WO2017161613A1 - 桉叶油助剂及其制法与面料后整理工作液 - Google Patents

桉叶油助剂及其制法与面料后整理工作液 Download PDF

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Publication number
WO2017161613A1
WO2017161613A1 PCT/CN2016/079580 CN2016079580W WO2017161613A1 WO 2017161613 A1 WO2017161613 A1 WO 2017161613A1 CN 2016079580 W CN2016079580 W CN 2016079580W WO 2017161613 A1 WO2017161613 A1 WO 2017161613A1
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Prior art keywords
eucalyptus oil
parts
solution
auxiliary agent
oil
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PCT/CN2016/079580
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English (en)
French (fr)
Inventor
葛乃君
陈红霞
陆鹏
丁可敬
Original Assignee
江苏金太阳纺织科技股份有限公司
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Priority to AU2016399387A priority Critical patent/AU2016399387A1/en
Publication of WO2017161613A1 publication Critical patent/WO2017161613A1/zh

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A01N25/28—Microcapsules or nanocapsules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules

Definitions

  • the invention relates to an auxiliary agent, a preparation method thereof and a finishing work liquid for a fabric, in particular to a eucalyptus oil auxiliary agent, a preparation method thereof and a working liquid for finishing a fabric, belonging to the technical field of textile auxiliaries and textile finishing.
  • Textiles are indispensable items in people's daily lives. However, fabrics that are not protected by any special functions are susceptible to environmental and human factors, and become a breeding ground for bacteria and microorganisms (such as mites) that grow together with humans. It is also subject to long-term damage from house dust mites in nature, causing various allergic symptoms and diseases. At present, the safety of textiles has become a hot spot for consumers, and the functional requirements such as antibacterial and anti-mite of textiles are becoming more and more urgent. Therefore, research and development of such textiles is of great significance and value.
  • Eucalyptus oil its main component is 1.8 eucalyptus, scientific name 1.3,3-trimethyl-2-oxocyclo[2.2,2]octane, is a pure natural plant essential oil. It is known that at lower concentrations, for bacteria, fungi, microorganisms, mosquitoes, etc., the repellent rate of only 5% of eucalyptus oil to aphids can reach 99.5%, which is better. The anti-caries effect; and its toxicity to the human body is small, does not cause secondary pollution, so it has broad development prospects. However, since eucalyptus oil itself is volatile, and its light resistance and heat resistance are unstable, it will have a certain negative impact on its pharmacological effects. If it is directly used on textiles, it will not achieve its original effect, but also May affect product quality.
  • the first object of the present invention is to provide a eucalyptus oil auxiliaries which have good antibacterial and antibacterial effects, low odor, low volatility and stable photothermal stability.
  • the second object of the present invention is to provide the eucalyptus oil A method for preparing a preparation;
  • a third object of the present invention is to provide a finishing work liquid for a fabric containing the eucalyptus oil adjuvant.
  • the eucalyptus oil adjuvant of the present invention comprises the following components by weight: 5-20 parts of eucalyptus oil microcapsules, 5-10 parts of eucalyptus oil, and 1-20 parts of nonionic emulsifier 5-10 parts of anionic thickener, 5-10 parts of polyurethane binder and 30-50 parts of deionized water.
  • the eucalyptus oil adjuvant further comprises at least one of 1-5 parts of eugenol, 1-5 parts of wormwood oil and 1-5 parts of cedar oil, which can uniformly dissolve the eucalyptus oil, if more The ingredients are used together to synergistically.
  • the nonionic emulsifier has an HLB value of 8.5-14.5 and has an excellent emulsification effect.
  • the eucalyptus oil adjuvant of the present invention may further comprise 0.1-0.2 parts of a Kasson preservative and 0.01-0.02 parts of a silicone emulsion type antifoaming agent to improve the stability of the auxiliary agent and the like.
  • the preparation method of the eucalyptus oil auxiliary agent of the invention comprises the following steps:
  • anionic thickener, polyurethane binder is added to the remaining deionized water by weight to obtain a solution C;
  • step (2) at least one of eugenol, wormwood oil and cedar oil is mixed with eucalyptus oil in parts by weight, and then added to a nonionic emulsifier for shear dispersion.
  • the eucalyptus oil microcapsule is obtained by adding eucalyptus oil to an aqueous solution of gum arabic and modified chitosan, stirring and drying; wherein, an aqueous solution of gum arabic and modified chitosan
  • the mass fraction is 3-5%, and the mass ratio of eucalyptus oil to the aqueous solution of gum arabic and modified chitosan is 1:4-10.
  • the modified chitosan is at least one of chitosan hydrochloride, chitosan nitrate, and chitosan citrate.
  • the Kaisong preservative and the silicone emulsion type antifoaming agent are further added to the remaining deionized water in parts by weight to obtain a solution C.
  • the fabric finishing work liquid containing the eucalyptus oil auxiliary agent of the invention adds 5-30 g/L eucalyptus oil auxiliary agent to the fabric finishing work liquid.
