WO2017163464A1 - グラフェンとカーボンナノチューブとの積層体の製造方法、グラフェンとカーボンナノチューブとの積層体からなる電極材料、および、それを用いた電気二重層キャパシタ - Google Patents
グラフェンとカーボンナノチューブとの積層体の製造方法、グラフェンとカーボンナノチューブとの積層体からなる電極材料、および、それを用いた電気二重層キャパシタ Download PDFInfo
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- WO2017163464A1 WO2017163464A1 PCT/JP2016/077866 JP2016077866W WO2017163464A1 WO 2017163464 A1 WO2017163464 A1 WO 2017163464A1 JP 2016077866 W JP2016077866 W JP 2016077866W WO 2017163464 A1 WO2017163464 A1 WO 2017163464A1
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- graphene
- laminate
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/52—Separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/04—Hybrid capacitors
- H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Definitions
- the present invention relates to a method for producing a laminate of graphene and carbon nanotubes, an electrode material comprising a laminate of graphene and carbon nanotubes, and an electric double layer capacitor using the same.
- Electrodes such as electric double layer capacitors and lithium ion batteries are attracting attention because of their large capacities.
- the performance of such an electricity storage device greatly depends on the electrode material, and the development of an electrode material capable of improving the capacitance, energy density, and power density is still active.
- Non-Patent Document 1 a porous graphene layered sheet electrode through which electrolyte ions can pass has been developed (see, for example, Non-Patent Document 1).
- Non-Patent Document 1 an energy density of 35 Wh / kg is achieved by accumulating graphene in layers.
- Non-Patent Document 2 there is a porous graphene sheet in which MgO is used as a template and graphene is grown by CVD (see, for example, Non-Patent Document 2).
- Non-Patent Document 2 electrolyte ions easily move in the vertical direction of the graphene sheet to achieve a capacitance of 303 F / g.
- Patent Document 1 a graphene sheet film in which carbon nanotubes are interposed between graphene sheets is known (see, for example, Patent Document 1).
- Patent Document 1 a capacitance of 290.6 F / g and an energy density of 62.8 Wh / kg are achieved by utilizing the conductivity of the carbon nanotubes in addition to the characteristics of the graphene sheet.
- Non-Patent Documents 3 and 4 and Patent Document 2 An electrode material made of graphene into which nanopores are introduced has also been developed (see, for example, Non-Patent Documents 3 and 4 and Patent Document 2).
- an electrode material in which nanopores are introduced into graphene by KOH using a microwave achieves an energy density of 100 Wh / kg.
- Non-Patent Document 4 introduces nanopores into graphene by exfoliating graphene oxide with microwaves, activating with KOH, and then heating. In such graphene, nanopores of 0.6 nm to 5 nm are introduced, and the specific surface area is 3100 m 2 / g.
- Patent Document 2 discloses that nanopores are introduced into graphene by a continuous electric field peeling method.
- Patent Document 2 discloses that a laminated body of graphene and carbon nanotubes into which nanopores are introduced by a continuous electric field peeling method is used as an electrode material. Such an electrode material achieves an energy density of 90.3 W
- Patent Document 3 discloses that a macromolecule is analyzed using a graphene-based nanopore device.
- Non-Patent Document 5 discloses a sensor that introduces nanopores into a graphene laminate and allows DNA to pass through the nanopores by an electric field.
- An object of the present invention is to provide a new method for producing a graphene laminate that can further improve the capacitor characteristics using graphene, to use this as an electrode material, and to provide an electric double layer capacitor using the same. is there.
- the present invention provides a new method for producing a laminate of graphene and carbon nanotubes. That is, the production method of the present invention is obtained by dispersing graphene in an MOH aqueous solution (M is an element selected from the group consisting of Li, Na and K), and adsorbing MOH on graphene, and the adsorbing step. Heating the graphene on which the MOH is adsorbed in a vacuum or in an inert atmosphere at a temperature range of 400 ° C. to 900 ° C.
- M is an element selected from the group consisting of Li, Na and K
- the graphene on which the MOH is adsorbed may be heated in a temperature range of 650 ° C. to 800 ° C. for a period of 10 minutes to 3 hours.
- the graphene on which the MOH is adsorbed may be heated in a temperature range of 650 ° C. to 750 ° C.
- the graphene on which the MOH is adsorbed may be heated in a temperature range of 675 ° C. to 725 ° C.
- the method may further include a step of thermally reducing for not less than 2 seconds and not more than 10 minutes to prepare graphene composed of one or more layers and three or less layers of graphene sheets.
- the molar concentration of the MOH aqueous solution may be in a range of 5M to 10M.
- the graphene may be dispersed so that the concentration of the graphene in the MOH aqueous solution is 5 g / L or more and 20 g / L or less.
- the adsorbing step may stir the aqueous MOH solution in which the graphene is dispersed for 12 hours to 30 hours at room temperature.
- the graphene and the carbon nanotube may be dispersed so that a mass ratio of the graphene to the carbon nanotube (graphene / carbon nanotube) satisfies a range of 1 to 50.
- the graphene and the carbon nanotube may be dispersed so that a mass ratio of the graphene to the carbon nanotube (graphene / carbon nanotube) satisfies a range of 5 to 15.
- the dispersion medium may be selected from the group consisting of water, N-methylpyrrolidone (NMP), N, N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO).
- NMP N-methylpyrrolidone
- DMF N-dimethylformamide
- DMSO dimethyl sulfoxide
- the graphene has pores through which electrolyte ions pass, and the graphene contains the carbon nanotubes at intervals through which electrolyte ions pass.
- the graphene may be composed of the graphene sheet having 1 to 3 layers, and may have pores having a pore diameter of 0.4 nm to 10 nm.
- the laminate may have a specific capacity in the range of 200 F / g or more and 400 F / g or less.
- the graphene may have a carboxy group and / or a hydroxyl group.
- the laminate may be manufactured by the method described above. In an electric double layer capacitor comprising an electrode according to the present invention and an electrolyte, the electrode is made of the electrode material described above, thereby solving the above-mentioned problems.
- the electrolyte may be an ionic liquid selected from the group consisting of EMI-TFSI, EMI-BF 4 and MPPp-TFSI or M′OH (M ′ is an alkali metal).
- the electrolyte may be EMI-TFSI, and the applied voltage may be 4V or less.
- the electrolyte may be MPPp-TFSI, and the applied voltage may be 4.5V or more.
- MOH is heated by heating graphene on which MOH (M is an element selected from the group consisting of Li, Na, and K) is adsorbed in a temperature range of 400 ° C. or higher and 900 ° C. or lower. It reacts with C of graphene to become M 2 CO 3 . M 2 CO 3 produced by the reaction is burned and removed by heating, so that graphene having pores through which electrolyte ions can pass is obtained.
