WO2017144694A1 - Dispersionsfarbe - Google Patents
Dispersionsfarbe Download PDFInfo
- Publication number
- WO2017144694A1 WO2017144694A1 PCT/EP2017/054386 EP2017054386W WO2017144694A1 WO 2017144694 A1 WO2017144694 A1 WO 2017144694A1 EP 2017054386 W EP2017054386 W EP 2017054386W WO 2017144694 A1 WO2017144694 A1 WO 2017144694A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- emulsion paint
- weight
- polymer
- weeks
- emulsion
- Prior art date
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- 239000003973 paint Substances 0.000 title claims abstract description 122
- 239000006185 dispersion Substances 0.000 title claims abstract description 42
- 229920000642 polymer Polymers 0.000 claims abstract description 35
- 239000000049 pigment Substances 0.000 claims abstract description 27
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 23
- 239000000945 filler Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000000839 emulsion Substances 0.000 claims description 78
- 239000000203 mixture Substances 0.000 claims description 27
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 150000001340 alkali metals Chemical class 0.000 claims description 11
- -1 perinones Inorganic materials 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 4
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 claims description 4
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 4
- YRJYANBGTAMXRQ-UHFFFAOYSA-N pyrazolo[3,4-h]quinazolin-2-one Chemical compound C1=C2N=NC=C2C2=NC(=O)N=CC2=C1 YRJYANBGTAMXRQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005871 repellent Substances 0.000 claims description 4
- 230000002940 repellent Effects 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000013799 ultramarine blue Nutrition 0.000 claims description 4
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 3
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 claims description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000006641 stabilisation Effects 0.000 claims description 3
- 238000011105 stabilization Methods 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 150000003440 styrenes Chemical class 0.000 claims description 3
- 229920001567 vinyl ester resin Polymers 0.000 claims description 3
- PVWWOFBIYKSBEX-UHFFFAOYSA-N 5-chloro-n-(4-chlorophenyl)-2-hydroxybenzamide Chemical compound OC1=CC=C(Cl)C=C1C(=O)NC1=CC=C(Cl)C=C1 PVWWOFBIYKSBEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- 239000004569 hydrophobicizing agent Substances 0.000 claims 1
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 13
- 238000009472 formulation Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000003755 preservative agent Substances 0.000 description 7
- UGGQKDBXXFIWJD-UHFFFAOYSA-N calcium;dihydroxy(oxo)silane;hydrate Chemical compound O.[Ca].O[Si](O)=O UGGQKDBXXFIWJD-UHFFFAOYSA-N 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229920000180 alkyd Polymers 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000001023 inorganic pigment Substances 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 235000013980 iron oxide Nutrition 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/18—Homopolymers or copolymers of nitriles
- C09D133/20—Homopolymers or copolymers of acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
- C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/003—Pigment pastes, e.g. for mixing in paints containing an organic pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
- C09D17/008—Titanium dioxide
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
Definitions
- the present invention relates to an emulsion paint, a process for
- silicate paints for the coating of substrates, various coating compositions are known.
- dispersion silicate paints for the coating of substrates, various coating compositions are known.
- plastic dispersion paints for the coating of substrates.
- Silicate paints are two-component paints that contain no organic components.
- the two main components of silicate paints are water glass and a water glass resistant pigment.
- Silicate paints are usually mixed just prior to application by combining the two main components. Therefore, silicate paints require several steps and their processing is generally difficult and requires a lot of experience.
- disperse silicate paints in addition to the water glass and the water glass resistant pigment, up to 5% by weight of organic constituents, 20 based on the total amount of disperse silicate paint, are contained.
- the organic constituents used are above all synthetic resin dispersions.
- other substances such as water repellents may be included.
- silicate paints and dispersion silicate paints usually have a very strong alkaline pH of up to 13, which requires more elaborate precautions regarding occupational safety.
- Plastic dispersion paints also known as emulsion paints, usually contain relatively large amounts of organochemical constituents, in particular on synthetic resins such as polymers, in particular in the form of
- Synthetic resin dispersions To ensure adequate storage stability, emulsion paints usually require preservatives such as isothiazolines. However, these can cause irritation and skin irritation especially in allergic persons.