  • the beneficial effects of the present invention are as follows: Firstly, the present invention adopts an emulsification process to dissolve eucalyptus oil into an emulsifier, and the obtained auxiliaries have good affinity and absorption effect on the fabric fiber; Secondly, the eucalyptus oil microcapsules are simultaneously added to the auxiliary agent, and the retention time of the active ingredient of the eucalyptus oil is increased under the protection of the capsule wall, The function effect is prolonged, which is beneficial to maintain the best use effect of the fabric; then, one or more essential oils can be added to the emulsifier, which can not only improve the oxidation resistance of the essential oil itself, but also improve the storage stability of the auxiliary agent and avoid long The stratification caused by the action of gravity; in addition, the preparation method of the auxiliary agent of the invention is simple and easy to implement.
  • the eucalyptus oil-containing auxiliary agent of the present invention comprises the following components by weight: 5-20 parts of eucalyptus oil microcapsules, 5-10 parts of eucalyptus oil, and 1-20 parts of nonionic emulsifier, 5-10 parts of anionic thickener, 5-10 parts of polyurethane binder, and 30-50 parts of deionized water.
  • the eucalyptus oil microcapsules are obtained by adding eucalyptus oil to an aqueous solution of gum arabic and modified chitosan, stirring and drying.
  • the active ingredient in the eucalyptus oil can be effectively prevented from being diffused into the air by the influence of temperature or moisture, thereby ensuring the stability of its function.
  • the modified chitosan is at least one of chitosan hydrochloride, chitosan nitrate and chitosan citrate, and the modified chitosan has a smaller molecular weight and a higher degree of deacetylation. It has good water solubility, is favorable for colloid formation, and improves microcapsule preparation efficiency.
  • the eucalyptus oil is emulsified by a nonionic emulsifier to prepare an emulsion which has affinity for cellulose fibers or chemical fibers and can be uniformly absorbed, and the fabric is protected from external force after finishing. It also exerts anti-bacterial and antibacterial effects when it is used.
  • the above nonionic emulsifier may be, for example, Span 20 (purchased from Zibo Haijie Chemical Co., Ltd.), Tween 85 (purchased from Zibo Haijie Chemical Co., Ltd.), and alkylphenol ethoxylate-4 (purchased from Zibohai).
  • the anionic thickener of the present invention has an effect of increasing the viscosity of the system and, while thickening, ensures that the water solubility of the product is not affected, for example, CMC is optional.
  • the polyurethane adhesive of the invention has the function of improving the combination of the auxiliary agent and the fiber, and can still combine with the fiber after multiple washings, and has good compatibility with the auxiliary system, and does not have a negative effect on the storage of the auxiliary agent.
  • the eucalyptus oil-containing adjuvant of the present invention may further comprise at least one of 1-5 parts of eugenol, 1-5 parts of wormwood oil, and 1-5 parts of cedar oil.
  • These essential oils can evenly dissolve the eucalyptus oil.
  • the eucalyptus oil-containing adjuvant of the present invention may further comprise 0.1-0.2 parts of a preservative and 0.01-0.02 parts of an antifoaming agent.
  • the preservative can be selected from Kaisong preservative
  • the antifoaming agent can be selected from the group consisting of silicone emulsion defoamers. Kaisong broad-spectrum high-efficiency, super-sterilization and antibacterial effect, silicone emulsion defoamer, low dosage, good effect, suitable for defoaming textile additives.
  • eucalyptus oil microcapsules 20 parts of eucalyptus oil microcapsules, 10 parts of eucalyptus oil, 5 parts of fatty alcohol polyoxyethylene ether AEO-3, 5 parts of octylphenol ethoxylate OP-4, alkylphenol ethoxylate-4 10 parts 10 parts of thickener CMC, 10 parts of polyurethane binder, and 50 parts of deionized water.
  • Step 1 Add eucalyptus oil to a mixed aqueous solution of gum arabic and chitosan nitrate with a mass fraction of 3%.
  • the mass ratio of eucalyptus oil to mixed aqueous solution is 1:4, and the gum arabic and chitosan in the mixed aqueous solution.
  • the mass ratio of nitrate is 1:1.
  • Step 2 5 parts of eucalyptus oil, added to the mixed Span 20, Tween 85, alkylphenol ethoxylate-4 mixture, emulsified and dispersed using a high-speed shear, shear time 30min, then added 1/2 amount of deionized water, stirring for 30min, to obtain solution A;
  • Step 3 taking the eucalyptus oil microcapsule powder is added to the solution A, and stirring to obtain the solution B;
  • Step 4 the thickener CMC, polyurethane binder, added to the remaining deionized water and stirred for 30min, to obtain a solution C;
  • step 5 the solution B and the solution C are uniformly stirred, and are obtained after standing.
  • Step 1 preparing a fabric finishing working liquid, wherein the eucalyptus oil-containing auxiliary agent prepared above is added, the adding amount is 30 g/L, and is added to the sizing machine chemical tank, and the stirring is uniform;
  • Step 2 the setting machine temperature is 140 ° C, the setting time is 60 s, and the fabric finishing is completed.
  • Step 1 Add eucalyptus oil to a mixed aqueous solution of gum arabic and chitosan hydrochloride with a mass fraction of 3%.
  • the mass ratio of eucalyptus oil to mixed aqueous solution is 1:4, and the gum arabic and shell aggregate in the mixed aqueous solution.
  • the mass ratio of sugar hydrochloride was 1:1. Fully shearing and stirring to obtain a mixture, and then drying at 140 ° C using a spray method, and collecting the eucalyptus oil microcapsule powder;
  • Step 2 5 parts of eucalyptus oil, added to the mixed Span 20, Tween 85, alkylphenol ethoxylate-4 mixture, emulsified and dispersed using a high-speed shear, shear time 30min, then added 1/2 amount of deionized water, stirring for 30min, to obtain solution A;
  • Step 3 taking the eucalyptus oil microcapsule powder is added to the solution A, and stirring to obtain the solution B;
  • Step 4 the thickener CMC, polyurethane adhesive, preservative, antifoaming agent, added to the remaining deionized water for 30min, to obtain a solution C;
