WO2015030370A1 - 산화형 염모제 조성물 - Google Patents
산화형 염모제 조성물 Download PDFInfo
- Publication number
- WO2015030370A1 WO2015030370A1 PCT/KR2014/006583 KR2014006583W WO2015030370A1 WO 2015030370 A1 WO2015030370 A1 WO 2015030370A1 KR 2014006583 W KR2014006583 W KR 2014006583W WO 2015030370 A1 WO2015030370 A1 WO 2015030370A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hair dye
- dye composition
- wax
- ester
- triacontanyl
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Definitions
- the present invention relates to an oxidative hair dye composition, and more particularly, to an oxidized hair dye composition in which volatilization of ammonia is suppressed by containing at least one ester having a long carbon number of 30 or more, thereby reducing eye irritation and stimulation. It is about.
- Hair dyeing or bleaching is generally used as a two-part hair dye or a bleaching agent comprising a hair dye which is a dye containing a dye and an alkaline agent and a oxidant which is a second agent containing a hydrogen peroxide solution.
- a hair dye which is a dye containing a dye and an alkaline agent
- a oxidant which is a second agent containing a hydrogen peroxide solution.
- Common hair dyes or bleaching agents often use ammonia as the alkali agent that swells the hair and promotes decomposition of hydrogen peroxide to cause oxidation.
- Ammonia which is a highly volatile alkaline agent, causes an irritating odor of ammonia when the first agent and the second agent are mixed or applied to the hair, causing stimulation and eye irritation.
- ammonia-induced irritation some of the ammonia may be replaced with ethanolamine, tromethamine, arginine, etc. to reduce the amount of use, or ethanolamine, sodium silicate and sodium metasilicate may be used as alkali agents. If the decolorization power is dropped or used in large quantities, the problem remains that scalp stimulation increases.
- the hair dye composition contains one or more esters having a long carbon number of 30 or more
- the hair dye composition can alleviate the stimulation and eye irritation caused by ammonia when the first agent and the second agent are mixed or applied to the hair.
- the present invention was completed.
- the present invention provides an oxidizing hair dye composition containing at least one ester having a long carbon number of 30 or more.
- Oxidative hair dye composition according to the present invention has the effect of suppressing volatilization of ammonia in the formulation to reduce the stimulation and eye irritation that may occur when mixing the first agent and the second agent or when applying the hair dye or bleaching agent.
- the present invention relates to a hair dye composition
- a hair dye composition comprising at least one ester having a long carbon number of 30 or more, characterized in that it is for suppressing ammonia volatilization, or for stimulating irritation and eye irritation.
- the ester used in the present invention consists of a combination of an alcohol having a long carbon chain of 30 or more and a fatty acid.
- the alcohol is an aliphatic alcohol having 30 to 36 carbon atoms, preferably 30 to 34 carbon atoms, and specifically, myricyl alcohol, 1-dotriacontanol, and 1-tetratricontanol ( 1-tetratriacontanol), 1-hexatriacontanol, and the like. If the carbon number is less than 30, the effect of suppressing ammonia volatilization is insignificant, and if it is more than 36, the emulsification is unstable during manufacture, which is not preferable.
- the fatty acid is preferably a fatty acid having 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms, and specifically, may include myristic acid, palmitic acid, stearic acid, and the like. . If the carbon number is less than 10, the effect of suppressing ammonia volatilization is insignificant, and if the carbon number is more than 22, it is not preferable because the emulsification is unstable during manufacturing.
- esters composed of alcohols and fatty acids are specifically triacontanyl palmitate, triacontanyl palmitoleate, triacontanyl myristate, triacontanyl stearate ), Dotriacontanyl palmitate, tetratricontanyl palmitate and the like.
- the ester used in the present invention may substitute the effects of the present invention by using a wax containing the ester as a component.
- the wax is a wax composed of an ester having a carbon number of 30 or more, specifically, beeswax, Chinese wax, shellac wax, lanolin, candela wax, jojoba wax, rice bran oil, Montan wax and the like.
- the hair dye composition according to the present invention may contain the ester at 0.1 to 5% by weight, preferably 0.5 to 3% by weight based on the total weight of the composition.
- the ester content is less than 0.1% by weight, the effect of suppressing ammonia volatilization is insignificant, and when it exceeds 5% by weight, the effect of inhibiting ammonia volatilization is no longer increased, but it is not preferable because it may damage the stability of the formulation.
- the oxidative hair dye composition is an oxidative hair dye composition comprising a first agent hair dye composition comprising an oxidizing dye precursor, a coupler, an alkali agent, a water soluble antioxidant, and a reducing agent and a second agent composition comprising an oxidant.
