WO2014171238A1 - ポンプフォーマー用洗浄剤組成物 - Google Patents
ポンプフォーマー用洗浄剤組成物 Download PDFInfo
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- WO2014171238A1 WO2014171238A1 PCT/JP2014/056841 JP2014056841W WO2014171238A1 WO 2014171238 A1 WO2014171238 A1 WO 2014171238A1 JP 2014056841 W JP2014056841 W JP 2014056841W WO 2014171238 A1 WO2014171238 A1 WO 2014171238A1
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- WIPO (PCT)
- Prior art keywords
- mass
- acid
- fatty acid
- composition
- propylene glycol
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2048—Dihydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Definitions
- the present invention relates to a cleaning composition that is housed in a non-gas type foam discharge container having a porous film such as a pump former, and is discharged in the form of foam through the porous film at the time of use. More specifically, the present invention relates to a cleaning composition for a pump former that has excellent foaming properties and foam quality, and also has excellent washability.
- a liquid detergent composition that is contained in a non-gas type foam discharge container such as a pump former and discharged from the container in a foam state when used is known.
- This type of cleaning composition is mixed with air and discharged in the form of bubbles when passing through the porous membrane provided in the container.
- this type of cleaning composition prevents creamy foam and clogging of the porous membrane.
- Various attempts have been made to achieve this.
- Patent Document 1 includes (a) an acyltaurine salt having a short chain length, (b) an amphoteric surfactant, and (c) a cationized starch. It is described that a creamy foam quality can be stably obtained and a conditioning effect can be obtained. However, the detergent composition of Patent Document 1 does not contain a higher fatty acid salt as an anionic surfactant.
- a surfactant of at least 5% by mass, preferably 8% by mass or more has been conventionally added in order to obtain a fine and creamy foam.
- a long chain higher fatty acid salt having more than 12 carbon atoms is blended, there is a problem that precipitation occurs at low temperatures.
- a higher fatty acid salt is an alkanolamine salt and is combined with a polyoxyethylene alkyl phosphate ester salt, 1 to 7% by weight monohydric alcohol, and 3 to 20% by weight polyhydric alcohol.
- Patent Document 3 discloses compounds in which the number of carbon atoms of an alkyl group in a higher fatty acid salt is adjusted to a specific ratio, an amphoteric or semipolar surfactant and an acid dissociation constant of 8.0 to 11.0 (specifically, monoethanol A detergent composition in combination with an amine compound such as an amine is described, and even if the pH of the detergent composition decreases with time, the occurrence of precipitates can be suppressed and clogging of the pump former container can be prevented. Has been.
- JP 2009-292969 A Japanese Patent Laid-Open No. 5-132700 Japanese Patent No. 5071687
- the present invention provides a cleaning composition for a pump former that is not only excellent in foam quality and low-temperature stability, but also can be easily washed out with a small amount of water in view of the current state of the prior art as described above. For the purpose.
- the present inventors have conducted intensive research. As a result, most of the ionic surfactants occupied by higher fatty acid soaps are suppressed, and polyhydric alcohols containing propylene glycol are used. In order to complete the present invention, it has been found that by blending a predetermined amount, it is possible to obtain a detergent composition having a dense foam quality, not only causing clogging even at low temperatures, but also having excellent washability. It came.
- the present invention (A) 2 to 5% by weight of an ionic surfactant, and (B) 20 to 60% by weight of a polyhydric alcohol containing propylene glycol, A cleaning composition discharged by a pump former, A higher fatty acid soap having 5 to 25 carbon atoms occupies 90% by mass or more of the (a) ionic surfactant, and the amount of propylene glycol contained in the (b) polyhydric alcohol is 20 with respect to the whole composition.
- a cleaning composition characterized by being less than mass%.
- the cleaning composition of the present invention has a dense foam quality, excellent low-temperature stability, and has excellent flushing properties that can be easily washed away with a small amount of water.
- the ionic surfactant used in the present invention is composed of one or more selected from anionic surfactants, cationic surfactants, and amphoteric surfactants.
- anionic surfactants include fatty acid soaps, N-acyl glutamates, carboxylate types such as alkyl ether acetic acids, sulfonic acid types such as ⁇ -olefin sulfonates, alkane sulfonates, and alkylbenzene sulfonic acids, and higher alcohols.
- examples thereof include sulfate ester salt types such as sulfate ester salts and phosphate ester salt types.
- the detergent composition of the present invention is characterized in that, among the anionic surfactants, the higher fatty acid soap accounts for 90% by mass or more of the ionic surfactant (component a).
