WO2014034619A1 - 香料担持シガレット構成部材およびそれを含むシガレット - Google Patents

香料担持シガレット構成部材およびそれを含むシガレット Download PDF

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Publication number
WO2014034619A1
WO2014034619A1 PCT/JP2013/072774 JP2013072774W WO2014034619A1 WO 2014034619 A1 WO2014034619 A1 WO 2014034619A1 JP 2013072774 W JP2013072774 W JP 2013072774W WO 2014034619 A1 WO2014034619 A1 WO 2014034619A1
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WIPO (PCT)
Prior art keywords
cigarette
menthol
fragrance
carrying
tobacco
Prior art date
Application number
PCT/JP2013/072774
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English (en)
French (fr)
Japanese (ja)
Inventor
田中　康男
拓哉 音川
Original Assignee
日本たばこ産業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本たばこ産業株式会社 filed Critical 日本たばこ産業株式会社
Priority to EP13833905.6A priority Critical patent/EP2891409B1/en
Priority to CN201910561087.2A priority patent/CN110279140B/zh
Priority to RU2015111175/12A priority patent/RU2587075C1/ru
Priority to JP2014533001A priority patent/JP5934799B2/ja
Priority to CN201380045426.2A priority patent/CN104582512A/zh
Publication of WO2014034619A1 publication Critical patent/WO2014034619A1/ja

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    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B3/00—Preparing tobacco in the factory
    • A24B3/12—Steaming, curing, or flavouring tobacco
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/02—Cigars; Cigarettes with special covers

