WO2014182294A1 - Procédé d'alkylation de composés aromatiques - Google Patents

Procédé d'alkylation de composés aromatiques Download PDF

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Publication number
WO2014182294A1
WO2014182294A1 PCT/US2013/040082 US2013040082W WO2014182294A1 WO 2014182294 A1 WO2014182294 A1 WO 2014182294A1 US 2013040082 W US2013040082 W US 2013040082W WO 2014182294 A1 WO2014182294 A1 WO 2014182294A1
Authority
WO
WIPO (PCT)
Prior art keywords
aromatic hydrocarbon
feedstock
aromatic
alkylation
transalkylation
Prior art date
Application number
PCT/US2013/040082
Other languages
English (en)
Inventor
Shyh-Yuan H. Hwang
Dana E. Johnson
Original Assignee
Badger Licensing Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Badger Licensing Llc filed Critical Badger Licensing Llc
Priority to CN201380076372.6A priority Critical patent/CN105339328B/zh
Priority to RU2015148012A priority patent/RU2640595C2/ru
Priority to PCT/US2013/040082 priority patent/WO2014182294A1/fr
Priority to TW103114026A priority patent/TWI654165B/zh
Publication of WO2014182294A1 publication Critical patent/WO2014182294A1/fr
Priority to RU2017145651A priority patent/RU2756570C2/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dans un procédé d'alkylation de composés aromatiques, une zone de déshydratation est alimentée en une charge d'alimentation d'hydrocarbures aromatiques comprenant un hydrocarbure aromatique pouvant être alkylé, au moins 150 ppm en poids d'eau et au moins une impureté azotée organique, l'eau étant éliminée de la charge d'alimentation d'hydrocarbures aromatiques pour fournir une charge d'alimentation de composés aromatiques déshydratés ayant une teneur en eau inférieure ou égale à 20 ppm en poids. La charge d'alimentation de composés aromatiques déshydratés est ensuite mise en contact avec un adsorbant argile dans des conditions comprenant une température inférieure à 130 °C de sorte que l'adsorbant élimine au moins une partie de l'impureté azotée organique contenue dans la charge d'alimentation et produise une charge d'alimentation aromatique traitée. Une zone de réaction d'alkylation et/ou une zone de réaction de transalkylation sont ensuite alimentées en charge d'alimentation aromatique traitée.
PCT/US2013/040082 2013-05-08 2013-05-08 Procédé d'alkylation de composés aromatiques WO2014182294A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201380076372.6A CN105339328B (zh) 2013-05-08 2013-05-08 芳烃烷基化方法
RU2015148012A RU2640595C2 (ru) 2013-05-08 2013-05-08 Способ алкилирования ароматических соединений
PCT/US2013/040082 WO2014182294A1 (fr) 2013-05-08 2013-05-08 Procédé d'alkylation de composés aromatiques
TW103114026A TWI654165B (zh) 2013-05-08 2014-04-17 芳族物的烷基化方法
RU2017145651A RU2756570C2 (ru) 2013-05-08 2017-12-25 Способ алкилирования ароматических соединений

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2013/040082 WO2014182294A1 (fr) 2013-05-08 2013-05-08 Procédé d'alkylation de composés aromatiques

Publications (1)

Publication Number Publication Date
WO2014182294A1 true WO2014182294A1 (fr) 2014-11-13

Family

ID=48483218

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/040082 WO2014182294A1 (fr) 2013-05-08 2013-05-08 Procédé d'alkylation de composés aromatiques

Country Status (4)

Country Link
CN (1) CN105339328B (fr)
RU (2) RU2640595C2 (fr)
TW (1) TWI654165B (fr)
WO (1) WO2014182294A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018140149A1 (fr) * 2017-01-25 2018-08-02 Exxonmobil Chemical Patents Inc. Procédé de transalkylation et composition catalytique utilisée dans celui-ci
WO2018183009A1 (fr) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Compositions de catalyseur et leur utilisation dans des processus d'alkylation aromatique
WO2018183012A1 (fr) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Procédés d'élimination d'impuretés d'un flux d'hydrocarbures et leur utilisation dans des processus d'alkylation aromatique
TWI665184B (zh) * 2017-01-25 2019-07-11 美商艾克頌美孚化學專利股份有限公司 轉烷基化製程及用於此之觸媒組成物
KR20190095465A (ko) * 2017-01-25 2019-08-14 엑손모빌 케미칼 패턴츠 인코포레이티드 트랜스알킬화 방법 및 이에 사용되는 촉매 조성물
RU2763741C2 (ru) * 2017-03-29 2021-12-30 Эксонмобил Кемикэл Пейтентс Инк. Каталитические композиции и их применение в способах алкилирования ароматических соединений
US11230515B2 (en) 2017-03-29 2022-01-25 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
CN115261064A (zh) * 2022-08-08 2022-11-01 内蒙古伊泰煤基新材料研究院有限公司 一种费托轻质油制烷基芳烃的原料预处理系统及方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915568A (zh) * 2016-10-08 2018-04-17 中国石油化工股份有限公司 生产烷基化芳族化合物的方法
CN107915566A (zh) * 2016-10-08 2018-04-17 中国石油化工股份有限公司 生产烷基化芳族化合物的装置
TWI665012B (zh) * 2017-03-29 2019-07-11 美商艾克頌美孚化學專利股份有限公司 自烴流移除雜質之方法及其於芳族烷基化製程之用途
CN114426451A (zh) * 2020-09-24 2022-05-03 中国石油化工股份有限公司 一种多取代异丙苯烷基转移制备异丙苯的方法及其所得异丙苯

