WO2014027272A3 - Kompositmaterialien für lithium-schwefel batterien - Google Patents

Kompositmaterialien für lithium-schwefel batterien Download PDF

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Publication number
WO2014027272A3
WO2014027272A3 PCT/IB2013/056393 IB2013056393W WO2014027272A3 WO 2014027272 A3 WO2014027272 A3 WO 2014027272A3 IB 2013056393 W IB2013056393 W IB 2013056393W WO 2014027272 A3 WO2014027272 A3 WO 2014027272A3
Authority
WO
WIPO (PCT)
Prior art keywords
composite materials
carbon composite
sulfur
lithium
electrochemical cells
Prior art date
Application number
PCT/IB2013/056393
Other languages
English (en)
French (fr)
Other versions
WO2014027272A2 (de
Inventor
Alexander Panchenko
Evgueni Klimov
Oliver Gronwald
Klaus Leitner
Peter Przybylski
Original Assignee
Basf Se
Basf (China) Company Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Basf (China) Company Limited filed Critical Basf Se
Priority to EP13829434.3A priority Critical patent/EP2885831A4/de
Priority to CN201380042885.5A priority patent/CN104541391A/zh
Priority to KR1020157006270A priority patent/KR20150043407A/ko
Priority to JP2015527039A priority patent/JP2015531967A/ja
Publication of WO2014027272A2 publication Critical patent/WO2014027272A2/de
Publication of WO2014027272A3 publication Critical patent/WO2014027272A3/de

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/626—Metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Secondary Cells (AREA)

Abstract

Schwefel-Kohlenstoffkompositmaterialien, enthaltend (A) mindestens ein Kohlenstoffkompositmaterial, umfassend (a) ein Verkohlungsprodukt mindestens eines kohlenstoffhaltigen Ausgangsmaterials, und darin eingeschlossen (aa) Partikel mindestens eines elektrisch leitfähigen Additivs, wobei die Partikel ein Aspektverhältnis von mindestens 10 aufweisen, und (B) elementaren Schwefel. Weiterhin ein Verfahren zur Herstellung dieser Schwefel-Kohlenstoffkompositmaterialien, Kathodenmaterialien für elektrochemische Zellen enthaltend die Schwefel-Kohlenstoffkompositmaterialien, entsprechende elektrochemische Zellen sowie die Verwendung von Kohlenstoffkompositmaterialien zur Herstellung von elektrochemischen Zellen.
PCT/IB2013/056393 2012-08-14 2013-08-05 Kompositmaterialien für lithium-schwefel batterien WO2014027272A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP13829434.3A EP2885831A4 (de) 2012-08-14 2013-08-05 Kompositmaterialien für lithium-schwefel batterien
CN201380042885.5A CN104541391A (zh) 2012-08-14 2013-08-05 锂-硫电池组用复合材料
KR1020157006270A KR20150043407A (ko) 2012-08-14 2013-08-05 리튬-황 배터리용 복합 물질
JP2015527039A JP2015531967A (ja) 2012-08-14 2013-08-05 硫黄‐炭素複合材料並びにその製造方法及びその使用方法、カソード材料、電気化学電池及びその使用方法、リチウムイオンバッテリー

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12180398 2012-08-14
EP12180398.5 2012-08-14

Publications (2)

Publication Number Publication Date
WO2014027272A2 WO2014027272A2 (de) 2014-02-20
WO2014027272A3 true WO2014027272A3 (de) 2014-10-30

Family

ID=46829639

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2013/056393 WO2014027272A2 (de) 2012-08-14 2013-08-05 Kompositmaterialien für lithium-schwefel batterien

Country Status (5)

Country Link
EP (1) EP2885831A4 (de)
JP (1) JP2015531967A (de)
KR (1) KR20150043407A (de)
CN (1) CN104541391A (de)
WO (1) WO2014027272A2 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107710463B (zh) * 2015-09-14 2020-11-10 株式会社Lg化学 锂-硫电池用正极、其制造方法以及包含其的锂-硫电池

Families Citing this family (10)

* Cited by examiner, † Cited by third party
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KR20150131652A (ko) * 2014-05-15 2015-11-25 현대자동차주식회사 Li2S를 이용한 복합화된 양극 구조
DE102014210249A1 (de) * 2014-05-28 2015-12-03 Volkswagen Aktiengesellschaft Verfahren zum Herstellen einer Kathode, Kathode, Lithium-Schwefel-Batterie
KR102602322B1 (ko) * 2015-05-21 2023-11-17 쇼오트 아게 리튬-황 배터리용 유리-세라믹 전해질
KR101811500B1 (ko) 2015-12-17 2017-12-22 오씨아이 주식회사 황-탄소 복합체 및 이의 제조방법
JP6872093B2 (ja) 2016-11-28 2021-05-19 エルジー・ケム・リミテッド 金属硫化物ナノ粒子を含むリチウム−硫黄電池用正極活物質及びこの製造方法
KR102363968B1 (ko) 2018-02-23 2022-02-16 주식회사 엘지에너지솔루션 황-탄소 복합체, 그의 제조방법 및 이를 포함하는 리튬 이차전지
KR102328259B1 (ko) 2017-11-16 2021-11-18 주식회사 엘지에너지솔루션 황-탄소 복합체, 그의 제조방법 및 이를 포함하는 리튬 이차전지
WO2019098733A1 (ko) 2017-11-16 2019-05-23 주식회사 엘지화학 황-탄소 복합체, 그의 제조방법 및 이를 포함하는 리튬 이차전지
US11658293B2 (en) 2017-11-16 2023-05-23 Lg Energy Solution, Ltd. Sulfur-carbon composite, preparation method therefor, and lithium secondary battery comprising same
KR102543246B1 (ko) * 2018-07-03 2023-06-14 주식회사 엘지에너지솔루션 황-탄소 복합체, 이를 포함하는 리튬-황 전지용 양극 및 리튬-황 전지

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JP4899396B2 (ja) * 2005-09-28 2012-03-21 住友ベークライト株式会社 炭素材と、これを用いた二次電池用負極材及び非水電解質二次電池
US20110165466A1 (en) * 2010-01-04 2011-07-07 Aruna Zhamu Lithium metal-sulfur and lithium ion-sulfur secondary batteries containing a nano-structured cathode and processes for producing same
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CN101841036A (zh) * 2010-05-26 2010-09-22 耿世达 一种锂离子电池用多元硫纳米碳纤维复合正极材料及制造方法
CN102208608A (zh) * 2011-05-18 2011-10-05 刘剑洪 一种锂离子电池碳负极材料用碳硫复合材料的制备方法

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107710463B (zh) * 2015-09-14 2020-11-10 株式会社Lg化学 锂-硫电池用正极、其制造方法以及包含其的锂-硫电池

Also Published As

Publication number Publication date
WO2014027272A2 (de) 2014-02-20
KR20150043407A (ko) 2015-04-22
EP2885831A4 (de) 2016-04-13
CN104541391A (zh) 2015-04-22
EP2885831A2 (de) 2015-06-24
JP2015531967A (ja) 2015-11-05

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