WO2015178440A1 - Système d'addition d'hydrogène et récipient pour liquide utilisé dans ledit système - Google Patents

Système d'addition d'hydrogène et récipient pour liquide utilisé dans ledit système Download PDF

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Publication number
WO2015178440A1
WO2015178440A1 PCT/JP2015/064548 JP2015064548W WO2015178440A1 WO 2015178440 A1 WO2015178440 A1 WO 2015178440A1 JP 2015064548 W JP2015064548 W JP 2015064548W WO 2015178440 A1 WO2015178440 A1 WO 2015178440A1
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WIPO (PCT)
Prior art keywords
hydrogen gas
hydrogen
liquid container
gas supply
liquid
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Application number
PCT/JP2015/064548
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English (en)
Japanese (ja)
Inventor
総 橋本
Original Assignee
株式会社ドクターズ・マン
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Filing date
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Application filed by 株式会社ドクターズ・マン filed Critical 株式会社ドクターズ・マン
Publication of WO2015178440A1 publication Critical patent/WO2015178440A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water

Definitions

  • the present invention relates to a system for adding hydrogen to a liquid by a simple technique, and a liquid container used in the system.
  • Patent Document 1 As an apparatus for producing hydrogen water, for example, there is one disclosed in Patent Document 1. This is a factory facility for producing hydrogen water by introducing hydrogen generated in the hydrogen generation section to a pressure tank and cannot be easily used at home or the like.
  • a test tube (Spitz) filled with a hydrogen generating material is placed in a container such as a plastic bottle containing water, the cap with a check valve is closed, and hydrogen water is produced in the container.
  • a container such as a plastic bottle containing water
  • the cap with a check valve is closed, and hydrogen water is produced in the container.
  • Spitz is made to be used exclusively for a specific volume of PET bottles.
  • Spitz used for a 500 ml PET bottle contains a hydrogen generating material in an amount corresponding thereto, and the amount of hydrogen generating material required varies depending on the capacity of the target PET bottle. Therefore, the following problems remain.
  • the hydrogen concentration increases, but the pressure becomes excessive and exceeds the pressure resistance of the PET bottle.
  • the hydrogen concentration is lower than the expected value. That is, it is necessary to prepare a dedicated spitz for each capacity of the PET bottle, which is inferior in versatility.
  • JP 2013-22567 A Japanese Patent No. 4651479 Japanese Patent No. 5095020
  • the present invention was devised in view of the current state of the prior art, and its purpose is to add high-concentration hydrogen to a liquid regardless of the size of the container by a simple and versatile technique. It is to provide means.
  • the hydrogenation system of the present invention includes a “hydrogen gas generator that extracts hydrogen gas from water (preferably purified water) under pressure control” and a “hydrogen gas supply that supplies hydrogen gas generated by the hydrogen gas generator to the outside” ”And“ a liquid container that is open when connected to the hydrogen gas supply path and is connected to the hydrogen gas supply path by an opening / closing means that closes when the connection is disconnected and that can contain liquid therein ” With.
  • the “liquid” referred to here is typically water, tea, coffee, any other beverage, and an electrolyte solution (physiological saline solution, infusion solution containing an electrolyte, etc.) used for medical purposes.
  • the hydrogen obtained therefrom is added to the liquid. That is, since no hydrogen gas cylinder is used, it is possible to easily add hydrogen to the liquid with a compact device that can be easily installed at home, office, other sports clubs, and the like.
  • the hydrogen gas generator used in the present invention can take out hydrogen gas under pressure control, and the pressure of the generated hydrogen gas can be set to about 0.2 to 0.5 MPa, for example. In that case, since it does not become 1 MPa or more, it does not correspond to the high-pressure gas referred to in the high-pressure gas safety law, and it is not necessary to install a gas leak detector compliant with the law.
  • a hydrogen gas generator that can control the pressure of the generated hydrogen gas is used. Therefore, according to Henry's law, a hydrogen addition amount corresponding to the adjusted gas pressure can be realized, so that high concentration hydrogen can be added in the same manner regardless of the size of the liquid container.
  • Henry's law is a law concerning the amount of gas that can be dissolved in a liquid. In short, the gas in contact with the liquid can be dissolved in the liquid in an amount proportional to the pressure. That is, the higher the hydrogen gas pressure is, the more hydrogen gas can be added.
  • a consumer can make a beverage with added hydrogen (for example, hydrogen water) on the spot when he / she wants to drink it.
  • hydrogen for example, hydrogen water
  • an electrolyte solution physiological saline solution, infusion solution containing an electrolyte, etc.
  • hydrogen water produced in factories has been sold in plastic bottles, aluminum pouches and cans, but since hydrogen was released over time after hydrogen was added, there was dissatisfaction with the hydrogen concentration.
  • hydrogen gas is extracted from “water” using a hydrogen gas generator, but the “water” to be used is preferably “purified water”.
