WO2017122687A1 - Procédé de lutte contre des arthropodes hématophages et composition de lutte contre des arthropodes hématophages pour le traitement d'éléments formant des habitations - Google Patents

Procédé de lutte contre des arthropodes hématophages et composition de lutte contre des arthropodes hématophages pour le traitement d'éléments formant des habitations Download PDF

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Publication number
WO2017122687A1
WO2017122687A1 PCT/JP2017/000655 JP2017000655W WO2017122687A1 WO 2017122687 A1 WO2017122687 A1 WO 2017122687A1 JP 2017000655 W JP2017000655 W JP 2017000655W WO 2017122687 A1 WO2017122687 A1 WO 2017122687A1
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WIPO (PCT)
Prior art keywords
blood
sucking
arthropod control
living space
sucking arthropod
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PCT/JP2017/000655
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English (en)
Japanese (ja)
Inventor
英則 大同
あゆみ 川瀬
新葉 笹倉
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三井化学アグロ株式会社
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Application filed by 三井化学アグロ株式会社 filed Critical 三井化学アグロ株式会社
Priority to BR112018014039-2A priority Critical patent/BR112018014039B1/pt
Publication of WO2017122687A1 publication Critical patent/WO2017122687A1/fr
Priority to PH12018550106A priority patent/PH12018550106A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00—Stationary means for catching or killing insects
    • A01M1/20—Poisoning, narcotising, or burning insects
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14—Ethers
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives

Definitions

  • the present invention relates to a blood-sucking arthropod control method and a blood-sucking arthropod control composition for treating living space formations for preventing the spread of infections mediated by blood-sucking arthropods.
  • Pest control methods to control these disease-borne pests include spraying an insecticide containing a pest control ingredient, applying a contact insecticide on the surface of an indoor wall, immersing the insecticide in a mosquito net, etc. Has been used.
  • Known pest control components include pyrethroid compounds and neonicotinoid compounds.
  • Patent Document 1 International Publication No. 2005/21488
  • Patent Document 2 International Publication No. 2005/73165
  • Patent Document 3 International Publication No. 2006/137376
  • Patent Document 4 International Publication No. 2006/137395
  • Patent Document 5 International Publication No. 2010/013567 Pamphlet
  • Patent Documents 1 to 5 describe that it is possible to control disease-borne pests, details of specific effective concentrations and methods of use are not disclosed, and the above amide derivatives are used. The method for controlling pests has not been substantially disclosed.
  • one embodiment of the present invention provides a blood-sucking arthropod control method and a blood-sucking arthropod control composition for treating living space formation, which are excellent in durability and effective against resistant pests. Is an issue.
  • the present inventors have formed residential spaces such as house walls and mosquito nets with a composition containing an amide derivative represented by the general formula (1) as an active ingredient.
  • the present inventors have found that pest control is possible for a long period of time and is effective against resistant pests.
  • One embodiment of the present invention is as follows.
  • Q represents a phenyl group or a phenyl group substituted with a fluorine atom.
  • R represents a hydrogen atom or a methyl group.
  • Y 1 and Y 2 are each independently a bromine atom, an iodine atom or a trifluoromethyl group.
  • the amide derivative represented by the general formula (1) is 2-fluoro-3- (N-methylbenzamide) -N- (2-bromo-6-trifluoromethyl-4- (heptafluoropropane-).
  • ⁇ 3> The blood-sucking arthropod control method according to ⁇ 1> or ⁇ 2>, wherein the living space formation is a house wall surface or a mosquito net.
  • ⁇ 4> The method for controlling blood-sucking arthropods according to any one of ⁇ 1> to ⁇ 3>, wherein the method for treating the living space formation is spraying or dipping treatment.
  • the blood-sucking arthropod to be controlled is at least one selected from the group consisting of Anopheles insects, Aedes genus insects and Culex genus insects which are Diptera mosquitoes (Clicidae), ⁇
  • the method for controlling blood-sucking arthropods according to any one of 1> to ⁇ 4>.