- the higher fatty acid soap is a hydrocarbon composed of a salt of a higher fatty acid anion and a counter cation in which a carboxyl group is bonded to a linear or branched, saturated or unsaturated monovalent hydrocarbon group having about 5 to 25 carbon atoms. A part of the group may be optionally substituted with a hydroxyl group or the like.
- fatty acids constituting higher fatty soaps include caproic acid, heptanoic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, caproleic acid, undecylenic acid, lauroleic acid, 2-ethylbutanoic acid, isopentanoic acid 2-ethylpentanoic acid, 2-ethylhexanoic acid, isononanoic acid, 3,5,5-trimethylhexanoic acid, tridecanoic acid, tetramethylnonanoic acid, myristic acid, pentadecanoic acid, palmitic acid, stearic acid, arachidic acid, behen Acid, lignoceric acid, serotic acid, myristic acid, palmitoleic acid, oleic acid, elaidic acid, gondoic acid, erucic acid, ceracoleic acid, linoleic acid, l
- lauric acid it is preferable to use one type selected from lauric acid, myristic acid, and palmitic acid, or a combination of two or three types.
- lauric acid myristic acid, and palmitic acid
- the counter cation for neutralizing the higher fatty acid anion is not particularly limited, but is preferably an alkali metal cation, particularly a potassium cation.
- cationic surfactant examples include aliphatic amine salts, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridinium salts, imidazolinium salts, and the like.
- Amphoteric surfactants include carbobetaine amphoteric surfactants such as alkylbetaines and alkylamidobetaines, sulfobetaine amphoteric surfactants such as alkylsulfobetaines and alkylhydroxysulfobetaines, phosphobetaine amphoteric surfactants, imidazolines. Examples include amphoteric surfactants and amide amino acid salts. Examples of alkylbetaines include lauryldimethylaminoacetic acid betaine. Examples of the alkylamide betaine include coconut oil fatty acid amidopropyl betaine. Examples of the alkylsulfobetaine include coconut oil fatty acid dimethylsulfopropylbetaine.
- alkylhydroxysulfobetaine examples include lauryldimethylaminohydroxysulfobetaine.
- examples of the phosphobetaine amphoteric surfactant examples include lauryl hydroxyphosphobetaine.
- Examples of the imidazoline type amphoteric surfactant include coconut oil alkyl-N-hydroxyethyl imidazolinium betaine.
- the blending amount of the ionic surfactant (component a) in the cleaning composition of the present invention is 2 to 5% by mass.
- the blending amount is less than 2% by mass, sufficient foaming properties cannot be obtained, and when the blending amount exceeds 5% by mass, the washing-off property becomes insufficient.
- it can also be set as 4.5 mass% or 4.0 mass%, for example.
- the blending amount of the ionic surfactant is suppressed as compared with the conventional cleaning agent for pump former, and the proportion of the higher fatty acid soap is more than the predetermined value (90% by mass). By doing so, it was possible to remarkably improve the washability while maintaining good foam quality.
- the polyhydric alcohol blended in the cleaning composition of the present invention can be selected from those usually blended in cosmetics and the like, and is not particularly limited.
- glycerin, propylene glycol examples include dipropylene glycol, 1,3-butylene glycol, ethylene glycol, sorbitol and the like.
- blending propylene glycol is preferable because low temperature stability is improved, and the polyhydric alcohol in the present invention contains propylene glycol as an essential component.
- the upper limit of the blending amount of propylene glycol is less than 20% by mass, preferably less than 15% by mass, more preferably less than 12% by mass with respect to the entire composition.
- the lower limit of the amount of propylene glycol is not particularly limited, but is preferably 1% by mass or more, more preferably 3% by mass or more, more preferably 5% by mass or more, based on the entire composition. is there. Moreover, since the foam quality produced
- the blending amount of the polyhydric alcohol (component b) in the cleaning composition of the present invention is 20 to 60% by mass, preferably 25 to 55% by mass, more preferably 30 to 50% by mass.
- the blending amount is less than 20% by mass, the porous film of the pump former may be clogged.
- the blending amount exceeds 60% by mass, the foam quality tends to decrease.
- the detergent composition of the present invention can further improve low-temperature stability by blending a small amount of a nonionic surfactant.
- a nonionic surfactant particularly effective in the present invention include coconut oil fatty acid diethanolamide (1: 1 type; 1: 2 type), polyglyceryl-4 lauryl ether and the like.