- the first hair dye composition of the oxidative hair dye composition may be in various forms such as liquid, lotion, cream, gel, and the like, and is not particularly limited in formulation.
- the single agent hair dye composition may contain an oxidized dye precursor and a coupler, which are commonly used in the art, and may preferably contain two or more oxidized dye precursors and a coupler.
- an oxidizing dye precursor o-aminophenol, p-aminophenol, p-phenylenediamine, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenyl sulfate Rendiamine, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate or p-phenylenediamine sulfate, and the like, but are not limited thereto.
- the coupler may be used as long as it can be used in combination with the oxidizing dye precursor to give a variety of color to the hair, for example 2-methyl-5-hydroxyethyl aminophenol, p-amino-o-cre Sol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m-phenylenediamine, ⁇ -naphthol, resorcinol or 2-methylresorcinol can be used.
- the present invention is not limited thereto.
- the first hair dye composition may further add direct dyes that are commonly used within the scope of not impairing the object of the present invention, and such direct dyes include arianol dye, p- Nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine, picramic acid or other vegetable dyes Henna etc. may be used.
- the first hair dye composition may be used in a pH range of 6 to 12, which is neutral to alkaline, and is preferably used under alkaline conditions of pH 8 to 11.
- the pH range is less than 6, it is not easy to decompose the oxidizing agent included in the second agent, widening the cuticle of the hair, and effectively preventing the treatment agent from penetrating into the hair, and when the pH range exceeds 12, the hair This may be due to protein damage or skin irritation.
- an alkali agent component commonly used in hair dyes such as ammonia, monoethanolamine, aminomethylpropanol, isopropanolamine, sodium hydroxide and potassium hydroxide can be used.
- the first hair dye composition contains a water-soluble antioxidant and a reducing agent commonly used in the art, and specifically, the antioxidants include ascorbic acid, erythorbic acid and salts thereof, and the reducing agents include sodium sulfite and pyrothiane. Sodium sulfate, thioglycolic acid, thiolactate, cysteine and salts thereof.
- the component normally used for a hair dye can be used for the 1-dye hair dye composition of this invention within the range which does not impair the effect of this invention.
- antioxidants, metal containment agents, solvents, surfactants, thickeners, fragrances and conditioning agents and the like are used, but are not particularly limited to those that can be commonly used in hair dyes.
- antioxidants examples include butylhydroxyanisole, dibutylhydroxytoluene, tertiary butylhydroquinone, tocopherols, and the like.
- metal blocking agent eddiey (EDTA), disodium idieti, tetrasodium- Ethane, pentasodium pentate, and the like.
- solvent examples include ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol, and the like.
- Anionic surfactants or nonionic surfactants may be used, and as the thickener, higher alcohols having 12 to 22 carbon atoms may be used alone or in combination, polymer thickeners, etc. may be used, and nonionic polymers and anions may be used. Sex polymers, paraffins or hard flow isoparaffins, and the like, and the conditioning agent may be cationic polymers, Quaternary ammonium salts or silicones;
- oxidizing agent contained in the second composition of the oxidizing hair dye composition of the present invention one or more selected from hydrogen peroxide, urea peroxide, alkali metal bromate, ferricyanide, perborate, and persulfate, which are commonly used, may be used. In particular, it is preferable to use hydrogen peroxide.
- the two-component composition can also be used in the range that does not impair the effects of the present invention components commonly used in the art.
- emulsions such as paraffin, light flow isoparaffin higher fatty alcohols, higher fatty acid esters, cationic or nonionic surfactants, stabilizers such as phenacetin, metal blockers such as disodium editie, phosphoric acid, and the like. pH adjusters and the like.
- the 1 agent and the 2 agent composition of the oxidative hair dye composition by this invention contain water normally other than the component mentioned above.
- water it is preferable to use purified water, such as ion-exchange water and distilled water,
- the content is not specifically limited, As long as it is the quantity which can fully melt
- the oxidizing hair dye composition according to the present invention is used by mixing the first agent and the second agent composition immediately before applying to the hair.
- the mixing ratio of the first agent and the second agent composition is generally used by mixing in a weight ratio of 1: 1 to 1: 3, but is not particularly limited to this ratio.
- Examples 1 to 7 and Comparative Examples 1 to 4 were prepared in the composition of Tables 1 to 2 (unit: wt%).
