WO2014054777A1 - 抗菌性化粧用ブラシ毛材、その毛材を用いた抗菌性化粧用ブラシ及びその製造方法 - Google Patents
抗菌性化粧用ブラシ毛材、その毛材を用いた抗菌性化粧用ブラシ及びその製造方法 Download PDFInfo
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- WO2014054777A1 WO2014054777A1 PCT/JP2013/077061 JP2013077061W WO2014054777A1 WO 2014054777 A1 WO2014054777 A1 WO 2014054777A1 JP 2013077061 W JP2013077061 W JP 2013077061W WO 2014054777 A1 WO2014054777 A1 WO 2014054777A1
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- cosmetic brush
- antibacterial cosmetic
- antibacterial
- hair material
- filament
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/006—Antimicrobial, disinfectant bristles, handle, bristle-carrier or packaging
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0207—Bristles characterised by the choice of material, e.g. metal
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/04—Preparing bristles
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1006—Brushes for cleaning the hand or the human body
- A46B2200/1013—Brushes for cleaning fingers or finger nails
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2976—Longitudinally varying
Definitions
- the present invention relates to an antibacterial cosmetic brush hair material using a polyester resin filament, an antibacterial cosmetic brush using the hair material, and a method for producing the same, and more specifically, polytrimethylene terephthalate (hereinafter referred to as a polyester resin). , "PTT”) and polybutylene terephthalate (hereinafter referred to as "PBT”) resin composition containing silver-containing soluble glass filaments, the surface of which has been roughened by alkali treatment.
- the present invention relates to a cosmetic brush bristle material, an antibacterial cosmetic brush excellent in the feeling of use using the bristle material, and excellent in cosmetic content (scraping and holding properties) and transferability, and a method for producing the same.
- animal hairs such as squirrel hair, horse hair, goat hair, etc. have been used as hair materials for cosmetic brushes, and these animal hairs have good skin contact, that is, have a good feeling of use and containability. And transferability is said to be good.
- the squirrel hair brush is highly regarded by consumers as the highest quality animal hair brush.
- animal hair has the above-mentioned advantages, it is a natural resource, so there are drawbacks such as limited supply, and in recent years, it has been made from synthetic fibers as a substitute for animal hair.
- Cosmetic brush hair materials have been proposed.
- Patent Document 1 proposes a cosmetic brush hair material having a dent on the surface.
- 100 parts by weight of PBT and 5 to 15 parts by weight of inorganic powders such as silica, talc and silver zeolite having an average particle size of 0.5 to 1.0 ⁇ m are mixed and melt-spun, and the resulting filament Is stretched 5 to 6 times to bury the inorganic powder on the surface and form a dent.
- the one end side of the fiber bundle obtained by concentrating the filament and cutting it to a certain length is immersed in an alkaline solution to enlarge the dent, and the one end side is dissolved to reduce the taper.
- a cosmetic brush hair material formed into a shape has been proposed.
- Patent Document 2 proposes a brush bristle material having irregularities on the surface of the PTT.
- This PTT brush bristle material requires more than three times the normal hydrolysis time to be immersed in an alkali treatment solution and hydrolyzed as compared to PBT brush bristle material, and is difficult to hydrolyze.
- the productivity of taper formation is inferior and the cost is high. Therefore, the brush bristle material is formed by melting and spinning PTT of the obtained filaments 5-6 times in order to make the tip of the taper-shaped tapered portion into a converged lengthwise direction.
- One end of about 10 to 20 mm is immersed in an amine catalyst-containing alkali treatment solution and treated at 110 to 130 ° C. for 1 to 2 hours to form a tapered taper at the tip of the filament by alkali treatment.
- irregularities of 1 to 20 ⁇ m can be formed on the surface.
- the fineness of the PTT filament of Examples 1 and 2 of the cosmetic brush hair material in Patent Document 2 is 80 dtex and 100 dtex.
- a treatment liquid comprising sodium hydroxide, a hydrolysis promoting catalyst, a penetrant and an oligomer solubilizer is used.
- the surface of the tapered tapered surface is spaced at intervals of 5 to 50 ⁇ m and 1 to 20 ⁇ m. It is disclosed that a brush bristle material having fine irregularities can be obtained, and antibacterial properties can be imparted by post-treatment with a heated aqueous solution of a benzylammonium chloride compound or a naphthoquinone compound after the alkali treatment. (See Patent Document 2).
- JP 2008-109990 A Japanese Patent Laid-Open No. 2006-141991
- the cosmetic brush bristle material made of polyester resin filaments of Patent Documents 1 and 2 forms a tapered taper on one end side of the filament by alkali treatment. Since the PBT filament of Patent Document 1 is mixed with PBT in an amount of 5 to 15 parts by weight of inorganic powder and stretched 5 to 6 times, unless the stretching speed, temperature, etc. are strictly controlled in the stretching process, There is a possibility that the filament may be cut, and because the dent is formed on the surface of the filament by the alkali treatment, the brush bristle material may be cut in a region where the dents in the middle of the tapered taper face each other. There is.
- the fineness of the brush hair material for PTT filament makeup of patent document 2 is 80 dtex (88.52 ⁇ m (specific gravity is calculated by 1.30)) and 100 dtex (98.97 ⁇ m (specific gravity is calculated by 1.30)).
- the filaments of these thicknesses are immersed in an alkali treatment solution containing an amine catalyst at a high temperature and treated for 1 to 2 hours, whereby irregularities of 1 to 20 ⁇ m are provided on the surface of the filaments at intervals of about 5 to 50 ⁇ m, Thereafter, antibacterial treatment is performed with a heated aqueous solution of a benzylammonium chloride compound or the like.
- the above-mentioned cosmetic brush hair material has been commercialized as the highest grade product that can provide a feeling of use of squirrel hair, but it takes time to form the tapered taper and the subsequent antibacterial treatment, compared to the PBT filament.
