WO2016186057A1 - 蛍光体、その製造方法、照明器具および画像表示装置 - Google Patents
蛍光体、その製造方法、照明器具および画像表示装置 Download PDFInfo
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- WO2016186057A1 WO2016186057A1 PCT/JP2016/064385 JP2016064385W WO2016186057A1 WO 2016186057 A1 WO2016186057 A1 WO 2016186057A1 JP 2016064385 W JP2016064385 W JP 2016064385W WO 2016186057 A1 WO2016186057 A1 WO 2016186057A1
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- phosphor
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- alon
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 174
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000005286 illumination Methods 0.000 title abstract 2
- 239000013078 crystal Substances 0.000 claims abstract description 187
- 229910017109 AlON Inorganic materials 0.000 claims abstract description 112
- 230000005284 excitation Effects 0.000 claims abstract description 37
- 239000006104 solid solution Substances 0.000 claims abstract description 34
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 33
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 23
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims description 38
- 239000002994 raw material Substances 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 claims description 3
- 239000011572 manganese Substances 0.000 description 49
- 239000000843 powder Substances 0.000 description 30
- 238000010304 firing Methods 0.000 description 26
- 239000012071 phase Substances 0.000 description 20
- 239000011777 magnesium Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 238000010894 electron beam technology Methods 0.000 description 12
- 229910052744 lithium Inorganic materials 0.000 description 10
- 150000004767 nitrides Chemical class 0.000 description 10
- 238000000295 emission spectrum Methods 0.000 description 9
- 238000000695 excitation spectrum Methods 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 7
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052748 manganese Inorganic materials 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 230000009257 reactivity Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000002189 fluorescence spectrum Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- 102100032047 Alsin Human genes 0.000 description 1
- 101710187109 Alsin Proteins 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910017414 LaAl Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000003991 Rietveld refinement Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002772 conduction electron Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- IDBFBDSKYCUNPW-UHFFFAOYSA-N lithium nitride Chemical compound [Li]N([Li])[Li] IDBFBDSKYCUNPW-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 238000001683 neutron diffraction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- -1 oxides Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
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- 238000011160 research Methods 0.000 description 1
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- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000012856 weighed raw material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
- C09K11/641—Chalcogenides
- C09K11/643—Chalcogenides with alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/0883—Arsenides; Nitrides; Phosphides
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- C—CHEMISTRY; METALLURGY
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/61—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing fluorine, chlorine, bromine, iodine or unspecified halogen elements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/507—Wavelength conversion elements the elements being in intimate contact with parts other than the semiconductor body or integrated with parts other than the semiconductor body
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/56—Materials, e.g. epoxy or silicone resin
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/483—Containers
- H01L33/486—Containers adapted for surface mounting
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- H—ELECTRICITY
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- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/54—Encapsulations having a particular shape
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- H—ELECTRICITY
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- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/62—Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
Definitions
- the present invention relates to a phosphor using an AlON (aluminum oxynitride) crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON as a base crystal, a method for producing the same, and an application thereof.
- the present invention provides an AlON (aluminum oxynitride) crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON that emits light having a peak in a wavelength range of 490 nm to 550 nm.
- the present invention relates to a phosphor as a base crystal, a method for manufacturing the same, and a lighting apparatus and an image display device using the phosphor.
- Phosphors are fluorescent display tubes (VFD (Vacuum-Fluorescent Display)), field emission displays (FED (Field Emission Display) or SED (Surface-Conduction Electron Display) (Plasma Display) (PDP). ), Cathode ray tube (CRT (Cathode-Ray Tube)), liquid crystal display backlight (Liquid-Crystal Display Backlight), white light emitting diode (LED (Light-Emitting Diode)) and the like.
- VFD Voluum-Fluorescent Display
- FED Field Emission Display
- SED Surface-Conduction Electron Display
- Cathode ray tube CRT (Cathode-Ray Tube)
- liquid crystal display backlight Liquid-Crystal Display Backlight
- LED Light-Emitting Diode
- sialon phosphors can be used as phosphors with little reduction in luminance even when excited with high energy.
- phosphors based on inorganic crystals containing nitrogen in the crystal structure such as oxynitride phosphors and nitride phosphors.
- this oxynitride phosphor As an example of this oxynitride phosphor, a phosphor in which Mn is activated in an AlON crystal is known (see, for example, Patent Document 1). When excited with ultraviolet light, blue light, or an electron beam, this phosphor emits green light having a peak at 510 to 520 nm, a small half width of the spectrum, and good color purity. Therefore, it is suitable as a green phosphor for an image display device.
- the phosphor obtained by activating Mn in an AlON crystal has good color purity as green, it cannot be said that the excitation characteristic in blue of 440 nm to 449 nm (also simply referred to as blue excitation characteristic) is sufficient. Further, when Mg is added to the AlON crystal, the blue excitation characteristics are improved, but further improvement in emission intensity has been demanded.
- An object of the present invention is to meet such a demand, and is superior in emission characteristics than conventional AlON phosphors, and in particular, a phosphor excellent in blue excitation characteristics of 440 nm to 449 nm, its manufacturing method, It is providing the lighting fixture and image display apparatus which used this.
- the object of the present invention is to provide a phosphor emitting a green light having a good color purity and having a peak in a wavelength range of 490 nm or more and 550 nm or less, a manufacturing method thereof, a lighting fixture using the same, and an image display device. It is to be.
- an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON is added with at least Mn and an A element (where A is a monovalent metal).
- an inorganic compound having a specific composition range containing Mn and Li as an element A has high luminous efficiency with blue excitation and becomes a phosphor emitting green light with good color purity. Found to be suitable.
- the phosphor of the present invention contains at least Mn and an A element (provided that the A element is a monovalent metal element) in an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON. 490 nm or more by irradiating an excitation source containing an inorganic compound containing a D element (wherein the D element is an element other than Mn, the A element, Al, O, and N) as necessary. Fluorescence having a peak at a wavelength in the range of 550 nm or less is emitted, thereby solving the above problem.
- the Mn and A elements, and optionally the D element, may be dissolved in the AlON crystal, the AlON solid solution crystal, or an inorganic crystal having the same crystal structure as the AlON.
