WO2016104371A1 - 炭化炉及び熱分解炉、並びに、水性ガス生成システム、水素ガス生成システム、及び、発電システム - Google Patents
炭化炉及び熱分解炉、並びに、水性ガス生成システム、水素ガス生成システム、及び、発電システム Download PDFInfo
- Publication number
- WO2016104371A1 WO2016104371A1 PCT/JP2015/085517 JP2015085517W WO2016104371A1 WO 2016104371 A1 WO2016104371 A1 WO 2016104371A1 JP 2015085517 W JP2015085517 W JP 2015085517W WO 2016104371 A1 WO2016104371 A1 WO 2016104371A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbide
- combustion
- gas
- carbonization furnace
- temperature
- Prior art date
Links
- 239000007789 gas Substances 0.000 title claims abstract description 419
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 298
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000010248 power generation Methods 0.000 title claims abstract description 30
- 238000010000 carbonizing Methods 0.000 title claims abstract description 28
- 239000000567 combustion gas Substances 0.000 claims abstract description 390
- 238000003763 carbonization Methods 0.000 claims abstract description 332
- 238000002485 combustion reaction Methods 0.000 claims abstract description 255
- 239000010815 organic waste Substances 0.000 claims abstract description 223
- 238000000197 pyrolysis Methods 0.000 claims abstract description 194
- 238000006243 chemical reaction Methods 0.000 claims abstract description 186
- 230000002093 peripheral effect Effects 0.000 claims abstract description 163
- 238000010438 heat treatment Methods 0.000 claims abstract description 86
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- 239000001257 hydrogen Substances 0.000 claims abstract description 23
- 230000007246 mechanism Effects 0.000 claims abstract description 21
- 238000001816 cooling Methods 0.000 claims description 56
- 238000001514 detection method Methods 0.000 claims description 52
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 36
- 238000009825 accumulation Methods 0.000 claims description 32
- 230000008021 deposition Effects 0.000 claims description 29
- 150000001247 metal acetylides Chemical class 0.000 claims description 24
- 238000011084 recovery Methods 0.000 claims description 23
- 238000004140 cleaning Methods 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 20
- 238000007599 discharging Methods 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 15
- 230000001737 promoting effect Effects 0.000 claims description 15
- 238000007664 blowing Methods 0.000 claims description 13
- 239000005539 carbonized material Substances 0.000 claims description 13
- 239000002699 waste material Substances 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 239000008236 heating water Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 abstract description 19
- 238000000746 purification Methods 0.000 abstract description 7
- 230000001133 acceleration Effects 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 106
- 229910052757 nitrogen Inorganic materials 0.000 description 46
- 238000012856 packing Methods 0.000 description 33
- 210000004907 gland Anatomy 0.000 description 27
- 230000000694 effects Effects 0.000 description 21
- 229930195733 hydrocarbon Natural products 0.000 description 19
- 150000002430 hydrocarbons Chemical class 0.000 description 19
- 239000003638 chemical reducing agent Substances 0.000 description 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 238000002309 gasification Methods 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 16
- 238000007670 refining Methods 0.000 description 16
- 229910001873 dinitrogen Inorganic materials 0.000 description 14
- 239000000446 fuel Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 14
- 230000005855 radiation Effects 0.000 description 14
- 239000002028 Biomass Substances 0.000 description 13
- 230000008569 process Effects 0.000 description 13
- 239000002994 raw material Substances 0.000 description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- 239000011810 insulating material Substances 0.000 description 10
- 238000010304 firing Methods 0.000 description 9
- 238000012986 modification Methods 0.000 description 9
- 230000004048 modification Effects 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 230000009467 reduction Effects 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 230000007723 transport mechanism Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000003779 heat-resistant material Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000012498 ultrapure water Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 3
- 210000000078 claw Anatomy 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000006148 magnetic separator Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 239000002916 wood waste Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000008214 highly purified water Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000003949 liquefied natural gas Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
- B09B3/45—Steam treatment, e.g. supercritical water gasification or oxidation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/08—Non-mechanical pretreatment of the charge, e.g. desulfurization
- C10B57/10—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B1/00—Retorts
- C10B1/02—Stationary retorts
- C10B1/04—Vertical retorts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/02—Multi-step carbonising or coking processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/34—Grates; Mechanical ash-removing devices
- C10J3/40—Movable grates
- C10J3/42—Rotary grates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/094—Char
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1246—Heating the gasifier by external or indirect heating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1853—Steam reforming, i.e. injection of steam only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1876—Heat exchange between at least two process streams with one stream being combustion gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Definitions
- the present invention relates to a carbonization furnace, a pyrolysis furnace, a water gas generation system, hydrogen, which can efficiently perform biomass fuel and biomass power generation using organic waste which is one of renewable energy sources.
- the present invention relates to a gas generation system and a power generation system. Furthermore, the present invention also provides these control methods.
- organic waste is converted into gas (CO, H 2 , CH 4 , CO 2 , H 2 O), carbide, under low oxygen and high temperature (200 to 600 ° C.).
- Water gas (hydrogen gas, carbon monoxide gas, carbon dioxide gas) is mainly decomposed into hydrocarbons by a thermal decomposition reaction between the carbides and superheated steam (hereinafter referred to as “steam”) that is a gasifying agent.
- steam superheated steam
- a system that generates a mixed gas as a component and uses water gas as a power generation fuel is of interest as an integrated biomass fuel production process and power generation system for carbonization, gasification, and power generation of organic waste.
- attempts have been reported to produce hydrogen from water gas produced by direct gasification of biomass.
- the carbonization furnace for example, a carbonization furnace that partially burns organic waste and carbonizes the organic waste by the heat of combustion is known.
- Fuel gas containing combustible gas is generated.
- the carbonization furnace disclosed in Patent Document 3 forms a carbonized portion for carbonizing a solid content containing a large amount of carbide above a region formed between a substantially cylindrical main body and a cylindrical body accommodated in the main body.
- an incombustible portion for extinguishing the carbide is formed below.
- a combustible gas contained in a combustion gas generated by partial combustion of organic waste can be combusted in a secondary combustion section above the carbonization furnace.
- a pyrolysis gasification furnace that generates a water gas by heating a carbide generated by partially burning organic waste together with a gasifying agent such as water vapor to cause a thermal decomposition reaction. It has been.
- the pyrolysis gasification furnace disclosed in Patent Document 4 has an outer cylinder and an inner cylinder, supplies carbide and a gasifying agent to the inner peripheral side of the inner cylinder, and includes an outer cylinder and an inner cylinder. Combustion gas generated in a carbonization furnace is supplied to the space between them. By supplying a high-temperature combustion gas to the gap, the outer peripheral surface of the inner cylinder is heated by the combustion gas, and the thermal decomposition reaction on the inner peripheral side of the inner cylinder can be promoted.
- Non-Patent Document 2 hydrogen is produced from a raw material gas mainly composed of hydrogen gas and carbon monoxide gas obtained by directly gasifying wood chips and waste plastic with high-temperature steam.
- This technology basically consists of a gasification facility and a hydrogen production facility.
- Gasification equipment consists of gasification furnace, reforming furnace, air preheater, reformed gas cooler, dust filter, gas cooling purification tower, gas purification equipment, pyrolysis evaporator, high temperature steam generation, etc., and hydrogen production
- the equipment consists of a pretreatment device, a carbon monoxide transformer, and the like.
- Conventional carbonization furnaces mainly include: 1) a polymer that is contained in a combustible gas generated by partial combustion of organic waste and becomes a liquid (also called “tar”) that solidifies upon cooling and exhibits high viscosity. Problems of hydrocarbons, 2) Insufficient cooling of carbides generated by partial combustion of organic waste, damage of carbide transport mechanism, ignition problems due to contact between discharged carbide and air, and 3) Organic waste There is a problem of carbonization efficiency of carbides generated by partial combustion of products.
- the problem with the above-mentioned polymer hydrocarbons is that if the combustion gas contains a large amount of polymer hydrocarbons, the polymer hydrocarbons solidify and adhere to the carbonization furnace and equipment installed downstream thereof. It is a problem. Therefore, it is desirable to increase the combustion efficiency of the combustible gas contained in the combustion gas and reduce the polymer hydrocarbon.
- the carbonization furnace disclosed in Patent Document 3 supplies air from the air supply port provided in the main body and the air supply port provided in the cylindrical body toward the carbonization section. For this reason, when the amount of air supplied toward the carbonization section is adjusted, the amount of air supplied to the secondary combustion section varies accordingly. If the amount of air supplied to the secondary combustion unit is not an amount suitable for burning the combustible gas in the secondary combustion unit, the combustible gas contained in the combustion gas cannot be combusted appropriately. In particular, if an excessive amount of air is supplied to the secondary combustion section, the ambient temperature of the secondary combustion section is lowered, and the combustion efficiency of the combustible gas contained in the combustion gas is deteriorated. And the combustion efficiency of combustible gas deteriorates, and if a combustible gas contains many polymer hydrocarbons, a malfunction may occur in a carbonization furnace or equipment installed downstream thereof.
- the problem with the carbonization efficiency is that air necessary for partial combustion of organic waste is generally supplied from an air supply port provided in the carbonization furnace, but the external air lowers the ambient temperature of the carbonization section.
- the carbonization furnace disclosed in Patent Document 3 supplies external air from the air supply port provided in the cylindrical body to the carbonization section.
- the temperature of the external air supplied to the carbonization part may not be fully controlled, and it is difficult to sufficiently eliminate the reduction in carbonization efficiency. there were.
- the conventional pyrolysis furnace mainly includes 1) the combustion gas generated in the carbonization furnace supplied to the gap between the outer cylinder and the inner cylinder and the water gas generated in the pyrolysis furnace to the outside. There are spill problems and 2) water gas yield problems.
- the problem of the outflow of the combustion gas has an outer cylinder (main body part) and an inner cylinder (reaction tube) as disclosed in Patent Document 4, and carbide and gas are present on the inner peripheral side of the inner cylinder.
- the inner cylinder is supplied by supplying high-temperature combustion gas to the gap. This is a problem caused by the difference in thermal expansion between the inner cylinder and the outer cylinder because the outer peripheral surface of the inner cylinder is heated by the combustion gas and promotes the thermal decomposition reaction on the inner circumference side of the inner cylinder.
- the problem of the yield of water gas is the low yield due to the narrow gasification region that causes the conventional thermal decomposition reaction.
- the pyrolysis furnace disclosed in Patent Document 4 is characterized in that a heat storage protrusion is provided on the lower end side inside the inner cylinder.
- This thermal storage protrusion can quickly uniformize the temperature distribution of carbides in the gasification region between the thermal storage protrusions and the inner cylinder due to the radiant heat, and cause a thermal decomposition reaction between the carbides and the gasifying agent. Therefore, the composition ratio of the pyrolysis gas can be made uniform.
- Patent Document 4 the water gas production
- combustion gas generated together with carbides in a carbonization furnace is introduced into a pyrolysis furnace and used as a heat source for a pyrolysis reaction, and steam is used as a gasifying agent for carbides.
- Patent Document 4 does not specifically disclose a heat source that generates water vapor as a gasifying agent from water.
- a dedicated heat source is used as the heat source for generating water vapor, the thermal efficiency of the entire system including the carbonization furnace, the pyrolysis gasification furnace, and the heat source is not sufficiently high and there is room for improvement.
- Patent Document 2 discloses a combination of the carbonization furnace and the pyrolysis furnace using a combustion exhaust gas supplied from a carbonization furnace or a pyrolysis furnace as a heat source of water vapor serving as a gasification agent in response to the problem of thermal efficiency.
- a biomass power generation system using water gas generated in this manner is disclosed.
- it since there are problems with the carbonization furnace and the pyrolysis furnace, it is difficult to efficiently generate high-purity water gas, and it is difficult to efficiently generate power.
- Non-Patent Document 2 achieves a hydrogen recovery rate of 99.9% of about 60%.
- organic waste is gasified by a thermal decomposition reaction with high-temperature steam, hydrogen gas is generated.
- carbon monoxide gas a large amount of low-molecular hydrocarbons (methane, ethane, etc.) and high-molecular hydrocarbons (tar) are contained, which increases the burden on facilities required for separation and reforming.
- the present invention has been made in view of such circumstances, and in summary, the following carbonization furnace, pyrolysis furnace, water gas generation system, hydrogen gas generation system, and power generation system are provided. It is for the purpose.
- the present invention related to a carbonization furnace increases the combustion efficiency of a combustible gas contained in a combustion gas generated by partial combustion of organic waste, and suppresses problems caused to the apparatus installed on the apparatus and its downstream side.
- An object of the present invention is to provide a carbonization furnace capable of improving the carbonization efficiency of waste and a control method thereof.
- the present invention related to the pyrolysis furnace is that the upper surface of the main body and the outer peripheral surface of the reaction tube are thermally expanded when the reaction tube in which the pyrolysis reaction is performed is heated by the heating gas flowing between the main body and the main body.
- the temperature lowers due to the endothermic reaction due to thermal decomposition while expanding the thermal decomposition furnace where the heating gas can be prevented from flowing out of the gap between and the carbide and the gasifying agent.
- An object of the present invention is to provide a pyrolysis furnace capable of suppressing the generation of a region.
- the present invention relating to a water gas generation system can improve the thermal efficiency and accelerate the thermal decomposition reaction in the thermal decomposition furnace without using a dedicated heat source for generating water vapor used as a carbide gasifying agent.
- a carbonization furnace with high combustion efficiency that discharges carbides whose burned carbide temperature has been appropriately reduced, and a pyrolysis furnace in which the outflow of the heating gas is suppressed and the pyrolysis reaction proceeds It is an object of the present invention to provide a high yield water gas generation system and a combustion gas supply method used.
- an object of the present invention is to provide an efficient hydrogen gas generation system and a power generation system using the water gas produced from the water gas generation system.
- the present invention employs the following various means in order to solve the various problems described above.
- a carbonization furnace, a pyrolysis furnace, a water gas system, a hydrogen gas generation system, and a power generation system will be sequentially described.
- the carbonization furnace of the present invention will be described.
- the carbonization furnace according to one embodiment of the present invention capable of increasing the combustion efficiency of the combustible gas contained in the combustion gas and reducing the polymer hydrocarbon is formed in a cylindrical shape extending along the axis.
- a cylindrical portion having an outer peripheral surface that is formed in a cylindrical shape extending along the axis and that forms a gap for carbonizing organic waste between the inner peripheral surface of the main body portion, and An input portion for introducing the organic waste into the gap, a carbide discharge portion for discharging the carbide obtained by carbonizing the organic waste from the gap, and primary combustion air for partially combusting the organic waste deposited in the gap And a second air supply unit for supplying secondary combustion air for burning a combustible gas contained in a combustion gas generated by the combustion of the organic waste into the main body. And a combustion gas for discharging the combustion gas.
- a carbonization furnace comprising: a discharge unit; a temperature detection unit that detects a temperature of the combustion gas discharged from the combustion gas discharge unit; and a control unit that controls the first air supply unit and the second air supply unit.
- the control unit controls the supply amount of the secondary combustion air supplied by the second air supply unit so that the temperature of the combustion gas detected by the temperature detection unit is equal to or higher than the first combustion gas temperature. Is preferred.
- the control unit reduces the supply amount of the secondary combustion air to reduce the combustion gas.
- the temperature of the combustion gas detected by the temperature detector exceeds the second combustion gas temperature, the supply amount of the secondary combustion air is increased. More preferably, the temperature of the combustion gas is lowered below the second combustion gas temperature. More preferably, the first combustion gas temperature is 900 ° C. to 1000 ° C., and the second combustion gas temperature is 1200 ° C. to 1300 ° C.
- the method for controlling a carbonization furnace capable of reducing the polymer hydrocarbon includes a main body formed in a cylindrical shape extending along an axis, and a cylindrical shape extending along the axis.
- a cylindrical portion having an outer peripheral surface which is formed and forms a gap for carbonizing organic waste between the inner peripheral surface of the main body portion, an input portion for introducing the organic waste into the gap, and
- a carbide discharge unit that discharges carbonized carbon from the organic waste immediately before, a first air supply unit that supplies primary combustion air that partially burns the organic waste deposited in the gap, and the organic waste
- a second air supply unit for supplying secondary combustion air for burning a combustible gas contained in the combustion gas generated by the combustion of the main body to the inside of the main body, and a combustion gas discharge unit for discharging the combustion gas to the outside Of a carbonization furnace comprising
- the temperature detection step of detecting the temperature of the combustion gas discharged from the combustion gas discharge section, and the temperature of the combustion gas detected by the temperature detection step is equal
- organic waste is carbonized between a main body portion formed in a cylindrical shape extending along an axis and a cylindrical portion extending along the axis, and an inner peripheral surface of the main body portion.
- a cylindrical portion having an outer peripheral surface that forms a gap for causing the gap, an input portion that inputs the organic waste into the gap, a carbide discharge portion that discharges the carbide carbonized by the organic waste from the gap, and the gap
- An air supply unit for supplying combustion air for partially combusting the organic waste deposited on the surface, a temperature detection unit for detecting the temperature of the carbide deposited on the lower end side of the gap, and the temperature detection unit detecting the temperature
- a control unit for product discharge section controls the discharge amount of the carbide to be discharged, a carbonization furnace having a.
- the carbide discharge section is provided at a position facing the lower end of the gap and the lower end of the gap, and guides the carbide from the lower end of the gap to the outlet by rotating around the axis. It is preferable that it is a carbonization furnace which has a rotary body and the drive part which rotates the said rotary body around the said axis line.
- the control unit preferably controls a rotation speed at which the driving unit rotates the rotating body according to the temperature detected by the temperature detection unit, and the temperature detected by the temperature detection unit is predetermined.
- the drive unit When the temperature is lower than the temperature, the drive unit is controlled to rotate the rotating body at a first rotation speed, and when the temperature detected by the temperature detection unit is equal to or higher than the predetermined temperature, the first rotation speed is lower than the first rotation speed. More preferably, the drive unit is controlled to rotate the rotating body at two rotation speeds.
- the method for controlling a carbonization furnace which detects the temperature of the carbide and controls the temperature of the carbide, includes a main body formed in a cylindrical shape extending along the axis, and a cylinder extending along the axis. And a cylindrical portion having an outer peripheral surface that forms a gap for carbonizing organic waste between the inner peripheral surface of the main body portion and an input portion that inputs the organic waste into the gap.
- a carbonization furnace comprising: a carbide discharge unit that discharges the carbide obtained by carbonizing the organic waste from the gap; and an air supply unit that supplies combustion air for partially burning the organic waste deposited in the gap.
- the carbonization furnace according to the present invention carbonizes organic waste between a body portion formed in a cylindrical shape extending along an axis and a cylindrical portion extending along the axis, and between the inner peripheral surface of the body portion.
- a control unit that the carbide discharge unit controls the discharge amount of the carbide is discharged Te is a carbonization furnace having a.
- the carbide discharge section is provided at a position facing the lower end of the gap and the lower end of the gap, and guides the carbide from the lower end of the gap to the outlet by rotating around the axis. It is preferable that it is a carbonization furnace which has a rotary body and the drive part which rotates the said rotary body around the said axis line.
- the said control part controls the rotational speed by which the said drive part rotates the said rotary body according to the said accumulation amount which the said accumulation amount detection part detects,
- the said accumulation amount detection part detects the said When the accumulation amount is equal to or greater than the predetermined accumulation amount, the drive unit is controlled to rotate the rotating body at the first rotation speed, and the accumulation amount detected by the accumulation amount detection unit is equal to or less than the predetermined accumulation amount More preferably, the drive unit is controlled to rotate the rotating body at a second rotational speed lower than the first rotational speed.
- the method for controlling a carbonization furnace which detects the amount of organic waste deposited and controls the temperature of carbide, includes a main body formed in a cylindrical shape extending along an axis, and the axis And a cylindrical portion having an outer peripheral surface that forms a gap for carbonizing organic waste with the inner peripheral surface of the main body portion, and the organic waste leaf into the gap.
- a carbonization furnace control method comprising: a deposition amount detection step for detecting a deposition amount of the organic waste deposited in the gap; and the carbide discharge unit according to the deposition amount detected by the deposition amount detection step. Discharge of the carbides discharged to the outside And a control step of controlling.
