WO2016065864A1 - Oled阵列基板及其制备方法、显示面板、显示装置 - Google Patents
Oled阵列基板及其制备方法、显示面板、显示装置 Download PDFInfo
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- WO2016065864A1 WO2016065864A1 PCT/CN2015/076848 CN2015076848W WO2016065864A1 WO 2016065864 A1 WO2016065864 A1 WO 2016065864A1 CN 2015076848 W CN2015076848 W CN 2015076848W WO 2016065864 A1 WO2016065864 A1 WO 2016065864A1
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- 230000008020 evaporation Effects 0.000 claims description 12
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- 239000000463 material Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 9
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- 238000000034 method Methods 0.000 claims description 7
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- 238000000605 extraction Methods 0.000 abstract description 8
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- 239000004973 liquid crystal related substance Substances 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
- H10K50/852—Arrangements for extracting light from the devices comprising a resonant cavity structure, e.g. Bragg reflector pair
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/86—Arrangements for improving contrast, e.g. preventing reflection of ambient light
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/166—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/302—Details of OLEDs of OLED structures
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/1201—Manufacture or treatment
Definitions
- the present invention relates to the field of display technologies, and in particular, to an OLED array substrate and a method for fabricating the same, an OLED display panel, and an OLED display device.
- OLED Organic Light Emitting Diode
- OLED displays are considered as a new generation of flat panel display products after liquid crystal displays and plasma displays.
- OLEDs have a wide range of applications in the field of display and illumination.
- it is necessary to increase the external quantum efficiency of the semiconductor light-emitting element itself as much as possible.
- the external quantum efficiency of a semiconductor light-emitting element depends on its own internal quantum efficiency and Light Extraction Efficiency (LEE).
- the internal quantum efficiency is determined by the characteristics of the material itself. Therefore, in the case where the internal quantum efficiency cannot be effectively improved, it is particularly important to improve the light extraction efficiency of the semiconductor light-emitting element.
- the light extraction efficiency is increased in order to direct the light emitted inside the OLED to the outside of the semiconductor light emitting element as much as possible.
- the existing OLED array substrate includes a substrate 1 provided with a thin film transistor (not shown), and an OLED unit controlled by a thin film transistor on the substrate 1, and a typical OLED unit includes an anode 2 which is sequentially disposed.
- the cathode 4 is generally a translucent metal electrode, the reflection of light emitted from the organic light-emitting layer 3 at the electrode is increased, thereby causing multi-photon beam interference, resulting in a microcavity effect ( The phenomenon that the intensity of light at different emission angles and the wavelength of light waves are different due to optical interference inside the component is very obvious. Therefore, when a display including the top emission type OLED array substrate is used, the light emission intensity and color change with the viewing angle.
- the photocoupling layer 5 may be covered on the cathode 4, and the refractive index of the material forming the optical coupling layer 5 is larger than the refractive index of the material forming the cathode 4, in other words, the optical coupling layer.
- the refractive index of 5 is greater than the refractive index of the cathode 4. It has been found that when the refractive index of the light coupling layer 5 (the refractive index of the light coupling layer 5 is generally greater than 2.0) is greater than the refractive indices of the organic light-emitting layer 3 and the cathode 4, the transmittance of the cathode 4 is increased, and the cathode 4 is transparent. An increase in the overshoot will attenuate the microcavity effect.
- the optical coupling layer 5 is formed by evaporation using an open mask, that is, all of the OLED units are simultaneously vapor-deposited to form an equal-thickness optical coupling layer 5 as shown in FIG.
- the refractive index of the light coupling layer 5 is relatively high, it is generally larger than the refractive index of the gas layer located outside the light coupling layer 5, for example, larger than the refractive index of the nitrogen layer located outside thereof, resulting in an iso-thick optical coupling layer. 5
- the internal total reflection of light occurs, which loses part of the light intensity, which reduces the light extraction efficiency.