- the parameters a, b, c, d, e and f are 0.004 ⁇ a ⁇ 0.10 0.002 ⁇ b ⁇ 0.032 0.31 ⁇ c ⁇ 0.41 0.5 ⁇ d ⁇ 0.57 0.02 ⁇ e ⁇ 0.075 and 0 ⁇ f ⁇ 0.02 May be satisfied.
- the element A may be Li.
- the element D may be Mg. Part or all of the element D is Mg, and the parameter value f 1 (atomic fraction) indicating the content of Mg may satisfy 0.001 ⁇ f 1 ⁇ 0.09. Part or all of the element D is F, and the parameter value f 2 (atomic fraction) indicating the content of F may satisfy 0.0001 ⁇ f 2 ⁇ 0.05.
- a luminaire according to the present invention includes at least a light emitting source that emits light having a wavelength of 410 nm or more and 460 nm or less, and a phosphor or a light transmissive material in which the phosphor is dispersed, and the phosphor includes the phosphor described above. This solves the above problem.
- the light emitting source may be an LED (light emitting diode) or an LD (laser diode) that emits light having a peak in a wavelength range of 430 nm to 460 nm.
- the light emitting source may be an LED (light emitting diode) or an LD (laser diode) that emits light having a peak in a wavelength range of 440 nm to 449 nm.
- the phosphor may further include a red phosphor having a peak at a wavelength in a range of 620 nm to 670 nm.
- the red phosphor may be a Mn 4+ activated phosphor.
- the red phosphor may be KSF and / or KSNAF.
- the ratio of the phosphor in the light transmitting body may be 30% by volume or more and 90% by volume or less.
- the light transmitting body may be selected from the group consisting of acrylic resin, silicone resin, and glass.
- the phosphor production method includes at least a raw material containing Al 2 O 3 , AlN, Mn and a raw material containing an A element (however, the A element is a monovalent metal element), if necessary
- the raw material containing D element (however, the D element is an element other than Mn, A element, Al, O, N) is mixed at 1500 ° C. in a nitrogen atmosphere in the range of 0.2 to 100 atm. Baking is performed at a temperature in the range of 2400 ° C. or lower, thereby solving the above-described problem.
- the element A may be Li.
- the element D may be a divalent metal element.
- the phosphor of the present invention includes an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as that of AlON, containing Mn as a metal ion serving as an emission center and an A element that is a monovalent metal element.
- an inorganic compound containing as a main component green light having a peak at a wavelength in the range of 490 nm to 550 nm and having good color purity can be emitted.
- the phosphor of the present invention having a specific composition is excellent in blue excitation characteristics of emitting fluorescence having a peak in a wavelength range of 510 nm or more and 530 nm or less when irradiated with excitation light having a wavelength of 410 nm or more and 449 nm or less. . Therefore, it is a useful phosphor that can be suitably used for LED, FED, SED, CRT and the like. In particular, it is useful for backlight LEDs for liquid crystal televisions and portable terminals.
- FIG. 3 shows an XRD pattern of an inorganic compound of Example 1.
- FIG. 3 shows an excitation spectrum and an emission spectrum of the inorganic compound of Example 1.
- the schematic structure figure of the lighting fixture (LED lighting fixture) of this invention. 1 is a schematic structural diagram of an image display device (field emission display panel) of the present invention.
- the phosphor of the present invention contains at least Mn and A elements (provided that the A element is a monovalent metal element) in an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON.
- An inorganic compound can be included as a main component.
- the AlON crystal is a crystal having a cubic spinel crystal structure, and is also called ⁇ -AlON (where Non-Patent Documents 1 and 2 are , Incorporated herein by reference (Theentities contents of Non-patent References 1 and 2 are incorporated here by reference.)).
- This crystal is synthesized by mixing Al 2 O 3 with AlN and firing at 1850 ° C.
- the AlON solid solution crystal is a crystal in which the oxygen / nitrogen ratio is changed while maintaining the crystal structure of AlON and / or a crystal to which other elements are added.
- Other added elements include silicon, Mg, F and the like.
- An inorganic crystal having the same crystal structure as AlON is a crystal in which a part or all of Al, O, and N are substituted with other elements while maintaining the AlON crystal structure.
- these crystals can be used as host crystals.
- An AlON crystal or an AlON solid solution crystal can be identified by X-ray diffraction or neutron diffraction. The details of the crystal structure are described in Non-Patent Documents 1 and 2, and the crystal structure and the X-ray diffraction pattern are uniquely determined from the lattice constant, space group, and atomic position data described therein.
- inorganic crystals having the same crystal structure as AlON, whose lattice constants are changed by replacing constituent elements with other elements are also the same. Identified and included as part of the present invention.
- AlON crystal, AlON solid solution crystal, or inorganic crystal having the same crystal structure as AlON is used as a base crystal, and the main component is an inorganic compound containing optically active metal element Mn. It becomes a fluorescent substance.
- MON-containing AlON crystal, AlON solid solution crystal, or inorganic crystal having the same crystal structure as AlON is further added to element A (where A element is a monovalent metal element) ),
- element A where A element is a monovalent metal element
- Monovalent metals are easily dissolved in the base crystal such as AlON crystal, and Mn 2+ can be stably present in the crystal to stabilize the crystal structure, and these ions are easily taken into the crystal. Become. Thereby, the brightness
- the A element is Li, this effect is large. Therefore, the A element is preferably Li for improving the light emission characteristics.
- the phosphor of the present invention more preferably has the same crystal structure as AlON crystal, AlON solid solution crystal, or AlON containing Mn and A element (where A element is a monovalent metal element).
- the inorganic crystal further contains an inorganic compound containing a D element (provided that the D element is an element other than Mn, A element, Al, O, and N) as a main component, further excellent light emission characteristics are exhibited.
- the element D is a divalent metal
- the divalent metal easily dissolves in the base crystal such as an AlON crystal, and Mn 2+ can exist stably in the crystal in order to stabilize the crystal structure. These ions are easily taken into the crystal. Thereby, the brightness
- the D element is Mg
- the D element is preferably Mg for improving the light emission characteristics.
- Mn, A element and, if necessary, D element are dissolved in AlON crystal, AlON solid solution crystal, or inorganic crystal having the same crystal structure as AlON.
- these elements are dissolved in these matrix crystals, high-luminance emission is possible.