- MOH is an element selected from the group consisting of Li, Na, and K
- the electrolyte ions can enter not only the surface of the graphene but also through the pores into the laminate, and the invaded electrolyte ions can easily move between the layers of graphene. Even inside the body, graphene and electrolyte ions can exchange electrons. As a result, the capacitance can be significantly increased, and the energy density and power density can be improved. Therefore, if a capacitor is constituted by using the electrode material comprising the laminate of the present invention, an electric double layer capacitor having high capacitor performance with increased energy density and power density can be provided.
- FIG. The figure which shows the SEM and TEM image of the laminated body of Example 2.
- Embodiment 1 In Embodiment 1, the laminate of the present invention and the manufacturing method thereof will be described.
- FIG. 1 is a schematic view of the laminate of the present invention.
- graphene 110 and carbon nanotubes 120 are laminated.
- the graphene 110 has pores 130 through which electrolyte ions pass.
- the graphene 110 is stacked via the carbon nanotubes 120, and the stacking interval is an interval through which electrolyte ions pass.
- FIG. 1 shows a state in which three layers of graphene 110 are stacked, but the present invention is not limited to this. Four or more layers may be laminated, or those laminated in a plurality of directions may be mixed.
- the inventors of the present application have found that such a design using graphene and carbon nanotubes can be an electrode material capable of remarkably increasing capacitor performance.
- electrolyte ions can enter not only the surface of the graphene 110 but also the inside of the laminate 100 through the pores 130 (that is, graphene of electrolyte ions) 110, and the invading electrolyte ions can easily move between the layers of the graphene 110 (that is, the movement of the electrolyte ions in the same horizontal direction as the plane direction of the graphene 110).
- the graphene 110 and electrolyte ions can exchange electrons even in the stacked body 100. As a result, the capacitance can be significantly increased, and the energy density and power density can be improved.
- the graphene 110 is preferably composed of one or more and three or less graphene sheets.
- the graphene 110 is a wall that forms a space between the graphene 110 layers, but the wall is extremely thin and flexible. Therefore, the size of the space between the graphene 110 layers can be easily expanded by the applied voltage using the flexibility of the graphene 110.
- the diameter of the pores 130 is preferably in the range of 0.4 nm to 10 nm. Thereby, electrolyte solution ion can be passed. More preferably, the pore diameter is in the range of 2 nm to 4 nm, and more electrolyte ions can be passed.
- the graphene 110 may have a functional group 140 such as a carboxy group or a hydroxyl group. Such functional groups 140 remain on the surface of the graphene 110 at the time of production, but even if these functional groups 140 are included, the capacitor performance can be maintained.
- a functional group 140 such as a carboxy group or a hydroxyl group.
- the laminated body 100 has a specific capacity in the range of 200 F / g or more and 400 F / g or less, if such an electrode material is used for a capacitor, the energy density and the power density can be improved.
- the carbon nanotube 120 may be an aggregate in which a plurality of carbon nanotubes exist, or may be a single body, and the form of existence thereof is not particularly limited.
- the carbon nanotubes 120 may exist independently, or may exist in a bundle form, a entanglement form, or a mixed form thereof.
- Various layers and outer diameters may be included.
- the carbon nanotube 120 is a single-walled carbon nanotube (SWNT), a double-walled carbon nanotube (DWNT), or a multi-walled carbon nanotube (MWNT), and is preferably a single-walled carbon nanotube.
- the single-walled carbon nanotube has a high conductivity of 10 4 S / cm or more, and the conductivity of the multilayer body 100 is improved, so that the capacitor performance can be improved.
- the carbon nanotubes 120 are controlled so that the stacking interval of the graphenes 110 in the stacked body 100 corresponds to electrolyte ions.
- the diameter of the carbon nanotube 120 is preferably 0.4 nm or more and 10 nm or less.
- the layer interval can be controlled by the applied voltage so that the electrolyte ions pass. More preferably, the diameter of the carbon nanotube 120 is 1 nm or more and 3 nm or less.
- the mass ratio of graphene to carbon nanotubes preferably satisfies the range of 1 to 50.
- the mass ratio is less than 1, the content of graphene decreases and the electrode material does not function.
- the mass ratio exceeds 50 the carbon nanotubes do not function as spacers.
- mass ratio fills the range of 5-15. If it is this range, the laminated body 100 can achieve the above-mentioned specific surface area and specific capacity.
- the carbon nanotubes 120 are used between the layers of the graphene 110, but a fibrous substance other than the carbon nanotubes 120 may be employed from the viewpoint of a spacer.
- the average value of the outer diameter of the fibrous material is not particularly limited, but from the viewpoint of more efficiently combining with the two-dimensional material, the average value of the outer diameter is within the range of 0.4 to 5.0 nm. Is preferably considered, and more preferably in the range of 1.0 to 3.0 nm.
- the average value of the outer diameter of the fibrous material is observed with an arbitrary magnification using, for example, a transmission electron microscope, and a plurality of fibrous materials arbitrarily extracted from a visual field in which a certain proportion of the visual field area is the fibrous material. It can be an arithmetic average value when the outer diameter of the substance is measured.
- the carbon nanotubes 120 are preferably dispersed and positioned without being aggregated in a bundle shape between the layers of the graphene 110.
- the electrolyte ions can easily move between the layers of the graphene 110.
- Such a dispersed state of the carbon nanotube 120 is achieved by the manufacturing method of the present invention described later.
- FIG. 2 is a schematic diagram for explaining the improvement of energy density and power density by the laminate 100 of the present invention.
- the laminate 100 of the present invention includes an electrolyte formed between layers of the graphene 110 through the pores 130 through which the electrolyte ions of the graphene 110 pass and the carbon nanotubes 120. And a space through which ions pass.
- the former pores 130 are formed in the graphene 110 composed of one or more and three or less graphene sheets.
- the size of the pores 130 is controlled by adjusting the heating conditions described later.
- the latter space is a space formed between the graphenes 110 composed of one to three layers of graphene sheets, and the walls forming the space are thin and flexible. Also, the size of the space can have a relatively large distribution from the interlayer of the graphene 110 to the carbon nanotube 120.
- the electrolyte ions 210 can enter and diffuse into the laminated body 100 from the pores 130 of the graphene 110, which is the surface of the laminated body 100. It is desirable that the electrolyte ions 210 that have entered and diffused further diffuse into the laminate 100. However, as shown in the upper part of FIG. 2B, the electrolyte ions 210 may not be able to diffuse any more in the stacked body 100 when the layer spacing of the graphene 110 is small. However, as described above, if the flexibility of the graphene 110 is used, the space formed between the layers of the graphene 110 can be easily expanded by the applied voltage when actually employed as the capacitor electrode material ( FIG. 2 (B) bottom). As a result, when the laminate 100 of the present invention is used as an electrode material, electrolyte ions significantly permeate and diffuse into the laminate 100, causing a dramatic increase in energy density and power density.
