WO2015096562A1 - Revêtement aqueux expansible nanoignifugé pour câbles et son procédé de préparation - Google Patents

Revêtement aqueux expansible nanoignifugé pour câbles et son procédé de préparation Download PDF

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Publication number
WO2015096562A1
WO2015096562A1 PCT/CN2014/090889 CN2014090889W WO2015096562A1 WO 2015096562 A1 WO2015096562 A1 WO 2015096562A1 CN 2014090889 W CN2014090889 W CN 2014090889W WO 2015096562 A1 WO2015096562 A1 WO 2015096562A1
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Prior art keywords
flame retardant
nano
parts
fireproof coating
coating
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PCT/CN2014/090889
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English (en)
Chinese (zh)
Inventor
方章建
郑兴才
程宇婷
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中盈长江国际新能源投资有限公司
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Publication of WO2015096562A1 publication Critical patent/WO2015096562A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/54—Aqueous solutions or dispersions

Definitions

  • the invention relates to the field of fireproof coatings, in particular to a novel nano fireproof coating for aqueous expansion cables and a preparation method thereof.
  • Wire and cable are important materials for the electric power industry. With the rapid development of China's economy, the energy industry as a basic industry and the communication industry as a high-tech industry have developed rapidly. The application of heavy-duty and ultra-high-voltage transmission and power supply technologies is becoming more and more common, and various cables are laid as dense as spider webs. Wire and cable fire hazards are becoming increasingly prominent. In the mid-1970s, China began to study cable fire-retardant coatings. It was developed on the basis of decorative fire-retardant coatings in combination with its own requirements. Due to the thick coating of non-intumescent fire-retardant coatings, it is difficult to meet the bending requirements of cables.
  • cable fire-retardant coatings are mainly based on intumescent fire-retardant coatings, and most of them are solvent-based.
  • cable fireproof coating plays an active role in preventing the spread of flame, preventing the occurrence and development of fire, reducing the loss of cable fire, and protecting the safety of people's lives and property. Its application is also from standard to standard.
  • the solvent-based fireproof coating is better. Although it has strong decoration, high adhesion to the substrate and good physical and chemical properties, it has high production cost and inherent toxicity, and it is polluting production personnel, construction workers and surrounding ecological environment. From the perspective of environmental protection, in the future, efforts should be made to develop water-soluble cable fire-retardant coatings that have good adhesion to the cable sheath, good flexibility, resistance to bending, non-toxicity, and good flame retardancy.
  • Patent 02110297.X discloses an intumescent fireproof coating comprising an acrylic resin, a catalyst, a carbon forming agent, a foaming agent, a flame retardant, a reinforcing agent, a pigment filler, an auxiliary agent, an aerosol inhibitor, and the like, and an acrylic resin. Modification, surface treatment of the catalyst and addition of smoke inhibitors to improve the overall performance of the coating.
  • the coating film is thermally expanded, a carbonized layer of a non-flammable three-dimensional structure is formed, so that the heat of the flame is isolated to reduce the conduction to the substrate, and at the high temperature, the coating decomposes the non-combustible gas, isolates and dilutes the air, and prevents the flame from expanding and spreading.
  • Patent 200810045431.4 discloses a high-expansion fireproof sealant and a preparation method thereof, which utilizes a flame retardant such as aluminum hydroxide, has excellent flame retardancy, strong adhesion and good elasticity, and is particularly suitable for various penetration parts such as cables. , fire separation of cable trays and pipes.
  • Patent No. 01212028.5 discloses a silane crosslinked flame-retardant polyethylene insulating plastic for wire and cable insulation. Its composition is as follows: polyethylene resin, silane crosslinker, lubricant and bromine flame retardant.
  • the invention has the advantages of improved flame retardant performance, high mechanical strength, good electrical performance and good temperature resistance, and is suitable for the manufacture of an insulating layer of wires and cables.
  • the technical problem to be solved by the present invention is to provide a novel nano fireproof coating for water-swellable cable and a preparation method thereof, which overcome the disadvantages of poor compatibility of various components and poor flame retardancy of the conventional intumescent fireproof coating.