- the object of the present invention is to solve the problem that the light extraction efficiency is reduced due to the total reflection of light occurring inside the equal-thickness optical coupling layer of the OLED array substrate existing in the prior art, and an OLED array substrate and a preparation method thereof are provided.
- an OLED array plate includes a substrate and a plurality of pixel units disposed on the substrate, each of the pixel units including a thin film transistor and a first one sequentially disposed on the thin film transistor An electrode, an organic light emitting layer, a second electrode, and an optical coupling layer, wherein
- the light coupling layer includes a bottom portion in contact with the second electrode and a curved top portion convex toward the light emission direction.
- the thickness of the light coupling layer is ⁇ /4n, where ⁇ is the wavelength of light emitted by the organic light emitting layer, and n is the refractive index of the light coupling layer.
- the first electrode is an anode and the second electrode is a cathode.
- the light coupling layer has different thicknesses corresponding to portions of pixel units of different colors.
- An arc-top light coupling layer is formed on the substrate on which the first electrode, the organic light-emitting layer, and the second electrode are formed by evaporation using a mask.
- the mask has a thickness of 100 to 200 nm.
- the mask comprises a plurality of openings corresponding to the respective pixel units, the openings for passing the evaporation material and forming an arc-top light coupling layer on the corresponding pixel unit;
- each of the openings are respectively 20-50 nm larger than the length and width of the corresponding pixel unit.
- the thickness of the arc top light coupling layer is ⁇ /4n, wherein ⁇ is the wavelength of light emitted by the organic light emitting layer, and n is the refractive index of the arc top light coupling layer.
- the same mask is used when making the arc-top light coupling layer of the pixel unit corresponding to different colors.
- a mask plate corresponding to the pixel unit of the color is used when making the arc-top light coupling layer of the pixel unit of different colors.
- an OLED display panel comprising any one of the above OLED array substrates.
- an OLED display device comprising the above OLED display panel.
- the OLED array substrate and the preparation method thereof, the OLED display panel and the OLED display device of the invention reduce the total reflection of light inside the optical coupling layer by forming the optical coupling layer into an arc-top light coupling layer, thereby improving light extraction efficiency .
- FIG. 1 is a schematic structural view of an OLED array substrate in the prior art
- FIG. 2 is a schematic structural view of an OLED array substrate according to Embodiment 1 of the present invention.
- FIG. 3 is a schematic view showing a comparison of optical paths in an arc-top light coupling layer according to Embodiment 1 of the present invention and an equal-thickness optical coupling layer in the prior art;
- FIG. 4 is a top plan view showing a mask used for preparing an arc-top light coupling layer in Embodiment 2 of the present invention
- Figure 5 is a cross-sectional view showing a mask used in the vapor deposition according to Embodiment 2 of the present invention. As well as
- FIG. 6 is a view showing the size comparison between the opening 71 of the mask and the corresponding pixel unit in the embodiment 2 of the present invention.
- the embodiment provides an OLED array substrate, including a substrate 1 and a plurality of pixel units disposed on the substrate 1, each of the pixel units including a thin film transistor (not shown) and the thin film a first electrode 2, an organic light-emitting layer 3, a second electrode 4, and a light coupling layer 6 disposed in sequence above the transistor, the light-coupling layer 6 including a bottom portion in contact with the second electrode 4 and a direction toward the light exiting direction (FIG. 2) A convex curved top in the direction of the arrow.
- the light coupling layer 6 having a curved top portion provided in the present invention is referred to as an arc top light coupling layer 6.
- the thin film transistor is used to control the light emission of the organic light-emitting layer 3.
- the first electrode 2 and the second electrode 4 are used to supply holes and electrons to the organic light-emitting layer 3 to cause the organic light-emitting layer 3 to emit light.
- the refractive index of the arc-top light coupling layer 6 is greater than the refractive index of the second electrode 4, and the arc-top light coupling layer 6 is used to increase the light transmittance of the second electrode 4.
