WO2014079142A8 - 一种复合氧化物、其制造方法及其应用 - Google Patents

一种复合氧化物、其制造方法及其应用 Download PDF

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Publication number
WO2014079142A8
WO2014079142A8 PCT/CN2013/001217 CN2013001217W WO2014079142A8 WO 2014079142 A8 WO2014079142 A8 WO 2014079142A8 CN 2013001217 W CN2013001217 W CN 2013001217W WO 2014079142 A8 WO2014079142 A8 WO 2014079142A8
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Prior art keywords
composite oxide
preparation
application
same
oxidation catalyst
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PCT/CN2013/001217
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English (en)
French (fr)
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WO2014079142A1 (zh
Inventor
张舒冬
金英杰
倪向前
李�杰
张喜文
张信伟
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中国石油化工股份有限公司
中国石油化工股份有限公司抚顺石油化工研究院
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Application filed by 中国石油化工股份有限公司, 中国石油化工股份有限公司抚顺石油化工研究院 filed Critical 中国石油化工股份有限公司
Priority to EP13857060.1A priority Critical patent/EP2915582B1/en
Priority to PL13857060T priority patent/PL2915582T3/pl
Priority to KR1020157014527A priority patent/KR101880623B1/ko
Priority to US14/440,096 priority patent/US9314776B2/en
Publication of WO2014079142A1 publication Critical patent/WO2014079142A1/zh
Publication of WO2014079142A8 publication Critical patent/WO2014079142A8/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/0201—Impregnation
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

本发明涉及一种复合氧化物、其制造方法及其作为甲烷选择性氧化催化剂的应用。该复合氧化物的组成用式RhRxMoyVzOδ-α表示，其中各符号的说明同说明书。在作为甲烷选择性氧化催化剂使用时，该复合氧化物表现出甲烷转化率和目标产物选择性高的特点。
PCT/CN2013/001217 2012-11-01 2013-10-10 一种复合氧化物、其制造方法及其应用 WO2014079142A1 (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP13857060.1A EP2915582B1 (en) 2012-11-01 2013-10-10 Composite oxide, preparation method for same, and application thereof
PL13857060T PL2915582T3 (pl) 2012-11-01 2013-10-10 Złożony tlenek, sposób jego wytwarzania i jego zastosowanie
KR1020157014527A KR101880623B1 (ko) 2012-11-01 2013-10-10 복합 산화물, 그의 제조 방법 및 그의 용도
US14/440,096 US9314776B2 (en) 2012-11-01 2013-10-10 Composite oxide, preparation method for same, and application thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201210427642.0 2012-11-01
CN201210427646 2012-11-01
CN201210427646.9 2012-11-01
CN201210427642 2012-11-01

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WO2014079142A1 WO2014079142A1 (zh) 2014-05-30
WO2014079142A8 true WO2014079142A8 (zh) 2015-05-28

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US (1) US9314776B2 (zh)
EP (1) EP2915582B1 (zh)
KR (1) KR101880623B1 (zh)
CN (1) CN103801327B (zh)
PL (1) PL2915582T3 (zh)
TW (1) TWI605030B (zh)
WO (1) WO2014079142A1 (zh)

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CN106552618A (zh) * 2015-09-25 2017-04-05 上海华谊能源化工有限公司 一种芳香族羧酸酯类苯环选择性加氢的催化剂及其制备方法和应用
CN106596224B (zh) * 2016-12-14 2019-02-19 中国石油大学(华东) 两步法制备天然气水合物岩样的实验装置及方法
CN109731571B (zh) * 2019-02-26 2020-07-10 武汉大学 一种用于高选择催化甲烷转化为乙醇的催化剂及其制备方法和用途
WO2022004778A1 (ja) * 2020-06-30 2022-01-06 国立研究開発法人科学技術振興機構 アルカンの部分酸化方法
CN114477298B (zh) * 2020-10-27 2024-02-09 中国石油化工股份有限公司 一种复合氧化物及其制备方法和应用

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FR2628101B1 (fr) * 1988-03-03 1990-07-20 Rhone Poulenc Chimie Procede d'oxydation catalytique d'alcanes en melanges d'alcools et de cetones
US5220080A (en) * 1992-06-29 1993-06-15 Sun Company, Inc. (R&M) Chromia on metal oxide catalysts for the oxidation of methane to methanol
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KR100343550B1 (ko) * 1999-11-26 2002-07-20 한국화학연구원 희박농도의 메탄 산화촉매 및 그 제조방법
US20050107252A1 (en) * 2003-11-17 2005-05-19 Gaffney Anne M. Process for preparing mixed metal oxide catalyst
KR20050112375A (ko) * 2004-05-25 2005-11-30 주식회사 엘지화학 저온형 연료전지용 백금-로듐 합금 양극 촉매
CN101146753A (zh) * 2005-02-24 2008-03-19 罗伊·A·佩里亚纳 用于将烃转化成官能化产物的新型催化体系
CN101239310B (zh) * 2007-02-09 2010-05-19 中国石油化工股份有限公司 甲烷选择氧化制甲醛催化剂及其制备方法和应用
CN101239316B (zh) * 2007-02-09 2010-05-19 中国石油化工股份有限公司 一种甲烷选择氧化制甲醛催化剂及其制备方法和应用
WO2010133461A1 (de) 2009-05-20 2010-11-25 Basf Se Anlage und verfahren zur herstellung von höherwertigen kohlenwasserstoffen aus methan

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Publication number Publication date
CN103801327B (zh) 2016-01-06
EP2915582A4 (en) 2016-07-13
CN103801327A (zh) 2014-05-21
TWI605030B (zh) 2017-11-11
KR101880623B1 (ko) 2018-07-19
WO2014079142A1 (zh) 2014-05-30
PL2915582T3 (pl) 2018-06-29
US9314776B2 (en) 2016-04-19
EP2915582B1 (en) 2017-12-27
US20150321179A1 (en) 2015-11-12
EP2915582A1 (en) 2015-09-09
KR20150103664A (ko) 2015-09-11
TW201431824A (zh) 2014-08-16

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