Definitions

  • the present invention relates to a fragrance-carrying cigarette constituent member and a cigarette including the same.
  • Patent Documents 1 to 3 have been reported as examples in which a fragrance component is arranged on a cigarette that is a burning part or a wrapping paper that encloses it.
  • Patent Document 1 discloses that a fragrance material in which a fragrance component is incorporated in a three-dimensional network structure of glucan molecules is applied to a wrapping paper enclosing a tobacco filler. Since the cigarette of patent document 1 takes in a fragrance
  • Patent Document 2 a liquid perfume and a carrageenan sol are mixed and dropped into an ionic solution (a solution containing potassium ions) to prepare a granular gel, which is dried in the air, so that “stable and stable up to 180 ° C.”
  • ionic solution a solution containing potassium ions
  • the preparation of "aromatized fragrance material” is disclosed.
  • the method of patent document 2 dries a granular gel in the air, it requires a long time and a large installation in order to prepare a large amount of materials.
  • Patent Document 3 a slurry containing a fragrance component such as menthol and a polysaccharide is dried to prepare a sheet containing the fragrance component coated with a polysaccharide gel, and this is cut into tobacco. Report that it is added every hour. Since the fragrance
  • the inventors of the present invention incorporated a fragrance-containing sheet having a high fragrance content into a cigarette as a cigarette filler in a small amount (for example, 2 wt% blending ratio). It was noticed that the fragrance distribution may be biased in the rod. In order to improve such a point, the present invention has an object of providing a fragrance-carrying cigarette component that has high fragrance stability and can be uniformly mixed with a cigarette when incorporated in a cigarette. To do.
  • a cigarette constituent member includes a fragrance composition in a sol state containing carrageenan, gellan gum, a polysaccharide selected from the group consisting of a combination of gellan gum and tamarind gum, a fragrance, and water. Then, the cigarette component to which the fragrance composition is applied is cooled to 0 to 40 ° C. to gel the fragrance composition, and then the cigarette component to which the fragrance composition is applied is heated. A fragrance-carrying cigarette constituent member obtained by drying is provided.
  • the heat drying is performed such that the surface temperature of the fragrance composition is maintained at 70 to 100 ° C.
  • the cigarette constituent member is a tobacco filler or a cigarette paper.
  • the tobacco filler is tobacco or sheet tobacco.
  • a cigarette including the fragrance-carrying cigarette constituent member of the present invention.
  • the fragrance-carrying cigarette constituent member of the present invention has high storage fragrance, and evenly mixes the fragrance into the cigarette (more precisely, at the site where the fragrance-carrying cigarette constituent member is incorporated).
  • flavor carrying cigarette structural member of this invention mix
  • flavor content between cigarettes can be suppressed. Also have.
  • the graph which shows the storage fragrance property of the menthol in the tobacco cut which applied the menthol containing composition to the surface The graph which shows the storage fragrance property of the menthol in the cigarette containing the tobacco cut which applied the menthol containing composition to the surface.
  • the graph which shows the storage fragrance property of the menthol in the sheet tobacco which applied the menthol containing composition to the surface The graph which shows the storage fragrance property of the menthol in the cigarette containing the sheet tobacco which applied the menthol containing composition to the surface.
  • the graph which shows the storage fragrance property of the menthol in the cigarette paper which applied the menthol containing composition to the surface The graph which shows the storage fragrance property of the menthol in the cigarette paper which applied the menthol containing composition to the surface.
  • the flavor-carrying cigarette component of the present invention is a surface of a cigarette component comprising a sol-like flavor composition containing carrageenan, gellan gum, a polysaccharide selected from the group consisting of gellan gum and tamarind gum, a flavor, and water. Then, the cigarette component to which the fragrance composition is applied is cooled to 0 to 40 ° C. to gel the fragrance composition, and then the cigarette component to which the fragrance composition is applied is heated and dried. Can be obtained.
  • any fragrance can be used without limitation as long as it is used in smoking articles.
  • Main flavors include menthol, leaf tobacco extract, natural plant flavors (e.g. cinnamon, sage, herbs, chamomile, kuzukusa, sweet tea, clove, lavender, cardamom, clove, nutmeg, bergamot, geranium, honey essence, rose Oil, lemon, orange, cinnamon, caraway, jasmine, ginger, coriander, vanilla extract, spearmint, peppermint, cassia, coffee, celery, cascarilla, sandalwood, cocoa, ylang ylang, fennel, anise, licorice, st john's bread , Plum extract, peach extract, etc.), saccharides (e.g., glucose, fructose, isomerized sugar, caramel, etc.), cocoa (powder, extract, etc.), esters (e.g., isoamyl acetate, linalyl acetate,
  • natural plant flavors
  • the flavor-carrying cigarette component of the present invention comprises a carrageenan, gellan gum, a polysaccharide selected from the group consisting of gellan gum and tamarind gum, and a composition comprising menthol (hereinafter referred to as menthol). And menthol-containing composition) is applied to the cigarette component.
  • menthol menthol-containing composition
  • the fragrance-carrying cigarette constituent member of the present invention is obtained by applying the fragrance composition to the surface of the cigarette constituent member.
  • the menthol-containing composition used in the present invention is in a state of a slurry having fluidity at a heating temperature (for example, 60 to 90 ° C.) as a state before being dried.
  • a heating temperature for example, 60 to 90 ° C.
  • the composition of the menthol-containing composition (slurry) is, for example, 200 to 500 grams of polysaccharide, 1000 to 2500 grams of menthol, and 2 to 10% by weight of an emulsifier solution of 80 to 200 ml per 10 liters of water. it can.
  • the water content of the menthol-containing composition (slurry) is generally 70 to 95% by weight, preferably 80 to 90% by weight.
  • the ratio (weight ratio) between the polysaccharide and menthol in the menthol-containing composition can be 1: 1 to 1:10.
