WO2015029878A1 - Composition aqueuse de vernis de surimpression durcissable par rayonnement uv - Google Patents

Composition aqueuse de vernis de surimpression durcissable par rayonnement uv Download PDF

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Publication number
WO2015029878A1
WO2015029878A1 PCT/JP2014/071906 JP2014071906W WO2015029878A1 WO 2015029878 A1 WO2015029878 A1 WO 2015029878A1 JP 2014071906 W JP2014071906 W JP 2014071906W WO 2015029878 A1 WO2015029878 A1 WO 2015029878A1
Authority
WO
WIPO (PCT)
Prior art keywords
overprint varnish
ultraviolet curable
varnish composition
aqueous
water
Prior art date
Application number
PCT/JP2014/071906
Other languages
English (en)
Japanese (ja)
Inventor
健作 小林
吉厚 関野
高橋　雅人
Original Assignee
Ｄｉｃグラフィックス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ｄｉｃグラフィックス株式会社 filed Critical Ｄｉｃグラフィックス株式会社
Priority to CN201480004955.2A priority Critical patent/CN105051132B/zh
Priority to JP2014560153A priority patent/JP5712338B1/ja
Publication of WO2015029878A1 publication Critical patent/WO2015029878A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate

Definitions

  • the present invention relates to an aqueous ultraviolet curable overprint varnish composition that is applied to the surface of a printed material such as paper and imparts a soft hand feeling such as velvet or suede to the surface.
  • the present invention relates to an aqueous ultraviolet curable overprint varnish composition suitable for coating with an offset in-line coater.
  • Patent Document 1 a suede-like finish paint having no color fading and excellent stain resistance has been studied.
  • Patent Document 2 a urethane resin composition for coating excellent in surface characteristics such as waterproofness, soft touch feeling, and slipperiness has been studied (for example, Patent Document 2).
  • Patent Document 3 an invention of a water-dispersible coating composition containing a water-based acrylic resin, which includes urethane beads as a matting agent and can obtain a suede-like finish has been made (for example, Patent Document 3).
  • an aqueous coating agent containing styrene / acrylic resin and polyethylene wax has been found to have an excellent matting effect and anti-slip effect (for example, Patent Document 4).
  • an aqueous coating agent composition (for example, Patent Document 5) in which urethane resin beads are fixed using a styrene / acrylic resin as a binder has been studied in order to impart a similar touch feeling.
  • a later heat drying type there is a limit to the fixing force and fixing force of the urethane resin beads, the urethane resin beads are easily detached by friction, and the friction resistance is not sufficient.
  • the moist and soft hand touch evaluation method of the varnish application surface is limited to sensory evaluation by touching with a hand or a finger, and numerical evaluation of surface properties and the like has not been made.
  • the present invention is an aqueous UV curable offset in-line coating varnish that retains the moist soft touch feeling of velvet or suede tone that solves the above problems by making it an UV curable type.
  • a moist and smooth feel can be expressed.
  • An object of the present invention is to provide an aqueous ultraviolet curable overprint varnish composition that retains a soft velvet-like or suede-like soft hand feeling on a substrate such as a printed matter.
  • an aqueous ultraviolet curable overprint varnish composition characterized in that the rate of increase of the dynamic friction coefficient when increased from / s to 20 mm / s is 10% or more.
  • the coated product using the overprint varnish composition of the present invention can form a high-quality film with a soft, velvet or suede-like moist feel on the coated surface.
  • the overprint varnish of the present invention contains a urethane resin, an ultraviolet curable monomer having water-soluble (meth) acrylate as essential components, and water.
  • overprint varnish processing mainly with an offset inline machine
  • a pattern is printed with UV ink, cured with an intermediate cylinder, coated with the overprint varnish of the present invention with a varnish coater cylinder, and again irradiated with UV and dried. ⁇ Curing.
  • the moisture of the overprint varnish of the present invention evaporates with the help of the lamp heat, and the UV curable monomer becomes a strong binder for fixing the blended urethane resin beads by UV light, and is fixed to the original fabric.
  • urethane resin beads or those obtained by dispersing beads in an aqueous solvent also referred to as a dispersion, including urethane resin dispersion, aliphatic polyurethane dispersion, etc.
  • a dispersion also referred to as a dispersion, including urethane resin dispersion, aliphatic polyurethane dispersion, etc.
  • Tg glass transition point
  • the glass transition point (Tg) confirmed in the present invention was measured by using [DSC822e] manufactured by METTLER TOLEDO, and after putting about 7 mg of a measurement object into an aluminum pan in a nitrogen atmosphere and press-sealing and sealing, It is obtained from the inflection point of the heat flow curve when the range of + 150 ° C. is scanned at a heating rate of 10 ° C./min.
  • the average particle diameter of the urethane beads is preferably in the range of 0.1 to 10 ⁇ m, more preferably 0.8 to 6 ⁇ m.
  • the particle size is small, there is a tendency that a soft hand feeling is difficult to be produced, and when the particle size is large, there are various problems such as poor friction resistance, product stability (sedimentation), and coating unevenness.