- the blending amount is 3% by mass or less, preferably 1% by mass or less, more preferably 0.8% by mass or less.
- components that can be blended are not particularly limited as long as they are usually used in liquid detergent compositions. Specific examples include oils, silicones, lower or higher alcohols, lanolin derivatives, protein derivatives, various drugs, bactericides, preservatives, pH adjusters, antioxidants, sequestering agents, chelating agents, UV absorption Agents, animal and plant extracts or derivatives thereof, pigments, fragrances, pigments, organic or inorganic powders, clay minerals and the like. These 1 type (s) or 2 or more types can be selected arbitrarily and can be mix
- the amount of oil to be blended is preferably reduced from the viewpoint of emulsion stability.
- the amount of oil in the cleaning agent of the present invention is preferably less than 1% by mass, more preferably less than 0.8% by mass, and even more preferably less than about 0.5% by mass. .
- the cleaning composition of the present invention is not limited, but is provided as a low-viscosity liquid having a viscosity of 30 mPa ⁇ s or less, preferably about 10 mPa ⁇ s, as measured with a Brookfield type rotational viscometer at a temperature of 0 to 50 ° C., for example. Is done.
- the cleaning composition of the present invention can be produced according to a usual method using the above-described essential components and optional components.
- the prepared cleaning composition of the present invention is accommodated in a non-gas type foam discharge container having a porous film.
- the non-gas type foam discharge container used in the present invention is of any known type as long as a certain amount of liquid detergent composition is mixed with a certain amount of air and discharged from the container at the time of use as a foam state. But you can. Specifically, for example, a squeeze foamer that is used by pressing the torso of a soft container with fingers, a pump former that is used by pressing the head of a cap equipped with a pump mechanism with fingers, and the like. .
- the liquid detergent composition in the container is discharged from the container discharge port as a foam by passing a mixture obtained by mixing the liquid detergent composition with air through the porous membrane (one to a plurality of sheets). It is like that.
- porous film of the pump former container examples include a sponge, a sintered body, and a net, but a thin net is preferable from the viewpoint of usability.
- a coarseness of about 30 to 400 mesh is preferably used.
- the cleaning composition of the present invention is suitably used as a cleaning agent for hair and skin contained in a pump former container for facial cleansing, body soap, hand soap, shampoo and the like.
- a detergent was prepared according to a conventional method with the composition described in each example of the following table. About the cleaning agent obtained in each case, the following items were evaluated according to the following criteria. (1) Low-temperature stability Carbon dioxide was forcibly blown into the prepared cleaning composition so that the pH was lowered over time during actual use (pH 9.5). The detergent composition is filled into a vial made of hard glass and stored for one month in an evaluation room maintained at each temperature ( ⁇ 5 to 20 ° C.), and then the low temperature stability of the detergent composition is visually observed. Observed and evaluated according to the following evaluation criteria.
- Example 1 containing 20 to 60% by mass of alcohol have sufficient foaming properties, excellent foam quality and low-temperature stability, and have good washout properties.
- Example 1 containing coconut oil fatty acid diethanolamide exhibits good stability even at a low temperature of 0 ° C. or lower, and has a characteristic that it can sufficiently withstand winter use in cold regions, for example.
- Comparative Example 1 in which the blending amount of the ionic surfactant (higher fatty acid soap) exceeds 5% by mass, the foamability / foam quality is sufficient, but the washout property is inferior and the low-temperature stability is also insufficient. It was shown that.
