WO2016084335A1 - 電縫鋼管およびその製造方法 - Google Patents
電縫鋼管およびその製造方法 Download PDFInfo
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- WO2016084335A1 WO2016084335A1 PCT/JP2015/005716 JP2015005716W WO2016084335A1 WO 2016084335 A1 WO2016084335 A1 WO 2016084335A1 JP 2015005716 W JP2015005716 W JP 2015005716W WO 2016084335 A1 WO2016084335 A1 WO 2016084335A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B23/00—Tube-rolling not restricted to methods provided for in only one of groups B21B17/00, B21B19/00, B21B21/00, e.g. combined processes planetary tube rolling, auxiliary arrangements, e.g. lubricating, special tube blanks, continuous casting combined with tube rolling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- B21C37/08—Making tubes with welded or soldered seams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C51/00—Measuring, gauging, indicating, counting, or marking devices specially adapted for use in the production or manipulation of material in accordance with subclasses B21B - B21F
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K11/00—Resistance welding; Severing by resistance heating
- B23K11/08—Seam welding not restricted to one of the preceding subgroups
- B23K11/087—Seam welding not restricted to one of the preceding subgroups for rectilinear seams
- B23K11/0873—Seam welding not restricted to one of the preceding subgroups for rectilinear seams of the longitudinal seam of tubes
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/50—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for welded joints
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/17—Rigid pipes obtained by bending a sheet longitudinally and connecting the edges
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/04—Tubular or hollow articles
- B23K2101/06—Tubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
Definitions
- the present invention relates to an electric resistance welded pipe and a method for manufacturing the same, and more particularly to an improvement in toughness and reliability in an electric resistance welded portion.
- An electric resistance steel pipe is formed by continuously cold-forming a steel strip into a substantially circular cross section (tubular body) with a plurality of rolls, butting the opposite end faces of the tubular body together, and applying a high-frequency current to the abutted part (butting part) Is applied and welded (electrically welded) while applying pressure to form a tubular body (electrically welded steel pipe) having a seam portion.
- the butt portion is heated to a temperature higher than the melting point by resistance heat generation and pressure is applied, and the steel strip itself becomes the joining metal and is joined. For this reason, electric resistance welding is substantially positioned as fusion welding.
- Patent Document 1 describes an ERW steel pipe having high crack resistance and excellent sour resistance in an environment containing wet hydrogen sulfide.
- the Ca / Al ratio in the steel is set to 0.10% or less.
- the inclusions are stretched in the plate thickness direction as the shape of the inclusion viewed in a cross section perpendicular to the abutting surface and perpendicular to the tube axis direction
- the inclusions having a ratio of the length in the plate thickness direction to the length in the circumferential direction of 2 or more and a length of 10 ⁇ m or more in the transverse section are within the region of 100 ⁇ m on both sides of the abutting surface in the transverse section.
- the number per 1 mm 2 of the area is 5 or less.
- Patent Document 2 describes a gas seal welding method for an electric resistance welded steel pipe.
- the floating scale on the pipe inner surface side is washed with mist, and the pipe inner surface side sealing device is used for the local sealing of the welded portion except for the holding roller, It is characterized by sealing as non-contact.
- the scale remains in the welded portion, and the toughness of the welded portion is markedly improved.
- Patent Document 3 describes a high-strength electric seam line pipe.
- the high-strength ERW line pipe described in Patent Document 3 is in mass%, C: more than 0.04 to 0.08%, Si: 0.1 to 0.3%, Mn: more than 1.6 to 2 0.0%, P: 0.02% or less, S: 0.003% or less, Nb: 0.04-0.08%, V: 0.05-0.1%, Ni: 0.1-0.
- the composition includes Ni, Cu, and Mo so as to satisfy a specific relationship, and the metal structure is an acicular ferrite structure having an average crystal grain size of 5 ⁇ m or less, and the tensile strength in the circumferential direction after flattening Is 700 N / mm 2 or more, 0.5% proof stress is 550 N / mm 2 or more, and the oxide occupation area of the ERW welding contact portion is 0.1% (corresponding to 1000 ppm)
- a high-strength ERW line pipe is as follows.
- the electric seam line pipe described in Patent Document 3 is manufactured from hot coil through cold roll forming, electric seam welding, seam heat treatment, sizer process, outer diameter 200-610mm, wall thickness / outer This is an ERW steel pipe having a diameter ratio (t / D) of 2% or less. According to this, the electric-welded welded portion has soundness similar to that of the base material, and the line pipe can be further thinned.
- Patent Document 4 describes an electric seam boiler steel pipe.
- the electric-resistance-welded boiler steel pipe described in Patent Document 4 is, in mass%, C: 0.01 to 0.20%, Si: 0.01 to 1.0%, Mn: 0.10 to 2.0%, Cr: 0.5 to 3.5%, P: 0.030% or less, S: 0.010% or less, O: 0.020% or less, (Si%) / (Mn% + Cr %) Is 0.005 or more and 1.5 or less, and the area ratio of the ternary mixed oxide of SiO 2 , MnO, and Cr 2 O 3 generated during the electric resistance welding is 0.1% (corresponding to 1000 ppm) or less.
- This is an electric-welded boiler steel pipe consisting of an electric-welded welded portion with few defects in the electric-welded welded portion and excellent in creep rupture strength and toughness.
- Non-Patent Document 1 In electro-welding welding, the butt portion (steel strip end) of the tubular body is sufficiently melted to form a droplet and press-contacted under conditions that provide optimum welding heat input. However, when the amount of heat input becomes low, the liquid droplets are pressed without being sufficiently formed. Therefore, as shown in FIG. 1A of Non-Patent Document 1, when the welded portion is destroyed along the welded surface, a large number of oxides are formed on the welded surface in a welded portion welded under a low heat input condition. Is observed. A weld where a large number of oxides are observed on the fracture surface is generally referred to as cold welding (also referred to as cold weld or cold joint). The weld shown in Non-Patent Document 1 is a high-frequency weld, but even in high-frequency welding with small fluctuations in heat input, it means that cold welding (welding defects) may be formed depending on the welding conditions. ing.
- Patent Document 1 has a problem that it is impossible to avoid the occurrence of cold welding caused by a local decrease in heat input.
- the technique described in Patent Document 1 is difficult to apply to high-strength steel, and has low temperature toughness, which is problematic for application in cold districts.
- each technique described in Patent Documents 2, 3, and 4 has a problem that the occurrence of cold welding caused by a local decrease in heat input cannot be avoided.
- the present invention solves the problems of the prior art, avoids the occurrence of welding defects such as cold welding, and has a high strength ERW steel pipe having excellent internal pressure leakage resistance and excellent ERW weld toughness and its manufacture It aims to provide a method.
- high strength here means a case where the base material part of the ERW steel pipe is equivalent to API X 56 Great, that is, the yield strength YS: 400 MPa or more.
- excellent in internal pressure leak resistance means that an internal pressure test was performed under the condition that the test temperature was 0 ° C. and an internal pressure of 95% of the yield strength ( ⁇ y RT ) at normal temperature was loaded. It means that no leak occurs. It should be noted that the internal pressure test was performed in a non-patent document (S. Toyoda, S. Goto, T. Okabe, H. Kimura, S. Igi, Y. Matsui, S. Yabumoto, A. Sato, M. Suzuki, and T. Inoue. : Proc. Of IPC (2012), IPC2012-90448.) The pipe body is held in a refrigerant held at a predetermined temperature (0 ° C.
- a steel pipe having a length eight times the outer diameter is held in a refrigerant (ethanol) cooled to a predetermined temperature, and gas (atmosphere) is blown from both sealed ends of the steel pipe to a predetermined pressure. To determine whether there is a leak or breakage.
- ethanol refrigerant
- gas atmosphere
- excellent toughness in ERW welds means that the absorbed energy vE at ⁇ 60 ° C. in the Charpy impact test conducted in accordance with the provisions of JIS Z 2242 in ERW welds.