- FIG. 3 is a flowchart showing the manufacturing process of the laminate of the present invention.
- Step S310 Graphene is dispersed in an MOH aqueous solution (M is an element selected from the group consisting of Li, Na, and K), and MOH is adsorbed on the graphene.
- M is an element selected from the group consisting of Li, Na, and K
- the molar concentration of the MOH aqueous solution is preferably in the range of 0.1M to 10M. If it is less than 0.1M, sufficient MOH cannot be adsorbed on the graphene, so that pores may not be formed. When it exceeds 10M, MOH is excessively adsorbed on graphene, and the control of the pore diameter may be difficult.
- the molar concentration of the MOH aqueous solution is more preferably in the range of 5M or more and 10M or less. This ensures the adsorption of MOH on graphene.
- the MOH aqueous solution is preferably a KOH aqueous solution. KOH is easily adsorbed on graphene.
- Graphene is dispersed so that the concentration of graphene in the MOH aqueous solution is 1 g / L or more and 50 g / L or less.
- concentration of graphene in the aqueous solution is less than 1 g / L, since there is little graphene, MOH is excessively adsorbed on the graphene, and the control of the pore diameter may be difficult.
- concentration of graphene in the aqueous solution exceeds 50 g / L, since there is too much graphene, there is a possibility that sufficient MOH is not adsorbed on the graphene and pores are not formed.
- the graphene is dispersed so that the concentration of graphene in the MOH aqueous solution is 5 g / L or more and 20 g / L or less.
- sucks to a graphene and the graphene which has the above-mentioned pore diameter can be obtained.
- the graphene is dispersed so that the concentration of graphene in the MOH aqueous solution is 15 g / L or less. Thereby, MOH is reliably adsorbed on the graphene, and the graphene having the above-mentioned pore diameter can be obtained with good control.
- the specific procedure for adsorption is to hold an aqueous MOH solution in which graphene is dispersed for 12 hours or more and 30 hours or less at room temperature. Adsorption may occur even if the retention is less than 12 hours, but may not be sufficient. Even if it is kept for more than 30 hours, there is no change in the amount of adsorption. After the holding, the MOH aqueous solution in which graphene is dispersed is filtered.
- room temperature intends the temperature range of 15 degreeC or more and 30 degrees C or less.
- Step S320 The graphene adsorbed with MOH obtained in step S310 is heated in a temperature range of 400 ° C. to 900 ° C. in a vacuum or in an inert atmosphere. As a result, the following reaction occurs between MOH and graphene carbon, and finally, pores are formed in graphene at high density.
- the inert atmosphere can be nitrogen or a noble gas such as Ar.
- MOH adsorbed on graphene reacts with carbon of graphene to generate M carbonate (formula (1)).
- the M carbonate and the carbon of the graphene further react, decompose, and burn, thereby forming the pores 130 (FIG. 1).
- the M carbonate is decomposed and burned, and the pores 130 are formed.
- the heating temperature is in the range of 650 ° C. to 800 ° C.
- the heating time is in the range of 10 minutes to 3 hours.
- the graphene which has the pore which has the pore diameter of the range of 0.4 nm or more and 10 nm or less, and has a specific surface area (BET method) of 700 m 2 / g or more and 4000 m 2 / g or less is obtained.
- heating temperature is the range of 650 degreeC or more and 750 degrees C or less.
- graphene comprising pores having a pore size of 10nm or less in the range above 0.4 nm, graphene can be surely obtained, having the following specific surface area 700 meters 2 / g or more 4000 m 2 / g. More preferably, the heating temperature is in the range of 675 ° C. or higher and 725 ° C. or lower. Thereby, the graphene which has the pore which has the pore diameter of the range of 0.4 nm or more and 10 nm or less, and has a high specific surface area of 2000 m 2 / g or more and 4000 m 2 / g or less is obtained.
- Step S330 Graphene and carbon nanotubes having pores obtained in step S320 are dispersed in a dispersion medium, and graphene having pores and carbon nanotubes are laminated.
- the dispersion medium is preferably selected from the group consisting of water, N-methylpyrrolidone (NMP), N, N-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO).
- NMP, NMP, DMF, and DMSO can well disperse graphene and carbon nanotubes.
- Water can also disperse graphene and carbon nanotubes, but it is even better to use with a surfactant.
- the surfactant for example, sodium dodecylbenzenesulfonate, sodium dodecylsulfate, sodium cholate, sodium deoxycholate and the like can be used.
- the carbon nanotube is a single-walled carbon nanotube (SWNT), a double-walled carbon nanotube (DWNT) or a multi-walled carbon nanotube (MWNT), and preferably a single-walled carbon nanotube.
- SWNT single-walled carbon nanotube
- DWNT double-walled carbon nanotube
- MWNT multi-walled carbon nanotube
- Single-walled carbon nanotubes have a high conductivity of 10 4 S / cm or more, and can provide a laminate with improved conductivity.
- step S330 it is preferable to disperse the graphene and carbon nanotube having pores in a dispersion medium so that the mass ratio of graphene to the carbon nanotube (graphene / carbon nanotube) is in the range of 1 to 50.
- the mass ratio is less than 1, the content of graphene decreases and the electrode material does not function. If the mass ratio exceeds 50, the carbon nanotubes may not function as spacers and a laminate may not be formed.
- mass ratio fills the range of 5-15. If it is this range, a graphene and a carbon nanotube can be laminated
- the specific procedure for stacking may be, for example, by dispersing graphene having pores in a dispersion medium, adding carbon nanotubes thereto, and stirring at room temperature. Thereby, a laminate in which carbon nanotubes are positioned between graphene layers can be obtained in a self-organizing manner.
- the graphene manufactured by the thermal reduction method is composed of one or more graphene sheets and is excellent in dispersibility. Furthermore, since graphene produced by the thermal reduction method has abundant functional groups such as carboxy group and hydroxyl group in the production process, if graphene having such a functional group is used as a starting material, MOH is obtained in step S310. Adsorption to graphene is promoted, and pores can be formed at high density.
- FIG. 4 is a flowchart showing a process for producing graphene by a thermal reduction method.
- Step S410 The graphene oxide dispersion liquid in which the graphene oxide is dispersed in water is freeze-dried. Thereby, it becomes the graphene oxide in a foaming state.
- the graphene oxide may be a commercially available graphene oxide, or may be produced from graphite particles by, for example, the Brodie method, the Staudenmeier method, the Hummer method, the modified Hummers method, or the like. Functional groups such as a carbonyl group, a carboxy group, and a hydroxyl group are imparted to the surface of the graphene oxide.
- Graphene oxide is also called graphene oxide (GO).
- the graphene oxide is dispersed in water so that the concentration of the graphene oxide in the dispersion is 0.5 mg / mL to 50 mg / mL. More preferably, the graphene oxide is dispersed in water so that the concentration is 1 mg / mL or more and 5 mg / mL or less. Thereby, freeze-drying is promoted, and a foamed graphene oxide having a density of 1 g / L or more and 50 g / L or less is obtained.
