WO2015088295A1 - 터치 센서 및 이의 제조방법 - Google Patents
터치 센서 및 이의 제조방법 Download PDFInfo
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- WO2015088295A1 WO2015088295A1 PCT/KR2014/012362 KR2014012362W WO2015088295A1 WO 2015088295 A1 WO2015088295 A1 WO 2015088295A1 KR 2014012362 W KR2014012362 W KR 2014012362W WO 2015088295 A1 WO2015088295 A1 WO 2015088295A1
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- electrode part
- pattern
- touch sensor
- wiring electrode
- sensing
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/044—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
- G06F3/0446—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a grid-like structure of electrodes in at least two directions, e.g. using row and column electrodes
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/044—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
- G06F3/0443—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a single layer of sensing electrodes
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04103—Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04107—Shielding in digitiser, i.e. guard or shielding arrangements, mostly for capacitive touchscreens, e.g. driven shields, driven grounds
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04112—Electrode mesh in capacitive digitiser: electrode for touch sensing is formed of a mesh of very fine, normally metallic, interconnected lines that are almost invisible to see. This provides a quite large but transparent electrode surface, without need for ITO or similar transparent conductive material
Definitions
- the present application relates to a touch sensor and a method of manufacturing the same.
- a display device is a term referring to a TV, a computer monitor, and the like, and includes a display element for forming an image and a case for supporting the display element.
- Examples of the display device may include a plasma display panel (PDP), a liquid crystal display (LCD), an electrophoretic display, and a cathode-ray tube (CRT).
- the display device may be provided with an RGB pixel pattern and an additional optical filter for implementing an image.
- the optical filter includes an anti-reflection film that prevents external light incident from the outside from being reflected back to the outside, a near-infrared shielding film that shields near infrared rays generated from a display element to prevent malfunction of electronic devices such as a remote control, and color control dyes. At least one of a color correction film to increase the color purity by adjusting the color tone, and an electromagnetic shielding film for shielding the electromagnetic waves generated from the display element when the display device is driven.
- the electromagnetic shielding film includes a transparent substrate and a metal mesh pattern provided on the substrate.
- Touch sensors having the above functions may be classified as follows according to a signal detection method.
- a resistive type that senses a position pressed by pressure in a state in which a DC voltage is applied through a change in current or a voltage value, and a capacitance coupling in which an AC voltage is applied
- a capacitive type and an electromagnetic type for sensing a selected position as a change in voltage in the state of applying a magnetic field.
- the most common resistive and capacitive touch sensors use a transparent conductive film, such as an ITO film, to recognize whether the touch is performed by an electrical contact or a change in capacitance.
- a transparent conductive film such as an ITO film
- the transparent conductive film has a high resistance of 100 ohm / square or more, sensitivity decreases at the time of enlargement, and as the size of the screen increases, commercialization is not easy due to the problem that the price of ITO film increases rapidly.
- an attempt has been made to implement an enlargement by using a metal pattern with high conductivity.
- the present application is to improve the manufacturing process of the touch sensor, to reduce the manufacturing cost of the touch sensor, and to improve the weight, thinning and the like of the touch sensor.
- a touch sensor including a driving electrode part, a sensing electrode part, and a wiring electrode part provided on the same surface on the substrate.
- the driving electrode part, the sensing electrode part, and the wiring electrode part each include a conductive pattern including a shield part and an opening part,
- the wiring electrode part includes a first wiring electrode part located in a touch sensing area of a touch sensor and a second wiring electrode part located in a touch non-sensing area of a touch sensor, and the first wiring electrode part includes the driving electrode part or the sensing electrode part. 1 or 2 or more bundles of wires connected to the second wire electrode part,
- Each of the wirings is made of a mesh pattern
- a touch sensor In a bundle including a maximum number of wires among the bundles, a neighbor sharing at least one side of a width W of the bundle, the number of wires n included in the bundle, and a mesh pattern constituting the wires. It provides a touch sensor, characterized in that the minimum value (P) of the distance between the center points of one of the network structures satisfy the following equation (1).
- a touch sensor including a driving electrode part, a sensing electrode part, and a wiring electrode part provided on the same surface on the substrate.
- the driving electrode part, the sensing electrode part and the wiring electrode part may include a conductive pattern including a shield part and an opening part.
- the wiring electrode part includes a first wiring electrode part located in a touch sensing area of a touch sensor and a second wiring electrode part located in a touch non-sensing area of a touch sensor, and the first wiring electrode part includes the driving electrode part or the sensing electrode part. 1 or 2 or more bundles of wires connected to the second wire electrode part,
- the bundle consists of a pattern in which a closed figure having two disconnection points is continuously disposed in a direction from one side of the substrate adjacent to the end of the second wiring electrode to the other side of the substrate opposite thereto,
- the virtual straight line connecting the adjacent disconnection points of the continuously arranged closed figures in the shortest distance has one or more inflection points, the angle formed by the virtual straight line at the inflection point is 90 degrees or more,
- the pattern in contact with the virtual straight line provides a touch sensor, wherein the driving electrode part or the sensing electrode part is electrically connected to the second wiring electrode part.
- another exemplary embodiment of the present application provides a display device including the touch sensor.
- the thickness of the touch sensor can be minimized and the manufacturing method is easy because all the conductive patterns are formed on the cross-section.
- it is a single sheet type, there is an advantage that the lamination is not required as compared with the prior art formed by using two or more substrates.
- the sensing electrode part and the driving electrode part are on the same plane, installation and attachment of the FPCB (Flexible Printed Circuit Board) is easy.
- it is a single sheet
- when laminating the functional surface film on the surface of the touch sensor there is an advantage that bubbles are not occupied because the step is not large.
- the manufacturing process of the touch sensor by improving the manufacturing process of the touch sensor, it is possible to reduce the manufacturing cost of the touch sensor, it is possible to improve the weight, thinning and the like of the touch sensor.
- 1 to 3 schematically show a conventional touch sensor.
- FIG. 4 is a view schematically showing a wiring electrode part of a conventional touch sensor.
- 5 and 6 are schematic diagrams of a touch sensor according to an exemplary embodiment of the present application.
- FIG. 7 to 9 are diagrams schematically showing a moiré evaluation result of the touch sensor according to an exemplary embodiment of the present application.
- 10 to 14 are views schematically showing the results of evaluation of the aperture ratio of the touch sensor according to the exemplary embodiment of the present application.
- 15 and 16 are diagrams schematically illustrating a conductive metal line pattern of a wiring electrode part of a touch sensor according to an exemplary embodiment of the present application.
- 17 to 24 are diagrams schematically illustrating a moiré evaluation result according to a shape of a conductive metal line pattern of a wiring electrode part of a touch sensor according to an exemplary embodiment of the present application.
- 25 is a view schematically illustrating a touch sensor and a display device including the same according to an exemplary embodiment of the present application.
- FIG. 26 is a diagram schematically illustrating a disconnection point of a conductive metal line pattern according to an exemplary embodiment of the present application.
- FIG. 27 is a diagram schematically illustrating a touch sensor according to an exemplary embodiment of the present application.
- FIG. 28 is a view schematically showing a printing direction of a wiring electrode of a touch sensor according to an exemplary embodiment of the present application.
- a driving electrode pattern (Tx pattern) serving as voltage driving and a sensing electrode pattern (Rx pattern) that receive a signal of mutual capacitance and transmit it to a circuit are separate. It is mainly formed of a product formed on the substrate, or a product in which the driving electrode pattern and the sensing electrode pattern are formed on both sides of the substrate, that is, the form in which the driving electrode pattern and the sensing electrode pattern are spatially separated.
- this method has continuously generated cost issues in terms of the cost of the sensor in terms of using two sheets of indium tin oxide (ITO) film that is used as an optically clear adhesive (OCA) and a transparent electrode corresponding to a dielectric.
- ITO indium tin oxide
- OCA optically clear adhesive
- Tx pattern driving electrode pattern
- Rx pattern sensing electrode pattern
- the touch sensor of the first-layer single layer can be largely classified into a method using self capacitance, a method using mutual capacitance, and a so-called Fxy method using a metal bridge.
- the method of using self-capacitance and the method of using metal bridges respectively, have performance issues (limiting ghost phenomenon and multi-touch in the case of self-cap) and yield issues between manufacturing processes. It is true that the back did not give great charm.