  • Nano fireproof coating for water-swellable cable characterized in that it contains 20-40 parts by weight of coating substrate, 15-45 parts of nano flame retardant, 2-10 parts of flame retardant synergist, 5- 10 parts of filler, 1-5 parts of auxiliary agent and 10-30 parts of water, the nano flame retardant is obtained by nanocrystallization of a flame retardant, the flame retardant comprises soluble aluminum salt and charcoal a catalyst, a char forming agent and a blowing agent component; the flame retardant synergist is a biomass power plant ash.
  • the flame retardant is nano-sized by adding each flame retardant component to water of 1-10 times of the total weight of each flame retardant component, and then adding a surface modifier, and heating to 25-90 ° C.
  • the pH of the system was adjusted to 5.0-9.0, and the reaction was cooled for 0.5-6 hours to obtain a nano-flame retardant sol containing aluminum hydroxide.
  • the surface modifier is selected from the group consisting of alkylphenol ethoxylates, silane coupling agents, fatty acid polyoxyethylene esters, sodium lauryl sulfate, cetyltrimethylammonium bromide (CTAB).
  • CTL cetyltrimethylammonium bromide
  • the soluble aluminum salt is one or more selected from the group consisting of aluminum nitrate, sodium metaaluminate, and aluminum chloride; and the carbon forming catalyst is selected from the group consisting of ammonium polyphosphate, ammonium dihydrogen phosphate, and ammonium pyrophosphate.
  • the carbon forming agents selected from one or more of starch, sorbitol, and pentaerythritol; and the foaming agent is one or more selected from the group consisting of amino resins, urea resins, and melamines.
  • the flame retardant components are in parts by weight: soluble aluminum salt 10-20, carbon forming catalyst 8-15, carbon forming agent 1-10, and foaming agent 1-10.
  • the biomass power plant ash is preferably biomass power plant ash having a SiO 2 content of more than 30% by weight and an Al 2 O 3 content of more than 20% by weight.
  • the filler is selected from one or more of titanium white powder, light calcium carbonate, kaolin, alumina, and expandable graphite.
  • the coating substrate is a mixture of an aqueous epoxy emulsion, an aqueous epoxy curing agent, and a self-crosslinking silicone-acrylic emulsion.
  • the auxiliary agent is selected from one or more of urea, polyvinyl alcohol, epoxy resin, polysiloxane, and silicone oil.
  • the preparation method of the nano fireproof coating for the above aqueous expansion type cable comprises the following steps:
  • the flame retardant component used in the intumescent waterborne fire retardant coating contains a large amount of polar groups, is a hydrophilic substance, and has poor compatibility with a nonpolar polymer base. Therefore, it is easy to get detached from the substrate during actual use, resulting in a decrease in fire resistance and physical and chemical properties of the coating.
  • the novel aqueous intumescent nano fireproof coating prepared by nanometerizing each flame retardant raw material can fix and uniformly disperse each flame retardant component in the nano aluminum hydroxide microspheres, and contribute to the formation of the flame retardant. Dispersion in the membrane material significantly improves the compatibility of the components of the fire retardant coating.
  • the flame retardant synergistic effect, the additives, the filler and the coating substrate can be used to make the fire retardant coating have good flame retardancy and carbonization height. Low, can significantly improve the fire performance and physical and chemical properties of fire retardant coatings.
  • the water-swellable fireproof coating provided by the invention has good compatibility, good bending resistance, heat and humidity resistance, oil resistance, water resistance, excellent flame retardancy and low carbonization height;
  • the nano-flame retardant is used to nano-process the flame retardant, which can improve the dispersion performance of the flame retardant in the coating, thereby improving the physical and chemical properties and flame-retardant properties of the coating;
  • the flame retardant synergist biomass power plant ash and flame retardant and other flame retardant components are uniformly dispersed in the system, and the dispersibility is good, and a hard white ceramic-like substance can be formed on the surface of the carbonized layer under flame ablation. Thereby increasing the strength of the carbonized layer and prolonging its fire endurance;
  • fillers and auxiliary components in Table 2-3 According to the selection of fillers and auxiliary components in Table 2-3, and according to the amount of each component in the formulation of Table 4, first add the coating matrix into the mixing tank, stir evenly, then add nano flame retardant, flame retardant synergist , filler, auxiliary agent and water, stir for 20min, then grind into the ball mill, evenly mix and use the scraper fineness meter to check whether the fineness of the paint reaches less than 90 ⁇ m. After the requirement is reached, the grinding is stopped, filtered by the filter, separated and removed. Grind the beads and discharge the barrel.