- the specific procedure for freeze-drying is to hold the graphene oxide dispersion controlled to the above-mentioned concentration in a dry freezer maintained at ⁇ 5 ° C. or lower for 5 hours to 100 hours, or in liquid nitrogen. What is necessary is just to immerse for 1 minute or more and 10 minutes or less.
- Step S420 The graphene oxide dispersion freeze-dried in Step S410 is thermally reduced at a temperature range of 300 ° C. to 700 ° C. for a time of 1 second to 10 minutes. Thereby, the carbonyl group imparted to the freeze-dried graphene oxide dispersion is removed, and the graphene oxide is reduced to graphene.
- the reduced graphene is composed of one or more layers of graphene sheets, but the functional groups such as carboxy group and hydroxyl group provided in step S410 remain, so that the hydrophilicity is maintained, and in step S310, the MOH Adsorption can be promoted.
- the atmosphere of thermal reduction can be in the air or in an inert atmosphere such as argon, nitrogen or the like.
- Embodiment 2 In Embodiment 2, an application using the electrode material formed of the laminate of the present invention obtained in Embodiment 1 will be described.
- FIG. 5 is a schematic diagram of an electric double layer capacitor provided with an electrode material composed of the laminate of the present invention.
- the electric double layer capacitor of the present invention includes at least an electrode and an electrolyte.
- a positive electrode 510 and a negative electrode 520 are immersed in an electrolyte 530 as electrodes.
- the positive electrode 510 and the negative electrode 520 are made of the electrode material of the laminate 100 described in the first embodiment.
- the electrolyte 530 comprises 1-ethyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide (EMI-TFSI), 1-ethyl-3-methylimidazolium borofluoride (EMI-BF 4 ) and 1-methyl-1-
- An ionic liquid selected from the group consisting of propylpiperidinium bis (trifluoromethylsulfonyl) imide (MPPp-TFSI) or M′OH (M ′ is an alkali metal).
- the laminate of the present invention can promote the penetration / diffusion of electrolyte ions by the applied voltage.
- the electric double layer capacitor 500 is operated at 4 V or less, if EMI-TFSI is selected as the electrolyte, the specific capacity can be improved and the energy density can be increased.
- the electric double layer capacitor 500 is operated at 4.5 V or more, if MPPp-TFSI is selected as the electrolyte, the specific capacity can be improved and the energy density can be increased.
- the electric double layer capacitor 500 further includes a separator 540 between the positive electrode 510 and the negative electrode 520 to isolate the positive electrode 510 and the negative electrode 520.
- the material of the separator 540 is, for example, fluoropolymer, polyether such as polyethylene oxide or polypropylene oxide, polyolefin such as polyethylene or polypropylene, polyacrylonitrile, polyvinylidene chloride, polymethyl methacrylate, polymethyl acrylate, polyvinyl alcohol, polymethacrylo It is a material selected from nitrile, polyvinyl acetate, polyvinyl pyrrolidone, polyethyleneimine, polybutadiene, polystyrene, polyisoprene, polyurethane polymers and derivatives thereof, cellulose, paper, and nonwoven fabric.
- fluoropolymer polyether such as polyethylene oxide or polypropylene oxide
- polyolefin such as polyethylene or polypropylene
- polyacrylonitrile polyvinylidene chloride
- polymethyl methacrylate polymethyl acrylate
- polyvinyl alcohol polymethacrylo It is a material selected from nitrile,
- the positive electrode 510, the negative electrode 520, the electrolyte 530, and the separator 540 described above are accommodated in the cell 550. Further, each of the positive electrode 510 and the negative electrode 520 may have an existing current collector.
- Such an electric double layer capacitor 500 may be a chip type, a coin type, a mold type, a pouch type, a laminate type, a cylindrical type, a square type, or the like, and is used in a module in which a plurality of these are connected. May be.
- the electrolyte ions (anions) of the electrolyte 530 are adsorbed on the positive electrode 510, and the electrolyte ions (cations) of the electrolyte 530 are adsorbed on the negative electrode 520, respectively.
- an electric double layer is formed on each of the positive electrode 510 and the negative electrode 520 and charged.
- the positive electrode 510 and the negative electrode 520 are formed from the laminate described in Embodiment 1, adsorption and diffusion of cations and anions are facilitated, and high rate characteristics can be achieved.
- the positive electrode 510 and the negative electrode 520 are formed from the stacked body described in Embodiment 1, not only the surface of the stacked body but also a large amount of electrolyte ions are adsorbed to form an electric double layer. Is done. As a result, the exchange of electrons between graphene and electrolyte ions increases, and a high energy density can be achieved.
- the anions and cations adsorbed on the positive electrode 510 and the negative electrode 520 are desorbed and discharged.
- the positive electrode 510 and the negative electrode 520 are formed from the laminate described in the first embodiment, desorption / diffusion of electrolyte ions is facilitated, and high rate characteristics and power density can be achieved.
- power density can also be improved with ease of desorption / diffusion.
- the electric double layer capacitor 500 of the present invention functions as an electrode material having a high energy density (100 Wh / kg or more) and a high power density (500 kW / kg or more), so that quick charging can be performed. And can achieve high energy density and high power density. Moreover, since the formation of an electric double layer is used for charging / discharging, it is excellent in repeated use.
- the electric double layer capacitor 500 of the present invention can be used for wind power generation, electric vehicles and the like.
- the laminate of the present invention is effective as an electrode material, but biofunctional molecules such as DNA, enzymes, antibodies, etc. in the pores of graphene through which electrolyte ions pass, or spaces between graphene layers through which electrolyte ions pass If this is held, a sensor using these biofunctional molecules as sensitive elements can be constructed.
- Example 1 In Example 1, a graphene produced by a thermal reduction method was used to produce a laminate in which graphene having pores formed by heating at 650 ° C. and carbon nanotubes (CNT) were laminated.
- CNT carbon nanotubes
- graphene oxide Prior to producing graphene by the thermal reduction method, graphene oxide was prepared from natural graphite powder by the modified Hummers method. Graphite powder (2 g) and sodium nitrate (1 g) were mixed, sulfuric acid (50 mL) was added, and the mixture was stirred in an ice bath. Sodium permanganate (12 g) was added slowly so that the temperature did not exceed 20 ° C. These mixtures were reacted in a 35 ° C. water bath for 1 hour. Thereby, the mixture became a paste.
- the yellow suspension was centrifuged, and the obtained solid was washed 6 times with 5% by mass hydrochloric acid and deionized water to remove metal ions and acid and dried in vacuum. In this way, graphene oxide was obtained.
- a graphene oxide dispersion (2 mg / mL) in which graphene oxide was dispersed in water was freeze-dried at ⁇ 10 ° C. for 72 hours (step S410 in FIG. 4).