- the test temperature of the CTOD test conducted in accordance with the provisions of BS 7448-1995 is ⁇ 60 is 110 J or more, and the CTOD value at 0 ° C. is 0.80 mm or more.
- the present inventors diligently studied various factors affecting the internal pressure leakage resistance and the ERW weld toughness. As a result, it is important to improve the reliability of ERW welds by preventing weld defects, especially cold welding, in ERW welds, and strengthening quality control of ERW welds. I thought.
- the inventors focused on corona bond during spot welding of a thin plate as a phenomenon similar to cold welding in electric seam welding, and compared cold welding with corona bond in electric seam welding.
- Corona bond in spot welding of a thin plate refers to the crimped part around the nugget (molten pool). Coronabond is formed by pressing the upper and lower plates and heating them for a short time during spot welding. It is known that small fractured oxides are scattered on the fracture surface of coronabond. ing. On the other hand, at the time of ERW welding, the end faces of the steel strips (steel plates) to be abutted are preheated by a high frequency current. For this reason, it is considered that more oxide is formed at the time of ERW welding than at the time of spot welding.
- cold welding in ERW welding is “the temperature at the end of the steel strip (steel plate) decreases due to a decrease in heat input, the fluidity of the molten steel decreases, and is generated during heating. It was thought that this was a welding defect in which the oxidized oxide was not completely discharged and remained in the weld joint (seam portion). It has been thought that the prevention of the occurrence of such cold welding results in two points: suppression of generation and remaining of oxide during heating, and improvement of detection sensitivity of generated and remaining oxide.
- the obtained electric resistance welded steel pipe is an ultrasonic flaw detector (hereinafter, also referred to as “high-sensitivity array UT”) using an array flaw detector 6 arranged in the circumferential direction of the pipe. ), And investigated the soundness of ERW welds, especially the presence or absence of cold welding.
- the frequency of the used ultrasonic wave was 18 MHz, and the wave width on the welding surface of the seam (electric seam welded portion) 2 was transmitted so that the beam width was 1.5 mm.
- the position of the transmitting and receiving transducers can be electronically switched to scan the welded portion in the thickness direction, and the thickness cross section of the welded portion is flawed along the longitudinal direction of the pipe. Is possible.
- the seam of the ERW welded portion is tapered, and the welding heat input is changed from 1.1 to 0.75 with the normal heat input as the standard, and the ERW welding of API 5L X80 standard is performed.
- a steel pipe (outer diameter 660.4 mm ⁇ ⁇ thickness 25.4 mm) was prepared, and similarly, using “high-sensitivity array UT”, the soundness of the ERW welded part, particularly the presence or absence of cold welding was investigated.
- the welding heat input was within the control range of 1.1 to 0.9 based on normal, no significant increase in echo height was observed.
- an increase in echo height was observed when the welding heat input decreased and the control range was 0.8.
- the Fe (Si, Mn) type oxide formed at the time of ERW welding was observed in the portion where the echo height increased. Further, when the welding heat input decreases and becomes 0.75 below the control range, an increase in the echo height is continuously observed, and a coarse oxide layer is formed in the portion where the echo height is increased. It was. Thus, it was confirmed that the welding heat input amount, the echo height, and the oxide correspond to each other even in the case of an electric resistance welded pipe having a thick wall and having a groove.
- the present inventors have suppressed the formation of oxides in the ERW welds, and in order to ensure excellent ERW weld toughness and excellent internal pressure leakage resistance, oxides are added to the ERW welds.
- the content of elements such as C, Si, Mn, etc. that are likely to remain, for example, needs to be adjusted within an appropriate range, and the composition of the ERW steel pipe is C: 0.025 to 0.168 in mass%. %, Si: 0.10 to 0.30%, Mn: 0.60 to 1.90%, P: 0.001 to 0.018%, S: 0.0001 to 0.0029%, Al: 0.0.
- the present invention has been completed based on such findings and further studies. That is, the gist of the present invention is as follows. [1] By mass% C: 0.025 to 0.168%, Si: 0.10 to 0.30%, Mn: 0.60 to 1.90%, P: 0.001 to 0.018%, S: 0.0001 to 0.0029%, Al: 0.010 to 0.10%, Ca: 0.0001 to 0.0035%, N: 0.0050% or less, O: 0.0030% or less, Further, one or more selected from Nb: 0.001 to 0.070%, V: 0.001 to 0.065%, Ti: 0.001 to 0.033%, 1) Pcm defined by the formula is included so as to satisfy 0.20 or less, and has a composition consisting of the balance Fe and unavoidable impurities, Both the base metal part and the ERW welded part have a pseudopolygonal ferrite phase with a volume ratio of 90% or more and an average particle size of 10 ⁇ m or less as the main phase, and
- the yield strength YS has a base material part of 400 MPa or more
- the internal pressure test performed under the conditions that the CTOD value at 0 ° C. has an electric resistance welded portion toughness of 0.80 mm or more, and the test temperature is 0 ° C., the internal pressure is 0.95 ⁇ (room temperature yield strength ⁇ y RT ), ERW steel pipe that does not leak.
- Pcm C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B (1)
- C, Si, Mn, Cu, Ni, Cr, Mo, V, B Content (mass%) of each element, and elements not contained are 0.
- Cu may be selected from 0.001 to 0.350%, Ni: 0.001 to 0.350%, and Mo: 0.001 to 0.350% by mass%.
- the tubular body is formed with a squeeze roll.
- the end face parts of the pipes are butted together and subjected to electro-resistance welding by high-frequency heating to form a tubular body, and then the welded steel pipe is inspected for the welded surface in the axial direction of the electro-welded portion of the tubular body
- the steel pipe material is, by mass%, C: 0.025 to 0.168%, Si: 0.10 to 0.30%, Mn: 0.60 to 1.90%, P: 0.001 to 0.018%, S: 0.0001 to 0.0029%, Al: 0.010 to 0.10%, Ca: 0.0001 to 0.0035%, N: 0.0050% or less, O: 0.0030% or less, Further, one or more selected from Nb: 0.001 to 0.070%, V: 0.001 to 0.065%, Ti: 0.001 to 0.033%, 1) Pcm defined by the formula is included so as to satisfy 0.20 or less, and has a composition composed of the balance Fe and inevitable impurities,
- the steel pipe material is a hot-rolled steel
- the groove When forming a groove on the end surface in the width direction of the hot-rolled steel sheet by forming with the fin pass roll, the groove is a tapered groove.
- the groove from the taper start position of the taper groove to the pipe surface is a groove having a total ratio of the distance from the outer surface of the pipe and the distance from the inner surface of the pipe to a thickness of 10 to 80% in terms of the steel sheet thickness,
- ultrasonic waves are transmitted so that the beam width is in the range of 0.1 mm to 4.0 mm with respect to the welded surface in the tube axial direction of the electro-welded welded portion of the tube, and reflection from the welded surface is performed.
- an inspection is performed to confirm that there are no more than a predetermined amount of non-metallic parts in the electro-welded welded part of the tube.
- the electric resistance welded portion of the tube obtained by the electric resistance welding is heated to a heating temperature of 850 to 1150 ° C., and an average cooling is performed in the range of 780 to 630 ° C. at the temperature of the thickness center portion.
- Test temperature of Charpy impact test conducted in accordance with the provisions of JIS Z 2242 Test temperature of CTOD test conducted in accordance with the provisions of BS 7448-1995 when the absorbed energy vE- 60 at ⁇ 60 ° C. is 110 J or more
- the internal pressure test performed under the conditions that the CTOD value at 0 ° C. has an electric resistance welded portion toughness of 0.80 mm or more, and the test temperature is 0 ° C., the internal pressure is 0.95 ⁇ (room temperature yield strength ⁇ y RT ), A method for producing an electric resistance welded steel pipe that does not cause leakage.