- EP 1 297 079 Bl describes an emulsion paint containing polymer dispersion, pigment and / or filler, water glass and water.
- This emulsion paint is characterized by the fact that it requires no preservatives. However, the presence of water glass additionally contains an inorganic binder, which may impair the properties of the emulsion paint, in particular its processability.
- DE 1 031 910 describes an alkyd resin emulsion paint comprising titanium dioxide, fillers, an alkyd resin and water. This color will be in front of you
- DE 1 031 910 makes no statement about the pH of the alkyd emulsion emulsion, its storage stability or the presence of preservatives. Furthermore, an alkyd resin emulsion paint containing Natriummethylsilikonat for storage according to DE 1 031 910 is not provided.
- an object of the invention was to provide a dispersion paint which is substantially free of preservatives, has a good shelf life and / or is easy to process. All or some of these objects are achieved according to the invention by the emulsion paint of claim 1, the method of claim 11, the use of claim 13 and the use of claim 14.
- Advantageous embodiments of the invention are specified in the dependent claims and are explained in detail below.
- the emulsion paint of the invention has a pH of 10 to 12 and contains, based in each case on the total weight of the emulsion paint, the following constituents:
- Alkalimetallalkylsilikonat and 25 to 70 wt .-% of water in an emulsion paint having a pH of 10 to 12 is obtained an emulsion paint in which the
- Components have excellent compatibility with each other.
- surfaces which have been coated with the emulsion paint according to the invention have a more homogeneous appearance. This manifests itself, in particular, in the fact that the surfaces which have been coated with the emulsion paint according to the invention are very uniform due to their good flow. This allows the
- the dispersion paint according to the invention has no discoloration even without a preservative after a storage time of several weeks.
- the pH of the emulsion paint according to the invention remained substantially constant over a storage period of several weeks.
- the alkali metal alkyl siliconate on the one hand seems to stabilize the emulsion paint, in particular the pH of the emulsion paint, and on the other hand to ensure a good compatibility of the components.
- the alkali metal alkyl silicate apparently acts as a pH buffer.
- the presence of exclusively organic binders seems to favor good compatibility between the components at the pH of the emulsion paint. This effect was in view of the requirements mentioned in DE 1031 910 necessary additives for Alkalimetallalkylsilikonatitesen with
- Disperse dyes in the sense of the invention are, in particular, disperse interior paints, exterior dispersion paints, silicone resin paints and plasters
- Dispersion base including interior and exterior plasters, into consideration.
- Alkalimetallalkylsilikonate according to the invention are in particular compounds having the formula MOSi [R] (OH) 2, wherein M is an alkali metal and R is an alkyl radical.
- Alkali metal alkyl siliconates can be obtained, for example, by reacting alkylsilane triol with an alkali metal hydroxide.
- the preparation of solutions of alkali metal alkyl siliconates, in particular aqueous solutions, is described, for example, in DE 1 031 910.
- the alkali metal M may in particular be selected from the group consisting of lithium, sodium, potassium and
- the alkyl radical R is preferably selected from the group consisting of methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, tert-butyl, n-pentyl, iso-pentyl , tert-pentyl, neopentyl, phenyl, aryl, and cyclohexyk
- the alkyl radical is preferably methyl. More preferably that is
- Alkalimetallalkylsilikonat the dispersion paint according to the invention selected from the group consisting of lithium methylsiliconate, sodium methylsiliconate and Potassium methyl. Most preferred is the alkali metal alkyl silicone
- Kaliummethylsilikonat give homogeneous surfaces and are easy to handle.
- the alkali metal alkyl siliconate is contained in the dispersion paint according to the invention in an amount of 0.1 to 3.5 wt .-%, based on the total weight of
- Emulsion paint preferably contains from 0.1 to 2% by weight, in particular from 0.3 to 2% by weight or from 0.5 to 1.5% by weight,
- Emulsion paint Emulsion paints with these contents show a good
- the dispersion paint contains 1 to 15% by weight of pigment.
- a pigment various substances come into question.