- an ocher graphene oxide dispersion in a foamed state having a density of 2 g / L was obtained.
- the ocher-colored graphene oxide dispersion in the foamed state was thermally reduced in the atmosphere at 400 ° C. for 1 minute (step S420 in FIG. 4). As a result, the ocher graphene oxide dispersion became black graphene.
- the resulting graphene had a density of 0.07 g / L.
- the morphology of the graphene obtained was observed with a scanning electron microscope (SEM, JSM-6500 manufactured by JEOL Ltd.) and a transmission electron microscope (TEM, EMM-2100 manufactured by JEOL Ltd.). It confirmed that it consisted of a graphene sheet of 3 or more layers.
- the obtained graphene (0.4 g) was dispersed in a KOH aqueous solution (7M) and held at room temperature for 24 hours (step S310 in FIG. 3).
- the concentration of graphene in the KOH aqueous solution was 10 g / L.
- KOH was made to adsorb
- the KOH aqueous solution in which graphene was dispersed was filtered.
- the graphene after filtration was heated in an Ar atmosphere at a temperature of 650 ° C. for 0.5 hour (step S320 in FIG. 3). Thereby, KOH adsorbed on the graphene and carbon of the graphene reacted to generate potassium carbonate, and the potassium carbonate was burned and decomposed to form pores.
- an electric double layer capacitor using this as an electrode was manufactured.
- the specific manufacturing procedure was as follows. The product (90 wt%) and polytetrafluoroethylene (PTFE, 10 wt%) were dispersed in ethanol and sonicated to obtain a suspension. The suspension was passed through a porous membrane by vacuum filtration. This porous membrane was dried in vacuum for 24 hours, and the membrane made of graphene and PTFE obtained by vacuum filtration was cut into a circle and used as an electrode. The electrode was circular with a diameter of 15 mm and weighed about 1 mg. Next, a porous separator (540 in FIG. 5) is placed between these electrodes (510 and 520 in FIG.
- An electric double layer capacitor (500 in FIG. 5) was manufactured by filling each with KOH (530 in FIG. 5). The electric double layer capacitor was assembled in a glove box filled with Ar gas.
- Electrochemical measurement of the electric double layer capacitor was performed using a multi-channel potentiostat galvanostat (manufactured by Bio-Logic, VMP-300). Specific capacity-voltage measurement (CV measurement) and galvanostat charge / discharge measurement were performed in a potential range of 0 V to 3.5 V at room temperature.
- CV measurement Specific capacity-voltage measurement
- galvanostat charge / discharge measurement were performed in a potential range of 0 V to 3.5 V at room temperature.
- I (A) is a constant current
- m (g) is the total mass of the two electrodes
- dV / dt (V / s) is Vmax (voltage at the start of discharge) and 1/2 Vmax.
- Is a slope obtained by linear fitting of the discharge curve.
- a laminate was formed using graphene having pores, which is graphene after heating. That is, graphene having pores is dispersed in N-methylpyrrolidone (NMP, 500 mL) as a dispersion medium, and then single-walled CNT (Cheap Tube Inc., purity 90% or more) is added, and at room temperature, 2 The mixture was stirred for a time (step S330 in FIG. 3). Here, graphene and CNT were dispersed so that the mass ratio of graphene to CNT was 10.
- NMP N-methylpyrrolidone
- the single-walled CNT used contained 3 wt% amorphous carbon.
- the single-walled CNT had a specific surface area of 407 m 2 / g, a conductivity of 10 4 S / m, a length of 5 ⁇ m to 30 ⁇ m, and a diameter of 4 nm to 10 nm.
- CV measurement and galvanostat charge / discharge measurement were performed in a potential range of 0 V to 3.5 V at room temperature, and the specific capacity, energy density, and power density were calculated.
- Example 2 In Example 2, a graphene produced by a thermal reduction method was used to produce a laminate in which graphene having pores formed by heating at 700 ° C. and CNTs were laminated. Since Example 2 is the same as Example 1 except that the heating temperature in Step S320 is set to 700 ° C., description thereof is omitted.
- Example 2 the morphology of the graphene after heating in step S320 and before lamination in step S330 was observed by atomic resolution TEM, and the Raman spectrum was measured. The nitrogen adsorption / desorption isotherm by the BET method was measured to determine the specific surface area and pore distribution. These results are shown in FIGS. 7 to 11 and Table 2.
- Example 2 As in Example 1, the structure of the stacked body after step S330 was observed with SEM and TEM. The results are shown in FIG. 14 and FIG.
- Example 2 an electric double layer capacitor using the laminate after step S330 as an electrode was prepared, and CV measurement and galvanostat charge / discharge measurement were performed in a potential range of 0 V to 3.5 V at room temperature. The specific capacity, energy density and power density were calculated. The results are shown in FIGS. 16 and 17 and Table 3.
- Example 3 In Example 3, using a graphene manufactured by a thermal reduction method, a laminated body in which graphene having pores formed by heating at 800 ° C. and CNTs were stacked was manufactured. Since Example 3 is the same as Example 1 except that the heating temperature in Step S320 is set to 800 ° C., description thereof is omitted.
- Example 2 the morphology of the graphene after heating in step S320 and before lamination in step S330 was observed by atomic resolution TEM, and the Raman spectrum was measured. The nitrogen adsorption / desorption isotherm by the BET method was measured to determine the specific surface area and pore distribution. These results are shown in FIGS. 9 and 11 and Table 2.
- Example 1 the structure of the stacked body after step S330 was observed with SEM and TEM. An electric double layer capacitor using the laminated body after step S330 as an electrode is manufactured, and CV measurement and galvanostat charge / discharge measurement are performed in a potential range of 0 V to 3.5 V at room temperature, specific capacity, energy density And the power density was calculated.
- Comparative Example 4 In Comparative Example 4, a laminate of graphene and CNT having no pores was produced.
- graphene produced by the thermal reduction method as in Example 1 was heated at a temperature of 650 ° C. for 0.5 hours in an Ar atmosphere.
- Graphene after heating was dispersed in NMP, and then single-walled CNTs were added and stirred at room temperature for 2 hours.
- graphene and CNT were dispersed so that the mass ratio of graphene to CNT was 10. That is, Comparative Example 4 was the same as Example 2 except that Step S310 was not passed.
- Example 2 the morphology of graphene after heating and before lamination was observed by atomic resolution TEM, and the Raman spectrum was measured. The nitrogen adsorption / desorption isotherm by the BET method was measured to determine the specific surface area and pore distribution. These results are shown in FIG. 8, FIG. 9, FIG. 10, and Table 2.
- Example 2 In the same manner as in Example 1, an electric double layer capacitor using graphene after heating and before lamination as an electrode was prepared, and CV measurement and galvanostat charge / discharge measurement were performed at 0 V to 3 at room temperature. The specific capacity, energy density, and power density were calculated in a potential range of 0.5 V. These results are shown in FIGS. 12 and 13 and Table 2.
