and the Y-axis direction avoidance position by the shortest route moving unit 18.
- the warning generation unit 24 is configured to issue a warning to the user when the head 2 and the arm 4 cannot avoid the obstacle by the obstacle avoiding operation.
- a warning to the user an error may be displayed on a monitor such as a liquid crystal display connected to the control unit 16, or a warning sound may be emitted.
- the obstacle avoidance operation described below is an operation performed during teaching to determine a route for moving the head 2 from a preset reference position to the destination G.
- the obstacle sensors 10 and 14 are defined as “X-axis direction sensors” that detect the presence of an obstacle within a certain distance in the X-axis plus direction between the head 2 and the arm 4.
- 12 is defined as a “Y-axis direction sensor” that detects the presence of an obstacle within a certain distance in the Y-axis plus direction of the head 2.
- the head 2 tries to move to the destination G in a straight line, that is, by the shortest route.
- the head 2 moves in the direction of the destination G along the shortest route.
- the head 2 reaches the destination G by the shortest route.
- the head 2 When avoidance is possible, as shown in FIG. 5, the head 2 is moved in the Y-axis minus direction to a position where the head 2 can move in the X-axis plus direction.
- the position where the head 2 can move in the X-axis plus direction can be recognized based on the detection signal of the X-axis direction sensor 10. That is, in consideration of the size of the head 2, the head 2 is moved further in the Y-axis minus direction by a certain distance after the X-axis direction sensor 10 no longer detects an obstacle.
- the operation of moving the head 2 to this position is the “Y-axis direction avoiding operation”.
- the position of the head 2 immediately after the completion of the Y-axis direction avoidance operation is stored in the avoidance position storage unit 22 as the “Y-axis direction avoidance position”.
- FIG. 6 shows a case where there is an obstacle on the straight line from the “Y-axis direction avoidance position” to the destination G immediately after the completion of the Y-axis direction avoidance operation after the completion of the Y-axis direction avoidance operation.
- the head 2 is moved in the X-axis plus direction to a position where the head 2 can linearly move to the destination G. This operation is the X-axis direction avoidance operation.
- the position of the head 2 immediately after the completion of the X-axis direction avoidance operation is stored in the avoidance position storage unit 22 as an “X-axis direction avoidance position”.
- the X-axis direction avoidance operation will be described more specifically.
- the Y-axis direction sensor 12 detects an obstacle. Further, when the head 2 is moved in the positive direction of the X axis, the Y axis direction sensor 12 does not detect an obstacle.
- the “X-axis direction avoidance position” refers to the size of the head 2 and the head 2 when the Y-axis direction sensor 12 is further moved in the X-axis plus direction by a certain distance after the obstacle is no longer detected. Position.
- the head 2 is linearly moved from the “X-axis direction avoiding position” to the destination G as shown in FIG. Thereby, the search for the shortest route from the reference position to the destination G avoiding the obstacle is completed.
- a warning is displayed.
- the head 2 may move in the X-axis direction although the “Y-axis direction avoiding operation” is attempted. It is physically impossible to move the head 2 in the Y-axis minus direction to such a position as possible. Therefore, in such a case, the head 2 and the arm 4 cannot avoid an obstacle. In such a case, a warning is issued to the user and an obstacle is moved.
- the head 2 can be moved to the destination G by the shortest route via the X-axis direction avoidance position and the Y-axis direction avoidance position. That is, first, the head 2 is linearly moved from the current position to the Y-axis direction avoidance position, and then moved to the Y-axis direction avoidance position. Thereafter, the head 2 is linearly moved from the Y-axis direction avoidance position to the destination G. Thereby, even when the head 2 is at an arbitrary position, the head 2 can be moved to the destination G by the shortest route while reliably avoiding the head 2 and the arm 4 from coming into contact with the obstacle.
- the head 2 may be moved linearly from the current position to the destination G without passing through the X-axis direction avoidance position and the Y-axis direction avoidance position. Therefore, when the head 2 is moved, the X-axis direction avoidance position and the Y-axis direction avoidance are based on the coordinates of the current position of the head 2, the coordinates of the destination G, the X-axis direction avoidance position, and the Y-axis direction avoidance position. It is preferable that the control unit 16 determines whether or not to pass the position.