  • ⁇ 6> The blood-sucking arthropod control method according to ⁇ 5>, wherein the Dipteridae (Clicidae) insect is an Anopheles genus insect.
  • the blood-sucking arthropod control composition for treating living space formations contains, as a further active ingredient, at least one compound selected from the group consisting of permethrin, alpha cypermethrin, deltamethrin, and etofenprox.
  • the blood-sucking arthropod control method according to any one of ⁇ 1> to ⁇ 7>.
  • the blood-sucking arthropod control method according to any one of ⁇ 1> to ⁇ 8>, wherein the blood-sucking arthropod control composition for treating living space formations is a wettable powder or a flowable agent. .
  • a blood-sucking arthropod control composition for treating living space formations which contains at least one amide derivative represented by the formula:
  • the amide derivative represented by the general formula (1) is 2-fluoro-3- (N-methylbenzamide) -N- (2-bromo-6-trifluoromethyl-4- (heptafluoropropane-).
  • the blood-sucking arthropod control composition for living space formation treatment according to ⁇ 12> or ⁇ 13>, which is used for treatment of a house wall or a mosquito net as a living space formation.
  • ⁇ 15> Used for control of at least one species selected from the group consisting of Anopheles insects, Aedes insects, and Culex insects, which are Fliesidae (Diptera) as a blood-sucking arthropod, ⁇ The blood-sucking arthropod control composition for treating living space formations according to any one of 12> to ⁇ 14>.
  • the blood-sucking arthropod control composition for treating living space formations according to ⁇ 15>, wherein the Dipteridae (Clicidae) insect is an Anopheles insect.
  • ⁇ 17> The blood-sucking arthropod control for treating living space formations according to ⁇ 15> or ⁇ 16>, wherein the Anopheles genus insect is at least one of Gambier gambiae and Anopheles sinensis Composition.
  • the blood-sucking arthropod control composition for living space formation treatment according to any one of ⁇ 12> to ⁇ 18>, which is a wettable powder or a flowable agent.
  • a method for controlling blood-sucking arthropods and a composition for controlling blood-sucking arthropods for treating living space formation which are excellent in durability and effective against resistant pests. be able to.
  • a blood-sucking arthropod control composition for treating living space formation according to an embodiment of the present invention is at least an amide derivative represented by the following general formula (1): Contains one as an active ingredient.
  • the blood-sucking arthropod control method according to one embodiment of the present invention includes a blood-sucking node for treating living space formations, which contains at least one amide derivative represented by the following general formula (1) as an active ingredient.
  • the living space formation is treated with the paw animal control composition.
  • the blood-sucking arthropod control method according to the present embodiment is also excellent in sustainability and effective against resistant pests, and exhibits a high pest control effect.
  • Q represents a phenyl group or a phenyl group substituted with a fluorine atom.
  • R represents a hydrogen atom or a methyl group.
  • Y 1 and Y 2 each independently represents a bromine atom, an iodine atom or a trifluoromethyl group.
  • the amide derivative represented by the general formula (1) used in the present embodiment may contain one or more asymmetric carbon atoms or asymmetric centers in the structural formula, and two or more kinds of optical derivatives may be used. Although isomers may exist, all of the optical isomers and a mixture in which they are contained in an arbitrary ratio are also included.
  • the amide derivative represented by the general formula (1) used in the present embodiment may have two or more geometric isomers derived from a carbon-carbon double bond in the structural formula. And all geometric isomers and mixtures in which they are contained in any proportion.
  • the compound represented by the general formula (1) is 2-fluoro-3- (N-methylbenzamide) -N- (2-bromo-6-trifluoromethyl-4-methyl represented by the following formula (2). (Heptafluoropropan-2-yl) phenyl) benzamide is preferred.
  • the amide derivative represented by the general formula (1) used in the present embodiment can be produced, for example, according to the method described in the specification of International Publication No. 2010/013567.
  • blood-sucking arthropod that can be controlled by the composition and the method for controlling a blood-sucking arthropod according to the present embodiment include the following blood-sucking arthropods. It is not limited.
