WO2016013166A1 - 燃料電池装置 - Google Patents

燃料電池装置 Download PDF

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Publication number
WO2016013166A1
WO2016013166A1 PCT/JP2015/003413 JP2015003413W WO2016013166A1 WO 2016013166 A1 WO2016013166 A1 WO 2016013166A1 JP 2015003413 W JP2015003413 W JP 2015003413W WO 2016013166 A1 WO2016013166 A1 WO 2016013166A1
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WO
WIPO (PCT)
Prior art keywords
fuel cell
cell stack
combustor
cylindrical body
reformer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2015/003413
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English (en)
French (fr)
Japanese (ja)
Inventor
厚 早坂
康弘 長田
杉原　真一
佑輝 向原
悠太 今井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denso Corp
Original Assignee
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denso Corp filed Critical Denso Corp
Priority to DE112015003352.1T priority Critical patent/DE112015003352T5/de
Publication of WO2016013166A1 publication Critical patent/WO2016013166A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H01M8/04022—Heating by combustion
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/2475—Enclosures, casings or containers of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • This disclosure relates to a fuel cell device.
  • a fuel cell device is a power generation device that directly converts chemical energy of a fuel and an oxidant into electrical energy. Its power generation efficiency is very high, and the discharged gas is relatively clean, so it is attracting attention as a next-generation power generation device.
  • Hydrogen is used as the fuel, but at present, the hydrogen infrastructure is not fully developed.
  • the fuel cell device is generally provided with a reformer that reforms raw fuel (city gas, LPG, etc.) obtained from the existing infrastructure to generate hydrogen.
  • a reforming catalyst is disposed inside the reformer. In the reformer, the supplied raw fuel and steam come into contact with the high-temperature reforming catalyst to cause a reforming reaction, thereby generating hydrogen.
  • the gas containing hydrogen is supplied from the reformer to the fuel cell stack (cell stack) as fuel.
  • a combustor for heating the reformer from the outside is disposed in the vicinity of the reformer.
  • the combustor burns the remaining fuel discharged from the fuel cell stack, and heats the reformer with the generated combustion heat.
  • the reformer and the combustor are arranged in the vicinity of the fuel cell stack.
  • An air preheater that preheats air (oxidant) supplied to the fuel cell stack is also disposed in the vicinity of the fuel cell stack.
  • This indication is providing the fuel cell device which can control that a combustor deteriorates early, while making the whole compact composition.
  • a fuel cell device includes a reformer that reforms a raw fuel to generate a reformed fuel, a fuel cell stack that generates power by receiving supply of the reformed fuel and the oxidant, and And a combustor that heats the reformer by burning the reformed fuel discharged from the fuel cell stack, and a case that accommodates the fuel cell stack, the reformer, and the combustor inside.
  • the reformer and the combustor are arranged at positions where radiant heat from the fuel cell stack does not reach directly.
  • the fuel cell stack, the reformer, and the combustor are arranged in a single case, and the overall configuration is compact. Even with such a configuration, the radiant heat from the fuel cell stack does not reach the reformer and the combustor directly.
  • the reformer is not heated directly by radiant heat, and the temperature of the reformer does not rise too much, so the heat transfer from the combustor to the reformer decreases and the temperature of the combustor rises too much. Nor. As a result, it is possible to prevent the combustor from deteriorating early due to excessive temperature rise.
  • FIG. 1 is a schematic diagram illustrating an internal structure of a fuel cell device according to an embodiment of the present disclosure.
  • FIG. 2 is a perspective view showing an appearance of the reforming unit.
  • FIG. 3 is a block diagram for explaining the flow of gas and water in the fuel cell device.
  • FIG. 4 is a schematic diagram for explaining radiation inside the fuel cell device.
  • the fuel cell apparatus FC includes a fuel cell stack CS (cell stack), a casing 10, a combustor 20, and a reforming unit 30.
  • the fuel cell stack CS is an assembly of a plurality of fuel cells (not shown).
  • Each fuel cell is a solid oxide fuel cell (SOFC), and a fuel electrode (anode) is formed on one surface of a flat solid electrolyte, and the other surface.
  • SOFC solid oxide fuel cell
  • an air electrode cathode
  • These fuel electrode and air electrode are both porous bodies formed of conductive ceramics.
  • the fuel cell stack CS In the fuel cell stack CS, all the fuel cells are stacked in the vertical direction, and these are electrically connected in series.
  • the fuel cell stack CS is erected on the upper surface side of the base plate BP via the stack adapter AD.
  • the stack adapter AD is a plate-like member in which a plurality of gas flow paths (not shown) are formed. As will be described later, the fuel gas is supplied to the fuel cell stack CS via the stack adapter AD. Further, gas is discharged from the fuel cell stack CS (discharge of residual fuel gas and air that has not been used for power generation) via the stack adapter AD.
