WO2015013961A1 - 一种会呼吸的全粒面仿皮的生产方法 - Google Patents

一种会呼吸的全粒面仿皮的生产方法 Download PDF

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WO2015013961A1
WO2015013961A1 PCT/CN2013/080651 CN2013080651W WO2015013961A1 WO 2015013961 A1 WO2015013961 A1 WO 2015013961A1 CN 2013080651 W CN2013080651 W CN 2013080651W WO 2015013961 A1 WO2015013961 A1 WO 2015013961A1
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fabric
coating
embossing
imitation leather
drying
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PCT/CN2013/080651
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English (en)
French (fr)
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沈明荣
唐族平
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浙江皮意纺织有限公司
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Priority to PCT/CN2013/080651 priority Critical patent/WO2015013961A1/zh
Priority to CN201380024398.6A priority patent/CN104271824B/zh
Publication of WO2015013961A1 publication Critical patent/WO2015013961A1/zh

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0013—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using multilayer webs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/105—Resistant to abrasion, scratch
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable

Definitions

  • the invention relates to a method for producing leather-like skin, in particular to a method for producing full-grained imitation leather which can breathe.
  • the common artificial leather fabric is realized by the process of direct coating or transfer coating, which has the luster of the leather, and the hand feels thick and elastic, but the direct coating is affected by the texture of the fabric, and the difference between the appearance and the leather is large.
  • the transfer coating product solves this problem, and its appearance is very similar to that of the leather.
  • the raw material release paper needs to be imported, and the cost is high.
  • the release coating process of the release paper uses a continuous coating process to make the coating too regular and causes the gas permeability problem of the product; and at present, the production of the transfer coating has a certain influence on the environment, and the requirements for environmental protection facilities are also high.
  • the transfer coating artificial leather fabric can be used for clothing and home textiles, there is always a drawback of being suffocating and airtight, and the fabric is not durable due to the action of the additive.
  • the technical problem to be solved by the present invention is to provide a method for producing a full-grained imitation leather which can be breathed, and the produced leather-like fabric has good air permeability, good texture and wear resistance.
  • the technical solution adopted by the present invention to solve the technical problem is: a production method of full-grained imitation leather which can breathe, including a material selection, coating, embossing, surface treatment, water washing and drying step, wherein
  • Washing and drying firstly washing with water, then smashing the fabric under the action of hot air to make the surface shrink freely, and drying in a continuous manner at 100 ° C.
  • the density of the printing anilox roller is between 70 mesh and 45 mesh, and the mesh number is controlled during plate making; after multiple transfer printing, the surface of the composite fabric still exists.
  • the raw material is a composite fabric in which two layers of knitted brushed fabric are composited by using an ultrafine fiber warp knitted fabric as a fabric.
  • the invention has the beneficial effects that the production method is simple, and the produced leather-like fabric has good air permeability, good texture and wear resistance.
  • Figure 1 is a flow chart showing the process of two transfer printing in the coating step of the embodiment of the present invention.
  • 1 carrier 1 carrier, 2 first transfer printing, 3 used carriers, 4 second transfer printing, 5 belt temperature rollers, 6 finished products, 7 Warp knitted microfiber fleece material
  • a method for producing a full-grained imitation leather that can breathe including material selection, coating, embossing, surface treatment, drying steps,
  • Material selection composite fabric with superfine fiber warp knitted fabric as composite fabric and composite two-layer knitted brushed fabric, combined with two-component polyurethane glue, can provide sufficient bonding strength of the product;
  • the polyurethane resin is first printed on the carrier, then transferred from the carrier to the surface of the warp, and the process is repeated twice, and different carriers are used (as shown in Figure 1); It can print polyurethane slurry, and it will not be solidified. It will be separated during transfer.
  • This carrier is called release film (paper), and the second transfer printing uses carrier printing technology, so the transfer material
  • the surface has a printed pattern;
  • the density of the printing anilox roller is 60 mesh, and the mesh number is controlled in the plate making; after the secondary transfer printing, there are still small holes with a diameter of 3 ⁇ m on the cloth surface;

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明提供了一种会呼吸的全粒面仿皮的生产方法，包括选料、涂层、压花、表面处理、水洗烘干步骤，其中，（1）选料：采用以超细纤维经编织物为面料、针织拉绒布为底料的复合织物为原料；（2）涂层：采用转移印刷技术，先将聚氨脂树脂印刷在载体上，然后由载体转移到经编织物表面，并重复此过程两次以上且每次使用不同的载体；（3）压花：在经涂层的织物表面用带温度的辊筒压花，所述辊筒表面有连续的皮纹纹路；（4）表面处理：在经压花的织物表面印涂丙烯酸树脂与聚氨酯的混合物；（5）水洗烘干：先水洗，然后在热空气作用下揉搓织物，使表面产生自由收缩，并采用连续式在100℃平幅烘干。本发明生产的仿皮面料透气性好、质感佳，且耐磨。