  • each flame retardant component Adding each flame retardant component to water of 6 times the total weight of each flame retardant component, then adding a surface modifier, heating to 50 ° C, adjusting the pH of the system to 6.0 with dilute sulfuric acid, and cooling after 5 hours.
  • a nano flame retardant sol containing aluminum hydroxide is a nano flame retardant. The selection and dosage of each flame retardant component and surface modifier are shown in Table 1.
  • fillers and auxiliary components in Table 2-3 According to the selection of fillers and auxiliary components in Table 2-3, and according to the amount of each component in the formulation of Table 4, first add the coating matrix into the mixing tank, stir evenly, add nano flame retardant, flame retardant synergist , filler, auxiliary agent and water, stir for 20min, then grind into the ball mill, evenly mix and use the scraper fineness meter to check whether the fineness of the paint reaches less than 90 ⁇ m. After the requirement is reached, the grinding is stopped, filtered by the filter, separated and removed. Grind the beads and discharge the barrel.
  • each flame retardant component Adding each flame retardant component to water of 10 times the total weight of each flame retardant component, then adding a surface modifier, heating to 30 ° C, adjusting the pH of the system to 5.5 with dilute sulfuric acid, and reacting for 0.5 hours and then cooling.
  • a nano flame retardant sol containing aluminum hydroxide is a nano flame retardant. The selection and dosage of each flame retardant component and surface modifier are shown in Table 1.
  • fillers and auxiliary components in Table 2-3 According to the selection of fillers and auxiliary components in Table 2-3, and according to the amount of each component in the formulation of Table 4, first add the coating matrix into the mixing tank, stir evenly, add nano flame retardant, flame retardant synergist , filler, auxiliary and water, stir after 20min Grinding in a ball mill, uniformly mixing, and using a squeegee fineness meter to check whether the fineness of the coating reaches less than 90 ⁇ m. After the requirement is reached, the grinding is stopped, the filter is filtered, the grinding beads are separated, and the discharging barrel is discharged.
  • each flame retardant component Adding each flame retardant component to water of 10 times the total weight of each flame retardant component, then adding a surface modifier, heating to 70 ° C, adjusting the pH of the system to 9.0 with dilute sulfuric acid, and cooling after 6 hours.
  • a nano flame retardant sol containing aluminum hydroxide is a nano flame retardant. The selection and dosage of each flame retardant component and surface modifier are shown in Table 1.
  • fillers and auxiliary components in Table 2-3 According to the selection of fillers and auxiliary components in Table 2-3, and according to the amount of each component in the formulation of Table 4, first add the coating matrix into the mixing tank, stir evenly, add nano flame retardant, flame retardant synergist , filler, auxiliary agent and water, stir for 20min, then grind into the ball mill, evenly mix and use the scraper fineness meter to check whether the fineness of the paint reaches less than 90 ⁇ m. After the requirement is reached, the grinding is stopped, filtered by the filter, separated and removed. Grind the beads and discharge the barrel.
  • each flame retardant component Adding each flame retardant component to water of 10 times the total weight of each flame retardant component, then adding a surface modifier, heating to 90 ° C, adjusting the pH of the system to 5.0 with dilute sulfuric acid, and cooling after 1 hour.
  • a nano flame retardant sol containing aluminum hydroxide is a nano flame retardant. The selection and dosage of each flame retardant component and surface modifier are shown in Table 1.
  • fillers and auxiliary components in Table 2-3 According to the selection of fillers and auxiliary components in Table 2-3, and according to the amount of each component in the formulation of Table 4, first add the coating matrix into the mixing tank, stir evenly, add nano flame retardant, flame retardant synergist , filler, auxiliary agent and water, stir for 20min, then grind into the ball mill, evenly mix and use the scraper fineness meter to check whether the fineness of the paint reaches less than 90 ⁇ m. After the requirement is reached, the grinding is stopped, filtered by the filter, separated and removed. Grind the beads and discharge the barrel.
  • the biomass power plant ash in the above embodiments 1-3 is preferably a biomass power plant ash having a SiO 2 content of more than 30% by weight and an Al 2 O 3 content of more than 20% by weight.
  • Example 1 Example 2 Example 3 Example 4 Example 5 Alumina 2 Kaolin 2 Titanium dioxide 2 Expandable graphite 4 3 2 Light calcium carbonate 3 5 3
  • Example 1 Example 2 Example 3 Example 4 Example 5 Polyvinyl alcohol 0.5 Silicone oil 0.5 Urea 0.5 Epoxy resin 3 Polysiloxane 3 0.5 0.5