  • Anopheles genus As a Diptera (Clicidae) insect, Anopheles genus, Anopheles gambiae, Anopheles arabiensis, Anopheles funestus, Anopheles melas, Anopheles minimus, Anopheles dibes, Anopheles staphines Culex pipiens molestus, Culex pipiens pipiens, Culex quinquefasciatus, Culex pipiens pallens, Culex restus, Culex tarsitalis, Culex tarsalis Aedes genus, Aedes aegypti, Aedes albopictus, Aedes Japanicus, Aedes vexans, etc.
  • insects such as abs, flies, flyfish, sand flies, nucifers, tsetse flies, chironomids, fleas, lices, bed bugs, sand turtles, ticks, ticks.
  • the blood-sucking arthropod is a fly order mosquito insect from the viewpoint of controlling effect.
  • the amide derivative represented by the general formula (1) in the present embodiment is usually mixed with a suitable solid carrier or liquid carrier, and further, a surfactant, a penetrating agent, a spreading agent, a thickening agent if desired.
  • a surfactant emulsion (emulsifiable concentrate), Wettable powder, flowable, water-soluble powder, water dispersible granule, water-soluble granule, suspension concentrate, milk Any dosage form such as concentrated emulsion, suspoemulsion, microemulsion, dustable powder, granule tablet, emulsifiable gel
  • Rukoto can.
  • the preparations of any of the above dosage forms can be provided by being enclosed in a water-soluble package such as a water-soluble capsule or a water-soluble film bag.
  • a water-soluble package such as a water-soluble capsule or a water-soluble film bag.
  • the composition according to the present embodiment may be a wettable powder or a flowable agent.
  • the inert carrier that can be used in the composition according to this embodiment may be a solid or a liquid.
  • Examples of materials that can be used as a solid inert carrier include soybean powder, cereal powder, wood powder, bark powder, saw powder, tobacco stem powder, walnut shell powder, bran, fiber powder, residue after extraction of plant extracts, Synthetic polymers such as pulverized synthetic resins, clays (eg kaolin, bentonite, acid clay), talc (eg talc, pyrophyllide, etc.), silicas (eg diatomaceous earth, silica sand, mica, white carbon (hydrous finely divided silicon, hydrous) Synthetic high-dispersion silicic acid, also called silicic acid, may contain calcium silicate as the main component depending on the product.]), Activated carbon, sulfur powder, pumice, calcined diatomaceous earth, brick ground (eg clay), fly ash, sand, calcium carbonate , Inorganic mineral powders such as calcium phosphate, chemical fertilizers such as ammonium sulfate, phosphoric acid, ammonium nitrate
  • the active ingredient compound can be dispersed with the aid of an auxiliary agent (for example, a surfactant) in addition to those having a solvent ability per se, and having no solvent ability.
  • an auxiliary agent for example, a surfactant
  • water alcohols (eg, methanol, ethanol, isopropanol, butanol, ethylene glycol, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, etc.), ethers (eg, Diethyl ether, dioxane, cellosolve, diisopropyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (eg kerosene, mineral oil, etc.), aromatic hydrocarbons (eg benzene, toluene, xylene, solvent naphtha, alkylnaphthalen
  • solid carriers and liquid carriers may be used alone or in combination of two or more.
  • surfactant examples include polyoxyethylene (mono or di) alkyl ether, polyoxyethylene alkyl (mono or di) phenyl ether, polyoxyethylene (mono, di or tri) styryl phenyl ether, polyoxyethylene polyoxypropylene Block copolymer, polyoxyethylene fatty acid (mono or di) ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, castor oil ethylene oxide adduct, acetylene glycol, acetylene alcohol, ethylene oxide adduct of acetylene glycol, ethylene of acetylene alcohol
  • Nonionic surfactants such as oxide adducts and alkyl glycosides, alkyl sulfate esters, alkylbenzene sulfonates, ligni Sulfonate, alkylsulfosuccinate, dialkylsulfosuccinate, naphthalenesulf
  • the content of these surfactants is not particularly limited, but is usually in the range of 0.05 to 20 parts by weight per 100 parts by weight of the preparation. These surfactants may be used alone or in combination of two or more.