- Patent Documents 1 and 2 a phosphor having an AlON crystal as a base crystal has been reported. However, it has been studied to use an AlON crystal containing a monovalent metal element, particularly Li, as a base crystal. Absent. That is, by containing an A element which is a monovalent metal element, a phosphor having an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON as a base crystal has excellent blue excitation characteristics. It should be noted that the discovery of emitting green light with good color purity was first discovered by the present inventors.
- a composition range selected from is preferred.
- the A element is a monovalent metal element
- the D element is an element other than Mn, A element, Al, O, and N.
- the phosphor of the present invention satisfying the above composition can emit fluorescence having a peak at a wavelength in the range of 490 nm to 550 nm when irradiated with an excitation source.
- the parameters a, b, c, d, e and f are 0.004 ⁇ a ⁇ 0.10 0.002 ⁇ b ⁇ 0.032 0.31 ⁇ c ⁇ 0.41 0.5 ⁇ d ⁇ 0.57 0.02 ⁇ e ⁇ 0.075 and 0 ⁇ f ⁇ 0.02 Meet.
- the phosphor of the present invention satisfying the above composition can emit high-intensity fluorescence having a peak in a wavelength range of 510 nm or more and 530 nm or less when irradiated with an excitation source.
- a represents the amount of metal ion Mn that becomes the emission center, and satisfies 0.0003 ⁇ a ⁇ 0.10. If the a value is less than 0.0003, the number of ions that become the emission center is small, and the emission luminance may be reduced. If it is greater than 0.10, concentration quenching may occur due to interference between ions, resulting in a reduction in luminance. More preferably, a satisfies 0.004 ⁇ a ⁇ 0.01, whereby the light emission luminance is improved.
- B is the amount of element A (monovalent metal element) and satisfies 0.002 ⁇ b ⁇ 0.24. More preferably, b satisfies 0.002 ⁇ b ⁇ 0.032. If the b value is within this range, the emission intensity can be improved.
- the element A is Li, Na, K, etc. Among them, Li can particularly increase the emission intensity.
- C is the amount of Al element and satisfies 0.25 ⁇ c ⁇ 0.45. More preferably, c satisfies 0.31 ⁇ c ⁇ 0.41.
- the generation ratio of crystal phases other than AlON crystals, AlON solid solution crystals, or inorganic crystals having the same crystal structure as AlON increases, and the light emission intensity may decrease.
- D is the amount of oxygen, and satisfies 0.42 ⁇ d ⁇ 0.58. More preferably, d satisfies 0.5 ⁇ d ⁇ 0.57. If the d value is out of this range, the generation rate of crystal phases other than AlON crystals, AlON solid solution crystals, or inorganic crystals having the same crystal structure as AlON increases, and the light emission intensity may decrease.
- E is the amount of nitrogen and satisfies 0.02 ⁇ e ⁇ 0.13. More preferably, e satisfies 0.02 ⁇ e ⁇ 0.075. If the e value is out of this range, the generation ratio of crystal phases other than AlON crystals, AlON solid solution crystals, or inorganic crystals having the same crystal structure as AlON increases, and the light emission intensity may decrease.
- F is the amount of an element (D element) other than Mn, A element, Al, O, N, and satisfies 0 ⁇ f ⁇ 0.1.
- the f value is an amount contained in or dissolved in an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON, and in a mixture as another crystal phase or an amorphous phase. The amount contained in is not included. Furthermore, as long as the crystal structure of the AlON crystal, the AlON solid solution crystal, or the inorganic crystal having the same crystal structure as that of AlON is not destroyed, fluorine, chlorine or the like can be contained as the non-metallic ion as the D element.
- the phosphor of the present invention satisfying the above composition can emit high-intensity fluorescence having a peak at a wavelength in the range of 515 nm to 530 nm when irradiated with an excitation source.
- the phosphor of the present invention satisfying the above composition can emit particularly high-intensity fluorescence having a peak in a wavelength range of 510 nm or more and 530 nm or less when irradiated with an excitation source.
- a divalent metal can be contained as the D element, and among them, those containing Mg as the D element have high emission intensity.
- the D element is Mg and the parameter value f 1 (atomic fraction) indicating the Mg content satisfies 0.001 ⁇ f 1 ⁇ 0.09, the emission intensity is high.
- fluorine, chlorine, and the like can be included as non-metal ions.
- the D element is F and the parameter value f 2 (atomic fraction) indicating the F content satisfies 0.0001 ⁇ f 2 ⁇ 0.05, the emission intensity is high.
- the above-described f value is the sum of the parameter values of each element.
- the f value is the sum of the f 1 value and the f 2 value.
- the phosphor of the present invention emits green fluorescence having a peak in a wavelength range of 490 nm to 550 nm when irradiated with an excitation source.
- the excitation source is efficiently excited by ultraviolet rays, electron beams, X-rays, and the like.
- excitation efficiency is high at a wavelength of 410 nm or more and 460 nm or less, preferably 420 nm or more and 460 nm or less, preferably 430 nm or more and 460 nm or less, more preferably 440 nm or more and 450 nm or less, and further preferably 440 nm or more and 449 nm or less, and 510 nm or more and 530 nm or less. Since it emits green fluorescence having a peak at a wavelength in the above range, it is suitable for use in white or colored LED lighting in which a light emitting diode (LED) emitting light in this range and the phosphor of the present invention are combined.
- LED light emitting diode
- fluorescence having a peak at a wavelength in the range of 510 nm to 530 nm is emitted.
- the fluorescence spectrum is a sharp spectrum with a narrow line width, and emits green with good color purity. Therefore, the fluorescence spectrum is suitable for a green phosphor used for a backlight LED for liquid crystal image display elements.
- the phosphor of the present invention emits light efficiently with an electron beam, and is therefore suitable for a green phosphor for use in an image display element such as a CRT or FED excited by an electron beam.
- the inorganic compound as the main component is an AlON crystal containing at least Mn and an A element, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON in terms of fluorescence.
- it may be composed of a single phase if possible, but may be a mixture with other crystalline phase or amorphous phase as long as the characteristics are not deteriorated.
- the content of the AlON crystal containing at least Mn and the A element, the AlON solid solution crystal or the inorganic crystal having the same crystal structure as AlON is 10% by mass or more, more preferably 50% by mass or more. Desirable to get.