- the arc-top light coupling layer 6 can reduce the total reflection inside the optical coupling layer.
- FIG. 3 when light is incident at the same angle, for an equal-thickness optical coupling layer, since the incident angle is larger than the critical angle, total reflection occurs at the interface of the iso-thick optical coupling layer; The layer has a curved interface, so the incident angle is reduced.
- the incident angle is smaller than the critical angle, refraction occurs at the interface of the arc-top light coupling layer, and light is emitted to the outside of the arc-top light coupling layer, thereby facilitating light. extract.
- the OLED array substrate of the present invention has the optical coupling layer disposed to have a curved top portion, the light coupling can be reduced with respect to the iso-thick optical coupling layer in the prior art. Total reflection inside the layer, which improves light extraction efficiency.
- the thickness of the arc top light coupling layer 6 is ⁇ /4n, where ⁇ is the wavelength of light emitted by the organic light emitting layer 3; n is the refractive index of the arc top light coupling layer 6.
- the arc-top light coupling layer 6 having the above thickness has the highest light transmittance (minimum total reflection of light). It should be noted that, in the present invention, the thickness of the arc-top light coupling layer 6 is ⁇ /4n, which means that the maximum thickness of the arc-top light-coupling layer 6 is ⁇ /4n.
- the arc-top light coupling layer 6 has different thicknesses corresponding to portions of pixel units of different colors. For example, in a case where the pixel unit is divided into a red pixel unit, a green pixel unit, and a blue pixel unit, the portion of the arc top light coupling layer 6 corresponding to the red pixel unit has a first thickness, and the arc top light coupling layer 6 corresponds to the green pixel unit.
- the portion has a second thickness
- the portion of the arc-top light coupling layer 6 corresponding to the blue pixel unit has a third thickness, wherein the first thickness, the second thickness, and the third thickness are not equal to each other.
- the arc-top light coupling layer 6 has different thicknesses corresponding to portions of pixel units of different colors, which contributes to improving the optical performance of the device.
- the first electrode 2 is an anode
- the second electrode 4 is a cathode. That is, the above OLED array substrate is of a top emission type.
- the embodiment provides a method for preparing an OLED array substrate. After the thin film transistor, the first electrode 2, the organic light-emitting layer 3, and the second electrode 4 are sequentially formed on the substrate, the mask is further included.
- the plate 7 is formed by vapor deposition on the substrate 1 on which the second electrode 4 is formed to form the arc-shaped light coupling layer 6.
- the method of forming the thin film transistor, the first electrode 2, the organic light-emitting layer 3, and the second electrode 4 on the substrate can be referred to the prior art, which is not specifically limited in the present invention.
- vapor deposition of the material for forming the arc-shaped light coupling layer 6 is also in the prior art, and will not be described herein.
- a top view of a partial structure of the mask 7 used in the vapor deposition is as shown in FIG.
- the mask 7 includes a plurality of openings 71 corresponding to the respective pixel units, and each of the openings 71 corresponds to one pixel unit, and the opening 71 is configured to pass the evaporation material and form on the corresponding pixel unit.
- the opening 71 of the mask 7 is arranged to correspond to the pixel unit such that the evaporation material 8 is evaporated on the corresponding pixel unit through the opening 71 to form the arc-top light coupling layer 6.
- the opening 71 of the mask 7 is arranged to correspond to the pixel unit such that the evaporation material 8 is evaporated on the corresponding pixel unit through the opening 71 to form the arc-top light coupling layer 6.
- a cross-sectional view of the mask 7 when it is used for vapor deposition is as shown in FIG. 5, and the vapor deposition material 8 on the vapor deposition plate is vapor-deposited through the opening 71 of the mask 7 to a portion corresponding to the pixel unit on the cathode 4.