Abstract
Description
(a)2~5質量%のイオン性界面活性剤、及び、
(b)20~60質量%の、プロピレングリコールを含む多価アルコールを含み、
ポンプフォーマーで吐出される洗浄剤組成物であって、
前記(a)イオン性界面活性剤の90質量%以上を炭素数が5~25の高級脂肪酸石鹸が占め、前記(b)多価アルコールに含まれるプロピレングリコールの量が組成物全体に対して20質量%未満であることを特徴とする洗浄剤組成物を提供する。
(a)イオン性界面活性剤
本発明で使用されるイオン性界面活性剤は、アニオン性界面活性剤、カチオン性界面活性剤、及び両性界面活性剤から選択される1種又は2種以上からなる。
アニオン性界面活性剤としては、脂肪酸石鹸、N-アシルグルタミン酸塩、アルキルエーテル酢酸等のカルボン酸塩型、α-オレフィンスルホン酸塩、アルカンスルホン酸塩、アルキルベンゼンスルホン酸等のスルホン酸型、高級アルコール硫酸エステル塩等の硫酸エステル塩型、リン酸エステル塩型等が挙げられる。
高級脂肪酸石鹸は、炭素数およそ5~25の直鎖状又は分岐鎖状の飽和又は不飽和の一価炭化水素基にカルボキシル基が結合した高級脂肪酸アニオンと対カチオンとの塩からなり、炭化水素基は任意に一部が水酸基等で置換されていてもよい。
アルキルベタインとしては、ラウリルジメチルアミノ酢酸ベタイン等が挙げられる。アルキルアミドベタインとしては、ヤシ油脂肪酸アミドプロピルベタイン等が挙げられる。アルキルスルホベタインとしては、ヤシ油脂肪酸ジメチルスルホプロピルベタイン等が挙げられる。アルキルヒドロキシスルホベタインとしては、ラウリルジメチルアミノヒドロキシスルホベタイン等が挙げられる。ホスホベタイン型両性界面活性剤としては、ラウリルヒドロキシホスホベタイン等が挙げられる。イミダゾリン型両性界面活性剤としては、ヤシ油アルキル-N-ヒドロキシエチルイミダゾリニウムベタイン等が挙げられる。
本発明の洗浄剤組成物に配合される多価アルコールは、化粧料等に通常配合されるものから選択することができ、特に限定されないが、例えば、グリセリン、プロピレングリコール、ジプロピレングリコール、1,3-ブチレングリコール、エチレングリコール、ソルビトール等が挙げられる。
上記の多価アルコールの中でも、プロピレングリコールを配合すると低温安定性が向上するので好ましく、本発明における多価アルコールはプロピレングリコールを必須成分として含有している。ただし、プロピレングリコールの配合量の上限は組成物全体に対して20質量%未満、好ましくは15質量%未満、より好ましくは12質量%未満とする。一方、プロピレングリコールの配合量の下限は特に限定されるものではないが、好ましくは組成物全体に対して1質量%以上であり、さらに好ましくは3質量%以上、より好ましくは5質量%以上である。また、ソルビトールを配合すると生成される泡質が向上するので好ましい。
非イオン性界面活性剤を配合する場合、その配合量は3質量%以下、好ましくは1質量%以下、より好ましくは0.8質量%以下とする。
例えば、本発明の洗浄剤は、限られた量の非イオン性界面活性剤しか含んでいないため、乳化安定性の観点から、配合する油分量は少なくするのが好ましい。特に限定されるものではないが、本発明の洗浄剤における油分の配合量は、好ましくは1質量%未満、より好ましくは0.8質量%未満、さらに好ましくは0.5質量%未満程度である。
なお、以下の実施例等における配合量は特記しない限り質量%である。
各例で得られた洗浄剤について、以下の項目について下記の基準に従って評価した。
(1)低温安定性
調製した洗浄剤組成物に二酸化炭素を強制的に吹き込み、実使用中に経時でpHが低下した状態(pH9.5)にした。この洗浄剤組成物を硬質ガラスのバイアルビンに充填し、各温度(-5~20℃)に保持された評価室において1か月保存させた後、洗浄剤組成物の低温安定性を目視で観察し、下記評価基準で評価した。
○:良好(析出物、沈殿物がなく、外観の変化がない。)
△:実用上良好(若干の外観変化(析出物、沈殿物)があるが実用上問題ない。)
×:不良(析出物、沈殿物があり、品質上問題がある。)
10名の専門パネルにより、各例の洗浄剤をポンプフォーマー容器(メッシュ200×305)に収容し、泡状に吐出させてから実使用して、起泡性、泡質、洗い流し性などの項目について以下の基準に従って評価した。各項目について、専門パネルの評価点の合計によって下記の4段階に分類した。評価結果が◎又は○であるものは、商品として提供するのに十分な特性を備えていると言える。
[評価点基準]
5点:非常に優れている
4点:優れている
3点:普通
2点:劣る
1点:非常に劣る
[評価結果]
◎:合計点が40点以上
○:合計点が30~39点
△:合計点が20~29点
×:合計点が19点以下
調製した洗浄剤組成物を200×305メッシュの多孔質膜を備えたポンプフォーマー容器に充填し数回吐出した後、50℃恒温槽内で1週間乾燥させた。その後、再度吐出したときにメッシュの目詰まりが生じるか否かを評価した(N=5)。
[評価結果]
○:5例中1つの目詰まりも生じなかった。
×:5例中1つ以上に目詰まりが生じた。
一方、多価アルコールが10質量%のプロピレングリコールを含んでいる場合、各項目について満足のできる結果が得られるが、特に多価アルコールとしてソルビトールを配合した場合には泡質が更に向上し、モチモチした感触の良好な泡が得られた(表2)。
それに対してイオン性界面活性剤(高級脂肪酸石鹸)の配合量が5質量%を超える比較例1では、起泡性/泡質は十分であるが、洗い流し性に劣り、低温安定性も不十分であることが示された。