- inferior productivity it is necessary to prepare various processing solutions, and problems that cannot be produced at low prices have been pointed out.
- a thin hair having a thickness of about 45 to 65 ⁇ m such as a squirrel hair is produced, it is difficult to produce a brush bristle material because the dents in the middle of the taper are cut in regions facing each other.
- an object of the present invention has been made in view of the above circumstances, and does not use an amine catalyst in an alkaline treatment liquid, and thereafter does not perform an antibacterial treatment with a heated aqueous solution such as a benzylammonium chloride compound.
- Manufacturing brush hair for cosmetics In addition, by providing an antibacterial cosmetic brush hair material in which an uneven portion is formed on the surface of a tapered tapered detail using a polyester-based resin filament and is not cut in a region in the middle of the tapered tapered detail. is there. And it can be manufactured at a low price using this brush bristle material, has a feeling of use similar to animal hair cosmetic brushes including squirrel hairs, and contains and transfers of cosmetics such as powders. It is to provide an antibacterial cosmetic brush that is good.
- the present inventors have obtained a cosmetic filament containing a water-soluble silver-containing soluble glass in a resin composition containing polyester-based resin PTT and PBT.
- a cosmetic filament containing a water-soluble silver-containing soluble glass in a resin composition containing polyester-based resin PTT and PBT.
- the antibacterial cosmetic brush hair material of the invention according to claim 1 is an antibacterial cosmetic brush hair material comprising a tape made of polyester resin containing inorganic particles and having a tapered shape.
- the polyester resin filament is a resin composition containing 70.0 to 90.0% by weight of polytrimethylene terephthalate and 29.2 to 9.9% by weight of polybutylene terephthalate, and the inorganic particles contain silver.
- the soluble glass is 0.8 to 0.1% by weight, and the tip is characterized by having an uneven portion on the entire surface.
- the antibacterial cosmetic brush hair material of the invention according to claim 2 is characterized in that the silver concentration contained in the silver-containing soluble glass is in the range of 1.0 to 4.0% by weight.
- the antibacterial cosmetic brush hair material of the invention according to claim 3 is characterized in that the filament has a thickness of 50 to 150 ⁇ m.
- the antibacterial cosmetic brush hair material has a bacteriostatic activity value of 2.2 to 6 (JIS L 1902-1998 (ISO 20743)). It is characterized by that.
- the antibacterial cosmetic brush hair material of the invention according to claim 5 is characterized in that a convex exposed portion of the silver-containing soluble glass is formed on the body portion of the hair material following the tapered taper. To do.
- the antibacterial cosmetic brush hair material of the invention according to claim 6 is characterized in that the antibacterial cosmetic brush hair material is linear or curled.
- the antibacterial cosmetic brush of the invention according to claim 7 is characterized in that the antibacterial cosmetic brush hair material of claim 1 is used.
- the antibacterial cosmetic brush of the invention according to claim 8 is a liquid brush, a lip brush or a nail care brush.
- the method for producing an antibacterial cosmetic brush of the invention according to claim 9 is an antibacterial cosmetic brush bristle material comprising a tape made of polyester resin filaments containing inorganic particles and having a tapered shape.
- the polyester resin filament is composed of 70.0 to 90.0% by weight of polytrimethylene terephthalate and 29.2 to 9.9% by weight of polybutylene terephthalate.
- the antibacterial cosmetic brush hair material has a resin composition of 0.1% by weight and the tip portion is provided with uneven portions on the entire surface, and the resin composition is melted and kneaded with a spinning machine.
- the antibacterial cosmetic brush hair material of the present invention has a polyester resin of PTT of 70.0 to 90.0% by weight and PBT of 29.2 to 9.9% by weight, and the thermal conductivity is about 5 times that of the resin.
- the said antibacterial cosmetic brush hair material does not cut
- the antibacterial cosmetic brush of the present invention has an uneven portion of 1 to 2 ⁇ m formed on the entire surface of the tapered taper, and is similar to the surface shape of animal hair. Good containment and transferability.
- the thickness of a plate brush conventionally used for stage makeup has been about 150 ⁇ m because of the need for waist strength, but the antibacterial cosmetic brush of the present invention is a PBT. If the blending ratio is 25% by weight or more, a thick and strong plate brush of about 150 ⁇ m can be manufactured.
- the antibacterial cosmetic brush according to the present invention can be applied to various cosmetics according to the facial part and the condition of the cosmetics by changing the blending ratio of PTT and PBT of the antibacterial cosmetic brush hair material.
- liquid brushes, lip brushes, nail care brushes, foundation brushes, powder brushes, shadow brushes, teak brushes, highlight brushes, concealer brushes, and the like can be manufactured.
- the antibacterial cosmetic brush of the present invention has a silver-containing soluble glass on the surface of the tapered taper, the antibacterial effect is excellent.
- a lip brush that applies lip gloss to the lips is said to be contaminated with food such as food on the lips and transferred to the brush bristle material.
- An excellent deodorizing effect can be obtained by suppressing the propagation of bacteria by silver ions.
- Thermoplastic resin As the polyester-based resin used for the cosmetic brush hair material, a resin composition in which PTT and PBT are mixed is used from the viewpoints of flexibility, elastic recovery, and water resistance. As described above, the PTT cosmetic brush bristle material requires three times or more time to be immersed and hydrolyzed in the alkaline treatment liquid as compared with the PBT cosmetic brush bristle material. A filament is prepared by blending PBT which is easily hydrolyzed with liquid. PTT filaments have both the form stability of polyester and the softness of nylon, but it is said that the softness of the PTT filaments is not suitable for cosmetic brush hair materials that are disadvantageous and require hardness. Yes.
- PBT filaments are easy to dye and have excellent stretch properties when processed into yarns, and are harder than PTT filaments, so various cosmetic brushes have been put to practical use. Therefore, a filament in which PBT is blended with PTT to make up the softness of the PTT filament is produced.