- the present invention is a high-strength electric resistance welded steel pipe that avoids occurrence of welding defects such as cold welding and has excellent internal pressure leak resistance and excellent electric resistance welded portion toughness, and a method for manufacturing the same.
- FIG. 1 is an explanatory view showing a comparison of echo height mapping of the longitudinal section of the welded part of each ERW steel pipe.
- FIG. 2 is a photomicrograph of an optical microscope showing a cross-sectional structure of an ERW weld with increased echo height.
- FIG. 3 is an explanatory view showing an outline of a flaw detection method using an ultrasonic flaw detector for a welded portion using an array flaw detector.
- FIG. 4 is a schematic diagram illustrating a tapered groove. The distance from the taper start position to the tube surface is indicated by a (tube outer surface side) and b (tube inner surface side). The distance from the taper start position to the tube surface is determined along the thickness direction.
- the ERW steel pipe of the present invention is a high-strength ERW steel pipe having a yield strength YS: 400 MPa or more in the pipe axis direction, avoids the occurrence of welding defects such as cold welding, and has excellent internal pressure leakage resistance and excellent electrical resistance.
- This is an ERW steel pipe having a sewn weld zone toughness and a highly reliable ERW weld zone.
- the electric resistance welded steel pipe of the present invention has a test temperature of Charpy impact test conducted in accordance with the provisions of JIS Z 2242: Absorbed energy vE- 60 at ⁇ 60 ° C. is 110 J or more, and conforms to the provisions of BS 7448-1995.
- the test temperature of the CTOD test conducted as described above The CTOD value at 0 ° C. is 0.80 mm or more, and has excellent ERW weld toughness. Needless to say, the base material toughness also has the toughness described above. Moreover, the electric resistance welded steel pipe of the present invention has excellent internal pressure leak resistance that does not cause a leak in an internal pressure test performed under the conditions of a test temperature: 0 ° C. and an internal pressure: 0.95 ⁇ (room temperature yield strength ⁇ y RT ).
- the electric resistance welded steel pipe is a squeeze roll after forming a tubular body by cold forming continuously by a forming mill in which a plurality of cage rolls and fin pass rolls are continuously arranged on a steel pipe material.
- the end surfaces of the tubular body are butted against each other, and the butted portion is heated and melted by high-frequency heating and melted to form a tubular body by electro-welding, and then welded in the axial direction of the electro-welded welded portion of the tubular body
- the surface is inspected to make a product pipe.
- the pipe axis direction welding surface is a surface parallel to the pipe axis direction and at a central position in the pipe circumferential direction.
- the steel pipe material used is a hot rolled steel sheet having a yield strength YS: 360 MPa or more.
- the “steel plate” includes a steel strip.
- C 0.025 to 0.168%
- C is a solid solution strengthening, strengthening by forming a hard phase such as pearlite, pseudo-pearlite, cementite, etc., or strengthening by forming a hard phase such as bainite, martensite by improving hardenability. It is an element having an action contributing to an increase in strength of (steel pipe).
- C affects the oxide formation of the electric resistance welded part through a decrease in the freezing point, CO formation reaction with O 2 in the gas phase, etc., it is desirable that C be as low as possible.
- yield strength of the steel pipe material 360 MPa or more, yield strength in the pipe axis direction of the steel pipe base part: 400 MPa or more
- About content Preferably it is 0.030% or more.
- the content exceeds 0.168%, the volume ratio of the hard phase of the electric seam welded part and the base material part exceeds 10%, and the toughness decreases.
- the toughness of ERW welds decreases, the internal pressure leak resistance decreases, and there is no leakage or breakage over the entire length during an internal pressure test that applies an internal pressure of 95% of the yield strength YS at room temperature at 0 ° C. It cannot be guaranteed. Therefore, C is limited to a range of 0.025 to 0.168%.
- About content Preferably it is 0.084% or less.
- Si 0.10 to 0.30% Si contributes to the strength increase of a steel plate (steel pipe) through solid solution strengthening.
- Si has a stronger affinity with O (oxygen) than Fe, and forms a eutectic oxide having a high viscosity together with Mn oxide in the ERW weld. If Si is less than 0.10%, the Mn concentration in the eutectic oxide increases, the melting point of the oxide exceeds the molten steel temperature, and it tends to remain in the ERW weld as an oxide.
- the oxide present in the ERW weld increases, the toughness of the ERW weld decreases, and leaks over the entire length during an internal pressure test that gives an internal pressure of 95% of the yield strength YS at room temperature at 0 ° C. It can no longer be guaranteed that no destruction will occur. Therefore, the content is 0.10% or more, preferably 0.15% or more.
- Si is limited to the range of 0.10 to 0.30%.
- the content is preferably 0.25% or less.
- Mn 0.60 to 1.90% Mn contributes to increasing the strength of the steel sheet (steel pipe) through solid solution strengthening and transformation structure strengthening. Mn has a stronger affinity for O (oxygen) than Fe, and forms a high-eutectic eutectic oxide together with Si oxide in the electro-welded weld. If the Mn content is less than 0.60%, the Si concentration in the eutectic oxide increases, the melting point of the oxide exceeds the molten steel temperature, and the oxide easily remains in the ERW weld. The toughness of the steel is reduced, and it is impossible to guarantee that no leakage or breakage will occur over the entire length during the internal pressure test performed at 0 ° C.
- the content is 0.60% or more, preferably 0.85% or more.
- Mn content exceeds 1.90%
- Mn concentration in the eutectic oxide increases in the ERW weld
- the melting point of the oxide exceeds the molten steel temperature
- the absolute amount as an oxide is It increases and tends to remain as an oxide in the ERW weld
- the toughness of the ERW weld decreases, and it becomes impossible to guarantee that no leak or breakage will occur over the entire length during an internal pressure test performed at 0 ° C.
- Mn content exceeds 1.90%
- the fraction of the hard phase in the base metal part and the ERW weld part exceeds 10%, and the toughness decreases. Therefore, Mn is limited to the range of 0.60 to 1.90%.
- about content Preferably it is 1.65% or less.
- P 0.001 to 0.018%
- P is an element that is present in steel as an impurity, easily segregates at grain boundaries, and co-segregates with Mn and adversely affects toughness. It is desirable to reduce it as much as possible, but it is economical in the steelmaking process. From the viewpoint, it is limited to 0.001% or more. On the other hand, if the content exceeds 0.018%, the toughness of the base metal part and the ERW welded part is significantly reduced. Therefore, P is limited to 0.001 to 0.018%. The content is preferably 0.013% or less.
- S 0.0001 to 0.0029%
- S is an element that exists as a sulfide such as MnS and CaS in the base metal part and the electric seam welded part, and has an adverse effect on toughness and the like, and is desirably reduced as much as possible.
- it was limited to 0.0001% or more from the economical viewpoint in the steelmaking process.
- the content exceeds 0.0029%, the toughness is remarkably lowered, and it is impossible to guarantee that no leak or breakage occurs over the entire length in the internal pressure test performed at 0 ° C. For this reason, S was limited to the range of 0.0001 to 0.0029%.
- the content is 0.0001 to 0.0019%.
- Al 0.010 to 0.10%
- Al is an element that acts as a deoxidizer in the steelmaking stage. Moreover, Al precipitates as AlN, suppresses grain growth during austenite heating, and contributes to improvement of low temperature toughness.
- Al has an affinity for O (oxygen) further than Si and Mn, and forms an oxide in a form of a solid solution in a Mn—Si eutectic oxide such as 2MnO ⁇ SiO 2 (Tephrite).
- Al needs to be contained by 0.010% or more. If it is less than 0.010%, a desired deoxidizing ability cannot be ensured in the steelmaking stage, and the cleanliness of the steel is lowered. Also, the oxide present in the ERW welds increases, the toughness decreases, and it becomes impossible to guarantee that no leak or breakage will occur over the entire length during the internal pressure test conducted at 0 ° C. On the other hand, if the Al content exceeds 0.10%, the Al concentration in the eutectic oxide increases, the melting point of the oxide exceeds the molten steel temperature, and it tends to remain as an oxide in the ERW part. Oxides present increase and toughness decreases.