- the method of using mutual capacitance has been greatly received recently. This is mainly due to the fact that in the method of using mutual capacitance, the area where capacitance is formed is formed in a plane in the same space. This is because there is an issue of pattern manufacturing in terms of issues such as sensitivity and wiring area formed on the screen, but it has the best characteristics in terms of performance compared to other methods. Accordingly, in the case of ITO, development activities for implementing the same are actively progressing. However, this method also has the issue of resistance due to the use of a relatively high resistance material called ITO, which is because the limit of the applicable inches is limited to 5 inches or less.
- the present application proposes a touch sensor having a single-sided single layer using a conductive metal wire as a driving electrode pattern and a sensing electrode pattern.
- FIGS. 1 and 2 A touch sensor of one layer of cross section using a conventional ITO electrode is schematically shown in FIGS. 1 and 2.
- the driving electrode pattern and the sensing electrode pattern of the touch sensor having a single-sided single layer using the conventional ITO electrode are shown in more detail in FIG. 3.
- a sensing electrode pattern (Rx pattern) and a driving electrode pattern (Tx pattern) that is an X-shaped pattern are shown. That is, the sensing electrode pattern (Rx pattern) is designed to have a larger area than the driving electrode pattern (Tx pattern), and the signal is applied through the common electrode.
- the driving electrode pattern (Tx pattern) is embodied in an X-shaped pattern, and a wiring portion is formed through a dead zone region to apply a signal to each driving electrode pattern (Tx pattern).
- the dead zone according to the wiring area is most preferably minimized in view of touch resolution, and for this purpose, appropriate control of the width of the conductive metal wire and / or the space of the dead zone is required.
- the width of the space is more than a predetermined value, it can be said to be a pattern of an advantageous form in the interference of mutual signals.
- the width of the conductive metal wire should be wide, and the smaller the width of the space, the more advantageous. Therefore, it is desirable to appropriately adjust the width of the conductive metal wire and / or space of the dead zone.
- portions other than the sensing electrode pattern, the driving electrode pattern, and the dead zone are areas corresponding to the dummy electrode or the area in which the pattern is not formed, and have no significant effect on the actual electrical connectivity. can do.
- the wiring part is generally formed of a line / space concept, and a pattern having a form as shown in FIG. 4 is formed. Accordingly, the present application has introduced a design that minimizes the space in order to secure the connectivity of the conductive metal wire and improve the yield.
- a touch sensor including a driving electrode part, a sensing electrode part, and a wiring electrode part provided on the same surface on the substrate.
- the driving electrode part, the sensing electrode part, and the wiring electrode part each include a conductive pattern including a shield part and an opening part,
- the wiring electrode part includes a first wiring electrode part located in a touch sensing area of a touch sensor and a second wiring electrode part located in a touch non-sensing area of a touch sensor, and the first wiring electrode part includes the driving electrode part or the sensing electrode part. 1 or 2 or more bundles of wires connected to the second wire electrode part,
- Each of the wirings is made of a mesh pattern
- the minimum value (P) of the distances between the center points of one network structure is characterized by satisfying the following equation (1).
- the driving electrode part, the sensing electrode part and the wiring electrode part each include a conductive pattern including a shielding part and an opening part.
- the shielding portion means a region in which a conductive metal line, for example, a conductive metal line, is provided on the substrate, and includes a conductive pattern of the driving electrode portion, the sensing electrode portion, and the wiring electrode portion. it means. That is, the shield may mean an area that is not optically transparent, for example, the transmittance of the shield may be 20% or less, or 10% or less.
- the mesh pattern a pattern form in the art such as a mesh pattern may be used.
- the mesh pattern may include a polygonal pattern including at least one of triangular, square, pentagonal, hexagonal, and octagonal shapes.
- the distance between the center points of neighboring network structures sharing at least one side of the mesh patterns constituting the wires may correspond to the pitch of the mesh pattern when the mesh pattern is a regular mesh pattern.
- the mesh pattern is a polygonal pattern including various shapes
- the mesh pattern may correspond to a distance between center points of the neighboring polygon patterns sharing at least one side or a distance between centers of gravity.
- Equation 1 may be represented by Equation 2 below.
- [theta] 1 represents a smaller value among angles formed by a straight line connecting the shortest distance in the width direction of the bundle and a straight line connecting the center points of neighboring network structures sharing at least one side with the shortest distance.
- the touch sensing area of the touch sensor may include a driving electrode part, a sensing electrode part, and a first wiring electrode part.
- the touch non-sensing area of the touch sensor may include a second wiring electrode part.
- the touch sensing area may be expressed in terms such as a touch sensitive area, a touch enabled area, and a touch activation area.
- the driving electrode part and the sensing electrode part of the touch sensor according to the exemplary embodiment of the present application are as shown in FIG. 5.
- the shape of the wiring electrode part of the touch sensor according to the exemplary embodiment of the present application is as shown in FIG. 6.
- a touch sensor including a driving electrode part, a sensing electrode part, and a wiring electrode part provided on the same surface on the substrate.
- the driving electrode part, the sensing electrode part and the wiring electrode part may include a conductive pattern including a shield part and an opening part.
- the wiring electrode part includes a first wiring electrode part located in a touch sensing area of a touch sensor and a second wiring electrode part located in a touch non-sensing area of a touch sensor, and the first wiring electrode part includes the driving electrode part or the sensing electrode part. 1 or 2 or more bundles of wires connected to the second wire electrode part,
- the bundle consists of a pattern in which a closed figure having two disconnection points is continuously disposed in a direction from one side of the substrate adjacent to the end of the second wiring electrode to the other side of the substrate opposite thereto,
- the virtual straight line connecting the adjacent disconnection points of the continuously arranged closed figures in the shortest distance has one or more inflection points, the angle formed by the virtual straight line at the inflection point is 90 degrees or more,
- the pattern in contact with the virtual straight line may be electrically connected to the driving electrode part or the sensing electrode part to the second wiring electrode part.
- the disconnection point means a region in which a part of the edge pattern of the closed figure is disconnected to disconnect the electrical connection, and may be expressed in terms of disconnection point and disconnection part. That is, when the wiring electrode part includes a pattern made of a conductive metal line, the pattern may include two or more metal lines spaced apart in the longitudinal direction of the conductive metal line by a disconnection point.
- the moire is evaluated.
- the average diameter of the disconnection point or the width of the disconnection part is within 13 ⁇ m.
- the moiré evaluation result of the wiring electrode part including the conductive pattern having the average diameter of the disconnection point or the width of the disconnection part is 15 ⁇ m is shown in FIG. 7, and the average diameter or the disconnection part of the disconnection point is shown in FIG. 7.
- the moiré evaluation result of the wiring electrode part including the conductive pattern having a width of 10 ⁇ m is shown in FIG. 8.
- the moiré evaluation result of the wiring electrode part including the conductive pattern having the average diameter of the disconnection point or the width of the disconnection part is 7 ⁇ m. It is shown in Figure 9 below.
- the average diameter of the disconnection point or the width of the disconnection part may mean a distance between the closest ends of two or more conductive metal wires spaced apart.
- the distance between the closest ends of the two or more conductive metal wires spaced apart means a distance between the closest ends of the two or more conductive metal wires spaced apart from each other, and specific examples thereof are shown in FIG. 26.
- Equation 1 may be represented by Equation 3 below.
- [theta] 2 represents a smaller value of an angle formed by a straight line in the vertical direction with respect to an imaginary straight line connecting the disconnection points at the shortest distance and a straight line connecting the center points of neighboring network structures sharing at least one side with the shortest distance.
- the longest part between the inflection points of the imaginary straight line is parallel to each other or forms an angle of more than 0 degrees and less than 90 degrees with at least one side constituting the closed figure. Can be.
- the conductive patterns of the driving electrode part and the sensing electrode part may further include a disconnection point or a disconnection part as described above.
- the average diameter of the disconnection point or the width of the disconnection part may be 13 ⁇ m or less, 10 ⁇ m or less, or 7 ⁇ m or less, but is not limited thereto.
- the aperture ratio may mean a ratio of the entire planar area of the opening to the entire planar area of the driving electrode part, the sensing electrode part, and the wiring electrode part.