- PTT and PBT are blended in a range of 70.0 to 90.0: 29.2 to 9.9.
- Silver-containing soluble glass is soluble in water. Desirably, the total composition of the filament is 100% by weight, and the soluble glass containing silver is blended in an amount of 0.8 to 0.1% by weight.
- the silver concentration contained in the silver-containing soluble glass is preferably in the range of 1.0 to 4.0% by weight.
- Three types of silver-containing soluble glass having an average particle diameter of 1 to 10 ⁇ m and silver concentrations of 1.4, 2.0 and 3.0% by weight are commercially available in Japan. This silver-containing soluble glass is generally called “silver glass”, and is indicated by this silver glass when shown in the table.
- a silver-containing soluble glass having a silver concentration of 1.4% by weight and a blending ratio of less than 0.1% by weight is not preferable because hydrolysis is not promoted. If the blending ratio exceeds 0.8% by weight, the filament may be cut in the hydrolysis step. Therefore, silver-containing soluble glass is blended with the above resin in the blending ratio range of 0.1 to 0.8% by weight. It is preferable to do. Moreover, in order to suppress that a filament cut
- the heat conductivity of a silver containing soluble glass is a value with the width
- the silver-containing soluble glass used in the examples has a value of 1.40 W / m ⁇ K.
- the filaments of the antibacterial cosmetic bristle include PTT pellets and PBT pellets and silver-containing soluble glass powder, PTT pellets and silver-containing soluble glass-containing PBT pellets (or vice versa), or PTT powder, PBT powder and silver
- the contained soluble glass powder is stirred so that it is uniformly dispersed, put into a hopper of a spinning machine, melted, kneaded, extruded, spun from the spinneret, and stretched 4 to 5 times by three-stage heat stretching. A filament of about 76 ⁇ m is produced.
- the filaments are collectively gathered into a cylindrical shape and cut into a predetermined length.
- One end of the cut is subjected to alkali treatment with an aqueous sodium hydroxide solution. Thereafter, it is washed with water and dried.
- the filament is subjected to crimping by a gear crimping method or the like, and the filament is converged into a cylindrical shape and cut into a predetermined length.
- One end of the cut is subjected to alkali treatment with an aqueous sodium hydroxide solution. Thereafter, it is washed with water and dried.
- the silver-containing soluble glass on the filament surface is dissolved in the alkali treatment liquid, and the surface area in contact with the alkali treatment liquid is expanded to cause hydrolysis. Promoted.
- the action of promoting hydrolysis by dissolving the silver-containing soluble glass is hereinafter referred to as “dissolution promoting action”.
- the region where the uneven portion having a tapered shape in the tip direction appears is called ⁇ tapered detail '', and the sodium hydroxide aqueous solution is sucked up by a capillary phenomenon into a filament converging in a columnar shape,
- the resin film covering the silver-containing soluble glass coated by hydrolysis of the resin is dissolved and removed.
- the silver-containing soluble glass is in a state where a resin film is formed on the surface by spinning, the silver glass-soluble glass is scattered in the form of particles, and a resin film is formed thereon, and resin shrinkage action such as sink In addition, it is scattered in a convex shape. Only a resin film portion is removed by a small amount of the alkali agent sucked up by the capillary phenomenon, and silver glass is exposed on the surface of the body portion to be convex.
- the antibacterial cosmetic brush bristle material of the present invention has convex portions formed in the tapered tapered region and the body region where the concavo-convex portions are formed on the entire surface.
- the tip of the tapered taper has a conical shape.
- the antibacterial cosmetic brush of this invention apply
- the linear shape is used for liquid brushes, lip brushes or nail care brushes, and is used to apply liquid cosmetics.
- the curled shape is used for foundation brushes, powder brushes, shadow brushes, teak brushes, highlight brushes or concealer brushes, and is used for applying powdery cosmetics.
- a gear crimping method is generally used from the viewpoint of workability.
- the method for producing an antibacterial cosmetic brush of the present invention includes steps of blending resin, spinning, alkali treatment, and bristle material embedding.
- the blending step of the polyester-based resin was carried out by adding a silver-containing soluble glass 0.8 to 0 to a resin composition containing 70.0 to 90.0% by weight of polytrimethylene terephthalate and 29.2 to 9.9% by weight of polybutylene terephthalate. This is a step of blending 1 wt%.
- the spinning process is a process for producing a filament by melting, kneading, and extruding the blended resin with a spinning machine, and stretching it 4 to 5 times by heat stretching from the spinning port.
- the alkali treatment step is a step in which the spun filament is converged into a cylindrical shape and cut into a predetermined length, and one end of the cut filament is alkali treated with an aqueous sodium hydroxide solution, and then washed with water and dried.
- a tapered taper is formed in the tip direction of the tip portion, and an uneven portion is formed on the surface thereof.
- the filaments can be crimped when converging, and the filaments can be converged and cut into a predetermined length.
- the bristle material embedding step is a step of embedding the above-mentioned alkali-treated brush bristle material in a hair bundle holding member to form a cosmetic brush.
- PTT pellets SORONA J2240 Semi-Dull; Du Pont product
- PBT pellets PBT pellets (TORAYCOM 1401X06 Toray product) and silver-containing soluble glass (PG721ST Koa glass product) are mixed and stirred to be uniform.
- PTT powder SORONA J2240 Semi-Dull; Du Pont product
- PBT powder PBT powder
- silver-containing soluble glass PG721ST Koa glass product
- the uniformly mixed resin is put into a hopper of a spinning machine, melted at 270 ° C., kneaded at 250 ° C., extruded, spun from the spinneret, and stretched 4 to 5 times by three-stage heat stretching.
- the filament was focused into a cylindrical shape having a diameter of 5 cm and cut to a length of 6 cm.