  • step 5 the solution B and the solution C are uniformly stirred, and are obtained after standing.
  • the fabric is made of cotton C60*C60/200*100
  • Step 1 preparing a fabric finishing working liquid, wherein the eucalyptus oil-containing auxiliaries prepared above are added, the adding amount is 10 g/L, and is added to the sizing machine chemical tank, and the stirring is uniform;
  • Step 2 the setting machine temperature is 150 ° C, the setting time is 60 s, and the fabric finishing is completed.
  • Example 2 On the basis of Example 2, 5 parts of eugenol, 4 parts of wormwood oil, and 1 part of cedar oil were added.
  • step 2 the compound oil prepared from eugenol, wormwood oil and cedar oil was added to the eucalyptus oil to co-emulsifie.
  • Example 2 The above raw materials were basically the same as those of Example 2 except that no eucalyptus oil was added.
  • Step 1 Add eucalyptus oil to a mixed aqueous solution of gum arabic and chitosan hydrochloride with a mass fraction of 3%.
  • the mass ratio of eucalyptus oil to mixed aqueous solution is 1:4, and the gum arabic and shell aggregate in the mixed aqueous solution.
  • the mass ratio of the sugar hydrochloride is 1:1, and the mixture is sufficiently sheared and stirred to obtain a mixture, which is then dried by using a spray method at 140 ° C to obtain a eucalyptus oil microcapsule powder;
  • Step 2 5 parts of the eucalyptus oil microcapsules obtained in the step 1 are added to the mixture of the mixed Span 20, Tween 85, and alkylphenol ethoxylate-4, and emulsified and dispersed using a high-speed shearing machine. Cutting time 30min, then adding 1/2 amount of deionized water, stirring for 30min, to obtain solution A;
  • Step 3 taking the eucalyptus oil microcapsule powder is added to the solution A, and stirring to obtain the solution B;
  • Step 4 the thickener CMC, polyurethane adhesive, preservative and antifoaming agent, added to the remaining deionized water for 30min, to obtain a solution C;
  • step 5 the solution B is mixed with the solution C, and a preservative and an antifoaming agent are added, and the mixture is allowed to stand.
  • the above raw materials were basically the same as those of the example 2 except that no eucalyptus oil microcapsules were added.
  • Step 1 5 parts of eucalyptus oil, added to the mixed Span 20, Tween 85, alkylphenol ethoxylate-4 mixture, emulsified and dispersed using a high-speed shear, shear time 30min, then added 1/2 amount of deionized water, stirring for 30min, to obtain solution A;
  • Step 2 adding a thickener 5 parts, a binder 5 parts, a preservative and an antifoaming agent to the solution A prepared in the step 1, and adding the remaining deionized water for 30 minutes to obtain a solution B;
  • step 3 the preservative and the antifoaming agent are added to the solution B prepared in the step 3, and the solution is obtained after standing.
  • Example 3 The difference from Example 3 is that no wormwood oil and cedar oil are added;
  • Example 3 The difference from Example 3 is 1 part of eugenol, 1 part of wormwood oil, and 1 part of cedar oil;
  • Example 3 The difference from Example 3 is 6 parts of eugenol, 6 parts of wormwood oil, and 6 parts of cedar oil;
  • Bacteriostaticity is divided into good, good, average, poor and poor according to the order of priority, the same below.
  • Example 1 does not add preservatives and antifoaming agents and essential oils.
  • the finishing agent is prone to foaming and has poor stability, but the bacteriostasis and inhibition rate are good, which can meet the overall requirements of the auxiliaries of the present invention, but in large quantities.
  • the finishing agent appears bubble The foam will prolong the reaction cycle of the finishing agent, and the retention of the bubbles will also cause the spots on the cloth surface to be smeared, and the finishing agent with poor stability cannot be stored for a long time, and needs to be used immediately, which is not suitable for production;
  • Example 3 On the basis of Example 2, eugenol, wormwood oil and cedar oil were added to the emulsifier to increase the inhibition rate and the bacteriostasis;
  • Comparative Example 1 did not add eucalyptus oil, and the direct test inhibition rate and bacteriostasis were lower, but after washing, it had lower sputum inhibition and bacteriostasis; Comparative Example 2 did not add eucalyptus oil microcapsules, and the direct test had The lower inhibition rate and bacteriostasis have no inhibition rate and bacteriostasis after washing.
  • Comprehensive control case 1 and control 2 show that the addition of eucalyptus oil has a greater influence on bacteriostatic and mites;
  • Example 3 In Comparative Example 3, wormwood oil and cedar oil were not added, and the inhibition rate and bacteriostasis of Example 3 were lower than that of Example 3. The selection of the three essential oils showed the best effect, and the compounded oils were better. The solubility can not only enhance the antibacterial and antibacterial effects, but also improve the stability and make up for the deficiency of a single essential oil;
  • Comparative Example 4 reduced the addition amount of eugenol, wormwood oil, and cedar oil, and the inhibition rate and the bacteriostatic property were lower than those in Example 3;
  • Example 5 the addition amount of eugenol, wormwood oil and cedar oil was increased, and the inhibition rate and the bacteriostatic property of Example 3 were decreased, which indicates that although the increase of the auxiliary essential oil content can enhance the sputum inhibition and bacteriostatic effects, Excessive addition also destroys the emulsion system, leading to delamination.
  • the ratio of the ratio of the eucalyptus oil and the eucalyptus oil microcapsules disclosed in the present invention can obtain the maximum beneficial effect.