  • thickeners examples include natural gums such as xanthan gum, welan gum, guar gum, tragacanth gum, and gum arabic; fine powders of inorganic minerals such as smectite, sepiolite, attapulgite, laponite, montmorillonite, hectorite; carboxymethylcellulose, hydroxyethylcellulose, carboxy Cellulose derivatives such as ethyl cellulose, methyl cellulose, hydroxypropyl cellulose and salts thereof; starch derivatives such as various grades of dextrin and sodium carboxymethyl starch; natural products such as sodium alginate and sodium caseinate and derivatives thereof; polyvinyl alcohol, polyacryl Examples thereof include acids and derivatives thereof, and water-soluble synthetic polymers such as polyvinylpyrrolidone. Moreover, these thickeners may be used independently or may use 2 or more types together.
  • the protective colloid agent examples include water-soluble celluloses such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose and carboxymethylcellulose, polyalkylene glycols such as polyethylene glycol and polypropylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, guar gum and gum arabic. , Gelatin, polyacrylate, alginate and the like. Moreover, these protective colloid agents may be used alone or in combination of two or more.
  • antifreezing agent examples include ethylene glycol, diethylene glycol, propylene glycol, glycerin and the like. These antifreeze agents may be used alone or in combination of two or more.
  • antifoaming agents examples include silicone, acetylene glycol, fluorine, and fatty acid. These antifoaming agents may be used alone or in combination of two or more.
  • antifungal agent examples include benzothiazole derivatives, sorbic acid, potassium sorbate, butyl p-oxybenzoate, and the like. These antifungal agents may be used alone or in combination of two or more.
  • the composition according to this embodiment further includes at least one of other generally known insecticidal components (insect controlling components) and synergists.
  • insecticidal ingredients include, for example: Acrinathrin, permethrin, phenothrin, d-phenothrin, allethrin, dd-alleslin, dd-alleslin, pyrethrin, praretrin, ciphenothrin, cyfluthrin, beta-cyfluthrin, bifenthrin, cycloprotorin, cyhalothrin, lambda cihalothrin, gamma cyhalothrin , Cypermethrin, sigmacipermethrin, alpha cypermethrin, zetacypermethrin, dimefluthrin,
  • composition according to the present embodiment tends to be more excellent in insecticidal effect on blood-sucking arthropods, and therefore, as other insecticidal components, at least selected from the group consisting of permethrin, alpha cypermethrin, deltamethrin and etofenprox.
  • insecticidal components at least selected from the group consisting of permethrin, alpha cypermethrin, deltamethrin and etofenprox.
  • one kind of compound may be further contained as an active ingredient.
  • the weight ratio of the amide derivative represented by the general formula (1) to the total of other insecticidal components and synergists is such that the other pesticidal components are contained in 1 part by weight of the amide derivative represented by the general formula (1).
  • the amount is usually 0.01 to 100 parts by weight, preferably 0.02 to 50 parts by weight.
  • the amount of the active ingredient of the composition according to this embodiment is usually 0.1 to 20% by weight for powders, 5 to 50% by weight for emulsions, 3 to 90% by weight for wettable powders, and 0.1 to 20 for granules. It is preferably 5% by weight, 5% to 90% by weight for flowable preparations, and 3% to 90% by weight for wettable granules.
  • the amount of carrier in each dosage form is usually 60 to 99.9% by weight for powders, 40 to 95% by weight for emulsions, 10 to 90% by weight for wettable powders, and 80 to 99.9% by weight for granules.
  • the flowable preparation is preferably 10 to 95% by weight, and the granular wettable powder is preferably 10 to 90% by weight.
  • the amount of the adjuvant is usually 0.1 to 20% by weight for powders, 1 to 20% by weight for emulsions, 0.1 to 20% by weight for wettable powders, 0.1 to 20% by weight for granules, It is preferably 0.1 to 20% by weight for flowable preparations and 0.1 to 20% by weight for granular wettable powders.
  • the composition according to the present embodiment may be used as it is, or may be used by diluting or suspending it appropriately with water or the like.