- Example 2 the structure of the laminate was observed with SEM and TEM.
- An electric double layer capacitor using the laminated body after step S330 as an electrode is manufactured, and CV measurement and galvanostat charge / discharge measurement are performed in a potential range of 0 V to 3.5 V at room temperature, specific capacity, energy density And the power density was calculated.
- Comparative Example 5 In Comparative Example 5, a capacitor was produced according to the procedure of Example 3 described in Patent Document 2. The capacitor was subjected to CV measurement and galvanostat charge / discharge measurement at room temperature in a potential range of 0 V to 3.5 V, and the specific capacity, energy density, and power density were calculated. These results are shown in FIG.
- Reference Example 6 a laminate of graphene and CNT in which pores were not intentionally formed was manufactured.
- the graphene used for the laminate was prepared as follows. Graphene oxide (100 mg) produced by the modified Hummers method in the same manner as in Example 1 was added to 30 mL of distilled water, and sonicated for 30 minutes to be dispersed. This was heated to 100 ° C. on a hot plate, hydrazine hydrate (3 mL) was added, and the mixture was held at 98 ° C. for 24 hours for reduction. Thereby, black graphene was obtained. Black graphene was washed with distilled water to remove excess hydrazine.
- Example 2 Similar to Example 1, the structure of the laminate was observed with SEM and TEM.
- electrolyte using various ionic liquids (EMI-TFSI, EMI-BF 4 and MPPp-TFSI), was prepared an electric double layer capacitor with an electrode laminate.
- CV measurement and galvanostat charge / discharge measurement were performed in a potential range of 0 V to 3.5 V at room temperature, and the specific capacity, energy density, and power density were calculated. These results are shown in FIG. 19 and Table 4.
- the cycle characteristics of the electric double layer capacitor were investigated. The charge / discharge of the electric double layer capacitor was repeated up to 6000 times, and after each charge / discharge cycle, the change in specific capacity at a current density of 0.2 A / g was measured. The results are shown in FIG.
- FIG. 6 is a diagram showing an atomic resolution TEM of graphene after heating in Example 1.
- FIG. 7 is a diagram showing an atomic resolution TEM of graphene after heating in Example 2.
- FIG. 8 is a graph showing Raman spectra of graphene after heating in Example 2 and Comparative Example 4.
- FIG. 8A is a Raman spectrum of graphene after heating in Example 2
- FIG. 8B is a Raman spectrum of graphene after heating in Comparative Example 4.
- FIG. 8 (A) showed D band at 1340 cm -1, G band at 1590 cm -1, three prominent peaks of 2D band at 2680cm -1.
- the Raman spectrum of FIG. 8B also showed peaks of the D band and G band, but these peak intensities were lower than that of FIG. Further, the Raman spectrum in FIG. 8B did not show a clear 2D band peak. From this, it was found that the crystallinity of graphene is remarkably improved by steps S310 and S320 according to the present invention.
- the Raman spectra of graphene after heating in Examples 1 and 3 were also similar to that in FIG.
- FIG. 9 is a graph showing nitrogen adsorption / desorption isotherms of graphene after heating in Examples and Comparative Examples 1 to 4.
- FIG. 10 is a graph showing the pore distribution of graphene after heating in Example 2 and Comparative Example 4.
- FIG. FIG. 11 is a graph showing the pore distribution of graphene after heating in Examples 1 to 3.
- the graphene after heating in Examples 1 to 3 had pores having a pore diameter of 0.4 nm or more and 10 nm or less.
- the graphene after heating in Example 2 mainly has pores in the range of 2 nm or more and 4 nm or less, and can pass more electrolyte ions.
- FIG. 12 is a diagram showing a specific capacity-voltage curve (CV curve) and a charge / discharge curve when graphene after heating in Example 2 and Comparative Example 4 is used and the electrolyte is EMI-BF 4 .
- FIG. 13 is a diagram showing a specific capacity-voltage curve (CV curve) and a charge / discharge curve when graphene after heating in Example 2 and Comparative Example 4 is used and the electrolyte is KOH.
- the CV curves in FIGS. 12 and 13 are the results when the sweep speed is 50 mV / s. Even when the graphene after heating of Example 2 and Comparative Example 4 was used, a rectangular CV curve representing an ideal electric double layer capacitor was shown. However, the capacity of the electric double layer capacitor with graphene after heating in Example 2 was significantly larger than that in Comparative Example 4. Although not shown, the CV curves of the heated graphene of Example 1 and Example 3 using the graphene were the same.
- the charge / discharge curves in FIGS. 12 and 13 both showed a constant current charge / discharge curve typical of an electric double layer capacitor.
- the charge / discharge curve in the case of using graphene after heating in Example 2 was significantly longer than that in Comparative Example 4.
- the charge / discharge curves of the graphene after heating in Example 1 and Example 3 were the same. Based on the specific capacity obtained, energy density and power density were calculated. As shown in Table 2, it was found that when graphene having pores is used as an electrode material, both energy density and output density are improved as compared with the case of using graphene without pores as an electrode material.
- FIG. 14 is a diagram showing a TEM image of the stacked body of Example 2.
- FIG. 15 is a diagram showing an SEM and TEM image of the laminate of Example 2.
- FIG. 16 is a diagram showing a specific capacity-voltage curve (CV curve) when the laminates of Example 2 and Comparative Example 4 are used and the electrolyte is EMI-BF 4 .
- FIG. 17 is a diagram showing a charge / discharge curve when the laminates of Example 2 and Comparative Example 4 are used and the electrolyte is EMI-BF 4 .
- the CV curves in FIG. 16 are the results when the sweep speed is 50 mV / s.
- the laminates of Example 2 and Comparative Example 4 both showed rectangular CV curves representing ideal electric double layer capacitors.
- the capacitances of the electric double layer capacitors using the laminates of Example 2 and Comparative Example 4 were larger than those of the graphene after heating of Example 2 and Comparative Example 4, respectively. From this, it was confirmed that an increase in capacity can be expected by stacking.
- the CV curves of the laminates of Example 1 and Example 3 were the same.
- the charge / discharge curves in FIG. 17 all showed a constant current charge / discharge curve typical of an electric double layer capacitor.
- the charge / discharge curve in the case of using the laminate of Example 2 has a significantly longer discharge time than that in the case of using graphene after heating in Example 2.
- the charge / discharge curve when the laminate of Example 2 was used was significantly longer in discharge time than that of Comparative Example 4.
- the charge / discharge curves of the graphene after heating in Example 1 and Example 3 were the same. Based on the specific capacity obtained, energy density and power density were calculated.