  • the polysaccharide has the property of gelling the aqueous solution upon cooling and fixing and coating the micelle of a fragrance such as menthol.
  • a polysaccharide selected from carrageenan, gellan gum, and a combination of gellan gum and tamarind gum can be used.
  • carrageenan when carrageenan is used as a polysaccharide, other polysaccharides such as gellan gum and tamarind gum may be contained in the menthol-containing composition in a smaller amount than carrageenan.
  • gellan gum is used as a polysaccharide, other polysaccharides such as carrageenan may be included in the menthol-containing composition in a smaller amount than gellan gum.
  • l-menthol can be used as the menthol.
  • a naturally-derived emulsifier such as lecithin, specifically, sun lecithin A-1 (Taiyo Chemical Co., Ltd.) can be used.
  • the slurry of the menthol-containing composition comprises (i) a step of mixing and heating a polysaccharide and water to prepare an aqueous solution of the polysaccharide, and (ii) adding a menthol and an emulsifier to the aqueous solution and kneading and And emulsifying.
  • the step (i) can be performed by adding a small amount of polysaccharide to water and dissolving it with stirring.
  • the heating temperature here can be 60 to 90 ° C., preferably 75 to 85 ° C.
  • the step (ii) is performed by a known emulsification technique using a homogenizer because the slurry of the menthol-containing composition has a viscosity that does not hinder emulsification of about 10,000 ⁇ mPas or less (sol state) at the heating temperature. it can.
  • the menthol-containing composition described above is applied to a cigarette component.
  • it is applied to the surface of a cigarette component.
  • the cigarette constituent member is a constituent member that is disposed at a position that does not contact the smoker's mouth or oral cavity when incorporated into the cigarette, in other words, the cigarette constituent member is a cigarette. It is a structural member that is arranged at a position where, when incorporated, a fragrance such as menthol can be delivered together with mainstream smoke by combustion during smoking.
  • the cigarette constituent member is a tobacco filler or a cigarette paper. More specifically, the tobacco filler is tobacco or sheet tobacco.
  • the method of applying the menthol-containing composition to the cigarette component is not particularly limited as long as the menthol-containing composition (slurry) can be uniformly applied to the cigarette component, and the menthol-containing composition (slurry) is added to the surface of the cigarette component
  • the menthol-containing composition (slurry) may be sprayed on the surface of the cigarette constituent member, or the cigarette constituent member may be immersed in the menthol-containing composition (slurry). Good.
  • the menthol-containing composition (slurry) When applying a slurry of a menthol-containing composition (about 60 to 90 ° C. in a sol state) to the cigarette, the menthol-containing composition (slurry) is directly added to the tobacco surface by a transfer pump, or a cigarette is cut by a nozzle smoker. A method of spraying on the surface can be adopted. Alternatively, application of the menthol-containing composition (slurry) to the tobacco cut may immerse the tobacco in a slurry of the menthol-containing composition.
  • a slurry of menthol composition (about 60 to 90 ° C., sol state)
  • a method of extruding and adding to the surface of the sheet tobacco with a slit feeder, or a coating method using a film applicator or the like can be employed.
  • a technique such as spraying or dipping may be employed in accordance with the same technique as that applied to tobacco.
  • a method of extruding and adding with a slit feeder or a method of applying with a film applicator can be employed.
  • a technique such as spraying or dipping may be employed in accordance with the same technique as that applied to tobacco.
  • the application amount of the slurry of the menthol-containing composition can be 5 to 40 parts by weight, preferably 15 to 25 parts by weight with respect to 100 parts by weight of the cigarette.
  • the application amount of the slurry of the menthol-containing composition can be 50 to 400 parts by weight, preferably 100 to 200 parts by weight, per 100 parts by weight of sheet tobacco.
  • the amount of the menthol-containing composition slurry applied can be 10 to 70 parts by weight, preferably 30 to 50 parts by weight, per 100 parts by weight of tobacco wrapping paper.
  • the cigarette component to which the slurry of the menthol-containing composition is applied has a temperature (0 ° C.) at which the slurry of the menthol-containing composition is sufficiently gelled (40 ° C. or lower) and generally the emulsion does not freeze and break before drying.
  • the temperature is once cooled to 0 to 40 ° C., preferably 0 to 30 ° C., more preferably 15 to 25 ° C.
  • the slurry of the menthol-containing composition before cooling has a temperature of 60 to 90 ° C., preferably 75 to 85 ° C., and is in a sol state.
  • a cigarette constituent member to which a slurry of a menthol-containing composition is applied is applied with a simple air blow or a cold air (eg, 10 ° C.) generated by a spot cooler (eg, suiden SS-25DD-1) for 2 to 3 minutes.
  • a spot cooler eg, suiden SS-25DD-1
  • the pre-cooling is performed by passing a cigarette constituent member to which the slurry of the menthol-containing composition is applied through a refrigerant (for example, 10 ° C.) generated by a cold / hot water generator (chiller, for example, Apiste PCU-1600R). This may be done by contacting the tube for 1-2 minutes.
  • the precooling may be performed by leaving the cigarette constituent member to which the slurry of the menthol-containing composition is applied at room temperature.
  • the polysaccharide aqueous solution used in the present invention can be maintained in a gelled state, even if the temperature is raised, and it does not easily sol even at the temperature at which the gel is transferred. It has the property that it can be performed (see the examples described later). If precooling is performed before drying the slurry of the menthol-containing composition by utilizing such properties, the undried menthol-containing composition after the precooling is contained in a large amount even if the temperature is increased during drying. Saccharides are difficult to sol, and menthol coated with such polysaccharides is particularly difficult to volatilize. Thus, in the present invention, thanks to the preliminary cooling, it becomes possible to expose the menthol-containing composition to heat in the subsequent drying step, and thereby, drying in a short time can be realized.
