WO2015075683A1 - 预浸料制成的半成品及三维预成型体和包塑成型件 - Google Patents
预浸料制成的半成品及三维预成型体和包塑成型件 Download PDFInfo
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- WO2015075683A1 WO2015075683A1 PCT/IB2014/066238 IB2014066238W WO2015075683A1 WO 2015075683 A1 WO2015075683 A1 WO 2015075683A1 IB 2014066238 W IB2014066238 W IB 2014066238W WO 2015075683 A1 WO2015075683 A1 WO 2015075683A1
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- WIPO (PCT)
- Prior art keywords
- prepreg
- layer
- semi
- finished product
- dimensional
- Prior art date
Links
- 239000011265 semifinished product Substances 0.000 title claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 claims abstract description 60
- 239000002184 metal Substances 0.000 claims abstract description 60
- 229920005992 thermoplastic resin Polymers 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 10
- 239000000047 product Substances 0.000 abstract description 10
- 230000002787 reinforcement Effects 0.000 abstract description 10
- 238000003303 reheating Methods 0.000 abstract description 4
- 230000000717 retained effect Effects 0.000 abstract 1
- 230000000153 supplemental effect Effects 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 22
- 229920005989 resin Polymers 0.000 description 22
- 239000011347 resin Substances 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
Classifications
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
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- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29B11/00—Making preforms
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
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- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
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- B29C45/1418—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
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- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
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- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
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- B32B38/18—Handling of layers or the laminate
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
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- B29C45/1418—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
- B29C2045/14237—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure the inserts being deformed or preformed outside the mould or mould cavity
- B29C2045/14245—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure the inserts being deformed or preformed outside the mould or mould cavity using deforming or preforming means outside the mould cavity
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2623/00—Use of polyalkenes or derivatives thereof for preformed parts, e.g. for inserts
- B29K2623/10—Polymers of propylene
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- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/07—Parts immersed or impregnated in a matrix
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Definitions
- the present invention relates to the field of prepreg products, and more particularly to a semi-finished product made of a prepreg and a three-dimensional product made of the semi-finished product. Preforms and overmolded parts.
- a prepreg (“PREPREG" in English) is a commonly used intermediate material for making composite materials, usually composed of a resin matrix and a reinforcement (for example, fiber or fabric) impregnated in the matrix. Due to the inclusion of reinforcements, prepregs have a high mechanical strength and are often used in the manufacture of parts or areas where reinforcement is required, such as automotive parts. Prepregs purchased on the market are usually in the form of sheets or rolls.
- a method of manufacturing such a three-dimensional component is known to comprise the following steps: Step 1: Cutting the purchased prepreg into a suitable shape and size (usually obtained by two-dimensional expansion of a desired three-dimensional preform) And stacking several layers of prepregs having suitable shapes and sizes as needed to obtain a semi-finished product; Step 2: heating the semi-finished product and then performing hot stamping to obtain a three-dimensional preform; Step 3: The three-dimensional preform is taken out from the hot stamping forming die and machined after cooling, such as contour finishing, drilling, etc., to have the desired final dimensions and geometry; Step 4: Re-repair the three-dimensional preform Heating above the melting point of the prepreg resin matrix for subsequent overmolding in the resin matrix of the prepreg and A good adhesion between the overmolding resin is obtained; Step 5: transferring the hot three-dimensional preform into an overmolding mold, and molding the thermoplastic resin
- FIG. 1 shows a three-dimensional preform obtained after the step 3 by the above method
- FIG. 2 shows a three-dimensional preform obtained after the step 4.
- the three-dimensional preform includes two layers of prepreg. Material layers 10, 12.
- the present invention provides a semi-finished product made of a prepreg comprising at least a first prepreg layer and a second prepreg layer, characterized in that the first prepreg layer and the A metal layer is laid between the second prepreg layers.
- prepreg English "PREPREG"
- PREPREG a commonly used intermediate material for the manufacture of composite materials. It has the usual meaning in the field of composite materials, which is made by impregnating the reinforcement with a resin matrix under strictly controlled conditions. A combination of a resin matrix and a reinforcement.
- the term "semi-finished product” refers to an intermediate product that has not yet been manufactured as a final product and still requires further processing.