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)
  • Fireproofing Substances (AREA)

Abstract

L'invention concerne un revêtement aqueux expansible nanoignifugé pour câbles et son procédé de préparation. Le revêtement aqueux expansible nanoignifugé pour câbles comprend en parties en poids : 20-40 parties de matrice de revêtement, 15-45 parties de nanoignifugeant, 2-10 parties d'agent synergétique ignifugeant, 5-10 parties de charge, 1-5 parties d'un auxiliaire de fabrication et 10-30 parties d'eau. Le nanoignifugeant est obtenu par des nanoparticules de l'ignifugeant comprenant du sel d'aluminium soluble, un catalyseur de carbonisation, un agent de carbonisation et un agent d'expansion. L'agent synergétique ignifugeant est de la cendre de biomasse issue d'une centrale électrique. Comme les constituants du revêtement aqueux expansible nanoignifugé pour câbles présentent une bonne compatibilité, le revêtement aqueux expansible nanoignifugé présente de bonnes résistance au flambage, résistance à l'humidité, résistance à l'huile et résistance à l'eau, une excellente propriété de résistance aux flammes et une faible hauteur de carbonisation.
PCT/CN2014/090889 2013-12-26 2014-11-12 Revêtement aqueux expansible nanoignifugé pour câbles et son procédé de préparation WO2015096562A1 (fr)

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CN201310730530.7A CN103740231B (zh) 2013-12-26 2013-12-26 一种水性膨胀型电缆用纳米防火涂料及其制备方法
CN201310730530.7 2013-12-26

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CN109461531A (zh) * 2018-11-29 2019-03-12 广州番禺电缆集团有限公司 一种智能预警型防火防水阻燃电缆
CN110964385A (zh) * 2019-11-27 2020-04-07 河北晨阳工贸集团有限公司 一种水性防火功能质感涂料及其制备方法
CN112310523A (zh) * 2019-07-29 2021-02-02 浙江启墨新材料科技有限公司 一种含有膨胀型防火毡的蓄电装置
CN113683965A (zh) * 2021-08-19 2021-11-23 沈阳浩丰科技有限公司 一种防火胶的制备方法
CN114736567A (zh) * 2022-02-23 2022-07-12 国网安徽省电力有限公司电力科学研究院 一种电力消防设备用丙烯酸阻燃漆及其制备方法与应用
CN114904739A (zh) * 2022-06-16 2022-08-16 广东百安环保新材料有限公司 一种用于钢结构的水性防火涂料及其制备方法
CN115073961A (zh) * 2022-07-04 2022-09-20 北京东方雨虹防水技术股份有限公司 一种具阻燃性的高耐水水性防水涂料及其制备方法
CN116656161A (zh) * 2023-05-04 2023-08-29 河南联防科技防火材料有限公司 一种高强度保温环保防火涂料及制备方法
CN116875130A (zh) * 2023-07-25 2023-10-13 千浪化研新材料(上海)有限公司 一种高耐化学品防火哑黑涂料及其制备方法
WO2024108681A1 (fr) * 2022-11-23 2024-05-30 江西天永诚高分子材料有限公司 Matériau d'enrobage isolant thermique à base d'organosilicium super-ignifuge à ultra-faible densité et son procédé de préparation