  • the base plate BP is a circular metal plate disposed horizontally within the casing 10. The internal space of the casing 10 is roughly divided into two upper and lower chambers by the base plate BP.
  • the casing 10 is a substantially cylindrical housing that houses the fuel cell stack CS, the combustor 20, the reforming unit 30, and the like.
  • the casing 10 is entirely covered with a heat insulating material (not shown) on its side surface and upper surface.
  • the casing 10 includes a first cylindrical body 110, a second cylindrical body 120, a third cylindrical body 130, a fourth cylindrical body 140, a fifth cylindrical body 150, and a sixth cylindrical body 160. And have.
  • the first cylindrical body 110, the second cylindrical body 120, the third cylindrical body 130, the fourth cylindrical body 140, the fifth cylindrical body 150, and the sixth cylindrical body 160 are all made of metal and centered. It is formed in a substantially cylindrical shape around the axis, and is arranged so that the respective central axes are coaxial.
  • FIG. 1 is a schematic cross-sectional view of a fuel cell device FC whose cross section is a plane along the central axis.
  • the first cylindrical body 110 is a cylindrical body arranged on the innermost side of the casing 10 and accommodates the fuel cell stack CS and the stack adapter AD therein.
  • the upper end of the first cylindrical body 110 is closed by a horizontal top plate 181. Further, the lower end of the first cylindrical body 110 is fixed in contact with the upper surface of the base plate BP.
  • the height from the lower end to the upper end of the first cylindrical body 110 is higher than the height from the lower end of the stack adapter AD to the upper end of the fuel cell stack CS. For this reason, the top plate 181 and the upper end of the fuel cell stack CS are separated from each other.
  • a plurality of air outlets 111 that are through holes are formed in the lower portion of the first cylindrical body 110.
  • the plurality of air outlets 111 are formed at equal intervals at the same height.
  • the blower outlet 111 is a hole through which power generation air (oxidant gas) supplied toward the fuel cell stack CS passes.
  • the second tubular body 120 is a tubular body disposed so as to surround the first tubular body 110 from the outside.
  • a constant gap is formed between the inner surface of the second cylindrical body 120 and the outer surface of the first cylindrical body 110 over the entire circumference.
  • a space formed between the second cylindrical body 120 and the first cylindrical body 110 is a flow path (air flow path 403) through which the power generation air is heated.
  • the inner diameter of the second cylindrical body 120 is substantially equal to the outer diameter of the base plate BP.
  • the inner side surface in the vicinity of the lower end portion of the second cylindrical body 120 is in contact with the side surface of the base plate BP over the entire circumference. In the contact portion, the second cylindrical body 120 is fixed to the base plate BP. With such a configuration, gas cannot enter or leave between the space below the base plate BP and the air flow path 403.
  • 3rd cylindrical body 130 is a cylindrical body arrange
  • a constant gap is formed between the inner surface of the third cylindrical body 130 and the outer surface of the second cylindrical body 120 over the entire circumference.
  • the space formed between the third cylindrical body 130 and the second cylindrical body 120 is a flow path (combustion exhaust gas flow path 411) through which high-temperature combustion exhaust gas generated by combustion in the combustor 20 passes. .
  • the upper end of the third cylindrical body 130 is disposed at a position lower than the upper end of the second cylindrical body 120.
  • the third cylindrical body 130 extends further below the lower end of the base plate BP.
  • the fourth tubular body 140 is a tubular body disposed so as to surround the third tubular body 130 from the outside. A constant gap is formed over the entire circumference between the inner surface of the fourth cylindrical body 140 and the outer surface of the third cylindrical body 130.
  • the space formed between the fourth cylindrical body 140 and the third cylindrical body 130 is a flow path (combustion exhaust gas flow path 412) through which high-temperature combustion exhaust gas generated by combustion in the combustor 20 passes. .
  • the upper end of the second cylindrical body 120 and the upper end of the fourth cylindrical body 140 have the same position in the height direction. Both are connected by the top plate 182 which is a donut-shaped disk arranged horizontally. That is, the upper end of the second cylindrical body 120 is connected to the inner peripheral end of the top plate 182, and the upper end of the fourth cylindrical body 140 is connected to the outer peripheral end of the top plate 182. A gap is formed between the upper end of the third cylindrical body 130 and the top plate 182. For this reason, the combustion exhaust gas flow path 411 and the combustion exhaust gas flow path 412 are connected to each other at their upper ends.
  • the lower end of the third cylindrical body 130 and the inner surface of the fourth cylindrical body 140 are connected by a bottom plate 183 that is a horizontally arranged donut-shaped disk. That is, the lower end of the combustion exhaust gas channel 412 is closed by the bottom plate 183.
  • a gas discharge pipe 191 is connected to the lower part of the fourth cylindrical body 140 (slightly above the bottom plate 183).
  • the internal space of the gas exhaust pipe 191 communicates with the combustion exhaust gas passage 412.