- the pigment is preferably selected from the group consisting of titanium dioxide, iron oxide yellow, arylid (monoazo),
- the dispersion paint contains 3 to 13% by weight of pigment, more preferably 5 to 12% by weight of pigment.
- inorganic pigments are preferably used.
- examples of inorganic pigments are oxides such as titanium dioxide, iron oxides, e.g. P.Y. 42, P.R. 101, P.Bk. 11, chrome oxide green, e.g. P. G. 17, mixed phase pigments e.g.
- organic pigments are preferably used.
- organic pigments are azo pigments, e.g. Arylide Yellow
- (Monoazo) PY 74 polycyclic pigments, eg quinacridone PR 122, Perinone PO 43, pyrazolo-quinazolone PO 67, diketo-pyrrolo-pyrrole (DPP) PR 254, dioxazine PV 23 and metal complex pigments, eg copper phthalocyanines Blue PB 15: 3 and green PG 7.
- polycyclic pigments eg quinacridone PR 122, Perinone PO 43, pyrazolo-quinazolone PO 67, diketo-pyrrolo-pyrrole (DPP) PR 254, dioxazine PV 23 and metal complex pigments, eg copper phthalocyanines Blue PB 15: 3 and green PG 7.
- DPP diketo-pyrrolo-pyrrole
- mixtures of inorganic and organic pigments are used.
- the emulsion paint according to the invention contains filler.
- the filler is selected from the group consisting of dolomite, barium sulfate, feldspar, quartz, calcium carbonate, mica, kaolin, calcined kaolin, talc, diatomaceous earth and mixtures thereof. More preferably, the filler is a mixture of at least calcium carbonate and kaolin. Such fillers give emulsion paints with good processability.
- Calcium carbonate can be used in various forms, for example in the form of chalk or calcite.
- Dispersion paint a size of less than 100 ⁇ , in particular less than 80 ⁇ , preferably from 0.1 to 50 ⁇ , more preferably from 1 to 30 ⁇ ⁇ ⁇ on.
- Methods for determining particle size are known to the person skilled in the art.
- the particle size is determined by means of a grindometer according to DIN EN ISO 1524, in particular according to DIN EN ISO 1524: 2013-06.
- the particle size of the fillers refers in particular to the maximum agglomerate size in the emulsion paint.
- the particle size, in particular the particle size distribution can also be determined by means of transmission electron microscopy.
- the pH of the emulsion paint according to the invention is from 10 to 12, preferably from 10.5 to 11.5. It was found that emulsion paints with the indicated pH values even if stored for several weeks no or only
- the pH of the emulsion paint is from 10.5 to 11.4. Dispersion paints according to the invention with such pH values had the additional advantage, even without particular
- Precautions can be used in terms of occupational safety.
- the pH value can be adjusted, for example, by adding alkaline substances, also called alkaline dishes.
- alkaline substances are alkali metal hydroxides such as lithium hydroxide, sodium hydroxide and / or potassium hydroxide,
- Alkaline earth metal hydroxides such as magnesium, calcium, and / or barium hydroxide, ammonium hydroxide, xonotlite (6CaO 6S1O 2 H 2 O) and / or ittringite (Ca 6 [Al (OH) 6] 2 (SO 4 ⁇ 26 H 2 O)).
- the xonotlite preferably has a monoclinic crystal system (xonotlite monoclinic). It has been shown that xonotlite and / or ittringite in a particularly advantageous manner in combination with that in the inventive
- Dispersion paint contained alkali metal alkyl silicone can be used.
- disperse paints which contain, in addition to alkali metal alkyl silicate, xonotlite and / or ittringite as the alkaline counter, have increased pH stability.
- the dispersion paint according to the invention in addition to Alkalimetallalkylsilikonat alkali metal in an amount of 0.005 to 3 wt.%, In particular from 0.01 to 1 wt.%, Based on the
- dispersion paint 0.005 to 3 wt.%, In particular from 0.01 to 1 % By weight, xonotlite and / or ittringite, based on the total composition of the emulsion paint.
- the pH remains
- dispersion paint according to the invention over a period of at least 4 weeks, preferably at least 8 weeks, more preferably at least 12 weeks, even more preferably at least 16 weeks, even more preferably at least 20 weeks, substantially constant.