- One end of the filament bundling was dipped in a 12 wt% sodium hydroxide aqueous solution at 120 ° C., and the dipped portion that was the filament bundling soaked with time was gradually pulled up and dipped for a maximum of 120 minutes. The dipping time was adjusted so that the tip of the tapered tapered tip of the filament converging was hydrolyzed to a thickness of 5 to 10 ⁇ m.
- the filament above the filament converging immersion part is a body in which the convex part is scattered by sucking up the sodium hydroxide aqueous solution by capillary action and dissolving and removing the resin covering the convex part of the silver-containing soluble glass on the filament surface. Part was formed.
- the width of the body portion can be arbitrarily changed by adjusting the strength of focusing the filament. Subsequently, it was washed with water and dried to obtain an antibacterial cosmetic brush hair material.
- the tapered taper When forming a tapered taper by applying an alkali treatment to a filament of about 76 ⁇ m, if the silver-containing soluble glass is blended inhomogeneously, the tapered taper may be cut from the heterogeneously blended portion. Therefore, it is important to uniformly mix and stir the PTT powder, PBT powder and silver-containing soluble glass powder and put them into the hopper of the spinning machine. It is optional to mix and stir the three components, or to mix the two components first and then add and mix the remaining components.
- Examples 1 to 9 Three types of antibacterial cosmetic brush hair materials having different content ratios of the silver-containing soluble glass shown in Examples 1 to 9 below were produced by the production method using melt spinning described above. It shows concretely in Table 1. Examples 1 to 3 containing 0.1% by weight of silver-containing soluble glass, Examples 4 to 6 containing 0.5% by weight of silver-containing soluble glass, Examples containing 0.8% by weight of silver-containing soluble glass 7-9. Filaments blended with three kinds of silver-containing soluble glass by the above-described production method were stretched 4 to 5 times under the above conditions to produce filaments having a thickness of about 76 ⁇ m. These filaments were subjected to the alkali treatment described above to form tapered details.
- Comparative Examples 1 to 4 In Comparative Example 1, 100% by weight PTT filament was subjected to the alkali treatment. In Comparative Example 2, 1 wt% silver-containing soluble glass was blended with 99 wt% PTT. In Comparative Example 3, the alkali treatment was performed on 100 wt% PBT filament. In Comparative Example 4, 1 wt% silver-containing soluble glass was blended with 99 wt% PBT. These filaments are subjected to the alkali treatment to form a body part and a tapered tapered detail. The PTT and PBT of the comparative examples are the same resins used in the examples and the silver-containing soluble glass of the comparative examples is also used in the examples.
- FIG. 1 is a 1000 ⁇ surface photograph of a squirrel hair tip taken with a laser microscope.
- the thickness of the tip of the tip is 7 ⁇ m, and it can be seen that many irregularities are formed on the surface.
- FIG. 2 is a 1000 ⁇ surface photograph of a squirrel hair body taken with a laser microscope. It can be seen that the body portion has a thickness of 25 ⁇ m, and a large number of ring-shaped uneven portions are formed on the surface thereof.
- FIG. 3 is a 1000 ⁇ surface photograph of the tip of the filament of Example 5 taken with a laser microscope. It can be seen that the thickness of the tip of the tip is 5 ⁇ m, and numerous irregularities are formed on the surface thereof.
- FIG. 4 is a 1000 ⁇ surface photograph of the body of the filament of Example 5 taken with a laser microscope. It can be seen that the thickness of the body portion is 45 ⁇ m, and a large number of uneven portions are formed on the surface thereof.
- FIG. 5 is a 1000 ⁇ surface photograph of the tip of the filament of Comparative Example 2 taken with a laser microscope. The thickness of the tip of the tip is 53 ⁇ m, and it can be seen that the tip is broken halfway.
- FIG. 6 is a 1000 ⁇ surface photograph of the body of the filament of Comparative Example 2 taken with a laser microscope. It can be seen that the thickness of the body portion is 45 ⁇ m, and a large number of uneven portions are formed on the surface thereof.
- the surface of the tapered tapered details of the antibacterial cosmetic brush hair materials of Examples 1 to 9 was measured with a laser microscope (VK-8710 VK-Analyzer (manufactured by Keyence)) and the height of the irregularities on the surface. And its distribution, and the thickness of the tip of the tapered taper. The height, distribution and thickness are shown in Table 3.
- the surface of the tapered taper of the hair material of Comparative Examples 1 to 4 was measured with a laser microscope (VK-8710 VK-Analyzer (manufactured by Keyence)), the height and distribution of the irregularities on the surface, and the above The tip thickness of the tapered taper was measured.
- the height, distribution, and thickness are shown in Table 4. From Table 4, in Comparative Examples 2 and 4, 30% of the tip having a thickness of 40 ⁇ m is generated.
- the thickness of the tip is more than 10 times the normal thickness and is abnormal.
- the thickness of the filament is about 76 ⁇ m, and it is abnormal that the tip formed by the alkali treatment is 40 ⁇ m thick. Is a serious drawback that irritate the skin.
- This extraordinary thickness occurs in a tapered tapered region due to alkali treatment when 1.0% by weight of silver-containing soluble glass is contained. Therefore, it was found that it is difficult to contain 1.0% by weight of silver-containing soluble glass in PTT and PBT.
- the bacteriostatic activity values in Table 3 and Table 4 are values of the antibacterial test of Staphylococcus aureus based on the criteria of JIS L 1902-1998 (ISO 20743).
- the test results in Table 3 show that the bacteriostatic activity value of S. aureus is in the range of 3.8 to 5.6, indicating that excellent antibacterial properties are obtained.
- the bacteriostatic activity value is a value of 2.2 or more, it is determined that the antibacterial deodorization standard is exceeded. It is far beyond that.
- the antibacterial cosmetic brush hair materials of Examples 1 to 9 have a bacteriostatic activity value in the range of 3.8 to 5.6, and the bacteria in a shorter time than the bacteriostatic activity value 2.2. It can be seen that odor can be sterilized and the generation of odor can be prevented immediately.