- the touch sensor of FIG. 10 is to process the disconnection of the conductive metal wire pattern into dots of a predetermined size, and then process the dummy pattern portion as an irregular pattern.
- the touch sensor of FIG. 11 minimizes the difference between the wiring electrode portion and the aperture ratio by disconnecting the conductive pattern region and the dummy pattern region with different dots.
- the conductive pattern area and the dummy pattern area of the sensing electrode part are disconnected by dots of the same size, but the gap between the dots is different from the conductive pattern area and the dummy pattern area of the sensing electrode part.
- the conductive pattern region and the dummy pattern region of the sensing electrode unit are disconnected by dots having the same size, but the gap between the dots introduces the conductive pattern region and the dummy pattern region as similarly as possible.
- the touch sensor of FIG. 14 maintains transmittance of the wiring part by positioning the touch sensor immediately after disconnection rather than removing the disconnected segment.
- the width of the bundle is called W
- the aperture ratio deviation between arbitrary regions of the touch sensor corresponding to the area of (W ⁇ W) is 10 based on the area of (W ⁇ W). It may be within%, may be within 5%, may be within 3%, but is not limited thereto.
- Arbitrary areas of the touch sensor may include an area inside the driving electrode part, an area inside the sensing electrode part, an area inside the wiring electrode part, an area where the driving electrode part and the sensing electrode part are combined, and the driving electrode part and the wiring electrode part are combined. And a region in which the detected electrode portion and the wiring electrode portion are combined.
- the driving electrode part and the sensing electrode part may be made of a conductive metal line, and the disconnection point or the disconnection part may be provided at an intersection area where conductive metal lines in the driving electrode part or the sensing electrode part cross each other.
- the present invention is not limited thereto.
- the diameter of the disconnection point may be 40 ⁇ m or less, or 20 ⁇ m or less, in terms of moiré characteristics and visibility. It is not limited only to this. Optical characteristics when the disconnection point is provided in the intersection region are shown in FIG. 27.
- an electrically isolated conductive metal wire may be further provided within a predetermined distance from the disconnection point or the center of the disconnection part.
- the length of the electrically isolated conductive metal wire is not particularly limited, and may be within 10% of the average diameter of the disconnection point or the width of the disconnection part.
- the electrically isolated conductive metal wire may be provided in parallel with the disconnection point or the disconnection part, or may be provided vertically or irregularly.
- the electrically isolated conductive metal wire may have an area of 80% to 120% with respect to the product of the average diameter of the disconnection point or the width of the disconnection part and the line width of the conductive metal wire.
- the distance between the terminal of the electrically isolated conductive metal wire and the terminal of the conductive metal wire adjacent thereto may be 13 ⁇ m or less.
- the size, shape, length, etc. of the electrically isolated conductive metal wire can be appropriately adjusted so that the aperture ratio deviation between arbitrary regions of the touch sensor is within 10%.
- the conductive pattern constituting the wiring electrode part is a mesh pattern and the mesh pattern is a square shape
- the width of the bundle is W
- the pitch of the mesh pattern is P
- n the number of the mesh pattern
- the directionality of the disconnection means the direction of the line displayed when adjacent disconnection points or disconnection portions are connected at the shortest distance.
- the directionality of the disconnection is a straight line through proper design of the disconnection position.
- the flow direction of the current can be set.
- the moiré evaluation results according to the shape of the conductive metal wire pattern of the wiring electrode part are shown in FIGS. 17 to 20 and Table 1 below.
- the moiré evaluation results of the conductive metal line patterns according to FIGS. 17 to 20 are shown in FIGS. 21 to 24, respectively.
- the optimum bundle width is formed when 16 wires are formed according to the pitch of the mesh pattern.
- the touch sensor according to the present application may recognize a touch input by using a mutual capacitance method.
- the touch sensor according to the present application does not insert a separate insulating material between the driving electrode part and the sensing electrode part, and performs electrical disconnection between the driving electrode part and the sensing electrode part using a disconnection point, a disconnection part, or a dummy pattern. This is different from the conventional touch sensor using a metal bridge, an insulating layer, or the like.
- the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part may be formed by independent printing processes, and the printing patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part are printed once. It can also form simultaneously.
- the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part may have the same consensus.
- At least a part of the conductive pattern of the driving electrode part and the wiring electrode part may include a region connected to each other, and the connected region may have no joint.
- at least a part of the conductive pattern of the sensing electrode part and the wiring electrode part may include an area connected to each other, and the connected area may have no joint.
- the absence of seams means that there are no artificial trailing traces in the electrically connected conductive pattern.
- the pattern shape and scale of the touch part and the wiring part are different, in the related art, since the touch part and the wiring part are formed in different ways, a joint part is inevitably formed at the part where these patterns are connected.
- the touch part, the wiring part, and the like can be formed by using one process, there is no joint part and their consensus can have the same feature.
- the same sentence means that the standard deviation of the sentence is less than 10%, preferably less than 5%, or more preferably less than 2%.
- the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part are provided on the substrate, and the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part are all provided on the same side of the substrate. Can be.
- At least one surface of the substrate may further include a hard coating layer.
- one surface of the substrate may be provided with a hard coating layer having a high hardness
- the other surface of the substrate may include a conductive pattern of a driving electrode, a sensing electrode, and a wiring electrode, but is not limited thereto.
- a conductive pattern may be provided on the hard coating layer of the hard electrode, the sensing electrode, and the wiring electrode, but the present invention is not limited thereto.
- the high hardness hard coat layer a binder monomer comprising a 3 to 6 functional acrylate monomer; Inorganic fine particles; Photoinitiator; And a solid coating composition comprising an organic solvent, wherein the weight ratio of the solid content to the organic solvent is 70:30 to 99: 1 with respect to the solid content including the binder monomer, the inorganic fine particles, and the photoinitiator. can do.
- the high hardness hard coat layer a binder monomer containing a 3 to 6 functional acrylate monomer; Inorganic fine particles; And a hard coating composition in a solvent-free form including a photoinitiator.
- the acrylate-based means not only acrylate but also methacrylate or a derivative in which a substituent is introduced into acrylate or methacrylate.
- the 3 to 6 functional acrylate monomers include trimethylolpropane triacrylate (TMPTA), trimethylolpropaneethoxy triacrylate (TMPEOTA), glycerin propoxylated triacrylate (GPTA), pentaerythritol tetraacrylate (PETA) or dipentaerythritol hexaacrylate (DPHA).
- TMPTA trimethylolpropane triacrylate
- TMPEOTA trimethylolpropaneethoxy triacrylate
- GPTA glycerin propoxylated triacrylate
- PETA pentaerythritol tetraacrylate
- DPHA dipentaerythritol hexaacrylate
- the 3 to 6 functional acrylate monomers may be used alone or in combination with each other.
- the binder monomer may further include 1 to 2 functional acrylate monomers.
- the 1 to 2 functional acrylate monomers are, for example, hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate (HEMA), hexanediol diacrylate (HDDA), or tripropylene glycol diacrylate. (TPGDA), ethylene glycol diacrylate (EGDA), etc. are mentioned.
- the 1 to 2 functional acrylate monomers may also be used alone or in combination with each other.
- the binder monomer is about 35 to about 85 parts by weight, or about 45 to about 80 parts by weight based on 100 parts by weight of the solid content including the binder monomer, the inorganic fine particles and the photoinitiator. It can be included as a wealth.
- the monomer for the binder is in the above range can exhibit a high hardness and can form a hard coating film with less curl or crack generation with excellent processability.
- the binder monomer further includes 1 to 2 functional acrylate monomers
- the content ratio of the 1 to 2 functional acrylate monomers and the 3 to 6 functional acrylate monomers is not particularly limited.
- the 1 to 2 functional acrylate monomer and the 3 to 6 functional acrylate monomer is about 1: 99 to about 50: 50, or about 10: 90 to And from about 50:50, or about 20:80 to about 40:60 by weight.
- 1 to 2 functional acrylate monomers and 3 to 6 functional acrylate monomers in the weight ratio it is possible to impart high hardness and flexibility without deterioration of other physical properties such as curling properties and light resistance.
- the binder monomer may further include a photocurable elastomer.
- the photocurable elastomer means a polymer material that exhibits elasticity and includes a functional group capable of crosslinking polymerization by ultraviolet irradiation.