  • Purified water generally means “water” from which impurities have been removed by techniques such as distillation, filtration, and ion exchange. “Purified water” is available at a low price in the general market. Once the hydrogenation system of the present invention is installed, it can be continuously used by replenishing water (preferably purified water) thereafter, and therefore has an advantage of low running costs.
  • the liquid container of the present invention is suitable for use in the above hydrogenation system, and includes “opening / closing means that opens when connected to an external hydrogen gas supply path and closes when the connection is disconnected”.
  • the liquid can be stored inside.
  • the opening / closing means provided in the liquid container is preferably composed of one or both of a detachable plug and a socket, but a check valve or the like may be used.
  • FIG. 1 is an external perspective view of a hydrogenation system according to an embodiment of the present invention.
  • the block diagram which shows the internal mechanism about the hydrogen gas generator in FIG.
  • the perspective view which expands and demonstrates the liquid container in FIG.
  • the present invention relates to adding hydrogen to a liquid such as a beverage or a medical electrolyte solution.
  • a liquid such as a beverage or a medical electrolyte solution.
  • Hydrogen can be added to the medical electrolyte solution in the same manner.
  • a hydrogen gas generator 10 used in the present invention will be described with reference to FIGS.
  • a hydrogen gas generator that can take out hydrogen gas from the charged water (preferably purified water) under pressure control is used.
  • Such a hydrogen gas generator itself is generally known, and any hydrogen gas generator can be used in the present invention as long as it has such a function.
  • FIG. 1 shows the external appearance of the hydrogen gas generator 10, and FIG. 2 is a block diagram schematically showing its internal mechanism.
  • the cap 11 is opened and purified water is poured into the water tank 12 in the apparatus. The amount of water in the tank can be confirmed from a window 18 provided on the apparatus wall surface.
  • Purified water is sent from the water tank 12 to the electrolysis cell 13 while the switch 17 is turned on and the electrolysis cell 13 is energized.
  • a chemical reaction represented by the following formula (1) occurs on the anode side of the electrolytic cell 13, a chemical reaction represented by the following formula (1) occurs.
  • Formula (1) 2H 2 O ⁇ O 2 + 4H + + 4e ⁇ Part of the generated oxygen (O 2 ) and water (H 2 O) is returned to the water tank 12 from the anode side of the electrolysis cell 13.
  • a chemical reaction represented by the following formula (2) occurs on the cathode side of the electrolytic cell 13.
  • Formula (2): 4H + + 4e ⁇ ⁇ 2H 2 Part of the generated hydrogen gas (2H 2 ) and water (H 2 O) is sent from the cathode side of the electrolysis cell 13 to the hydrogen separation tank 14.
  • water is returned from the hydrogen separation tank 14 to the water tank 12.
  • the hydrogen gas stored in the hydrogen separation tank 14 flows into an external hydrogen gas supply tube (hydrogen gas supply path) 30 through the connection portion 20.
  • a pressure sensor 15 and a pressure gauge 16 are provided in a flow path 19 from the hydrogen separation tank 14 to the connection portion 20 in the hydrogen gas generator 10, and the hydrogen gas pressure detected by the sensor is displayed on the pressure gauge 16. Is done.
  • the pressure gauge 16 is arranged on the apparatus wall surface and can read the value from the outside.
  • the power supplied to the electrolysis cell 13 is controlled as follows so that the hydrogen gas pressure discharged to the outside from the connection portion 20 is kept constant. That is, the output of the DC power source 19 is controlled using the output from the pressure sensor 15 to keep the gas pressure at a constant value.
  • the fixed value may be fixed, or may be changed by the user operating a lever or the like. In either case, it may be realized by a generally known method and is not a point of the present invention, and therefore will not be described in detail here.
  • a hydrogen gas generator that generates hydrogen gas by using water is used without using a hydrogen gas cylinder. Therefore, the entire system can be made compact, and sports clubs and homes can be made compact. It can be installed in an office or other suitable place.
  • the size of the hydrogen gas generator 10 can be designed to be, for example, about a width (37 cm), a depth (44 cm), a height (36 cm), or less, and therefore has a great advantage in terms of compactness.
  • Liquid container 80 Is connected to the hydrogen gas generator 10 via a coupler 50 (opening / closing means) located at the tip of a hydrogen gas supply tube (hydrogen gas supply path) 30. Although details will be described later, in FIG. 1A, the coupler 50 is disconnected, and in FIG. 1B, the coupler 50 is connected.
  • FIG. 3 shows an enlarged detail of the liquid container 80 in FIG.
  • the liquid container 80 contains a liquid to be hydrogenated, and the cap 81 is provided with a plug 56.
  • the plug 56 is an element constituting the coupler 50 as shown in FIG. That is, the coupler 50 is constituted by a socket 55 and a plug 56, and when both are connected, the flow path is opened, and when separated, the flow path is closed. When the connected socket 55 and plug 56 are removed, the separation button 55 a provided on the side surface of the socket 55 is pressed.
  • the tube 85 is extended from the plug 56 to the inside of the beverage. Therefore, hydrogen gas is directly supplied into the beverage, so that the hydrogenation efficiency is considered to be increased. However, since the hydrogen addition amount according to the gas pressure can be obtained according to Henry's law, the tube 85 can be omitted.