- the range of the inorganic compound as the main component in the phosphor of the present invention is such that the content of the AlON crystal containing at least Mn and the A element, the AlON solid solution crystal or the inorganic crystal having the same crystal structure as AlON is at least 10 mass. % Or more.
- X-ray diffraction measurement is performed, and the ratio of the content is obtained by performing a Rietveld analysis on the crystalline phase of the AlON crystal, the AlON solid solution crystal, or the inorganic crystal having the same crystal structure as the AlON and other crystalline phases.
- Can do In a simple manner, it can be obtained from the intensity ratio of the strongest peak of each phase of the crystal phase of an inorganic crystal having the same crystal structure as AlON crystal, AlON solid solution crystal or AlON and the other crystal phase. .
- the other crystal phase or amorphous phase may be an inorganic substance having conductivity.
- the conductive inorganic material may be an oxide, oxynitride, nitride, or a mixture thereof containing one or more elements selected from Zn, Ga, In, and Sn.
- indium oxide and indium-tin oxide (ITO) are preferable because they have little decrease in fluorescence intensity and high conductivity.
- the phosphor of the present invention develops a green color, but if it is necessary to mix with other colors such as yellow and red, it may be mixed with an inorganic phosphor that develops these colors as necessary.
- Other inorganic phosphors include inorganic phosphors having a base crystal of fluoride, oxide, oxyfluoride, sulfide, oxysulfide, oxynitride, nitride crystal, etc. When durability is required, an oxynitride or nitride crystal is preferably used as a base crystal.
- Phosphors having an oxynitride or nitride crystal as a base crystal include ⁇ -sialon: Eu yellow phosphor, ⁇ -sialon: Ce blue phosphor, CaAlSiN 3 : Eu, and (Ca, Sr) AlSiN 3 : Eu red phosphor (Ca part of CaAlSiN 3 crystal substituted with Sr), blue phosphor hosting JEM phase ((LaAl (Si 6-z Al z ) N 10-z O z ): Ce ), La 3 Si 8 N 11 O 4 : Ce blue phosphor, AlN: Eu blue phosphor, and the like.
- a red phosphor having a peak in a wavelength range of 620 nm to 670 nm can be added.
- a Mn 4+ activated phosphor can be used.
- the Mn 4+ activated phosphor is preferably K 2 SiF 6 : Mn (KSF), KSNAF (K 2 Si 1 ⁇ 1 ) in which a part of constituent elements of KSF (preferably 10 mol% or less) is substituted with Al and Na.
- x Na x Al x F 6 : Mn K 2 TiF 6 : Mn (KTF), and the like.
- the phosphor of the present invention differs in excitation spectrum and fluorescence spectrum depending on the composition, and phosphors having various emission spectra can be designed by appropriately selecting and combining them. What is necessary is just to set the fluorescent substance which has the emission spectrum required based on a use.
- the method for producing the phosphor of the present invention is not particularly limited, but the following method can be given as an example.
- a raw material containing Mn, a raw material containing aluminum, and a raw material containing A element are prepared.
- the raw material containing Mn is selected from the group consisting of Mn metal, oxide, carbonate, nitride, fluoride, chloride, oxynitride, and combinations thereof.
- the raw material containing aluminum is selected from the group consisting of metallic aluminum, aluminum oxide, aluminum nitride, and an organic precursor containing aluminum, preferably aluminum nitride (AlN) and aluminum oxide (Al 2 O 3 ).
- the amount of aluminum nitride and aluminum oxide may be designed from the ratio of oxygen and nitrogen having a target AlON composition.
- the raw material containing A element is A nitride, carbonate, fluoride or the like.
- the raw material containing the A element is selected from the group consisting of lithium nitride, lithium carbonate, and lithium fluoride.
- a raw material containing a D element (however, the D element is an element other than Mn, A element, Al, O, and N) may be added.
- the raw material containing element D is selected from the group consisting of metals, oxides, carbonates, nitrides, fluorides, chlorides, oxynitrides, and combinations thereof of element D.
- the element D is, for example, a divalent metal element.
- a metal, oxide, carbonate, nitride, fluoride, chloride, oxynitride or a combination thereof containing a solid solution element may be further added as necessary.
- the phosphor of the present invention containing an inorganic compound containing at least Mn and A elements in an AlON crystal, an AlON solid solution crystal, or an inorganic crystal having the same crystal structure as AlON is produced. be able to.
- Optimized firing temperature may vary depending on the composition and can be optimized as appropriate. In general, it is preferable to fire in a temperature range of 1700 ° C. or higher and 2100 ° C. or lower. In this way, a high-luminance phosphor can be obtained. When the firing temperature is lower than 1700 ° C., the production rate of AlON crystals, AlON solid solution crystals, or inorganic crystals having the same crystal structure as AlON may be low. Further, if the firing temperature exceeds 2100 ° C., a special apparatus is required, which is not industrially preferable.
- an inorganic compound that generates a liquid phase at a temperature lower than the firing temperature can be added to the raw material mixture as necessary.
- the inorganic compound those that generate a stable liquid phase at the reaction temperature are preferable, and fluorides, chlorides, iodides, bromides, or phosphates of Li, Na, K, Mg, Ca, Sr, Ba, and Al are used. Is suitable.
- these inorganic compounds may be added alone or in combination of two or more.
- magnesium fluoride, aluminum fluoride, and lithium fluoride are preferable because they improve the reactivity of synthesis.
- the addition amount of the inorganic compound is not particularly limited, but a range of 0.1 to 10 parts by weight with respect to 100 parts by weight of the raw material mixture is preferable because the reactivity is improved. If the amount is less than 0.1 parts by weight, the reactivity is not improved, and if it exceeds 10 parts by weight, the luminance of the phosphor may be lowered.
- these inorganic compounds are added to the raw material mixture and baked, the reactivity is improved, grain growth is promoted in a relatively short time, a single crystal having a large grain size grows, and the brightness of the phosphor is improved. .
- the nitrogen atmosphere is preferably a gas atmosphere having a pressure range of 0.2 to 100 atm. Heating to a temperature of 2400 ° C. or higher in a nitrogen gas atmosphere lower than 0.2 atm is not preferable because the raw material is likely to be thermally decomposed. If it exceeds 100 atmospheres, a special device is required, which is not suitable for industrial production.