  • the cigarette constituent member to which the menthol-containing composition is applied can be heated and dried by any heating and drying means such as hot air drying or infrared heat drying.
  • the drying of the menthol-containing composition applied to the cigarette constituent member can be performed so that the sample temperature is kept at 100 ° C. or less, preferably 70 to 100 ° C. in the entire drying process.
  • a drying temperature of preferably 100 ° C. to 130 ° C. can be employed.
  • a drying temperature of 100 to 130 ° C. can be preferably used.
  • sample temperature means the temperature of the surface of the menthol-containing composition in the drying step
  • drying temperature refers to the temperature in the dryer. In the case of hot air drying, the temperature in the dryer is the hot air temperature. The same.
  • the drying includes drying at a drying temperature of 100 ° C. or higher (preferably 100 ° C. to 130 ° C.) over a quarter of the total drying time, with a total drying time of 20 minutes or less, This can be done until the perfume-carrying cigarette component has a moisture content of less than 10%.
  • drying at a drying temperature of 100 ° C. or higher is performed at the time of the initial drying, and then dried at the same temperature as the initial drying temperature or lower than the initial drying temperature (preferably 70 ° C. or higher and lower than 100 ° C.). .
  • the drying temperature may be a constant temperature throughout the entire drying process or may be changed during the drying process after the sample temperature is always 100 ° C. or lower in the entire drying process.
  • the drying is preferably performed by initial drying at a high drying temperature of 100 ° C. or higher and subsequent drying at a low drying temperature of less than 100 ° C.
  • “initial drying” means the initial drying of the drying process using a high temperature of 100 ° C. or higher
  • “late drying” refers to the drying following the initial drying using a low temperature of less than 100 ° C. means.
  • the drying is Initial drying over a quarter of the total drying time at a drying temperature of 100 ° C. or higher, then It is carried out by late drying at a drying temperature of less than 100 ° C. over a quarter of the total drying time, and until the perfume-carrying cigarette component has a predetermined moisture content in a total drying time of 20 minutes or less (specifically Specifically, in the fragrance-carrying cigarette component in which the menthol-containing composition is applied to the sheet cigarette and the cigarette paper until the moisture content is about 12% by weight or less in the fragrance-carrying cigarette component in which the menthol-containing composition is applied to the cigarette, Up to a water content of about 10% by weight or less).
  • the flavor-carrying cigarette component of the present invention has a particularly high menthol content after production, and even after storage. It is possible to maintain the menthol content at a particularly high value.
  • initial drying can be performed at a hot air temperature of, for example, 100 ° C. or higher and 130 ° C. or lower for 4 to 6 minutes
  • late drying is performed at a hot air temperature of, for example, 70 ° C. or higher and lower than 100 ° C. for 4 to 6 minutes. It can be carried out.
  • the amount of hot air can be set to 3 to 20 m / second, for example.
  • the total drying time is 20 minutes or less, preferably 10 to 18 minutes.
  • the conditions for initial drying and late drying can be appropriately set within the above range, for example.
  • the drying temperature during the initial drying may be constant, or may be changed so as to decrease sequentially between 100 ° C. and 130 ° C. Further, the drying temperature during the late drying may be constant, or may be changed so as to sequentially decrease between 70 ° C. and less than 100 ° C.
  • the dryer used in the examples described later has three drying chambers, and the sample is conveyed by the belt conveyor in the order of the first chamber ⁇ the second chamber ⁇ the third chamber. May be used for initial drying (above 100 ° C.) at the same or different temperatures, the third chamber may be used for late drying (below 100 ° C.), or the first chamber may be used for initial drying (above 100 ° C.). ) And the second and third chambers may be used for late drying (less than 100 ° C.) at the same or different temperatures.
  • the drying is preferably performed until the moisture content of the flavor-carrying cigarette component reaches a predetermined moisture content (specifically, about 12% by weight or less in the flavor-carrying cigarette component in which the menthol-containing composition is applied to the tobacco). Until it becomes about 10% by weight or less in the case of a fragrance-carrying cigarette constituent member in which a menthol-containing composition is applied to a sheet tobacco or a cigarette paper.
  • the water content here refers to a value measured by the measurement method described in the examples described later.
  • flavor carrying cigarette structural member of this invention is provided.
  • the cigarette of the present invention has the same configuration as that of a normal cigarette except that the constituent members of the normal cigarette are replaced with the fragrance-carrying cigarette constituent members of the present invention.
  • the cigarette of the present invention is a cigarette engraved with the perfume composition of the present invention, a sheet cigarette applied with the perfume composition of the present invention, or a cigarette applied with the perfume composition of the present invention. Including wrapping paper.
  • the cigarette of the present invention may include a combination of the constituent members of the present invention.
  • a cigarette to which the fragrance composition of the present invention is applied may be combined with a sheet tobacco to which the fragrance composition of the present invention is applied, or a tobacco to which the fragrance composition of the present invention is applied. It may contain a combination of the chopping and the cigarette paper to which the fragrance composition of the present invention is applied.
  • the tobacco engraved with the fragrance composition of the present invention can be formulated so as to occupy 20 to 100% by weight of the total tobacco filler, assuming that the tobacco filler contained in one cigarette is 100% by weight.
  • the sheet tobacco to which the fragrance composition of the present invention is applied can be formulated so as to occupy 10 to 40% by weight of the total tobacco filler when the tobacco filler contained in one cigarette is 100% by weight. .