  • the liquid container 80 has an opening / closing means that opens when connected to the hydrogen gas supply tube (hydrogen gas supply path) 30 and closes when the connection is broken.
  • the specific configuration is not limited to a specific one.
  • the plug 56 is an opening / closing means.
  • the socket 55 may be provided in the liquid container and this may be used as the opening / closing means, or the entire coupler 55 including the socket 55 and the plug 56 may be provided in the liquid container and used as the opening / closing means.
  • a check valve may be employed as the opening / closing means.
  • the liquid container 80 is sealed by the cap 81 before being connected to the hydrogen gas supply tube 30, and when connected to the hydrogen gas supply tube 30, the hydrogen from the hydrogen gas supply tube 30 is Gas can enter the container.
  • the liquid container 80 includes a cap 81, and the cap includes an opening / closing means (plug 56).
  • the liquid container may be a container that can store a liquid therein, and may be provided with opening / closing means having the same function as described above at any position (for example, a container wall surface).
  • the connecting portion 20 provided in the hydrogen gas generator 10 is also composed of the same coupler as the coupler 50 shown in FIG.
  • the connecting portion 20 may be formed of a normal joint member.
  • the tube 30 may be omitted and the liquid container 80 may be directly connected to the connection part 20.
  • the hydrogen gas generated in the hydrogen gas generator 10 is supplied into the liquid container 80 from the flow path 19 (hydrogen gas supply path) through the connection part 20 as an opening / closing means.
  • the connection unit 20 is not limited to the upper surface of the apparatus as illustrated, and can be disposed at any convenient position such as the front surface or the side surface.
  • the socket 55 provided at the tip of the hydrogen gas supply tube 30 is connected to the plug 56 provided in the cap 81 of the liquid container 80 as shown in FIG.
  • hydrogen gas is injected into the liquid container 80 at a desired gas pressure. Since hydrogen gas is injected into the container instantly, the socket 55 is removed thereafter. As described above, since the flow path is closed simultaneously with the removal of the socket 55, the container is sealed in a pressurized state. The consumer can shake the container to dissolve the hydrogen gas in the liquid and drink it.
  • the amount of dissolved hydrogen follows Henry's law. For example, if the gas pressure is 0.5 MPa, a theoretical hydrogen concentration of 8 ppm can be realized. At normal temperature and normal pressure, only a hydrogen concentration of 1.6 ppm or less can be realized according to Henry's law.
  • hydrogen gas generated under pressure control using the hydrogen gas generator 10 is contained in a liquid container. Therefore, it is possible to add hydrogen at a high concentration by controlling the gas pressure at the time of injection.
  • the amount of hydrogen added can be controlled by the gas pressure, it is possible to add hydrogen at a desired concentration regardless of the size of the liquid container. If a liquid container of a size that can be consumed at a time (for example, 150 to 200 ml) is used, it is possible to drink up all of the beverage with hydrogen added on the spot.
  • a liquid container of a size that can be consumed at a time for example, 150 to 200 ml
  • hydrogen water produced in factories has been sold in plastic bottles, aluminum pouches and cans, but since hydrogen was released over time after hydrogen was added, there was dissatisfaction with the hydrogen concentration. According to the present invention, such dissatisfaction can be completely eliminated.
  • the hydrogen gas pressure may be fixed as a value inherent to the hydrogen gas generator 10, or may be changed by the user operating a lever or the like.
  • one system of hydrogen gas supply tubes 30 is provided for the hydrogen gas generator 10, but as another example, if two or more systems of hydrogen gas supply tubes 30 are provided, two or more liquid containers are provided. Hydrogen gas can be supplied simultaneously in parallel with 80.
  • the hydrogen gas supply tube 30 is preferably a single system.
  • One hydrogen gas supply tube may be branched into two or three or more on the way. When such a plurality of systems are used, for example, it is possible to supply hydrogen gas simultaneously to containers of different sizes, or to supply hydrogen gas simultaneously to different liquids.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Medicinal Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Afin de fournir un moyen qui, à l'aide d'un procédé simple et polyvalent, ajoute de l'hydrogène hautement concentré à un liquide indépendamment de la taille du récipient, un système d'addition d'hydrogène est pourvu d'un générateur d'hydrogène gazeux qui extrait de l'hydrogène gazeux à partir d'eau sous pression régulée, d'un canal d'alimentation en hydrogène gazeux qui fournit l'hydrogène gazeux produit dans le générateur d'hydrogène gazeux vers l'extérieur, et d'un récipient pour liquide qui est capable de recevoir un liquide à l'intérieur de celui-ci et communique de manière amovible avec le canal d'alimentation en hydrogène gazeux à l'aide d'un moyen d'ouverture et de fermeture, qui s'ouvre lorsqu'il est connecté au canal d'alimentation en hydrogène gazeux et se ferme lorsque ladite connexion est rompue, le générateur d'hydrogène gazeux étant en outre capable de réguler de manière variable la pression de gaz de l'hydrogène gazeux.
PCT/JP2015/064548 2014-05-23 2015-05-21 Système d'addition d'hydrogène et récipient pour liquide utilisé dans ledit système WO2015178440A1 (fr)