- the laminated body of graphene and CNT having pores according to the steps S310 to S330 of the present invention remarkably improves electrical characteristics, a high energy density of 100 Wh / kg or more, and 500 kW / kg or more. It has been shown that an electric double layer capacitor having a high energy density and a high power density can be provided. This suggests that graphene has a large specific surface area due to pores, and electrolyte ions pass through the pores and diffuse into the laminate.
- FIG. 18 is a view showing a specific capacity-voltage curve (CV curve) and a charge / discharge curve when the laminate of Comparative Example 5 is used and the electrolyte is EMI-BF 4 .
- the specific capacity of the laminate of Example 2 is that of the laminate of Comparative Example 5. Shown to be significantly larger than that of the body. Comparing the charge / discharge curve of FIG. 18B with that of FIG. 17A, the discharge time of the laminate of Example 2 was significantly longer than that of the laminate of Comparative Example 5.
- FIG. 19 is a graph showing specific capacity-voltage curves (CV curves) and charge / discharge curves for various electrolytes using the laminate of Reference Example 6.
- 19A to 19C are CV curves when the electrolytes are EMI-TFSI, EMI-BF 4 and MPPp-TFSI, respectively.
- 19D to 19F are charge / discharge curves when the electrolyte is EMI-TFSI, EMI-BF 4 and MPPp-TFSI, respectively.
- FIGS. 19 (A) and 19 (B) a peak was shown in a region indicated by a dotted line at an applied voltage of 4 V or more.
- 19D and 19E also show inflection points in the region indicated by the dotted line at an applied voltage of 4 V or higher. From this, it was found that the electrolyte (ionic liquid) and the electrode reacted at an applied voltage of 4 V or more.
- an ionic liquid is used as the electrolyte, it is desirable to consider the applied voltage and the reaction with the electrode material.
- FIGS. 19C and 19F at an applied voltage of 4 V or more, MPPp It is suggested that -TFSI is preferable as an electrolyte because it does not react with the laminate of graphene and CNT.
- FIG. 20 is a diagram showing cycle characteristics for various electrolytes using the laminate of Reference Example 6.
- a laminate of graphene and CNT having pores excellent in capacitor characteristics can be obtained.
- An electric double layer capacitor using such a laminate as an electrode is advantageous for wind power generation, electric vehicles and the like.
- Such a laminate constructs a sensor that uses biofunctional molecules such as DNA, enzymes, and antibodies in the pores of graphene, or spaces between graphene layers, and uses these biofunctional molecules as sensitive elements. it can.
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Abstract
Description
前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、650℃以上800℃以下の温度範囲で10分以上3時間以下の時間、加熱してもよい。
前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、650℃以上750℃以下の温度範囲で加熱してもよい。
前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、675℃以上725℃以下の温度範囲で加熱してもよい。
前記吸着させるステップに先立って、グラフェン酸化物が水に分散したグラフェン酸化物分散液を冷凍乾燥するステップと、前記冷凍乾燥されたグラフェン酸化物分散液を300℃以上700℃以下の温度範囲で1秒以上10分以下の時間熱還元し、1層以上3層以下のグラフェンシートからなるグラフェンを調製するステップとをさらに包含してもよい。
前記吸着させるステップにおいて、前記MOH水溶液のモル濃度は、5M以上10M以下の範囲であってもよい。
前記吸着させるステップは、前記MOH水溶液における前記グラフェンの濃度が5g/L以上20g/L以下となるように前記グラフェンを分散してもよい。
前記吸着させるステップは、室温において、12時間以上30時間以下の間、前記グラフェンが分散したMOH水溶液を撹拌してもよい。
前記積層させるステップは、前記グラフェンと前記カーボンナノチューブとを、前記カーボンナノチューブに対する前記グラフェンの質量比(グラフェン/カーボンナノチューブ)が、1以上50以下の範囲を満たすように、分散させてもよい。
前記積層させるステップは、前記グラフェンと前記カーボンナノチューブとを、前記カーボンナノチューブに対する前記グラフェンの質量比(グラフェン/カーボンナノチューブ)が、5以上15以下の範囲を満たすように、分散させてもよい。
前記積層させるステップにおいて、前記分散媒は、水、N-メチルピロリドン(NMP)、N,N-ジメチルホルムアミド(DMF)およびジメチルスルホキシド(DMSO)からなる群から選択されてもよい。
本発明によるグラフェンとカーボンナノチューブとの積層体からなる電極材料は、前記グラフェンは、電解液イオンが通過する細孔を有し、前記グラフェンは、電解液イオンが通過する間隔で、前記カーボンナノチューブを介して積層されており、これにより上記課題を解決する。
前記グラフェンは、前記1層以上3層以下のグラフェンシートからなり、細孔径が0.4nm以上10nm以下である細孔を有してもよい。
前記積層体は、200F/g以上400F/g以下の範囲の比容量を有してもよい。
前記グラフェンは、カルボキシ基および/または水酸基を有してもよい。
前記積層体は、上述の方法によって製造されてもよい。