  • the amount of the active ingredient is usually preferably used at a concentration of 0.0001 to 5000 ppm, more preferably 0.01 to 1000 ppm.
  • the living space is a space into which at least one of humans and livestock enters
  • examples of the living space formation include a house wall surface, a ceiling, a pillar, a column, a window, a door, a tent, and a mosquito net.
  • the house wall surface of a house When the wall surface of a house is treated with the composition according to the present embodiment, the house wall surface may be treated such as spraying, coating, and transpiration. Moreover, using the material spread
  • the material of the house wall is concrete (cement), brick, bamboo, wood, tile, ceramic, mud, etc.
  • the material of the ceiling is thatch, tin, concrete (cement), bamboo, wood, etc. The present invention is not limited to these examples.
  • the mosquito net When treating a mosquito net with the composition according to the present embodiment, the mosquito net may be immersed in the composition according to the present embodiment, or a solution or suspension in which the composition according to the present embodiment is appropriately diluted with water or the like. The mosquito net may be soaked in the chemical solution thus applied, and other treatments such as spraying and coating may be applied to the mosquito net.
  • Examples of the material of the mosquito net include resin, natural fiber, fiber material such as glass fiber, and the like, and among them, resin is preferable.
  • examples of natural fibers include pulp, cellulose, cotton, hemp, and hair.
  • a thermoplastic resin is preferable.
  • examples of the thermoplastic resin include polyolefin resin, polyvinyl alcohol, polyvinyl acetate, polycarbonate, polyester, polyamide (for example, nylon), polystyrene, polymethyl methacrylate, acrylonitrile-butadiene-styrene copolymer, and polyvinyl chloride. Can be mentioned.
  • polyolefin resin is preferable.
  • polystyrene resin the compounds listed in the following (i) to (iii) are preferable.
  • ⁇ -olefin homopolymer polyethylene, polypropylene, etc.
  • ethylene- ⁇ -olefin copolymer for example, ethylene-propylene copolymer, ethylene-1-butene copolymer, ethylene-4-methyl-1-pentene copolymer, or ethylene-hexene copolymer Such.
  • (Iii) Copolymer of an organic carboxylic acid derivative having an ethylenically unsaturated bond and ethylene: for example, ethylene-methyl methacrylate copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene- Vinyl acetate-methyl methacrylate copolymer.
  • the amount of the active ingredient carried on the surface of the living space formation may be appropriately adjusted according to the application time, application place, treatment method, etc., and is preferably 0.1 to 3000 mg / m 2 , for example. More preferably, it is 1 to 500 mg / m 2 .
  • the composition according to the present embodiment is for living space formation treatment, but is a blood-sucking arthropod, for example, a lake, a wetland, a paddy field, a reservoir, a septic tank, a drainage channel, etc. It can be expected to prevent infections such as malaria, dengue fever and zika fever prophylactically.
  • composition according to the present embodiment may be used by mixing with various other insecticides, acaricides, nematicides, bactericides, synergists and the like as needed during processing.
  • a brofuranilide slurry, a thickener solution A, and a thickener solution B were prepared.
  • ⁇ Preparation Example 1> Compound represented by formula (2) (2-fluoro-3- (N-methylbenzamide) -N- (2-bromo-6-trifluoromethyl-4- (heptafluoropropan-2-yl) phenyl) benzamide ) 50.0 parts, 2.0 parts of polyoxyethylene styrylated phenol phosphate salt, 1.0 part of dioctyl sulfosuccinate, 0.1 part of silicone antifoaming agent and 46.9 parts of water were mixed uniformly.
  • Example 1 ⁇ Formulation example 1> 50.0 parts of the compound represented by the formula (2), 2.5 parts of diethylene glycol monododecyl ether (polyoxyethylene monoalkyl ether), 2.5 parts of nonaethylene glycol monododecyl ether (polyoxyethylene monoalkyl ether), Polyvinyl alcohol (2.0 parts), kaolin (38.0 parts), white carbon (5.0 parts) were uniformly ground and mixed to obtain a wettable powder.