- the emulsion paint contains from 1 to 25% by weight of polymer, based on the total weight of the emulsion paint.
- the emulsion paint preferably contains from 2 to 23% by weight, more preferably from 4 to 20% by weight, of polymer, based in each case on the total weight of the emulsion paint.
- the information relating to the content of polymer in the emulsion paint in each case refer to the polymer as a solids content.
- the polymer is preferably added in the preparation of an emulsion paint in the form of a dispersion, in particular an aqueous dispersion.
- these polymer dispersions in particular the aqueous polymer dispersions, 40 to 70 wt .-%, preferably 45 to 60 wt .-%, more preferably 45 to 55 wt .-%, polymer.
- the polymer as aqueous
- the water of the polymer dispersion is calculated as part of the total water content of the emulsion paint.
- Emulsion paints containing polymer in these amounts have shown good processing properties.
- the polymer of the emulsion paint according to the invention preferably comprises at least one polymer and / or copolymer based on at least one monomer selected from the group consisting of acrylic acid, acrylic acid derivatives,
- Acrylic acid esters methacrylic acid, methacrylic acid derivatives, methacrylic acid esters, styrene, styrene derivatives, N-vinylpyrrolidone, acrylonitrile, vinyl acetate, vinyl propionate, ethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acid esters, ethylenically unsaturated carboxylic acid anhydrides, ethylenically unsaturated Carboxylic acid amides and carboxylic acid vinyl esters.
- the polymer of the emulsion paint particularly preferably contains at least one polymer based on
- Acrylic acid derivatives and / or styrene When using acrylic acid esters and / or methacrylic acid esters, it is preferred that the alcohol radical contain from 1 to 12 carbon atoms.
- the alcohol residue can also be branched or unbranched. According to a preferred embodiment, the polymer is the
- Emulsion paint of at least one of the aforementioned polymers and / or copolymers can also dispersants, wetting agents, thickeners, stabilizers, defoamers and / or as further additives
- Water repellents contain.
- thickeners are alcohol alkoxylates, ethylene oxide-propylene oxide copolymers, maleic anhydride-diisobutylene copolymers, polyacrylic and
- Polymethacrylic acid and its salts methylcelluloses, carboxymethylcelluloses, hydroxymethylcelluloses, polyurethanes, alkali metal phosphates and salts
- modified phosphoric acids and mixtures thereof.
- defoamers are polyglycols, triglycerides, polysiloxane-polyether copolymers and silicone oils.
- water repellents are in particular oligomeric and polymeric siloxanes and silicone resins.
- Emulsion paint substantially free of preservatives, in particular of isothiazolines.
- the invention further provides a process for the preparation of the dispersion paint of the invention comprising the steps a.
- Providing a composition comprising, in each case based on the total weight of the emulsion paint,
- Alkalimetallalkylsilikonat the process of the invention Alkalimetallalkylsilikonat the process of the invention.
- the dispersion paint according to the invention is suitable for various uses. In particular, it is suitable for indoor and / or outdoor use.
- the invention also relates to the use of alkali metal alkylsiconates, in particular of potassium methylsiliconate, for the stabilization of emulsion paints.