- a carbonization furnace that solves the problem of carbonization efficiency of carbides generated by partial combustion of organic waste includes a main body portion formed in a cylindrical shape extending along an axis, and the axis And a cylindrical portion having an outer peripheral surface forming a gap for carbonizing organic waste between the inner peripheral surface of the main body portion and the organic waste into the gap.
- a charging unit that discharges carbides carbonized by the organic waste from the gap, and combustion air that partially burns the organic waste toward the organic waste that accumulates in the gap.
- An air supply unit wherein the air supply unit blows air introduced from outside, a heating unit that heats air blown by the blower unit, and air heated by the heating unit Is supplied to the gap A gas supply port, a carbonization furnace having a. Furthermore, it has a cover part which forms the closed space which is arrange
- the heating unit includes a heat transfer member that transfers heat to the atmosphere of the gap via the outer peripheral surface of the main body, and the heat transfer member is located below the air supply port. It is provided for the purpose of heating the air supplied to the closed space by the blower. Therefore, the air blowing part blows air introduced from the outside toward the outer peripheral surface of the main body part located on the outer peripheral side below the gap, and at the position where the air supply port is disposed. It is preferable that the distance from the inner peripheral surface of the main body to the outer peripheral surface at a position where the heat transfer member is disposed is shorter than the distance from the inner peripheral surface of the main body to the outer peripheral surface. .
- the heat transfer member is an annular radiating fin that contacts the outer peripheral surface of the main body and extends around the axis along the outer peripheral surface, and is provided at a plurality of locations along the axis. More preferably, it is a heat radiating fin that forms a spiral flow path that contacts the outer peripheral surface of the main body portion and turns from the lower side to the upper side around the axis along the outer peripheral surface. Is more preferable.
- the pyrolysis furnace according to the present invention is heated between a main body (outer cylinder) formed in a cylindrical shape extending along an axis and an inner peripheral surface of the main body formed in a cylindrical shape extending along the axis.
- a reaction tube (inner cylinder) having an outer peripheral surface that forms a heating gas flow path for circulating a working gas, with an upper end and a lower end projecting from an upper surface and a bottom surface of the main body, respectively;
- a supply unit for supplying carbide and a gasifying agent to the inside of the reaction tube in order to generate water gas inside, and a pyrolysis reaction of the carbide in the reaction tube and attached to the lower end of the reaction tube
- a water gas outlet part for guiding the water gas generated by the outside to the outside, and the body part
- a first surface that is provided in contact with the upper surface below the surface and has an inner peripheral surface that contacts the outer peripheral surface of the reaction tube, and blocks outflow of the heating gas from the upper surface of the main body.
- a seal portion and an inner peripheral surface provided in contact with the bottom surface above the bottom surface of the main body portion and in contact with the outer peripheral surface of the reaction tube, and the heating from the bottom surface of the main body portion And a second seal portion for blocking outflow of the working gas.
- a pyrolysis furnace characterized in that the following solution is provided at a location where water gas may flow out. That is, the pyrolysis furnace according to one aspect of the present invention is the above pyrolysis furnace, and further, at the attachment position of the lower end portion of the reaction tube and the water gas outlet portion, the outer peripheral surface of the reaction tube and the aqueous solution.
- the pyrolysis furnace includes a third seal portion that has an inner peripheral surface that comes into contact with each of the outer peripheral surfaces of the gas outlet portion and blocks outflow of the water gas from the mounting position.
- the said upper surface of the said main-body part is comprised by the upper board, and the 1st flange part is provided in the upper end of the side surface of the said main-body part, and the said upper board and said 1st
- the flange portion may be fastened by a fastening member in a state where a fourth seal portion is sandwiched between the upper plate and the first flange portion at a plurality of points around the axis.
- the bottom surface of the main body portion is constituted by a bottom plate, a second flange portion is provided at the lower end of the side surface of the main body portion, and the bottom plate and the second flange portion. May be fastened by a fastening member in a state where a fifth seal portion is sandwiched between the bottom plate and the second flange portion at a plurality of locations around the axis.
- a third flange portion is provided at the upper end portion of the reaction tube of the pyrolysis furnace of the present invention, and a fourth flange portion is provided at a lower end portion of the supply portion, and the third flange portion and the fourth flange portion are provided.
- the flange portion may be fastened by a fastening member in a state where a sixth seal portion is sandwiched between the third flange portion and the fourth flange portion at a plurality of cylinders around the axis.
- a pyrolysis furnace capable of solving the problem of the yield of water gas includes a main body formed in a cylindrical shape extending along the axis, and along the axis.
- a reaction tube that is formed in an extending cylindrical shape and has an outer peripheral surface that forms a heating gas passage for circulating a heating gas between the inner peripheral surface of the main body portion and an upper end portion of the reaction tube;
- a supply portion for supplying a carbide and a gasifying agent to the inside of the reaction tube in order to generate a water gas inside the reaction tube; and a lower end portion of the reaction tube and an inside of the reaction tube.
- a water gas outlet that guides the water gas generated in the outside to the outside, a heating gas supply unit that is provided above the main body and supplies the heating gas to the heating gas flow path, and the main body And the heating gas flow path
- a heating gas discharge section for discharging the heating gas; and the carbide contained in the reaction tube and supplied from the upper end section in a stepwise manner from the upper end side to the lower end side of the cylindrical member.
- a thermal decomposition promoting mechanism for promoting a thermal decomposition reaction of the carbide and the gasifying agent.
- the thermal decomposition promotion mechanism includes a plurality of first inclined surfaces that form a first inclined surface that is inclined so as to guide the carbide from one end portion of the inner peripheral surface of the reaction tube to a first opening provided at the other end portion. And a second inclined surface inclined so as to guide the carbide falling downward from the first opening to the second opening provided in the one end by the first inclined plate.
- the plurality of second inclined plates and the plurality of first inclined plates and the plurality of second inclined plates so that the first inclined plates and the second inclined plates are alternately arranged along the axis.
- the holding portion is composed of a rod-shaped member extending along the axis, and the plurality of first inclined plates and the plurality of second inclined plates are arranged on the axis of the rod-shaped member. It is preferable to be held by the rod-shaped member at a plurality of locations along.
- the thermal decomposition promoting mechanism is more preferably detachable from the tubular member.
- a water gas generation system capable of efficiently generating high-purity water gas includes a carbonization furnace that partially burns organic waste to generate carbide and combustion gas.
- a pyrolysis furnace for generating a water gas by heating the carbide generated by the carbonization furnace together with steam with the combustion gas, a steam generator for heating the water with the combustion gas to generate the steam, and the steam A steam superheater for heating the steam generated by the generator with the combustion gas and supplying the heated steam to the pyrolysis furnace; and drying the organic waste with the combustion gas and drying the organic A drying machine that supplies waste to the carbonization furnace; and the combustion gas generated by the carbonization furnace is supplied to the pyrolysis furnace, and the combustion gas discharged from the pyrolysis furnace is supplied to the steam A combustion gas flow path for supplying to the heater, supplying the combustion gas discharged from the steam superheater to the steam generator, and supplying the combustion gas discharged from the steam generator to the dryer;
- a water gas generation system comprising: More preferably, the water
- the combustion efficiency is high and the temperature of the burned carbide is appropriately reduced by taking measures that can solve various problems inherent in conventional carbonization furnaces and pyrolysis furnaces.
- a carbonization furnace with high carbonization efficiency that discharges the generated carbide and a pyrolysis furnace in which the outflow of the heating gas is suppressed and the pyrolysis reaction proceeds, water water with higher purity can be more efficiently Can be generated.
- a hydrogen gas generation system includes a carbonization furnace that partially burns organic waste to generate a carbide and a combustion gas, and the carbide generated by the carbonization furnace is heated by steam and the combustion gas. And a steam generator for heating the water with the combustion gas to generate the steam, and the steam generated by the steam generator is overheated with the combustion gas and heated.
- a steam superheater for supplying the steam to the pyrolysis furnace, a drying machine for drying the organic waste by the combustion gas and supplying the dried organic waste to the carbonization furnace, and the carbonization furnace The generated combustion gas is supplied to the pyrolysis furnace, the combustion gas discharged from the pyrolysis furnace is supplied to the steam superheater, and the combustion gas discharged from the steam superheater Generated in the pyrolysis furnace, a combustion gas flow path for supplying the combustion gas to the steam generator and supplying the combustion gas discharged from the steam generator to the dryer, a cyclone for removing residues contained in the water gas, and And a hydrogen purifier for purifying hydrogen from the generated water gas. Furthermore, it is more preferable to provide a water gas cooling device and a water gas holder for storing water gas.
- a power generation system includes a carbonization furnace that partially burns organic waste to generate carbide and combustion gas, and the carbide generated by the carbonization furnace is heated by the combustion gas together with steam to be aqueous.
- a pyrolysis furnace for generating gas; a steam generator for heating the water by the combustion gas to generate the steam; and the steam generated by the steam generator is heated by the combustion gas and heated.
- the combustion gas is supplied to the pyrolysis furnace, the combustion gas exhausted from the pyrolysis furnace is supplied to the steam superheater, and the combustion gas exhausted from the steam superheater is steamed.
- a combustion gas flow path for supplying the combustion gas discharged to the generator and supplying the combustion gas discharged from the steam generator to the dryer, a cyclone for removing residues contained in the water gas, and the pyrolysis furnace And a generator capable of operating with water gas as fuel.
- the said generator is a gas engine which operate
- carbonization that can increase the combustion efficiency of the combustible gas contained in the combustion gas generated by the partial combustion of organic waste and suppress problems caused to the device and the equipment installed downstream thereof.
- a furnace and a method for controlling the carbonization furnace can be provided.
- the reaction tube in which the pyrolysis reaction is carried out internally by the heating gas flowing between the main body and the main body is thermally expanded, the heating gas is generated from the gap between the upper surface of the main body and the outer peripheral surface of the reaction tube. It is possible to provide a pyrolysis furnace capable of suppressing the outflow to the outside.
- a pyrolysis furnace capable of suppressing the occurrence of a region where the temperature decreases due to an endothermic reaction due to thermal decomposition while expanding the region where the carbide and the gasifying agent undergo thermal decomposition reaction.
- a water gas generation system capable of improving thermal efficiency and promoting a thermal decomposition reaction in a thermal decomposition furnace without using a dedicated heat source for generating water vapor used as a gasifying agent for carbide, and its combustion gas supply A method can be provided. Furthermore, by using at least one carbonization furnace or pyrolysis furnace of the carbonization furnace that provides the first, second, and third effects and the pyrolysis furnace that provides the fourth and fifth effects, the purity is further improved. It is possible to produce a high-efficiency water gas with high efficiency.
- the water gas generation system of the present invention efficiently generates high-purity water gas that does not discharge harmful substances, it can be reused without being depleted by using a general hydrogen purifier. It is possible to construct a hydrogen gas generation system that enables hydrogen gas expected as renewable clean energy from biomass to be produced with high purity and high efficiency without destroying the environment.
- the power generation system of the present invention can efficiently provide electric energy by using water gas generated from biomass as a fuel using a general power generator, like the hydrogen gas generation system of the present invention. it can.
- FIG. 1 is an overall configuration diagram illustrating an embodiment of a water gas generation system, a hydrogen gas generation system, and a power generation system. It is a longitudinal cross-sectional view of the carbonization furnace shown in FIG. It is a principal part enlarged view of the carbonization furnace shown in FIG. It is a figure which shows the clinker crusher shown in FIG. 3, (a) is a top view, (b) is CC arrow end surface of (a). FIG. 3 is an end view of the carbonization furnace shown in FIG. 2, (a) is an end view taken along arrow AA, and (b) is an end view taken along arrow BB. It is a longitudinal cross-sectional view which shows the 1st modification of the primary air supply part of a carbonization furnace.
- FIG. 11 is a cross-sectional view of the reaction tube of the pyrolysis furnace shown in FIG. 10, (a) is a cross-sectional view taken along the line DD, and (b) is a cross-sectional view taken along the line EE.
- FIG. 1 It is a principal part enlarged view of the thermal decomposition furnace shown in FIG. It is a block diagram which shows the thermal decomposition furnace, temperature reducer, cyclone, steam generator, and steam superheater which are shown in FIG. It is a block diagram which shows the dryer shown in FIG.
- the water gas generation system 100 of the present embodiment carbonizes organic waste, which is carbon-containing waste, to generate carbide, and then uses superheated steam (hereinafter also referred to as “steam”) as a gasifying agent.
- steam superheated steam
- This is a system that generates a water gas (a mixed gas containing hydrogen gas, carbon monoxide gas, carbon dioxide gas as a main component) by causing a thermal decomposition reaction of carbides.
- Organic waste is, for example, food waste, construction waste, shredder dust, livestock waste, wood waste such as thinned wood and pruned branches, sludge, and general waste discharged from households.
- Various organic wastes as exemplified above can be used as a raw material for generating water gas, but it is particularly preferable to use wood waste (also referred to as “woody biomass”).
- the water gas generation system 100 includes a dryer 10 that dries organic waste, a hopper 11 that stores organic waste to be input to the dryer 10, and a dryer 10.
- a temperature reducer 40 that cools the water gas generated in the pyrolysis furnace 30, a char recovery device 41 that recovers unburned carbide discharged from the carbonization furnace 20, and a temperature reducer 40.
- recovers the residue removed with the cyclone 50 are provided.
- the water gas generation system 100 includes a water gas cooling device 60 that cools the water gas from which the residue has been removed by the cyclone 50, a water gas holder 70 that stores the water gas cooled by the water gas cooling device 60, and a surplus gas.
- a flare stack 71 for incinerating water gas or the like, a power generation facility 72 using water gas as fuel, a hydrogen purifier 73 for purifying hydrogen gas from water gas, a steam generator 80 for generating saturated steam from water, steam A steam superheater 81 that superheats steam generated by the generator 80, a water supply device 82 that supplies water to the steam generator 80, and a control device 90 that controls the entire water gas generation system 100 are provided.
- the dryer 10 is an apparatus that dries organic waste with combustion gas and supplies the dried organic waste to the carbonization furnace 20.
- the dryer 10 is supplied with organic waste from a hopper 11 that stores the organic waste through a raw material supply path 11a.
- emitted from the steam generator 80 is supplied to the dryer 10 through the combustion gas flow path 200d as a heat source which dries organic waste.
- the organic waste supplied from the hopper 11 to the dryer 10 is, for example, a wood chip having a length of 5 mm or more and 60 mm or less. Moreover, what contains a water
- the dryer 10 reduces the moisture contained in the organic waste to a weight ratio of about 15% by heating and drying the wood chips containing the water at a weight ratio of about 55%.
- the dryer 10 supplies the organic waste dried by the heat of the combustion gas to the hopper 12 through the raw material supply path 10a. Further, the dryer 10 supplies the combustion gas used as a heat source for drying the organic waste to the exhaust gas cooling and cleaning device 13 through the combustion gas channel 200e.
- the temperature of the combustion gas supplied from the dryer 10 to the exhaust gas cooling and cleaning device 13 is adjusted to be 150 ° C. or higher and 210 ° C. or lower.
- the exhaust gas cooling and cleaning device 13 is a device that removes harmful substances such as sulfur oxide (SO X ), sulfuric acid (H 2 SO 4 ), hydrochloric acid (HCl), and the like contained in the combustion gas and renders the combustion gas harmless.
- the exhaust gas cooling and cleaning device 13 cools the combustion gas (exhaust gas) from which harmful substances have been removed while detoxifying it, and then discharges it into the atmosphere.
- the exhaust gas cooling and cleaning device 13 is a scrubber, for example, and is adjusted so that the temperature of the combustion gas discharged into the atmosphere is 120 ° C. or higher and 180 ° C. or lower.
- the carbonization furnace 20 is an apparatus that generates carbide and combustion gas by partially burning dry organic waste.
- the carbonized furnace 20 is supplied with the dried organic waste from the hopper 12 that stores the organic waste through the raw material supply path 12a.
- the carbonization furnace 20 supplies the carbide generated by the combustion of the organic waste to the pyrolysis furnace 30 via the carbide supply path 101.
- the carbonization furnace 20 supplies the combustion gas produced
- the pyrolysis furnace 30 is an apparatus that generates a water gas by heating a carbide generated by the carbonization furnace 20 with a combustion gas together with superheated steam to cause a thermal decomposition reaction.
- the pyrolysis furnace 30 is supplied with the carbide generated by the carbonization furnace 20 through the carbide supply path 101.
- the pyrolysis furnace 30 is supplied with superheated steam generated by the steam superheater 81 as a gasifying agent.
- the pyrolysis furnace 30 is supplied with combustion gas from the combustion gas channel 200a as a heat source for promoting the pyrolysis reaction.
- the pyrolysis furnace 30 causes a pyrolysis reaction of the carbide and superheated steam to generate a water gas mainly composed of hydrogen gas, carbon monoxide gas, and carbon dioxide gas.
- the thermal decomposition reaction between carbide and superheated steam is a reaction mainly represented by the following formulas (1) and (2).
- the water gas reaction shown in Formula (1) is an endothermic reaction
- the water gas shift reaction shown in Formula (2) is an exothermic reaction.
- the endothermic amount of the endothermic reaction shown in formula (1) is larger than the exothermic amount of the exothermic reaction shown in formula (2). Therefore, the thermal decomposition reaction between the carbide and the superheated steam is an endothermic reaction as a whole.
- the temperature of the carbide supplied to the pyrolysis furnace 30 is adjusted to be normal temperature (for example, 25 ° C.) or higher and 350 ° C. or lower. Moreover, the temperature of the superheated steam supplied to the pyrolysis furnace 30 is adjusted to be 730 ° C. or more and 830 ° C. or less. The temperature of the combustion gas supplied to the pyrolysis furnace 30 is adjusted to be 900 ° C. or higher and 1300 ° C. or lower. Moreover, the temperature of the water gas which the pyrolysis furnace 30 produces
- the pyrolysis furnace 30 supplies the water gas and carbide unreacted components and residues generated by the pyrolysis reaction to the temperature reducer 40 via the water gas supply path 102. Further, the pyrolysis furnace 30 supplies the combustion gas used as a heat source for the pyrolysis reaction to the steam superheater 81 through the combustion gas channel 200b. The temperature of the combustion gas supplied to the steam superheater 81 is adjusted to be 820 ° C. or more and 920 ° C. or less.
- the temperature reducer 40 is a device that lowers the temperature of the water gas supplied from the water gas supply path 102 by spraying liquid water. Water is supplied to the temperature reducer 40 from a water supply device 82 by a water supply pump (not shown). The temperature reducer 40 supplies the temperature-reduced water gas to the cyclone 50 through the water gas supply path 103. Further, the temperature reducer 40 supplies unreacted carbide residues and residues supplied from the water gas supply path 102 to the char recovery device 41. The temperature reducer 40 adjusts the spray amount of water so that the water gas adjusted in the pyrolysis furnace 30 is 650 ° C. or more and 850 ° C. or less, and the water gas is 220 ° C. or more and 280 ° C. or less.
- the char recovery device 41 is a device that recovers an unreacted portion of the carbide and supplies it to the pyrolysis furnace 30 again. By providing the char recovery device 41, it is possible to avoid that the unreacted portion of the carbide is not used for the generation of the water gas and is discarded. Therefore, by providing the char recovery device 41, the yield of water gas from the carbide is improved.
- the cyclone 50 is a device that removes residues contained in the water gas supplied via the water gas supply path 103.
- the cyclone 50 turns the water gas supplied through the water gas supply path 103 inside to centrifuge the residue contained in the water gas, guide it downward, and supply it to the residue collecting device 51. Further, the cyclone 50 guides the water gas from which the residue has been removed upward and supplies the water gas to the water gas cooling device 60 through the water gas supply path 104.
- the water gas cooling device 60 is a device that lowers the temperature of the water gas supplied from the water gas supply path 104 by spraying liquid water.
- the water gas cooling device 60 circulates the cooling water so that the cooling water sprayed in the water gas is collected and sprayed into the water gas again by a circulation pump (not shown).
- the water gas cooling device 60 supplies the cooled water gas to the water gas holder 70.
- the water gas cooling device 60 is provided with a temperature sensor (not shown) for detecting the temperature of the water gas supplied to the water gas holder 70 and is circulated by a circulation pump (not shown) so that the detected temperature matches the target temperature. Control the amount of cooling water.