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CN105368166A (zh) * 2015-11-27 2016-03-02 沈阳顺风新城建筑材料有限公司 一种膨胀型氯化橡胶防火涂料及其制备方法
CN105694620B (zh) * 2016-04-03 2018-05-11 北京化工大学 一种高固含量水性超薄膨胀型防火涂料及其制备方法
CN106280777A (zh) * 2016-08-26 2017-01-04 吴小慧 一种缆线用的水性隔热防火涂料
CN106752682B (zh) * 2016-11-23 2019-06-14 厦门大学 一种钢结构用环氧树脂膨胀型防火涂料及其制备方法
CN106833283A (zh) * 2017-03-02 2017-06-13 合肥英索莱特新材料科技有限公司 基于可膨胀石墨的防火涂料
CN107353803B (zh) * 2017-08-16 2019-11-05 辽宁科隆精细化工股份有限公司 一种高效防火聚氨酯涂饰材料及其制备方法
CN107556799A (zh) * 2017-09-07 2018-01-09 深圳市嘉达高科产业发展有限公司 防火涂料及其制备方法
CN108912953A (zh) * 2018-06-12 2018-11-30 常州大学 一种钢结构耐腐防火涂料及其制备方法
CN108691211B (zh) * 2018-06-22 2021-02-19 宁波天盾防水材料有限公司 刀刮涂层布
CN109322167B (zh) * 2018-10-30 2021-09-14 宁波天盾防水材料有限公司 帐篷专用膜材
CN111320887A (zh) * 2020-03-23 2020-06-23 广东省潮州市公安消防局 一种水性环保多功能膨胀型饰面防火涂料
CN114990919A (zh) * 2021-04-15 2022-09-02 深圳朗晖展示有限公司 防析出的高阻燃瓦楞纸板生产方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6102995A (en) * 1998-03-06 2000-08-15 Georgia-Pacific Resins, Inc. High performance intumescent system for imparting heat/flame resistance to thermally unstable substrates
CN1680502A (zh) * 2004-04-09 2005-10-12 中国科学院金属研究所 一种可膨胀石墨纳米防火涂料及其制备方法和应用
CN101746787A (zh) * 2008-12-08 2010-06-23 广州慧谷化学有限公司 一种纳米氢氧化铝的制备方法及其应用
JP2010174120A (ja) * 2009-01-29 2010-08-12 Panasonic Corp 難燃剤およびそれを配合した難燃樹脂
CN101914333A (zh) * 2010-08-05 2010-12-15 安徽工业大学 一种水性纳米超薄型钢结构防火涂料及其制备方法
CN103045037A (zh) * 2012-12-14 2013-04-17 中盈长江国际新能源投资有限公司 水性膨胀型钢结构防火涂料及制备方法
CN103328611A (zh) * 2010-12-10 2013-09-25 株式会社亚都玛科技 阻燃剂及其制造方法、阻燃性树脂组合物及其制造方法
CN103740231A (zh) * 2013-12-26 2014-04-23 中盈长江国际新能源投资有限公司 一种水性膨胀型电缆用纳米防火涂料及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101659823B (zh) * 2009-09-27 2012-09-19 中国科学技术大学 一种膨胀型防火涂料及其制备方法
CN101955710B (zh) * 2010-05-14 2012-10-24 袁雪祥 水性纳米超薄型钢结构防火涂料及制备方法
CN103351524B (zh) * 2013-08-09 2015-08-26 中国日用化学工业研究院 一种改性纳米镁铝复合阻燃剂的制备方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6102995A (en) * 1998-03-06 2000-08-15 Georgia-Pacific Resins, Inc. High performance intumescent system for imparting heat/flame resistance to thermally unstable substrates
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JP2010174120A (ja) * 2009-01-29 2010-08-12 Panasonic Corp 難燃剤およびそれを配合した難燃樹脂
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CN103328611A (zh) * 2010-12-10 2013-09-25 株式会社亚都玛科技 阻燃剂及其制造方法、阻燃性树脂组合物及其制造方法
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