- Emulsion paints having the following formulations shown in Table 1 were prepared by mixing the ingredients shown in Table 1, each in weight percent.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
Claims
Priority Applications (20)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR122021014606-3A BR122021014606B1 (pt) | 2016-02-26 | 2017-02-24 | Tinta de dispersão, seu processo de produção, e uso de siliconatos de alquila de metal alcalino |
EP17707304.6A EP3420038B1 (de) | 2016-02-26 | 2017-02-24 | Dispersionsfarbe |
US16/079,201 US10988627B2 (en) | 2016-02-26 | 2017-02-24 | Dispersion paint |
BR112018017074-7A BR112018017074B1 (pt) | 2016-02-26 | 2017-02-24 | Tinta de dispersão, seu processo de produção, e uso de siliconatos de alquila de metal alcalino |
CN202210047663.3A CN114350211A (zh) | 2016-02-26 | 2017-02-24 | 分散体颜料 |
KR1020187027902A KR102311708B1 (ko) | 2016-02-26 | 2017-02-24 | 분산 페인트 |
CN201780013637.6A CN108779346B (zh) | 2016-02-26 | 2017-02-24 | 分散体颜料 |
LTEPPCT/EP2017/054386T LT3420038T (lt) | 2016-02-26 | 2017-02-24 | Dispersiniai dažai |
FIEP17707304.6T FI3420038T3 (fi) | 2016-02-26 | 2017-02-24 | Dispersiomaali |
CA3015720A CA3015720C (en) | 2016-02-26 | 2017-02-24 | Dispersion paint |
PL17707304.6T PL3420038T3 (pl) | 2016-02-26 | 2017-02-24 | Farba dyspersyjna |
EP23170429.7A EP4239030A1 (de) | 2016-02-26 | 2017-02-24 | Dispersionsfarbe |
JP2018563941A JP6714106B2 (ja) | 2016-02-26 | 2017-02-24 | 分散塗料 |
RU2018133547A RU2740756C2 (ru) | 2016-02-26 | 2017-02-24 | Дисперсионная краска |
KR1020217031940A KR102589153B1 (ko) | 2016-02-26 | 2017-02-24 | 분산 페인트 |
MX2018010308A MX2018010308A (es) | 2016-02-26 | 2017-02-24 | Pintura de dispersion. |
AU2017223024A AU2017223024B2 (en) | 2016-02-26 | 2017-02-24 | Dispersion paint |
AU2020200681A AU2020200681B2 (en) | 2016-02-26 | 2020-01-30 | Dispersion Paint |
US17/208,699 US20210206982A1 (en) | 2016-02-26 | 2021-03-22 | Dispersion paint |
AU2021232794A AU2021232794B2 (en) | 2016-02-26 | 2021-09-16 | Dispersion paint |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016002221.3 | 2016-02-26 | ||
DE102016002221.3A DE102016002221A1 (de) | 2016-02-26 | 2016-02-26 | Dispersionsfarbe |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/079,201 A-371-Of-International US10988627B2 (en) | 2016-02-26 | 2017-02-24 | Dispersion paint |
US17/208,699 Continuation US20210206982A1 (en) | 2016-02-26 | 2021-03-22 | Dispersion paint |
Publications (1)
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WO2017144694A1 true WO2017144694A1 (de) | 2017-08-31 |
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PCT/EP2017/054386 WO2017144694A1 (de) | 2016-02-26 | 2017-02-24 | Dispersionsfarbe |
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US (2) | US10988627B2 (de) |
EP (2) | EP3420038B1 (de) |
JP (1) | JP6714106B2 (de) |
KR (2) | KR102589153B1 (de) |
CN (2) | CN108779346B (de) |
AU (3) | AU2017223024B2 (de) |
BR (2) | BR112018017074B1 (de) |
CA (1) | CA3015720C (de) |
DE (2) | DE102016002221A1 (de) |
FI (1) | FI3420038T3 (de) |
LT (1) | LT3420038T (de) |
MA (1) | MA43681A (de) |
MX (2) | MX2018010308A (de) |
PL (1) | PL3420038T3 (de) |
RU (2) | RU2020143353A (de) |
WO (1) | WO2017144694A1 (de) |
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DE102017008984A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
DE102017008987A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
DE102017008986A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
EP3333231B1 (de) | 2016-12-07 | 2020-08-19 | Daw Se | Wässrige zusammensetzung für ein abtönsystem, kit-of-parts abtönsystem, abgetönte anstrich- und putzsysteme sowie anstriche und putze erhältlich durch auftragen der abgetönten anstrich- bzw. putzsysteme |
WO2024094292A1 (de) | 2022-11-02 | 2024-05-10 | Wacker Chemie Ag | Mehrstufen-copolymere als bindemittel für beschichtungsmittel |
WO2024175246A1 (de) | 2023-02-23 | 2024-08-29 | Thor Gmbh | Gegen mikrobiellen befall stabilisiertes wässriges technisches produkt |