- the photocurable elastomer is about 15% or more, for example about 15 to about 200%, or about 20 to about 200%, or about 20 to about as measured by ASTM D638. It can have an elongation of 150%.
- the hard coating composition of the present application further includes a photocurable elastomer
- the photocurable elastomer is cross-polymerized with the 3 to 6 functional acrylate-based monomer to form a hard coating layer after curing, thereby being flexible to the hard coating layer formed. And impact resistance can be imparted.
- the binder monomer further comprises a photocurable elastomer
- the content ratio of the photocurable elastomer and the 3 to 6 functional acrylate monomer is not particularly limited, but according to an embodiment of the present invention,
- the photocurable elastomer and the 3 to 6 functional acrylate monomer may be included in a weight ratio of about 5:95 to about 20:80.
- the 3 to 6 functional acrylate-based monomer and the photocurable elastomer in the weight ratio, it provides high hardness and flexibility without deterioration of other physical properties such as curling properties and light resistance, in particular to prevent damage by external impact Excellent impact resistance can be secured.
- the photocurable elastomer has a weight average molecular weight of about 1,000 to about 600,000 g / mol, or about 10,000 to about 600,000 g / mol It may be a polymer or oligomer in the range of.
- the photocurable elastomer may be, for example, at least one member selected from the group consisting of polycaprolactone, urethane acrylate polymer, and polyrotaxane.
- polycaprolactone is formed by ring-opening polymerization of caprolactone and has excellent physical properties such as flexibility, impact resistance, and durability.
- the urethane acrylate polymer has excellent elasticity and durability, including urethane bonds.
- the polyrotaxane refers to a compound in which a dumbbell shaped molecule and a cyclic compound are structurally sandwiched.
- the dumbbell shaped molecule includes a constant linear molecule and a blocking group disposed at both ends of the linear molecule, the linear molecule penetrates the interior of the cyclic compound, and the cyclic compound can move along the linear molecule. And the departure is prevented by the blocker.
- a cyclic compound in which a lactone compound having a (meth) acrylate compound introduced therein is bound; Linear molecules penetrating the cyclic compound; And a rotasein compound disposed at both ends of the linear molecule and including a blocking group to prevent the cyclic compound from being separated.
- the cyclic compound may be used without limitation as long as it has a size enough to penetrate or surround the linear molecule, and may be a hydroxyl group, an amino group, a carboxyl group, a thiol group, or the like, which may react with another polymer or compound.
- Functional groups such as an aldehyde group, may also be included.
- Specific examples of such cyclic compounds include ⁇ -cyclodextrin and ⁇ -cyclodextrin, ⁇ -cyclodextrin or mixtures thereof.
- a compound having a straight chain form having a molecular weight of a predetermined or more may be used without great limitation, but a polyalkylene compound or a polylactone compound may be used.
- a polyoxyalkylene compound containing a oxyalkylene repeating unit having 1 to 8 carbon atoms or a polylactone compound having a lactone repeating unit having 3 to 10 carbon atoms may be used.
- the blocking group may be appropriately adjusted according to the properties of the rotacein compound to be produced, for example, one selected from the group consisting of dinitrophenyl group, cyclodextrin group, ammantane group, triyl group, fluorescein group and pyrene group or Two or more kinds can be used.
- Such polyrotaxane compounds may have excellent scratch resistance and may exhibit self-healing ability when scratches or external damages occur.
- the hard coating composition of the present application includes inorganic fine particles.
- the inorganic fine particles may be included in a form dispersed in the binder monomer.
- inorganic fine particles having a particle size of nanoscale, for example, nanoparticles having a particle diameter of about 100 nm or less, or about 10 to about 100 nm, or about 10 to about 50 nm may be used.
- inorganic fine particles for example, silica fine particles, aluminum oxide particles, titanium oxide particles, zinc oxide particles, or the like can be used.
- the hardness of the hard coat film can be further improved.
- the inorganic fine particles are about 10 to about 60 parts by weight, or about 20 to about 50 parts by weight based on 100 parts by weight of the solid content including the monomer for the binder, the inorganic fine particles and the photoinitiator. May be included.
- the inorganic fine particles in the above range it is possible to achieve the effect of improving the hardness of the hard coat film according to the addition of the inorganic fine particles within a range not lowering the physical properties.
- the hard coating composition of the present application includes a photo initiator.
- the photoinitiator is 1-hydroxy-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, 2-hydroxy-1- [4- (2-hydroxyethoxy) phenyl] -2-methyl-1-propanone, methylbenzoylformate, ⁇ , ⁇ -dimethoxy- ⁇ -phenylacetophenone, 2-benzoyl-2- (dimethylamino ) -1- [4- (4-morpholinyl) phenyl] -1-butanone, 2-methyl-1- [4- (methylthio) phenyl] -2- (4-morpholinyl) -1 -Propanone diphenyl (2,4,6-trimethylbenzoyl) -phosphine oxide, or bis (2,4,6-trimethylbenzoyl) -phenylphosphine oxide, and the like, but are not limited thereto.
- commercially available products include Irgacure 184, Irgacure 500, Irgacure 651, Irgacure 369, Irgacure 907, Darocur 1173, Darocur MBF, Irgacure 819, Darocur TPO, Irgacure 907, and Esacure KIP 100F.
- These photoinitiators can be used individually or in mixture of 2 or more types different from each other.
- the photoinitiator is about 0.5 to about 10 parts by weight, or about 1 to about 5 parts by weight based on 100 parts by weight of the solid content including the monomer for the binder, the inorganic fine particles and the photoinitiator. May be included.
- the photoinitiator is in the above range, sufficient crosslinking photopolymerization can be achieved without lowering the physical properties of the hard coat film.
- the hard coating composition of the present application in addition to the above-described binder monomer, inorganic fine particles and photoinitiator, further comprises additives commonly used in the art to which the present application belongs, such as surfactants, anti-yellowing agents, leveling agents, antifouling agents can do.
- additives commonly used in the art to which the present application belongs such as surfactants, anti-yellowing agents, leveling agents, antifouling agents can do.
- the content can be variously adjusted within a range that does not lower the physical properties of the hard coating composition of the present application, it is not particularly limited, for example, it is included in about 0.1 to about 10 parts by weight based on 100 parts by weight of the solid content Can be.
- the hard coating composition may include a surfactant as an additive, and the surfactant may be a 1 to 2 functional fluorine acrylate, a fluorine surfactant or a silicone surfactant.
- the surfactant may be included in the form of being dispersed or crosslinked in the crosslinked copolymer.
- the additive may include a yellowing inhibitor
- the yellowing inhibitor may include a benzophenone compound or a benzotriazole compound.
- the hard coating composition of the present application includes an organic solvent.
- the organic solvent is a solid ratio of the solid content: organic solvent with respect to the solid content including the monomer for the binder, the inorganic fine particles, and the photoinitiator is about 70: 30 to about In the range of 99: 1 May be included.
- the hard coating composition of the present invention contains a solid content in a high content, a high viscosity composition is obtained, thereby enabling a thick coating, thereby forming a hard coating layer having a high thickness, for example, 50 ⁇ m or more. have.
- the organic solvent is an alcohol solvent such as methanol, ethanol, isopropyl alcohol, butanol, 2-methoxyethanol, 2-ethoxyethanol, 1-methoxy-2-propanol and Alkoxy alcohol solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, methyl propyl ketone, ketone solvents such as cyclohexanone, propylene glycol monopropyl ether, propylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono Ethers such as propyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethyl glycol monoethyl ether, diethyl glycol monopropyl ether, diethyl glycol monobutyl ether, diethylene glycol-2-ethylhexyl ether
- aromatic solvents such as benzen
- the viscosity of the hard coating composition is not particularly limited as long as it has a range of appropriate fluidity and applicability, but may exhibit high viscosity due to its relatively high solid content.
- the hard coating composition of the present invention may have a viscosity of about 100 to about 1,200 cps, or about 100 to about 1,200 cps, or about 150 to about 1,200 cps, or about 300 to about 1,200 cps at a temperature of 25 ° C. It can have
- the solvent- or solvent-free hard coating composition of the present invention comprising the above-described components may form a hard coating layer by applying a support substrate to photocuring.
- the thickness of the hard coating layer should be increased to 50 ⁇ m, 70 ⁇ m, or 100 ⁇ m or more.