  • a water-soluble (meth) acrylate may be contained.
  • water-soluble (meth) acrylates include hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, polyethylene glycol (meth) acrylate, methoxypolyethylene glycol (meth) acrylate, N- (2-hydroxyethyl) acrylamide (abbreviation: HEAA), N- (2-hydroxyethyl) methacrylamide, N- (2-hydroxymethyl) acrylamide, N- (2-hydroxymethyl) methacrylamide, acryloylmorpholine, methylolacrylamide Dimethylacrylamide, methoxymethylacrylamide, diethylacrylamide, isopropylacrylamide, polyethylene glycol di (meth) acrylate, etc. But it is, not to be limited to these.
  • the ratio between the urethane resin part and the ultraviolet curable monomer part containing water-soluble (meth) acrylate as an essential component is urethane resin part: UV curable in terms of nonvolatile content.
  • the ratio shown here makes the physical properties moderately compatible.
  • the water blended and contained is 1 to 65% by weight, preferably 25 to 60% by weight, and more preferably 40 to 60% by weight. Water evaporates from the coated surface, leaving the urethane resin part and the UV curable monomer part, that is, when the water content increases to some extent, the urethane beads are easily exposed from the binder of the dry coating film. Will be buried. However, when an extremely large amount of water is contained, the binder becomes too small and problems such as poor urethane bead fixing are likely to occur. Therefore, the optimum value is within the above range.
  • the dynamic friction coefficient with respect to the rubbing speed with the coated surface is controlled, thereby controlling the specific measuring speed.
  • the inventor has found that a coated surface that retains a soft velvet-like or suede-like soft feel in the numerical range of the dynamic friction coefficient can be obtained. That is, the dynamic friction coefficient at a high test speed is increased compared to the dynamic friction coefficient at a low test speed, the dynamic friction coefficient is 0.1 to 0.7, and the measurement speed is increased from 2 mm / s to 20 mm / s.
  • the effect of the present invention is achieved when the rate of increase in the dynamic friction coefficient when increased is 10% or more.
  • a water-insoluble polyfunctional (meth) acrylate may be added. If all UV-curable monomers are composed of water-soluble (meth) acrylate, the resulting coating will be less resistant to blocking, such as poor blocking resistance, and combined with water-insoluble polyfunctional (meth) acrylate. These can be supplemented.
  • water-insoluble polyfunctional (meth) acrylate that can be used in the present invention include polypropylene glycol di (meth) acrylate, hexanediol di (meth) acrylate, nonanediol di (meth) acrylate, and bisphenol A di (meth).
  • TMPTA trimethylolpropane tri (meth) acrylate
  • pentaerythritol tri (meth) acrylate pentaerythritol tetra (meth) acrylate
  • ditrimethylolpropane tetra (meth) acrylate polypropylene Polyglycol, hexanediol, nonanediol, bisphenol A, bisphenol F, trimethylolpropane, pentaerythritol, ditrimethylolpropane, etc.
  • EO alkylene oxide
  • the amount added is less than 0% relative to the total amount of the aqueous ultraviolet curable overprint varnish composition of the present invention because the coated surface is hardly damaged. It is preferably 5% by weight or more, and preferably 10.0% by weight or less, more preferably 5.0% by weight or less, because soft touch feeling such as velvet tone or suede tone is good. It is preferably 0.5% by weight or more and 15% by weight or less in terms of solid content excluding water, more preferably 0.5% by weight or more and 8% by weight or less in terms of solid content.
  • the aqueous ultraviolet curable overprint varnish composition of the present invention needs to be added with a photopolymerization initiator or a sensitizer in order to be cured with ultraviolet rays.
  • photopolymerization initiators and sensitizers include 2,2-dimethoxy-1,2-diphenylethane-1-one, 1-hydroxy-cyclohexyl-phenyl-ketone, 2-hydroxy-2-methyl-1 -Phenyl-propan-1-one, benzophenone, 1- [4- (2-hydroxyethoxy) -phenyl] -2-hydroxy-2-methyl-propan-1-one, 2-methyl-1- [4- ( Methylthio) phenyl] -2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butanone-1, bis (2,6-dimethoxybenzoyl) -2, 4,4-trimethyl-pentylphosphine oxide, bis (2,4,6-trimethylbenzoyl) -phenylphosphine oxide, 2,4,6 Trimethylbenzoyldiphenylphosphine oxide, benzyldimethyl ketal
  • photopolymerization initiators and sensitizers should be added within a range of 1 to 15% and 1 to 20% in terms of solid content with respect to the UV curable monomer part in the aqueous UV curable overprint varnish composition. Is preferred.
  • the printing substrate that is the target of the aqueous ultraviolet curable overprint varnish composition of the present invention.
  • paper such as fine paper, coated paper, art paper, imitation paper, thin paper, and cardboard, polyester resin , Acrylic resin, vinyl chloride resin, vinylidene chloride resin, polyvinyl alcohol, polyethylene, polypropylene, polyacrylonitrile, ethylene vinyl acetate copolymer, ethylene vinyl alcohol copolymer, ethylene methacrylic acid copolymer, nylon, polylactic acid, polycarbonate, etc.