- Triacontanil palmitate, triacontanyl myristate, triacontanyl stearate, dotriacontanyl palmitate, tetratricontanyl palmitate were used as esters, and cetyl palmitate and stearyl palmitate of the present invention. Since it did not meet conditions, it was used as a component of a comparative example.
- wax bead wax and candela wax were used.
- p-phenylenediamine was used as the oxidation dye precursor
- m-aminophenol was used as the coupler
- ammonia water (28%) was used as the alkali
- metal dispersant was used as disodium ethane. (35%) was used.
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Abstract
Description
1제 조성물 | ||||||||||||
성분 | 실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | 비교예 1 | 비교예 2 | 비교예 3 | 비교예 4 | |
1 | 세토스테아릴 알코올 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 |
2 | 미네랄오일 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 |
3 | 폴리옥시에틸렌스테아릴에테르 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 |
4 | 폴리옥시에틸렌세토스테아릴에테르 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 |
5 | 트리아콘타닐 팔미테이트 | 1 | - | - | - | - | - | - | - | - | - | 6 |
6 | 트리아콘타닐 미리스테이트 | - | 1 | - | - | - | - | - | - | - | - | - |
7 | 트리아콘타닐 스테아레이트 | - | - | 1 | - | - | - | - | - | - | - | - |
8 | 도트리아콘타닐 팔미테이트 | - | - | - | 1 | - | - | - | - | - | - | - |
9 | 테트라트리아콘타닐 팔미테이트 | - | - | - | - | 1 | - | - | - | - | - | - |
10 | 비즈왁스 | - | - | - | - | - | 1 | - | - | - | - | - |
11 | 칸델리라왁스 | - | - | - | - | - | - | 1 | - | - | - | - |
12 | 세틸 팔미테이트 | - | - | - | - | - | - | - | 1 | - | - | - |
13 | 스테아릴 팔미테이트 | - | - | - | - | - | - | - | - | 1 | - | - |
14 | p-페닐렌디아민 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 |
15 | m-아미노페놀 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
16 | 암모니아수(28%) | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 | 14.45 |
17 | 디소듐이디티에이 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
18 | 에리소르빈산 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
19 | 소듐설파이트 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
20 | 레조시놀 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 | 1.3 |
21 | 모노에탄올아민 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 |
22 | 조합향료 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
23 | 정제수 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 |
2제 조성물 | ||
성분 | 함량 | |
1 | 세테아릴알코올 | 3.5 |
2 | 미네랄오일 | 1.0 |
3 | 경질유동이소파리핀 | 1.5 |
4 | 폴리옥시에틸렌라우릴에테르 | 0.5 |
5 | 폴리옥시에틸렌스테아릴에테르 | 1.5 |
6 | 페나세틴 | 0.03 |
7 | 디소듐이디티에이 | 0.2 |
8 | 인산 | 0.16 |
9 | 과산화수소수(35%) | 17 |
10 | 정제수 | 잔량 |
평가항목 | 실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | 비교예 1 | 비교예 2 | 비교예 3 | 비교예 4 |
취강도 | 4.2 | 4.9 | 4.3 | 4.4 | 6.3 | 3.9 | 6.3 | 10 | 9 | 10 | 5.1 |
평가항목 | 실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | 비교예 1 | 비교예 2 | 비교예 3 | 비교예 4 |
NH3 (%) | 0.52 | 0.60 | 0.55 | 0.55 | 0.70 | 0.55 | 0.75 | 0.97 | 0.93 | 1.0 | 0.60 |
Claims (7)
- 30 이상의 탄소수를 갖는 에스테르를 1종 이상 함유하는 염모제 조성물.
- 제1항에 있어서, 상기 에스테르는 알코올과 지방산의 결합으로 이루어지며,상기 알코올은 탄소수가 30~45의 지방족 알코올이며,상기 지방산은 탄소수 10~22의 지방산인 것을 특징으로 하는 염모제 조성물.
- 제1항에 있어서, 상기 에스테르는 트리아콘타닐 팔미테이트(triacontanyl palmitate), 트리아콘타닐 팔미트올리에이트(triacontanyl palmitoleate), 트리아콘타닐 미리스테이트(triacontanyl myristate), 트리아콘타닐 스테아레이트(triacontanyl stearate) 및 도트리아콘타닐 팔미테이트(dotriacontanyl palmitate)로 이루어진 군에서 선택된 1종 이상인 것을 특징으로 하는 염모제 조성물.
- 제1항에 있어서,상기 에스테르는 조성물 총 중량에 대하여 0.1∼5중량%로 함유되는 것을 특징으로 하는 염모제 조성물.