- the water gas cooling device 60 adjusts the spray amount of water so that the water gas adjusted by the temperature reducer 40 is 220 ° C. or more and 280 ° C. or less, and the water gas is 30 ° C. or more and 50 ° C. or less.
- the water gas holder 70 is a device that stores the water gas supplied from the water gas cooling device 60.
- the water gas holder 70 can supply the stored water gas individually to the flare stack 71, the power generation facility 72, and the hydrogen purifier 73.
- the flare stack 71 is an apparatus for incineration when excess water gas is generated, such as when the amount of water gas holder 70 stored becomes excessive.
- the flare stack 71 is always combusted by a fuel such as liquefied natural gas. Therefore, when water gas is supplied to the flare stack 71, the water gas is incinerated.
- the power generation facility 72 is a facility that obtains a power generation output by driving a generator by operating water gas as a fuel.
- a power source for driving the generator by the power generation facility 72 for example, a gas engine that operates by burning water gas is used, but the power source is not limited thereto.
- the hydrogen purification device 73 is a device that purifies the hydrogen gas with high purity (for example, hydrogen gas with a purity of 99.995% or more) by removing components such as carbon monoxide gas and carbon dioxide gas contained in the water gas. is there.
- the hydrogen purifier 73 pressurizes water gas to a predetermined pressure with a compressor (not shown) and fills with an adsorbent (suitable for removing components such as carbon monoxide gas and carbon dioxide gas). It is supplied to an adsorption tower (not shown), and components such as carbon monoxide gas and carbon dioxide gas are adsorbed and removed by an adsorbent, and purified to high purity hydrogen gas.
- the adsorption tower of the hydrogen purifier 73 is depressurized to desorb components such as carbon monoxide gas and carbon dioxide gas from the adsorbent.
- components such as carbon monoxide gas and carbon dioxide gas from the adsorbent.
- hydrogen can be continuously purified and delivered.
- a hydrogen purification module using a palladium alloy film that does not transmit any substance other than hydrogen can be used as the hydrogen purification device 73.
- the steam generator 80 is an apparatus that generates saturated steam by vaporizing water by heating with combustion gas. Water is supplied to the steam generator 80 from the water supply device 82 via a water supply pump (not shown). Further, the combustion gas discharged from the steam superheater 81 is supplied to the steam generator 80 via the combustion gas flow path 200c. The temperature of the combustion gas supplied to the steam generator 80 is adjusted to be 750 ° C. or higher and 850 ° C. or lower.
- the saturated steam generated by the steam generator 80 is supplied to the steam superheater 81.
- the combustion gas used as a heat source for vaporizing water in the steam generator 80 is supplied to the dryer 10 through the combustion gas flow path 200d.
- the temperature of the combustion gas supplied to the dryer 10 is adjusted to be 540 ° C. or higher and 640 ° C. or lower.
- the steam superheater 81 is a device that generates heated steam from saturated steam by heating the saturated steam with combustion gas.
- the steam superheater 81 is supplied with saturated steam generated by the steam generator 80. Further, the combustion gas discharged from the pyrolysis furnace 30 is supplied to the steam superheater 81 through the combustion gas flow path 200b.
- the temperature of the combustion gas supplied to the steam superheater 81 is adjusted to be 820 ° C. or more and 920 ° C. or less.
- the superheated steam generated by the steam superheater 81 is supplied to the pyrolysis furnace 30 as a gasifying agent.
- the combustion gas used as a heat source for generating superheated steam in the steam superheater 81 is supplied to the steam generator 80 via the combustion gas flow path 200c.
- the control device 90 is a device that controls the water gas generation system 100.
- the control device 90 can communicate with a control unit (not shown) provided in each unit constituting the water gas generation system 100.
- the control device 90 can control each unit by transmitting a control command to a control unit included in each unit constituting the water gas generation system 100.
- the control device 90 can receive a signal indicating the state of each part such as temperature and pressure from each part constituting the water gas generation system 100.
- the control device 90 can cause each unit constituting the water gas generation system 100 to perform a desired operation by reading and executing a control program stored in a storage unit (not shown).
- the combustion gas generated in the carbonization furnace 20 flows as follows through the combustion gas flow path including the combustion gas flow paths 200a, 200b, 200c, 200d, and 200e.
- the combustion gas generated by the carbonization furnace 20 is supplied to the pyrolysis furnace 30 through the combustion gas flow path 200a.
- the combustion gas discharged from the pyrolysis furnace 30 is supplied to the steam superheater 81 through the combustion gas channel 200b.
- the combustion gas discharged from the steam superheater 81 is supplied to the steam generator 80 through the combustion gas flow path 200c.
- the combustion gas discharged from the steam generator 80 is supplied to the dryer 10 through the combustion gas channel 200d.
- the combustion gas discharged from the dry operation machine 10 is supplied to the exhaust gas cooling and cleaning device 13 through the combustion gas channel 200e.
- the combustion gas detoxified by the exhaust gas cooling and cleaning device 13 is discharged into the atmosphere by the exhaust gas cooling and cleaning device 13.
- the combustion gas generated by the carbonization furnace 20 is supplied to the pyrolysis furnace 30 without performing heat exchange with other heat medium.
- the reason is that the combustion gas maintained at a high temperature is used for the pyrolysis furnace. This is because the thermal decomposition reaction at 30 is promoted to improve the yield of water gas from the carbide.
- the inside of the pyrolysis furnace 30 can be maintained at a high temperature. The reaction is accelerated and the yield of water gas from the carbide is improved.
- FIG. 2 is a longitudinal sectional view of the carbonization furnace 20 shown in FIG.
- the axis X indicates the vertical direction (gravity direction) orthogonal to the installation surface (not shown) on which the carbonization furnace 20 is installed.
- the carbonization furnace 20 of the present embodiment includes a main body part 21, a cylindrical part 22 (cylinder part), an organic waste input part 23 (input part), a carbide discharge part 24, and a primary part.
- a level sensor 28d deposition amount detection unit
- an ignition burner 20c and a carbonization furnace control unit 29 (control unit).
- the main body 21 is a member that is formed in a substantially cylindrical shape extending along the axis X and is an exterior of the carbonization furnace 20.
- the main body 21 forms a primary combustion region R2 in which organic waste is partially combusted and a secondary combustion region R4 in which combustible gas contained in the combustion gas generated from the organic waste is combusted. Yes.
- the main body 21 is attached to a metal (for example, iron) housing 21a that forms the exterior of the carbonization furnace 20, a heat insulating material 21b that is attached to the inner peripheral surface of the housing 21a, and an inner peripheral surface of the heat insulating material 21b.
- Refractory material 21c Refractory material 21c.
- the cylindrical portion 22 is a member formed in a substantially cylindrical shape extending along the axis X.
- the cylindrical portion 22 has an outer peripheral surface 22 a that forms a gap 20 a for combusting organic waste to generate carbides with the inner peripheral surface 21 d of the main body portion 21. Since the cylindrical part 22 becomes high temperature by combustion of organic waste, it is preferable to form the cylindrical part 22 from a heat-resistant material (for example, a metal material such as stainless steel).
- a heat-resistant material for example, a metal material such as stainless steel.
- the inside of the cylindrical portion 22 is a hollow closed space, and this closed space is not in communication with other spaces. Therefore, the cylindrical portion 22 can heat a certain amount of heat, and is not easily affected by external temperature changes.
- the cylindrical portion 22 is attached to a turntable 24a, which will be described later, and rotates around the axis X in response to the turntable 24a rotating around the axis X. As the cylindrical portion 22 rotates about the axis X, the gap 20a and the organic waste existing above the gap 20a are guided along the gap 20a from above to below.
- the organic waste supplied to the gap 20a is partially combusted by the primary combustion air supplied from the primary air supply unit 25 in the primary combustion region R2, and burns containing solids containing a large amount of carbides and combustible gas. Gas is generated.
- the solid content containing a large amount of carbide is guided to the lower carbide refining / cooling region R1 along the immediate side 20a, and the combustion gas containing combustible gas is guided to the secondary combustion region R4.
- the carbide refining / cooling region R ⁇ b> 1 is a region where the upper side is closed with organic waste and the primary combustion air from the primary air supply unit 25 is not supplied. Therefore, the carbide is refined while being cooled in the carbide refinement / cooling region R1.
- the organic waste input unit 23 is an opening that is provided in the main body 21 and inputs organic waste (not shown) supplied from the hopper 12 through the raw material supply path 12 a into the main body 21.
- An inclined surface 23a is formed below the organic waste throwing portion 23.
- the inclined surface 23a is inclined downward from above as it approaches the axis X.
- the organic waste supplied from the organic waste input part 23 is guided to the upper surface 22b and the gap 20a of the cylindrical part 22 along the inclined surface 23a.
- the region where the organic waste charging unit 23 is disposed is a raw material charging region R3.
- an inspection window 20b is provided on the side opposite to the organic waste charging unit 23 with respect to the axis X.
- the inspection window 20b makes the inside of the carbonization furnace 20 visible.
- the carbide discharge unit 24 is a mechanism for discharging carbide generated by partial combustion of organic waste in the gap 20 a to the carbide supply path 101.
- the carbide discharged from the carbide discharge unit 24 to the carbide supply path 101 is supplied to the pyrolysis furnace 30.
- carbonized_material discharge part 24 has the turntable 24a (rotary body), the drive part 24b, and the carbide
- the turntable 24a is a member provided at a position facing the lower end in the axis X direction of the gap 20a as shown in FIG. 3, and is an annular rotator extending in the circumferential direction around the axis X.
- the turntable 24a rotates around the axis X by the driving force transmitted from the driving unit 24b.
- the surface of the turntable 24 a that faces the lower end of the gap 20 a is an inclined surface that is inclined downward as the distance from the axis X increases. Therefore, a gap is formed between the lower end of the gap 20a and the inclined surface of the turntable 24a.
- Carbide (not shown) existing at the lower end of the gap 20a moves downward along the inclined surface of the turntable 24a as the turntable 24a rotates about the axis X, and is guided to the carbide discharge port 24c. . Therefore, as the rotational speed of the turntable 24a increases, the amount of carbide guided from the lower end of the gap 20a to the carbide discharge port 24c increases. At the same time, as the rotational speed of the turntable 24a decreases, the amount of carbide guided from the lower end of the gap 20a to the carbide discharge port 24c decreases.
- the driving unit 24b is a device that transmits driving force to the turntable 24a and rotates the turntable 24a around the axis X. As shown in FIG. 2, the drive unit 24b includes a drive motor 24e, a speed reducer 24f, a drive belt 24g, and a drive shaft 24h.
- the drive motor 24e is an inverter motor whose rotation speed is controlled by a control signal transmitted from the carbonization furnace control unit 29.
- the rotational power of the drive motor 24e is transmitted to the speed reducer 24f by the drive belt 24g.
- the speed reducer 24f is a device that increases the torque while reducing the rotational speed of the rotational power transmitted from the drive motor 24e by the drive belt 24g.
- the speed reducer 24f transmits the rotational power with increased torque to the drive shaft 24h extending around the axis X.
- the turntable 24a is connected to the drive shaft 24h. Therefore, the turntable 24a rotates about the axis X as the drive shaft 24h rotates about the axis X.
- the carbide discharge rod 24 c is an opening for discharging carbide to the carbide supply path 101.
- the carbide discharged from the carbide discharge port 24 c to the carbide supply path 101 is supplied to the pyrolysis furnace 30 through the carbide supply path 101.
- the clinker crusher 24d is a member for crushing a clinker that is a lump larger than a gap formed between the lower end of the gap 20a and the inclined surface of the turntable 24a.
- the clinker is obtained by melting the combustion ash generated by the combustion of the organic waste in the primary combustion region R2 into a lump.
- the clinker crusher 24d is a substantially annular member disposed around the axis X, and claws 24i projecting radially inward are provided at a plurality of positions in the circumferential direction. ing.
- FIG. 4B end view taken along the line CC in FIG. 4A
- the claw 24i is bent upward along the inclined surface of the turntable 24a.
- the clinker crusher 24d is attached to the main body 21 by fastening bolts.
- the clinker crusher 24d remains fixed to the main body 21 even when the turntable 24a rotates about the axis X. Therefore, when the clinker moves as the turntable 24a rotates, the clinker collides with the claws 24i of the clinker crusher and is crushed.
- the primary air supply unit 25 is a device that supplies primary combustion air that partially burns organic waste toward the organic waste accumulated in the gap 20a.
- the primary air supply unit 25 includes a primary combustion fan 25a (air blowing unit), a cover unit 25b, and an air supply port 25c.
- the primary combustion fan 25a is a device that blows air (atmosphere) introduced from the outside, and includes an inverter motor (not shown) and a fan (not shown) driven by the inverter motor.
- the primary combustion fan 25a can adjust the air volume to blow by controlling the rotation speed of the inverter motor.
- the cover portion 25b is a member that forms a closed space 25d through which air blown from the primary combustion fan 25a is introduced and air is supplied to the air supply port 25c.
- the cover portion 25b is a closed space extending around the axis X between the outer peripheral surface 21e of the main body portion 21. 25d is formed.
- the air supply port 25c is a flow path for supplying air blown from the primary combustion fan 25a to the closed space 25d to the primary combustion region R2 inside the main body 21 from the closed space 25d. As shown in FIG. 2, the air supply ports 25 c are provided at a plurality of locations in the vertical direction along the axis X in the primary combustion region R ⁇ b> 2 where the organic waste is partially combusted by the primary combustion air.
- the air supply ports 25c are provided in the main body portion 21 at equal intervals along the circumferential direction around the axis X (30 ° intervals in FIG. 5A).
- the air supply port 25 c is a linear flow path extending from the outer peripheral surface 21 e of the main body 21 toward the axis X.
- the air supply ports 25c are arranged at intervals of 30 ° along the circumferential direction around the axis X.
- other intervals for example, 20 °, 45 °, etc.
- they may be arranged at arbitrary intervals instead of at equal intervals.
- the primary air supply unit 25 shown in FIG. 2 has a heating unit (not shown) for heating the air blown from the primary combustion fan 25a.
- the air supply port 25c supplies the air heated by the heating unit to the air supply port 25c. Therefore, compared with the case where the air blown from the primary combustion fan 25a is not heated, the atmospheric temperature of the primary combustion region R2 can be maintained at a high temperature.
- the radiation fins 25e shown in FIGS. 6 and 7 may be employed.
- the modification of the primary air supply part 25 shown in FIG.6 and FIG.7 uses the air blown from the primary combustion fan 25a using the heat
- FIG. The heat dissipating fins 25e are provided.
- the radiation fin 25e is an annular member that contacts the outer peripheral surface 21e of the main body 21 and extends around the axis X along the outer peripheral surface 21e.
- the radiation fins 25e are provided at a plurality of locations along the axis X.
- the radiation fin 25e is attached to the outer peripheral surface 21e of the main body 21 by welding or the like.
- FIG. 6 is a longitudinal sectional view showing a first modification of the primary air supply unit 25.
- the cover part 25b of the primary air supply unit 25 shown in FIG. 2 is provided only at substantially the same position in the axis X direction as the air supply rod 25c.
- the cover portion 25b of the primary air supply unit 25 shown in FIG. 6 is provided so as to include a position below the air supply port 25c in addition to substantially the same position in the axis X direction as the air supply port 25c. It is done.
- the heat transfer member 6 is a heat transfer member to which the ambient temperature of the gap 20a is transferred through the outer peripheral surface 21e of the main body 21.
- the outer peripheral surface 21e of the main body 21 is heated to about 50 ° C. to 70 ° C., although the housing 21a is protected by the refractory material 21c and the heat insulating material 21b so as not to be overheated. Therefore, the air (atmosphere) blown from the primary combustion fan 25a can be heated by the radiation fin 25e.
- the primary combustion fan 25a blows air introduced from the outside toward the outer peripheral surface 21e of the main body portion 21 located on the outer peripheral side below the gap 20a. This is because the outer peripheral surface 21e of the main body 21 located on the outer peripheral side below the gap 20a is cooled by air introduced from the outside.
- the carbide refining / cooling region R1 is a region in which the carbide generated in the primary combustion region R2 is refined while being cooled, and therefore it is desirable to maintain the temperature at a certain low level. Therefore, in the present embodiment, the position where the primary combustion fan 25a blows air is set so that the carbide refining / cooling region R1 is cooled.
- FIG. 7 is a cross-sectional view showing a second modification of the primary air supply unit 25.
- the second modified example of the primary air supply unit 25 shown in FIG. 7 is different in that the thickness of the heat insulating material 21b and the position of the outer peripheral surface 21e of the main body 21 are different at the positions where the heat radiating fins 25e are arranged. It is the same as that of the 1st modification shown in FIG.
- the distance from the inner peripheral surface 21d of the main body 21 to the outer peripheral surface 21e at the position where the air supply port 25c is arranged is a distance D1.
- the distance from the inner peripheral surface 21d of the main body 21 to the outer peripheral surface 21e at the position where the radiation fin 25e is disposed is the distance D2.
- the distance D2 is shorter than the distance D1.
- the second modified example of the primary air supply unit 25 shown in FIG. 7 compared to the first modified example of the primary air supply unit 25 shown in FIG.
- the atmospheric temperature is easily transmitted to the outer peripheral surface 21e. Therefore, according to the second modification, the radiating fins 25e are heated to a higher temperature than in the first modification. Therefore, according to the primary air supply unit 25 of the second modification, the air blown by the primary combustion fan 25a can be supplied to the air supply port 25c while being heated to a higher temperature.
- the heat radiating fins 25e shown in FIGS. 6 and 7 are annular members extending around the axis X, but may be in other forms.
- the heat dissipating fin 25e may have a structure that forms a spiral flow path that contacts the outer peripheral surface 21e of the main body 21 and swivels around the axis X along the outer peripheral surface 21e from below to above. .
- the secondary air supply unit 26 is a device that supplies secondary combustion air for burning the combustible gas contained in the combustion gas generated by the combustion of the organic waste in the primary combustion region R2 to the inside of the main body 21. is there. As shown in FIG. 2, the secondary air supply unit 26 is provided in the secondary combustion region R4, and supplies secondary combustion air toward the secondary combustion region R4.
- the secondary air supply unit 26 includes a secondary combustion fan 26a, a cover unit 26b, and an air supply port 26c.
- the secondary combustion fan 26a is a device that blows air (atmosphere) introduced from the outside, and includes an inverter motor (not shown) and a fan (not shown) driven by the inverter motor.
- the secondary combustion fan 26a can adjust the air volume to blow by controlling the rotation speed of the inverter motor.
- the cover portion 26b is a member that forms a closed space 26d that introduces air blown from the secondary combustion fan 26a and supplies air to the air supply port 26c.
- the cover portion 26b is a closed space extending around the axis X between the outer peripheral surface 2le of the main body portion 21. 26d is formed.
- the air supply port 26c is a flow path for supplying air blown from the secondary combustion fan 26a to the closed space 26d to the secondary combustion firing region R4 inside the main body 21 from the closed space 26d. As shown in FIG. 2, the air supply ports 26 c are provided at a plurality of locations in the vertical direction along the axis X in the secondary combustion region R ⁇ b> 4 where the combustible gas contained in the combustion gas is combusted by the secondary combustion air. ing.
- the air supply ports 26c are provided in the main body 21 at equal intervals along the circumferential direction around the axis X (30 ° intervals in FIG. 5B). Further, as shown in FIG. 5B, the air supply port 26 c is a linear flow path extending from the outer peripheral surface 21 e of the main body portion 21 toward the axis X. In the example shown in FIG. 5B, the air supply ports 26c are arranged at intervals of 30 ° along the circumferential direction around the axis X. However, as other intervals (for example, 20 °, 45 °, etc.) Alternatively, they may be arranged at arbitrary intervals instead of at equal intervals.
- the combustion gas discharge unit 27 is an exhaust port that discharges the combustion gas generated in the primary combustion region R2 and combusted with the combustible gas component in the secondary combustion region R4 to the combustion gas channel 200a.
- the combustion gas discharged to the combustion gas flow path 200a is supplied to the pyrolysis furnace 30 for use as a heat source for the pyrolysis reaction.
- the temperature sensor 28 a is a sensor that detects the temperature of the combustion gas discharged from the combustion gas discharge unit 27.
- the temperature sensor 28 a transmits a temperature detection signal indicating the detected temperature to the carbonization furnace control unit 29.