  • the environment in which the aqueous ultraviolet curable overprint varnish composition of the present invention can be used is any of an offset inline coater, an offline coater, a flexographic printing method, and a gravure printing method that can be applied to a printed material by a coater unit provided in an offset printing machine. This printing method can also be used.
  • a water-based ultraviolet curable overprint varnish composition that can be used for the above-mentioned original fabric, and a laminate comprising a printing ink layer and an overprint coating composition film formed on each of the above-mentioned original fabrics. is there.
  • Example varnish-1 Preparation of aqueous UV curable overprint varnish (Example varnish-1)> 27.0 parts of an aqueous aliphatic polyurethane dispersion having a glass transition point (Tg) of ⁇ 80 ° C. and an average particle size of 1.5 ⁇ m, 54.0 parts of water, N- (2-hydroxyethyl) acrylamide (HEAA) 17.5 1 part, 0.5 parts of trimethylolpropane triacrylate (TMPTA) is mixed, stirred and dispersed using a mixer, and 2-hydroxy-2-methyl-1-phenyl-propane- as a photopolymerization initiator.
  • Example Varnish-1 was prepared by adding 1.0 part of 1-one (DAROCUR 1173, manufactured by BASF) and completely dissolving it.
  • Example Varnishes 2 to 5 ⁇ Preparation of (Example Varnishes 2 to 5) and (Comparative Example Varnishes 1 to 6)>
  • the raw materials were mixed in the formulations shown in Tables 1 and 2, stirred and dispersed using a mixer, and completely dissolved in the photopolymerization initiator, and prepared in the same manner as in Example Varnish-1.
  • Laminates for use in the evaluation test were prepared by the following procedures using the aqueous ultraviolet curable overprint varnishes (Example varnishes 1 to 5) and (Comparative Example varnishes 1 to 6) prepared as described above.
  • ⁇ Production of evaluation laminate> (1) Board paper (UF coated paper 270 g / m 2 , manufactured by Oji Paper Co., Ltd.) was used as the substrate.
  • (2) “Dicure Avirio Process Ink N” (manufactured by DIC Graphics Co., Ltd.), which is an ultraviolet curable offset ink, was developed on this base material using an RI tester. A two-segment roller was used as a color developing rubber roll.
  • the amount of the ultraviolet curable ink was developed by applying 0.150 ml of ink to a rubber roller so that the amount of the ink was 1 to 2 g / m 2 on the substrate. (3) After the ultraviolet curable offset ink is developed by irradiating the substrate with ultraviolet rays and cured, an overprint varnish composition to be immediately evaluated is applied with a bar coater # 6 and irradiated with ultraviolet rays. (4) The resulting laminate is left at room temperature for 24 hours. (5) Check the coefficient of dynamic friction and feel the hand.
  • ⁇ Evaluation method> (Lamination body evaluation method 1: measurement of dynamic friction coefficient)
  • the measurement of the dynamic friction coefficient conforms to ASTM D1894-90 (test conditions for measuring the friction coefficient of plastic films and sheets when sliding on the same material or other materials), and uses a device manufactured by Stable MicroSystems. And measured.
  • the contact surface was 63.5 mm ⁇ 63.5 mm
  • the load was 200 g
  • the surface was felt at the standard equipment
  • the pulling speed was 2 mm / s and 20 mm / s.
  • the calculation method of the rate of increase in the dynamic friction coefficient was 100 ⁇ (dynamic friction coefficient at 20 mm / s ⁇ 2 mm / s dynamic friction coefficient) / 2 mm / hour.
  • an average particle diameter measuring method it computed from the condition of the frequency distribution measured using the Hitachi operation
  • Table 1 shows the compositions of the aqueous ultraviolet curable overprint varnishes of Examples 1 to 5 and Table 2 of Comparative Examples 1 to 6, and the evaluation results.
  • Raw material A Solid content of aliphatic polyurethane dispersion containing urethane resin having an average particle size of about 1.5 ⁇ m
  • B Water raw material C: N- (2-hydroxyethyl) acrylamide (HEAA)
  • Raw material D trimethylolpropane triacrylate (TMPTA)
  • Raw material E 2-hydroxy-2-methyl-1-phenyl-propan-1-one (DAROCUR1173, manufactured by BASF)
  • Comparative Example 1 containing no polyurethane dispersion and in Comparative Examples 2 to 4 in which the weight ratio of urethane resin part / ultraviolet curable monomer part was less than 0.5, the measurement speed was increased from 2 mm / s to 20 mm / s. The rate of increase in the coefficient of dynamic friction is 0 to less than 10%, and all 10 people do not feel “moist soft touch”, or only about 2 people feel “moist soft touch” No results.
  • Comparative Example 5 in which water-insoluble trifunctional acrylate (TMPTA) was used instead of water-soluble (meth) acrylate (HEAA), gelation proceeded due to poor compatibility, and application measurement was not achieved.
  • Example 6 in which the weight ratio of urethane resin part / ultraviolet curable monomer part exceeded 2.0, uneven coating and poor scratch resistance occurred due to a large amount of precipitation of urethane beads, and measurement was not possible.
  • the printed matter using the aqueous UV curable overprint varnish composition of the present invention is a sanitary / cosmetic / pharmaceutical / audio electrical appliance in addition to publications such as posters, pamphlets, etc., book covers such as book covers with design characteristics added. It can be widely used for packaging and packaging applications.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paper (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