  • diethylene glycol monododecyl ether polyoxyethylene monoalkyl ether
  • nonaethylene glycol monododecyl ether polyoxyethylene monoalkyl ether
  • Polyvinyl alcohol 2.0 parts
  • kaolin 38.0 parts
  • white carbon 5.0 parts
  • Example 2 ⁇ Formulation example 2> 50.0 parts of the compound represented by the formula (2), 3.0 parts of alkyl sulfate ester salt, 4.0 parts of dialkyl sulfosuccinate, 3.0 parts of polyoxyethylene monoalkyl ether, 2.0 parts of polyvinyl alcohol, 38.0 parts of kaolin and the above were ground and mixed uniformly to obtain a wettable powder.
  • Example 3 ⁇ Formulation example 3> 2. 50.0 parts of the compound represented by the formula (2), 4.0 parts of dialkylsulfosuccinate, 3.0 parts of polyoxyethylene alkyl ether, salt of formalin condensate (formaldehyde condensate) of alkylnaphthalenesulfonic acid 0 parts, 39.5 parts of kaolin, 0.5 parts of a silicone-based antifoaming agent, and the above were ground and mixed uniformly to obtain a wettable powder.
  • Example 4 ⁇ Formulation example 4> 50.0 parts of the compound represented by formula (2), 5.0 parts of alkylnaphthalene sulfonate, 3.0 parts of lignin sulfonate, 36.5 parts of kaolin, 5.0 parts of white carbon, silicone-based defoaming 0.5 parts of the agent was uniformly ground and mixed to obtain a wettable powder.
  • Example 5 ⁇ Formulation example 5> 50.0 parts of the compound represented by the formula (2), 1.8 parts of polyoxyethylene tristyryl phenyl ether ammonium sulfate (ethylene oxide addition mole number 14), 1.2 parts of polyoxyethylene polyoxypropylene block copolymer, propylene A flowable agent was obtained by uniformly mixing 5.0 parts of glycol, 0.5 parts of a silicone-based antifoaming agent, 0.1 part of bentonite and 41.4 parts of water and wet pulverizing them.
  • Example 6 ⁇ Formulation example 6> 10.0 parts of brofuranilide slurry obtained in Preparation Example 1, 3.0 parts of polyoxyethylene tristyryl phenyl ether ammonium sulfate (ethylene oxide addition mol number 14), formalin condensate (formaldehyde condensate) of alkylnaphthalene sulfonic acid A flowable agent was obtained by uniformly mixing 5.0 parts of the above salt, 60.0 parts of the thickener solution A obtained in Preparation Example 2, and 22.0 parts of water.
  • Example 7 ⁇ Formulation example 7> Example 6 In Example 6, except that 5.0 parts of salt of formalin condensate (formaldehyde condensate) of alkylnaphthalenesulfonic acid was changed to 10.0 parts and 22.0 parts of water were changed to 17.0 parts. In the same manner as above, a flowable agent was obtained.
  • Example 8 ⁇ Formulation example 8> In Example 7, except that 3.0 parts of polyoxyethylene tristyrylphenyl ether ammonium sulfate salt (ethylene oxide addition mole number 14) was changed to 5.0 parts, and 17.0 parts of water was changed to 15.0 parts. A flowable agent was obtained in the same manner as in Example 7.
  • Example 9 ⁇ Formulation example 9>
  • Example 6 is the same as Example 6 except that polyoxyethylene tristyryl phenyl ether sulfate ammonium salt (ethylene oxide addition mole number 14) is changed to polyoxyethylene tristyryl phenyl ether ammonium sulfate salt (ethylene oxide addition mole number 9). The flowable agent was obtained.
  • Example 10 ⁇ Formulation Example 10> 40.0 parts of brofuranilide slurry, 3.0 parts of polyoxyethylene tristyryl phenyl ether ammonium sulfate (ethylene oxide addition mole number 14), 5.0 parts of formalin condensate (formaldehyde condensate) of alkylnaphthalene sulfonic acid
  • the flowable agent was obtained by mixing 40.0 parts of the thickener solution B obtained in Preparation Example 3 and 12.0 parts of water.