- the temperature sensor 28a is arranged in a region close to the combustion gas channel 200a in the secondary combustion firing region R4. Therefore, the combustion gas temperature Tg detected by the temperature sensor 28a is substantially the same as the temperature of the combustion gas discharged to the combustion gas flow path 200a.
- the temperature sensor 28b is a sensor that detects the ambient temperature of the primary combustion firing region R2.
- the temperature sensor 28 b transmits a temperature detection signal indicating the detected temperature to the carbonization furnace control unit 29.
- the temperature sensor 28c is a sensor that detects a carbide temperature Tc that is a temperature of carbide deposited on the lower end side of the gap 20a.
- the temperature sensor 28 c transmits a temperature detection signal indicating the detected carbide temperature Tc to the carbonization furnace control unit 29.
- the level sensor 28d is a sensor that detects the amount of organic waste deposited in the gap 20a. In the primary combustion region R2, the level sensor 28d detects the amount of organic waste accumulated in the direction of the axis Y shown in FIG. 1 by obtaining an output signal corresponding to the amount of accumulation.
- the level sensor 28d may be a reflective sensor that detects the amount of deposition by receiving reflection of emitted light, ultrasonic waves, or the like. Further, the level sensor 28d may be a transmission type sensor in which a receiving part for receiving emitted X-rays or the like is provided in the cylindrical part 22.
- the level sensor 28d detects that the amount of organic waste deposited in the gap 20a has decreased, such as when the introduction of new organic waste from the organic waste supply unit 23 is stopped. It is a sensor for. For this reason, the level sensor 28d detects the amount of deposition along the axis Y directed downward from the mounting position in the vertical direction.
- the carbonization furnace control unit 29 outputs a detection signal indicating that the deposition amount Ao, which is the deposition amount of organic waste detected by the level sensor 28d, is 0, the deposition amount of the organic waste present in the gap 20a is predetermined. It is determined that the first deposition amount Ao1 has decreased.
- the ignition burner 20c is a device used to ignite organic waste when starting combustion of organic waste in the carbonization furnace 20. As shown in FIG. 2, the ignition burner 20c is provided on the lower end side of the gap 20a. In addition, as shown in FIG. 2, the ignition burners 20 c are arranged at two locations facing the axis X.
- the ignition burner 20c burns organic waste accumulated on the lower end side of the gap 20a by generating a flame using ignition fuel such as kerosene.
- the ignition burner 20c generates a flame when starting combustion of organic waste in the carbonization furnace 20 in accordance with a control command from the carbonization furnace control unit 29. Further, the ignition burner 20c stops the generation of flame at a predetermined timing in accordance with a control command from the carbonization furnace control unit 29.
- the carbonization furnace control unit 29 is a device that controls each part by receiving a detection signal indicating the state of each part from each part of the carbonization furnace 20 and transmitting the control signal to each part based on the detection signal.
- the carbonization furnace control unit 29 is a device that transmits a signal indicating the state of the carbonization furnace 20 to the control device 90 and controls the carbonization furnace 20 in response to a control signal transmitted from the control device 90.
- the carbonization furnace control unit 29 receives a temperature detection signal indicating the temperature detected by each of the temperature sensors 28a, 28b, and 28c, and a deposition amount detection signal indicating the deposition amount Ao of the organic waste detected by the level sensor 28d. . Further, the carbonization furnace control unit 29 transmits a control signal for controlling the blown amount of the primary combustion fan 25 a to the primary air supply unit 25. Further, the carbonization furnace control unit 29 transmits a control signal for controlling the blown amount of the secondary combustion fan 26 a to the secondary air supply unit 26. The carbonization furnace control unit 29 transmits a control signal to the ignition burner 20c to generate a flame when starting the combustion of organic waste, and transmits a control signal at a predetermined timing to stop the generation of the flame. Let Moreover, the carbonization furnace control unit 29 transmits a control signal for controlling the rotation speed of the turntable 24a to the drive motor 24e.
- the carbonization furnace control unit 29 controls the amount of air blown by the primary combustion firing fan 25a based on the atmospheric temperature of the primary combustion region R2 detected by the temperature sensor 28b.
- the amount of air blown by the primary combustion fan 25a coincides with the amount of primary combustion air supplied from the air supply port 25c to the primary combustion region R2 of the carbonization furnace 20. Therefore, the carbonization furnace control unit 29 can adjust the amount of primary combustion air blown to the primary combustion region R2 by controlling the amount of air blown by the primary combustion fan 25a. .
- the carbonization furnace control unit 29 performs primary operation based on the atmospheric temperature in the primary combustion region R2 detected by the temperature sensor 28b so that the combustion state suitable for carbonizing the organic waste leaves deposited in the gap 20a is maintained.
- the amount of air blown by the combustion fan 25a is controlled.
- the carbonization furnace control unit 29 controls the amount of air blown by the primary combustion firing fan 25a so that the atmospheric temperature of the primary combustion region R2 is within a range of 1000 ° C. or more and 1200 ° C. or less.
- the carbonization furnace control unit 29 controls the amount of air blown by the secondary combustion fan 26a based on the combustion gas temperature Tg detected by the temperature sensor 28a.
- the amount of air blown by the secondary combustion fan 26a matches the amount of air for secondary combustion supplied to the secondary combustion region R4 of the carbonization furnace 20 from the air supply port 26c. Therefore, the carbonization furnace control unit 29 can adjust the amount of secondary combustion air blown to the secondary combustion region R4 by controlling the amount of air blown by the secondary combustion fan 26a. .
- the carbonization furnace control unit 29 is based on the combustion gas temperature Tg detected by the temperature sensor 28a so that the combustion state suitable for burning the combustible gas contained in the combustion gas in the secondary combustion firing region R4 is maintained.
- the amount of air blown by the secondary combustion fan 26a is controlled.
- the carbonization furnace control unit 29 controls the amount of air blown by the secondary combustion fan 26a according to the flowchart shown in FIG.
- Each process in the flowchart shown in FIG. 8 is a process performed when a calculation unit (not shown) included in the carbonization furnace control unit 29 executes a control program stored in a storage unit (not shown).
- the carbonization furnace control unit 29 Prior to the processing shown in the flowchart of FIG. 8, when the carbonization furnace control unit 29 starts combustion of the organic waste in the carbonization furnace 20, the organic waste is generated by the ignition burner 20 c and accumulated in the gap 20 a. Start burning. Thereafter, the carbonization furnace control unit 29 starts blowing external air (atmosphere) by the secondary combustion fan 26a. The carbonization furnace control unit 29 controls the secondary combustion fan 26a so that the air flow rate is constant until the combustion gas temperature Tg detected by the temperature sensor 28a becomes equal to or higher than the first combustion firing gas temperature Tg1. After the combustion gas temperature Tg detected by the temperature sensor 28a becomes equal to or higher than the first combustion gas temperature Tg1, the processes shown in the flowchart of FIG. 8 are started.
- the amount of secondary combustion air blown by the secondary combustion fan 26a before the combustion gas temperature Tg becomes equal to or higher than the first combustion gas temperature Tg1 is assumed to exist in the secondary combustion region R4. It is an amount obtained by adding a certain surplus amount to the amount necessary to completely burn the fuel.
- step S800 the carbonization furnace control unit 29 receives the temperature detection signal transmitted from the temperature sensor 28a, thereby detecting the combustion combustion gas temperature Tg that is the temperature of the combustion gas discharged from the combustion gas discharge unit 27.
- step S801 the carbonization furnace control unit 29 determines whether or not the combustion gas temperature Tg detected by the temperature sensor 28a is lower than the first combustion gas temperature Tg1. If it is determined that the combustion gas temperature Tg is lower than the first combustion firing gas temperature Tg1, the carbonization furnace control unit 29 proceeds to step S802, otherwise proceeds to step S803.
- step S802 the carbonization furnace control unit 29 transmits a control signal for reducing the blown amount of the secondary combustion fan 26a to the secondary combustion fan 26a.
- the secondary combustion fan 26a reduces the blown air volume in response to receiving the control signal from the carbonization furnace control unit 29.
- the blowing amount of the secondary combustion fan 26a is decreased for the following reason.
- the amount of secondary combustion air that the secondary air supply unit 26 supplies to the secondary combustion region R4 is a fixed amount rather than the amount that causes complete combustion of the combustible gas contained in the combustion gas present in the secondary combustion region R4. A large amount is preferable. That is, the excess air ratio in the secondary combustion region R4 is preferably set to a constant value larger than 1.0.
- the amount of combustible gas present in the secondary combustion region R4 generally varies depending on factors such as the properties of the organic waste and the combustion state of the organic waste in the primary combustion region R2. Therefore, if the amount of secondary combustion air supplied from the secondary air supply unit 26 to the secondary combustion region R4 is kept constant, an air amount suitable for complete combustion of the combustible gas cannot be maintained.
- the combustion efficiency of the combustible gas in the secondary combustion region R4 is deteriorated, and the combustion gas containing a large amount of the combustible gas is discharged from the combustion gas discharge unit 27.
- the combustible gas contains polymer hydrocarbons which are components that solidify to become tar. Therefore, if a large amount of components that solidify into combustible gas and become tar remains contained, the carbonization furnace 20 and equipment installed downstream thereof may be damaged. For this reason, it is desirable that a large amount of components that solidify into the combustion gas and become tar are not included, and damage to the carbonization furnace 20 and equipment installed downstream thereof is desirably suppressed. Therefore, when the carbonization furnace control unit 29 determines that the combustion gas temperature Tg is lower than the first combustion gas temperature Tg1, the secondary combustion is performed in order to reduce the amount of surplus air supplied to the secondary combustion region R4. The air volume of the fan 26a is reduced.
- step S803 the carbonization furnace control unit 29 determines whether or not the combustion gas temperature Tg detected by the temperature sensor 28a is higher than the second combustion gas temperature Tg2.
- the carbonization furnace control unit 29 advances the process to step S804, and if not, advances the process to step S801.
- step S804 the carbonization furnace control unit 29 transmits a control signal for increasing the blowing amount of the secondary combustion fan 26a to the secondary combustion fan 26a.
- the secondary combustion fan 26a increases the blown air volume in response to receiving the control signal from the carbonization furnace control unit 29.
- the carbonization furnace control unit 29 starts executing the process shown in FIG. 8 again.
- the blowing amount of the secondary combustion fan 26a is increased for the following reason.
- the combustion gas temperature Tg be equal to or lower than a predetermined upper limit temperature.
- the carbonization furnace control unit 29 increases the blowing amount of the secondary combustion fan 26a when it is determined that the combustion gas temperature Tg is higher than the second combustion gas temperature Tg2. As described above, when a large amount of surplus air is supplied to the secondary combustion region R4 by increasing the amount of air blown from the secondary combustion fan 26a, the atmospheric temperature in the secondary combustion region R4 is lowered.
- the carbonization furnace control unit 29 controls the amount of air blown by the secondary combustion fan 26a based on the combustion gas temperature Tg detected by the temperature sensor 28a, so that the combustion gas temperature Tg is the first. It is made to become more than combustion gas temperature Tg1 and below the 2nd combustion gas temperature Tg2.
- the first combustion gas temperature Tg1 and the second combustion gas temperature Tg2 for example, the first combustion gas temperature Tg1 can be set to 900 ° C., and the second combustion gas temperature Tg2 can be set to 1300 ° C.
- the reason why the first combustion gas temperature Tg1 is set to 900 ° C. is that most of the polymer hydrocarbons can be removed from the combustion gas by maintaining the temperature of the secondary combustion region R4 at 900 ° C. or higher. .
- the polymer hydrocarbon is a component that solidifies into a tar in the combustible gas contained in the combustion gas. Therefore, by removing most of the polymer hydrocarbons from the combustion gas, it is possible to suppress damage to the carbonization furnace 20 and equipment installed downstream thereof.
- the first combustion gas temperature Tg1 and the second combustion gas temperature Tg2 may be set to 1000 ° C.
- the second combustion gas temperature Tg2 may be set to 1200 ° C.
- both the first combustion gas temperature Tg1 and the second combustion gas temperature Tg2 may be set to 1100 ° C.
- the carbonization furnace control unit 29 decreases the blowing amount when the combustion gas temperature Tg is lower than the first combustion gas temperature Tg1, and increases the blowing amount when the combustion gas temperature Tg is higher than the second combustion gas temperature Tg2.
- the secondary combustion fan 26a is controlled so as to cause this to occur.
- Each process in the flowchart shown in FIG. 9 is a process performed when a calculation unit (not shown) included in the carbonization furnace control unit 29 executes a control program stored in a storage unit (not shown).
- the carbonization furnace control unit 29 controls the discharge amount of the carbide discharged by the carbide discharge unit 24.
- the amount of carbide discharged by the carbide discharge unit 24 is controlled because the input of the organic waste from the organic waste input unit 23 to the gap 20a is stopped. This is to prevent the temperature of the carbide discharged from 24 from rising.
- the carbide refining / cooling region R1 for extinguishing the carbide gradually decreases.
- the rotation speed of the turntable 24a is maintained constant, the carbide is discharged from the lower end of the gap 20a in a state where the carbide is not sufficiently cooled. This is because the carbide that has been carbonized in the primary combustion region R2 to a high temperature is not sufficiently cooled in the carbide refining / cooling region R1.
- the carbonization furnace control part 29 adjusts the temperature of the carbide
- the carbonization furnace control unit 29 adjusts the temperature of the carbide discharged by the carbide discharge unit 24 using both the temperature sensor 28c and the level sensor 28d.
- the former is a sensor that directly detects the temperature of the carbide
- the latter is a sensor that indirectly detects a state in which the temperature of the carbide is high from the amount of deposited carbide.
- step S900 the carbonization furnace control unit 29 receives the temperature detection signal transmitted from the temperature sensor 28c, thereby detecting the carbide temperature Tc, which is the temperature of the carbide deposited on the lower end side of the gap 20a.
- step S901 the carbonization furnace control unit 29 receives the accumulation amount detection signal transmitted from the level sensor 28d, and thereby detects the accumulation amount Ao that is the accumulation amount of the organic waste deposited on the immediate side 20a.
- step S902 the carbonization furnace control unit 29 determines whether the carbide temperature Tc detected by the temperature sensor 28c is equal to or higher than the first carbide temperature Tc1.
- the carbonization furnace control unit 29 proceeds to step S903, and otherwise proceeds to step S904.
- 1st carbide carbonized_material temperature Tc1
- arbitrary temperature of the range of 250 degreeC or more and 300 degrees C or less can be set, for example.
- step S903 the carbonization furnace control unit 29 controls the drive unit 24b to rotate the rotation speed of the turntable 24a at the second rotation speed Rs2.
- the second rotation speed Rs2 is lower than the first rotation speed Rs1 described later.
- the first rotation speed Rs1 is a speed for discharging the amount of carbide necessary for the carbonization furnace 20 to maintain the normal operation state from the carbide discharge portion 24.
- the rotational speed of the turntable 24a is set to the first speed so that the temperature of the carbide discharged by the carbide discharge unit 24 is lowered when the carbide temperature Tc detected by the temperature sensor 28c is equal to or higher than the first carbide temperature Tc1.
- the second rotation speed Rs2 is lower than the rotation speed Rs1.
- step S904 the carbonization furnace control unit 29 determines whether or not the deposition amount Ao detected by the level sensor 28d is equal to or less than the first deposition amount Ao1.
- the carbonization furnace control unit 29 advances the process to step S905, and otherwise advances the process to step S906.
- step S905 the carbonization furnace control unit 29 controls the drive unit 24b to rotate the rotation speed of the turntable 24a at the second rotation speed Rs2.
- the second rotation speed Rs2 is lower than the first rotation speed Rs1 described later.
- the rotation speed of the turntable 24a is set to the first speed so that the temperature of the carbide discharged by the carbide discharge unit 24 decreases when the accumulation amount Ao detected by the level sensor 28d becomes equal to or less than the first accumulation amount Ao1.
- the second rotation speed Rs2 is lower than the rotation speed Rs1.
- step S906 the carbonization furnace control unit 29 controls the drive unit 24b to rotate the rotation speed of the turntable 24a at the first rotation speed Rs1.
- the first rotation speed Rs1 is a speed for discharging the amount of carbide necessary for the carbonization furnace 20 to maintain the normal operation state from the carbide discharge section 24. Since the carbide temperature Tc is lower than the first carbide temperature Tc1 and the accumulation amount Ao is larger than the first accumulation amount Ao1 in step S906, the carbonization furnace control unit 29 requires an amount necessary to predict the operating state.
- the drive unit 24 b is controlled so as to discharge the carbide from the carbide discharge unit 24.
- the carbonization furnace control unit 29 starts execution of the process shown in FIG. 9 again when the process of the flowchart shown in FIG. 9 is completed.
- the carbonization furnace control unit 29 is configured so that the drive unit 24b rotates the turntable 24a based on the carbide temperature Tc detected by the temperature sensor 28c and the organic waste accumulation amount Ao detected by the level sensor 28d. To control.
- the rotation speed of the turntable 24a is switched between two stages depending on whether or not the carbide temperature Tc detected by the temperature sensor 28c is equal to or higher than the first carbide temperature Tc1.
- the rotational speed of the turntable 24a may be switched in two or more stages according to the carbide temperature Tc.
- the rotational speed of the turntable 24a may be controlled so as to be a speed inversely proportional to the carbide temperature Tc detected by the temperature sensor 28c without switching the rotational speed of the turntable 24a stepwise.
- the rotation speed of the turntable 24a is switched in two steps depending on whether or not the accumulation amount Ao detected by the level sensor 28d is equal to or more than the first accumulation amount Ao1.
- the rotation speed of the turntable 24a may be switched in a plurality of stages of two or more stages according to the accumulation amount Ao.
- the rotational speed of the turntable 24a may be controlled so as to be a speed proportional to the accumulation amount Ao detected by the level sensor 28d without switching the rotational speed of the turntable 24a stepwise.
- the rotational speed of the turntable 24a is controlled using both the carbide temperature Tc detected by the temperature sensor 28c and the accumulation amount Ao detected by the level sensor 28d.
- Other embodiments may be used.
- the rotational speed of the turntable 24a may be controlled using either the carbide temperature Tc detected by the temperature sensor 28c or the deposition amount Ao detected by the level sensor 28d.
- FIG. 10 is a longitudinal sectional view of the pyrolysis furnace 30 shown in FIG.
- the axis Z indicates the vertical direction (gravity direction) orthogonal to the installation surface (not shown) on which the pyrolysis furnace 30 is installed.
- the pyrolysis furnace 30 of the present embodiment includes a main body 31, a reaction tube 32, a reaction tube head 33 (supply portion), a water gas outlet nozzle 34 (water gas outlet portion), Combustion gas supply part 35 (heating gas supply part), combustion gas discharge part 36 (heating gas discharge part), gland packing 37 (first seal part), gland packing 38 (second seal part), And a gland packing 39 (third seal portion).
- the main body 31 is a member formed in a substantially cylindrical shape extending along the axis Z.
- the main body 31 forms a space for accommodating the reaction tube 32 therein.
- the main body 31 is attached to a metal (for example, iron) housing 31a that forms the exterior of the pyrolysis furnace 30, a heat insulating material 31b that is attached to the inner peripheral surface of the housing 31a, and an inner peripheral surface of the heat insulating material 31b. And a heat-resistant material 31c.
- the upper surface of the substantially cylindrical main body 31 is composed of an upper plate 31d that is annular in plan view, and the bottom surface of the main body 31 is composed of a bottom plate 31e that is annular in plan view.
- An upper end flange 31g (first flange portion) is provided at the upper end of the side surface 31f of the main body 31, and a lower end flange 31i (second flange portion) is provided at the lower end of the side surface 31f of the main body 31.
- the upper plate 31d and the upper end flange portion 31g are a fastening bolt 31h (fastening member) in a state where a gasket (fourth seal portion) (not shown) is sandwiched between the upper plate 31d and the upper end flange portion 31g at a plurality of positions around the axis Z. ).
- the bottom plate 31e and the lower end flange 31i are a fastening bolt 31j (fastening member) in a state where a gasket (fifth seal portion) (not shown) is sandwiched between the bottom plate 31e and the lower end flange 31i at a plurality of locations around the axis Z.
- the reaction tube 32 is a mechanism formed in a substantially cylindrical shape extending along the axis Z.