  • the gas exhaust pipe 191 is a pipe for exhausting the combustion exhaust gas that has passed through the combustion exhaust gas passage 412 to the outside of the casing 10 and supplying the exhaust gas to the exhaust heat recovery unit 62 described later.
  • the fourth tubular body 140 extends further downward than the lower end of the third tubular body 130.
  • a horizontal flange portion 141 extending outward from the lower end is formed at the lower end of the fourth cylindrical body 140.
  • the flange portion 141 is a flange used for fixing the casing 10 when the fuel cell device FC is installed.
  • a bottom plate 184 that is a horizontal disc is disposed.
  • the outer diameter of the bottom plate 184 is substantially equal to the inner diameter of the fourth cylindrical body 140.
  • the bottom plate 184 is fixed in a state where the entire outer surface thereof is in contact with the inner surface of the fourth cylindrical body 140.
  • a heat insulating material TI is disposed in the space below the bottom plate 184.
  • the fifth cylindrical body 150 is a cylindrical body arranged on the outermost side of the casing 10, and is arranged so as to surround the upper part of the fourth cylindrical body 140 from the outside.
  • a constant gap is formed between the inner side surface of the fifth cylindrical body 150 and the outer side surface of the fourth cylindrical body 140 over the entire circumference.
  • a space formed between the fifth cylindrical body 150 and the fourth cylindrical body 140 is a flow path (air flow path 401) through which power generation air is heated.
  • the fifth cylindrical body 150 extends further upward than the upper ends of any of the first cylindrical body 110, the second cylindrical body 120, the third cylindrical body 130, and the fourth cylindrical body 140.
  • the upper end of the fifth cylindrical body 150 is closed by a horizontal top plate 185.
  • a gap 402 is formed between the top plate 185 and the top plate 182.
  • the upper end portion of the air flow path 401 and the upper end portion of the air flow path 403 are connected to each other through a gap 402.
  • the lower end of the fifth cylindrical body 150 and the outer surface of the fourth cylindrical body 140 are connected to each other by a bottom plate 186 that is a horizontally arranged donut-shaped disk. That is, the lower end of the air flow path 401 is blocked by the bottom plate 186.
  • An air introduction pipe 192 is connected to the lower part of the fifth cylindrical body 150 (slightly above the bottom plate 186). The internal space of the air introduction pipe 192 communicates with the air flow path 401.
  • the air introduction pipe 192 is a pipe for introducing power generation air into the casing 10.
  • the sixth cylindrical body 160 is a cylindrical body arranged at a position inside the third cylindrical body 130 and on the lower side of the base plate BP.
  • the sixth cylindrical body 160 has an upper cylindrical portion 161 that is an upper portion and a lower cylindrical portion 162 that is a lower portion.
  • the diameter of the upper cylindrical portion 161 is smaller than the diameter of the lower cylindrical portion 162.
  • the lower end of the upper cylindrical portion 161 and the upper end of the lower cylindrical portion 162 are connected by an intermediate portion 163 that is a horizontally arranged donut-shaped disk.
  • the upper end of the upper cylindrical portion 161 is in contact with the lower surface of the base plate BP.
  • the lower end of the lower cylindrical portion 162 is in contact with the upper surface of the bottom plate 184.
  • the diameter of the lower cylindrical portion 162 is smaller than the diameter of the third cylindrical body 130. Therefore, a gap is formed between the third cylindrical body 130 and the sixth cylindrical body 160 over the entire circumference. Further, the reforming unit 30 is disposed in the gap, but a gap is also formed between the reforming unit 30 and the sixth cylindrical body 160 over the entire circumference.
  • the space formed inside the sixth cylindrical body 160 is also referred to as “inner space 601”.
  • a space formed between the lower cylindrical portion 162 of the sixth cylindrical body 160 and the inner cylinder 320 of the reforming unit 30 is also referred to as “outer space 602”.
  • a plurality of outlets 165 that are through holes are formed at a position lower than the lower end portion of the reforming unit 30.
  • the plurality of outlets 165 are formed so as to be arranged at equal intervals at the same height.
  • the inner space 601 and the outer space 602 are communicated with each other through these outlets 165.
  • the outlet 165 is a hole through which high-temperature flue gas generated by combustion in the combustor 20 passes.
  • the combustor 20 mixes and burns residual fuel gas that has not been used for power generation (hereinafter also referred to as “residual fuel”) and residual air that has not been used for power generation (hereinafter also referred to as “residual air”).
  • the combustor 20 is made of stainless steel.
  • the entire combustor 20 is formed in a substantially cylindrical shape, and is disposed so as to protrude downward from the center of the lower surface of the base plate BP. Further, the combustor 20 is arranged at a position (a position along the central axis of the upper cylindrical portion 161) that is the center of the casing 10 in a top view.
  • Residual fuel and residual air discharged from the fuel cell stack CS are combusted through a flow path (not shown) formed in the stack adapter AD and a flow path (not shown) formed in the base plate BP.