本発明による電極と、電解質とを備えた電気二重層キャパシタは、前記電極は、上述の電極材料からなり、これにより上記課題を解決する。
前記電解質は、EMI-TFSI、EMI-BF4およびMPPp-TFSIからなる群から選択されるイオン液体またはM’OH(M’はアルカリ金属)であってもよい。
前記電解質は、EMI-TFSIであり、印加電圧は4V以下であってもよい。
前記電解質は、MPPp-TFSIであり、印加電圧は4.5V以上であってもよい。
実施の形態1では、本発明の積層体およびその製造方法について説明する。
図3は、本発明の積層体の製造工程を示すフローチャートである。
6MOH+2C→2M+3H2+2M2CO3・・・(1)
次いで、さらに加熱が進むと、(2)式に示すように、Mの炭酸塩とグラフェンの炭素とがさらに反応し、分解・燃焼することにより、細孔130(図1)が形成される。
M2CO3+2C→2K+3CO・・・(2)
あるいは、加熱が進むと、(3)、(4)式に示すように、Mの炭酸塩が分解・燃焼し、細孔130が形成される。
M2CO3→K2O+CO2・・・(3)
CO2+C→2CO・・・(4)
図4は、熱還元法によるグラフェンの製造工程を示すフローチャートである。
実施の形態2では、実施の形態1で得た本発明の積層体からなる電極材料を用いた用途について説明する。
実施例1では、熱還元法によって製造したグラフェンを用いて、650℃の加熱により細孔を形成したグラフェンとカーボンナノチューブ(CNT)とを積層した積層体を製造した。
実施例2では、熱還元法によって製造したグラフェンを用いて、700℃の加熱により細孔を形成したグラフェンとCNTとを積層した積層体を製造した。実施例2は、ステップS320における加熱温度を700℃にした以外、実施例1と同様であるため、説明を省略する。
実施例3では、熱還元法によって製造したグラフェンを用いて、800℃の加熱により細孔を形成したグラフェンとCNTとを積層した積層体を製造した。実施例3は、ステップS320における加熱温度を800℃にした以外、実施例1と同様であるため、説明を省略する。
比較例4では、細孔を有しないグラフェンとCNTとの積層体を製造した。比較例4では、実施例1と同様に熱還元法によって製造したグラフェンを、Ar雰囲気中、650℃の温度で0.5時間加熱した。加熱後のグラフェンをNMPに分散させ、次いで、単層CNTを添加し、室温にて、2時間撹拌した。ここで、グラフェンとCNTとは、CNTに対するグラフェンの質量比が10となるように分散された。すなわち、比較例4では、ステップS310を経ない以外は、実施例2と同様であった。
比較例5では、特許文献2に記載の実施例3の手順にしたがってキャパシタを作製した。キャパシタについて、CV測定、および、ガルバノスタット充放電測定を、室温において、0V~3.5Vの電位範囲で行い、比容量、エネルギー密度およびパワー密度を算出した。これらの結果を図18に示す。
参考例6では、細孔を意図的に形成しないグラフェンとCNTとの積層体を製造した。積層体に用いたグラフェンは、次のようにして調製された。実施例1と同様に改良Hummers法により製造されたグラフェン酸化物(100mg)を、蒸留水30mLに加え、30分間超音波処理を行い、分散させた。これを、ホットプレート上で100℃になるまで加熱し、ヒドラジン水和物(3mL)を加え、98℃で24時間保持し、還元させた。これにより、黒色のグラフェンが得られた。黒色のグラフェンを蒸留水で洗浄し、余剰のヒドラジンを除去した。
図7は、実施例2の加熱後のグラフェンの原子分解能TEMを示す図である。
図11は、実施例1~3の加熱後のグラフェンの細孔分布を示す図である。
図13は、実施例2および比較例4の加熱後のグラフェンを用い、電解質がKOHの場合の比容量-電圧曲線(CV曲線)および充放電曲線を示す図である。
図15は、実施例2の積層体のSEMおよびTEM像を示す図である。
図17は、実施例2および比較例4の積層体を用い、電解質がEMI-BF4の場合の充放電曲線を示す図である。
110 グラフェン
120 カーボンナノチューブ
130 細孔
140 官能基
500 電気二重層キャパシタ
510 正極電極
520 負極電極
530 電解質
540 セパレータ
550 セル
Claims (20)
- グラフェンとカーボンナノチューブとの積層体を製造する方法であって、
MOH水溶液(Mは、Li、NaおよびKからなる群から選択される元素)にグラフェンを分散し、グラフェンにMOHを吸着させるステップと、
前記吸着させるステップで得られたMOHが吸着したグラフェンを、真空中、または、不活性雰囲気中、400℃以上900℃以下の温度範囲で加熱し、前記グラフェンに細孔を形成するステップと、
前記細孔を形成するステップで得られた細孔を有するグラフェンおよびカーボンナノチューブを分散媒に分散させ、前記細孔を有するグラフェンと前記カーボンナノチューブとを積層させるステップと
を包含することを特徴とするグラフェンとカーボンナノチューブとの積層体の製造方法。 - 前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、650℃以上800℃以下の温度範囲で10分以上3時間以下の時間、加熱する、請求項1に記載の方法。
- 前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、650℃以上750℃以下の温度範囲で加熱する、請求項2に記載の方法。
- 前記細孔を形成するステップは、前記MOHが吸着したグラフェンを、675℃以上725℃以下の温度範囲で加熱する、請求項3に記載の方法。
- 前記吸着させるステップに先立って、
グラフェン酸化物が水に分散したグラフェン酸化物分散液を冷凍乾燥するステップと、
前記冷凍乾燥されたグラフェン酸化物分散液を300℃以上700℃以下の温度範囲で1秒以上10分以下の時間熱還元し、1層以上3層以下のグラフェンシートからなるグラフェンを調製するステップと
をさらに包含する、請求項1に記載の方法。 - 前記吸着させるステップにおいて、前記MOH水溶液のモル濃度は、5M以上10M以下の範囲である、請求項1に記載の方法。
- 前記吸着させるステップは、前記MOH水溶液における前記グラフェンの濃度が5g/L以上20g/L以下となるように前記グラフェンを分散する、請求項6に記載の方法。
- 前記吸着させるステップは、室温において、12時間以上30時間以下の間、前記グラフェンが分散したMOH水溶液を撹拌する、請求項1に記載の方法。
- 前記積層させるステップは、前記グラフェンと前記カーボンナノチューブとを、前記カーボンナノチューブに対する前記グラフェンの質量比(グラフェン/カーボンナノチューブ)が、1以上50以下の範囲を満たすように、分散させる、請求項1に記載の方法。
- 前記積層させるステップは、前記グラフェンと前記カーボンナノチューブとを、前記カーボンナノチューブに対する前記グラフェンの質量比(グラフェン/カーボンナノチューブ)が、5以上15以下の範囲を満たすように、分散させる、請求項9に記載の方法。
- 前記積層させるステップにおいて、前記分散媒は、水、N-メチルピロリドン(NMP)、N,N-ジメチルホルムアミド(DMF)およびジメチルスルホキシド(DMSO)からなる群から選択される、請求項1に記載の方法。
- グラフェンとカーボンナノチューブとの積層体からなる電極材料であって、
前記グラフェンは、電解液イオンが通過する細孔を有し、
前記グラフェンは、電解液イオンが通過する間隔で、前記カーボンナノチューブを介して積層されている、電極材料。 - 前記グラフェンは、前記1層以上3層以下のグラフェンシートからなり、細孔径が0.4nm以上10nm以下である細孔を有する、請求項12に記載の電極材料。
- 前記積層体は、200F/g以上400F/g以下の範囲の比容量を有する、請求項12に記載の電極材料。
- 前記グラフェンは、カルボキシ基および/または水酸基を有する、請求項12に記載の電極材料。
- 前記積層体は、請求項1から11のいずれか一項に記載の方法によって製造されたものである、請求項12に記載の電極材料。
- 電極と、電解質とを備えた電気二重層キャパシタであって、
前記電極は、請求項12から16のいずれか一項に記載の電極材料からなる、電気二重層キャパシタ。 - 前記電解質は、EMI-TFSI、EMI-BF4およびMPPp-TFSIからなる群から選択されるイオン液体またはM’OH(M’はアルカリ金属)である、請求項17に記載の電気二重層キャパシタ。
- 前記電解質は、EMI-TFSIであり、印加電圧は4V以下である、請求項18に記載の電気二重層キャパシタ。
- 前記電解質は、MPPp-TFSIであり、印加電圧は4.5V以上である、請求項18に記載の電気二重層キャパシタ。
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WO2019065004A1 (ja) | 2017-09-27 | 2019-04-04 | 国立研究開発法人物質・材料研究機構 | グラフェンを含有する電極、その製造方法およびそれを用いた蓄電デバイス |
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