- the reaction tube 32 has an outer peripheral surface 32 d that forms a combustion gas flow path 30 a for allowing a combustion gas (heating gas) to flow between the inner peripheral surface of the main body 31.
- the reaction tube 32 includes a center pipe 32a (tubular member), an upper end flange 32b (third flange portion), a plurality of first inclined plates 32f, a plurality of second inclined plates 32g, and a plurality of holding rods 32h (holding portions). ).
- the upper end flange 32b of the reaction tube 32 and the end of the center pipe 32a on the upper end flange 32b side protrude upward from the upper plate 31d (upper surface) of the main body 31. Further, the lower end portion 32 c of the reaction tube 32 protrudes downward from the bottom plate 31 d (bottom surface) of the main body portion 31.
- the center pipe 32a is a member formed in a cylindrical shape extending along the axis Z. Inside the center pipe 32a is housed a thermal decomposition promotion mechanism including a plurality of first inclined plates 32f, a plurality of second inclined plates 32g, and a plurality of holding rods 32h (holding portions).
- the thermal decomposition promotion mechanism promotes the thermal decomposition reaction of carbide and superheated steam (gasification agent) by guiding the carbide stepwise from the upper end side to the lower end side of the center pipe 32a and retaining the carbide in the reaction tube 32. It is a mechanism to make.
- the plurality of first inclined plates 32f and the plurality of second inclined plates 32g are held by four holding bars 32h at a plurality of locations along the axis Z.
- the first inclined plates 32f and the second inclined plates 32g are alternately arranged along the axis Z.
- the upper ends of the four holding rods 32 h are attached to the lower surface of the lower end flange 33 a of the reaction tube head 33.
- the first inclined plate 32f shown in FIG. 11 (a) has the carbide in one end (the left end in FIG. 11 (a)) of the inner peripheral surface 32e of the reaction tube 32 and the other end (in FIG. 11 (a)). It is arranged so as to form a first inclined surface that is inclined so as to be led to the first opening 32i provided at the right end).
- the second inclined plate 32f shown in FIG. 11 (b) has one end (FIG. 11 (b)) from the other end (the right end in FIG. 11 (b)) of the carbide 32 to the carbide. It is arranged so as to form a second inclined surface that is inclined so as to be led to the second opening 32j provided at the left end portion in the middle.
- the first inclined surface formed by the first inclined plate 32f is inclined so as to guide the carbide falling from the second opening 32j downward
- the second inclined plate 32g forms the second inclined surface.
- the inclined surface is inclined so as to guide the carbide falling from the first opening 32i downward.
- the thermal decomposition promoting mechanism guides the carbide stepwise from the upper end side to the lower end side of the center pipe 32a using the first inclined plates 32f and the second inclined plates 32g that are alternately arranged along the axis Z. be able to.
- the inclination angle of the first inclined surface and the second inclined surface with respect to the plane orthogonal to the axis Z can be arbitrarily set according to the properties of the carbide, but in order to reliably move the carbide along the inclined surface, the carbide. It is preferable that the angle be equal to or greater than the angle of repose. On the other hand, if the inclination angle is too large, the residence time of the carbide in the reaction tube 32 is shortened, and the thermal decomposition reaction is not sufficiently promoted. Therefore, it is particularly preferable that the inclination angle of the first inclined surface and the second inclined surface with respect to the plane orthogonal to the axis Z is determined to be equal to or greater than the repose angle of the carbide in the range of 20 ° to 60 °.
- the reaction tube head 33 is attached to the reaction tube 32 and supplies carbide and superheated steam (gasification agent) to the inside of the reaction tube 32 to generate water gas inside the reaction tube 32.
- the reaction tube head 33 includes a lower end flange 33a (fourth flange) attached to the reaction tube 32, an upper end flange 33b attached to the carbide supply passage 101, and a flow path (not shown) through which superheated steam is supplied from the steam superheater 81. ) And a side flange 33c attached thereto.
- the lower end flange 33a of the reaction tube head 33 and the upper end flange 32b of the reaction tube 32 are fastened by fastening bolts 33d with a gasket (sixth seal portion) (not shown) sandwiched between them at a plurality of locations around the axis Z. ing.
- the water gas outlet nozzle 34 is a substantially cylindrical member attached to the lower end portion 32 c of the reaction tube 32.
- the water gas outlet nozzle 34 is used to reduce the temperature of the water gas generated by the pyrolysis reaction of the carbide in the reaction tube 32, the unreacted portion of the carbide, the ash, and the like through the water gas supply path 102. Lead to.
- the combustion gas supply unit 35 is an opening that is provided above the main body 31 and supplies combustion gas guided from the combustion gas channel 200a to the combustion gas channel 30a.
- the combustion gas discharge unit 36 is an opening that is provided below the main body 31 and discharges the combustion gas from the combustion gas channel 30a to the combustion gas channel 200b.
- the combustion gas supplied from the combustion gas supply part 35 to the combustion gas flow path 30a flows from the upper end side to the lower end side of the center pipe 32a while heating the outer peripheral surface 32d of the center pipe 32a, and is discharged from the combustion gas discharge part 36. Is done.
- the gland packing 37 is a member that blocks the combustion gas in the combustion gas flow path 30a from flowing out from the upper plate 31d of the main body 31 to the outside.
- the gland packing 37 is an annular member that is provided in contact with the lower surface of the upper plate 31 d of the main body 31 and has an inner peripheral surface 37 d that contacts the outer peripheral surface 32 d of the reaction tube 32.
- the gland packing 37 is configured such that the ceramic board 37a, the ceramic board 37b, and the ceramic fiber 37c are in close contact with each other.
- the ceramic fiber 37c which is a fibrous material that can be deformed relatively easily, the sealing performance at the portion in contact with the heat insulating material 31b and the heat resistant material 31c is enhanced.
- the gland packing 38 is a member that blocks the combustion gas in the combustion gas flow path 30a from flowing out from the bottom surface 31e of the main body 31 to the outside.
- the gland packing 38 is an annular member that is provided in contact with the upper surface of the bottom plate 31 e of the main body 31 and has an inner peripheral surface 38 d that contacts the outer peripheral surface 32 d of the reaction tube 32.
- the gland packing 38 is configured in a state where the ceramic board 38a, the ceramic board 38b, and the ceramic fiber 38c are in close contact with each other.
- the ceramic fiber 38c which is a fibrous material that can be deformed relatively easily, the sealing performance at the portion in contact with the heat insulating material 31b and the heat resistant material 31c is enhanced.
- the gland packing 39 is a member that blocks outflow of water gas from the mounting position at the mounting position of the lower end portion 32 c of the reaction tube 32 and the water gas outlet nozzle 34.
- the gland packing 39 is an annular member in plan view having an inner peripheral surface 39d that contacts each of the outer peripheral surface 32d of the reaction tube 32 and the outer peripheral surface 34a of the water gas outlet nozzle 34.
- the gland packing 39 includes an annular packing member 39a, an annular packing member 39b, and a packing pressing member 39c.
- the packing member 39a and the packing member 39b contract in the axis Z direction and expand in the radial direction perpendicular to the axis Z.
- the inner peripheral surface 39d of the gland packing 39 comes into contact with the outer peripheral surface 32d of the reaction tube 32 and the outer peripheral surface 34a of the water gas outlet nozzle 34, thereby forming a seal region.
- the carbide supply path 101 includes a screw conveyor 101a, a clinker removing device 101b, a belt conveyor 101c, a magnetic separator 101d, a screw conveyor 101e, and a screw conveyor 101f.
- the screw conveyor 101a is a device that conveys the carbide discharged from the carbonization furnace 20.
- the screw conveyor 101a accommodates a screw in a linearly extending cylindrical body.
- the screw conveyor 101a conveys the carbide along the extending direction of the cylinder by rotating the screw inside the cylinder by the driving force of the motor.
- the clinker removing device 101b is a device that removes a clinker having a particle size of a certain size or more from the carbide discharged from the screw conveyor 101a with a net or the like.
- the carbide from which the clinker is removed is conveyed to the magnetic separator 101d by the belt conveyor 101c.
- the magnetic separator 101d is a device that removes iron scraps such as nails contained in carbide with a magnet.
- the carbide from which the iron scrap has been removed is supplied to the screw conveyor 101e.
- the screw conveyor 101e and the screw conveyor 101f are apparatuses for conveying carbides, respectively.
- the screw conveyor 101f supplies the carbide to the nitrogen replacement unit 30b included in the pyrolysis furnace 30.
- description is abbreviate
- the screw conveyor 101e and the screw conveyor 101f carry the carbide to the upper side of the pyrolysis furnace 30 because the carbide is supplied from above the pyrolysis furnace 30 and in the reaction tube 32 of the pyrolysis furnace 30 by its own weight. This is to allow carbide to pass through.
- the entire region from the upper end to the lower end of the reaction tube 32 can be used as a region for promoting the pyrolysis reaction. Further, since the carbide is passed through the reaction tube 32 by its own weight, no special power for moving the carbide is required.
- Carbide is transported in two stages, screw conveyor 101e and screw conveyor 101f, because each screw conveyor requires an expensive motor with a large driving force by reducing the power required to rotate the screw. This is to avoid the above.
- the nitrogen replacer 30b is a device that constitutes the pyrolysis furnace 30, and is a device for replacing oxygen contained in the air supplied from the screw conveyor 101f together with the carbide with inert nitrogen gas.
- the nitrogen purger 30b is disposed on the upper side connected to the screw conveyor 101f and the lower side connected to the reaction tube head 33, and is an electric control valve (for example, a ball valve) whose open / close state is controlled by the control device 90. ).
- the control device 90 supplies carbide to the inside of the nitrogen purger 30b by opening the upper control valve and closing the lower control valve.
- the control device 90 stops the transportation of the carbide by the screw conveyor 101f and closes the control valve above the nitrogen purger 30b. .
- Nitrogen gas is always supplied to the nitrogen replacer 30b from a device that generates nitrogen gas such as an air separation device. Therefore, when the control valve above and below the nitrogen purger 30b is closed and a certain time has elapsed, the air supplied into the nitrogen purger 30b together with the carbide is discharged to the outside, and the inside is replaced with nitrogen gas. It becomes a state.
- the control device 90 switches the control valve below the nitrogen purger 30b to the open state to transfer the carbide from the nitrogen purger 30b to the reaction tube head 33. Supply. After supplying carbide to the reaction tube head 33 from the nitrogen purger 30b, the controller 90 closes the control valve below the nitrogen purger 30b. Further, the control device 90 then opens the control valve above the nitrogen purger 30b and supplies new carbide into the nitrogen purger 30b.
- control device 90 controls the opening and closing of the control valves above and below the nitrogen purger 30b, so that the gas supplied to the reaction tube head 33 together with the carbide is nitrogen gas.
- This nitrogen gas is an inert gas that does not react with the water gas generated in the reaction tube 32. For this reason, it is possible to suppress the reduction of the yield of the water gas due to the reaction between the oxygen and the water gas due to the supply of the air containing the acid cord together with the carbide to the reaction tube 32.
- the char collection device 41 includes a nitrogen purger 41a and a char collection unit 41b.
- the nitrogen replacer 41a is a device for replacing the water gas supplied from the temperature reducer 40 together with the unreacted portion of the carbide with inert nitrogen gas.
- the char recovery unit 41b is an apparatus that recovers an unreacted portion of the carbide and supplies the unreacted component to a nitrogen purger 30b from a supply path (not shown).
- the nitrogen purger 41a is disposed on the upper side connected to the temperature reducer 40 and the lower side connected to the char recovery unit 41b, and is an electric control valve (for example, a ball) whose opening / closing state is controlled by the control device 90. Valve).
- the control device 90 supplies unreacted carbide to the inside of the nitrogen purger 41a by opening the upper control valve and closing the lower control valve. When the unreacted amount of the carbide supplied into the nitrogen purger 41a reaches a certain amount, the control device 90 closes the control valve above the nitrogen purger 41a.
- Nitrogen gas is always supplied to the nitrogen replacer 41a from a device that generates nitrogen gas such as an air separation device. Therefore, when the upper and lower control valves of the nitrogen purger 41a are closed and a certain period of time has elapsed, the water gas supplied into the nitrogen purger 41a together with the unreacted portion of the carbide is discharged to the outside, and the interior becomes nitrogen. The gas is replaced. The water gas discharged from the nitrogen purger 41a is supplied to the flare stack 71.
- the control device 90 switches the control valve below the nitrogen purger 41a to the open state, and the carbide is transferred from the nitrogen purger 41a to the char recovery unit 41b. The unreacted portion is supplied. After supplying the unreacted portion of the carbide from the nitrogen purger 41a to the char recovery unit 41b, the control device 90 closes the control valve below the nitrogen purger 41a. In addition, the control device 90 then opens the control valve above the nitrogen purger 41a and supplies new unreacted carbon carbide into the nitrogen purger 41a.
- control device 90 controls the opening and closing of the control valves above and below the nitrogen purger 41a, so that the water gas supplied to the char recovery unit 41b together with the unreacted carbide is supplied to the char recovery unit 41b. It is prevented from being supplied.
- the residue collection device 51 has a nitrogen purger 51a and a residue collection unit 51b.
- the nitrogen replacer 51a is a device for replacing the water gas supplied from the cyclone 50 together with the residue with inert nitrogen gas.
- the residue collection unit 51b is a device that collects the residue discharged from the nitrogen purger 51a.
- the nitrogen purger 51a is disposed on each of an upper side connected to the cyclone 50 and a lower side connected to the residue recovery unit 51b, and an electric control valve (for example, a ball valve) whose open / close state is controlled by the control device 90.
- an electric control valve for example, a ball valve
- Nitrogen gas is always supplied to the nitrogen replacer 51a from a device that generates nitrogen gas such as an air separation device.
- the control device 90 controls the control valve of the nitrogen purger 51a in the same manner as the control valve of the nitrogen purger 41a, and prevents water gas from being supplied to the residue recovery unit 51b. .
- the method by which the control device 90 controls the control valve of the nitrogen purger 51a is the same as the method by which the control device 90 controls the control valve of the nitrogen purger 41a, and thus the description thereof is omitted.
- the steam generator 80 includes a steam generation unit 80a and a steam circulation tank 80b.
- the steam generator 80a includes a heat transfer tube (not shown) that circulates water that exchanges heat with the combustion gas, and a jacket (not shown) that is provided in a cylindrical body that is formed so as to cover the heat transfer tube. Abbreviation). Water is supplied to the heat transfer tube and the jacket from the steam circulation tank 80b.
- the steam circulation tank 80b is supplied with water from the water supply device 82 and supplies water to the heat transfer tube and the jacket of the steam generation unit 80a.
- the hot water heated by the jacket and the steam generated by heating the heat transfer tube with the combustion gas are respectively collected in the steam circulation tank 80b.
- the steam circulation tank 80b supplies the steam (saturated steam) supplied from the heat transfer tube of the steam generating unit 80a to the steam superheater 81.
- the dryer 10 is a dryer of a type called a rotary kiln, and includes a combustion gas introduction unit 10b, a rotating body 10c, and a discharge unit 10d.
- the combustion gas introduction part 10b introduces the combustion gas supplied from the combustion gas flow path 200d into the dryer 10 and introduces the introduced combustion gas into the rotary body 10c.
- the rotating body 10c is a cylindrical member formed in a direction extending along the axis W, and rotates around the axis W when it receives rotational power from a drive motor. Moreover, organic waste is supplied into the inside of the rotary body 10c from the raw material supply path 11a. The organic waste supplied to the inside of the rotating body 10c is guided toward the discharge unit 10d while being dried by the combustion gas guided from the combustion gas introduction unit 10b. The organic waste is directly heated by the combustion gas while being stirred by the rotation of the rotating body 10c, and is conveyed by the flow of the combustion gas from one end to the other end of the rotating body 10c.
- the discharge unit 10d collects the dried organic waste while being conveyed by the rotating body 10c, and supplies it to the raw material supply path 10a.
- the organic waste supplied to the raw material supply path 10 a is supplied to the carbonization furnace 20 via the hopper 12. Further, the discharge unit 10d supplies the combustion gas introduced from the combustion gas introduction unit 10b through the inside of the rotating body 10c to the combustion gas channel 200e.
- the combustion gas supplied to the combustion gas flow path 200e is supplied to the exhaust gas cooling and cleaning device 13.
- organic waste is introduced from the organic waste input unit 23 into the gap 20a formed between the inner peripheral surface 21d of the main body 21 and the outer peripheral surface 22a of the cylindrical portion 22.
- the organic waste is partially burned by the primary combustion air that is supplied and supplied from the primary air supply unit 25 to the gap 20a.
- the organic waste input from the organic waste input unit 23 accumulates in the gap 20 a between the main body portion 21 and the cylindrical portion 22 from the lower side along the axis X to the upper side. is doing.
- the upper layer side of the gap 20a is a primary combustion region R2 in which organic waste is partially combusted by the primary combustion air.
- the organic waste is partially combusted by the primary combustion air, and a solid content containing a large amount of carbide and a combustion gas containing a combustible gas are generated.
- the organic waste on the lower layer side of the gap 20a is blocked by the organic waste on the upper layer side, and becomes a carbide refining / cooling region R1 in which a solid content containing a large amount of carbide is refined and cooled.
- the solid content containing a large amount of carbide is refined while being further carbonized in a state where the oxygen concentration is low, and is gradually extinguished as it approaches the lower end of the gap 20a.
- interval 20a is cooled.
- the carbonization furnace 20 includes a combustible gas contained in the combustion gas separately from the primary air supply unit 25 that supplies primary combustion air that partially burns organic waste toward the gap 20a.
- the secondary combustion air supplied by the secondary air supply unit 26 is provided with a secondary air supply unit 26 that supplies secondary combustion air for burning the property gas to the secondary combustion region R4 inside the main body 21.
- the supply amount is a system controlled by the carbonization furnace control unit 29 according to the temperature detected by the temperature sensor 28a.
- the problem of polymer hydrocarbons occurs due to the following factors.
- the amount of secondary combustion air becomes excessive with respect to the amount by which the combustible gas contained in the combustion gas in the secondary combustion region R4 is completely burned, and surplus air that is not used for combustion of the combustible gas is secondary combustion.
- the temperature of the air (atmosphere) blown by the secondary combustion fan 26a is lower than the atmospheric temperature of the secondary combustion region R4, so the atmosphere of the secondary combustion region R4 is caused by a large amount of excess air. The temperature drops.
- the carbonization furnace control unit 29 determines that the temperature Tg of the combustion gas detected by the temperature sensor 28a is lower than the first combustion gas temperature Tg1, secondary combustion is performed.
- the amount of air blown from the secondary combustion fan 26a is reduced.
- the atmospheric temperature in the secondary combustion region R4 is maintained without lowering, and the combustible gas is combusted so as not to contain a large amount of components that solidify into the combustion gas and become tar. There is an effect that it is possible to suppress damage to equipment installed on the side.
- the carbonization furnace control unit 29 determines that the temperature Tg of the combustion gas detected by the temperature sensor 28a is higher than the first combustion gas temperature Tg1, the secondary air supply unit is set to be equal to or lower than the second combustion gas temperature Tg2. Control is performed so as to increase the supply amount of the secondary combustion air supplied by 26.
- the temperature Tg of the combustion gas discharged from the combustion gas discharge unit 27 is equal to or lower than the second combustion gas temperature Tg2, the combustion gas flow that guides the combustion gas from the carbonization furnace 20 and the carbonization furnace 20 to the pyrolysis furnace 30.
- the heat resistant temperature required by the path 200a can be set to the second combustion gas temperature Tg2 or less. Therefore, there is an effect that the carbonization furnace 20 and the combustion gas flow path 200a can be manufactured with an inexpensive material having a relatively low heat-resistant temperature.
- the carbonization furnace controller 29 controls the supply amount of the secondary combustion air so that the first combustion gas temperature Tg1 is 900 ° C. and the second combustion gas temperature Tg2 is 1300 ° C. It is preferable to control. Furthermore, it is more preferable that the carbonization furnace controller 29 controls the supply amount of the secondary combustion air so that the first combustion gas temperature Tg1 is 1000 ° C. and the second combustion gas temperature Tg2 is 1200 ° C.
- the combustible gas is combusted in the secondary combustion region R4 in the carbonization furnace 20 so as not to contain a large amount of polymer hydrocarbons that are solidified and become tar, and heat is generated from the carbonization furnace 20 and the carbonization furnace 20.