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Abstract

一种桉叶油助剂及其制备方法与面料后整理工作液。桉叶油助剂包括桉叶油微胶囊5-20份、桉叶油5-10份、非离子型乳化剂1-20份、阴离子型增稠剂5-10份、聚氨酯粘合剂5-10份以及去离子水30-50份。该助剂制备方法采用乳化工艺，将桉叶油溶于乳化剂中，得到的助剂对面料纤维具有良好的亲和力和吸收效果；助剂中同时加入桉叶油微胶囊，在囊壁的保护下，桉叶油有效成分的保持时间增加，其功能效果延长，有利于保持面料最佳的使用效果；乳化剂中可添加一种或多种精油，既能提高精油本身的抗氧化性，也能提高助剂的储存稳定性，避免长时间由于重力作用而造成的分层；该制作方法简单易行，容易实现。

Description

桉叶油助剂及其制法与面料后整理工作液 技术领域
本发明涉及到一种助剂及其制备方法与面料后整理工作液，尤其涉及一种桉叶油助剂及其制备方法与面料后整理工作液，属于纺织品助剂及纺织品后整理技术领域。
背景技术
纺织品是人们日常生活中必不可少的用品，然而未经任何特殊功能防护的面料容易受到环境、人为等因素，成为细菌、与人体共生的微生物(例如螨虫等)增长和繁殖的温床，此外，还会受到来自于自然界中的屋尘螨等的长期侵害，引起各种过敏症状及疾病。目前，纺织品的安全问题已经成为消费者普遍关注的热点，且纺织品抗菌防螨等功能性需求越来越迫切，因此研究开发此类纺织品具有十分重要的意义和价值。
目前在纺织品抗菌防螨领域，大多采用有机合成的抗菌剂来实现抗菌防螨的功效，例如：季铵盐类化合物、银离子系列抗菌剂、高分子有机化合物抗菌剂、硝基化合物、甲醛衍生物等。但其中绝大多数抗菌剂不仅会对人体造成一定的伤害，而且存在不可降解、对环境造成影响等问题。近年来一些企业、高校将重点转移至天然的中草药及纯植物来源的物质研究上，因此研究绿色、安全的抗菌防螨助剂已经/即将成为开发热点。
桉叶油，其主要成分为1.8桉叶素，学名1.3，3-三甲基-2氧杂环[2.2，2]辛烷，是一种纯天然的植物精油。已知其在较低浓度时，对于细菌、真菌、微生物、蚊虫等具有驱避和灭杀的效果，仅5％的桉叶油对螨虫的驱避率30min可达到99.5％，属于具有较好的防螨效果；且其对人体毒性较小，不会造成二次污染，因此具有广阔的开发前景。但是由于桉叶油本身具有挥发性，并且耐光性和耐热性均不稳定，会对其药理作用产生一定的负面影响，如果直接使用到纺织品上，不仅达不到其原本的效果，而且还可能影响产品品质。
因此，如何有效开发和利用桉叶油并将其用于纺织品上，成为目前亟待解决的技术难题。
发明内容
发明目的：本发明的第一目的是提供一种防螨抑菌效果良好、气味小、不易挥发且耐光热性稳定的桉叶油助剂；本发明的第二目的是提供该桉叶油助剂的制备方法；本发明的第三目的是提供含有该桉叶油助剂的面料后整理工作液。
技术方案：本发明所述的桉叶油助剂，按重量份计包括如下组分：桉叶油微胶囊5-20份、桉叶油5-10份、非离子型乳化剂1-20份、阴离子型增稠剂5-10份、聚氨酯粘合剂5-10份以及去离子水 30-50份。
其中，该桉叶油助剂还包括丁香酚1-5份、艾草油1-5份和雪松油1-5份中的至少一种，能起到均匀溶解桉叶油的作用，如果多种成分一起使用，可起到协同增效的作用。
所述非离子型乳化剂的HLB值为8.5-14.5，乳化效果较好。
本发明的桉叶油助剂还可以包括凯松防腐剂0.1-0.2份和有机硅乳液型消泡剂0.01-0.02份，以提高助剂的稳定性等。
本发明所述桉叶油助剂的制备方法，包括如下步骤：
(1)制作桉叶油微胶囊；
(2)按重量份将桉叶油加入非离子型乳化剂中进行剪切分散，然后加入1/3-2/3量的去离子水，得溶液A；
(3)将桉叶油微胶囊加入溶液A，搅拌均匀得溶液B；