- the antibacterial cosmetic brush hair materials of Examples 1 to 9 have 25-39 / ⁇ m 2 distribution density of silver-containing soluble glass on the entire surface of the tip, so that the skin resident bacteria and Excellent antibacterial and deodorant properties against varicella.
- Comparative Examples 1 and 3 in Table 4 show values of 0.1 and 0.2 because silver-containing soluble glass is not contained in PTT and PBT.
- Comparative Examples 2 and 4 containing 1.0% by weight of the above-mentioned silver-containing soluble glass show a high bacteriostatic activity value of 5.6 and are excellent in antibacterial effect. If an abnormal thickness of 40 ⁇ m is generated at the tip formed, and the cosmetic brush includes the thickness, the hair becomes a serious defect that stimulates the skin.
- Tables 7 to 9 show the results of measuring the elastic modulus (%) and Young's modulus (N / mm 2 ), which are physical properties of Examples 3, 6 and 9 of 9.2% by weight.
- Table 10 shows the results of measuring the tensile elastic modulus (%) and Young's modulus (N / mm 2 ) of Comparative Examples 1 to 4.
- Examples 1, 4 and 7 having a PBT content of 29.9 to 29.2% by weight had an elastic modulus (%) of 78 to 82 (%) and a Young's modulus (N / mm 2 ) of 3334 to 3434.
- Examples 2, 5 and 8 having a PBT content of 19.9 to 19.2% by weight had an elastic modulus (%) of 83 to 87 (%) and a Young's modulus (N / mm 2 ) of 3233 to Examples 3, 6 and 9 having a PBT content of 9.9 to 9.2% by weight had a tensile modulus (%) of 88 to 92 and a Young's modulus (N / mm 2 ) of 3128 to 3232. It is.
- Comparative Example 1 (PTT 100 wt%) has an elastic modulus of 94 and Young's modulus of 3067
- Comparative Example 3 has an elastic modulus of elasticity of 40 and Young's modulus of 4047. 29.2% by weight
- the tensile elastic modulus 94 of Comparative Example 1 can be decreased to 78
- the Young's modulus 3067 of Comparative Example 1 can be increased to 3434.
- the above-mentioned ratio of the blended amount of PBT and the relationship between the elastic modulus of elasticity and Young's modulus can be found in liquid brushes, lip brushes, nail care brushes, foundation brushes, powder brushes, shadow brushes, cheek brushes, highlight brushes, concealer brushes, etc. It shows that the corresponding physical properties can be arbitrarily selected.
- the brush bristle materials of Examples 1 to 9 have a tapered detail in the tip direction of one end or both ends, and a 1 to 2 ⁇ m uneven portion is provided on the entire surface of the tapered detail. It can be seen that the containability and transferability are superior to those of Comparative Example 1 (PTT 100 wt%).
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Abstract
Description
即ち本発明は、以下の通りのものである。
請求項1に係る発明の抗菌性化粧用ブラシ毛材は、無機粒子を含有するポリエステル系樹脂製フィラメントからなり、テーパー状に形成された先細部を備えた抗菌性化粧用ブラシ毛材であって、ポリエステル系樹脂製フィラメントは、ポリトリメチレンテレフタレート70.0~90.0重量%、及びポリブチレンテレフタレート29.2~9.9重量%を含む樹脂組成物であり、無機粒子が銀を含有する可溶性ガラス0.8~0.1重量%であり、先細部は、表面全面に凹凸部を備えてなることを特徴とする。