- Al is limited to the range of 0.010 to 0.10%.
- the lower limit side of content Preferably it is 0.03% or more.
- the upper limit side of content Preferably it is 0.08% or less.
- Ca 0.0001 to 0.0035%
- Ca is an element that controls the shape of sulfide in steel in a spherical shape, and contributes particularly to the improvement of toughness in the vicinity of the ERW weld of the steel pipe. In order to acquire such an effect, 0.0001% or more of content is required. Since Ca has a strong affinity with O, if it exceeds 0.0035%, the Ca concentration in the oxide increases, the melting point of the oxide exceeds the molten steel temperature, and the absolute amount as an oxide increases.
- Ca is limited to the range of 0.0001 to 0.0035%.
- the lower limit side of content Preferably it is 0.0002% or more.
- the upper limit side of content Preferably it is 0.0028% or less.
- N 0.0050% or less
- N combines with a nitride-forming element such as Ti and precipitates as a nitride, or dissolves in a solid solution and adversely affects the toughness of the steel pipe base material and the ERW weld. For this reason, it is desirable to reduce as much as possible. However, it is preferable to set the lower limit to 0.0001% from the economical viewpoint in the steel making process.
- the content exceeds 0.0050%, nitrides and solid solution N increase, leading to a decrease in toughness. For this reason, N was limited to 0.0050% or less. In addition, Preferably it is 0.0040% or less.
- O 0.0030% or less
- O oxygen
- the content is preferably 0.0001% or more from the viewpoint of economy in the steelmaking process. If the amount exceeds 0.0030%, the toughness is significantly reduced. For this reason, O was limited to 0.0030% or less. In addition, Preferably it is 0.0020% or less.
- Nb 0.001 to 0.070%
- V 0.001 to 0.065%
- Ti 0.001 to 0.033%
- Nb, V, and Ti are Any of them is an element which mainly precipitates as carbides and contributes to an increase in the strength of the steel sheet (steel pipe) through precipitation strengthening, and is selectively contained in one or more kinds.
- Nb mainly precipitates as carbides and contributes to an increase in steel plate (steel pipe) strength through precipitation strengthening. In order to acquire such an effect, 0.001% or more of content is required. If Nb is less than 0.001%, a desired steel plate (steel pipe) strength cannot be ensured. On the other hand, when the content exceeds 0.070%, undissolved large-sized Nb carbonitrides remain and cause a decrease in toughness. For this reason, when contained, Nb is limited to the range of 0.001 to 0.070%. In addition, about the lower limit side of content, Preferably it is 0.005% or more. Moreover, about the upper limit side of content, Preferably it is 0.055% or less.
- V like Nb, precipitates mainly as carbides and contributes to an increase in steel plate (steel pipe) strength through precipitation strengthening. In order to acquire such an effect, 0.001% or more of content is required. If V is less than 0.001%, a desired steel plate (steel pipe) strength cannot be ensured. On the other hand, if the content exceeds 0.065%, undissolved large V carbonitrides remain, resulting in a decrease in toughness. For this reason, when contained, V is limited to the range of 0.001 to 0.065%. In addition, about the lower limit side of content, Preferably it is 0.005% or more. Moreover, about the upper limit side of content, Preferably it is 0.050% or less.
- Ti like Nb and V, precipitates mainly as carbides and contributes to an increase in steel plate (steel pipe) strength through precipitation strengthening. In order to acquire such an effect, 0.001% or more of content is required. If Ti is less than 0.001%, a desired steel plate (steel pipe) strength cannot be ensured. On the other hand, if the content exceeds 0.033%, undissolved large Ti carbonitrides remain, leading to a decrease in toughness. For this reason, when Ti is contained, it is limited to the range of 0.001 to 0.033%. In addition, about the lower limit side of content, Preferably it is 0.005% or more. Moreover, about the upper limit side of content, Preferably it is 0.020% or less.
- the balance is Fe and inevitable impurities.
- the above components are basic components. In addition to the basic components, if necessary, Cu: 0.001 to 0.350%, Ni: 0.001 to 0.350%, Mo: One or more selected from 0.001 to 0.350%, and / or Cr: 0.001 to 0.350%, B: 0.0001 to 0.0030% You may contain 1 type or 2 types chosen from these.
- One or more selected from Cu: 0.001 to 0.350%, Ni: 0.001 to 0.350%, Mo: 0.001 to 0.350% Cu, Ni, Mo are Any of these is an element that improves the corrosion resistance of the steel pipe, and it can be selected as necessary and contained in one or more kinds.
- Cu is an element that has the effect of improving the corrosion resistance of the steel pipe and improving the hardenability.
- the structure of the base metal part and the ERW welded part of the thick-walled steel pipe is included so as not to become coarse pseudo-polygonal ferrite or polygonal ferrite.
- the term “coarse” as used herein refers to a structure having a particle size exceeding 10 ⁇ m. In order to acquire such an effect, it is preferable to contain 0.001% or more. However, even if the content exceeds 0.350%, the effect is saturated and an effect commensurate with the content cannot be expected, which is economically disadvantageous. Therefore, when contained, Cu is preferably limited to a range of 0.001 to 0.350%. In addition, about the lower limit side of content, More preferably, it is 0.05% or more. Moreover, about the upper limit side of content, More preferably, it is 0.290% or less.
- Ni is an element that improves the corrosion resistance of the steel pipe and improves the hardenability.
- the structure of the base metal part and the ERW welded part of the thick-walled steel pipe is included so as not to become coarse pseudopolygonal ferrite.
- it is preferable to contain 0.001% or more.
- Ni is preferably limited to a range of 0.001 to 0.350%.
- about the lower limit side of content More preferably, it is 0.05% or more.
- the upper limit side of content More preferably, it is 0.290% or less.
- Mo is an element that improves the corrosion resistance of the steel pipe and improves the hardenability.
- the structure of the base metal part and the ERW welded part of the thick-walled steel pipe is included so as not to become coarse pseudopolygonal ferrite.
- Mo is preferably limited to a range of 0.001 to 0.350%.
- about the lower limit side of content More preferably, it is 0.05% or more.
- about the upper limit side of content More preferably, it is 0.290% or less.
- Cr and B are both strengthened by transformation structure strengthening of steel sheet (steel pipe). It is an element that increases the amount, and can contain one or two kinds as necessary.
- B is an element that increases the strength of the steel sheet (steel pipe) by strengthening the transformation structure.
- B is preferably contained in an amount of 0.0001% or more.
- B is preferably limited to a range of 0.0001 to 0.0030%.
- about the lower limit side of content More preferably, it is 0.0003% or more.
- about the upper limit side of content More preferably, it is 0.0022% or less.
- Pcm C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B
- C, Si, Mn, Cu, Ni, Cr, Mo, V, B Content of each element (mass%)
- the Pcm value defined by is adjusted so as to satisfy 0.20 or less.
- the content of the said element shall be calculated as "zero"%.
- the structure of the hot-rolled steel sheet is not particularly limited, but is preferably a structure that can ensure the above-described high strength and high-temperature toughness.
- a structure capable of ensuring such toughness it has a structure composed of a fine pseudo-polygonal ferrite phase having an average particle size of 10 ⁇ m or less as a main phase and the balance of a second phase having a volume ratio of 10% or less.
- “pseudopolygonal ferrite” includes acicular ferrite and bainitic ferrite.
- a hot-rolled steel sheet having the above-described composition and preferably having the above-described structure and having a yield strength of 360 MPa or more is used as the steel pipe material.
- this steel pipe raw material is continuously cold formed by a conventional forming mill in which a plurality of cage rolls and fin pass rolls are continuously arranged to form a tubular body.