(4)按重量份将阴离子型增稠剂、聚氨酯粘合剂加入剩余的去离子水中，得溶液C；
(5)将溶液B与溶液C搅拌均匀、静置后得到含桉叶油助剂。
其中，步骤(2)中，按重量份将丁香酚、艾草油和雪松油中的至少一种与桉叶油混合，然后加入非离子型乳化剂中进行剪切分散。
步骤(1)中，所述桉叶油微胶囊是将桉叶油加入阿拉伯胶与改性壳聚糖的水溶液中，搅拌、烘干即得；其中，阿拉伯胶与改性壳聚糖的水溶液的质量分数为3-5％，桉叶油与阿拉伯胶与改性壳聚糖的水溶液的质量比为1∶4-10。
所述改性壳聚糖为壳聚糖盐酸盐、壳聚糖硝酸盐、壳聚糖柠檬酸盐中的至少一种。
步骤(4)中，按重量份还将凯松防腐剂和有机硅乳液型消泡剂一并加入剩余的去离子水中，得溶液C。
本发明所述含桉叶油助剂的面料后整理工作液，在面料后整理工作液中加入5-30g/L的桉叶油助剂。
有益效果：与现有技术相比，本发明的有益效果为：首先，本发明采用乳化工艺，将桉叶油溶于乳化剂中，得到的助剂对面料纤维具有良好的亲和力和吸收效果；其次，助剂中同时加入桉叶油微胶囊，在囊壁的保护下，桉叶油有效成分的保持时间增加，其 功能效果延长，有利于保持面料最佳的使用效果；然后，乳化剂中可添加一种或多种精油，既能提高精油本身的抗氧化性，也能提高助剂的储存稳定性，避免长时间由于重力作用而造成的分层；此外，本发明助剂的制作方法简单易行，容易实现。
具体实施方式：
本发明的含桉叶油助剂，按重量份计(下同)包括如下组分：桉叶油微胶囊5-20份、桉叶油5-10份、非离子乳化剂1-20份、阴离子增稠剂5-10份、聚氨酯粘合剂5-10份以及去离子水30-50份。
其中，桉叶油微胶囊是将桉叶油加入阿拉伯胶与改性壳聚糖的水溶液中，搅拌、烘干得到。有了微胶囊壁材的保护，可有效维持桉叶油中的有效成分不易受到温度或水分的影响扩散到空气中，从而保证其功能的稳定性。其中，改性壳聚糖为壳聚糖盐酸盐、壳聚糖硝酸盐、壳聚糖柠檬酸盐中的至少一种，经过改性后的壳聚糖分子量更小，脱乙酰度更高，具有很好的水溶性，有利胶体形成，提高微胶囊制备效率。
在上述助剂中，桉叶油经过非离子乳化剂的乳化处理后，制成无论是对纤维素纤维还是化学纤维都具有亲和力、且能均匀吸收的乳液，保证整理后，织物在不受外力作用时也能发挥抑螨和抑菌的效果。上述非离子乳化剂例如可以是司盘20(购自淄博海杰化工有限公司)、吐温85(购自淄博海杰化工有限公司)、烷基酚聚氧乙烯醚-4(购自淄博海杰化工有限公司)、脂肪醇聚氧乙烯醚AEO-3、AEO-7辛基酚聚氧乙烯醚OP-4、OP-6(购自海安石化)等。当选用HLB值为8.5-14.5的乳化剂时，乳化效果更加；RHLB为乳化油相时的需求值，当HLB＝RHLB时，效果最好，水包油体系(RHLB：8.0-18.0)，本发明中的油相HLB在8.5-14.5之间，稳定性最佳。
本发明的阴离子型增稠剂具有增加体系粘度作用，并且在增稠作用的同时，保证不影响产品水溶性，例如可选用CMC。
本发明的聚氨酯粘合剂具有提高助剂与纤维结合的作用，多次洗涤后仍能与纤维结合较好的作用，且与助剂体系相容性好，对助剂储存不产生负面效果。
本发明含桉叶油助剂还可以包括丁香酚1-5份、艾草油1-5份和雪松油1-5份中的至少一种。这些精油能起到均匀溶解桉叶油的作用，通过多次实施对比发现，采用多种药理相似的精油复配，能够有效提升有益效果，从而达到最佳效果，且弥补单方精油可能存在的一些缺陷，如挥发性、气味、颜色等；采用纯天然植物来源精油，较人工合成的精油，具有无毒副作用、安全放心等优点。
本发明含桉叶油助剂还可以包括防腐剂0.1-0.2份和消泡剂0.01-0.02份。其中，防腐剂可以选用凯松防腐剂，消泡剂可以选自有机硅乳液型消泡剂。凯松广谱高效、超强灭菌及抑菌功效，有机硅乳液型消泡剂，用量少，效果好，适合纺织品助剂消泡。
实施例1
(一)桉叶油助剂原料组分