  • a flow path (not shown) formed in the stack adapter AD To the upper end of the vessel 20. Thereafter, the residual fuel and the residual air reach the lower end portion of the combustor 20 through a flow path (not shown) formed in the combustor 20, and are jetted downward while being mixed at the lower end portion. .
  • the ejected residual fuel and residual air are combusted, and high-temperature combustion exhaust gas is generated. Further, the combustor 20 itself also becomes high temperature due to the heat of the combustion.
  • An igniter IG is disposed below the combustor 20.
  • the igniter IG is an apparatus for igniting a mixed gas of residual fuel and residual air ejected from the combustor 20 and starting combustion.
  • the igniter IG penetrates the bottom plate 184 and the heat insulating material TI up and down, and is arranged in a state where an upper end portion where spark discharge is generated is brought close to the lower end of the combustor 20. Ignition by the igniter IG is performed when the fuel cell device FC is started.
  • the reforming unit 30 includes a reformer 302 that generates fuel gas (reformed fuel: hydrogen-containing gas) from city gas (raw fuel) by a reforming reaction, and an evaporation that generates steam and supplies the steam to the reformer 302.
  • the unit 301 is integrated.
  • the reforming unit 30 has a substantially cylindrical shape as a whole (see FIG. 2), and is disposed in the space between the third cylindrical body 130 and the sixth cylindrical body 160 in the casing 10. Yes.
  • the reforming unit 30 includes an outer cylinder 310, an inner cylinder 320, a top plate 330, a first bottom plate 340, a second bottom plate 350, a first partition plate 360, and a second partition plate 370. Yes.
  • the portion below the first bottom plate 340 is the portion of the reforming unit 30.
  • the outline is defined.
  • the outer cylinder 310 is a cylindrical body that forms the outer surface of the reforming unit 30.
  • the central axis of the outer cylinder 310 coincides with the central axis of the third cylindrical body 130.
  • the outer diameter of the outer cylinder 310 is substantially equal to the inner diameter of the third cylindrical body 130.
  • the outer cylinder 310 is substantially in contact with the inner surface of the third cylindrical body 130 on the entire outer surface.
  • the outer cylinder 310 extends further downward than the bottom plate 183.
  • the inner cylinder 320 is a cylindrical body that forms the inner surface of the reforming unit 30.
  • the central axis of the inner cylinder 320 coincides with the central axis of the third cylindrical body 130.
  • the outer diameter of the inner cylinder 320 is smaller than the inner diameter of the outer cylinder 310. For this reason, a space is formed between the outer cylinder 310 and the inner cylinder 320. As will be described later, a part of the space is a space in which water flows as water vapor. Further, another part of the space is a space in which a reforming reaction occurs and fuel gas is generated.
  • the inner diameter of the inner cylinder 320 is larger than the outer diameter of the lower cylindrical portion 162 of the third cylindrical body 130. For this reason, as already described, a gap is formed between the reforming unit 30 and the sixth cylindrical body 160 over the entire circumference.
  • the height of the upper end of the inner cylinder 320 is the same as the height of the upper end of the outer cylinder 310.
  • the lower end of the inner cylinder 320 is higher than the lower end of the outer cylinder 310 and is the same as the lower end of the bottom plate 183.
  • the top plate 330 is a donut-shaped disk arranged horizontally.
  • the outer surface of the top plate 330 is connected to the upper end portion of the inner surface of the outer cylinder 310. Further, the inner surface of the top plate 330 is connected to the upper end portion of the outer surface of the inner cylinder 320. Thus, the top plate 330 connects the upper end of the outer cylinder 310 and the upper end of the inner cylinder 320.
  • the first bottom plate 340 is a donut-shaped disk arranged horizontally.
  • the first bottom plate 340 is disposed at the same height as the bottom plate 183.
  • the outer surface of the first bottom plate 340 is connected to the inner surface of the first partition plate 360 described later. Further, the inner side surface of the first bottom plate 340 is connected to the lower end portion of the inner side surface of the inner cylinder 320.
  • the second bottom plate 350 is a donut-shaped disk arranged horizontally.
  • the outer surface of the second bottom plate 350 is connected to the lower end portion of the inner surface of the outer cylinder 310.
  • the inner side surface of the second bottom plate 350 is connected to the lower end portion of the outer side surface of the first partition plate 360 described later. For this reason, the second bottom plate 350 is disposed at a position lower than the first bottom plate 340.
  • the first partition plate 360 is a cylindrical body part of which is disposed inside the reforming unit 30.
  • the central axis of the first partition plate 360 coincides with the central axis of the outer cylinder 310 and the central axis of the inner cylinder 320.
  • the outer diameter of the first partition plate 360 is smaller than the inner diameter of the outer cylinder 310. Therefore, a constant gap is formed between the outer cylinder 310 and the first partition plate 360 over the entire circumference.