- the three-dimensional preform formed of the semi-finished product can be obtained during the reheating process before the overmolding
- the support of the metal layer maintains its three-dimensional shape well without collapse.
- the added metal layer remains in the finally obtained overmolded product, it can also enhance the mechanical strength of the product and provide a complementary reinforcement.
- the semi-finished product according to the present invention may further comprise one or more of the following technical features: when the thermoplastic resin contained in the first prepreg layer and the second prepreg layer is softened, the metal The layer remains solid.
- the metal layer is a metal mesh. Since the metal mesh has mesh, it can reduce the weight of the final product and save production costs.
- the resin matrix of the adjacent layer prepreg can be welded to each other through the mesh of the metal mesh, thereby fixing the metal mesh more firmly. Between two layers of prepreg.
- the first prepreg layer and the second prepreg layer have the same shape and size as the metal mesh.
- the metal mesh can cover the entire prepreg layer, providing support at every location without leaving a "support blind spot.” Therefore, the three-dimensional preform made of the semi-finished product can better maintain its three-dimensional shape during the reheating process before the overmolding.
- the metal contains iron. This can enhance the mechanical properties of the final product.
- the metal may be selected from the group consisting of iron, mild steel, copper alloys, and aluminum alloys.
- a polypropylene film is also laid between the first prepreg layer and/or the second prepreg layer and the metal mesh.
- the polypropylene film can fill the metal mesh, the air trapped therein is discharged, so that the uniformity of the product can be greatly improved. In addition, this also helps to improve the metal mesh Bonding Force to Prepreg Layer
- the polypropylene film has the same shape and size as the metal mesh.
- the reinforcing material in the prepreg is carbon or glass.
- the present invention also relates to a three-dimensional preform, which is produced by hot stamping from the above-mentioned semi-finished product. Further, the present invention relates to an overmolded molded article characterized in that it comprises at least one three-dimensional preform as described above and a thermoplastic resin portion which is overmolded on the three-dimensional preform.
- the overmolded part is a component of a motor vehicle, in particular a rear closing part of a motor vehicle.
- a motor vehicle in particular a rear closing part of a motor vehicle.
- FIG. 4 is an exploded perspective view of the semifinished product shown in Fig. 3;
- Fig. 5 is a view showing the process of processing the semifinished product shown in Fig. 3 into a three-dimensional preform;
- Fig. 6 is a process shown in Fig. 5.
- Figure 7 shows the internal structure of the three-dimensional preform shown in Figure 6;
- Figure 8 shows the entire manufacturing process from the commercially available prepreg to the final three-dimensional component;
- Figure 9 is the final three-dimensional component according to the present invention.
- Figure 3 shows a perspective view of a semi-finished product 1 made of a prepreg in accordance with one embodiment of the present invention.
- Figure 4 better illustrates the structure of the semi-finished product 1 in an exploded view.
- the semi-finished product 1 includes a first prepreg layer 10, a second prepreg layer 12, and a metal layer sandwiched between the two layers. It will be appreciated that the semi-finished product 1 may include more prepreg layers and/or metal layers, which can be determined by those skilled in the art according to specific design goals.
- the semi-finished product 1 includes first, second, and third prepreg layers stacked in sequence with a metal layer sandwiched between each two adjacent prepreg layers.
- the semifinished product 1 comprises first, second and third prepreg layers stacked in sequence, but with a metal layer sandwiched between the first and second prepreg layers.
- prepreg ("PREPREG" in English) is a commonly used intermediate material for the manufacture of composite materials, usually consisting of a resin matrix and a reinforcement (for example: fiber or fabric) impregnated in the matrix.
- the first prepreg layer 10 and the second prepreg layer 12 are each composed of a thermoplastic resin matrix and a reinforcement impregnated in the matrix, and the reinforcement may be carbon and/or glass fiber or fabric.
- the metal layer can be composed of any suitable metal or alloy (e.g., iron, mild steel, copper alloy, aluminum alloy, etc.).
- the metal layer is composed of a ferrous material which enhances the mechanical properties of the final product.
- the metal layer can be solid or perforated.
- the metal layer is a meshed metal mesh 14, which reduces the weight of the final product and saves production costs.