桉叶油微胶囊 20份、桉叶油 10份、脂肪醇聚氧乙烯醚AEO-3 5份、辛基酚聚氧乙烯醚OP-4 5份、烷基酚聚氧乙烯醚-4 10份、增稠剂CMC 10份、聚氨酯粘合剂 10份、去离子水 50份。
(二)桉叶油助剂制备方法
步骤1，将桉叶油加入到质量分数为3％的阿拉伯胶与壳聚糖硝酸盐混合水溶液中，桉叶油与混合水溶液的质量比为1∶4，混合水溶液中阿拉伯胶与壳聚糖硝酸盐的质量比为1∶1。充分剪切搅拌，得混合物，然后使用喷雾法，140℃进行烘干，收集得到桉叶油微胶囊粉末；
步骤2，将桉叶油5份，加入混合好的司盘20、吐温85、烷基酚聚氧乙烯醚-4混合物中，使用高速剪切机进行乳化分散，剪切时间30min，然后加入1/2量的去离子水，继续搅拌30min，得到溶液A；
步骤3，取桉叶油微胶囊粉末加入到溶液A中，搅拌均匀得到溶液B；
步骤4，将增稠剂CMC、聚氨酯粘合剂，加入剩余的去离子水中搅拌30min，得到溶液C；
步骤5，将溶液B与溶液C搅拌均匀，静置后即得。
(三)含桉叶油助剂的面料后整理工作液及整理方法
以面料以全棉C40*C40/144*76为例
步骤1，配制面料后整理工作液，其中加入上述制备的含桉叶油助剂，添加量为30g/L，加入到定型机化料缸中，搅拌均匀；
步骤2，定型机温度140℃，定型时间60s，面料整理完成。
实施例2
(一)含桉叶油助剂原料组分
桉叶油微胶囊 5份、桉叶油 5份、司盘20 3份、吐温85 3份、烷基酚聚氧乙烯醚-4 4 份、增稠剂CMC 5份、聚氨酯粘合剂 5份、去离子水 30份、防腐剂0.1份、消泡剂0.01份。
(二)含桉叶油助剂制备方法
步骤1，将桉叶油加入到质量分数为3％的阿拉伯胶与壳聚糖盐酸盐混合水溶液中，桉叶油与混合水溶液的质量比为1∶4，混合水溶液中阿拉伯胶与壳聚糖盐酸盐的质量比为1∶1。充分剪切搅拌，得混合物，然后使用喷雾法，140℃进行烘干，收集得到桉叶油微胶囊粉末；
步骤2，将桉叶油5份，加入混合好的司盘20、吐温85、烷基酚聚氧乙烯醚-4混合物中，使用高速剪切机进行乳化分散，剪切时间30min，然后加入1/2量的去离子水，继续搅拌30min，得到溶液A；
步骤3，取桉叶油微胶囊粉末加入到溶液A中，搅拌均匀得到溶液B；
步骤4，将增稠剂CMC、聚氨酯粘合剂、防腐剂、消泡剂，加入剩余的去离子水中搅拌30min，得到溶液C；
步骤5，将溶液B与溶液C搅拌均匀，静置后即得。
(三)含桉叶油助剂的面料后整理工作液及整理方法
面料以全棉C60*C60/200*100为例
步骤1，配制面料后整理工作液，其中加入上述制备的含桉叶油助剂，添加量为10g/L，加入到定型机化料缸中，搅拌均匀；
步骤2，定型机温度150℃，定型时间60s，面料整理完成。
实施例3
(一)含桉叶油助剂原料组分
在实施例2的基础上增加：丁香酚 5份、艾草油 4份、雪松油 1份。
(二)含桉叶油助剂制备方法
与实施例2相同，不同之处为：步骤2中将丁香酚、艾草油及雪松油调制的复方油加入桉叶油中共同乳化。
(三)含桉叶油助剂的面料整理方法
与实施例2相同。
对照例1
(一)含桉叶油助剂原料组分
桉叶油微胶囊 5份、司盘20 3份、吐温85 3份、烷基酚聚氧乙烯醚-4 4份、增稠剂CMC 5份、聚氨酯粘合剂 5份、去离子水 30份，防腐剂0.1份、消泡剂0.01份。
上述原料与实施例2原料基本相同，不同之处为：不加入桉叶油。
(二)含桉叶油助剂制备方法
步骤1，将桉叶油加入到质量分数为3％的阿拉伯胶与壳聚糖盐酸盐混合水溶液中，桉叶油与混合水溶液的质量比为1∶4，混合水溶液中阿拉伯胶与壳聚糖盐酸盐的质量比为1∶1，充分剪切搅拌，得混合物，然后使用喷雾法，140℃进行烘干，收集得到桉叶油微胶囊粉末；
步骤2，将步骤1制得的桉叶油微胶囊5份，加入混合好的司盘20、吐温85、烷基酚聚氧乙烯醚-4混合物中，使用高速剪切机进行乳化分散，剪切时间30min，然后加入1/2量的去离子水，继续搅拌30min，得到溶液A；