- the vapor-deposited material 8 is not vapor-deposited on the cathode 4 at a portion larger than the angle ⁇ , and the substance vapor-deposited in the middle portion of the pixel unit is thick, and the material evaporated in the edge portion of the pixel unit is thin (due to masking)
- the occlusion effect of the diaphragm is such that it is easy to form the arc-top light coupling layer 6 having a thin intermediate periphery.
- h is the thickness of the mask 7
- the thickness h of the mask 7 is 100-200 nm, and the arc-top light coupling layer 6 can be formed by appropriately controlling the thickness h of the mask 7.
- the inner rectangle in FIG. 6 corresponds to the size of the pixel unit 9, and the outer rectangle corresponds to the size of the opening 71 of the mask 7.
- the length of the opening 71 of the mask 7 (in the vertical direction in FIG. 6) is 5-20 ⁇ m longer than the length of the corresponding pixel unit 9 (the length of L2 of 2 times in FIG. 6), where L2 One end of the opening 71 is longer than the pixel unit 9 in the longitudinal direction (in the vertical direction in FIG. 6).
- the width of the opening 71 of the mask 7 (in the horizontal direction in FIG. 6) is 5-20 ⁇ m wider than the width of the corresponding pixel unit 9 (the width of L1 of 2 times in FIG. 6), where L1 is the opening 71 One end is wider than the pixel unit 9 in the width direction (horizontal direction in FIG. 6).
- the opening 71 of the mask 7 is sized to cover the corresponding pixel unit 9. Due to the shielding effect of the masking plate 7, the size of the opening 71 of the masking plate 7 is larger than the size of the corresponding pixel unit 9, and it is ensured that an arc-shaped light-coupling layer 6 having a thin intermediate periphery is formed on the pixel unit 9. It should be understood that the size relationship between the opening 71 on the mask 7 and the corresponding pixel unit 9 is suitable for the production of most products, but The dimensional relationship between the two can also be adapted to specific product or process conditions.
- the thickness of the arc-top light coupling layer 6 in the evaporation process for example, the evaporation time, the evaporation rate, the mask 7 and the evaporation material 8 and the surface to be vaporized (cathode 4)
- the distance between the two, etc., the arc-top light coupling layer 6 can be evaporated to a predetermined thickness by adjusting the above parameters, and details are not described herein again.
- the optimum thickness of the arc-top light coupling layer 6 is ⁇ /4n, where ⁇ is the wavelength of light emitted by the organic light-emitting layer 3; n is the refractive index of the arc-top light-coupling layer 6. At this time, the arc top light coupling layer 6 has the largest light transmittance and the least total light reflection;
- the vapor deposition of the arc top light coupling layer 6 may be performed using the mask 7 of the pixel unit corresponding to the color.
- the same mask 7 can be used in the production of the arc-top light coupling layer 6 corresponding to the pixel unit of different colors.
- the mask can be moved during evaporation.
- the board 7 completes the evaporation of the arc-top light coupling layer 6 corresponding to the pixel units of different colors.
- This embodiment provides an OLED display panel, including the above OLED array substrate.
- the OLED display panel provided in this embodiment may further include other known structures, such as a color film, etc., and the present invention will not be described herein.
- This embodiment provides an OLED display device including the above OLED display panel.
- the OLED display device provided in this embodiment may further include other known structures, such as a power supply unit, and the like, and the details are not described herein.