- the resin matrix of the adjacent layer prepreg may be welded to each other through the mesh of the metal mesh, thereby making the metal mesh more firmly It is fixed between two layers of prepreg.
- a polypropylene film can also be laid between the metal mesh and the prepreg layers 10 and/or 12 adjacent thereto. Since the polypropylene film can fill the metal mesh, the air trapped therein is discharged, so that the uniformity of the product can be greatly improved. In addition, this also helps to improve the bonding force between the metal mesh and the prepreg layer.
- the first prepreg layer 10 and the second prepreg layer 12 have the same shape and dimensions as the metal mesh 14.
- the three-dimensional preform obtained from the semi-finished product 1 can be fully supported by the metal layer 14 during reheating, thereby better maintaining its three-dimensional shape.
- Fig. 5 shows a process of processing the semi-finished product 1 shown in Fig. 3 into a three-dimensional preform 2
- Figs. 6 and 7 show a three-dimensional preform 2 obtained by the process.
- a portion of the second prepreg layer 12 is removed in FIG.
- the semi-finished product is heated before the semi-finished product 1 is placed in a molding die at a heating temperature higher than the melting point of the prepreg resin matrix. Then, the hot semi-finished product 1 is placed in a molding die (for example, the hot stamping dies 20, 22 shown in Fig. 5), and is three-dimensionally formed. It should be noted that in this molding step, the metal layers contained in the semi-finished product 1 are also molded together. Thereafter, demolding is carried out at a temperature lower than the melting point of the prepreg resin matrix to obtain a three-dimensional preform 2 having a desired three-dimensional shape, as shown in Figs. 6 and 7.
- Step A Cutting the purchased prepreg and metal mesh into a suitable shape and size (usually obtained by two-dimensional expansion of the desired three-dimensional preform)
- Step B stacking several layers of prepreg and metal mesh of suitable shape and size as needed to obtain a semi-finished product according to the present invention
- Step C heating the semi-finished product above the melting point of the resin matrix of the prepreg thereof temperature
- Step D The semi-finished product is three-dimensionally formed in a mold (for example, a hot stamping die);
- Step E demolding at a temperature lower than the melting point of the prepreg resin matrix to obtain a three-dimensional preform having a desired three-dimensional shape Body 2;
- Step F After the three-dimensional preform is cooled, it is machined, such as contour finishing, drilling, etc., into a three-dimensional preform 3 having a desired final size and geometric configuration;
- Step G The three-dimensional preform 3 is reheated to above the melting point of the prepreg resin matrix
- the three-dimensional component 4 thus obtained can be, for example, a component on a motor vehicle, such as a rear closure component of a motor vehicle.
- Fig. 9 shows an example of the three-dimensional member, which in this example is a trunk lid closing member 4, consisting of a prepreg three-dimensional preform 3, and a plastic molded resin portion 16, which is formed in a prepreg
- the three-dimensional preform 3 contains a metal layer. Since the metal layer is added between the prepreg layers, in the above steps G and H, the three-dimensional preform can obtain the support of the metal layer, thereby maintaining its three-dimensional shape well.
- the metal constituting the metal layer needs to have a melting point higher than that of the prepreg thermoplastic resin matrix, so that in the step G, the metal layer does not become molten, but can support the molten resin matrix.