- the process of planarizing the support substrate may be additionally performed, but since the crack occurs in the hard coating layer during the planarization process, it is not preferable.
- Hard coating composition according to the present application is less curl or crack generation even when applied and photocured to a high thickness on the support substrate in order to form a hard coating layer of high hardness, to form a hard coating layer having high transparency and high hardness Can be.
- a thickness of about 50 ⁇ m or more, for example, about 50 to about 150 ⁇ m, or about 70 to about 100 ⁇ m A hard coating layer having a thickness can be formed.
- the hard coating layer may be formed by a conventional method used in the art.
- the hard coating composition according to the present application is applied to one surface of the support substrate.
- the method of applying the composition is not particularly limited as long as it can be used in the technical field to which the present invention belongs, for example, bar coating method, knife coating method, roll coating method, blade coating method, die coating method, micro gravure A coating method, a comma coating method, a slot die coating method, a lip coating method, or a solution casting method may be used.
- the stabilizing step may be performed, for example, by treating the support substrate to which the hard coating composition is applied at a constant temperature. As a result, the coated surface may be stabilized by planarizing the coated surface and volatilizing the volatile components included in the hard coating composition.
- the hard coating layer may be formed by irradiating ultraviolet light on the applied hard coating composition to photocuring the same.
- the hard coating layer is formed on both sides of the supporting substrate using the hard coating composition of the present application, first the first hard coating composition is applied to one side of the supporting substrate and the first photocuring, and then the other side of the supporting substrate, That is, the second hard coating composition may be formed on the back by a two step process of second coating and second photocuring.
- the film including the hard coating layer formed by using the hard coating composition of the present application when exposed at a temperature of 50 ° C. or higher and a humidity of 80% or higher for 70 hours or more and placed on a flat surface, each corner or one side of the film is flat
- the maximum distance of the spaced apart may be about 1.0 mm or less, or about 0.6 mm or less, or about 0.3 mm or less. More specifically, when placed in a plane after exposure for 70 to 100 hours at a temperature of 50 ⁇ 90 °C and a humidity of 80 ⁇ 90%, the maximum value of the distance from each corner or one side plane of the film is about 1.0 mm or less, or about 0.6 mm or less, or about 0.3 mm or less.
- the film including the hard coating layer formed using the hard coating composition of the present application exhibits excellent high hardness, scratch resistance, high transparency, durability, light resistance, light transmittance, and the like, and may be usefully used in various fields.
- the film including the hard coating layer formed by using the hard coating composition of the present application may have a pencil hardness of 1H or more, 7H or more, or 8H or more, or 9H or more.
- the high hardness hard coating layer may be provided on only one side of the substrate, or both sides of the substrate may be provided.
- the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part may each independently include a pattern made of a conductive metal line.
- the pattern made of the conductive metal line may include a straight line, a curve, or a closed curve made of a straight line or a curve.
- the conductive patterns of the driving electrode part and the sensing electrode part may each independently be a regular pattern or an irregular pattern.
- the regular pattern a pattern form in the art such as a mesh pattern may be used.
- the mesh pattern may include a regular polygonal pattern including one or more of a triangle, a square, a pentagon, a hexagon, and an octagon.
- the conductive patterns of the driving electrode part and the sensing electrode part are regular patterns, and include intersection points formed by crossing a plurality of lines among the lines constituting the pattern, wherein the number of the intersection points is 3.5 cm It may be 3,000 to 122,500 pieces in an area of 3.5 cm, may be 13,611 to 30,625 pieces, and may be 19,600 to 30,625 pieces. In addition, according to the present application, it was confirmed that the case of 4,000 to 123,000 when mounted on the display exhibits optical characteristics that do not significantly damage the optical characteristics of the display.
- the conductive patterns of the driving electrode part and the sensing electrode part are irregular patterns, and include an intersection point formed by crossing a plurality of lines among the lines constituting the pattern, wherein the number of such intersection points is It may be 6,000 to 245,000 in an area of 3.5 cm ⁇ 3.5 cm, may be 3,000 to 122,500, may be 13,611 to 30,625, and may be 19,600 to 30,625.
- the pitch of the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part may be 600 ⁇ m or less, and 250 ⁇ m or less, but it may be adjusted by a person skilled in the art according to a desired transmittance and conductivity.
- a material having a specific resistance of 1 ⁇ 10 6 ohm ⁇ cm to 30 ⁇ 10 6 ohm ⁇ cm is appropriate, and it is 7 ⁇ 10 6 ohm ⁇ cm or less. More preferred.
- the conductive patterns of the driving electrode part and the sensing electrode part may be an irregular pattern.
- the irregular pattern includes a border structure of continuously connected closed figures, and there is no closed figure of the same shape in any irregular unit area (1 cm ⁇ 1 cm), and the number of vertices of the closed figures is: It may be different from the number of vertices of the same number of rectangles as the closed figures. More specifically, the number of vertices of the closed figures may be greater than the number of vertices of the same number of squares as the closed figures, and may be 1.9 to 2.1 times more, but is not limited thereto.
- closed figures are continuously connected to each other.
- adjacent closed figures may share a shape with at least one side.
- the irregular pattern includes a border structure of continuously connected closed figures, and the irregular pattern does not have the same closed figure within an arbitrary unit area (1 cm ⁇ 1 cm), and the number of vertices of the closed figures is
- the number of vertices of the polygon formed by connecting the shortest distance between the centers of gravity of each of the closed figures may be different. More specifically, the number of vertices of the closed figures may be greater than the number of vertices of the polygon formed by connecting the shortest distance between the centers of gravity of each of the closed figures, and may be 1.9 to 2.1 times more.
- the present invention is not limited thereto.
- the irregular pattern includes a border structure of continuously connected closed figures, and the irregular pattern does not have the same closed figure in an arbitrary unit area (1 cm ⁇ 1 cm), and the closed figures are represented by the following equation.
- the value of 1 may be 50 or more.
- the value of Equation 1 may be calculated within the unit area of the conductive pattern.
- the unit area may be an area where a conductive pattern is formed, and for example, 3.5 cm ⁇ 3.5 cm, but is not limited thereto.
- the vertex is defined as meaning that the lines constituting the border of the closed figures of the conductive pattern cross each other.
- the irregular pattern may be in the form of a border structure of closed figures in which arbitrary points are arranged in regularly arranged unit unit cells, and then each point is connected to a point closest to the distance from other points. have.
- the irregular pattern may be formed when an irregularity is introduced in a method of arranging arbitrary points in the regularly arranged unit unit cells. For example, when the irregularity is set to 0, if the unit unit cell is square, the conductive pattern has a square mesh structure. If the unit unit cell is a regular hexagon, the conductive pattern has a honeycomb structure. That is, the irregular pattern means a pattern in which the irregularity is not zero.
- the conductive pattern of the irregular pattern form according to the present application, it is possible to suppress the pulling phenomenon of the lines constituting the pattern, to obtain a uniform transmittance from the display and at the same time to maintain the same line density for the unit area, It is possible to ensure uniform conductivity.
- the conductive pattern of the driving electrode portion, the sensing electrode portion, and the wiring electrode portion is not particularly limited, but at least one selected from the group consisting of metals, metal oxides, metal nitrides, metal oxynitrides, and metal alloys. It is preferable to include.
- the material of the conductive pattern of the driving electrode part, the sensing electrode part and the wiring electrode part is preferably a material having excellent conductivity and easy etching.
- the total reflectance can be lowered, the visibility of the conductive pattern can be lowered, and the contrast characteristics can be maintained or improved.
- the material of the conductive pattern of the driving electrode part, the sensing electrode part and the wiring electrode part As a specific example of the material of the conductive pattern of the driving electrode part, the sensing electrode part and the wiring electrode part, a single film or a multilayer film containing gold, silver, aluminum, copper, neodymium, molybdenum, nickel or an alloy thereof is preferable.
- the thickness of the conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part is not particularly limited, but is preferably 0.01 to 10 ⁇ m in view of the conductivity of the conductive pattern and the economics of the forming process.