  • the height of the upper end of the first partition plate 360 is lower than the height of the upper end of the outer cylinder 310. For this reason, there is a gap between the upper end of the first partition plate 360 and the lower surface of the top plate 330.
  • the height of the lower end of the first partition plate 360 is the same as the height of the lower end of the outer cylinder 310.
  • the second bottom plate 350 is connected to the lower end of the first partition plate 360 from the outside.
  • a first bottom plate 340 is connected to the first partition plate 360 from the inside.
  • the second partition plate 370 is a cylindrical body that is entirely disposed inside the reforming unit 30.
  • the central axis of the second partition plate 370 coincides with the central axis of the outer cylinder 310 and the central axis of the inner cylinder 320.
  • the outer diameter of the second partition plate 370 is smaller than the inner diameter of the first partition plate 360. For this reason, a fixed gap is formed between the second partition plate 370 and the first partition plate 360 over the entire circumference.
  • the inner diameter of the second partition plate 370 is larger than the outer diameter of the inner cylinder 320. For this reason, a constant gap is formed between the second partition plate 370 and the inner cylinder 320 over the entire circumference.
  • the second partition plate 370 is fixed to the top plate 330 with its upper end in contact with the bottom surface of the top plate 330.
  • the height of the lower end of the second partition plate 370 is higher than the height of the lower end of the inner cylinder 320. For this reason, there is a gap between the lower end of the second partition plate 370 and the upper surface of the first bottom plate 340.
  • the reforming unit 30 has a first space 381, which is a space formed between the outer cylinder 310 and the first partition plate 360, and the first partition plate 360 and the second partition plate.
  • a second space 382 that is a space formed between the second partition 370 and a third space 383 that is a space formed between the second partition plate 370 and the inner cylinder 320 is formed.
  • the first space 381 and the second space 382 are connected above the first partition plate 360, and the second space 382 and the third space 383 are connected below the second partition plate 370.
  • a water supply pipe 391 is connected to the second bottom plate 350 from below.
  • the water supply pipe 391 is a pipe for supplying water to the first space 381.
  • the other end of the water supply pipe 391 is connected to a water supply pump (not shown) disposed outside the casing 10.
  • the water supplied from the water supply pipe 391 into the first space 381 is heated by the high-temperature combustion exhaust gas passing through the combustion exhaust gas passage 412 to become steam.
  • the water vapor passes through the first space 381 and the second space 382 in order, and reaches the inlet of the third space 383.
  • the first space 381, the second space 382, and the wall surface partitioning them correspond to a portion that receives water supply from the outside and generates water vapor, that is, the evaporator 301. It has become a part.
  • a support plate 352 is disposed in the first space 381.
  • the support plate 352 is a donut-shaped plate that is horizontally disposed so as to partition the first space 381 vertically.
  • the support plate 352 is fixed to the outer cylinder 310 and the first partition plate 360 at the same height as the first bottom plate 340.
  • a plurality of through holes are formed in the support plate 352 so that water can pass through the support plate 352.
  • a heat transfer promoting member CB for promoting heat transfer from the outer cylinder 310 to water is filled in the first space 381 above the support plate 352.
  • the heat transfer promoting member CB is a plurality of alumina spheres (ceramic balls).
  • the city gas supply pipe 392 is a pipe for supplying city gas to the entrance portion of the third space 383.
  • the other end of the city gas supply pipe 392 is connected to a desulfurizer 61 (see FIG. 3).
  • the third space 383 is filled with the reforming catalyst RC.
  • the reforming catalyst RC is a catalyst in which a catalytic metal such as nickel is supported on the surface of an alumina sphere.
  • a horizontal metal mesh (not shown) is fixed at a position slightly higher than the lower end of the second partition plate 370 in the third space 383, and the reforming catalyst RC is moved downward by the metal mesh. Supported by
  • the city gas supplied from the city gas supply pipe 392 to the inside of the reforming unit 30 is mixed with water vapor at the entrance of the third space 383 and then moves upward in the third space 383. Flowing.
  • the gas reforming reaction occurs when the city gas and steam touch the reforming catalyst RC, and fuel gas (hydrogen-containing gas) is generated.
  • the third space 383 and the wall surface partitioning the third space 383 are a portion where the steam reforming reaction occurs due to the supply of steam from the evaporator 301 and the supply of city gas from the outside. That is, it is a part corresponding to the reformer 302.
  • the reforming catalyst RC is filled over the entire circumferential direction of the third space 383. For this reason, the water vapor supplied from the evaporator 301 does not pass through the third space 383 without touching the reforming catalyst RC.
  • the fuel gas supply pipe 393 is a pipe for supplying the fuel gas generated in the reforming unit 30 (the reformer 302) to the fuel cell stack CS.
  • the other end of the fuel gas supply pipe 393 is connected to the lower surface of the base plate BP.