  • Example 11 ⁇ Formulation Example 11>
  • Example 6 is the same as Example 6 except that polyoxyethylene tristyryl phenyl ether sulfate ammonium salt (ethylene oxide addition mole number 14) is changed to polyoxyethylene tristyryl phenyl ether ammonium sulfate salt (ethylene oxide addition mole number 16). The flowable agent was obtained.
  • compositions and blood-sucking arthropod control method according to the present embodiment will be specifically described in the following test examples, but the present invention is not limited to these.
  • Example 1 Indoor residual spraying (IRS) using various wall materials for Anopheles gambiae Reagent: A wettable powder prepared according to Formulation Example 2 (Example 2), Bendiocarb WP (Reference Example 1) Wall material: Wood, Tile, Cement Test insects: Anopheles gambiae Kisumu system treatment method: In October, a diluted solution of the above formulation is sprayed on the wall surface material with a tower sprayer so as to have a predetermined dose, and then dried at a temperature of 30 ° C. And stored in a constant temperature room with a humidity of 80%.
  • Insecticidal test A standard WHO plastic cone was placed on the treated wall surface material, and a female Gambier anopheles female adult was placed on the lid. After exposure for 3 minutes, Gambier anopheles was placed in a separate container, and after 24 hours, life and death were examined to calculate the mortality. This was continued from November to the following April, and the residual effect was evaluated (three consecutive systems).
  • Insecticidal test A plastic cup was put on the wall material, and a female Chikaieka female was placed inside and covered. After 30 minutes of exposure, Chikaeka was placed in another plastic cup, and after 24 hours, life and death were investigated and the death rate was calculated (two-line system).
  • Test preparation for mosquito net immersion test for Anopheles gambiae flowable agent prepared in accordance with Formulation Example 5 (Example 5), PermaNet2 (Reference Example 3, Deltamethrin)
  • Test insect Anopheles gambiae Kisumu system treatment method: A polyester net was immersed in a diluted solution of the above preparation and dried.
  • Insecticidal test The above-mentioned net is covered with a standard WHO plastic cone, and adult female Gambier spp. Is exposed to 3 minutes or 20 minutes, then placed in another container and knocked down after 1, 24, 48, 72 hours ( The number of KD) was investigated and the KD rate was calculated (triple system).
  • Insecticidal test A standard WHO plastic cone was placed on the treated wall surface material, and a female Gambier anopheles female adult was placed on the lid. After exposure for 3 minutes, Gambier anopheles was placed in a separate container. Further, after 1, 24, 48, and 72 hours, the number of knockdowns (KD) was investigated and the KD rate was calculated (three consecutive systems).
  • Sensitivity test reagent for each strain of Abiepheus gambiae and Aedes aegypti Compound test insect represented by formula (2): Abiepheus gambiae strain , Kisumu RDL line, Akron line, Tiassale 2 line, Aedes aegypti Cayman line, New La line insecticidal test: The compound represented by formula (2) is diluted to a predetermined concentration with acetone, and the target insect is used using a local application device. Applied to adult female breast. After 24 hours, the death rate was investigated.
  • Sensitivity test reagent for Anopheles sinensis Compound represented by formula (2)
  • Test specimen Anopheles sinensis August 2016 Shiga
  • Prefecture collected line insecticide test compound represented by formula (2) was diluted to a predetermined concentration with acetone, and 0.2 ⁇ l / head was applied to the chest of a female target insect using a local application device. After 1, 24, 48 and 72 hours, the number of knockdowns (KD) was investigated and the KD rate was calculated (triple regime).
  • Example 7 Indoor Residual Spraying (IRS) test agent for Anopheles gambiae: wettable powder prepared according to Formulation Example 3 (Example 3), Bendiocarb WP (Reference Example 1), Deltamethrin WG (Reference Example 4) Wall material: Mud Test insects: Anopheles gambiae Kisumu system treatment method: In April, a diluted solution of the above preparation is sprayed on the wall surface material with a tower sprayer so as to have a predetermined amount, and then dried at a temperature of 30 ° C. And stored in a constant temperature room with a humidity of 80%.