- the conductive patterns of the driving electrode part and the sensing electrode part may have a line width of 10 ⁇ m or less, 7 ⁇ m or less, 5 ⁇ m or less, 4 ⁇ m or less, 2 ⁇ m or less, and 0.1 ⁇ m. It may be abnormal. More specifically, the conductive patterns of the driving electrode part and the sensing electrode part may have a line width of 0.1 to 1 ⁇ m, 1 to 2 ⁇ m, 2 to 4 ⁇ m, 4 to 5 ⁇ m, 5 to 7 ⁇ m, but are not limited thereto. no.
- the line width of the conductive patterns of the driving electrode and the sensing electrode may be 10 ⁇ m or less and the thickness of 10 ⁇ m or less, and the line width of the conductive patterns of the driving electrode and the sensing electrode may be 7 ⁇ m or less and the thickness may be 1 ⁇ m or less.
- the line widths of the conductive patterns of the driving electrode part and the sensing electrode part may be 5 ⁇ m or less and the thickness may be 0.5 ⁇ m or less.
- the line widths of the conductive patterns of the driving electrode part and the sensing electrode part are 10 ⁇ m or less, and the conductive patterns of the driving electrode part and the sensing electrode part are each of the closed figures within an area of 3.5 cm ⁇ 3.5 cm.
- the number of vertices can be between 6,000 and 245,000.
- the line widths of the conductive patterns of the driving electrode part and the sensing electrode part may be 7 ⁇ m or less, and the conductive pattern may have the number of vertices of the closed figures within the area of 3.5 cm ⁇ 3.5 cm.
- the line width of the conductive patterns of the driving electrode and the sensing electrode is 5 ⁇ m or less, and the number of vertices of the closed figures is 15,000 to 62,000 within the area of 3.5 cm ⁇ 3.5 cm. Can be.
- the opening ratio of the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part, that is, the area ratio not covered by the pattern may be 70% or more, 85% or more, or 95% or more.
- an opening ratio of the conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part may be 90 to 99.9%, but is not limited thereto.
- any region of 1 mm x 1 mm of the conductive patterns of the driving electrode portion, the sensing electrode portion, and the wiring electrode portion at least one region having different aperture ratios of the conductive patterns of the driving electrode portion, the sensing electrode portion, and the wiring electrode portion is different from each other. Including, the difference in the aperture ratio may be 0.1 to 5%, but is not limited thereto.
- the line width of the conductive pattern of the wiring electrode part may be 150 ⁇ m or less, 100 ⁇ m or less, 50 ⁇ m or less, 30 ⁇ m or less, 10 ⁇ m or less, or 0.1 ⁇ m or more, but is not limited thereto. It doesn't happen.
- At least a part of the conductive pattern of the wiring electrode part may have a line width different from the conductive patterns of the driving electrode part and the sensing electrode part.
- the difference in the line width may be 5 ⁇ 100 ⁇ m, may be 5 ⁇ 30 ⁇ m, may be 5 ⁇ 15 ⁇ m, but is not limited thereto.
- a thin line width is formed on the transparent substrate by using a printing method, thereby forming a precise conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part.
- the printing method may be performed by transferring a paste or ink including a conductive pattern material onto a transparent substrate in the form of a desired pattern and firing the same.
- the printing method is not particularly limited, and printing methods such as offset printing, screen printing, gravure printing, flexographic printing, inkjet printing, and nano imprint may be used, and one or more of these complex methods may be used.
- the printing method may use a roll to roll method, a roll to plate, a plate to roll or a plate to plate method.
- a reverse offset printing method it is preferable to apply a reverse offset printing method to realize a precise conductive pattern.
- an ink that can act as a resist during etching on a silicone rubber called a blanket is coated over the entire surface, and then, through the intaglio inscribed with a pattern called a first cliché, the unnecessary portion is removed and secondly.
- the printing pattern remaining on the blanket may be transferred onto a substrate such as a film or glass on which metal or the like is deposited, and thereafter, a method of forming the desired pattern may be performed through a baking and etching process.
- Using this method has the advantage of maintaining uniformity in the thickness direction as the uniformity of the consensus in the entire area is secured by using the metal deposited substrate.
- the present application may include a direct printing method of forming a desired pattern by directly printing a conductive ink such as Ag ink and then firing by using the reverse offset printing method described above.
- a conductive ink such as Ag ink
- the line height of the pattern is flattened by the pressing pressure, and the conductivity can be given by a thermo firing process or microwave firing process or laser partial firing process for the purpose of connection due to mutual surface fusion of Ag nanoparticles. have.
- the conductive pattern of the wiring electrode part is formed by a printing process
- the present invention is not limited thereto. That is, according to the exemplary embodiment of the present application, in order to ensure the dimensional stability of the FPCB bonding area, the FPCB bonding pads PAD may be disposed in the same direction in a direction in which the shrinkage expansion ratio of the film is easy, There is a feature to set the print direction. Details of the printing direction of the wiring electrode unit are schematically illustrated in FIG. 28.
- the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part may each independently include a darkening pattern provided in an area corresponding to the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part. It may include.
- the reflective diffraction intensity of the reflective diffraction image obtained by irradiating light from a point light source on one surface where the darkening pattern of the touch sensing region is visible, the conductive pattern is made of Al, and the darkening pattern Except that it does not include may be reduced by more than 60% compared to the touch sensor having the same configuration.
- the reflective diffraction intensity may be reduced by 60% or more and 70% or more, compared to the touch sensor having the same configuration except that the conductive pattern is made of Al and does not include a darkening pattern.
- the total reflectance measured by using a total reflectance measuring device assuming ambient light on one surface where the darkening pattern of the touch sensing area is visible the conductive pattern is Al Except that it is made and does not include a darkening pattern may be reduced by more than 20% compared to the touch sensor having the same configuration.
- the total reflectance may be reduced by 20% or more, and may be reduced by 25% or more compared to the touch sensor having the same configuration except that the conductive pattern is made of Al and does not include a darkening pattern. More than 30%. For example, it may be a 25 to 50% reduction.
- the darkening pattern of the touch sensing area may be provided on the upper and / or lower surfaces of the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part, and the driving electrode part, the sensing electrode part, and the wiring electrode part. It may be provided on at least a portion of the side surface as well as the top and bottom of the conductive pattern, and may be provided on the top, bottom and side surfaces of the conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part.
- the darkening pattern of the touch sensing area is provided on the entire surface of the conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part, so that the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part are formed. Visibility due to high reflectivity can be reduced.
- the darkening pattern since the darkening pattern has an extinction interference and its own absorbance under a certain thickness condition when combined with a layer having high reflectivity such as a conductive layer, the driving electrode passes through the light and the darkening pattern reflected by the darkening pattern.
- the drive electrode part, the sensing electrode part, and the wiring part are induced by mutually extinguishing interference between two lights under a certain thickness condition.
- the effect of lowering the reflectivity by the conductive pattern of the electrode portion is exhibited.
- the color range of the pattern region consisting of the darkening pattern and the conductive pattern, measured in view of the darkening pattern of the touch sensing area according to the present application L value is 20 or less, A value based on the CIE LAB color coordinates Is -10 to 10, B value can be -70 to 70, L value is 10 or less, A value is -5 to 5, B value can be 0 to 35, L value is 5 or less, A value is The value of -2 to 2 and B may be 0 to 15.
- the total reflectance of the pattern area including the darkening pattern and the conductive pattern of the driving electrode part, the sensing electrode part, or the wiring electrode part measured from the view of the darkening pattern of the touch sensing area according to the present application is based on the external light of 550 nm. When used, it may be 17% or less, 10% or less, and 5% or less.
- the total reflectance means a reflectance in consideration of both a diffuse reflectance and a specular reflectance.
- the total reflectance is a value observed by measuring only the reflectivity of the surface to be measured after making the reflectance zero using a black paste or a tape on the opposite side of the surface to which the reflectance is to be measured.
- the incoming light source introduced a diffuse light source most similar to the ambient light condition.
- the measurement position which measures a reflectance at this time was based on the position inclined about 7 degree
- the darkening pattern may be patterned simultaneously or separately with the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part, but a layer for forming each pattern is formed separately. However, it is most preferable to simultaneously form the conductive pattern and the darkened pattern so that the conductive pattern and the darkened pattern exist on the surface corresponding to each other.
- a fine conductive pattern required for the touch sensor may be realized while optimizing and maximizing the effect of the darkening pattern itself.
- the touch sensor when failing to implement a fine conductive pattern, it is not possible to achieve the properties required for the touch sensor, such as resistance.