步骤3，取桉叶油微胶囊粉末加入到溶液A中，搅拌均匀得到溶液B；
步骤4，将增稠剂CMC、聚氨酯粘合剂、防腐剂和消泡剂，加入剩余的去离子水中搅拌30min，得到溶液C；
步骤5，将溶液B与溶液C混合，加入防腐剂、消泡剂，静置后即得。
(三)含桉叶油助剂的面料整理方法
与实施例2一致。
对照例2
(一)含桉叶油助剂原料组分
桉叶油 5份、司盘20 3份、吐温85 3份、烷基酚聚氧乙烯醚-4 4份、增稠剂CMC 5份、聚氨酯粘合剂 5份、去离子水 30份、防腐剂0.1份、消泡剂0.01份。
上述原料与实施例2原料基本相同，不同之处为：不加入桉叶油微胶囊。
(二)含桉叶油助剂制备方法
步骤1，将桉叶油5份，加入混合好的司盘20、吐温85、烷基酚聚氧乙烯醚-4混合物中，使用高速剪切机进行乳化分散，剪切时间30min，然后加入1/2量的去离子水，继续搅拌30min，得到溶液A；
步骤2，向步骤1制得的溶液A中加入增稠剂5份、粘合剂5份、防腐剂和消泡剂，加入剩余去离子水中搅拌30min，得到溶液B；
步骤3，将步骤3制得的溶液B中，加入防腐剂、消泡剂，静置后即得。
(三)含桉叶油助剂的面料整理方法
与实施例2一致。
对照例3
与实施例3的区别在于不加入艾草油与雪松油；
其他步骤及组份及工艺实施方法不变。
对照例4
与实施例3的区别在于丁香酚 1份、艾草油 1份、雪松油 1份；
其他步骤及组份及工艺实施方法不变。
对照例5
与实施例3的区别在于丁香酚 6份、艾草油 6份、雪松油 6份；
其他步骤及组份及工艺实施方法不变。
表1 实施例1-3、对比例1-2桉叶油助剂的性能对比
Figure PCTCN2016079580-appb-000001
注：抑菌性按优先顺序分为很好、好、一般、较差及差，下同。
由表1可知：
实施例1不加入防腐剂与消泡剂及精油，整理剂易出现泡沫，稳定性较差，但抑菌性和抑螨率较好，可以满足本发明助剂的整体要求，但是在大货生产中，整理剂出现泡 沫会延长整理剂的反应周期，气泡的滞留也易使得布面产生斑痕疵点，稳定性较差的整理剂不能长久储存，需要即配即用，不适用于生产；
实施例3在实施例2的基础上，乳化剂中加入丁香酚、艾草油、雪松油，提高了抑螨率与抑菌性；
对照例1不加入桉叶油，直接测试抑螨率与抑菌性较低，但经过洗涤后具有较低的抑螨与抑菌性；对照例2不加入桉叶油微胶囊，直接测试具有较低的抑螨率与抑菌性，洗涤后不具有抑螨率与抑菌性，综合对照例1与对照例2说明桉叶油的添加对抑菌除螨的影响更大；
对照例3不加入艾草油与雪松油，相比实施例3抑螨率与抑菌性有一定降低，选择这说明三种精油复配效果最好，复配的精油之间相互具有较好的溶解性，既能提升抑螨抑菌效果，又能提高稳定性，弥补单一精油的不足；
对照例4减少丁香酚、艾草油、雪松油的添加量，相比实施例3抑螨率与抑菌性降低；
对照例5增加丁香酚、艾草油、雪松油的添加量，相比实施例3抑螨率与抑菌性降低，这说明辅助精油含量的增加虽然可以提升抑螨与抑菌功效，但是如果添加量过大，也破坏乳化体系，导致分层。
实施例4 研究桉叶油和桉叶油微胶囊的加入份数对助剂性能效果的影响
设计四组平行实验，原料组分与制备方法与实施例3基本相同，不同之处为桉叶油和桉叶油微胶囊的加入份数，比较得到的助剂性能，如表2所示。
表2 实施例4桉叶油助剂的性能对比
Figure PCTCN2016079580-appb-000002
由表2可知，组1桉叶油、桉叶油微胶囊含量较少，所以各项功能均无法达标；组3、组4在防螨、抑菌效果方面都较好，但桉叶油与桉叶油微胶囊用量增加，乳化体系易被破坏，造成产品分层助剂货架期不达标，稳定性较差；组2中桉叶油微胶囊量较大，直接测试抑螨率不达标。
综上所述，本发明公开的桉叶油与桉叶油微胶囊的配比范围能够获得最大有益效果。