- the added metal layer since the added metal layer remains in the finally obtained overmolded product, it can also enhance the mechanical strength of the product and complement it. Function.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Heat Treatment Of Articles (AREA)
- Reinforced Plastic Materials (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/037,343 US20160271901A1 (en) | 2013-11-22 | 2014-11-21 | Semi-finished product manufactured from prepreg, three-dimensional preformed body and overmolded part |
KR1020167016504A KR20160096626A (ko) | 2013-11-22 | 2014-11-21 | 프리프레그로 이루어진 반제품, 3차원 프리폼 및 오버몰드된 부품 |
MX2016006280A MX2016006280A (es) | 2013-11-22 | 2014-11-21 | Semiproducto hecho de preimpregnado, preforma y tridimensional y parte sobremoldeada. |
EP14828052.2A EP3072683B1 (en) | 2013-11-22 | 2014-11-21 | Semi-finished product manufactured from prepreg, three-dimensional preformed body and overmoulded part |
JP2016531996A JP6483682B2 (ja) | 2013-11-22 | 2014-11-21 | プリプレグで作られている半製品、3次元プリフォームおよびオーバーモールド部分 |
Applications Claiming Priority (2)
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CN201320747460.1U CN203864106U (zh) | 2013-11-22 | 2013-11-22 | 预浸料制成的半成品及三维预成型体和包塑成型件 |
CN201320747460.1 | 2013-11-22 |
Publications (1)
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WO2015075683A1 true WO2015075683A1 (zh) | 2015-05-28 |
Family
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PCT/IB2014/066238 WO2015075683A1 (zh) | 2013-11-22 | 2014-11-21 | 预浸料制成的半成品及三维预成型体和包塑成型件 |
Country Status (8)
Country | Link |
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US (1) | US20160271901A1 (zh) |
EP (1) | EP3072683B1 (zh) |
JP (1) | JP6483682B2 (zh) |
KR (1) | KR20160096626A (zh) |
CN (1) | CN203864106U (zh) |
MX (1) | MX2016006280A (zh) |
MY (1) | MY177904A (zh) |
WO (1) | WO2015075683A1 (zh) |
Families Citing this family (9)
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DE102014221165B4 (de) * | 2014-10-17 | 2020-06-18 | Magna Seating (Germany) Gmbh | Verfahren zum Herstellen eines Hybrid-Verbundbauteils aus Organoblechen und einem metallischen Verstärkungselement |
CN105799246B (zh) * | 2016-03-23 | 2018-12-14 | 江苏澳盛复合材料科技有限公司 | 高阻燃低翘曲碳纤维片材及其制备工艺 |
US10921859B2 (en) * | 2017-04-10 | 2021-02-16 | Securaplane Technologies, Inc. | Composite electronics cases and methods of making and using the same |
US11497643B2 (en) | 2017-07-20 | 2022-11-15 | Ossur Iceland Ehf | System for supporting a liner on a frame element |
CN108688729B (zh) * | 2017-11-22 | 2024-01-30 | 王子齐 | 轻量化乘用车承载式车身和车身覆盖件 |
KR102349669B1 (ko) * | 2017-12-28 | 2022-01-12 | 주식회사 성우하이텍 | 섬유 강화 플라스틱의 성형방법 |
DE102018121882A1 (de) * | 2018-09-07 | 2020-03-12 | Auto-Kabel Management Gmbh | Strukturelement für ein Kraftfahrzeug und Verfahren zum Herstellen eines Strukturelements |
JP6583873B1 (ja) * | 2019-05-20 | 2019-10-02 | 株式会社庄内工業 | 樹脂パネルの製造方法 |
JP7144881B1 (ja) * | 2021-09-22 | 2022-09-30 | 株式会社The MOT Company | プレス用積層体及びプレス済積層体 |
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- 2013-11-22 CN CN201320747460.1U patent/CN203864106U/zh not_active Expired - Fee Related
-
2014
- 2014-11-21 MY MYPI2016701690A patent/MY177904A/en unknown
- 2014-11-21 JP JP2016531996A patent/JP6483682B2/ja active Active
- 2014-11-21 MX MX2016006280A patent/MX2016006280A/es unknown
- 2014-11-21 WO PCT/IB2014/066238 patent/WO2015075683A1/zh active Application Filing
- 2014-11-21 US US15/037,343 patent/US20160271901A1/en not_active Abandoned
- 2014-11-21 KR KR1020167016504A patent/KR20160096626A/ko not_active Application Discontinuation
- 2014-11-21 EP EP14828052.2A patent/EP3072683B1/en active Active
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Also Published As
Publication number | Publication date |
---|---|
EP3072683B1 (en) | 2020-11-04 |
JP6483682B2 (ja) | 2019-03-13 |
MX2016006280A (es) | 2016-09-07 |
KR20160096626A (ko) | 2016-08-16 |
CN203864106U (zh) | 2014-10-08 |
MY177904A (en) | 2020-09-24 |
JP2017505244A (ja) | 2017-02-16 |
US20160271901A1 (en) | 2016-09-22 |
EP3072683A1 (en) | 2016-09-28 |
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