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USRE28341E (en) 1964-05-01 1975-02-18 Marshall dann
US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3293192A (en) 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
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US4016245A (en) 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
USRE29948E (en) 1973-11-02 1979-03-27 Mobil Oil Corporation Crystalline silicates and catalytic conversion of organic compounds therewith
US3923636A (en) 1974-06-03 1975-12-02 Texaco Inc Production of lubricating oils
US3972983A (en) 1974-11-25 1976-08-03 Mobil Oil Corporation Crystalline zeolite ZSM-20 and method of preparing same
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US8013199B2 (en) 2003-03-24 2011-09-06 Exxonmobil Chemical Patents Inc. Feed pretreating
US6894201B1 (en) 2003-12-19 2005-05-17 Uop Llc Process and apparatus for the removal of nitrogen compounds from a fluid stream
US20090036722A1 (en) * 2007-07-30 2009-02-05 Clark Michael C Alkylaromatics production

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2753341C2 (ru) * 2017-01-25 2021-08-13 Эксонмобил Кемикэл Пейтентс Инк. Способ трансалкилирования и применяющаяся в нем каталитическая композиция
TWI665184B (zh) * 2017-01-25 2019-07-11 美商艾克頌美孚化學專利股份有限公司 轉烷基化製程及用於此之觸媒組成物
KR20190095465A (ko) * 2017-01-25 2019-08-14 엑손모빌 케미칼 패턴츠 인코포레이티드 트랜스알킬화 방법 및 이에 사용되는 촉매 조성물
TWI690509B (zh) * 2017-01-25 2020-04-11 美商艾克頌美孚化學專利股份有限公司 轉烷基化製程及用於此之觸媒組成物
WO2018140149A1 (fr) * 2017-01-25 2018-08-02 Exxonmobil Chemical Patents Inc. Procédé de transalkylation et composition catalytique utilisée dans celui-ci
KR102315640B1 (ko) 2017-01-25 2021-10-21 엑손모빌 케미칼 패턴츠 인코포레이티드 트랜스알킬화 방법 및 이에 사용되는 촉매 조성물
WO2018183009A1 (fr) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Compositions de catalyseur et leur utilisation dans des processus d'alkylation aromatique
WO2018183012A1 (fr) * 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Procédés d'élimination d'impuretés d'un flux d'hydrocarbures et leur utilisation dans des processus d'alkylation aromatique
RU2763741C2 (ru) * 2017-03-29 2021-12-30 Эксонмобил Кемикэл Пейтентс Инк. Каталитические композиции и их применение в способах алкилирования ароматических соединений
US11230515B2 (en) 2017-03-29 2022-01-25 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
US11951463B2 (en) 2017-03-29 2024-04-09 ExxonMobil Engineering & Technology Company Catalyst compositions and their use in aromatic alkylation processes
CN115261064A (zh) * 2022-08-08 2022-11-01 内蒙古伊泰煤基新材料研究院有限公司 一种费托轻质油制烷基芳烃的原料预处理系统及方法
CN115261064B (zh) * 2022-08-08 2023-11-21 内蒙古伊泰煤基新材料研究院有限公司 一种费托轻质油制烷基芳烃的原料预处理系统及方法

Also Published As

Publication number Publication date
RU2017145651A3 (fr) 2021-03-17
TW201509877A (zh) 2015-03-16
CN105339328B (zh) 2020-08-25
TWI654165B (zh) 2019-03-21
CN105339328A (zh) 2016-02-17
RU2756570C2 (ru) 2021-10-01
RU2017145651A (ru) 2019-06-25
RU2640595C2 (ru) 2018-01-10
RU2015148012A (ru) 2017-06-14

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