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Abstract
Description
Claims (12)
- 一种OLED阵列基板,包括基板和在所述基板上设置的多个像素单元,每个像素单元包括薄膜晶体管基以及在所述薄膜晶体管上依次设置的第一电极、有机发光层、第二电极和光耦合层,其特征在于,所述光耦合层包括与所述第二电极接触的底部和朝向光出射方向凸起的弧形顶部。
- 根据权利要求1所述的OLED阵列基板,其特征在于,所述光耦合层的厚度为λ/4n,其中,λ为所述有机发光层发出的光的波长,n为所述光耦合层的折射率。
- 根据权利要求1所述的OLED阵列基板,其特征在于,所述第一电极为阳极,所述第二电极为阴极。
- 根据权利要求1所述的OLED阵列基板,其特征在于,所述光耦合层对应不同颜色的像素单元的部分具有不同厚度。
- 一种OLED阵列基板的制作方法,其特征在于,包括步骤:采用掩膜板通过蒸镀在形成有第一电极、有机发光层和第二电极的基板上形成弧顶光耦合层。
- 如权利要求5所述OLED阵列基板的制作方法,其特征在于,所述掩膜板的厚度为100-200nm。
- 如权利要求5所述OLED阵列基板的制作方法,其特征在于,所述掩膜板包括与各像素单元对应的多个开孔,所述开孔用于使蒸镀物质通过,并在对应的像素单元上形成弧顶光耦合层;并且所述每个开孔的长度和宽度分别比对应的像素单元的长度和宽度大20-50nm。
- 如权利要求5所述OLED阵列基板的制作方法,其特征在于,所述弧顶光耦合层的厚度为λ/4n,其中,λ为所述有机发光层发出的光的波长,n为所述弧顶光耦合层的折射率。
- 如权利要求5所述OLED阵列基板的制作方法,其特征在于,制作对应不同颜色的像素单元的弧顶光耦合层时采用同一个掩膜板。
- 如权利要求5所述OLED阵列基板的制作方法,其特征在于,制作对应不同颜色的像素单元的弧顶光耦合层时采用对应该颜色的像素单元的掩膜板。
- 一种OLED显示面板,其特征在于,包括如权利要求1-4中任一项所述的OLED阵列基板。
- 一种OLED显示装置,其特征在于,包括如权利要求11所述的OLED显示面板。
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US14/761,962 US9728749B2 (en) | 2014-10-31 | 2015-04-17 | OLED array substrate, manufacturing method thereof, display panel and display device |
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CN201410602692.7A CN104319351A (zh) | 2014-10-31 | 2014-10-31 | Oled阵列基板及其制备方法、显示面板、显示装置 |
CN201410602692.7 | 2014-10-31 |
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US11588135B2 (en) | 2020-07-07 | 2023-02-21 | Avalon Holographies Inc. | Microcavity pixel array design and method |
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CN104319351A (zh) * | 2014-10-31 | 2015-01-28 | 京东方科技集团股份有限公司 | Oled阵列基板及其制备方法、显示面板、显示装置 |
CN104630703B (zh) * | 2015-01-29 | 2017-09-19 | 四川虹视显示技术有限公司 | Oled器件的掩膜板组及基板 |
CN105826354A (zh) * | 2016-04-14 | 2016-08-03 | 鄂尔多斯市源盛光电有限责任公司 | 一种阵列基板、显示面板及显示装置 |
CN106653806B (zh) * | 2016-11-30 | 2019-12-20 | 上海天马有机发光显示技术有限公司 | 一种有机发光显示面板、电子设备及其制作方法 |
CN106848097B (zh) * | 2017-02-10 | 2019-02-26 | 上海天马有机发光显示技术有限公司 | 一种有机发光显示面板、显示装置及其制作方法 |
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US11430969B2 (en) * | 2019-08-28 | 2022-08-30 | Wuhan China Star Optoelectronics Semiconductor Display Technology Co., Ltd. | Electroluminescent component having metal layer disposed between two of optical coupling layers and display device having the same |
CN110729413B (zh) * | 2019-09-25 | 2021-12-03 | 武汉华星光电半导体显示技术有限公司 | 显示面板以及显示装置 |
CN110571356B (zh) * | 2019-10-14 | 2022-04-08 | 京东方科技集团股份有限公司 | 一种发光器件、制作方法、显示面板及显示装置 |
CN113178467B (zh) * | 2021-04-14 | 2022-07-29 | 武汉华星光电半导体显示技术有限公司 | 显示面板及显示装置 |
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