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DE102018004945A1 (de) | 2018-06-22 | 2019-12-24 | Brillux Gmbh & Co. Kg | Konservierungsmittelfreie Pigmentpaste |
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DE102018008666A1 (de) | 2018-11-05 | 2020-05-07 | Brillux Gmbh & Co. Kg | Verfahren zur Konservierung einer Dispersion in einer Dosieranlage und Dosieranlage |
AU2019384792A1 (en) * | 2018-11-20 | 2021-06-10 | Arr-Maz Products, L.P. | Fertilizer coating applied in the reduction of caking and moisture adsorption |
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DE102019003940A1 (de) | 2019-06-06 | 2020-12-10 | BriIIux GmbH & Co. KG | Konservierungsmittelfreie Pigmentpaste |
EP3838992A1 (de) | 2019-12-20 | 2021-06-23 | Daw Se | Wässriges beschichtungsstoffsystem, dessen verwendung sowie innenfarbe, fassadenfarbe, spachtelmasse, putz, grundierung, klebemasse, lack, lasur oder pigmentpaste, enthaltend das wässrige beschichtungsstoffsystem |
EP4001365A1 (de) * | 2020-11-16 | 2022-05-25 | Daw Se | Im wesentlichen konservierungsmittelfreie pastöse beschichtungsmasse, insbesondere putz- oder spachtelmasse, und deren verwendung sowie beschichtung erhältlich aus der beschichtungsmasse, substrat enthaltend die beschichtung und beschichtungsverfahren |
MX2023014031A (es) * | 2021-05-27 | 2023-12-13 | Arkema Inc | Composicion pigmentada de revestimiento estable al almacenamiento. |
WO2023242363A1 (en) | 2022-06-15 | 2023-12-21 | Omya International Ag | Storage stabilization agent for stabilizing aqueous compositions, process for stabilizing and uses thereof |
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2016
- 2016-02-26 DE DE102016002221.3A patent/DE102016002221A1/de active Pending
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2017
- 2017-02-24 PL PL17707304.6T patent/PL3420038T3/pl unknown
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- 2017-02-24 KR KR1020217031940A patent/KR102589153B1/ko active IP Right Grant
- 2017-02-24 DE DE202017107111.1U patent/DE202017107111U1/de not_active Ceased
- 2017-02-24 LT LTEPPCT/EP2017/054386T patent/LT3420038T/lt unknown
- 2017-02-24 RU RU2020143353A patent/RU2020143353A/ru unknown
- 2017-02-24 CA CA3015720A patent/CA3015720C/en active Active
- 2017-02-24 MA MA043681A patent/MA43681A/fr unknown
- 2017-02-24 CN CN202210047663.3A patent/CN114350211A/zh active Pending
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- 2017-02-24 AU AU2017223024A patent/AU2017223024B2/en active Active
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- 2017-02-24 MX MX2018010308A patent/MX2018010308A/es unknown
- 2017-02-24 BR BR122021014606-3A patent/BR122021014606B1/pt active IP Right Grant
- 2017-02-24 WO PCT/EP2017/054386 patent/WO2017144694A1/de active Application Filing
- 2017-02-24 KR KR1020187027902A patent/KR102311708B1/ko active IP Right Grant
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Cited By (7)
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EP3333231B1 (de) | 2016-12-07 | 2020-08-19 | Daw Se | Wässrige zusammensetzung für ein abtönsystem, kit-of-parts abtönsystem, abgetönte anstrich- und putzsysteme sowie anstriche und putze erhältlich durch auftragen der abgetönten anstrich- bzw. putzsysteme |
DE102017008984A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
DE102017008987A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
DE102017008986A1 (de) | 2017-09-26 | 2019-03-28 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
DE202018006752U1 (de) | 2017-09-26 | 2022-07-13 | Sto Se & Co. Kgaa | Lagerstabile Beschichtungszusammensetzung |
WO2024094292A1 (de) | 2022-11-02 | 2024-05-10 | Wacker Chemie Ag | Mehrstufen-copolymere als bindemittel für beschichtungsmittel |
WO2024175246A1 (de) | 2023-02-23 | 2024-08-29 | Thor Gmbh | Gegen mikrobiellen befall stabilisiertes wässriges technisches produkt |
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