- the darkening pattern and the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part have a separate pattern layer in a stacked structure, at least a part of the light absorbing material is recessed or dispersed in the conductive pattern.
- the structure of a single layer or a conductive layer of a single layer is different from the structure in which a part of the surface is physically or chemically modified by surface treatment.
- the darkening pattern is provided directly on the substrate or directly on the conductive patterns of the driving electrode part, the sensing electrode part, and the wiring electrode part without interposing the adhesive layer or the adhesive layer.
- the adhesive layer or adhesive layer may affect durability or optical properties.
- the laminate included in the touch sensor according to the present application is completely different in the manufacturing method compared with the case of using the adhesive layer or the adhesive layer.
- the interface characteristic of the conductive pattern and the darkening pattern of a base material or a drive electrode part, a sensing electrode part, and a wiring electrode part is excellent.
- the etching characteristics with the conductive pattern during the manufacturing process it is preferable to select between 10nm to 400nm, the preferred thickness may vary depending on the material and the manufacturing process used, the scope of the present application It is not limited by the numerical range.
- the darkening pattern may be formed of a single layer or may be formed of two or more layers.
- the darkening pattern is preferably close to an achromatic color. However, it does not necessarily need to be achromatic, and even if it has color, it can be introduced if it has low reflectivity.
- the achromatic color means a color that appears when light incident on the surface of the object is not selectively absorbed and is evenly reflected and absorbed for the wavelength of each component.
- the darkening pattern may use a material having a standard deviation of 50% of the total reflectance for each wavelength band when measuring the total reflectance in the visible region (400 nm to 800 nm).
- a material made of a metal, a metal oxide, a metal nitride, or a metal oxynitride having the above-described physical properties when the front layer is formed may be used without particular limitation.
- the darkening pattern may be an oxide film, a nitride film, an oxide-nitride film, a carbide film, a metal film, or a combination thereof according to deposition conditions set by those skilled in the art using Ni, Mo, Ti, Cr, and the like.
- the darkening pattern may include Ni and Mo simultaneously.
- the darkening pattern may include 50 to 98 atomic% of Ni and 2 to 50 atomic% of Mo, and may further include 0.01 to 10 atomic% of other metals such as Fe, Ta, Ti, and the like.
- the darkening pattern may further include 0.01 to 30 atomic% nitrogen or 4 atomic% or less oxygen and carbon, if necessary.
- the darkening pattern is a dielectric material selected from SiO, SiO 2 , MgF 2 and SiNx (x is an integer of 1 or more) and Fe, Co, Ti, V, Al, Cu, Au and Ag.
- the metal may be selected, and may further include an alloy of two or more metals selected from Fe, Co, Ti, V, Al, Cu, Au, and Ag.
- the dielectric material is distributed such that it gradually decreases away from the direction in which external light is incident, and the metal and alloy components are distributed in the opposite direction. At this time, the content of the dielectric material is 20 to 50% by weight, the content of the metal is preferably 50 to 80% by weight.
- the darkening pattern further includes an alloy
- the darkening pattern may include 10 to 30 wt% of dielectric material, 50 to 80 wt% of metal, and 5 to 40 wt% of alloy.
- the darkening pattern may be formed of a thin film including at least one of an alloy of nickel and vanadium, an oxide of nickel and vanadium, nitride, and oxynitride.
- vanadium is preferably contained at 26 to 52 atomic%, and the atomic ratio of vanadium to nickel is preferably 26/74 to 52/48.
- the darkening pattern may include a transition layer having two or more elements, and one elemental composition ratio increases by up to about 20% per 100 angstroms according to the direction in which external light is incident.
- one element may be a metal element such as chromium, tungsten, tantalum, titanium, iron, nickel or molybdenum, and elements other than the metal element may be oxygen, nitrogen, or carbon.
- the darkening pattern may include a first chromium oxide layer, a metal layer, a second chromium oxide layer, and a chromium mirror, wherein tungsten, vanadium, iron, chromium, molybdenum and It may include a metal selected from niobium.
- the metal layer may have a thickness of 10 to 30 nm
- the first chromium oxide layer may have a thickness of 35 to 41 nm
- the second chromium oxide layer may have a thickness of 37 to 42 nm.
- a layered structure of an alumina (Al 2 O 3 ) layer, a chromium oxide (Cr 2 O 3 ) layer, and a chromium (Cr) layer may be used as the darkening pattern.
- the alumina layer has an improvement in reflection characteristics and light diffusion prevention characteristics
- the chromium oxide layer may improve contrast characteristics by reducing mirror reflectance.
- the darkening pattern is provided in an area corresponding to the conductive pattern of the driving electrode part, the sensing electrode part, and the wiring electrode part.
- the region corresponding to the conductive pattern means that the pattern has the same shape as the conductive pattern.
- the pattern scale of the darkening pattern is not necessarily the same as the conductive pattern, and the case where the line width of the darkening pattern is narrower or wider than the line width of the conductive pattern is also included in the scope of the present application.
- the darkening pattern preferably has an area of 80% to 120% of the area provided with the conductive pattern.
- the darkening pattern may have a pattern shape having a line width equal to or larger than the line width of the conductive pattern.
- the darkening pattern has a pattern shape having a line width larger than the line width of the conductive pattern
- the glossiness of the conductive pattern itself may be greater because the darkening pattern may give a greater effect of masking the conductive pattern when viewed by a user.
- the line width of the darkening pattern is the same as the line width of the conductive pattern can achieve the desired effect in the present application. It is preferable that the line width of the darkening pattern has a width larger than the line width of the conductive pattern by a value according to Equation 2 below.
- Tcon is the thickness of the conductive pattern
- ⁇ 3 is the angle that the light makes with the normal to the surface of the substrate when the light incident from the user's sight of the touch sensor passes through the edges of the conductive pattern and the darkening pattern.
- ⁇ 3 is Snell's law based on the user's vision of the touch sensor and the angle between the substrate ( ⁇ 1 ) by the refractive index of the substrate and the medium of the region where the darkening pattern and the conductive pattern are disposed, for example, the refractive index of the adhesive of the touch sensor. Along the angle.
- the darkening pattern is based on the side width of the conductive pattern. It is preferable that the thickness is as large as about 2.24 ⁇ m (200 nm ⁇ tan (80) ⁇ 2). However, as described above, even when the darkening pattern has the same line width as the conductive pattern, the effect desired in the present application can be achieved.
- the manufacturing process of the touch sensor by improving the manufacturing process of the touch sensor, it is possible to reduce the manufacturing cost of the touch sensor, it is possible to improve the weight, thinning and the like of the touch sensor.
- the thickness of the touch sensor can be minimized and the manufacturing method is easy because all the conductive patterns are formed on the cross-section.
- it is a single sheet type, there is an advantage that the lamination is not required as compared with the prior art formed by using two or more substrates.
- the driving electrode portion and the sensing electrode portion are on the same surface, installation and attachment of the FPCB (Flexible Printed Circuit Board) is easy.
- it is a single sheet
- when laminating the functional surface film on the surface of the touch sensor there is an advantage that bubbles are not occupied because the step is not large.
- the manufacturing process of the touch sensor by improving the manufacturing process of the touch sensor, it is possible to reduce the manufacturing cost of the touch sensor, it is possible to improve the weight, thinning and the like of the touch sensor.