- the heat-resistant temperature required for the combustion gas channel 200a that guides the combustion gas to the cracking furnace 30 can be further reduced.
- the problem of carbide temperature is caused by the following factors.
- the amount of the organic waste deposited in the gap 20a is gradually reduced, and the carbide refining / cooling region R1 for extinguishing the carbide is gradually narrowed.
- the rotation speed of the turntable 24a is kept constant, the carbide that has been carbonized in the primary combustion region R2 and has reached a high temperature is not sufficiently cooled in the carbide refining / cooling region R1, so the carbide is sufficiently cooled.
- the carbide refining / cooling region R1 There is a problem in that it is discharged from the lower end of the gap 20a when it is not.
- the carbonization furnace control unit 29 controls the discharge amount of the carbide discharged by the carbide discharge unit 24 to the outside according to the temperature of the carbide detected by the temperature sensor 28b. It is characterized by that. More specifically, when the temperature of the carbide detected by the temperature sensor 28b is lower than the first carbide temperature Tc1, the carbonization furnace control unit 29 sets the drive motor 24b to rotate the turntable 24a at the first rotation speed Rs1. When the temperature of the carbide detected by the temperature sensor 28b is equal to or higher than the first carbide temperature Tc1, the drive motor 24b is controlled to rotate the turntable 24a at the second rotation speed Rs2 lower than the first rotation speed Rs1. That is.
- the carbonization furnace control unit 29 reduces the rotation speed for rotating the turntable 24a, thereby lowering the lower end of the gap 20a per unit time.
- the amount of carbide led to the carbide discharge port 24c decreases.
- the effect that the carbide is discharged from the lower end of the gap 20a is exhibited.
- the carbonization furnace 20 that discharges the carbide in which the temperature of the carbide combusted by the organic waste is appropriately reduced. For example, even when the input of organic waste is stopped, the temperature of discharged carbide can be appropriately reduced.
- the carbide whose temperature has been appropriately lowered from the carbonization furnace it is possible to solve the problem that the discharged carbide is ignited again by touching the air.
- the solution is that the carbonization furnace control unit 29 has the carbide discharge unit 24 discharge to the outside in accordance with the amount Ao of organic waste detected by the level sensor 28d. Is to control the amount of emissions. More specifically, the carbonization furnace control unit 29 drives the drive motor 24e to rotate the turntable 24a at the first rotational speed Rs1 when the amount of carbide deposition detected by the level sensor 28d is equal to or greater than the first deposition amount Ao1.
- the drive motor rotates the turntable 24a at a second rotational speed Rs2 lower than the first rotational speed Rs1. It is a means to control 24e.
- the carbonization furnace control unit 29 reduces the rotation speed for rotating the turntable 24a, thereby reducing the gap per unit time.
- the amount of carbide guided from the lower end of 20a to the carbide discharge port 24c decreases.
- the effect that the carbide is discharged from the lower end of the gap 20a is exhibited.
- the carbonization efficiency of the organic waste is low when the external air (atmosphere) is used as the primary combustion air supplied to the primary combustion region R2 because the external air is lower than the ambient temperature of the primary combustion region R2. This is because the ambient temperature in the primary combustion region R2 is lowered by the external air.
- the carbonization furnace 20 heats the air blown by the primary combustion fan 25a by the heat radiating fins 25e and supplies the heated air to the gap 20a from the air supply port 25c. It is characterized by that. Since the air supplied to the gap 20a is heated by the radiating fins 25e, it is possible to suppress a decrease in the ambient temperature of the primary combustion region R2 as compared with the case where the air supplied to the gap 20a is not heated. Therefore, according to one embodiment of the present invention, it is possible to provide a carbonization furnace 20 capable of improving the carbonization efficiency of organic waste leaves while supplying external air as combustion air for organic waste. .
- the primary air supply unit 25 of the carbonization furnace 20 is disposed on the outer peripheral side of the gap 20a and extends around the axis X between the outer peripheral surface 21e of the main body 21. It is preferable to have a cover portion 25b that forms a space 25d.
- the air introduced from the outside by the primary combustion fan 25a is heated inside the closed space 25d and is also heated by the radiating fins 25e inside the closed space 25d. There is an effect that it can be efficiently heated sufficiently and supplied from the air supply port 25c to the gap 20a.
- a heat transfer member that transfers the heat radiation fin 25e of the primary air supply unit 25 of the carbonization furnace 20 according to the embodiment of the present invention to the ambient temperature of the gap 20a via the outer peripheral surface 21e of the main body unit 21; It is preferable to do. Accordingly, the air introduced from the outside by the primary combustion fan 25a can be heated by using the ambient temperature of the middle 20a of the carbonization furnace 20 without using a dedicated heating source for heating the closed space 25d. This produces the effect.
- the heat dissipating fins 25e of the primary air supply unit 25 of the carbonization furnace 20 are arranged below the air supply port 25c. Since the air supply port 25c supplies air toward the gap 20a, the outer peripheral surface 21e of the main body 21 below the air supply port 25c is a region where the ambient temperature of the gap 20a is transferred, The atmospheric temperature of the gap 20a is also transferred to the fins 25e via the outer peripheral surface 21e of the main body 21. Therefore, the air introduced from the outside by the primary combustion fan 25a by the radiating fins 25e can be efficiently heated and supplied to the gap 20a from the air supply port 25c.
- the primary combustion fan 25a of the primary air supply unit 25 of the carbonization furnace 20 is externally directed toward the outer peripheral surface 21e of the main body 21 located on the outer peripheral side below the gap 20a. It is characterized in that the air introduced from is blown. Below the gap 20a is a carbide refining / cooling region R1 in which solids containing a large amount of carbides generated by the combustion of organic waste are refined and cooled, so the lower part of the gap 20a is at a relatively low temperature. It is desirable to be maintained.
- the outer peripheral surface 21e of the main body portion 21 located on the outer peripheral side below the gap 20a is cooled by the air blown by the primary combustion fan 25a. There is an effect that it can be maintained at a low temperature.
- the carbonization furnace 20 has the radiation fins 25e more than the distance D1 from the inner peripheral surface 21d to the outer peripheral surface 21e of the main body 21 at the position where the air supply port 25c is disposed.
- the distance D2 from the inner peripheral surface 21d of the main body 21e to the outer peripheral surface 21e at the position where it is disposed is shorter.
- the atmosphere of the gap 20a is more likely to transfer heat at the position where the radiation fins 25e are disposed. Therefore, in the atmosphere of the gap 20a, heat is transferred from the heat radiation fins 25e more efficiently, and the air introduced from the outside by the primary combustion fan 25a can be heated to a higher temperature.
- the heat radiation fin 25e of the carbonization furnace 20 of the embodiment of the present invention is formed in an annular shape that contacts the outer peripheral surface 21e of the main body 21 and extends around the axis X along the outer peripheral surface 21e. It is characterized by being provided at a plurality of locations along. A plurality of air flow paths extending along the outer peripheral surface 21e of the main body portion 21 are formed by adjacent radiating fins 25e provided at a plurality of locations along the axis X, so that the air flowing through the air flow paths can be efficiently The effect of heating occurs.
- the heat radiation fin 25e forms a spiral flow path that contacts the outer peripheral surface 21e of the main body 21 and turns around the axis X from the lower side to the upper side along the outer peripheral surface 21e. preferable.
- the air blown by the primary combustion fan 25a is guided to the air supply port 25c while turning from below to above around the axis X along the outer peripheral surface 21e. The air is smoothly circulated, and the effect of heating the air flowing through the air flow path formed by the radiation fins 25e is improved.
- the carbide and gasifying agent superheated steam supplied from the reaction tube head 32 to the inside of the reaction tube 32 are heated at a high temperature.
- a thermal decomposition reaction is performed by being heated by the combustion gas (heating gas), and water gas is generated.
- the outer peripheral surface 32d of the reaction tube 32 is heated and thermally expanded by the high-temperature combustion gas flowing through the combustion gas flow path 30a, and the length along the axis Z becomes longer. Since the reaction tube 32 is arranged along the axis Z, the reaction tube 32 has a lower end 32c that is fixed to the bottom plate 31e of the main body 31 even if thermal expansion occurs. Due to the thermal expansion of the tube 32, the position along the axis Z of the upper end flange 32b of the reaction tube 32 may move upward.
- the pyrolysis furnace 30 is characterized by including a gland packing 37 provided below the upper plate 31d of the main body 31 so as to be in contact with the upper plate 31d.
- the gland packing 37 is an annular member that has an inner peripheral surface 37d that contacts the outer peripheral surface 32d of the reaction tube 32 in plan view.
- the reaction tube 32 is thermally expanded, the outer peripheral surface 32d of the reaction tube 32 and the inner peripheral surface 37d of the gland packing 37 slide, but the outer peripheral surface 32d of the reaction tube 32 and the inner peripheral surface 37d of the gland packing 37 are in contact with each other.
- the state where the seal region is formed is maintained.
- the gland packing 37 is provided so as to be in contact with the upper plate 31d, the state where the seal region is formed between the gland packing 37 and the upper plate 31d is maintained.
- the reaction tube 32 in which the pyrolysis reaction is performed is thermally expanded by the combustion gas flowing between the main body 31 and the upper plate 31d of the main body 31, An effect that the combustion gas can be prevented from flowing out from the gap with the outer peripheral surface 32d of the reaction tube 32 is produced.
- the pyrolysis furnace 30 is provided above the bottom plate 31e of the main body 31 so as to be in contact with the bottom plate 31e and has an inner peripheral surface 38d that is in contact with the outer peripheral surface 32d of the reaction tube 32.
- a gland packing 38 is provided.
- the gland packing 38 is an annular member in plan view having an inner peripheral surface 38 d that contacts the outer peripheral surface 32 d of the reaction tube 32.
- the reaction tube 32 is heated, there is a temperature distribution, and the extension due to thermal expansion is relatively small on the lower end 32c side, so that the outer peripheral surface 32d of the reaction tube 32 and the inner peripheral surface 38d of the gland packing 38 are in contact with each other. The state where the seal region is formed is maintained. Further, since the gland packing 38 is provided so as to be in contact with the bottom plate 31e, a state where a seal region is formed between the gland packing 38 and the bottom plate 31e is maintained.
- the reaction with the bottom plate 31e of the main body 31 occurs when the reaction tube 32 in which the pyrolysis reaction is performed is thermally expanded by the combustion gas flowing between the main body 31 and the combustion gas. There is an effect that the combustion gas can be prevented from flowing out from the gap with the outer peripheral surface 32d of the pipe 32.
- the pyrolysis furnace 30 also has a fastening portion in which combustion gas may flow out due to thermal expansion of the reaction tube 32 caused by high-temperature combustion gas flowing through the combustion gas passage 30a. Measures are taken.
- the fastening portion is a position where the upper plate 31d and the upper end flange portion 31g are fastened, and a position where the bottom plate 31e and the lower end flange 31i are fastened.
- the upper end flange 31g and the upper plate 31d provided at the upper end of the side surface 31f of the main body 31 are in the state where the gasket is sandwiched between them.
- a plurality of locations around Z are fastened by fastening bolts 31h.
- the lower end flange 31i provided at the lower end of the side surface 31f of the main body 31 and the bottom plate 31e are fastened at a plurality of locations around the axis Z by fastening bolts 31j with a gasket interposed therebetween. It is characterized by.
- a water gas outlet nozzle 34 that guides water gas generated by the pyrolysis reaction of carbide inside the reaction tube 32 to the lower end 32 c of the reaction tube 32.
- a gland packing 39 for blocking outflow of water gas generated from the attachment position is provided.
- the gland packing 39 has an annular shape in plan view having an inner peripheral surface 39d that comes into contact with each of the outer peripheral surface 32a of the reaction tube 32 and the outer peripheral surface 34a of the water gas outlet nozzle 34. Therefore, according to one embodiment of the present invention, it is possible to prevent the aqueous gas generated inside the reaction tube 32 from flowing out from the attachment position of the lower end portion 32c of the reaction tube 32 and the water gas outlet nozzle 34. There is an effect that can.
- the reaction tube 32 is provided with an upper end flange 32b, and the reaction tube head 33 is provided with a lower end flange 33a at the lower end thereof.
- the upper end flange portion 32b of the pipe 32 and the lower end flange portion 33a of the reaction tube head 33 are fastened by fastening bolts 33d at a plurality of locations around the axis Z with a gasket interposed therebetween. To do.
- the lower end flange 33a of the reaction tube head 33 and the upper end flange 32b of the reaction tube 32 are fastened, it is possible to suppress the outflow of water gas generated inside the reaction tube 32 to the outside. There is an effect.
- the carbide and the superheated steam that is a gasifying agent supplied from the reaction tube head 32 to the inside of the reaction tube 32 move from the upper end to the lower end of the reaction tube 32. For this reason, the entire region from the upper end to the lower end of the reaction tube 32 is heated by the high-temperature combustion gas flowing through the combustion gas flow path 30a, so that the pyrolysis reaction is performed and water gas is generated. Since the thermal decomposition reaction between the carbide and the superheated steam is an endothermic reaction, the atmospheric temperature inside the reaction tube 32 tends to decrease on the upper end side of the reaction tube 32, and the atmospheric temperature inside the reaction tube 32 decreases. There is a possibility that the thermal decomposition reaction is not accelerated and the yield of the water gas is deteriorated.
- a combustion gas supply unit 35 for supplying combustion gas to the combustion gas channel 30a is provided above the main body 31 and combustion is performed from the combustion gas channel 30a.
- a combustion gas discharge portion 36 for discharging gas is provided below the main body portion 31.
- the reaction tube 32 includes a center pipe 32a formed in a cylindrical shape extending along the axis Z, and a carbide that is housed inside and supplied from the upper end. It is characterized by having a thermal decomposition promotion mechanism that accelerates the thermal decomposition reaction of carbide and superheated steam (gasification agent) by guiding the gas from the upper end to the lower end portion 32c step by step.
- the thermal decomposition promoting mechanism is a mechanism including a plurality of first inclined plates 32f, a plurality of second inclined plates 32g, and a plurality of holding rods 32h that hold them.
- the first inclined plate 32f has a first inclined surface that is inclined so as to guide the carbide from one end of the inner peripheral surface 32e of the reaction tube 32 to a first opening 32i provided at the other end.
- the second inclined plate 32g is inclined so as to guide the carbide falling downward from the first opening 32i from the other end of the inner peripheral surface 32e of the reaction tube 32 to the second opening 32j provided at one end.
- the second inclined surface is provided.
- the first inclined plate 32f and the second inclined plate 32g are held so as to be alternately arranged along the axis Z by a plurality of holding bars 32h. Therefore, the carbide falls from the upper end of the reaction tube 32 to the first inclined surface, is guided to the first opening 32i, falls downward, falls to the second inclined surface, and then is guided to the second opening 32j. Repeated stepwise movement of falling downward. As a result, the time during which the carbide stays in the reaction tube 32 becomes longer (for example, 10 seconds to 15 seconds), and accordingly, the thermal decomposition reaction is promoted and the yield of the water gas is improved.
- the thermal solution promoting mechanism including the plurality of first inclined plates 32f, the plurality of second inclined plates 32g, and the plurality of holding structures 32h that hold them is provided from the center pipe 32a. It is preferable that it is detachable. Specifically, the upper end flange 32b and the lower end flange 33a of the reaction tube head 33 are fastened to the reaction tube 32 with fastening bolts 33d. By removing the fastening bolt 33d, the thermal decomposition promotion mechanism can be easily removed from the center pipe 32a. Therefore, the plurality of first inclined plates 32f and the plurality of second inclined plates 32g constituting the thermal decomposition promotion mechanism are connected to these. The plurality of holding rods 32h to be held can be easily washed. By effectively performing such cleaning, the yield of water gas is improved.
- the pyrolysis furnace 30 recovers unreacted carbide (char) discharged from the water gas outlet nozzle 34 of the pyrolysis furnace 30 to the outside to recover the reaction of the pyrolysis furnace 30. It is characterized by including a char recovery device 41 that supplies the pipe head 33 again. By supplying the unreacted carbide recovered by the char recovery device 41 to the reaction tube head 33 again, the yield of the water gas can be further improved.
- the water gas generation system 100 is configured as follows.
- the carbonization furnace 20 partially burns organic waste to generate carbide and combustion gas, and supplies the carbide to the reaction tube head 33 of the pyrolysis furnace 30.
- the carbide supplied to the reaction tube head 33 is supplied into the center pipe 32 a from the upper end side of the center pipe 32 a of the reaction tube 32 together with superheated steam supplied to the reaction tube head 33.
- the combustion gas discharged from the carbonization furnace 20 to the combustion gas flow path 200a is supplied to the combustion gas supply port 35 of the pyrolysis furnace 30 while maintaining a high temperature.
- the combustion gas supplied from the combustion gas supply port 35 to the combustion gas flow path 30a is guided downward while heating the upper end side of the center pipe 32a of the reaction tube 32, and is combusted from the combustion gas discharge port 36 on the lower end side of the center pipe 32a. It is discharged to the channel 200b. Since the inside of the reaction tube 32 is maintained at a high temperature by the combustion gas, the thermal decomposition reaction between the carbide and the superheated steam is promoted therein.
- the combustion gas generated in the carbonization furnace 20 maintains the temperature without exchanging heat with other heat medium, and the pyrolysis furnace. 30. Therefore, compared with the case where the combustion gas whose temperature has decreased due to heat exchange with another heat medium is supplied to the pyrolysis furnace 30, the pyrolysis reaction can be promoted and the yield of the water gas can be improved.
- the combustion gas used for promoting the pyrolysis reaction in the pyrolysis furnace 30 is used as a heat source for the steam superheater 81, and then steam is used. It is used as a heat source for the generator 80.
- the steam superheater 81 generates superheated steam having a temperature equal to or higher than the saturation temperature by heating the saturated steam generated by the steam generator 80 at an equal pressure, and the steam generator 80 is configured to convert water that is liquid. Heating produces saturated water vapor.
- the steam superheater 81 requires a heat source having a temperature higher than that of the steam generator 80, the steam is generated from the liquid water by supplying the combustion gas to the steam generator 80 after the steam superheater 81. It can be heated to produce superheated steam and supplied to the pyrolysis furnace 30 as a gasifying agent. Therefore, by generating superheated steam that has been raised to an appropriate temperature by the steam superheater 90, even if the temperature of the superheated steam decreases in the pyrolysis furnace 30 due to a thermal decomposition reaction (endothermic reaction), the steam is decomposed in the pyrolysis furnace 30. There is an effect that can be prevented from condensing in.
- the combustion gas used for promoting the thermal decomposition reaction in the thermal decomposition furnace 30 can also serve as a heat source for generating superheated steam from water. Used. Therefore, compared with the case where a dedicated heat source is used as a heat source for generating superheated steam, the thermal efficiency of the entire water gas generation system 100 can be improved.
- the combustion gas used as a heat source for generating water vapor by the steam generator 80 is then supplied to the dryer 10 through the combustion gas flow path 200d. It is characterized by that.
- the combustion gas supplied to the dryer 10 is used as a heat source for the steam superheater 81 and the steam generator 80 and has a reduced temperature, it reduces the permanent content of organic waste such as woody biomass. Is at a sufficient temperature. Therefore, compared to the case where a dedicated heat source is used as a heat source for drying organic waste, the thermal efficiency of the entire water gas generation system 100 can be improved.
- the combustion gas discharged from the carbonization furnace 20 is converted into a pyrolysis furnace 30, a steam superheater 81, a steam generator 81, and a dryer. After being used as a heat source of No. 10, it is supplied to the exhaust gas cooling and cleaning device 13.
- the exhaust gas cooling and cleaning device l3 needs to lower the temperature of the combustion gas in order to discharge the combustion gas into the atmosphere, but the temperature of the combustion gas supplied to the exhaust gas cooling and cleaning device 13 dries the organic waste. It is used as a heat source and is in a sufficiently lowered state. Therefore, according to the water gas generation system 100 of one embodiment of the present invention, the exhaust gas cooling and cleaning apparatus 13 can be manufactured at a relatively low cost by reducing the temperature range that the exhaust gas cooling and cleaning apparatus 13 should reduce.
- the thermal efficiency is improved without using a dedicated heat source for generating superheated steam used as a carbide gasifying agent, and in the pyrolysis furnace 30.