Description

一种会呼吸的全粒面仿皮的生产方法 技术领域
本发明涉及一种仿皮的生产方法，具体涉及一种会呼吸的全粒面仿皮的生产方法。
背景技术
目前，常见的仿真皮面料采用直接涂层或转移涂层的工艺实现，使其具有真皮的光泽，手感厚实而有弹性，但直接涂层受织物织纹的影响，其外观与真皮差距较大，而转移涂层产品解决了这个问题，其外观与真皮十分相似，但由于其生产工艺有一定局限性，原料离型纸需要进口，成本较高。而且离型纸转移涂层使用连续涂工艺，使涂层过于规则化而造成产品存在透气性问题；且目前转移涂层生产中对环境有一定影响，对环保设施要求也很高。虽然转移涂层仿真皮面料可以用于服装和家纺，但始终存在着发闷不透气的弊病，且由于添加剂的作用使面料不耐用。
技术问题
本发明所要解决的技术问题是提供一种会呼吸的全粒面仿皮的生产方法，生产的仿皮面料透气性好、质感佳，且耐磨。
技术解决方案
本发明解决技术问题所采用的技术方案是：一种会呼吸的全粒面仿皮的生产方法，包括选料、涂层、压花、表面处理、水洗烘干步骤，其中，
（1）选料：采用以超细纤维经编织物为面料、针织拉绒布为底料的复合织物为原料；
（2）涂层：采用转移印刷技术，先将聚氨脂树脂印刷在载体上，然后由载体转移到经编织物表面，并重复此过程两次以上且每次使用不同的载体；
（3）压花：在经涂层的织物表面用带温度的辊筒压花，所述辊筒表面有连续的皮纹纹路；
（4）表面处理：在经压花的织物表面印涂丙烯酸树脂与聚氨酯的混合物；
（5）水洗烘干：先水洗，然后在热空气作用下揉搓织物，使表面产生自由收缩，并采用连续式在100℃平幅烘干。
作为一种优选，所述涂层步骤（2）中，采用印刷网纹辊的密度在70目～45目之间，目数在制版时控制；经多次转移印刷后，复合织物表面仍存在直径2µm～5µm的小孔。
作为一种优选，所述原料为以超细纤维经编织物为面料复合两层针织拉绒布的复合织物。
 有益效果
本发明的有益效果是：生产方法简单，且生产的仿皮面料透气性好、质感佳，且耐磨。
附图说明
图1为本发明实施例涂层步骤中两次转移印刷的工艺流程图。
其中，1载体、2第一次转移印刷、3用过的载体、4第二次转移印刷、5带温度的辊筒、 6完成的产品、7 经编超细纤维起绒布原料
 本发明的最佳实施方式
一种会呼吸的全粒面仿皮的生产方法，包括选料、涂层、压花、表面处理、烘干步骤，
（1）选料：采用以超细纤维经编织物为面料，复合两层针织拉绒布的复合织物，复合用双组份聚氨脂胶水，能提供产品足够的贴合强度；
（2）涂层：
a 、采用转移印刷技术，先将聚氨脂树脂印刷在载体上，然后由载体转移到经编织物表面，并重复二次这个过程，且使用不同的载体（如附图1所示）；载体必须能承印聚氨脂浆料，同时它不会将其牢固化，在转移时被分离，这种载体被称为离型膜（纸），第二次转移印刷使用了载体印花技术，所以转移物表面拥有印花图案；
b 、涂层时采用印刷网纹辊的密度为60目，目数在制版中控制；经二次转移印刷后，布面仍存在直径3µm的小孔；
（3）压花：涂层后采用油加热辊筒压花，油加热辊筒表面温度100℃；
（4）表面处理：在已压花的仿皮产品表面印涂丙烯酸树脂与聚氨酯的混合物，达到光滑等皮感；
（5）水洗烘干：经水处理后在适当热空气作用下揉搓整个布面，使面料产生自由收缩，并连续式低温100℃平幅烘干，保持产品风格，并为产品增加平滑感。

Claims (3)

  1. 一种会呼吸的全粒面仿皮的生产方法，包括选料、涂层、压花、表面处理、水洗烘干步骤，其特征在于：
    （1）选料：采用以超细纤维经编织物为面料、针织拉绒布为底料的复合织物为原料；
    （2）涂层：采用转移印刷技术，先将聚氨脂树脂印刷在载体上，然后由载体转移到经编织物表面，并重复此过程两次以上且每次使用不同的载体；
    （3）压花：在经涂层的织物表面用带温度的辊筒压花，所述辊筒表面有连续的皮纹纹路；
    （4）表面处理：在经压花的织物表面印涂丙烯酸树脂与聚氨酯的混合物；
    （5）水洗烘干：先水洗，然后在热空气作用下揉搓织物，使表面产生自由收缩，并采用连续式在100℃平幅烘干。
  2. 根据权利要求1所述的会呼吸的全粒面仿皮的生产方法，其特征在于：所述涂层步骤（2）中，采用印刷网纹辊的密度在70目～45目之间，目数在制版时控制；经多次转移印刷后，复合织物表面仍存在直径2µm～5µm的小孔。
  3. 根据权利要求1所述的会呼吸的全粒面仿皮的生产方法，其特征在于：所述原料为以超细纤维经编织物为面料复合两层针织拉绒布的复合织物。
PCT/CN2013/080651 2013-08-01 2013-08-01 一种会呼吸的全粒面仿皮的生产方法 WO2015013961A1 (zh)

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CN106963175A (zh) * 2017-05-04 2017-07-21 浙江皮意纺织有限公司 一种坐垫
CN107351515A (zh) * 2017-07-16 2017-11-17 无锡金双面料科技有限公司 一种新型pu革植绒复合工艺

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