Abstract
Description
4 アーム
6 アーム移動機構
8 ガイドレール
10,12,14 障害物センサ
16 制御部
18 最短ルート移動部
20 障害物回避部
22 回避位置記憶部
24 警告発生部
Claims (3)
- ヘッド、水平面内における一方向であるY軸方向へ伸び、先端側で前記ヘッドを保持して前記Y軸方向へスライドするアーム、及び水平面内において前記Y軸方向と直交するX軸方向へ前記アームを移動させるアーム移動機構を備えた駆動部と、
前記駆動部に設けられ、前記ヘッド及び前記アームの移動経路上における障害物を検知する障害物センサと、
前記障害物センサからの信号に基づいて前記駆動部の動作を制御する制御部であって、前記ヘッドの目的地が設定された後で、前記目的地まで最短ルートで前記ヘッドが移動するように前記駆動部を駆動するように構成された最短ルート移動部、及び、前記ヘッドを最短ルートで移動させる際に前記障害物センサが障害物を検知したときに、前記アームの前記X軸方向への移動を停止させ、前記アームを前記X軸方向へ進行させても前記ヘッドと前記アームがその障害物と接触しない前記Y軸方向の位置に前記ヘッドがくるように、前記アームを前記Y軸方向へのみ移動させるY軸方向回避動作を実行し、そのY軸方向回避動作の後で、前記ヘッドを前記目的地方向へ直線的に移動させることができる位置まで、前記アームを前記X軸方向へのみ進行させるX軸方向回避動作を実行するように構成された障害物回避部を有する制御部と、を備え、
前記制御部の前記最短ルート移動部は、前記ヘッドが前記X軸方向回避動作の完了した直後の位置から前記目的地までの最短ルートを移動するように、前記駆動部を駆動するように構成されているオートサンプラ。 - 前記制御部は、前記Y軸方向回避動作を行なうことが物理的に不可能なときにユーザに対して警告を発する警告発生部をさらに備えている請求項1に記載のオートサンプラ。
- 前記Y軸方向回避動作が完了した直後の前記ヘッドの位置をY軸方向回避位置として記憶し、前記X軸方向回避動作が完了した直後の前記ヘッドの位置をX軸方向回避位置として記憶する回避位置記憶部をさらに備え、
前記最短ルート移動部は、前記回避位置記憶部に前記Y軸方向回避位置及び前記X軸方向回避位置が記憶されている状態で前記ヘッドを前記目的地まで移動させるときは、前記ヘッドが前記Y軸方向回避位置及び前記X軸方向回避位置を経由する前記目的地までの最短ルートで移動するように、前記駆動部を制御するように構成されている請求項1に記載のオートサンプラ。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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PCT/JP2016/061929 WO2017179157A1 (ja) | 2016-04-13 | 2016-04-13 | オートサンプラ |
US16/092,815 US20190128857A1 (en) | 2016-04-13 | 2016-04-13 | Autosampler |
RU2018135736A RU2018135736A (ru) | 2016-04-13 | 2016-04-13 | Автодозатор |
JP2018511823A JP6493623B2 (ja) | 2016-04-13 | 2016-04-13 | オートサンプラ |
CN201680084560.7A CN109073608B (zh) | 2016-04-13 | 2016-04-13 | 自动进样器 |
EP16898617.2A EP3444606A4 (en) | 2016-04-13 | 2016-04-13 | AUTOMATIC SAMPLER |
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PCT/JP2016/061929 WO2017179157A1 (ja) | 2016-04-13 | 2016-04-13 | オートサンプラ |
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EP (1) | EP3444606A4 (ja) |
JP (1) | JP6493623B2 (ja) |
CN (1) | CN109073608B (ja) |
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DE102018123363B4 (de) * | 2018-09-24 | 2021-01-07 | Bystronic Laser Ag | Verfahren zur Kollisionsvermeidung und Laserbearbeitungsmaschine |
DE102018125620A1 (de) * | 2018-10-16 | 2020-04-16 | Schuler Pressen Gmbh | Verfahren und Vorrichtung zum Schneiden einer Blechplatine aus einem kontinuierlich geförderten Blechband |
CN112747958B (zh) * | 2020-12-31 | 2021-11-09 | 武汉大学 | 仿生可避障大深度星际采样器及采样方法 |
CN113715006B (zh) * | 2021-08-19 | 2023-01-31 | 苏州华兴源创科技股份有限公司 | 机械手臂的驱动方法 |
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- 2016-04-13 EP EP16898617.2A patent/EP3444606A4/en not_active Withdrawn
- 2016-04-13 CN CN201680084560.7A patent/CN109073608B/zh not_active Expired - Fee Related
- 2016-04-13 JP JP2018511823A patent/JP6493623B2/ja active Active
- 2016-04-13 RU RU2018135736A patent/RU2018135736A/ru not_active Application Discontinuation
- 2016-04-13 WO PCT/JP2016/061929 patent/WO2017179157A1/ja active Application Filing
- 2016-04-13 US US16/092,815 patent/US20190128857A1/en not_active Abandoned
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See also references of EP3444606A4 * |
Also Published As
Publication number | Publication date |
---|---|
US20190128857A1 (en) | 2019-05-02 |
RU2018135736A3 (ja) | 2020-05-13 |
CN109073608B (zh) | 2020-10-09 |
JP6493623B2 (ja) | 2019-04-03 |
JPWO2017179157A1 (ja) | 2018-09-13 |
CN109073608A (zh) | 2018-12-21 |
EP3444606A1 (en) | 2019-02-20 |
RU2018135736A (ru) | 2020-05-13 |
EP3444606A4 (en) | 2019-10-30 |
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