  • Tobacco engraved with menthol-containing composition (slurry) is cooled by 10 ° C cold air (cold air generator; Suiden SS-25DD-1) until the temperature of the cigarette engraved with menthol-containing composition falls below 20 ° C Once cooled (product temperature measuring instrument; manufactured by Optics Corporation, PT-7LD).
  • the cigarette engraved with the menthol-containing composition is added to the cooled cigarette using a belt conveyor transfer type hot air dryer (hot air temperature condition: 110 ° C., 2.5 minutes ⁇ 100 ° C., 5 minutes ⁇ 80 ° C., 2.5 minutes).
  • hot air temperature condition 110 ° C., 2.5 minutes ⁇ 100 ° C., 5 minutes ⁇ 80 ° C., 2.5 minutes.
  • the flocked tobacco was loosened to prepare “the flavor-carrying tobacco of the present invention”.
  • Tobacco engraved with the menthol-containing composition 1 is designated as “perfume carrying tobacco 1 of the present invention”.
  • Tobacco engraved with the menthol-containing composition 2 is designated as “scented carrying tobacco 2 according to the present invention” and menthol-containing composition 3
  • the applied tobacco cut is referred to as “perfume carrying tobacco cut 3 of the present invention”.
  • the moisture content of the fragrance-carrying cigarettes 1 to 3 of the present invention was 12% by weight to 13% by weight.
  • a cigarette-cut control sample was prepared by adding menthol to a cigarette-cut by a normal method. That is, the tobacco was scented by spraying a perfume (menthol) ethanol solution onto the tobacco. The tobacco was scented so that the amount of menthol was 1.0% by weight per tobacco weight.
  • menthol-containing composition (slurry) (approximately 60 ° C., sol state) was applied as uniformly as possible to sheet tobacco (regenerated tobacco raw material) prepared by the papermaking process. . That is, the menthol-containing composition (slurry) was cast on a sheet tobacco (0.2 mm thickness) with a film applicator, and the slurry of the menthol-containing composition was applied to the sheet tobacco.
  • the menthol-containing composition was applied such that the menthol-containing composition (slurry) was 150 parts by weight with respect to the sheet tobacco (100 parts by weight).
  • Sheet tobacco coated with a menthol-containing composition has a temperature of 20 ° C. or less when the temperature of the menthol-containing composition applied to the sheet tobacco with 10 ° C. cold air (cold air generator; Suiden SS-25DD-1) (Temperature measuring device; manufactured by Optics, PT-7LD).
  • the moisture content of the sheet tobacco coated with the menthol-containing composition was 10 by a belt conveyor transfer type hot air dryer (hot air temperature condition: 110 ° C., 2.5 minutes ⁇ 100 ° C., 5 minutes ⁇ 80 ° C., 2.5 minutes). It was dried until it became about% by weight (see “Measurement of moisture content” described later) to prepare “the flavor-carrying sheet tobacco of the present invention”.
  • the sheet tobacco to which the menthol-containing composition 1 is applied is referred to as “the fragrance-carrying sheet tobacco 1 of the present invention”
  • the sheet tobacco to which the menthol-containing composition 2 is applied is referred to as “the fragrance-carrying sheet tobacco 2 of the present invention”
  • the menthol-containing composition 3 The applied sheet tobacco is referred to as “fragrance-carrying sheet tobacco 3 of the present invention”.
  • the moisture content of the fragrance-carrying sheet tobaccos 1 to 3 of the present invention was 9 to 10% by weight.
  • a control sample of sheet tobacco was obtained by applying the scenting method for ordinary tobacco to sheet tobacco. That is, the sheet tobacco was scented by spraying a fragrance (menthol) ethanol solution onto the sheet tobacco. The sheet tobacco was scented so that the amount of menthol was 5.0% by weight per sheet tobacco weight.
  • menthol fragrance
  • menthol-containing composition (slurry) (about 60 ° C., sol state) was applied to tobacco wrapping paper (basis weight 40 g / m 2, thickness 35 ⁇ m) as uniformly as possible. . That is, the menthol-containing composition (slurry) was applied to the cigarette paper with a thickness of 0.05 mm using a film applicator. Here, the menthol-containing composition was applied to the cigarette paper (100 parts by weight) so that the menthol-containing composition (slurry) was 40 parts by weight.
  • the temperature of the menthol-containing composition coated on the cigarette paper with 10 ° C cold air was applied to the cigarette paper coated with the menthol-containing composition (slurry) (Temperature measuring device; manufactured by Optics, PT-7LD).
  • the moisture content of the cigarette paper coated with the menthol-containing composition was 10 by a belt conveyor transfer type hot air dryer (hot air temperature condition: 110 ° C., 2.5 minutes ⁇ 100 ° C., 5 minutes ⁇ 80 ° C., 2.5 minutes). It was dried until it reached about% by weight (see “Measurement of moisture content” described later) to prepare “cigarette paper of the present invention”.
  • the cigarette paper to which the menthol-containing composition 1 was applied was designated as “the fragrance-carrying cigarette paper 1 of the present invention”, the cigarette paper to which the menthol-containing composition 2 was applied as “the fragrance-bearing cigarette paper 2”, and the menthol-containing composition 3
  • the applied cigarette paper is referred to as “perfume-carrying cigarette paper 3 of the present invention”.
  • the moisture content of the perfume-carrying cigarette papers 1 to 3 of the present invention was 6% to 7% by weight.
  • a cigarette paper control sample was applied to the cigarette paper using the scenting method for ordinary cigarettes. That is, the cigarette paper was scented by spraying an ethanol solution of a fragrance (menthol) on the cigarette paper. The cigarette paper was scented so that the amount of menthol was 1.0% by weight per cigarette paper weight.
  • menthol a fragrance
  • the menthol content of the prepared flavor-carrying cigarette constituent members was measured in order to examine the storage stability of the flavor and the blending uniformity of the flavor. Moreover, the menthol content in mainstream smoke was measured in order to investigate the storage fragrance property of a fragrance
  • Cigarette production and smoking experiment Cigarettes were produced as follows using the flavor-carrying cigarette constituent members of the present invention.
  • Cigarettes were prepared using the prepared flavor-carrying cigarette components in accordance with Mild Seven Super Lights (Japan Tobacco Inc.).
  • cigarettes containing the fragrance-carrying cigarettes of the present invention are prepared using Mild Seven Super Lights product cigarettes as a raw material, and the fragrance-carrying cigarettes of the present invention are prepared for the production of Mild Seven Super Lights. It was created using various materials (wrapping paper, filters, etc.).
