WO2013151588A1 - Hybrid energy storage systems utilizing redox active organic compounds - Google Patents

Hybrid energy storage systems utilizing redox active organic compounds Download PDF

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Publication number
WO2013151588A1
WO2013151588A1 PCT/US2012/069077 US2012069077W WO2013151588A1 WO 2013151588 A1 WO2013151588 A1 WO 2013151588A1 US 2012069077 W US2012069077 W US 2012069077W WO 2013151588 A1 WO2013151588 A1 WO 2013151588A1
Authority
WO
WIPO (PCT)
Prior art keywords
active material
cathode
anode
energy storage
redox
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/069077
Other languages
English (en)
French (fr)
Inventor
Wei Wang
Wu Xu
Liyu Li
Zhenguo Yang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Memorial Institute Inc
Original Assignee
Battelle Memorial Institute Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute Inc filed Critical Battelle Memorial Institute Inc
Priority to CA2867433A priority Critical patent/CA2867433A1/en
Priority to KR1020147030916A priority patent/KR20150003789A/ko
Priority to AU2012376225A priority patent/AU2012376225A1/en
Priority to CN201280072242.0A priority patent/CN104321924A/zh
Priority to IN7835DEN2014 priority patent/IN2014DN07835A/en
Priority to EP12873686.5A priority patent/EP2834875A1/en
Publication of WO2013151588A1 publication Critical patent/WO2013151588A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • Fig. 1 is a schematic diagram depicting an energy storage system in which the second active material is a solid, according to embodiments of the present invention.
  • FIG. 2 is a schematic diagram depicting an energy storage system in which the second active material is ilowablc, according to embodiments of the present invention.
  • One example of a modified AQ molecule is l,5-bis(2-(2-(2- methoxyethoxy)ethoxy)ethoxy)anthracene-9, 10-dione (abbreviated as 15 D3GAQ h shown in Fig. 3b.
  • 15 D3GAQ h shown in Fig. 3b.
  • the introduction of two triethylene glycol monomethyi ether groups into the AQ molecular structure has a large effect on the solubility, and the resulting molecule is soluble in most polar solvents and nonaqueous electrolytes.
  • Fig. 5b shows the electrochemical cycling performance in. terms of the energy efficiency and the discharge energy density of the hybrid metal organic RFB with 0.25 M 15D3GAQ in 1 .0 M Lil PC solution as the positive electrolyte (i.e., the positive cathode side) and lithium metal as negative electrode, in which an overall energy efficiency of -82% is achieved.
  • the discharge energy density representing the ultimate capability of the ceil to deliver useful energy, is aiso plotted in Fig. 5b. A specific volumetric energy density close to 25 W T is obtained, where the calculation was based on the positive electrolyte volume.
  • the nonaqueous electrolyte preparation and redox Sow ceil assembly were all completed inside a glove box filled with purified argon of moisture and oxygen content less than 1 ppm.
  • the RFB electrolyte was prepared by dissolving TEMPO with LiPF f; in EC:DMC (1 : 1 ) solvent at room temperature with concentrations of 0.5 M TEMPO and 1 .0 M LiPF f ,.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Secondary Cells (AREA)
  • Fuel Cell (AREA)
  • Battery Electrode And Active Subsutance (AREA)
PCT/US2012/069077 2012-04-04 2012-12-12 Hybrid energy storage systems utilizing redox active organic compounds Ceased WO2013151588A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2867433A CA2867433A1 (en) 2012-04-04 2012-12-12 Hybrid energy storage systems utilizing redox active organic compounds
KR1020147030916A KR20150003789A (ko) 2012-04-04 2012-12-12 산화환원 활성 유기 화합물을 이용하는 하이브리드 에너지 저장 시스템
AU2012376225A AU2012376225A1 (en) 2012-04-04 2012-12-12 Hybrid energy storage systems utilizing redox active organic compounds
CN201280072242.0A CN104321924A (zh) 2012-04-04 2012-12-12 利用氧化还原活性有机化合物的混合能量储存体系
IN7835DEN2014 IN2014DN07835A (https=) 2012-04-04 2012-12-12
EP12873686.5A EP2834875A1 (en) 2012-04-04 2012-12-12 Hybrid energy storage systems utilizing redox active organic compounds

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/439,083 2012-04-04
US13/439,083 US9130218B2 (en) 2012-04-04 2012-04-04 Hybrid energy storage systems utilizing redox active organic compounds

Publications (1)

Publication Number Publication Date
WO2013151588A1 true WO2013151588A1 (en) 2013-10-10

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PCT/US2012/069077 Ceased WO2013151588A1 (en) 2012-04-04 2012-12-12 Hybrid energy storage systems utilizing redox active organic compounds

Country Status (8)