- the specific configuration of the forming mill is not particularly limited, and any method for forming a tubular body using a conventional forming mill can be applied.
- the yield strength of the steel pipe base material is greater than that of the steel pipe material due to the work strengthening associated with forming into a tubular body.
- Oxide emission is facilitated by the total distance in the steel plate thickness direction between the taper start position at the width end face of the steel plate and the surface serving as the tube outer surface or the surface serving as the tube inner surface being 10 to 80% of the steel plate thickness.
- the lower limit of the total distance is preferably 30% or more.
- the upper limit side of the total distance is preferably 70% or less.
- the taper shape is not limited to a straight line, and can be an arbitrary curved shape.
- the obtained tubular body is then inspected on the welded surface in the tube axial direction of the ERW welded portion, and it is confirmed that the tubular body is free from any defects.
- a tubular ultrasonic flaw detector (hereinafter, also referred to as “high-sensitivity array UT”) using an array flaw array arranged in the circumferential direction of the pipe, schematically shown in FIG. Shall. Details of this ultrasonic inspection apparatus for a tubular body are described in Japanese Patent No. 4544240, Japanese Patent No. 4910770, and Japanese Patent No. 5076984.
- the beam width is 0.1 mm or less, it is not possible to detect all the welded surfaces that fluctuate in the circumferential direction, and there may be a case where flaw detection leaks.
- the beam width exceeds 4.0 mm, it is not possible to detect oxides that cause toughness deterioration and leakage due to cold welding.
- the beam width is not appropriate, there is a possibility that even if the oxide on the weld surface in the tube axis direction is sufficiently small, it cannot be accurately grasped. For this reason, the beam width was limited to 0.1 to 4.0 mm.
- the lower limit of the beam width is 0.3 mm
- the upper limit of the beam width is 2.0 mm.
- a tube that has been confirmed that there are no more than a predetermined amount of non-metallic parts in the electro-welded welded portion of the tube shall be the product tube.
- the "predetermined amount or more" here refers to a case where the non-metal portion exceeds 0.049 area% in the occupied area with respect to the entire ERW weld.
- the above-described inspection may be performed with a seam annealing process.
- the heating temperature of the weld reheating process is less than 850 ° C.
- the heating temperature is too low to ensure the desired ERW weld toughness.
- the heating temperature is higher than 1150 ° C.
- the structure becomes coarse, and the desired toughness of the electric resistance welded portion cannot be ensured.
- the heating temperature of the seam annealing treatment was limited to 850 to 1150 ° C.
- the cooling rate after seam annealing in the ERW weld is less than 20 ° C./s, the cooling is too slow, and the microstructure is mainly composed of a fine pseudopolygonal ferrite phase having a crystal grain size of 10 ⁇ m or less. It becomes impossible to ensure, and desired ERW weld hardness and toughness cannot be ensured.
- rapid cooling exceeds 200 ° C./s, it becomes impossible to ensure a structure having the pseudo-polygonal ferrite phase as a main phase in the electric resistance welded portion, and the desired electric resistance welded portion toughness cannot be ensured.
- the cooling after the seam annealing treatment was limited to a cooling rate in the range of 20 to 200 ° C./s on average in the temperature range of 780 to 630 ° C. at the temperature of the central portion of the thickness.
- the cooling stop temperature after the seam annealing treatment is preferably set to 500 ° C. or lower. Note that the cooling stop temperature is more preferably 450 ° C. or lower in order to suppress the formation of pearlite throughout the thickness.
- a tempering treatment may be further performed after the seam annealing treatment to stabilize the material.
- the temperature at the center of the wall thickness is calculated from the temperature distribution in the cross section of the weld using electromagnetic field analysis and heat transfer analysis (for example, Okabe et al .: Iron and Steel, Vol. 93 (2007) No. 5, p373-378). The result is obtained by correcting the result with the actual outer surface and inner surface temperatures.
- the product pipe manufactured by the above-described manufacturing method has the above-mentioned composition, and the pseudo-polygonal ferrite phase having an average particle diameter of 10 ⁇ m or less, in which the base material part and the ERW weld part are 90% or more by volume.
- This is an ERW steel pipe having a structure composed of a main phase and the remainder consisting of a second phase with a volume ratio of 10% or less and having no non-metal portion in the ERW weld.
- Such an ERW steel pipe has a yield strength YS: 400 MPa or more in the pipe axis direction, has no welding defects such as cold welding, has excellent internal pressure leak resistance and excellent ERW weld toughness, It is a highly reliable ERW steel pipe.
- the “pseudopolygonal ferrite” referred to here includes acicular ferrite and bainitic ferrite.
- the average grain size of “pseudopolygonal ferrite” is determined by measuring the area of a crystal grain surrounded by a grain boundary having an inclination angle between adjacent crystal grains of 15 ° or more with respect to the central thickness in the circumferential cross section. The equivalent circle diameter calculated from the area of the obtained crystal grains is obtained, and the average value thereof is taken.
- the value measured using the EBSD (Electro Backscatter Diffraction) apparatus is used for the inclination angle between adjacent crystal grains.
- Table 2-1 and Table 2-2 are collectively referred to as Table 2, and Table 3-1 and Table 3-2 are collectively referred to as Table 3.
- Table 1 Steel No. N is a missing number.
- Tables 2 to 3 the steel pipe No. 33 is a missing number.
- a tubular body is formed by continuously forming in a cold manner by a forming mill in which a plurality of cage rolls and fin pass rolls are continuously arranged. . Thereafter, the end portions of the tubular body (the width end portion of the hot-rolled steel sheet) are butted against each other, and the end portion of the tubular body is heated and melted by high-frequency heating while being pressurized with a squeeze roll, and is electro-welded and welded.
- a 22-inch (outer diameter 558.8 mm ⁇ ⁇ thickness 25 mm) ERW steel pipe was formed.
- Test specimens were collected from the base metal part and the electric resistance welded part of the obtained tubular body (electrically welded steel pipe), and subjected to structure observation, tensile test, Charpy impact test, fracture toughness test, and internal pressure test.
- the test method was as follows. (1) Microstructure observation From the base material portion (position 90 ° circumferentially away from the electro-resistance welded portion) and the central position of the electro-welded welded portion of the obtained tubular body (electrically welded steel pipe) Were collected.
- the surface perpendicular to the tube axis direction (C cross section) is taken as the observation surface, the specimen for structure observation is polished, corroded (Nital solution corrosion), optical microscope (magnification: 400 times) and scanning electron microscope (magnification: 2000). ) was used to observe the tissue near the center of the wall thickness, and images were taken in each of four or more fields of view.
- structure photograph scanning electron microscope structure photograph
- the structure fraction phase was identified, and the tissue fraction was determined by image analysis.
- the value of an area fraction was made into the value of a volume fraction, assuming that it was three-dimensionally homogeneous.
- a V-notch test piece was sampled so that the direction was the circumferential direction of the tube, and a Charpy impact test was performed in accordance with the provisions of JIS Z 2242.
- the test temperature was ⁇ 60 ° C., each of which was tested three times, and the average value was defined as the absorbed energy vE ⁇ 60 (J) of the steel pipe.
- J the absorbed energy vE ⁇ 60
- Partial leak refers to a state where a leak occurs in a test steel pipe exceeding 0% and 10% or less when evaluated with 10 or more pipes, and “leak” is a specimen exceeding 10%. A state where a leak has occurred.
- any of C, Si, Mn, P, S, Al, Ca, N, O, Ti, Nb, V, and Pcm is a steel pipe No. 26-No. 35, 44 to 48, and 50 to 52 cannot secure desired toughness with vE- 60 of less than 110 J and CTOD value of less than 0.80 mm at 0 ° C. in an electric resistance welded portion, and at least electric resistance welding in an internal pressure test. A leak occurred in the part.
- a steel pipe no. No. 49 has insufficient YS and TS of the base material part.