  • the cigarette containing the fragrance-carrying sheet cigarette of the present invention is blended with the tobacco for producing Mild Seven Super Lights (85 parts by weight) and the fragrance-carrying sheet cigarette of the present invention (15 parts by weight) to obtain a predetermined filling amount. This was made using various materials (wrapping paper, filters, etc.) from Mild Seven Super Lights products.
  • the cigarette including the flavor-carrying cigarette paper of the present invention was prepared by replacing the cigarette paper of the Mild Seven Super Lights product with the fragrance-carrying cigarette paper of the present invention.
  • the cigarette was adjusted so that the tar values were as uniform as possible.
  • Smoking conditions Smoking experiments were conducted under the standard smoking conditions defined in ISO (2 seconds of smoke absorption (waiting for 58 seconds), smoke absorption capacity of 35 mL, and cigarette shell length of 35 mm (chip paper + 3 mm)). The menthol content in mainstream smoke was measured by extracting the Cambridge filter collection as described above.
  • the cigarette was placed in an accelerated environment for a predetermined period (0th, 7th, 14th, 30th). Further, the menthol content in the cigarette was measured by GC-FID measurement as described above.
  • the result of the perfume carrying tobacco 1 of the present invention is shown as “carrageenan”
  • the result of the perfume carrying tobacco 2 of the present invention is shown as “gellan gum”
  • the perfume carrying tobacco 3 of the present invention Results are shown as “gellan gum + tamarind gum” and control sample results are shown as “control”.
  • the menthol content (% by weight) is determined by the formula: ⁇ measured value of menthol content (mg) / weight of tobacco (mg) ⁇ ⁇ 100.
  • the menthol content of the control sample was about 0.7% by weight at the start of storage (day 0). When this control sample was stored in a 50 ° C. incubator, the menthol content tended to decrease significantly with time.
  • the fragrance-carrying cigarettes 1 to 3 of the present invention have a menthol content of 1.2 to 1.5% by weight at the start of storage (day 0) and are at least 1 even after storage in an accelerated environment at 50 ° C. Good aroma retention was observed during the month.
  • Cigarettes containing “the fragrance-carrying cigarettes 1 to 3 of the present invention” and control cigarettes containing “tobacco control samples” were used to evaluate the storage fragrance retention of menthol in cigarettes. The result is shown in FIG.
  • the cigarette was placed in an accelerated environment for a predetermined period (0 days, 7 days, 14 days, and 30 days), a cigarette using the cigarette time was created, and a smoking experiment was performed.
  • the amount of menthol in mainstream smoke was measured by GC-FID measurement as described above.
  • the result of the cigarette containing the flavor-carrying tobacco stamp 1 of the present invention is shown as “carrageenan”, and the result of the cigarette containing the flavor-carrying tobacco stamp 2 of the present invention is shown as “gellan gum”.
  • the results for cigarettes containing 3 perfume-carrying cigarettes 3 are shown as “gellan gum + tamarind gum”, and the results for cigarettes containing control samples are shown as “control”.
  • the amount of menthol in mainstream smoke [mg / cig] represents the measured value (mg) of the amount of menthol per cigarette.
  • Cigarettes containing tobacco samples of the control sample showed a high amount of menthol in mainstream smoke when using a tobacco sample with a storage period of 0 days, but when using a tobacco sample with a storage period of 7 days, The amount was significantly reduced.
  • the cigarette containing the fragrance-carrying cigarettes 1 to 3 of the present invention showed a good fragrance retention for at least one month even when the cigarettes stored in an accelerated environment of 50 ° C. were used. .
  • a cut sample of menthol-containing sheet (International Publication 2009/142159) is blended in the cigarette at a ratio of 2% by weight, and the sample cigarette is aligned with the tar value. It was created.
  • the amount of menthol in the mainstream smoke of this sample cigarette was 0.4 mg, which is almost equivalent to the cigarette using the flavor-carrying cigarette of the present invention.
  • the cigarette containing the fragrance-carrying cigarette of the present invention can suppress variation in the amount of menthol blended between cigarettes than the cigarette containing the cut menthol-containing sheet as a tobacco filler. It can be seen that menthol can be uniformly mixed in the cigarette rod. Thereby, the cigarette containing the fragrance
  • Sheet cigarettes were placed in an accelerated environment for a predetermined period (0th, 7th, 14th, 30th).
  • the menthol content in the sheet tobacco was measured by GC-FID measurement as described above.
  • the result of the flavor-carrying sheet tobacco 1 of the present invention is shown as “carrageenan”
  • the result of the flavor-carrying sheet tobacco 2 of the present invention is shown as “gellan gum”
  • the flavor-carrying sheet tobacco 3 of the present invention Results are shown as “gellan gum + tamarind gum” and control sample results are shown as “control”.
  • the menthol content (% by weight) is determined by the formula: ⁇ measured value of menthol content (mg) / weight of sheet tobacco (mg) ⁇ ⁇ 100.
  • the menthol content of the control sample was about 3% by weight at the start of storage (day 0).
  • this control sample was stored in a 50 ° C. incubator, the menthol content was remarkably reduced with time, and became almost zero after one week.
  • the fragrance-carrying sheet cigarettes 1 to 3 of the present invention have a menthol content of about 5 to 7% by weight at the start of storage (day 0) and contain menthol even after storage in an accelerated environment of 50 ° C. The amount was relatively large, and good aroma retention was observed.
  • Cigarettes containing the “fragrance-carrying sheet cigarettes 1 to 3 of the present invention” and control cigarettes containing “sheet cigarette control samples” were used to evaluate the storage fragrance retention of menthol in cigarettes. The result is shown in FIG.
  • the sheet tobacco was placed in an accelerated environment for a predetermined period (0 day, 7 days, 14 days, and 30 days), and a sample cigarette using the sheet tobacco was prepared.
  • the amount of menthol in mainstream smoke was measured by GC-FID measurement as described above.