Le problème à résoudre par la présente invention est de fournir une composition aqueuse de vernis de surimpression durcissable par rayonnement UV qui conserve une texture agréablement douce de type velours ou suédine sur un matériau de base tel qu'un matériau imprimé. La solution proposée par l'invention consiste en une composition aqueuse de vernis de surimpression durcissable par rayonnement UV qui contient une résine uréthane, un monomère durcissable par rayonnement UV contenant un (méth)acrylate hydrosoluble en tant que constituant principal, et de l'eau, la composition étant caractérisée en ce que le rapport massique résine uréthane/monomère durcissable par rayonnement UV va de 1/2 à 2/1, le coefficient de frottement dynamique d'une surface revêtue séchée va de 0,1 à 0,7 après application de la composition aqueuse de vernis de surimpression durcissable par rayonnement UV, et en ce que si la vitesse de mesure est augmentée de 2 mm/s à 20 mm/s, l'accroissement en pourcentage du coefficient de frottement dynamique est supérieur ou égal à 10 %.
PCT/JP2014/071906 2013-08-30 2014-08-21 Composition aqueuse de vernis de surimpression durcissable par rayonnement uv WO2015029878A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201480004955.2A CN105051132B (zh) 2013-08-30 2014-08-21 水性紫外线固化型罩印清漆组合物
JP2014560153A JP5712338B1 (ja) 2013-08-30 2014-08-21 水性紫外線硬化型オーバープリントワニス組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013-179540 2013-08-30
JP2013179540 2013-08-30