- the mixed raw material mixture has a form in which fine powder having a particle size of several ⁇ m is aggregated to a size of several hundred ⁇ m to several mm (hereinafter referred to as “powder agglomeration”). Called “collection”).
- the powder aggregate is fired in a state where the bulk density is maintained at a filling rate of 40% or less. More preferably, the bulk density is 20% or less.
- the relative bulk density is a ratio of a value (bulk density) obtained by dividing the mass of the powder filled in the container by the volume of the container and the true density of the substance of the powder.
- a hot press method in which heating is performed while applying pressure or a production method in which baking is performed after mold forming (compacting) is used, but the firing at this time is performed with a high powder filling rate.
- the powder aggregates of the raw material mixture having the same particle size are left as they are.
- a container is filled with a bulk density of 40% or less. If necessary, the particle size can be controlled by granulating the powder aggregate to an average particle size of 500 ⁇ m or less using a sieve or air classification.
- the container may be granulated directly into a shape having an average particle diameter of 500 ⁇ m or less using a spray dryer or the like. Further, when the container is made of boron nitride, there is an advantage that there is little reaction with the phosphor.
- the reason why firing is performed while maintaining the bulk density at 40% or less is because firing is performed in a state where there is a free space around the raw material powder.
- the optimum bulk density varies depending on the shape and surface state of the granular particles, but is preferably 20% or less. In this way, the reaction product grows in a free space, so that the contact between the crystals is reduced and a crystal with few surface defects can be synthesized. Thereby, a fluorescent substance with high brightness is obtained. If the bulk density exceeds 40%, partial densification occurs during firing, resulting in a dense sintered body, which may hinder crystal growth and reduce the brightness of the phosphor. Moreover, it is difficult to obtain a fine powder.
- a powder aggregate having an average particle size of 500 ⁇ m or less is particularly preferable because of excellent crushability after firing.
- the furnace used for firing may be a metal resistance heating method or a graphite resistance heating method because the firing temperature is high and the firing atmosphere is nitrogen.
- An electric furnace using carbon as the material for the high temperature part of the furnace is preferred.
- the firing is preferably performed by a firing method in which no mechanical pressure is applied from the outside, such as an atmospheric pressure sintering method or a gas pressure sintering method, in order to perform the firing while maintaining a bulk density in a predetermined range.
- the powder aggregate obtained by firing is agglomerated tightly, it is pulverized by a pulverizer generally used in industry such as a ball mill and a jet mill.
- a pulverizer generally used in industry such as a ball mill and a jet mill.
- ball milling makes it easy to control the particle size.
- the balls and pots used at this time are preferably made of a silicon nitride sintered body or a sialon sintered body. Grinding is performed until the average particle size becomes 20 ⁇ m or less.
- the average particle size is particularly preferably 5 ⁇ m or more and 20 ⁇ m or less.
- the average particle diameter exceeds 20 ⁇ m, the fluidity of the powder and the dispersibility in the resin are deteriorated, and the light emission intensity becomes uneven depending on the part when the light emitting device is formed in combination with the light emitting element. If it is 5 ⁇ m or less, the luminous efficiency of the phosphor may be lowered. If the desired particle size cannot be obtained only by grinding, classification can be combined. As a classification method, sieving, air classification, precipitation in a liquid, or the like can be used.
- the content of inorganic compounds other than phosphors such as glass phase, second phase, or impurity phase contained in the reaction product obtained by firing is reduced.
- a solvent water and an aqueous solution of an acid can be used.
- the acid aqueous solution sulfuric acid, hydrochloric acid, nitric acid, hydrofluoric acid, a mixture of organic acid and hydrofluoric acid, or the like can be used. Of these, a mixture of sulfuric acid and hydrofluoric acid is highly effective. This treatment is particularly effective for a reaction product obtained by adding an inorganic compound that generates a liquid phase at a temperature lower than the firing temperature and firing at a high temperature.
- the powder after baking or the powder after particle size adjustment by pulverization or classification may be heat-treated at a temperature of 1000 ° C. or higher and lower than the baking temperature. At a temperature lower than 1000 ° C., the effect of removing surface defects is small. Above the firing temperature, the pulverized powders are fixed again, which is not preferable.
- the atmosphere suitable for the heat treatment varies depending on the composition of the phosphor, but one or two or more mixed atmospheres selected from the group consisting of nitrogen, air, ammonia and hydrogen can be used, and the nitrogen atmosphere is particularly defective. It is preferable because of its excellent removal effect.
- the phosphor of the present invention obtained as described above is characterized by having high-luminance visible light emission as compared with a normal oxide phosphor or an existing AlON phosphor.
- a specific composition is characterized by emitting green light, and is suitable for lighting equipment and image display devices.
- it since it does not deteriorate even when exposed to high temperatures, it has excellent heat resistance, and excellent long-term stability in an oxidizing atmosphere and moisture environment.
- the lighting fixture of the present invention includes at least a light emitting source that emits light having a wavelength of 410 nm or more and 460 nm or less, and a phosphor or a light transmitting body in which the phosphor is dispersed.
- the phosphor of the present invention described above is contained in the phosphor.
- Examples of lighting fixtures include LED lighting fixtures and LD (laser diode) lighting fixtures.
- An LED lighting apparatus is manufactured by using the phosphor of the present invention by a known method as described in JP-A-5-152609, JP-A-7-99345, JP-A-2927279, and the like. Can do. In this case, it is desirable that the light emission source emits light having a wavelength of 410 nm or more and 460 nm or less, and among them, an LED light emitting element or an LD light emitting element that emits light having a peak in a wavelength range of 430 nm or more and 460 nm or less is preferable.
- the phosphor of the present invention can emit light with high brightness.
- these light emitting elements include those made of nitride semiconductors such as GaN and InGaN, and can be light emitting light sources that emit light of a predetermined wavelength by adjusting the composition.
- a lighting fixture emitting a desired color can be configured by using it together with a phosphor having other light emission characteristics.
- a phosphor having other light emission characteristics there is a combination of a 445 nm blue LED or LD light emitting element, a yellow phosphor excited at this wavelength and having an emission peak at a wavelength of 550 nm to 600 nm, and the green phosphor of the present invention.
- ⁇ -sialon: Eu 2+ described in JP-A No. 2002-363554, (Y, Gd) 2 (Al, Ga) 5 O 12 described in JP-A No. 9-218149: Ce can be mentioned.