  • the result of the cigarette containing the fragrance-carrying sheet tobacco 1 of the present invention is shown as “carrageenan”, and the result of the cigarette containing the fragrance-carrying sheet tobacco 2 of the present invention is shown as “gellan gum”.
  • the results of the cigarette containing the fragrance-carrying sheet tobacco 3 are shown as “gellan gum + tamarind gum”, and the result of the cigarette containing the control sample is shown as “control”.
  • the amount of menthol in mainstream smoke [mg / cig] represents the measured value (mg) of the amount of menthol per cigarette.
  • the cigarette containing the control sheet cigarette showed the same amount of menthol in the mainstream smoke as the cigarette containing the fragrance-carrying sheet cigarette of the present invention when the sheet cigarette was stored for 0 days. However, when 7-day sheet cigarettes were used, the amount of menthol was almost zero.
  • the cigarette sample containing the fragrance-carrying sheet cigarettes 1 to 3 of the present invention has a relatively large amount of menthol in mainstream smoke even when a sheet cigarette stored in an accelerated environment of 50 ° C. is used. Fragrance was recognized.
  • the menthol-containing sheet cut (International Publication No. 2009/142159) is blended at a rate of 2% by weight in the same manner as described in the section of the above-mentioned fragrance-carrying tobacco. Sample cigarettes were prepared with the values aligned.
  • the cigarette containing the fragrance-carrying sheet tobacco of the present invention can suppress variation in the amount of menthol blended between cigarettes than the cigarette blended with the cut menthol-containing sheet as a tobacco filler. It can be seen that menthol can be uniformly mixed in the cigarette rod. Thereby, the cigarette containing the fragrance-carrying sheet cigarette of the present invention can suppress the variation of the flavor for each cigarette and the variation of the flavor over the cigarette smoking period.
  • the cigarette paper was placed in an accelerated environment for a predetermined period (0th, 7th, 14th, 30th). Further, the menthol content in the cigarette paper was measured by GC-FID measurement as described above.
  • the result of the perfume-carrying cigarette paper 1 of the present invention is shown as “carrageenan”
  • the result of the perfume-carrying cigarette paper 2 of the present invention is shown as “gellan gum”
  • the perfume-carrying cigarette paper 3 of the present invention Results are shown as “gellan gum + tamarind gum” and control sample results are shown as “control”.
  • the menthol content (% by weight) is determined by the formula: ⁇ measured value of menthol content (mg) / weight of sheet tobacco (mg) ⁇ ⁇ 100.
  • the menthol content of the control sample was about 0.7% by weight at the start of storage (day 0).
  • this control sample was stored in a 50 ° C. incubator, the menthol content was remarkably reduced with time, and became almost zero after one week.
  • the fragrance-carrying cigarettes 1 to 3 of the present invention showed a menthol content of about 1 to 4 to 1.7% by weight at the start of storage (day 0), and even after storage in an accelerated environment at 50 ° C.
  • the menthol content was relatively high, and good fragrance retention was observed.
  • Cigarettes containing the “perfume-carrying cigarette papers 1 to 3 of the present invention” and control cigarettes containing “a cigarette paper control sample” were used to evaluate the storage fragrance retention of menthol in cigarettes. The result is shown in FIG.
  • the cigarette paper was placed in an accelerating environment for a predetermined period (0 day, 7 days, 14 days, and 30 days), and a cigarette was prepared using the cigarette paper as described above.
  • the amount of menthol in mainstream smoke was measured by GC-FID measurement as described above.
  • the result of the cigarette containing the fragrance-carrying cigarette paper 1 of the present invention is shown as “carrageenan”, and the result of the cigarette containing the fragrance-carrying cigarette paper 2 of the present invention is shown as “gellan gum”.
  • the results for cigarettes containing the perfume-carrying cigarette paper 3 are shown as “gellan gum + tamarind gum”, and the results for cigarettes containing the control sample are shown as “control”.
  • the amount of menthol [mg / cig] in the mainstream smoke represents a measured value (mg) of the amount of menthol per cigarette.
  • the cigarette containing the cigarette paper of the control sample showed the same amount of menthol in the mainstream smoke as the cigarette containing the fragrance-carrying cigarette paper of the present invention when the cigarette paper having a storage time of 0 days was used. However, when cigarette paper was used for 7 days, the amount of menthol was almost zero.
  • the cigarette containing the fragrance-carrying cigarette papers 1 to 3 of the present invention has a relatively large amount of menthol in the mainstream smoke even when the cigarette paper stored in an accelerated environment at 50 ° C. is used. Sex was recognized.
  • the menthol-containing sheet cut (International Publication No. 2009/142159) is blended at a rate of 2% by weight in the same manner as described in the section of the above-mentioned fragrance-carrying tobacco. Sample cigarettes were prepared with the values aligned.
  • cigarettes containing the fragrance-carrying tobacco wrapping paper of the present invention can suppress variation in the amount of menthol blended between cigarettes, rather than cigarettes containing menthol-containing sheet cuts as cigarette fillers. It can be seen that menthol can be blended uniformly in the cigarette. Thereby, the cigarette containing the fragrance
  • FIGS. 7A and 7B show the results of the carrageenan-containing liquid
  • FIGS. 8A and 8B show the results of the gellan gum-containing liquid
  • FIGS. 9A and 9B show the results of the liquid containing gellan gum and tamarind gum.
  • the carrageenan-containing liquid had a low viscosity up to about 50 ° C., which is the sol-gel transition temperature, when the temperature was lowered to 25 ° C., but the viscosity rapidly increased below the transition temperature. (Gelation).
  • this gel was heated, as shown in FIG. 7B, it did not easily return to the sol even when heated beyond the transition temperature, and the gel state could be maintained.
  • the liquid containing gellan gum and tamarind gum had a low viscosity up to 40 ° C. when the temperature was lowered to 25 ° C., but the viscosity rapidly increased below 35 ° C. (gelation phenomenon).
  • the temperature of this gel was raised, as shown in FIG. 9B, it did not easily return to the sol even when the gelled temperature (35 ° C.) was exceeded, and the gel state was maintained at a considerably high temperature.