  • IVS Indoor Residual Spraying
  • Insecticidal test A standard WHO plastic cone was placed on the treated wall surface material, and a female Gambier anopheles female adult was placed on the lid. After exposure for 3 minutes, Gambier anopheles was placed in a separate container, and after 24 hours, life and death were investigated to calculate the mortality. This was continued from May to November, and the residual effect was evaluated (three consecutive systems).
  • Insecticidal test reagent for larvae of Culex pipiens molestus Compound test worm represented by formula (2): tiger squid (Culex pipiens molestus) Insecticidal test: 25 ml of water was put into a glass tube, and then 250 ⁇ l of an acetone solution of the compound represented by the formula (2) was added to prepare a predetermined concentration. Ten final-age larvae were released, and after 2 days, life and death were investigated, and the mortality rate was calculated. As a result, the compound represented by the formula (2) showed a death rate of 70% or more at 0.001 ppm.
  • composition according to the present embodiment has a long-term residual effect and is also effective against resistant pests, and therefore has high industrial applicability.

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne un procédé de lutte contre des arthropodes hématophages, dans lequel des éléments formant une habitation sont traités avec une composition de lutte contre des arthropodes hématophages pour traiter des éléments formant une habitation, la composition de lutte contenant au moins un dérivé d'amide représenté par la formule générale (1) comme principe actif. (Dans la formule, Q représente un groupe phényle ou un groupe phényle substitué par un atome de fluor, R représente un atome d'hydrogène ou un groupe méthyle, et Y1 et Y2 représentent chacun indépendamment un atome de brome, un atome d'iode ou un groupe trifluorométhyle.)
PCT/JP2017/000655 2016-01-12 2017-01-11 Procédé de lutte contre des arthropodes hématophages et composition de lutte contre des arthropodes hématophages pour le traitement d'éléments formant des habitations WO2017122687A1 (fr)

Priority Applications (2)

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BR112018014039-2A BR112018014039B1 (pt) 2016-01-12 2017-01-11 Método de controle de artrópodes hematófagos
PH12018550106A PH12018550106A1 (en) 2016-01-12 2018-07-05 Hematophagous arthropod control method, and hematophagous arthropod control composition for treating living space forming element

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JP2016-003657 2016-01-12
JP2016003657 2016-01-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023282140A1 (fr) * 2021-07-06 2023-01-12 住友化学株式会社 Composition de lutte antiparasitaire et procédé de lutte antiparasitaire

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010018714A1 (fr) * 2008-08-13 2010-02-18 三井化学アグロ株式会社 Dérivé amide, agent antiparasitaire contenant le dérivé amide et utilisation de l’agent antiparasitaire
JP2011157294A (ja) * 2010-01-29 2011-08-18 Mitsui Chemicals Agro Inc 有害生物防除組成物
JP2011523944A (ja) * 2008-05-21 2011-08-25 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト 表面に対する改善された長期効果を有する殺虫剤製剤
JP2012513379A (ja) * 2008-12-23 2012-06-14 ビーエーエスエフ ソシエタス・ヨーロピア 有害生物に対する保護活性を付与するための非生物材料の含浸方法および含浸用水性製剤

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011523944A (ja) * 2008-05-21 2011-08-25 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト 表面に対する改善された長期効果を有する殺虫剤製剤
WO2010018714A1 (fr) * 2008-08-13 2010-02-18 三井化学アグロ株式会社 Dérivé amide, agent antiparasitaire contenant le dérivé amide et utilisation de l’agent antiparasitaire
JP2012513379A (ja) * 2008-12-23 2012-06-14 ビーエーエスエフ ソシエタス・ヨーロピア 有害生物に対する保護活性を付与するための非生物材料の含浸方法および含浸用水性製剤
JP2011157294A (ja) * 2010-01-29 2011-08-18 Mitsui Chemicals Agro Inc 有害生物防除組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023282140A1 (fr) * 2021-07-06 2023-01-12 住友化学株式会社 Composition de lutte antiparasitaire et procédé de lutte antiparasitaire

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PH12018550106A1 (en) 2019-07-15

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