- a water gas generation system 100 capable of promoting a pyrolysis reaction can be provided.
- the combustion gas is used as a heat source for drying the organic waste, so that the thermal efficiency of the entire water gas generation system 100 can be improved and the exhaust gas cooling and cleaning device 13 can be manufactured at a relatively low cost. There is also.
- generation system 100 which is one Embodiment of this invention which was shown as one Embodiment of this invention was high, and the temperature of the combustion carbide
- a high-carbonization furnace and a pyrolysis furnace in which the outflow of the heating gas shown in an embodiment of the present invention is suppressed and a pyrolysis reaction proceeds, a higher purity water gas can be obtained.
- the water gas generation system 100 can efficiently generate water gas with high purity, it is possible to construct a hydrogen gas generation system with excellent productivity. it can.
- a conventional system for generating hydrogen gas from water gas since the purity of the water gas is low, equipment for removing impurities or increasing the hydrogen concentration is required for the hydrogen gas generation system (for example, Non-Patent Document 2).
- the hydrogen gas generation system according to an embodiment of the present invention includes the water gas generation system 100 according to an embodiment of the present invention and a general hydrogen purification apparatus 73 that adsorbs impurities. Hydrogen gas can be generated efficiently.
- the water gas generation system 100 can efficiently generate a water gas having a high purity and a constant composition ratio. Can be built. In a conventional system for generating power from water gas, the purity of the water gas is low, so the combustion efficiency is poor and impurities may be removed.
- the power generation system according to one embodiment of the present invention includes the water gas generation system 100 according to one embodiment of the present invention and a general power generation facility 72 that operates by burning water gas. And can generate electricity efficiently.
- a carbonization furnace and a pyrolysis furnace according to the present invention, and a water gas generation system, a hydrogen gas generation system, and a power generation system including these are obtained by directly burning biomass, particularly organic waste derived from biological resources.
- biomass particularly organic waste derived from biological resources.
- the carbonization furnace can be used not only to produce the carbide used in the pyrolysis furnace of the present invention, but also to produce an alternative fuel for coal.
- the pyrolysis furnace is effective not only for pyrolysis of carbides produced by the carbonization furnace of the present invention but also for pyrolysis of carbides produced by various other methods.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Gasification And Melting Of Waste (AREA)
- Processing Of Solid Wastes (AREA)
- Coke Industry (AREA)
Abstract
Description
C+H2O → CO+H2 (1)
CO+H2O → CO2+H2 (2)
その結果、2次燃焼領域R4における可燃性ガスの燃焼効率が悪化し、可燃性ガスを多く含んだままの燃焼ガスが燃焼ガス排出部27から排出されてしまうこととなる。このような可燃性ガスには、凝固してタールとなる成分である高分子炭化水素が含まれているため、可燃性ガスに多量に含まれるタールが凝固して、炭化炉20及びその下流側に設置される機器に損傷を与えるという問題が生じる。
本発明は上述した実施形態に限定されることはなく、その要旨を逸脱しない範囲内において適宜変更することができる。
20 炭化炉
20a 間隙
21 本体部
22 円筒部(筒部)
23 有機廃棄物投入部(投入部)
24 炭化物排出部
24a ターンテーブル(回転体)
24b 駆動部
24c 炭化物排出口(排出口)
24d クリンカクラッシャ
25 1次空気供給部(第1空気供給部)
25a 1次燃焼ファン(送風部)
25b カバー部
25c 空気供給口
25d 閉空間
25e 放熱フィン(加熱部)
26 2次空気供給部(第2空気供給部)
26a 2次燃焼ファン
26b カバー部
26c 空気供給口
26d 閉空間
27 燃焼ガス排出部
28a,28b,28c 温度センサ(温度検出部)
28d レベルセンサ(堆積量検出部)
29 炭化炉制御部(制御部)
30 熱分解炉
30a 燃焼ガス流路(加熱用ガス流路)
31 本体部
32 反応管
32a センターバイプ(筒状部材)
32b 上端フランジ(第3フランジ部)
32c 下端部
32f 第1傾斜板
32g 第2傾斜板
32h 保持棒(保持部)
33 反応管ヘッド(供給部)
33a 下端フランジ(第4フランジ部)
33d 締結ボルト(締結部材)
34 水性ガス出口ノズル(水性ガス出口部)
35 燃焼ガス供給部(加熱用ガス供給部)
36 燃焼ガス排出部(加熱用ガス排出部)
40 減温器
41 チャー回収装置
60 水性ガス冷却装置
70 水性ガスホルダ
80 蒸気発生器
81 蒸気過熱器
82 水供給装置
90 制御装置
100 水性ガス生成システム
102,103,104 水性ガス供給路
200a,200b,200c,200d,200e 燃焼ガス流路
R1 炭化物精錬・冷却領域
R2 1次燃焼領域
R3 原料投入領域
R4 2次燃焼領域
W,X,Y,Z 軸線
Claims (42)
- 軸線に沿って延びる筒状に形成される本体部と、
前記軸線に沿って延びる筒状に形成されるとともに前記本体部の内周面との間に有機廃棄物を炭化させるための間隙を形成する外周面を有する筒部と、
前記間隙へ前記有機廃棄物を投入する投入部と、
前記間隙に堆積する前記有機廃棄物の燃焼用空気を供給する空気供給部と、
前記有機廃棄物の燃焼により生成される燃焼ガスを排出する燃焼ガス排出部と、
前記間隙から前記有機廃棄物が燃焼により炭化した炭化物を排出する炭化物排出部と、
前記有機廃棄物の燃焼条件を制御する炭化炉制御部と
を備えた炭化炉。 - 請求項1に記載の炭化炉において、
前記空気供給部が、
前記間隙に堆積する前記有機廃棄物を部分燃焼させる1次燃焼用空気を供給する第1空気供給部と、前記有機廃棄物の部分燃焼により生成される燃焼ガスに含まれる可燃性ガスを燃焼させる2次燃焼用空気を前記本体部の内部へ供給する第2空気供給部とを備え、
前記本体部が、
前記1次燃焼用空気が供給される第1次燃焼領域の雰囲気の温度を検出する温度検出部を備え、
前記燃焼ガス排出部が、
前記燃焼ガス排出部から排出される燃焼ガスの温度を検出する温度検出部を備え、
前記炭化炉制御部が、
前記本体部に備えられた温度検出部が検出した温度と前記燃焼ガス排出部に備えられた前記温度検出部が検出した温度に応じて、前記第1空気供給部及び前記第2空気供給部の空気供給量を制御する制御部を備えたことを特徴とする炭化炉。 - 請求項2に記載の炭化炉において、
前記空気供給量を制御する制御部が、
前記燃焼ガス排出部に備えられた温度検出部が検出する温度が第1燃焼ガス温度を下回る場合に前記2次燃焼用空気の供給量を減少させることにより前記燃焼ガス排出部から排出される燃焼ガスの温度を前記第1燃焼ガス温度以上に上昇させ、
前記燃焼ガス排出部に備えられた温度検出部が検出する温度が第2燃焼ガス温度を上回る場合には前記2次燃焼用空気の供給量を増加させることにより前記燃焼ガス排出部から排出される燃焼ガスの温度を前記第2燃焼ガス温度以下に低下させる
ことを特徴とする炭化炉。 - 請求項3に記載の炭化炉において、
前記第1燃焼ガス温度が900℃~1200℃であり、前記第2燃焼ガス温度が1100℃~1300℃であることを特徴とする炭化炉。 - 請求項1から講求項4のいずれか1項に記載の炭化炉と、
前記炭化炉が前記有機廃棄物を炭化させることにより生成された前記炭化物をガス化剤により熱分解させて水性ガスを生成する熱分解炉と
を備える水性ガス生成システム。 - 軸線に沿って延びる筒状に形成される本体部と、前記軸線に沿って延びる筒状に形成されると共に前記本体部の内周面との間に有機廃棄物を炭化させるための間隙を形成する外周面を有する筒部と、前記間隙へ前記有機廃棄物を投入する投入部と、前記間隙から前記有機廃棄物が炭化した炭化物を排出する炭化物排出部と、前記間隙に堆積する前記有機廃棄物を部分燃焼させる1次燃焼用空気を供給する第1空気供給部と、前記有機廃棄物の燃焼により生成される燃焼ガスに含まれる可燃性ガスを燃焼させる2次燃焼用空気を前記本体部の内部へ供給する第2空気供給部と、前記有機廃棄物の燃焼により生成される燃焼ガスを外部へ排出する燃焼ガス排出部と、前記有機廃棄物の燃焼条件を制御する炭化炉制御部とを備える炭化炉において、
前記燃焼ガス排出部から排出される前記燃焼ガスの温度を検出する温度検出工程と、
前記温度検出工程が検出する前記燃焼ガスの温度が第1燃焼ガス温度以上となるように前記第2空気供給部が供給する前記2次燃焼用空気の供給量を制御する制御工程と
を備えることを特徴とする炭化炉の制御方法。 - 請求項1に記載の炭化炉において、
前記本体部が、
前記間隙の下端側に堆積する前記炭化物の温度を検出する温度検出部を備え、
前記炭化炉制御部が、
前記温度検出部が検出する前記炭化物の温度に応じて前記炭化物排出部が排出する前記炭化物の排出量を制御する制御部を備える
ことを特徴とする炭化炉。 - 請求項7に記載の炭化炉において、
前記炭化物排出部は、
前記炭化物を排出する排出口と、
前記間隙の下端と対向する位置に設けられるとともに前記軸線回りに回転することにより前記間隙の下端から前記排出口へ前記炭化物を導く回転体と、
前記回転体を前記軸線回りに回転させる駆動部とを有し、
前記炭化物の排出量を制御する制御部は、
前記温度検出部が検出する前記炭化物の温度に応じて、前記駆動部が前記回転体を回転させる回転速度を制御することを特徴とする炭化炉。 - 請求項8に記載の炭化炉において、
前記炭化物の排出量を制御する制御部は、前記温度検出部が検出する前記温度が所定温度より低い場合は第1回転速度で前記回転体を回転させるよう前記駆動部を制御し、前記温度検出部が検出する前記温度が前記所定温度以上である場合は前記第1回転速度より低い第2回転速度で前記回転体を回転させるよう前記駆動部を制御することを特徴とする炭化炉。 - 請求項7から請求項9のいずれか1項に記載の炭化炉と、
前記炭化炉が前記有機廃棄物を炭化させることにより生成された前記炭化物をガス化剤により熱分解させて水性ガスを生成する熱分解炉と
を備える水性ガス生成システム。 - 軸線に沿って延びる筒状に形成される本体部と、前記軸線に沿って延びる筒状に形成されると共に前記本体部の内周面との間に有機廃棄物を炭化させるための間隙を形成する外周面を有する筒部と、前記間隙へ前記有機廃棄物を投入する投入部と、前記間隙から前記有機廃棄物が炭化した炭化物を排出する炭化物排出部と、前記間隙に堆積する前記有機廃棄物の燃焼用空気を供給する空気供給部と、前記有機廃棄物の燃焼により生成される燃焼ガスを外部へ排出する燃焼ガス排出部と、前記有機廃棄物の燃焼条件を制御する炭化炉制御部と、を備える炭化炉において、
前記間隙の下端側に堆積する前記炭化物の温度を検出する温度検出工程と、
前記温度検出工程が検出する前記温度に応じて前記炭化物排出部が排出する前記炭化物の排出量を制御する制御工程と
を備えることを特徴とする炭化炉の制御方法。 - 請求項1に記載の炭化炉において、
前記本体部が、
前記間隙に堆積する前記有機廃棄物の堆績量を検出する堆積量検出部を備え、
前記炭化炉制御部が、
前記堆積量検出部が検出する前記堆積量に応じて前記炭化物排出部が排出する前記炭化物の排出量を制御する制御部を備える
ことを特徴とする炭化炉。 - 請求項12に記載の炭化炉において、
前記炭化物排出部は、
前記炭化物を外部へ排出する排出口と、
前記間隙の下端と対向する位置に設けられるとともに前記軸線回りに回転することにより前記間隙の下端から前記排出口へ前記炭化物を導く回転体と、
前記回転体を前記軸線回りに回転させる駆動部とを有し、
前記制御部は、前記堆積量検出部が検出する前記堆積量に応じて前記駆動部が前記回転体を回転させる回転速度を制御することを特徴とする炭化炉。 - 前記制御部は、前記堆積量検出部が検出する前記堆積量が所定堆積量以上である場合は第1回転速度で前記回転体を回転させるよう前記駆動部を制御し、前記堆積量検出部が検出する前記堆積量が前記所定堆積量以下である場合は前記第1回転速度より低い第2回転速度で前記回転体を回転させるよう前記駆動部を制御することを特徴とする請求項2に記載の炭化炉。
- 請求項12から請求項14のいずれか1項に記載の炭化炉と、
前記炭化炉が前記有機廃棄物を炭化させることにより生成された前記炭化物をガス化剤より熱分解させて水性ガスを生成する熱分解炉と
を備える水性ガス生成システム。 - 軸線に沿って延びる筒状に形成される本体部と、前記軸線に沿って延びる筒状に形成されると共に前記本体部の内周面との間に有機廃棄物を炭化させるための間隙を形成する周面を有する筒部と、前記間隙へ前記有機廃棄物を投入する投入部と、前記間隙から前記有機廃棄物が炭化した炭化物を排出する炭化物排出部と、前記間隙に堆積する前記有機廃棄の燃焼用空気を供給する空気供給部と、前記有機廃棄物の燃焼条件を制御する炭化炉制御部と、を備える炭化炉において、
前記間隙に堆積する前記有機廃棄物の堆積量を検出する堆積量検出工程と、
前記堆積量検出工程が検出する前記堆積量に応じて前記炭化物排出部が外部へ排出する前記炭化物の排出量を制御する制御工程と
を備えることを特徴とする炭化炉の制御方法。 - 請求項1に記載の炭化炉に置いて、
前記空気供給部が、
外部から導入した空気を送風する送風部と、
前記送風部により送風された空気を加熱する加熱部と、
前記加熱部により加熱された空気を前記間隙へ供給する空気供給口と
を備えることを特徴とする炭化炉。 - 請求項17に記載の炭化炉において、
前記間隙の外周側に配置されるとともに前記本体部の前記外周面との間に前記軸線回りに延びる閉空間を形成するカバー部を更に備え、
前記送風部は外部から導入した空気を前記閉空間に送風し、
前記加熱部は前記閉空間に配置されるとともに前記送風部により前記閉空間に供給された空気を加熱し、
前記空気供給口は前記閉空間で前記加熱部により加熱された空気を前記間隙へ供給することを特徴とする炭化炉。 - 請求項18に記載の炭化炉において、
前記加熱部は、前記本体部の前記外周面を介して前記間隙の雰囲気温度が伝熱される伝熱部材を前記空気供給口よりも下方に備えることを特徴とする炭化炉。 - 請求項19に記載の炭化炉において、
前記送風部は、前記間隙の下方の外周側に位置する前記本体部の前記外周面に向けて外部から導入した空気を送風することを特徴とする炭化炉。 - 請求項19または請求項20に記載の炭化炉において、
前記空気供給口が配置される位置における前記本体部の前記内周面から前記外周面までの距離よりも、前記伝熱部材が配置される位置における前記本体部の前記内周面から前記外周面までの距離の方が短いことを特徴とする炭化炉。 - 請求項19から請求項21のいずれか1項に記載の炭化炉において、
前記伝熱部材は前記本体部の前記外周面に接触するとともに前記外周面に沿って前記軸線回りに延びる環状の放熱フィンであり、
前記放熱フィンは前記軸線に沿った複数箇所に設けられていることを特徴とする炭化炉。 - 請求項20または請求項21に記載の炭化炉において、
前記伝熱部材は、前記本体部の前記外周面に接触するとともに前記外周面に沿って前記軸線回りに下方から上方へ向けて旋回する螺旋状の流路を形成する放熱フィンであることを特徴とする炭化炉。 - 請求項17から請求項23のいずれか1項に記載の炭化炉と、
前記炭化炉が前記有機廃棄物を炭化させることにより生成された前記炭化物をガス化剤により熱分解させて水性ガスを生成する熱分解炉と
を備える水性ガス生成システム。 - 軸線に沿って延びる筒状に形成される本体部と、
前記軸線に沿って延びる筒状に形成されるとともに前記本体部の内周面との間に加熱用ガスを流通させるための加熱用ガス流路を形成する外周面を有し、上端部が前記本体部の上面から突出した反応管と、
前記反応管の内部で水性ガスを生成させるために前記反応管の内部へ炭化物とガス化剤とを供給する供給部と、
前記本体部の上方に設けられるとともに前記加熱用ガス流路へ前記加熱用ガスを供給する加熱用ガス供給部と、
前記反応管の下端部に取り付けられるとともに前記反応管の内部で前記炭化物の熱分解反応により生成された水性ガスを外部へ導く水性ガス出口部と、
前記本体部の下方に設けられるとともに前記加熱用ガス流路から前記加熱用ガスを排出する加熱用ガス排出部と、
前記本体部の前記上面の下方に前記上面と接するように設けられるとともに前記反応管の前記外周面と接触する内周面を有しており、前記本体部の上面からの前記加熱用ガスの流出を遮断する第1シール部と、
前記反応管の下端部が前記本体部の底面から突出しており、前記本体部の前記底面の上方に前記底面と接するように設けられるとともに前記反応管の前記外周面と接触する内周面を有しており、前記本体部の底面からの前記加熱用ガスの流出を遮断する第2シール部と、
前記反応管の下端部と前記水性ガス出口部との取付位置において、前記反応管の前記外周面および前記水性ガス出口部の外周面のそれぞれと接触する内周面を有しており、前記取付位置からの前記水性ガスの流出を遮断する第3シール部と
を備える熱分解炉。 - 請求項25に記載の熱分解炉において、
前記本体部の前記上面は上板で構成され、前記本体部の側面の上端には第1フランジ部が設けられており、前記軸線回りの複数箇所で締結部材によって締結されている前記上板と前記第1フランジ部との間に、前記加熱用ガスの流出を遮断する第4シール部と、
前記本体部の前記底面は底板で構成され、前記本体部の側面の下端には第2フランジ部が設けられており、前記軸線回りの複数箇所で締結部材によって締結されている前記底板と前記第2フランジ部との間に、前記加熱用ガスの流出を遮断する第5シール部と、
前記反応管の前記上端部には第3フランジ部が設けられており、前記供給部の下端部には第4フランジ部が設けられており、前記軸線回りの複数筒所で締結部材によって締結されている前記第3フランジ部と前記第4フランジ部との間に、前記水性ガスの流出を遮断する第6シール部と
を更に備えることを特徴とする熱分解炉。 - 有機廃棄物を部分燃焼させて炭化物と燃焼ガスとを生成する炭化炉と、
請求項25または請求項26に記載の熱分解炉であって、前記炭化炉が生成した前記炭化物を前記炭化物とガス化剤の供給部から前記反応管の内部へ供給すると共に、前記加熱用ガスとして前記炭化炉が生成した前記燃焼ガスを前記加熱用ガス供給部から前記加熱用ガス流路へ供給する熱分解炉とを備えることを特徴とする水性ガス生成システム。 - 請求項25または請求項26に記載の熱分解炉において、
前記反応管は、
前記軸線に沿って延びる筒状に形成される筒状部材と、
前記筒状部材の内部に収容されると共に前記上端部から供給される前記炭化物を前記筒状部材の上端側から下端側まで段階的に導いて前記炭化物および前記ガス化剤の熱分解反応を促進させる熱分解促進機構とを備えることを特徴とする熱分解炉。 - 請求項28に記載の熱分解炉において、
前記熱分解促進機構は、
前記炭化物を前記反応管の内周面の一端部から他端部に設けられた第1開口部へ導くように傾斜した第1傾斜面を形成する複数の第1傾斜板と、
前記第1傾斜板によって前記第1開口部から下方へ落下した前記炭化物を前記他端部から前記一端部に設けられた第2開口部へ導くように傾斜した第2傾斜面を形成する複数の第2傾斜板と、
前記軸線に沿って前記第1傾斜板と前記第2傾斜板とが交互に配置されるように、前記複数の第1傾斜板と前記複数の第2傾斜板を保持する保持部とを備えることを特徴とする熱分解炉。 - 請求項29に記載の熱分解炉において、
前記保持部は前記軸線に沿って延びる棒状部材を有し、
前記複数の第1傾斜板及び前記複数の第2傾斜板は前記棒状部材の前記軸線に沿った複数箇所で前記棒状部材に保持されている
ことを特徴とする熱分解炉。 - 請求項28から請求項30のいずれか1項に記載の熱分解炉において、
前記熱分解促進機構は、前記筒状部材から着脱可能となっていることを特徴とする熱分解炉。 - 請求項25、請求項26、請求項28乃至請求項31のうちのいずれか1項に記載の熱分解炉と、
前記熱分解炉の前記水性ガス出口部から排出される未反応の前記炭化物を回収して前記解炉へ再び供給するチャー回収装置と
を備える水性ガス生成システム。 - 有機廃棄物を部分燃焼させて炭化物と燃焼ガスとを生成する炭化炉と、
請求項28から請求項32のいずれか1項に記載の熱分解炉であって、前記炭化炉が生成した前記炭化物を前記炭化物とガス化剤の供給部から前記反応管の内部へ供給すると共に前記加熱用ガスとして前記炭化炉が生成した前記燃焼ガスを前記加熱用ガス流路へ供給する熱分解炉と
を備える水性ガス生成システム。 - 請求項1乃至請求項4、請求項7乃至請求項9、請求項12乃至請求項14、請求項17乃至請求項23のうちのいずれか1項に記載の炭化炉と、
請求項25、請求項26、請求項28乃至請求項31のうちのいずれか1項に記載の熱分解炉であって、前記炭化炉が生成した前記炭化物を前記炭化物とガス化剤の供給部から前記反応管の内部へ供給すると共に前記加熱用ガスとして前記炭化炉が生成した前記燃焼ガスを前記加熱用ガス流路へ供給する熱分解炉と
を備える水性ガス生成システム。 - 請求項34に記載の生成ガス生成システムにおいて、
前記熱分解炉の前記水性ガス出口部から排出される未反応の前記炭化物を回収して前記解炉へ再び供給するチャー回収装置を更に備えることを特徴とする水性ガス生成システム。 - 有機廃棄物を部分燃焼させて炭化物と燃焼ガスとを生成する炭化炉と、
前記炭化炉が生成した前記炭化物を水蒸気とともに前記燃焼ガスにより加熱して水性ガスを生成する熱分解炉と、
前記燃焼ガスにより水を加熱して前記水蒸気を生成する蒸気発生器と、
前記蒸気発生器が生成した前記水蒸気を前記燃焼ガスにより過熱するとともに過熱された前記水蒸気を前記炭化炉へ供給する蒸気過熱器と、
前記有機廃棄物を前記燃焼ガスにより乾燥させるとともに乾燥された前記有機廃棄物を前記炭化炉へ供給する乾燥機と、