Claims (10)

  1. 一种桉叶油助剂，其特征在于，按重量份计包括如下组分：桉叶油微胶囊5-20份、桉叶油5-10份、非离子型乳化剂1-20份、阴离子型增稠剂5-10份、聚氨酯粘合剂5-10份以及去离子水30-50份。
  2. 根据权利要求1所述的桉叶油助剂，其特征在于按重量份计还包括丁香酚1-5份、艾草油1-5份和雪松油1-5份中的至少一种。
  3. 根据权利要求1所述的桉叶油助剂，其特征在于：所述非离子型乳化剂的HLB值为8.5-14.5。
  4. 根据权利要求1-3任一所述的桉叶油助剂，其特征在于按重量份计还包括凯松防腐剂0.1-0.2份和有机硅乳液型消泡剂0.01-0.02份。
  5. 根据权利要求1所述桉叶油助剂的制备方法，其特征在于包括如下步骤：
    (1)制作桉叶油微胶囊；
    (2)按重量份将桉叶油加入非离子型乳化剂中进行剪切分散，然后加入1/3-2/3量的去离子水，得溶液A；
    (3)将桉叶油微胶囊加入溶液A，搅拌均匀得溶液B；
    (4)按重量份将阴离子型增稠剂、聚氨酯粘合剂加入剩余的去离子水中，得溶液C；
    (5)将溶液B与溶液C搅拌均匀、静置后得到含桉叶油助剂。
  6. 根据权利要求5所述桉叶油助剂的制备方法，其特征在于：步骤(2)中，按重量份将丁香酚、艾草油和雪松油中的至少一种与桉叶油混合，然后加入非离子型乳化剂中进行剪切分散。
  7. 根据权利要求5所述桉叶油助剂的制备方法，其特征在于：步骤(1)中，所述桉叶油微胶囊是将桉叶油加入阿拉伯胶与改性壳聚糖的水溶液中，搅拌、烘干即得；其中，阿拉伯胶与改性壳聚糖的水溶液的质量分数为3-5％，桉叶油与阿拉伯胶与改性壳聚糖的水溶液的质量比为1∶4-10。
  8. 根据权利要求7所述桉叶油助剂的制备方法，其特征在于：所述改性壳聚糖为壳聚糖盐酸盐、壳聚糖硝酸盐、壳聚糖柠檬酸盐中的至少一种。
  9. 根据权利要求5所述桉叶油助剂的制备方法，其特征在于：步骤(4)中，按重量份还将凯松防腐剂和有机硅乳液型消泡剂一并加入剩余的去离子水中，得溶液C。
  10. 根据权利要求1所述含桉叶油助剂的面料后整理工作液，其特征在于：在面料后整理工作液中加入5-30g/L的桉叶油助剂。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3478064A4 (en) * 2016-06-30 2020-01-15 The Hong Kong University of Science and Technology ANTIMICROBIAL COLLOIDAL COATINGS AND BIOLOGICAL ANTI-CONTAMINATION FOR SURFACES

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107761398A (zh) * 2017-09-15 2018-03-06 南通香佳纺织科技有限公司 一种微胶囊纺织品抗螨整理剂及其制备方法
CN110846893A (zh) * 2019-11-28 2020-02-28 南京海派企业管理咨询有限公司 一种纺织品防螨剂及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030124A1 (en) * 1997-01-09 1998-07-16 Lice Busters International Pty Insect repellent substrate for headwear
JP2005154343A (ja) * 2003-11-26 2005-06-16 Soken Kogyo Kk 室内用不快害虫防除薬剤
CN102405941A (zh) * 2011-08-10 2012-04-11 华南农业大学 板蓝根油微胶囊和功能织物整理剂
CN104264473A (zh) * 2014-10-08 2015-01-07 苏州印丝特纺织数码科技有限公司 一种环保型驱蚊整理剂
CN104532595A (zh) * 2014-12-15 2015-04-22 西安工程大学 防蚊驱蝇微胶囊整理剂、其制备方法及其应用方法
CN104975513A (zh) * 2015-05-29 2015-10-14 天津城建大学 高效抗菌型壳聚糖精油微胶囊的制备方法
CN105002625A (zh) * 2015-06-25 2015-10-28 张家港市华源染织有限公司 一种驱蚊面料

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1203293A (zh) * 1998-07-03 1998-12-30 王雪平 清凉抗菌织物及其制作方法
CN103668945A (zh) * 2012-09-21 2014-03-26 青岛道合生物科技有限公司 纺织品专用防螨抗菌剂
CN104250927B (zh) * 2014-06-09 2016-04-13 浙江纺织服装科技有限公司 一种织物用艾草微胶囊整理剂及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030124A1 (en) * 1997-01-09 1998-07-16 Lice Busters International Pty Insect repellent substrate for headwear
JP2005154343A (ja) * 2003-11-26 2005-06-16 Soken Kogyo Kk 室内用不快害虫防除薬剤
CN102405941A (zh) * 2011-08-10 2012-04-11 华南农业大学 板蓝根油微胶囊和功能织物整理剂
CN104264473A (zh) * 2014-10-08 2015-01-07 苏州印丝特纺织数码科技有限公司 一种环保型驱蚊整理剂
CN104532595A (zh) * 2014-12-15 2015-04-22 西安工程大学 防蚊驱蝇微胶囊整理剂、其制备方法及其应用方法
CN104975513A (zh) * 2015-05-29 2015-10-14 天津城建大学 高效抗菌型壳聚糖精油微胶囊的制备方法
CN105002625A (zh) * 2015-06-25 2015-10-28 张家港市华源染织有限公司 一种驱蚊面料

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3478064A4 (en) * 2016-06-30 2020-01-15 The Hong Kong University of Science and Technology ANTIMICROBIAL COLLOIDAL COATINGS AND BIOLOGICAL ANTI-CONTAMINATION FOR SURFACES

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