イオン交換水 残余
グリセリン 15
プロピレングリコール 10
ジプロピレングリコール 5
1,3-ブチレングリコール 2
ソルビトール 15
ラウリン酸 1
ミリスチン酸 1
パルミチン酸 0.2
苛性カリ 0.55
ココイルメチルタウリンNa 0.1
ラウリルベタイン 0.1
ヤシ油脂肪酸ジエタノールアミド(1:1型) 0.45
EDTA-3Na 2H2O 0.02
フェノキシエタノール 0.2
Claims (3)
- (a)2~5質量%のイオン性界面活性剤、及び、
(b)20~60質量%の、プロピレングリコールを含む多価アルコールを含み、
ポンプフォーマーで吐出される洗浄剤組成物であって、
前記(a)イオン性界面活性剤の90質量%以上を炭素数が5~25の高級脂肪酸石鹸が占め、前記(b)多価アルコールに含まれるプロピレングリコールの量が組成物全体に対して20質量%未満であることを特徴とする、洗浄剤組成物。 - 前記多価アルコールがソルビトールを含む、請求項1に記載の組成物。
- ヤシ油脂肪酸ジエタノールアミドを更に含む、請求項1又は2に記載の組成物。
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KR1020157026229A KR101630221B1 (ko) | 2013-04-18 | 2014-03-14 | 펌프 포머용 세정제 조성물 |
CN201480021940.7A CN105142606B (zh) | 2013-04-18 | 2014-03-14 | 泵起泡器用清洗剂组合物 |
US14/785,035 US9758746B2 (en) | 2013-04-18 | 2014-03-14 | Cleansing composition for pump foamer comprising soap and propylene glycol |
HK16100282.9A HK1212233A1 (en) | 2013-04-18 | 2016-01-12 | Cleansing composition for pump foamer |
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JP2013087195A JP5373216B1 (ja) | 2013-04-18 | 2013-04-18 | ポンプフォーマー用洗浄剤組成物 |
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JP (1) | JP5373216B1 (ja) |
KR (1) | KR101630221B1 (ja) |
CN (1) | CN105142606B (ja) |
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JP6565363B2 (ja) * | 2015-06-18 | 2019-08-28 | 日油株式会社 | ポンプフォーマー用洗浄剤組成物 |
JP6619960B2 (ja) * | 2015-06-30 | 2019-12-11 | 花王株式会社 | 泡吐出容器入り液体洗浄剤組成物 |
JP6178382B2 (ja) * | 2015-11-12 | 2017-08-09 | 株式会社 資生堂 | ポンプフォーマー用洗浄剤組成物 |
US11678662B2 (en) | 2017-09-15 | 2023-06-20 | Gojo Industries, Inc. | Antimicrobial composition |
KR20230124096A (ko) | 2017-12-26 | 2023-08-24 | 카오카부시키가이샤 | 피부 세정제 조성물 |
KR102028590B1 (ko) * | 2018-03-29 | 2019-10-04 | 황병철 | 식기세척기용 친환경 고성능 세제 조성물 및 세제 |
AU2020376962A1 (en) | 2019-11-01 | 2022-04-07 | Rita Corporation | Substantially anhydrous, concentrated surfactant compositions |
CN115813788A (zh) * | 2022-12-26 | 2023-03-21 | 福建片仔癀化妆品有限公司 | 一种温和自防腐且泡沫绵密的洁面泡泡液及其制备方法 |
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CN105142606A (zh) | 2015-12-09 |
KR20150115021A (ko) | 2015-10-13 |
CN105142606B (zh) | 2017-05-03 |
US20160075974A1 (en) | 2016-03-17 |
TWI525191B (zh) | 2016-03-11 |
JP2014210720A (ja) | 2014-11-13 |
KR101630221B1 (ko) | 2016-06-14 |
JP5373216B1 (ja) | 2013-12-18 |
US9758746B2 (en) | 2017-09-12 |
TW201504425A (zh) | 2015-02-01 |
HK1212233A1 (en) | 2016-06-10 |
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