Publications (1)

Publication Number Publication Date
WO2015029878A1 true WO2015029878A1 (fr) 2015-03-05

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JP (1) JP5712338B1 (fr)
CN (1) CN105051132B (fr)
WO (1) WO2015029878A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180163086A1 (en) * 2015-06-03 2018-06-14 Sun Chemical Corporation Primer for digital printing
WO2022209932A1 (fr) * 2021-03-30 2022-10-06 Ｄｉｃグラフィックス株式会社 Stratifié ayant une couche d'impression d'encre liquide à base d'eau

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63273668A (ja) * 1987-04-30 1988-11-10 Dainippon Printing Co Ltd 親水性膜形成組成物及びその親水性膜並びにその製造方法
WO2007139157A1 (fr) * 2006-05-31 2007-12-06 Nippon Shokubai Co., Ltd. Acrylamide ou méthacrylamide multivalent et formule aqueuse de résine durcissable le contenant
JP2009511703A (ja) * 2005-10-10 2009-03-19 エスエスシーピー・カンパニー・リミテッド 低粘度の多官能ウレタンアクリレートオリゴマーを含むｕｖ硬化性ハイソリッド塗料組成物
JP2009227707A (ja) * 2008-03-19 2009-10-08 Dic Corp 水性コーティング剤組成物
JP2010270223A (ja) * 2009-05-21 2010-12-02 Mitsubishi Chemicals Corp 活性エネルギー線硬化性水性樹脂組成物、それを含有してなる塗料、インク、及び積層体
JP2013185001A (ja) * 2012-03-06 2013-09-19 Dic Graphics Corp 水性紫外線硬化性コーティングニス組成物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4132195B2 (ja) * 1998-03-27 2008-08-13 凸版印刷株式会社 活性エネルギー線硬化型オーバープリントニス組成物および印刷物
US7923482B2 (en) * 2005-03-08 2011-04-12 Dic Corporation Ultraviolet-curable resin composition, ultraviolet-curable coating and coated article
CN102676036B (zh) * 2012-05-22 2014-12-03 东莞市英科水墨有限公司 一种水性哑光触感光油及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63273668A (ja) * 1987-04-30 1988-11-10 Dainippon Printing Co Ltd 親水性膜形成組成物及びその親水性膜並びにその製造方法
JP2009511703A (ja) * 2005-10-10 2009-03-19 エスエスシーピー・カンパニー・リミテッド 低粘度の多官能ウレタンアクリレートオリゴマーを含むｕｖ硬化性ハイソリッド塗料組成物
WO2007139157A1 (fr) * 2006-05-31 2007-12-06 Nippon Shokubai Co., Ltd. Acrylamide ou méthacrylamide multivalent et formule aqueuse de résine durcissable le contenant
JP2009227707A (ja) * 2008-03-19 2009-10-08 Dic Corp 水性コーティング剤組成物
JP2010270223A (ja) * 2009-05-21 2010-12-02 Mitsubishi Chemicals Corp 活性エネルギー線硬化性水性樹脂組成物、それを含有してなる塗料、インク、及び積層体
JP2013185001A (ja) * 2012-03-06 2013-09-19 Dic Graphics Corp 水性紫外線硬化性コーティングニス組成物

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180163086A1 (en) * 2015-06-03 2018-06-14 Sun Chemical Corporation Primer for digital printing
US10851262B2 (en) * 2015-06-03 2020-12-01 Sun Chemical Corporation Primer for digital printing
WO2022209932A1 (fr) * 2021-03-30 2022-10-06 Ｄｉｃグラフィックス株式会社 Stratifié ayant une couche d'impression d'encre liquide à base d'eau
JP7195494B1 (ja) * 2021-03-30 2022-12-23 Ｄｉｃグラフィックス株式会社 水性リキッドインキの印刷層を有する積層体

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CN105051132A (zh) 2015-11-11
JP5712338B1 (ja) 2015-05-07
CN105051132B (zh) 2016-11-16
JPWO2015029878A1 (ja) 2017-03-02

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