  • the fuel gas reaches the base plate BP from the upper part of the third space 383 through the fuel gas supply pipe 393.
  • the fuel cell stack CS is supplied to the fuel cell stack CS through a flow path (not shown) formed in the base plate BP and a flow path (not shown) formed in the stack adapter AD.
  • the fuel gas supply pipe 393 has a horizontal portion 393a, a curved portion 393b, and a vertical portion 393c in order from the upstream side (see FIG. 2).
  • the horizontal portion 393 a is a pipe that extends horizontally from the inner cylinder 320 toward the central axis of the inner cylinder 320.
  • the curved portion 393b is a pipe that extends in an arc shape around the central axis of the inner cylinder 320 from the downstream end of the horizontal portion 393a.
  • the vertical portion 393c is a pipe extending vertically upward from the downstream end portion of the bending portion 393b.
  • the fuel gas supply pipe 393 is formed in such a shape, the entire fuel gas supply pipe 393 is easily bent, and a large thermal stress does not occur even when the fuel cell apparatus FC is heated and thermally expanded during operation. . As a result, the reforming unit 30, the base plate BP, and the fuel gas supply pipe 393 are prevented from being damaged due to thermal stress.
  • the reforming unit 30 is supported from below by a cylindrical seal block SB made of a heat resistant material.
  • the upper end of the seal block SB is in contact with the lower surface (first bottom plate 340) of the reforming unit 30, and the lower end is in contact with the upper surface of the bottom plate 184.
  • the inner diameter of the seal block SB is equal to the inner diameter of the reforming unit 30.
  • the dimension (thickness) in the radial direction of the seal block SB is smaller than the dimension (thickness) in the radial direction of the reforming unit 30. For this reason, as shown in FIG. 1, a space SP is formed outside the seal block SB (below the reforming unit 30).
  • the space outside the sixth cylindrical body 160 and the space SP are separated by the reforming unit 30 and the seal block SB, and gas cannot pass between them. Since high-temperature combustion exhaust gas does not flow into the space SP, the temperature in the space SP is kept relatively low.
  • Air is supplied from the blower (not shown) disposed outside the casing 10 to the inside of the casing 10 through the air introduction pipe 192.
  • the air supplied through the air introduction pipe 192 flows upward through the air flow path 401. Thereafter, the air flows into the air flow path 403 via the gap 402 and flows downward in the air flow path 403.
  • a combustion exhaust gas channel 411 and a combustion exhaust gas channel 412 are formed. Inside the combustion exhaust gas channel 411 and the combustion exhaust gas channel 412, high-temperature combustion exhaust gas passes. For this reason, the air introduced into the casing 10 is heated by the combustion exhaust gas while passing through the air flow path 401 and the air flow path 403 to increase its temperature. That is, heat exchange is performed between air and combustion exhaust gas.
  • the fuel cell stack CS is at a high temperature during power generation, and the first cylindrical body 110 is also at a high temperature due to radiant heat from the fuel cell stack CS. For this reason, the air is further heated by touching the first tubular body 110 when passing through the air flow path 403.
  • the air flow path 401 and the air flow path 403 are flow paths that flow while the air is heated by the heat of the combustion exhaust gas and the radiant heat from the fuel cell stack CS.
  • the air flow path 401 and the air flow path 403 are collectively referred to as “air heating flow path 40”.
  • the air heating channel 40 is disposed so as to surround the fuel cell stack CS from the side.
  • the air heating channel 40 corresponds to a “preheater” that exchanges heat between combustion exhaust heat (heat of combustion exhaust gas) generated by combustion in the combustor 20 and air supplied to the fuel cell stack CS. It can be said that
  • the air that has reached the lower part of the air flow path 403 is ejected from the air outlet 111 formed in the first tubular body 110 toward the fuel cell stack CS. Thereafter, the air reaches the air electrode of each fuel battery cell and is used for power generation.
  • the flow of the fuel gas supplied to the fuel cell stack CS and the flow of the city gas that is the raw material of the fuel gas will be described.
  • the city gas is supplied from the outside of the casing 10 into the reforming unit 30 through the city gas supply pipe 392.
  • a desulfurizer 61 is disposed between the city gas supply source and the city gas supply pipe 392.
  • the desulfurizer 61 is a device for removing sulfur components contained in city gas.
  • the city gas is supplied into the reforming unit 30 after the sulfur component that adversely affects the performance of the fuel cell is removed by the desulfurizer 61.
  • the city gas supplied from the city gas supply pipe 392 to the inside of the reforming unit 30 is mixed with water vapor at the entrance of the third space 383. Thereafter, it flows upward in the third space 383 filled with the reforming catalyst RC.
  • High-temperature combustion exhaust gas passes through a space formed between the lower cylindrical portion 162 of the sixth cylindrical body 160 and the inner cylinder 320 of the reforming unit 30. For this reason, the city gas and water vapor are heated by the combustion exhaust gas while passing through the third space 383, and the temperature thereof is increased. That is, heat exchange is performed between the city gas and water vapor and the combustion exhaust gas.