請求項2に係る発明の抗菌性化粧用ブラシ毛材は、前記銀含有可溶性ガラスに含まれる銀濃度が1.0~4.0重量%の範囲にあることを特徴とする。
請求項3に係る発明の抗菌性化粧用ブラシ毛材は、前記フィラメントの太さが、50~150μmであることを特徴とする。
請求項4に係る発明の抗菌性化粧用ブラシ毛材は、前記抗菌性化粧用ブラシ毛材が静菌活性値2.2~6(JIS L 1902-1998(ISO20743))の範囲の値であることを特徴とする。
請求項5に係る発明の抗菌性化粧用ブラシ毛材は、テーパー状先細部に続く毛材の胴体部に銀含有可溶性ガラスが凸状の露出している部分が形成されていることを特徴とする。
請求項6に係る発明の抗菌性化粧用ブラシ毛材は、前記抗菌性化粧用ブラシ毛材の形状が直線状又はカール状であることを特徴とする。
請求項7に係る発明の抗菌性化粧用ブラシは、請求項1の抗菌性化粧用ブラシ毛材を用いたことを特徴とする。
請求項8に係る発明の抗菌性化粧用ブラシは、リキッドブラシ、リップブラシまたはネイルケアブラシであることを特徴とする。
請求項9に係る発明の抗菌性化粧用ブラシの製造方法は、無機粒子を含有するポリエステル系樹脂製フィラメントからなり、テーパー状に形成された先細部を備えた抗菌性化粧用ブラシ毛材であって、ポリエステル系樹脂製フィラメントは、ポリトリメチレンテレフタレート70.0~90.0重量%、及びポリブチレンテレフタレート29.2~9.9重量%、無機粒子が銀を含有する可溶性ガラス0.8~0.1重量%である樹脂組成であり、先端部は、表面全面に凹凸部を備えてなる抗菌性化粧用ブラシ毛材の製造方法であって、樹脂組成物を紡糸機で溶融、混練し押出して、紡糸口より加熱延伸により4~5倍の延伸を行ってフィラメントを製造する工程と、上記フィラメントを束に集束して、所定の長さに切断する工程、切断した一端を水酸化ナトリウム水溶液でアルカリ処理を行って先端部にテーパー状先細部を形成すると共に、当該先細部の表面に凹凸部を形成する工程、その後に水洗して乾燥を行う工程と、ブラシ毛材を毛束保持部材に埋設する工程とからなることを特徴とする。
更に、本発明の抗菌性化粧用ブラシは、抗菌性化粧用ブラシ毛材のPTTとPBTの配合割合を変えることで、それを使用する顔の部位、化粧料の状態に応じて、各種の化粧用ブラシ、例えば、リキッドブラシ、リップブラシ、ネイルケアブラシ、ファンデーションブラシ、パウダーブラシ、シャドーブラシ、チークブラシ、ハイライトブラシまたはコンシーラーブラシ等が製造できる。
化粧用ブラシ毛材に用いるポリエステル系樹脂としては、柔軟性、弾性回復性、耐水性の物性面から、PTT及びPBTを混合した樹脂組成が用いられる。上述したように、PTTの化粧用ブラシ毛材は、PBTの化粧用ブラシ毛材に比べて、アルカリ処理液に浸漬して加水分解するのに3倍以上の時間が必要であるから、アルカリ処理液で加水分解し易いPBTを配合してフィラメントとする。そして、PTTフィラメントは、ポリエステルの形態安定性とナイロンの柔らかさを兼ね備えているが、その柔らかさが逆に欠点となり硬さを必要とする化粧用ブラシ毛材には向いていないと言われている。また、PBTフィラメントは、染色が容易であること、加工糸にした場合の伸縮特性に優れており、PTTフィラメントより硬いことから各種の化粧用ブラシが実用化されている。そこで、PTTフィラメントの柔らかさを補うためにPTTにPBTを配合したフィラメントを作製する。
フィラメントの全組成を100重量%として、PTTとPBTは、70.0~90.0:29.2~9.9の配合である。
銀含有可溶性ガラスは水に可溶性である。フィラメントの全組成を100重量%として銀含有可溶性ガラスは0.8~0.1重量%が配合されることが望ましい。また、銀含有可溶性ガラスに含まれる銀濃度は1.0~4.0重量%の範囲にあることが望ましい。
平均粒径が1~10μmであって銀濃度が1.4、2.0、3.0重量%の3種類の銀含有可溶性ガラスが日本で市販されている。この銀含有可溶性ガラスは、一般的に「銀ガラス」と呼ばれており、表に示すときはこの銀ガラスで表示する。
銀濃度が1.4重量%の銀含有可溶性ガラスで配合率が0.1重量%未満であると、加水分解が促進されないので好ましくない。配合率が0.8重量%を超えると加水分解の工程においてフィラメントが切断される状況が発生するので、上記樹脂に銀含有可溶性ガラスを配合率0.1~0.8重量%の範囲で配合することが好ましい。また、加水分解の工程においてフィラメントが切断するのを抑えるために、平均粒径が1μmのものが好ましい。
なお、銀含有可溶性ガラスの熱伝導率は、配合素材により1.40W/m・Kを中心にした幅を持った値である。実施例で用いた銀含有可溶性ガラスでは1.40W/m・Kの値のものである。
次に、本発明の抗菌性化粧用ブラシ毛材の製造方法を説明する。
抗菌性化粧用ブラシ毛材のフィラメントは、PTTペレットとPBTペレット及び銀含有可溶性ガラス粉末、PTTペレットと銀含有可溶性ガラス含有のPBTペレット(その逆も可)、または、PTT粉末、PBT粉末及び銀含有可溶性ガラス粉末を均一に分散するように撹拌し、紡糸機のホッパーに投入して溶融、混練し押出して、紡糸口より紡糸して3段の加熱延伸により4~5倍の延伸を行って約76μmのフィラメントを製造する。そして、上記フィラメントをまとめて円柱状に集束し所定の長さに切断する。切断した一端を水酸化ナトリウム水溶液でアルカリ処理を行う。その後水洗して乾燥を行う。
または、上記フィラメントにギヤクリンプ法等によりクリンプ加工を施し、そのフィラメントを円柱状に集束し所定の長さに切断する。切断した一端を水酸化ナトリウム水溶液でアルカリ処理を行う。その後、水洗して乾燥を行う。
したがって、本発明の抗菌性化粧用ブラシ毛材は、表面全面に凹凸部が形成されているテーパー状先細部の領域と胴体部の領域には凸が形成されている。上記テーパー状先細部の先端は円錐形状であり、その円錐形状を形成する基端の太さが小さいほど肌触りが優れている。この太さは、基本的にフィラメントの胴部の太さと同じである。
そして、本発明の抗菌性化粧用ブラシは、上記銀含有可溶性ガラスの溶解促進作用による凹凸部の領域を有するテーパー状先細部でファンデーション等の化粧料を塗布する。