- steel pipe No. C in which C deviates from the scope of the present invention is low. No.
- the steel pipe No. 25 is YS: less than 400 MPa and the desired strength cannot be secured, and the desired toughness can be secured with a vD- 60 of less than 110 J and a CTOD value of less than 0.80 mm at 0 ° C. in both the base metal part and the electric resistance welded part.
- the steel pipe No. As in the case of 11 to 19, the echo height should be about 20%, but the steel pipe No. which had a beam width outside the scope of the present invention. In 10, 20, and 21, the echo height was a different value, and it could not be determined that the oxide on the weld surface in the pipe axis direction was sufficiently small.
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Abstract
Description
信頼性の高い電縫溶接部を有することの一つの指標として、本発明者らは、試験温度:0℃で、常温での降伏強さの95%の内圧を負荷した条件で、内圧試験を行ない、リークが生じないことを意味する、「耐内圧リーク性」を採用した。内圧試験は、非特許文献(S.Toyoda,S.Goto,T.Okabe,H.Kimura,S.Igi,Y.Matsui,S.Yabumoto,A.Sato,M.Suzuki,and T.Inoue:Proc. of IPC(2012),IPC2012-90448.)に記載された要領で、所定の温度(ここでは0℃)に保持した冷媒中に管体を保持し、ノッチ無しの条件で行うものとする。
[1]質量%で
C:0.025~0.168%、 Si:0.10~0.30%、
Mn:0.60~1.90%、 P:0.001~0.018%、
S:0.0001~0.0029%、 Al:0.010~0.10%、
Ca:0.0001~0.0035%、 N:0.0050%以下、
O:0.0030%以下、
さらに、Nb:0.001~0.070%、V:0.001~0.065%、Ti:0.001~0.033%のうちから選ばれた1種または2種以上を、下記(1)式で定義されるPcmが0.20以下を満足するように含み、残部Fe及び不可避的不純物からなる組成を有し、さらに、
母材部および電縫溶接部がいずれも、体積率で90%以上の、平均粒径:10μm以下の擬ポリゴナルフェライト相を主相とし、残部が、体積率で10%以下の第二相とからなる組織を有し、
管軸方向で降伏強さYS:400MPa以上の母材部を有し、
JIS Z 2242の規定に準拠して行ったシャルピー衝撃試験の試験温度:-60℃での吸収エネルギーvE-60が110J以上で、BS 7448-1995の規定に準拠して行ったCTOD試験の試験温度:0℃におけるCTOD値が0.80mm以上の電縫溶接部靭性を有し、かつ試験温度:0℃、内圧:0.95×(常温降伏強さσyRT)の条件で行う内圧試験において、リークが生じない、電縫鋼管。
記
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B ・・・・(1)
ここで、C、Si、Mn、Cu、Ni、Cr、Mo、V、B:各元素の含有量(質量%)であり、含有しない元素は0とする。
[2]前記組成に加えてさらに、質量%で、Cu:0.001~0.350%、Ni:0.001~0.350%、Mo:0.001~0.350%のうちから選ばれた1種または2種以上を含有する組成とする[1]に記載の電縫鋼管。
[3]前記組成に加えてさらに、質量%で、Cr:0.001~0.350%、B:0.0001~0.0030%のうちから選ばれた1種または2種を含有する組成とする[1]または[2]に記載の電縫鋼管。
[4]鋼管素材に、複数の、ケージロールとフィンパスロールとを連続して配設した成形ミルにより、冷間で連続して成形加工を施し管状体としたのち、スクイズロールで該管状体の端面同士を突き合わせ、加圧しながら該突き合わせた部位を高周波加熱により電縫溶接して管体とし、ついで、該管体の電縫溶接部の管軸方向溶接面を検査する電縫鋼管の製造方法において、
前記鋼管素材が、質量%で
C:0.025~0.168%、 Si:0.10~0.30%、
Mn:0.60~1.90%、 P:0.001~0.018%、
S:0.0001~0.0029%、 Al:0.010~0.10%、
Ca:0.0001~0.0035%、 N:0.0050%以下、
O:0.0030%以下、
さらに、Nb:0.001~0.070%、V:0.001~0.065%、Ti:0.001~0.033%のうちから選ばれた1種または2種以上を、下記(1)式で定義されるPcmが0.20以下を満足するように含み、残部Fe及び不可避的不純物からなる組成を有し、
前記鋼管素材を降伏強さYS:360MPa以上を有する熱延鋼板とし、前記フィンパスロールによる成形で、前記熱延鋼板の幅方向端面に開先を付与するにあたり、該開先をテーパー開先とし、該テーパー開先のテーパー開始位置から管表面までの距離が、管外面からの距離と管内面からの距離との合計で鋼板肉厚に対する比率で10~80%である開先とし、
前記検査を、前記管体の電縫溶接部の管軸方向溶接面に対し、ビーム幅が0.1mmから4.0mmの範囲となるように超音波を送波し、該溶接面からの反射波の一部または全部を受波するアレイ探触子を用いた超音波探傷装置により、前記管体の電縫溶接部に非金属部が所定量以上存在しないことを確認する検査とし、
前記検査後に、前記電縫溶接して得られた前記管体の電縫溶接部に、加熱温度:850~1150℃に加熱し、肉厚中央部の温度で780~630℃の範囲を平均冷却速度20~200℃/sの範囲の冷却速度で冷却する溶接部再加熱処理を施す、
JIS Z 2242の規定に準拠して行ったシャルピー衝撃試験の試験温度:-60℃での吸収エネルギーvE-60が110J以上で、BS 7448-1995の規定に準拠して行ったCTOD試験の試験温度:0℃におけるCTOD値が0.80mm以上の電縫溶接部靭性を有し、かつ試験温度:0℃、内圧:0.95×(常温降伏強さσyRT)の条件で行う内圧試験において、リークが生じないものである、電縫鋼管の製造方法。
記
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B ・・・・(1)
ここで、C、Si、Mn、Cu、Ni、Cr、Mo、V、B:各元素の含有量(質量%)
[5]前記組成に加えてさらに、質量%で、Cu:0.001~0.350%、Ni:0.001~0.350%、Mo:0.001~0.350%のうちから選ばれた1種または2種以上を含有する組成とする[4]に記載の電縫鋼管の製造方法。
[6]前記組成に加えてさらに、質量%で、Cr:0.001~0.350%、B:0.0001~0.0030%のうちから選ばれた1種または2種を含有する組成とする[4]または[5]に記載の電縫鋼管の製造方法。
Cは、固溶強化、あるいはパーライト、擬似パーライト、セメンタイトなどの硬質相を形成することによる強化、あるいは焼入れ性を向上させて、ベイナイト、マルテンサイトなどの硬質相を形成することによる強化で、鋼板(鋼管)の強度増加に寄与する作用を有する元素である。一方で、Cは、電縫溶接時に、凝固点の低下、気相中O2とのCO形成反応などを介して、電縫溶接部の酸化物形成に影響を及ぼすため、できるだけ低いほうが望ましいが、所望の高強度(鋼管素材の降伏強さ:360MPa以上、鋼管母材部管軸方向の降伏強さ:400MPa以上)を確保するためには0.025%以上の含有を必要とする。含有量について、好ましくは0.030%以上である。一方、0.168%を超える含有は、電縫溶接部並びに母材部の硬質相の体積率が10%を超え、靭性が低下する。とくに、電縫溶接部の靭性低下に伴い、耐内圧リーク性が低下し、0℃で常温の降伏強さYSの95%の内圧を付与する内圧試験時に全長にわたりリーク、破壊の起こらないことを保証できなくなる。このため、Cは0.025~0.168%の範囲内に限定した。含有量について、好ましくは0.084%以下である。