- Ce blue light emitted from the LED or LD is applied to the phosphor, green and yellow light is emitted, and a white luminaire is obtained by mixing the blue light and the light from the phosphor.
- red phosphors include CaSiAlN 3 : Eu 2+ and Mn 4+ activated phosphors described in WO 2005/052087 pamphlet.
- Mn 4+ activated phosphor is K 2 SiF 6 : Mn (KSF), or K 2 Si obtained by substituting a part of constituent elements of KSF (preferably 10 mol% or less) with Al and Na. 1-x Na x Al x F 6 : Mn (KSNAF).
- the light transmitting body in which the phosphor containing at least the phosphor of the present invention is dispersed is selected from the group consisting of acrylic resin, silicone resin and glass. These materials are excellent in translucency with respect to the light from the light emitting light source described above, and can excite the phosphor of the present invention with high efficiency.
- the ratio of the phosphor in the light transmitting body in which the phosphor containing the phosphor of the present invention is dispersed is preferably in the range of 30% by volume to 90% by volume. Thereby, the phosphor of the present invention can be excited with high efficiency.
- the image display device of the present invention includes at least an excitation source and a phosphor, and the phosphor includes at least the phosphor of the present invention described above.
- the image display device include a fluorescent display tube (VFD), a field emission display (FED or SED), a plasma display panel (PDP), and a cathode ray tube (CRT).
- the phosphor of the present invention has been confirmed to emit light by excitation of vacuum ultraviolet rays of 100 to 190 nm, ultraviolet rays of 190 to 380 nm, electron beams, etc., and in combination of these excitation sources and the phosphor of the present invention, An image display apparatus as described above can be configured.
- the phosphor of the present invention is suitable for VFD, SED, PDP, and CRT applications that are used at an acceleration voltage of 10 V or more and 30 kV or less because it is highly efficient by an electron beam and excellent in excitation excitation efficiency.
- the FED is an image display device that emits light by accelerating electrons emitted from a field emission cathode and colliding with a phosphor applied to the anode, and is required to emit light at a low acceleration voltage of 5 kV or less. By combining these phosphors, the light emission performance of the display device is improved.
- Examples 1 to 10 and Comparative Example 11 As raw material powder, an aluminum nitride powder (F grade made by Tokuyama) with a specific surface area of 3.3 m 2 / g and an oxygen content of 0.79%, and an aluminum oxide powder with a specific surface area of 13.6 m 2 / g and a purity of 99.99% (Taimicron grade manufactured by Daimei Chemical), 99.99% pure lithium carbonate powder (high-purity chemical reagent grade), 99.9% pure manganese carbonate powder (high-purity chemical reagent grade), and purity 99 99% magnesium oxide (high purity chemical reagent grade) was used.
- An inorganic compound in which AlON contains at least Mn and an A element (here, the A element is Li) and, if necessary, a D element (here, the D element is Mg) was synthesized.
- Table 1 shows the design compositions of Examples and Comparative Examples 1-11.
- To obtain an inorganic compound represented by Table 1 shown design formula Mn a A b Al c O d N e D f (a + b + c + d + e + a f 1), it was weighed raw material powders in a mass ratio shown in Table 2.
- the raw material powder weighed was mixed using a mortar and pestle made of a silicon nitride sintered body, and then passed through a sieve having an opening of 125 ⁇ m to obtain a powder aggregate having excellent fluidity.
- this powder aggregate was naturally dropped into a boron nitride crucible having a diameter of 20 mm and a height of 20 mm, the bulk density was 15 to 30% by volume. The bulk density was calculated from the weight of the charged powder aggregate, the internal volume of the crucible, and the true density of the powder.
- the crucible was set in a graphite resistance heating type electric furnace.
- the firing atmosphere is evacuated by a diffusion pump, heated from room temperature to 800 ° C. at a rate of 500 ° C. per hour, nitrogen at a temperature of 800.degree.
- the temperature was raised to 1700 ° C. at 500 ° C. per hour, then the temperature was lowered to 1800 ° C. at 24 ° C. per hour and held at 1800 ° C. for 10 minutes.
- the synthesized sample was pulverized using a mortar and pestle made of silicon nitride.
- FIG. 1 is a diagram showing an XRD pattern of the inorganic compound of Example 1.
- FIG. 1 is a diagram showing an XRD pattern of the inorganic compound of Example 1.
- a ⁇ -type AlON structure crystal and a second phase of aluminum oxide or aluminum nitride were confirmed. From the ratio of the height of the main peak, the production ratio of crystals having a ⁇ -type AlON structure was determined to be 90% or more. In addition, the peak which shows the compound of Li was not detected.
- the XRD patterns of the other examples were the same.
- the samples obtained in the examples were mainly composed of an inorganic compound containing AlON crystals containing Mn and Li, and further Mg. Among them, Mn, Li, and Mg were AlON. It was found that it was dissolved in the crystal.
- the sample obtained in the example is a phosphor that emits green light mainly composed of an inorganic compound containing AlON crystal containing Mn and Li and further containing Mg.
- FIG. 2 is a diagram showing an excitation spectrum and an emission spectrum of the inorganic compound of Example 1.
- FIG. 2 shows an emission spectrum when excited at a wavelength of 445 nm and an excitation spectrum when the emission wavelength is fixed at 513 nm.
- Table 3 it was found that the inorganic compound of Example 1 was most excited at 444 nm and emitted green light having a peak at a wavelength of 513 nm.
- the inorganic compounds of Examples 1 to 10 have an excitation spectrum peak at a wavelength in the range of 420 nm to 449 nm, and an emission spectrum peak at a wavelength in the range of 510 nm to 530 nm in excitation at the peak wavelength of the excitation spectrum.
- the unit is an arbitrary unit. That is, the comparison can be made only within the present embodiment measured under the same conditions.
- the emission characteristics (cathode luminescence, CL) when irradiated with an electron beam were observed with a SEM equipped with a CL detector, and the CL image was evaluated. As a result, it was confirmed that the inorganic compounds of all the examples were excited by an electron beam and emitted green light.
- FIG. 3 shows a schematic structural diagram of the lighting fixture (white LED lighting fixture) of the present invention.