  • the reforming catalyst RC filled in the third space 383 is also at a high temperature due to heat transfer through the inner cylinder 320.
  • the sixth cylindrical body 160 surrounding the combustor 20 is heated by the radiant heat from the combustor 20 in addition to being heated by the combustion exhaust gas, and thus is very hot.
  • the radiant heat from the sixth cylindrical body 160 that has reached a high temperature also referred to as radiant heat reached from the combustor 20 via the sixth cylindrical body 160
  • the inner cylinder 320 of the reforming unit 30 reaches the inner cylinder 320 of the reforming unit 30. is doing. That is, the reformer 302 including the inner cylinder 320 is heated not only by the combustion exhaust gas but also by the radiant heat from the combustor 20.
  • the fuel gas generated in the reformer 302 is supplied to the fuel cell stack CS through the fuel gas supply pipe 393 and the flow path in the stack adapter AD.
  • the fuel gas reaches the fuel electrode of each fuel cell and is used for power generation.
  • the combustion exhaust gas flows upward in the outer space 602 along the inner cylinder 320.
  • the heat of the combustion exhaust gas is transmitted to the third space 383 through the inner cylinder 320 and used as part of the heat for maintaining the steam reforming reaction.
  • the flue gas that has passed through the outer space 602 flows upward through the flue gas passage 411 while exchanging heat with the air flowing through the air passage 403. Subsequently, while exchanging heat with the air flowing through the air flow path 401, it flows downward through the combustion exhaust gas flow path 412.
  • the outer cylinder 310 of the reforming unit 30 is in contact with the inner surface of the third cylindrical body 130 at a portion above the support plate 352. For this reason, the outer cylinder 310 is at a high temperature due to the combustion exhaust gas passing through the combustion exhaust gas passage 412.
  • Water supplied from the water supply pipe 391 into the first space 381 is heated by heat transfer from the outer cylinder 310 (heat of combustion exhaust gas) to become steam. That is, heat exchange is performed between the water and the combustion exhaust gas, whereby water vapor is generated in the first space 381.
  • the combustion exhaust gas that has reached the lower end of the combustion exhaust gas passage 412 is supplied to the exhaust heat recovery device 62 through the gas exhaust pipe 191.
  • the exhaust heat recovery device 62 generates hot water by exchanging heat between the combustion exhaust gas and water.
  • the fuel cell apparatus FC can generate hot water in addition to generating power, and is a cogeneration system that uses energy with high efficiency.
  • Water is supplied to the reforming unit 30 (evaporator 301) through a water supply pipe 391 from a water supply pump (not shown) arranged outside the casing 10.
  • the water supply pipe 391 is connected to the second bottom plate 350 from below. For this reason, the supplied water first accumulates in a space formed in the lower portion of the first space 381. Specifically, the first space 381 accumulates in the water storage section WS that is a space below the support plate 352.
  • the water reservoir WS includes a portion of the outer cylinder 310 that is below the bottom plate 183 (hereinafter, this portion is also referred to as “partition wall 311”), a second bottom plate 350, and a first partition plate 360 of the first partition plate 360. It is a space partitioned by a portion below the bottom plate 340 (hereinafter, this portion is also expressed as “partition wall 361”).
  • the partition wall 311, the second bottom plate 350, and the partition wall 361 that partition the water storage section WS are shaped such that a part of the bottom surface of the reforming unit 30 extends downward. ing. These are all arranged in the space SP (see FIG. 1). That is, the high-temperature combustion exhaust gas does not reach and is disposed in a relatively low temperature space.
  • the partition wall 311 is not directly heated by the combustion exhaust gas because the partition wall 311 is disposed below the bottom plate 183. For this reason, water does not boil in the water reservoir WS, and the entire water reservoir WS is filled with water (liquid).
  • the height of the water surface in the first space 381 is maintained at a position slightly higher than the upper surface of the support plate 352. For this reason, the heat transfer promoting member CB (alumina sphere) filled on the upper side of the support plate 352 is partially submerged.
  • the heat transfer promotion member CB is also at a high temperature due to heat transfer from the outer cylinder 310 that is at a high temperature due to the combustion exhaust gas.
  • the water present above the support plate 352 boils by being in contact with the high-temperature heat transfer promotion member CB, and becomes water vapor.
  • the radiant heat from the fuel cell stack CS is dissipated toward the periphery thereof.
  • the radiant heat radiated from the fuel cell stack CS toward the periphery is indicated by an arrow with a symbol RD1.
  • the radiant heat radiated from the fuel cell stack CS is also referred to as “radiant heat RD1”.