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Abstract
Description
Claims (17)
- 기재; 및 상기 기재 상의 동일 면 상에 구비된 구동 전극부, 감지 전극부 및 배선 전극부를 포함하는 터치 센서이고,상기 구동 전극부, 감지 전극부 및 배선 전극부는 각각 차폐부와 개구부를 포함하는 전도성 패턴을 포함하며,상기 배선 전극부는 터치 센서의 터치 감지영역에 위치한 제1 배선 전극부 및 터치 센서의 터치 비감지영역에 위치한 제2 배선 전극부를 포함하고, 상기 제1 배선 전극부는 상기 구동 전극부 또는 상기 감지 전극부를 상기 제2 배선 전극부에 연결하는 배선들의 번들(bundle)을 1 또는 2 이상 포함하고,상기 배선들 각각은 그물망 패턴으로 이루어지고,상기 번들 중 최대 개수의 배선들이 포함되는 번들에서, 상기 번들의 폭(W), 상기 번들에 포함되는 배선들의 개수(n), 및 상기 배선들을 구성하는 그물망 패턴 중 적어도 하나의 변을 공유하는 이웃한 그물망 구조들의 중심점들간의 거리 중 최소값(P)이 하기 식 1을 만족하는 것을 특징으로 하는 터치 센서:[식 1]
- 기재; 및 상기 기재 상의 동일 면 상에 구비된 구동 전극부, 감지 전극부 및 배선 전극부를 포함하는 터치 센서이고,상기 구동 전극부, 감지 전극부 및 배선 전극부는 차폐부와 개구부를 포함하는 전도성 패턴을 포함하며,상기 배선 전극부는 터치 센서의 터치 감지영역에 위치한 제1 배선 전극부 및 터치 센서의 터치 비감지영역에 위치한 제2 배선 전극부를 포함하고, 상기 제1 배선 전극부는 상기 구동 전극부 또는 상기 감지 전극부를 상기 제2 배선 전극부에 연결하는 배선들의 번들(bundle)을 1 또는 2 이상 포함하고,상기 번들은 2개의 단선점을 갖는 폐쇄도형이, 상기 제2 배선 전극의 단부에 인접한 상기 기재의 일 변으로부터 이에 대향하는 기재의 타 변까지의 방향으로 연속 배치되는 패턴의 형태로 이루어지고,상기 연속 배치된 폐쇄도형들의 인접하는 단선점들을 최단거리로 연결한 가상의 직선은 1 이상의 변곡점을 갖고, 상기 변곡점에서 상기 가상의 직선이 이루는 각은 90도 이상이고,상기 가상의 직선에 접하는 패턴은 상기 구동 전극부 또는 상기 감지 전극부를 상기 제2 배선 전극부에 전기적으로 연결하는 것을 특징으로 하는 터치 센서.
- 청구항 1에 있어서, 상기 번들은 2개의 단선점을 갖는 폐쇄도형이, 상기 제2 배선 전극의 단부에 인접한 상기 기재의 일 변으로부터 이에 대향하는 기재의 타 변까지의 방향으로 연속 배치되는 패턴의 형태로 이루어지고,상기 연속 배치된 폐쇄도형들의 인접하는 단선점들을 최단거리로 연결한 가상의 직선은 1 이상의 변곡점을 갖고, 상기 변곡점에서 상기 가상의 직선이 이루는 각은 90도 이상이고,상기 가상의 직선에 접하는 패턴은 상기 구동 전극부 또는 상기 감지 전극부를 상기 제2 배선 전극부에 전기적으로 연결하는 것을 특징으로 하는 터치 센서.
- 청구항 4에 있어서, 상기 식 1은 하기 식 3으로 표시되는 것을 특징으로 하는 터치 센서:[식 3]상기 식 3에서, W, n 및 P는 상기 식 1에서 정의한 바와 동일하고,θ2는 상기 단선점들을 최단거리로 연결한 가상의 직선에 대하여 수직방향의 직선과, 적어도 하나의 변을 공유하는 이웃한 그물망 구조들의 중심점들을 최단거리로 잇는 직선이 이루는 각 중 작은 값을 나타낸다.
- 청구항 2에 있어서, 상기 가상의 직선 중 변곡점 사이의 길이가 가장 긴 부분이,상기 폐쇄도형을 구성하는 적어도 하나의 변과 서로 평행하거나, 0도 초과 90도 미만의 각을 이루는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 구동 전극부, 감지 전극부 및 배선 전극부는 전도성 금속선으로 이루어진 것을 특징으로 하는 터치 센서.
- 청구항 7에 있어서, 상기 전도성 금속선은 금, 은, 알루미늄, 구리, 네오디윰, 몰리브덴, 니켈 및 이들의 합금으로 이루어진 군으로부터 선택되는 1종 이상을 포함하는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 구동 전극부, 감지 전극부 및 배선 전극부의 전도성 패턴은 각각 독립적으로, 상기 패턴 상에 암색화 패턴을 추가로 포함하는 것을 특징으로 하는 터치 센서.
- 청구항 2에 있어서, 상기 단선점의 평균 지름은 13㎛ 이하인 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 구동 전극부 및 감지 전극부의 전도성 패턴 중 적어도 일부는 단선점을 포함하고,상기 단선점의 평균 지름은 13㎛ 이하인 것을 특징으로 하는 터치 센서.
- 청구항 11에 있어서, 상기 구동 전극부 및 감지 전극부는 전도성 금속선으로 이루어지고,상기 단선점은 상기 구동 전극부 또는 감지 전극부 내 전도성 금속선이 서로 교차하는 교차점 영역에 구비되는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 구동 전극부, 감지 전극부 및 배선 전극부의 패턴은 각각 독립적으로 다각형의 메쉬 패턴을 포함하는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 번들의 폭이 W이고, (W × W)의 면적을 기준으로,상기 (W × W)의 면적에 대응되는 상기 터치 센서의 임의의 영역들 간의 개구율 편차는 10% 이내인 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 구동 전극부, 감지 전극부 및 배선 전극부는 1회의 인쇄공정에 의하여 동시에 형성되는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2에 있어서, 상기 터치 센서는 뮤추얼 캐패시턴스 방식을 이용하여 터치 입력을 인식하는 것을 특징으로 하는 터치 센서.
- 청구항 1 또는 2의 터치 센서를 포함하는 디스플레이 장치.
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US15/039,732 US10261638B2 (en) | 2013-12-13 | 2014-12-15 | Touch sensor and method for manufacturing same |
JP2016534159A JP6497752B2 (ja) | 2013-12-13 | 2014-12-15 | タッチセンサおよびその製造方法{touch sensor and method for manufacturing same} |
EP14870184.0A EP3082023A4 (en) | 2013-12-13 | 2014-12-15 | Touch sensor and method for manufacturing same |
CN201480068350.XA CN105830000B (zh) | 2013-12-13 | 2014-12-15 | 触控传感器以及该触控传感器的制造方法 |
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KR10-2013-0155800 | 2013-12-13 | ||
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KR102002882B1 (ko) * | 2015-06-14 | 2019-07-24 | 주식회사 엘지화학 | 터치 센서 및 이의 제조방법 |
-
2014
- 2014-12-15 TW TW103143734A patent/TWI559186B/zh active
- 2014-12-15 EP EP14870184.0A patent/EP3082023A4/en not_active Ceased
- 2014-12-15 KR KR1020140180756A patent/KR101682773B1/ko active IP Right Grant
- 2014-12-15 JP JP2016534159A patent/JP6497752B2/ja active Active
- 2014-12-15 WO PCT/KR2014/012362 patent/WO2015088295A1/ko active Application Filing
- 2014-12-15 US US15/039,732 patent/US10261638B2/en active Active
- 2014-12-15 CN CN201480068350.XA patent/CN105830000B/zh active Active
Patent Citations (5)
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US20100123670A1 (en) * | 2008-11-15 | 2010-05-20 | Atmel Corporation | Touch Screen Sensor |
US20100302204A1 (en) * | 2009-05-29 | 2010-12-02 | Mitsubishi Electric Corporation | Touch panel and display apparatus having the same |
US20130100054A1 (en) * | 2009-10-29 | 2013-04-25 | Harald Philipp | Dual-Substrate-Sensor Stack With Electrodes Opposing a Display |
KR20110127429A (ko) * | 2010-05-19 | 2011-11-25 | 주식회사 일야 | 금속박막을 이용한 터치패널 및 그 제조방법 |
US20130127775A1 (en) * | 2011-11-22 | 2013-05-23 | Esat Yilmaz | Single-Layer Touch Sensor with Crossovers |
Also Published As
Publication number | Publication date |
---|---|
CN105830000B (zh) | 2019-02-12 |
US20160364043A1 (en) | 2016-12-15 |
TWI559186B (zh) | 2016-11-21 |
JP6497752B2 (ja) | 2019-04-10 |
EP3082023A4 (en) | 2017-08-23 |
JP2016540304A (ja) | 2016-12-22 |
KR20150069568A (ko) | 2015-06-23 |
EP3082023A1 (en) | 2016-10-19 |
TW201543293A (zh) | 2015-11-16 |
US10261638B2 (en) | 2019-04-16 |
KR101682773B1 (ko) | 2016-12-05 |
CN105830000A (zh) | 2016-08-03 |
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