- the white LED of the present invention includes a phosphor mixture 1 including the phosphor of the present invention and other phosphors, and a light emission source 2.
- the phosphor mixture 1 was a mixture of the green phosphor manufactured in Example 1 of the present invention and a red phosphor of CaAlSiN 3 : Eu.
- the light emission source 2 is a light emitting element made of a 445 nm blue LED chip.
- the phosphor mixture 1 was dispersed in the resin layer 6 and covered with the blue LED chip 2, and was placed in the container 7.
- the phosphor mixture 1, the green phosphor and K 2 SiF 6 produced in Example 1 Using the Mn red fluorescent material, to constitute a lighting instrument of FIG. Also in this case, in the lighting fixture of the present invention, the phosphor mixture 1 of the green phosphor and the red phosphor is excited by the light of 445 nm emitted from the blue LED chip 2, and emits green and red light, respectively. These green light, red light, and blue light from the blue LED chip 2 were mixed to function as a luminaire that emits white light.
- FIG. 4 is a schematic structural diagram of the image display device (field emission display panel) of the present invention.
- the image display device of the present invention includes at least an emitter 55 as an excitation source and the green phosphor 56 manufactured in Example 1.
- the green phosphor 56 is applied to the inner surface of the anode 53.
- By applying a voltage between the cathode 52 and the gate 54 electrons 57 are emitted from the emitter 55.
- the electrons 57 are accelerated by the voltage between the anode 53 and the cathode 52, collide with the green phosphor 56, and emit green light.
- the entire image display device of the present invention is protected by glass 51.
- one light emitting cell composed of one emitter and one phosphor is shown, but in reality, in addition to green, a large number of blue and red cells are arranged to display various colors. Composed. Although it does not specify in particular about the fluorescent substance used for a blue or red cell, what emits high brightness
- the phosphor of the present invention emits green light with good color purity, and further, since the luminance of the phosphor does not decrease significantly when exposed to an excitation source, it is suitable for VFD, FED, PDP, CRT, white LED, etc. Can be used. In the future, it is expected to contribute greatly to industrial development by being widely used in backlight LEDs and various display devices excited by electron beams.
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Abstract
Description
前記MnおよびA元素、必要に応じてD元素は、前記AlON結晶、AlON固溶体結晶、または、AlONと同一の結晶構造を有する無機結晶に固溶していてもよい。
前記蛍光体は、組成式MnaAbAlcOdNeDf(ただし、式中a+b+c+d+e+f=1とする)で示され、パラメータa、b、c、d、eおよびfは、
0.0003≦ a ≦0.10
0.002≦ b ≦0.24
0.25≦ c ≦0.45
0.42≦ d ≦0.58
0.02≦ e ≦0.13および
0≦ f ≦0.10
を満たしてもよい。
前記パラメータa、b、c、d、eおよびfは、
0.004≦ a ≦0.10
0.002≦ b ≦0.032
0.31≦ c ≦0.41
0.5≦ d ≦0.57
0.02≦ e ≦0.075および
0≦ f ≦0.02
を満たしてもよい。
前記A元素はLiであってもよい。
前記D元素はMgであってもよい。
前記D元素の一部または全部はMgであり、前記Mgの含有量を示すパラメータ値f1(原子分率)は、0.001≦ f1 ≦0.09を満たしてもよい。
前記D元素の一部または全部はFであり、前記Fの含有量を示すパラメータ値f2(原子分率)は、0.0001≦ f2 ≦0.05を満たしてもよい。
430nm以上460nm以下の波長を有する励起光を照射することにより、510nm以上530nm以下の範囲の波長にピークを有する蛍光を発光してもよい。
本発明による照明器具は、少なくとも、410nm以上460nm以下の波長を有する光を発する発光光源と、蛍光体または蛍光体が分散した光透過体とを備え、前記蛍光体は、上述の蛍光体を含み、これにより上記課題を解決する。
前記発光光源は、430nm以上460nm以下の範囲の波長にピークを有する光を発するLED(発光ダイオード)またはLD(レーザダイオード)であってもよい。
前記発光光源は、440nm以上449nm以下の範囲の波長にピークを有する光を発するLED(発光ダイオード)またはLD(レーザダイオード)であってもよい。
前記蛍光体は、620nm以上670nm以下の範囲の波長にピークを有する赤色蛍光体をさらに含んでもよい。