Siは、固溶強化を介して、鋼板(鋼管)の強度増加に寄与する。また、Siは、FeよりもO(酸素)との親和力が強く、電縫溶接部で、Mn酸化物とともに粘度の高い共晶酸化物を形成する。Siが0.10%未満では、共晶酸化物中のMn濃度が増加し、酸化物の融点が溶鋼温度を超え、酸化物として電縫溶接部に残存し易くなる。そのため、電縫溶接部に存在する酸化物が増加し、電縫溶接部の靭性が低下し、0℃で常温の降伏強さYSの95%の内圧を付与する内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。よって、含有量は0.10%以上とし、好ましくは0.15%以上とする。一方、Si含有量が0.30%を超えると、共晶酸化物中のSi濃度が増加し、酸化物の融点が溶鋼温度を超えるとともに、酸化物としての絶対量が増え、電縫溶接部に酸化物として残存し易くなり、電縫溶接部の靭性が低下し、内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。このようなことから、Siは0.10~0.30%の範囲に限定した。なお、含有量について、好ましくは0.25%以下である。
Mnは、固溶強化と変態組織強化を介して、鋼板(鋼管)の強度増加に寄与する。Mnは、FeよりもO(酸素)との親和力が強く、電縫溶接部で、Si酸化物とともに粘度の高い共晶酸化物を形成する。Mn含有量が0.60%未満では、共晶酸化物中のSi濃度が増加し、酸化物の融点が溶鋼温度を超え、酸化物として電縫溶接部に残存し易くなり、電縫溶接部の靭性が低下し、0℃で行なう内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。さらに、Mn含有量が0.60%未満では、母材部並びに電縫溶接部の組織が、粒径:10μm超えの粗大な擬ポリゴナルフェライトやポリゴナルフェライトとなる。そのため、靭性が低下し、0℃で行なう内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。よって、含有量は0.60%以上とし、好ましくは0.85%以上とする。一方、Mn含有量が1.90%を超えると、電縫溶接部で、共晶酸化物中のMn濃度が増加し、酸化物の融点が溶鋼温度を超えるとともに、酸化物としての絶対量が増え、酸化物として電縫溶接部に残存し易くなり、電縫溶接部の靭性が低下し、0℃で行なう内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。さらに、Mn含有量が1.90%を超えると、母材部並びに電縫溶接部における硬質相の分率が10%を超え、靭性が低下する。このようなことから、Mnは0.60~1.90%の範囲に限定した。なお、含有量について、好ましくは1.65%以下である。
Pは、不純物として鋼中に存在し、粒界等に偏析しやすく、またMnと共偏析し、靭性等に悪影響を及ぼす元素であり、できるだけ低減することが望ましいが、製鋼プロセスにおける経済性の観点から0.001%以上に限定した。一方、0.018%を超える含有は、母材部並びに電縫溶接部の靭性低下が著しくなる。このため、Pは0.001~0.018%に限定した。なお、含有量について、好ましくは0.013%以下である。
Sは、母材部、電縫溶接部で、MnS、CaS等の硫化物として存在し、靭性等に悪影響を及ぼす元素であり、できるだけ低減することが望ましい。しかし、製鋼プロセスにおける経済性の観点から0.0001%以上に限定した。一方、0.0029%を超えて含有すると、靭性が顕著に低下し、0℃で行なう内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。このため、Sは0.0001~0.0029%の範囲に限定した。なお、好ましくは0.0001~0.0019%である。
Alは、製鋼段階での脱酸剤として作用する元素である。また、Alは、AlNとして析出し、オーステナイト加熱時の粒成長を抑制し、低温靭性の向上に寄与する。また、Alは、Si、MnよりもさらにO(酸素)との親和力が強く、2MnO・SiO2(Tephroite)などのMn-Si共晶酸化物に固溶する形で酸化物を形成する。
Caは、鋼中の硫化物を球状に形態制御する元素であり、とくに鋼管の電縫溶接部近傍の靭性向上に寄与する。このような効果を得るためには、0.0001%以上の含有を必要とする。CaはOとの親和力が強いため、0.0035%を超えて含有すると、酸化物中のCa濃度が増加し、酸化物の融点が溶鋼温度を超えるとともに、酸化物としての絶対量が増え、酸化物として電縫溶接部に残存し易くなり、電縫溶接部の靭性が低下し、0℃で行なう内圧試験時に、全長にわたりリーク、破壊の起こらないことを保証できなくなる。このため、Caは0.0001~0.0035%の範囲に限定した。なお、含有量の下限側について、好ましくは0.0002%以上である。また、含有量の上限側について、好ましくは0.0028%以下である。
Nは、Ti等の窒化物形成元素と結合し、窒化物として析出するか、固溶して、鋼管母材および電縫溶接部の靭性に悪影響を及ぼす。このため、できるだけ低減することが望ましい。しかし、製鋼プロセスにおける経済性の観点から0.0001%を下限とすることが好ましい。一方、0.0050%を超える含有は、窒化物並びに固溶Nが増加し、靭性の低下を招く。このため、Nは0.0050%以下に限定した。なお、好ましくは0.0040%以下である。
O(酸素)は、酸化物系介在物として残存し、靭性、延性等、各種の特性に悪影響を及ぼす。このため、できるだけ低減することが望ましい。しかし、製鋼プロセスにおける経済性の観点から含有量は0.0001%以上とすることが望ましい。0.0030%を超えて多くなると、著しい靭性の低下を招く。このため、Oは0.0030%以下に限定した。なお、好ましくは0.0020%以下である。
Nb、V、Tiはいずれも、主として炭化物として析出し、析出強化を介して鋼板(鋼管)強度の増加に寄与する元素であり、選択して1種または2種以上含有する。
上記した成分が基本の成分であるが、基本の成分に加えてさらに、必要に応じて、選択元素として、Cu:0.001~0.350%、Ni:0.001~0.350%、Mo:0.001~0.350%のうちから選ばれた1種または2種以上、および/または、Cr:0.001~0.350%、B:0.0001~0.0030%のうちから選ばれた1種または2種、を含有してもよい。
Cu、Ni、Moはいずれも、鋼管の耐食性を向上させる元素であり、必要に応じて選択して1種または2種以上含有できる。
Cr、Bはいずれも、変態組織強化により、鋼板(鋼管)の強度を増加させる元素であり、必要に応じて、1種または2種を含有できる。
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B ・・・・(1)
ここで、C、Si、Mn、Cu、Ni、Cr、Mo、V、B:各元素の含有量(質量%)
で定義されるPcm値が0.20以下を満足するように調整して含有する。なお、(1)式に記載されている元素を含有しない場合には、当該元素の含有量を「零」%として計算するものとする。
なお、肉厚中央部の温度は、電磁場解析および伝熱解析(例えば、岡部ら:鉄と鋼,Vol.93(2007)No.5,p373~378)により溶接部断面内の温度分布を計算し、その結果を実際の外面および内面の温度によって補正することにより求める。
(1)組織観察
得られた管体(電縫鋼管)の母材部(電縫溶接部から円周方向に90°離れた位置)および電縫溶接部中央位置から、それぞれ組織観察用試験片を採取した。管軸方向に直交する面(C断面)を観察面とし、組織観察用試験片を研磨し、腐食(ナイタール液腐食)し、光学顕微鏡(倍率:400倍)および走査型電子顕微鏡(倍率:2000倍)を用いて、肉厚中央位置付近の組織を観察し、各4視野以上で撮像した。得られた組織写真(走査型電子顕微鏡組織写真)を用い、構成する組織(相)の同定、および画像解析により、その組織分率を求めた。なお、面積分率で求めた場合は、三次元的に均質であるとして、面積分率の値を体積分率の値とした。