  • the air heating flow path 40 including the air flow path 401 and the air flow path 403 is arranged so that substantially the whole surrounds the fuel cell stack CS from the side. Further, there is no shield between the fuel cell stack CS and the air heating channel 40 that blocks the radiant heat RD1 from the fuel cell stack CS. Since the radiant heat RD1 reaches the air heating channel 40 directly, the air in the air heating channel 40 is efficiently heated.
  • the temperature of the air flowing through the air heating channel 40 is lower than the temperature of the fuel cell stack CS.
  • the temperature of the first cylindrical body 110 is lower than the temperature of the fuel cell stack CS.
  • the fuel cell stack CS is surrounded by the low-temperature air heating flow path 40 (preheater) and is cooled by radiation.
  • the fuel cell stack CS is surrounded by the low-temperature air heating flow path 40 (preheater) and is cooled by radiation.
  • the reformer 302 and the combustor 20 have a compact configuration in which the reformer 302 and the combustor 20 are arranged in a single case, but are caused by radiant heat from the fuel cell stack CS. Deterioration of the combustor 20 is suppressed.
  • the entire periphery of the fuel cell stack CS is surrounded by a reformer (not the air heating channel 40). It is done.
  • the entire wide range from the lower end to the upper end of the fuel cell stack CS needs to be surrounded by a reformer (a flow path filled with a reforming catalyst).
  • a reformer a flow path filled with a reforming catalyst.
  • the entire periphery of the fuel cell stack CS is surrounded by the air heating flow path 40 as in this embodiment, the entire wide range from the lower end to the upper end of the fuel cell stack CS is air. Even in the configuration surrounded by the heating channel 40, the channel resistance of the air heating channel 40 does not become too large.
  • the internal space of the casing 10 is roughly divided into two upper and lower chambers by a base plate BP which is a plate along a horizontal plane.
  • the fuel cell stack CS is disposed in a space above the base plate BP, and both the combustor 20 and the reforming unit 30 are disposed in a space below the base plate BP.
  • the radiant heat RD1 from the fuel cell stack CS is blocked by the base plate BP and does not directly reach the combustor 20 and the reforming unit 30.
  • the reforming unit 30 (reformer 302) and the combustor 20 are arranged in the casing 10 at a position where the radiant heat RD1 from the fuel cell stack CS does not reach directly. For this reason, the combustor 20 is not directly heated by the radiant heat RD1, and it is suppressed that the combustor 20 deteriorates or is damaged due to excessive temperature rise.
  • the base plate BP corresponds to the “shielding plate” of the present disclosure.
  • the combustor 20 is at a higher temperature than the fuel cell stack CS. For this reason, radiant heat is dissipated from the combustor 20 toward the surroundings.
  • the radiant heat radiated from the combustor 20 to the surroundings is indicated by an arrow with a symbol RD2.
  • the radiant heat radiated from the combustor 20 is also referred to as “radiant heat RD2”.
  • the reforming unit 30 including the reformer 302 is disposed so as to surround the combustor 20 from the side.
  • the reformer 302 is heated by the radiant heat RD2, and the steam reforming reaction (endothermic reaction) occurs stably in the reformer 302.
  • the temperature of the reforming unit 30 is lower than the temperature of the combustor 20. For this reason, it can be said that the combustor 20 is surrounded by the low-temperature reforming unit 30 and is cooled by radiation. With such a configuration, the combustor 20 is prevented from becoming too hot and deteriorating.
  • the radiant heat RD2 from the combustor 20 is blocked by the base plate BP, and does not reach the fuel cell stack CS directly. For this reason, the possibility that the fuel cell stack CS becomes too high is further reduced.
  • the air heating flow path 40 is disposed on the side (periphery) of the fuel cell stack CS, and the combustor 20 and the reformer 302 are not disposed. As a result, it is not necessary to form a complicated flow path surrounding the fuel cell stack CS from the side, and the inside of the casing 10 has a relatively simple configuration.

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PCT/JP2015/003413 2014-07-22 2015-07-07 燃料電池装置 Ceased WO2016013166A1 (ja)

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WO2011067930A1 (ja) * 2009-12-03 2011-06-09 パナソニック株式会社 燃料電池システム及び燃料電池システムのメンテナンス方法
JP2011238363A (ja) * 2010-05-06 2011-11-24 Kawasaki Heavy Ind Ltd 燃料電池

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US4808491A (en) * 1988-02-16 1989-02-28 Westinghouse Electric Corp. Corner heating in rectangular solid oxide electrochemical cell generators
JP5429748B2 (ja) * 2009-12-15 2014-02-26 アイシン精機株式会社 燃料電池モジュール
JP5851968B2 (ja) * 2012-10-09 2016-02-03 本田技研工業株式会社 燃料電池モジュール

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WO2011067930A1 (ja) * 2009-12-03 2011-06-09 パナソニック株式会社 燃料電池システム及び燃料電池システムのメンテナンス方法
JP2011238363A (ja) * 2010-05-06 2011-11-24 Kawasaki Heavy Ind Ltd 燃料電池

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