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Botany (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Fats And Perfumes (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
PCT/JP2013/072774 2012-08-31 2013-08-26 香料担持シガレット構成部材およびそれを含むシガレット WO2014034619A1 (ja)

Priority Applications (5)

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EP13833905.6A EP2891409B1 (en) 2012-08-31 2013-08-26 Fragrance-carrying cigarette constituent member and cigarette containing same
CN201910561087.2A CN110279140B (zh) 2012-08-31 2013-08-26 担载香料的香烟构成构件及含有其的香烟
RU2015111175/12A RU2587075C1 (ru) 2012-08-31 2013-08-26 Ароматонесущий компонент сигареты и содержащая его сигарета
JP2014533001A JP5934799B2 (ja) 2012-08-31 2013-08-26 香料担持シガレット構成部材およびそれを含むシガレット
CN201380045426.2A CN104582512A (zh) 2012-08-31 2013-08-26 担载香料的香烟构成构件及含有其的香烟

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105876852A (zh) * 2016-06-13 2016-08-24 云南巴菰生物科技有限公司 一种热感持香滤棒的生产方法
CN110693064A (zh) * 2019-11-20 2020-01-17 湖北中烟工业有限责任公司 白肋烟的处理料液及处理方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111500366B (zh) * 2020-05-07 2023-06-09 云南中烟工业有限责任公司 一种载香凝脂的制备方法和系统
WO2022138260A1 (ja) 2020-12-24 2022-06-30 日本たばこ産業株式会社 たばこ組成物、たばこ含有セグメント、非燃焼加熱型香味吸引器具、及び非燃焼加熱型香味吸引システム
JPWO2022138263A1 (ru) 2020-12-24 2022-06-30
CN113455699A (zh) * 2021-07-12 2021-10-01 河南中烟工业有限责任公司 一种香气逐口释放量均匀的加热卷烟

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0928366A (ja) 1995-07-24 1997-02-04 Japan Tobacco Inc シガレット
JPH11509566A (ja) 1995-07-07 1999-08-24 ブリティッシュ−アメリカン・タバコ・カンパニー・リミテッド 芳香剤の安定化
JP2007023065A (ja) * 2005-07-12 2007-02-01 Sanei Gen Ffi Inc 精油含有組成物
WO2009142159A1 (ja) 2008-05-19 2009-11-26 日本たばこ産業株式会社 シガレット用香料含有材料、その製造方法およびシガレット
WO2012118032A1 (ja) * 2011-03-02 2012-09-07 日本たばこ産業株式会社 喫煙物品用香料含有シートの製造方法、該方法により製造される喫煙物品用香料含有シート、およびそれを含む喫煙物品

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6174567A (ja) * 1984-09-19 1986-04-16 日本たばこ産業株式会社 タバコ用香喫味改善剤
GB9605117D0 (en) * 1996-03-07 1996-05-08 British American Tobacco Co Smokable filler material for smoking articles
CN1082356C (zh) * 1999-04-07 2002-04-10 颐中烟草(集团)有限公司 向烟粉中均匀掺兑木浆纤维制备烟草薄片的方法
EP1252831A3 (en) * 2001-04-26 2004-01-21 Givaudan SA Particles for tobacco products
CN1960648A (zh) * 2003-11-07 2007-05-09 美国无烟烟草制品公司 烟草组合物
US8646463B2 (en) * 2005-08-15 2014-02-11 Philip Morris Usa Inc. Gravure-printed, banded cigarette paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11509566A (ja) 1995-07-07 1999-08-24 ブリティッシュ−アメリカン・タバコ・カンパニー・リミテッド 芳香剤の安定化
JPH0928366A (ja) 1995-07-24 1997-02-04 Japan Tobacco Inc シガレット
JP2007023065A (ja) * 2005-07-12 2007-02-01 Sanei Gen Ffi Inc 精油含有組成物
WO2009142159A1 (ja) 2008-05-19 2009-11-26 日本たばこ産業株式会社 シガレット用香料含有材料、その製造方法およびシガレット
WO2012118032A1 (ja) * 2011-03-02 2012-09-07 日本たばこ産業株式会社 喫煙物品用香料含有シートの製造方法、該方法により製造される喫煙物品用香料含有シート、およびそれを含む喫煙物品

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2891409A4

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105876852A (zh) * 2016-06-13 2016-08-24 云南巴菰生物科技有限公司 一种热感持香滤棒的生产方法
CN110693064A (zh) * 2019-11-20 2020-01-17 湖北中烟工业有限责任公司 白肋烟的处理料液及处理方法
CN110693064B (zh) * 2019-11-20 2022-01-14 湖北中烟工业有限责任公司 白肋烟的处理料液及处理方法

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TW201420025A (zh) 2014-06-01
CN110279140B (zh) 2022-11-29
EP2891409B1 (en) 2019-06-12
EP2891409A1 (en) 2015-07-08
EP2891409A4 (en) 2016-04-13
JPWO2014034619A1 (ja) 2016-08-08
CN104582512A (zh) 2015-04-29
JP5934799B2 (ja) 2016-06-15
RU2587075C1 (ru) 2016-06-10

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