抗菌性化粧用ブラシ毛材の形状は、直線状とカール状の2種類がある。その形状が直線状のものは、リキッドブラシ、リップブラシまたはネイルケアブラシに用いられ、リキッド状の化粧料を塗布するのに用いられる。その形状がカール状のものは、ファンデーションブラシ、パウダーブラシ、シャドーブラシ、チークブラシ、ハイライトブラシまたはコンシーラーブラシに用いられ、粉末状の化粧料を塗布するのに用いられる。上記カールを付与させる加工方法としては、ギヤクリンプ法が作業性の観点から一般的に用いられている。
本発明の抗菌性化粧用ブラシの製造方法は、樹脂を配合、紡糸、アルカリ処理、毛材埋設の工程を経る。
ポリエステル系樹脂の配合工程は、ポリトリメチレンテレフタレート70.0~90.0重量%、ポリブチレンテレフタレート29.2~9.9重量%を含む樹脂組成物に、銀含有可溶性ガラス0.8~0.1重量%を配合する工程である。紡糸工程は、この配合された樹脂を紡糸機で溶融、混練し押出して、紡糸口より加熱延伸により4~5倍の延伸を行ってフィラメントを製造する工程である。アルカリ処理工程は、紡糸されたフィラメントを円柱状に集束し所定の長さに切断し、切断した一端を水酸化ナトリウム水溶液でアルカリ処理を行い、その後に水洗して乾燥が行われる工程である。このアルカリ処理によってその先端部の先端方向にテーパー状先細部が形成されると共に、その表面に凹凸部が形成される。または、集束する際に上記フィラメントにクリンプ加工を施し、そのフィラメントを集束し所定の長さに切断することもできる。毛材の埋設工程は、上記アルカリ処理したブラシ毛材を毛束保持部材に埋設して、化粧用ブラシに形成する工程である。
均一に混合された樹脂を紡糸機のホッパーに投入して、270℃で溶融し250℃で混練して押し出して、紡糸口より紡糸して3段の加熱延伸により4~5倍の延伸を行って約76μmのフィラメントを製造した。このフィラメントの表面は、粒子状銀ガラスがある部分は凸状に点在し、その表面は薄い樹脂皮膜が形成されている状態である。
このフィラメントを直径5cmの円柱状に集束して長さ6cmに切断した。
フィラメント集束の一端を12重量%濃度の水酸化ナトリウム水溶液に120℃で浸漬して、経時的にその浸漬したフィラメント集束である浸漬部を、徐々に引き上げて最高120分間を浸漬した。上記フィラメント集束のテーパー状先細部の先端が加水分解により5~10μmの太さになるように浸漬時間の調整を行った。
上記フィラメント集束の浸漬部の上方のフィラメントは、上記水酸化ナトリウム水溶液を毛細管現象により吸い上げて、上記フィラメント表面の銀含有可溶性ガラスの凸部を被覆する樹脂を溶解除去して凸部が散在する胴体部を形成した。この胴体部はフィラメントを集束する強弱を調整することによりその幅を任意に変えることができる。次いで水洗乾燥して抗菌性化粧用ブラシ毛材を得た。
上記した溶融紡糸による製造方法で以下実施例1~9に示す銀含有可溶性ガラスの3種類の含有率の異なる抗菌性化粧用ブラシ毛材を製造した。
表1に具体的に示す。銀含有可溶性ガラス0.1重量%を配合した実施例1~3、銀含有可溶性ガラス0.5重量%を配合した実施例4~6、銀含有可溶性ガラス0.8重量%を配合した実施例7~9である。上記した製造方法で3種類の銀含有可溶性ガラスを配合したフィラメントを前記の条件で4~5倍に延伸して太さ約76μmのフィラメントを製造した。これらのフィラメントに上記したアルカリ処理を施して、テーパー状先細部を形成した。
比較例1は、100重量%PTTフィラメントに上記アルカリ処理を施した。比較例2は、99重量%PTTに1重量%銀含有可溶性ガラスを配合した。比較例3は、100重量%PBTフィラメントに上記アルカリ処理を施した。比較例4は、99重量%PBTに1重量%銀含有可溶性ガラスを配合した。
これらのフィラメントに、上記アルカリ処理を施し、胴体部及びテーパー状先細部を形成したものである。
なお、比較例のPTT及びPBTは実施例で使用した樹脂、そして比較例の銀含有可溶性ガラスも実施例で使用したものを用いている。
図1は、レ-ザー顕微鏡で撮影したリス毛先端部の1000倍の表面写真である。先端部の先端の太さは7μmであり、その表面に凹凸部が多数形成されていることが分かる。
図2は、レ-ザー顕微鏡で撮影したリス毛胴体部の1000倍の表面写真である。胴体部の太さは25μmであり、その表面にリング状の凹凸部が多数形成されていることが分かる。
図4は、レ-ザー顕微鏡で撮影した実施例5のフィラメントの胴体部の1000倍の表面写真である。胴体部の太さは45μmであり、その表面に凹凸部が多数形成されていることが分かる。
図5は、レ-ザー顕微鏡で撮影した比較例2のフィラメントの先端部の1000倍の表面写真である。先端部の先端の太さは53μmであり、先端部が途中で破断していることが分かる。
図6は、レ-ザー顕微鏡で撮影した比較例2のフィラメントの胴体部の1000倍の表面写真である。胴体部の太さは45μmであり、その表面に凹凸部が多数形成されていることが分かる。
表4から、比較例2及び4では、上記先端が40μmの太さのものが30%発生している。この先端の太さは通常の10倍以上の太さであり異常なものである。フィラメントの太さは約76μmであり、アルカリ処理で形成される上記先端が40μmの太さであることは異常なことであり、化粧用ブラシにその太さのものが含まれたとすると、その毛が肌を刺激する重大な欠点となる。
この異常な太さは、銀含有可溶性ガラスを1.0重量%含有させると、アルカリ処理によりテーパー状先細部の領域で発生する。従って、銀含有可溶性ガラスをPTT及びPBTに1.0重量%含有させることは困難なことが分かった。
表3の試験結果は、黄色ブドウ球菌の測定の静菌活性値が3.8~5.6の範囲の値を示しており、優れた抗菌性が得られていることが分かる。上記基準では静菌活性値が2.2以上の値であれば、抗菌防臭基準を超えていると定められており、上記静菌活性値が3.8~5.6の範囲の値は、それを遥かに凌ぐものである。
銀含有可溶性ガラスを配合した実施例と比較例の毛材を用いて、パウダーブラシについて、5名の使用テストの結果を1~5の5段階で評価した。パウダーブラシの評価結果を表5(実施例)及び表6(比較例)に示す。
5段階の評価は、「5」が大変優れる、「4」が優れる、「3」が普通、「2」が劣る、そして、「1」が大変劣るとして評価した。
以上の結果から、伸張弾性率はPBTの配合割合が減少するに従って増加していることが分かり、ヤング率はPBTの配合割合が減少するに従って減少していることが分かる。また、比較例1(PTT100重量%)の伸張弾性率は94で、ヤング率は3067であり、比較例3(PBT100重量%)の伸張弾性率は40で、ヤング率は4047であるが、PBTを29.2重量%配合することで、比較例1の伸張弾性率94を78にまで減少させることができ、また、比較例1のヤング率3067を3434にまで増加させることができる。