前記炭化炉が生成した前記燃焼ガスを前記熱分解炉へ供給し、前記熱分解炉から排出された前記燃焼ガスを前記蒸気過熱器へ供給し、前記蒸気過熱器から排出された前記燃焼ガスを前記蒸気発生器へ供給し、前記蒸気発生器から排出された前記燃焼ガスを前記乾燥機へ供給する燃焼ガス流路と
を備える水性ガス生成システム。 - 請求項36に記載の水性ガス生成システムにおいて、
前記熱分解炉から排出される未反応の前記炭化物を回収して前記熱分解炉へ再び供給するチャー回収装置を更に備えることを特徴とする水性ガス生成システム。 - 請求項36または請求項37に記載の水性ガス生成システムにおいて、
前記乾燥機から排出される前記燃焼ガスを前記乾燥機から排出される前記燃焼ガスから有害物質を除去して無害化する排ガス冷却洗浄装置へ供給する燃焼ガス流路を更に備えることを特徴とする水性ガス生成システム。 - 有機廃棄物を部分燃焼させて炭化物と燃焼ガスとを生成する炭化炉と、前記炭化炉が生成した前記炭化物を水蒸気とともに前記燃焼ガスにより加熱して水性ガスを生成する熱分解炉と、前記燃焼ガスにより水を加熱して前記水蒸気を生成する蒸気発生器と、前記蒸気発生器が生成した前記水蒸気を前記燃焼ガスにより過熱するとともに過熱された前記水蒸気を前記炭化炉へ供給する蒸気過熱器と、前記有機廃棄物を前記燃焼ガスにより乾燥させるとともに乾燥された前記有機廃棄物を前記炭化炉へ供給する乾燥機とを備える水性ガス生成システムにおいて、
前記炭化炉が生成した前記燃焼ガスを前記熱分解炉に供給する第1工程と、
前記熱分解炉から排出された前記燃焼ガスを前記蒸気過熱器へ供給する第2工程と、
前記蒸気過熱器から排出された前記燃焼ガスを前記蒸気発生器へ供給する第3工程と、
前記蒸気発生器から排出された前記燃焼ガスを前記乾操機へ供給する第4工程と
を備える水性ガス生成システムの燃焼ガス供給方法。 - 請求項39に記載の水性ガス生成システムの燃焼ガス供給方法において、
前記乾燥機から排出された前記燃焼ガスを排ガス冷却洗浄装置へ供給する第5工程を更に備えることを特徴とする水性ガス生成システムの燃焼ガス供給方法。 - 請求項5、請求項10、請求項15、請求項24、請求項27、請求項32乃至請求項38のうちのいずれか1項に記載の水性ガス生成システムにおいて、
水素精製装置を更に備えたことを特徴とする水素ガス生成システム。 - 請求項5、請求項10、請求項15、請求項24、請求項27、請求項32乃至請求項38のうちのいずれか1項に記載の水性ガス生成システムと、
発電設備と
を備えた発電システム。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/538,408 US10618088B2 (en) | 2014-12-24 | 2015-12-18 | Pyrolytic furnace, water gas generation system, and combustion gas supply method for water gas generation system |
JP2016566315A JP6824745B2 (ja) | 2014-12-24 | 2015-12-18 | 炭化炉及び熱分解炉、並びに、水性ガス生成システム、水素ガス生成システム、及び、発電システム |
EP15872939.2A EP3239274B1 (en) | 2014-12-24 | 2015-12-18 | Water gas generation system and method for supplying combustion gas to said system |
CA2971688A CA2971688C (en) | 2014-12-24 | 2015-12-18 | Pyrolytic furnace, water gas generation system, and combustion gas supply method for water gas generation system |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014261403 | 2014-12-24 | ||
JP2014-261403 | 2014-12-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016104371A1 true WO2016104371A1 (ja) | 2016-06-30 |
Family
ID=56150390
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2015/085517 WO2016104371A1 (ja) | 2014-12-24 | 2015-12-18 | 炭化炉及び熱分解炉、並びに、水性ガス生成システム、水素ガス生成システム、及び、発電システム |
Country Status (5)
Country | Link |
---|---|
US (1) | US10618088B2 (ja) |
EP (1) | EP3239274B1 (ja) |
JP (1) | JP6824745B2 (ja) |
CA (1) | CA2971688C (ja) |
WO (1) | WO2016104371A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107603677A (zh) * | 2017-11-07 | 2018-01-19 | 山东京博众诚清洁能源有限公司 | 一种煤气生产设备及其安全开炉方法 |
CN109207176A (zh) * | 2017-06-29 | 2019-01-15 | 神华集团有限责任公司 | 热解装置、热解系统和热解方法 |
CN110072854A (zh) * | 2016-12-26 | 2019-07-30 | 日本瑞翁株式会社 | 聚合性化合物、混合物、高分子、光学膜、光学各向异性体、偏振片、显示装置以及防反射膜 |
KR102174941B1 (ko) * | 2020-02-27 | 2020-11-05 | 주식회사 솔벡 | 유기성폐기물류의 비연소 연속 가열식 수소 및 카본 자원화장치 및 이를 이용한 자원화방법 |
CN114181722A (zh) * | 2021-12-09 | 2022-03-15 | 中国科学院青岛生物能源与过程研究所 | 一种多源固废协同热处理装置及方法 |
US11725155B2 (en) | 2019-10-03 | 2023-08-15 | Street Design Corporation | Organic material gasification system, and carbonization furnace and gasification furnace used therefor |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10906844B2 (en) * | 2016-01-18 | 2021-02-02 | Anaconda Systems Limited | Composting apparatus and process of use thereof |
WO2018068127A1 (en) * | 2016-10-12 | 2018-04-19 | Anaconda Systems Limited | Composting apparatus usable in an industrial scale and process of use thereof |
CN108676573A (zh) * | 2018-05-22 | 2018-10-19 | 中蓝能源(深圳)有限公司 | 环保氢炭无人全自动智能生产设备 |
CN109266370B (zh) * | 2018-08-16 | 2020-12-15 | 武汉光谷蓝焰新能源股份有限公司 | 一种渐进式生物质高效节能热解炉 |
CN109838569B (zh) * | 2019-03-27 | 2023-10-03 | 湖南野百和科技有限公司 | 一种防止物料漏出的水封器 |
CN113993977A (zh) | 2019-05-24 | 2022-01-28 | 伊士曼化工公司 | 进入气体裂化器中加工的液体流中混入少量热解油 |
US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
KR20220093368A (ko) | 2019-11-07 | 2022-07-05 | 이스트만 케미칼 컴파니 | 재활용물 알파 올레핀 및 지방 알코올 |
CN111188594B (zh) * | 2020-02-22 | 2021-11-19 | 太原理工大学 | 一种老空区煤泥水气液流态化开采的装置及方法 |
KR20230004607A (ko) * | 2020-04-13 | 2023-01-06 | 이스트만 케미칼 컴파니 | 재활용물 수소 |
CN112029534B (zh) * | 2020-08-17 | 2021-08-03 | 赵明星 | 一种固体垃圾气化发电方法 |
SE2200133A1 (sv) * | 2022-04-06 | 2023-10-07 | Mats Hedman | Gengasaggregat för väteproduktion |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53128572A (en) * | 1977-04-13 | 1978-11-09 | Tenenge Desenvolvimento & Eng | Treatment of solid matter* especially apparatus for continuous treatment appliied to gasification of coal and schist or direct reduction of iron ore |
JP2001235133A (ja) * | 2000-02-23 | 2001-08-31 | Nippon Steel Corp | 有機系廃棄物の縦型自燃式炭化炉の操業方法 |
JP2002038165A (ja) * | 2000-07-21 | 2002-02-06 | Japan Science & Technology Corp | 湿潤燃料ガス化システム及びガス化方法 |
JP2006152193A (ja) * | 2004-12-01 | 2006-06-15 | Meidensha Corp | ガス化処理方法とその装置 |
JP2008208276A (ja) * | 2007-02-27 | 2008-09-11 | Mitsubishi Heavy Ind Ltd | 有機燃料ガス化液体燃料製造システム |
JP2009270050A (ja) * | 2008-05-09 | 2009-11-19 | Azuma Sansho:Kk | 炭化炉 |
WO2010049786A2 (en) * | 2008-10-28 | 2010-05-06 | Ansaldo Energia S.P.A. | Gasifier and method for ignition of said gasifier |
JP2013185093A (ja) * | 2012-03-08 | 2013-09-19 | Mitsuyuki Iijima | 熱分解ガス化装置 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5150657A (en) | 1974-10-30 | 1976-05-04 | Hitachi Ltd | Handotaisochino seizohoho |
JPS5934067B2 (ja) | 1976-09-30 | 1984-08-20 | 日本電気株式会社 | サイリスタゲ−トトリガパルス増幅回路 |
US4264435A (en) * | 1978-04-05 | 1981-04-28 | The Dow Chemical Company | Crude oil cracking using partial combustion gases |
US4412910A (en) * | 1981-10-21 | 1983-11-01 | Westinghouse Electric Corp. | Recovery of fuel from oil shale |
US4497637A (en) * | 1982-11-22 | 1985-02-05 | Georgia Tech Research Institute | Thermochemical conversion of biomass to syngas via an entrained pyrolysis/gasification process |
DE19618213A1 (de) * | 1996-05-07 | 1997-11-13 | Petersen Hugo Verfahrenstech | Verfahren zur Erzeugung von Brenngas und Anlage zur Durchführung des Verfahrens |
US7658776B1 (en) * | 1999-08-25 | 2010-02-09 | Pearson Larry E | Biomass reactor for producing gas |
JP4633216B2 (ja) | 2000-01-11 | 2011-02-16 | 巴工業株式会社 | スクリュー式炭化炉による炭化方法 |
WO2001051587A1 (fr) * | 2000-01-14 | 2001-07-19 | Ryoichi Okamoto | Dispositif de distillation seche/de reduction de volume pour dechets |
CA2501841C (en) * | 2004-03-23 | 2012-07-10 | Central Research Institute Of Electric Power Industry | Carbonization and gasification of biomass and power generation system |
JP5366147B2 (ja) * | 2008-02-05 | 2013-12-11 | 一般財団法人電力中央研究所 | 燃料ガス精製設備、発電システム及び燃料合成システム |
US8353973B2 (en) * | 2008-05-15 | 2013-01-15 | Tharpe Jr Johnny M | Apparatus, system, and method for producing bio-fuel utilizing concentric-chambered pyrolysis |
WO2011140401A2 (en) * | 2010-05-05 | 2011-11-10 | Eci Research Development Company | Method and apparatus for continuous production of carbonaceous pyrolysis by-products |
CN101906325B (zh) | 2010-07-20 | 2013-09-04 | 阳光凯迪新能源集团有限公司 | 生物质低温裂解高温气化工艺及其设备 |
ITMI20112011A1 (it) * | 2011-11-04 | 2013-05-05 | Ansaldo Energia Spa | Impianto e metodo per il recupero di energia da biomasse, in particolare da biomasse vegetali |
JP6597950B2 (ja) | 2013-07-24 | 2019-10-30 | 日本電気硝子株式会社 | 強化ガラス及び強化用ガラス |
JP5917735B2 (ja) | 2014-02-10 | 2016-05-18 | 株式会社高橋製作所 | バイオマス発電システム |
-
2015
- 2015-12-18 EP EP15872939.2A patent/EP3239274B1/en active Active
- 2015-12-18 CA CA2971688A patent/CA2971688C/en active Active
- 2015-12-18 US US15/538,408 patent/US10618088B2/en active Active
- 2015-12-18 WO PCT/JP2015/085517 patent/WO2016104371A1/ja active Application Filing
- 2015-12-18 JP JP2016566315A patent/JP6824745B2/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53128572A (en) * | 1977-04-13 | 1978-11-09 | Tenenge Desenvolvimento & Eng | Treatment of solid matter* especially apparatus for continuous treatment appliied to gasification of coal and schist or direct reduction of iron ore |
JP2001235133A (ja) * | 2000-02-23 | 2001-08-31 | Nippon Steel Corp | 有機系廃棄物の縦型自燃式炭化炉の操業方法 |
JP2002038165A (ja) * | 2000-07-21 | 2002-02-06 | Japan Science & Technology Corp | 湿潤燃料ガス化システム及びガス化方法 |
JP2006152193A (ja) * | 2004-12-01 | 2006-06-15 | Meidensha Corp | ガス化処理方法とその装置 |
JP2008208276A (ja) * | 2007-02-27 | 2008-09-11 | Mitsubishi Heavy Ind Ltd | 有機燃料ガス化液体燃料製造システム |
JP2009270050A (ja) * | 2008-05-09 | 2009-11-19 | Azuma Sansho:Kk | 炭化炉 |
WO2010049786A2 (en) * | 2008-10-28 | 2010-05-06 | Ansaldo Energia S.P.A. | Gasifier and method for ignition of said gasifier |
JP2013185093A (ja) * | 2012-03-08 | 2013-09-19 | Mitsuyuki Iijima | 熱分解ガス化装置 |
Non-Patent Citations (2)
Title |
---|
BIOMASS KARA NO KITAI NENRYO SEIZO TO SONO ENERGY RIYO, 5 October 2007 (2007-10-05), pages 80 - 83, XP009504183 * |
See also references of EP3239274A4 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110072854A (zh) * | 2016-12-26 | 2019-07-30 | 日本瑞翁株式会社 | 聚合性化合物、混合物、高分子、光学膜、光学各向异性体、偏振片、显示装置以及防反射膜 |
CN109207176A (zh) * | 2017-06-29 | 2019-01-15 | 神华集团有限责任公司 | 热解装置、热解系统和热解方法 |
CN109207176B (zh) * | 2017-06-29 | 2020-11-24 | 神华集团有限责任公司 | 热解装置、热解系统和热解方法 |
CN107603677A (zh) * | 2017-11-07 | 2018-01-19 | 山东京博众诚清洁能源有限公司 | 一种煤气生产设备及其安全开炉方法 |
CN107603677B (zh) * | 2017-11-07 | 2020-11-20 | 山东京博众诚清洁能源有限公司 | 一种煤气生产设备及其安全开炉方法 |
US11725155B2 (en) | 2019-10-03 | 2023-08-15 | Street Design Corporation | Organic material gasification system, and carbonization furnace and gasification furnace used therefor |
KR102174941B1 (ko) * | 2020-02-27 | 2020-11-05 | 주식회사 솔벡 | 유기성폐기물류의 비연소 연속 가열식 수소 및 카본 자원화장치 및 이를 이용한 자원화방법 |
CN114181722A (zh) * | 2021-12-09 | 2022-03-15 | 中国科学院青岛生物能源与过程研究所 | 一种多源固废协同热处理装置及方法 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2016104371A1 (ja) | 2017-12-21 |
EP3239274B1 (en) | 2020-06-24 |
CA2971688A1 (en) | 2016-06-30 |
US10618088B2 (en) | 2020-04-14 |
US20170348741A1 (en) | 2017-12-07 |
EP3239274A1 (en) | 2017-11-01 |
JP6824745B2 (ja) | 2021-02-03 |
EP3239274A4 (en) | 2018-08-08 |
CA2971688C (en) | 2020-06-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6824745B2 (ja) | 炭化炉及び熱分解炉、並びに、水性ガス生成システム、水素ガス生成システム、及び、発電システム | |
CN102359729B (zh) | 利用城市垃圾高温气化联合循环发电的方法及其系统 | |
JP6759492B2 (ja) | 炭化物製造装置、炭化物製造方法、および炭化物製造システム | |
EA022238B1 (ru) | Способ и система для производства чистого горячего газа на основе твердых топлив | |
EA023478B1 (ru) | Система утилизации отходов | |
JP2010077260A (ja) | 廃棄物をガス化する可燃ガス生成装置および可燃ガス製造方法 | |
CN101611123A (zh) | 燃料气化设备 | |
JP2016121257A (ja) | 水性ガス生成システムおよび水性ガス生成システムの燃焼ガス供給方法 | |
RU2668447C1 (ru) | Способ газификации твердого топлива и устройство для его осуществления | |
JP6170579B1 (ja) | バイオマス発電システムおよび熱分解炉のリターンシステム | |
JP6886242B2 (ja) | 水素供給システム | |
JP6642924B2 (ja) | 水素ステーションシステム | |
JP2009174392A (ja) | バイオマスガス化ガス発電システム | |
JP2003279013A (ja) | 廃棄物ガス化溶融システム | |
JP2016121256A (ja) | 熱分解炉および水性ガス生成システム | |
JP2016121255A (ja) | 炭化炉および水性ガス生成システム | |
JP2016121252A (ja) | 炭化炉、水性ガス生成システム、および炭化炉の制御方法 | |
JP2011220543A (ja) | ボイラ設備 | |
JP2016169341A (ja) | バイオマスガス化システム及びこれを用いるボイラ設備 | |
JP2004002552A (ja) | 廃棄物ガス化方法、廃棄物ガス化装置及びそれを用いた廃棄物処理装置 | |
JP2016121254A (ja) | 炭化炉、水性ガス生成システム、および炭化炉の制御方法 | |
JP2016121253A (ja) | 炭化炉、水性ガス生成システム、および炭化炉の制御方法 | |
JP5512200B2 (ja) | 高効率乾留炉およびガス化剤の調整方法 | |
JP2011089672A (ja) | 廃棄物溶融処理方法 | |
JP2017014474A (ja) | 連続式熱化学型バイオマス原料ガス化装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 15872939 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2971688 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15538408 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2016566315 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REEP | Request for entry into the european phase |
Ref document number: 2015872939 Country of ref document: EP |