また、発明例では主相である「擬ポリゴナルフェライト」について、EBSD(Electro Backscatter Diffraction)装置を用いて、肉厚中央位置で、隣接する結晶粒間の傾角が15°以上の粒界で囲まれた結晶粒の面積を測定し、得られた面積から円相当直径をもとめ、それらの平均値を、擬ポリゴナルフェライトの平均結晶粒径として求めた。
得られた管体(電縫鋼管)の母材部(電縫溶接部から円周方向に90°離れた位置)から、引張方向が管軸方向となるように、JIS 12号引張試験片を採取し、JIS Z 2241の規定に準拠して引張試験を実施し、引張特性(降伏強さYS、引張強さTS)を求めた。なお、TS:490MPa以上を良好と判断した。
(3)シャルピー衝撃試験
得られた管体(電縫鋼管)の母材部(電縫溶接部から円周方向に90°離れた位置)および電縫溶接部中央位置から、それぞれ試験片の長手方向が、管の円周方向となるように、Vノッチ試験片を採取し、JIS Z 2242の規定に準拠して、シャルピー衝撃試験を実施した。試験温度は-60℃とし、各3本ずつ試験し、その平均値を当該鋼管の吸収エネルギーvE-60(J)とした。なお、鋼種Bの電縫鋼管では、n:100で評価し、その最低値を示した。
(4)破壊靭性試験
得られた管体(電縫鋼管)の母材部(電縫溶接部から円周方向に90°離れた位置)および電縫溶接部中央位置から、BS 7448-1995の規定に準拠して、試験片長手方向が管軸方向に直交する方向となるように、CTOD試験片を採取した。そして、BS 7448-1995の規定に準拠して、試験温度:0℃で、CTOD値を求めた。なお、ノッチ位置は、母材部、電縫溶接部中央位置とした。
なお、鋼種Bの電縫鋼管では、n:100で評価し、その最低値を示した。
得られた管体(電縫鋼管)を試験鋼管とし、試験温度:0℃、内圧:0.95×(常温降伏強さσyRT)の条件で行う内圧試験を実施した。なお、内圧試験は、S.Toyoda,S.Goto,T.Okabe,H.Kimura,S.Igi,Y.Matsui,S.Yabumoto,A.Sato,M.Suzuki,and T.Inoue:Proc. of IPC(2012),IPC2012-90448.に記載された要領で、所定の温度(ここでは0℃)に保持した冷媒中に管体を保持し、ノッチ無しの条件で、試験鋼管に、内圧:0.95×(常温降伏強さσyRT)を負荷して、リーク、破壊の有無を評価した。なお、「一部リーク」とは、10本以上で評価した場合に0%を超え10%以下の試験鋼管でリークを起した状態をいい、「リーク」とは、10%を超える試験体でリークを起した状態をいう。
また、超音波探傷において、適正なビーム幅の場合には鋼管No. 11~19の場合のようにエコー高さ:20%程度となるべきところ、本発明の範囲を外れるビーム幅であった鋼管No.10、20、21においてはエコー高さが異なる値となり、管軸方向溶接面の酸化物が十分に少ないと判断できなかった。
Claims (6)
- 質量%で
C:0.025~0.168%、 Si:0.10~0.30%、
Mn:0.60~1.90%、 P:0.001~0.018%、
S:0.0001~0.0029%、 Al:0.010~0.10%、
Ca:0.0001~0.0035%、 N:0.0050%以下、
O:0.0030%以下、
さらに、Nb:0.001~0.070%、V:0.001~0.065%、Ti:0.001~0.033%のうちから選ばれた1種または2種以上を、下記(1)式で定義されるPcmが0.20以下を満足するように含み、残部Fe及び不可避的不純物からなる組成を有し、さらに、
母材部および電縫溶接部がいずれも、体積率で90%以上の、平均粒径:10μm以下の擬ポリゴナルフェライト相を主相とし、残部が、体積率で10%以下の第二相とからなる組織を有し、
管軸方向で降伏強さYS:400MPa以上の母材部を有し、
JIS Z 2242の規定に準拠して行ったシャルピー衝撃試験の試験温度:-60℃での吸収エネルギーvE-60が110J以上で、BS 7448-1995の規定に準拠して行ったCTOD試験の試験温度:0℃におけるCTOD値が0.80mm以上の電縫溶接部靭性を有し、かつ試験温度:0℃、内圧:0.95×(常温降伏強さσyRT)の条件で行う内圧試験において、リークが生じない、電縫鋼管。
記
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B ・・・・(1)
ここで、C、Si、Mn、Cu、Ni、Cr、Mo、V、B:各元素の含有量(質量%)であり、含有しない元素は0とする。 - 前記組成に加えてさらに、質量%で、Cu:0.001~0.350%、Ni:0.001~0.350%、Mo:0.001~0.350%のうちから選ばれた1種または2種以上を含有する組成とする請求項1に記載の電縫鋼管。
- 前記組成に加えてさらに、質量%で、Cr:0.001~0.350%、B:0.0001~0.0030%のうちから選ばれた1種または2種を含有する組成とする請求項1または2に記載の電縫鋼管。
- 鋼管素材に、複数の、ケージロールとフィンパスロールとを連続して配設した成形ミルにより、冷間で連続して成形加工を施し管状体としたのち、スクイズロールで該管状体の端面同士を突き合わせ、加圧しながら該突き合わせた部位を高周波加熱により電縫溶接して管体とし、ついで、該管体の電縫溶接部の管軸方向溶接面を検査する電縫鋼管の製造方法において、
前記鋼管素材が、質量%で
C:0.025~0.168%、 Si:0.10~0.30%、
Mn:0.60~1.90%、 P:0.001~0.018%、
S:0.0001~0.0029%、 Al:0.010~0.10%、
Ca:0.0001~0.0035%、 N:0.0050%以下、
O:0.0030%以下、
さらに、Nb:0.001~0.070%、V:0.001~0.065%、Ti:0.001~0.033%のうちから選ばれた1種または2種以上を、下記(1)式で定義されるPcmが0.20以下を満足するように含み、残部Fe及び不可避的不純物からなる組成を有し、
前記鋼管素材を降伏強さYS:360MPa以上を有する熱延鋼板とし、前記フィンパスロールによる成形で、前記熱延鋼板の幅方向端面に開先を付与するにあたり、該開先をテーパー開先とし、該テーパー開先のテーパー開始位置から管表面までの距離が、管外面からの距離と管内面からの距離との合計で鋼板肉厚に対する比率で10~80%である開先とし、
前記検査を、前記管体の電縫溶接部の管軸方向溶接面に対し、ビーム幅が0.1mmから4.0mmの範囲となるように超音波を送波し、該溶接面からの反射波の一部または全部を受波するアレイ探触子を用いた超音波探傷装置により、前記管体の電縫溶接部に非金属部が所定量以上存在しないことを確認する検査とし、
前記検査後に、前記電縫溶接して得られた前記管体の電縫溶接部に、加熱温度:850~1150℃に加熱し、肉厚中央部の温度で780~630℃の範囲を平均冷却速度20~200℃/sの範囲の冷却速度で冷却する溶接部再加熱処理を施す、
JIS Z 2242の規定に準拠して行ったシャルピー衝撃試験の試験温度:-60℃での吸収エネルギーvE-60が110J以上で、BS 7448-1995の規定に準拠して行ったCTOD試験の試験温度:0℃におけるCTOD値が0.80mm以上の電縫溶接部靭性を有し、かつ試験温度:0℃、内圧:0.95×(常温降伏強さσyRT)の条件で行う内圧試験において、リークが生じないものである、電縫鋼管の製造方法。
記
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B ・・・・(1)
ここで、C、Si、Mn、Cu、Ni、Cr、Mo、V、B:各元素の含有量(質量%) - 前記組成に加えてさらに、質量%で、Cu:0.001~0.350%、Ni:0.001~0.350%、Mo:0.001~0.350%のうちから選ばれた1種または2種以上を含有する組成とする請求項4に記載の電縫鋼管の製造方法。
- 前記組成に加えてさらに、質量%で、Cr:0.001~0.350%、B:0.0001~0.0030%のうちから選ばれた1種または2種を含有する組成とする請求項4または5に記載の電縫鋼管の製造方法。
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