Applications Claiming Priority (2)

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JP2014-107334 2014-05-23
JP2014107334A JP5710050B1 (ja) 2014-05-23 2014-05-23 水素添加システム、および当該システムに使用する液体容器

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WO2015178440A1 true WO2015178440A1 (fr) 2015-11-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6010716B1 (ja) * 2016-06-10 2016-10-19 浩章 皆川 水素水製造装置及び水素水製造方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7038419B2 (ja) * 2019-09-24 2022-03-18 株式会社ドクターズ・マン 注射容器内の液体へのガス溶解方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000186795A (ja) * 1998-12-22 2000-07-04 Yasuhiko Watanabe 流体継手装置及び流体継手
JP4652479B1 (ja) * 2010-07-14 2011-03-16 ミズ株式会社 生体適用液への選択的水素添加器具
JP5095020B1 (ja) * 2012-03-13 2012-12-12 エウレカ・ラボ株式会社 気体溶解水浄水器
JP2013022567A (ja) * 2011-07-25 2013-02-04 Bio Coke Lab Co Ltd 水素水製造装置及び水素水製造方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5730490U (fr) * 1980-07-30 1982-02-17
JP2001304478A (ja) * 2000-04-25 2001-10-31 Toyota Industries Corp 継 手
JP2008133953A (ja) * 2007-10-29 2008-06-12 Sony Corp コネクタ機構

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000186795A (ja) * 1998-12-22 2000-07-04 Yasuhiko Watanabe 流体継手装置及び流体継手
JP4652479B1 (ja) * 2010-07-14 2011-03-16 ミズ株式会社 生体適用液への選択的水素添加器具
JP2013022567A (ja) * 2011-07-25 2013-02-04 Bio Coke Lab Co Ltd 水素水製造装置及び水素水製造方法
JP5095020B1 (ja) * 2012-03-13 2012-12-12 エウレカ・ラボ株式会社 気体溶解水浄水器

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6010716B1 (ja) * 2016-06-10 2016-10-19 浩章 皆川 水素水製造装置及び水素水製造方法
JP2017217631A (ja) * 2016-06-10 2017-12-14 浩章 皆川 水素水製造装置及び水素水製造方法

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JP2015221423A (ja) 2015-12-10

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