- 제1항에 있어서,상기 조성물은 암모니아의 휘발을 억제하여 안자극과 취자극 감소를 특징으로 하는 염모제 조성물.
- 제1항에 있어서, 30 이상의 탄소수를 갖는 에스테르를 구성성분으로 함유하는 왁스를 더 포함하는 염모제 조성물.
- 제6항에 있어서, 상기 왁스는 비즈왁스, 차이니즈왁스, 셀락왁스(shellac wax), 라놀린, 칸델리라왁스, 호호바왁스, 라이스 브랜 오일(rice bran oil) 및 몬탄왁스(montan wax)로 이루어진 군에서 선택된 1종 이상인 것을 특징으로 하는 염모제 조성물.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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AU2014312620A AU2014312620B2 (en) | 2013-08-26 | 2014-07-21 | Oxidative hair dye composition |
CN201480030612.3A CN105392467A (zh) | 2013-08-26 | 2014-07-21 | 氧化性染发剂组合物 |
HK16110124.0A HK1221907A1 (zh) | 2013-08-26 | 2016-08-25 | 氧化性染發劑組合物 |
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KR1020130100852A KR102108499B1 (ko) | 2013-08-26 | 2013-08-26 | 산화형 염모제 조성물 |
KR10-2013-0100852 | 2013-08-26 |
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WO2015030370A1 true WO2015030370A1 (ko) | 2015-03-05 |
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CN (1) | CN105392467A (ko) |
AU (1) | AU2014312620B2 (ko) |
HK (1) | HK1221907A1 (ko) |
TW (1) | TWI635872B (ko) |
WO (1) | WO2015030370A1 (ko) |
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KR101679334B1 (ko) * | 2016-09-02 | 2016-11-24 | 이재일 | 암모니아 처방으로 인한 모발손상과 두피자극 최소화 및 암모니아 냄새 극소화 효과가 있는 염모 조성물 및 그의 제조방법 |
CN111278409B (zh) * | 2017-10-27 | 2023-01-06 | 株式会社爱茉莉太平洋 | 染发剂组合物 |
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JP3947756B2 (ja) * | 2005-11-11 | 2007-07-25 | ホーユー株式会社 | 酸化染毛剤組成物 |
JP3936960B1 (ja) * | 2006-06-02 | 2007-06-27 | 株式会社ダリヤ | 染毛剤組成物 |
US8545821B2 (en) * | 2009-11-05 | 2013-10-01 | Avon Products, Inc. | Cosmetic use of water-redispersible powders |
CN102871894A (zh) * | 2011-07-15 | 2013-01-16 | 赵强 | 一种无刺激染发剂 |
-
2013
- 2013-08-26 KR KR1020130100852A patent/KR102108499B1/ko active IP Right Grant
-
2014
- 2014-07-21 WO PCT/KR2014/006583 patent/WO2015030370A1/ko active Application Filing
- 2014-07-21 AU AU2014312620A patent/AU2014312620B2/en active Active
- 2014-07-21 CN CN201480030612.3A patent/CN105392467A/zh active Pending
- 2014-07-29 TW TW103125768A patent/TWI635872B/zh active
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2016
- 2016-08-25 HK HK16110124.0A patent/HK1221907A1/zh unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100754122B1 (ko) * | 2006-02-28 | 2007-08-30 | 주식회사 엘지생활건강 | 산화염색용 염모제 조성물 |
JP2012512856A (ja) * | 2008-12-19 | 2012-06-07 | ロレアル | 少なくとも1種の固体脂肪アルコールを含む組成物、それを用いる染色または明色化方法およびデバイス |
KR20120018107A (ko) * | 2009-06-01 | 2012-02-29 | 호유 가부시키가이샤 | 모발 화장료 조성물 |
WO2012095398A2 (en) * | 2011-01-10 | 2012-07-19 | L'oreal | Dyeing or lightening process using a composition rich in fatty substances comprising a solid alcohol and a solid ester, compositions and device |
KR20130084244A (ko) * | 2012-01-16 | 2013-07-24 | 가부시키가이샤 미르본 | 산화 염모제용 제1 제 |
Also Published As
Publication number | Publication date |
---|---|
HK1221907A1 (zh) | 2017-06-16 |
AU2014312620A1 (en) | 2015-12-10 |
AU2014312620B2 (en) | 2019-10-31 |
CN105392467A (zh) | 2016-03-09 |
KR20150024000A (ko) | 2015-03-06 |
TWI635872B (zh) | 2018-09-21 |
KR102108499B1 (ko) | 2020-05-08 |
TW201536339A (zh) | 2015-10-01 |
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