前記赤色蛍光体は、Mn4+付活蛍光体であってもよい。
前記赤色蛍光体は、KSF、および/または、KSNAFであってもよい。
前記蛍光体が分散した前記光透過体において、前記光透過体中の前記蛍光体の割合は、30体積%以上90体積%以下であってもよい。
前記光透過体は、アクリル樹脂、シリコーン樹脂およびガラスからなる群から選択されてもよい。
本発明による画像表示装置は、少なくとも励起源と蛍光体とを備え、前記蛍光体は、上述の蛍光体を含み、これにより上記課題を解決する。
本発明による蛍光体の製造方法は、少なくとも、Al2O3、AlN、Mnを含有する原料およびA元素を含有する原料(ただし、前記A元素は1価の金属元素である)、必要に応じてD元素を含有する原料(ただし、前記D元素はMn、A元素、Al、O、N以外の元素)を混合し、0.2気圧以上100気圧以下の範囲の窒素雰囲気中で、1500℃以上2400℃以下の範囲の温度で焼成し、これにより上記課題を解決する。
前記A元素は、Liであってもよい。
前記D元素は、2価の金属元素であってもよい。
本発明の蛍光体は、AlON結晶、AlON固溶体結晶、または、AlONと同一の結晶構造を有する無機結晶に、少なくともMnおよびA元素(ただし、A元素は1価の金属元素である)を含有する無機化合物を主成分として含むことができる。
0.0003≦ a ≦0.10
0.002≦ b ≦0.24
0.25≦ c ≦0.45
0.42≦ d ≦0.58
0.02≦ e ≦0.13および
0≦ f ≦0.10
上記組成を満たす本発明の蛍光体は、励起源を照射すると、490nm以上550nm以下の範囲の波長にピークを有する蛍光を発することができる。
0.004≦ a ≦0.10
0.002≦ b ≦0.032
0.31≦ c ≦0.41
0.5≦ d ≦0.57
0.02≦ e ≦0.075および
0≦ f ≦0.02
を満たす。これにより、上記組成を満たす本発明の蛍光体は、励起源を照射すると、510nm以上530nm以下の範囲の波長にピークを有する高輝度な蛍光を発することができる。
0.01≦ a ≦0.095
0.025≦ b ≦0.032
0.31≦ c ≦0.35
0.5≦ d ≦0.53
0.03≦ e ≦0.06および
0≦ f ≦0.02
を満たす。これにより、上記組成を満たす本発明の蛍光体は、励起源を照射すると、515nm以上530nm以下の範囲の波長にピークを有する高輝度な蛍光を発することができる。
0.004≦ a ≦0.006
0.02≦ b ≦0.03
0.35≦ c ≦0.4
0.54≦ d ≦0.57
0.01≦ e ≦0.04および
0≦ f ≦0.02
を満たす。これにより、上記組成を満たす本発明の蛍光体は、励起源を照射すると、510nm以上530nm以下の範囲の波長にピークを有する特に高輝度な蛍光を発することができる。
原料粉末として、比表面積3.3m2/g、酸素含有量0.79%の窒化アルミニウム粉末(トクヤマ製Fグレード)と、比表面積13.6m2/g、純度99.99%の酸化アルミニウム粉末(大明化学製タイミクロングレード)と、純度99.99%の炭酸リチウム粉末(高純度科学製試薬級)と、純度99.9%の炭酸マンガン粉末(高純度化学製試薬級)と、純度99.99%の酸化マグネシウム(高純度化学製試薬級)とを用いた。
図3は、本発明の照明器具(白色LED照明器具)の概略構造図を示す。
図4は、本発明の画像表示装置(フィールドエミッションディスプレイパネル)の概略構造図である。
2 青色LEDチップ
3、4 導電性端子
5 ワイヤーボンド
6 樹脂層
7 容器
51 ガラス
52 陰極
53 陽極
54 ゲート
55 エミッタ
56 本発明の蛍光体
57 電子
Claims (21)
- AlON結晶、AlON固溶体結晶、または、AlONと同一の結晶構造を有する無機結晶に、少なくともMnおよびA元素(ただし、前記A元素は1価の金属元素である)を含有し、必要に応じてD元素(ただし、前記D元素はMn、前記A元素、Al、O、N以外の元素である)を含有する無機化合物を含み、励起源を照射することにより、490nm以上550nm以下の範囲の波長にピークを有する蛍光を発する、蛍光体。
- 前記MnおよびA元素、必要に応じてD元素は、前記AlON結晶、AlON固溶体結晶、または、AlONと同一の結晶構造を有する無機結晶に固溶している、請求項1に記載の蛍光体。
- 前記蛍光体は、組成式MnaAbAlcOdNeDf(ただし、式中a+b+c+d+e+f=1とする)で示され、パラメータa、b、c、d、eおよびfは、
0.0003≦ a ≦0.10
0.002≦ b ≦0.24
0.25≦ c ≦0.45
0.42≦ d ≦0.58
0.02≦ e ≦0.13および
0≦ f ≦0.10
を満たす、請求項1に記載の蛍光体。 - 前記パラメータa、b、c、d、eおよびfは、
0.004≦ a ≦0.10
0.002≦ b ≦0.032
0.31≦ c ≦0.41
0.5≦ d ≦0.57
0.02≦ e ≦0.075および
0≦ f ≦0.02
を満たす、請求項3に記載の蛍光体。 - 前記A元素はLiである、請求項1に記載の蛍光体。
- 前記D元素はMgである、請求項1に記載の蛍光体。
- 前記D元素の一部または全部はMgであり、
前記Mgの含有量を示すパラメータ値f1(原子分率)は、0.001≦ f1 ≦0.09を満たす、請求項3に記載の蛍光体。 - 前記D元素の一部または全部はFであり、
前記Fの含有量を示すパラメータ値f2(原子分率)は、0.0001≦ f2 ≦0.05を満たす、請求項3に記載の蛍光体。 - 430nm以上460nm以下の波長を有する励起光を照射することにより、510nm以上530nm以下の範囲の波長にピークを有する蛍光を発光する、請求項1に記載の蛍光体。
- 少なくとも、410nm以上460nm以下の波長を有する光を発する発光光源と、蛍光体または蛍光体が分散した光透過体とを備える照明器具において、
前記蛍光体は、請求項1に記載の蛍光体を含む、照明器具。 - 前記発光光源は、430nm以上460nm以下の範囲の波長にピークを有する光を発するLED(発光ダイオード)またはLD(レーザダイオード)である、請求項10に記載の照明器具。
- 前記発光光源は、440nm以上449nm以下の範囲の波長にピークを有する光を発するLED(発光ダイオード)またはLD(レーザダイオード)である、請求項11に記載の照明器具。
- 前記蛍光体は、620nm以上670nm以下の範囲の波長にピークを有する赤色蛍光体をさらに含む、請求項10に記載の照明器具。
- 前記赤色蛍光体は、Mn4+付活蛍光体である、請求項13に記載の照明器具。
- 前記赤色蛍光体は、KSF、および/または、KSNAFである、請求項14に記載の照明器具。
- 前記蛍光体が分散した前記光透過体において、前記光透過体中の前記蛍光体の割合は、30体積%以上90体積%以下である、請求項10に記載の照明器具。
- 前記光透過体は、アクリル樹脂、シリコーン樹脂およびガラスからなる群から選択される、請求項10に記載の照明器具。
- 少なくとも励起源と蛍光体とを備える画像表示装置であって、
前記蛍光体は、請求項1に記載の蛍光体を含む、画像表示装置。 - 少なくとも、Al2O3、AlN、Mnを含有する原料およびA元素を含有する原料(ただし、前記A元素は1価の金属元素である)、必要に応じてD元素を含有する原料(ただし、前記D元素はMn、A元素、Al、O、N以外の元素)を混合し、0.2気圧以上100気圧以下の範囲の窒素雰囲気中で、1500℃以上2400℃以下の範囲の温度で焼成する、請求項1に記載の蛍光体の製造方法。
- 前記A元素は、Liである、請求項19に記載の方法。
- 前記D元素は、2価の金属元素である、請求項19に記載の方法。
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US10662374B2 (en) | 2020-05-26 |
US20180127648A1 (en) | 2018-05-10 |
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