そして、実施例1~9のブラシ毛材は、一方端又は両方端の先端方向にテーパー状先細部が形成されると共に、テーパー状先細部の表面全面に1~2μmの凹凸部が設けられており、含み性、転着性が比較例1(PTT100重量%)より優れていることが分かる。
Claims (9)
- 無機粒子を含有するポリエステル系樹脂製フィラメントからなり、テーパー状に形成された先細部を備えた抗菌性化粧ブラシ用毛材であって
ポリエステル系樹脂製フィラメントは、ポリトリメチレンテレフタレート70.0~90.0重量%、及びポリブチレンテレフタレート29.2~9.9重量%を含む樹脂組成物であり、無機粒子が銀を含有する可溶性ガラス0.8~0.1重量%であり、
先細部は、表面全面に凹凸部を備えてなることを特徴とする抗菌性化粧用ブラシ毛材。 - 前記銀含有可溶性ガラスに含まれる銀濃度が1.0~4.0重量%の範囲にあることを特徴とする請求項1に記載の抗菌性化粧用ブラシ毛材。
- 前記フィラメントの太さが、50~150μmであることを特徴とする請求項2に記載の抗菌性化粧用ブラシ毛材。
- 前記抗菌性化粧用ブラシ毛材が静菌活性値2.2~6(JIS L 1902-1998(ISO20743))の範囲の値であることを特徴とする請求項3に記載の抗菌性化粧用ブラシ毛材。
- テーパ状先細部に続く毛材の胴体部に銀含有可溶性ガラスが凸状の露出している部分が形成されていることを特徴とする請求項4記載の抗菌性化粧用ブラシ毛材。
- 前記抗菌性化粧用ブラシ毛材の形状が直線状又はカール状であることを特徴とする請求項1又は2に記載の抗菌性化粧用ブラシ毛材。
- 請求項1記載の抗菌性化粧用ブラシ毛材を用いた抗菌性化粧用ブラシ。
- リキッドブラシ、リップブラシまたはネイルケアブラシである請求項7に記載の抗菌性化粧用ブラシ。
- 無機粒子を含有するポリエステル系樹脂製フィラメントからなり、テーパー状に形成された先細部を備えた抗菌性化粧ブラシ用毛材であって、ポリエステル系樹脂製フィラメントは、ポリトリメチレンテレフタレート70.0~90.0重量%、及びポリブチレンテレフタレート29.2~9.9重量%、無機粒子が銀を含有する可溶性ガラス0.8~01重量%である樹脂組成であり、先細部は、表面全面に凹凸部を備えてなる抗菌性化粧用ブラシ毛材の製造方法であって、
樹脂組成を紡糸機で溶融、混練し押出して、紡糸口より加熱延伸により4~5倍の延伸を行ってフィラメントを製造する工程と、
上記フィラメントを束に集束して、所定の長さに切断する工程、
切断した一端を水酸化ナトリウム水溶液でアルカリ処理を行って先端部にテーパー状先細部を形成すると共に、当該先細部の表面に凹凸部を形成する工程、
その後に水洗して乾燥を行う工程と、
ブラシ毛材を毛束保持部材に埋設する工程と、
からなることを特徴とする抗菌性化粧用ブラシの製造方法。
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JP2013207866A JP6268575B2 (ja) | 2012-10-04 | 2013-10-03 | 抗菌性化粧用ブラシ毛材、その毛材を用いた抗菌性化粧用ブラシ及びその製造方法 |
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EP (1) | EP2904935B1 (ja) |
KR (1) | KR102126098B1 (ja) |
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CN105803563A (zh) * | 2014-12-31 | 2016-07-27 | 杜邦兴达(无锡)单丝有限公司 | 化妆刷用单丝 |
US20180027941A1 (en) * | 2016-07-28 | 2018-02-01 | DMCOSMETICS Co., Ltd. | Antibacterial puff for cosmetics |
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AU2015413648B2 (en) * | 2015-11-03 | 2018-09-06 | Colgate-Palmolive Company | Bristle and toothbrush incorporating the same |
CN114468516A (zh) * | 2015-12-31 | 2022-05-13 | 株式会社爱茉莉太平洋 | 具有抗菌力的海绵 |
US20180199700A1 (en) * | 2017-01-16 | 2018-07-19 | L'oreal Usa Creative, Inc. | Systems, devices, and method for making a cosmetic applicator |
JP7006624B2 (ja) * | 2017-02-13 | 2022-01-24 | 東レ株式会社 | 内視鏡洗浄器具 |
CN109251486A (zh) * | 2018-07-25 | 2019-01-22 | 安徽玉达工具有限公司 | 一种仿猪鬃毛刷丝及其制备方法 |
CN111374442A (zh) * | 2020-04-14 | 2020-07-07 | 广东迪魔生物科技有限公司 | 一种多孔抗菌纤维毛刷的制备方法 |
CN114381928B (zh) * | 2022-01-25 | 2024-05-07 | 江阴天而然纺织科技有限公司 | 一种仿羊毛纤维面料及其加工工艺 |
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Also Published As
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KR102126098B1 (ko) | 2020-06-23 |
KR20150067755A (ko) | 2015-06-18 |
JP2014087637A (ja) | 2014-05-15 |
CN104736015A (zh) | 2015-06-24 |
US10172446B2 (en) | 2019-01-08 |
EP2904935A1 (en) | 2015-08-12 |
US20150257524A1 (en) | 2015-09-17 |
EP2904935A4 (en) | 2016-05-25 |
HK1210923A1 (en) | 2016-05-13 |
EP2904935B1 (en) | 2018-08-22 |
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