Country Link
US (1) US9130218B2 (https=)
EP (1) EP2834875A1 (https=)
KR (1) KR20150003789A (https=)
CN (1) CN104321924A (https=)
AU (1) AU2012376225A1 (https=)
CA (1) CA2867433A1 (https=)
IN (1) IN2014DN07835A (https=)
WO (1) WO2013151588A1 (https=)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10263308B2 (en) 2014-03-24 2019-04-16 Cornell University Solar flow battery
WO2015148357A1 (en) 2014-03-24 2015-10-01 Cornell University Symmetric redox flow battery containing organic redox active molecule
KR101686127B1 (ko) * 2014-09-23 2016-12-13 한국에너지기술연구원 전 유기계 활물질을 포함하는 레독스 흐름전지
KR20160052096A (ko) * 2014-11-04 2016-05-12 고려대학교 산학협력단 산화환원 활성물질을 포함하는 수퍼커패시터용 유기 전해질
CN105679985B (zh) * 2014-11-17 2019-02-01 中国科学院大连化学物理研究所 一种醌多卤化物液流电池
US11050078B2 (en) 2015-01-22 2021-06-29 Battelle Memorial Institute Systems and methods of decoupled hydrogen generation using energy-bearing redox pairs
US11043686B2 (en) 2015-01-22 2021-06-22 Battelle Memorial Institute Systems and methods of long-duration energy storage and regeneration of energy-bearing redox pairs
US11050076B1 (en) 2015-01-22 2021-06-29 Battelle Memorial Institute Flow cell systems, flow cell batteries, and hydrogen production processes
CN104882624A (zh) * 2015-04-17 2015-09-02 大连理工大学 蒽醌液流电池
CN104835962A (zh) * 2015-04-17 2015-08-12 北京理工大学 一种低成本液流电池负极电解液及其制备方法
KR102415325B1 (ko) * 2015-07-23 2022-06-29 삼성에스디아이 주식회사 튜브형 레독스 플로우 전지 시스템
CN106549179B (zh) * 2015-09-21 2019-07-16 中国科学院大连化学物理研究所 一种有机体系锂醌液流电池
FR3042651B1 (fr) * 2015-10-20 2022-02-04 Commissariat Energie Atomique Batterie redox a circulation d'electrolyte fonctionnant avec un compose redox unique
DE102015014828A1 (de) * 2015-11-18 2017-05-18 Friedrich-Schiller-Universität Jena Hybrid-Flow-Zelle zur Speicherung elektrischer Energie und deren Verwendung
US10367222B2 (en) 2016-02-29 2019-07-30 Alliance For Sustainable Energy, Llc Materials for flow battery energy storage and methods of using
KR102157362B1 (ko) * 2017-07-27 2020-09-18 한국에너지기술연구원 하이브리드 레독스 흐름 전지 및 이의 용도
KR20190088161A (ko) 2018-01-18 2019-07-26 이에쓰씨 주식회사 2종의 유기성 활물질을 복합적으로 적용한 전지용 전해액
US11552351B2 (en) * 2018-04-04 2023-01-10 The Chinese University Of Hong Kong Electrical cells and batteries, method for manufacturing the same and method for improving the performances of electrical cells and batteries
JP7044020B2 (ja) * 2018-09-21 2022-03-30 三菱自動車工業株式会社 フロー電池
CN109378510B (zh) * 2018-10-25 2021-03-02 中盐金坛盐化有限责任公司 基于盐穴的水相体系有机液流电池系统
US10826102B1 (en) 2019-05-20 2020-11-03 Creek Channel Inc. Redox flow battery systems including a balance arrangement and methods of manufacture and operation
CN113718272B (zh) * 2020-05-11 2023-08-29 王昱飞 一种制取两碱的方法
US11990659B2 (en) 2020-11-16 2024-05-21 Cougar Creek Technologies, Llc Fe-Cr redox flow battery systems and methods for preparation of chromium-containing electrolyte therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009224141A (ja) * 2008-03-14 2009-10-01 Toyota Central R&D Labs Inc スラリー利用型二次電池
WO2010143634A1 (ja) * 2009-06-09 2010-12-16 シャープ株式会社 レドックスフロー電池
WO2011131959A1 (en) * 2010-04-19 2011-10-27 The Queen's University Of Belfast Redox battery

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102119461B (zh) * 2008-06-12 2016-08-03 麻省理工学院 高能量密度氧化还原液流装置
JP5401389B2 (ja) * 2010-03-31 2014-01-29 株式会社豊田自動織機 アニリン誘導体を含有するリチウムイオン二次電池用の正極活物質、該正極活物質を備えるリチウムイオン二次電池用の正極及び該正極を構成要素として含むリチウムイオン二次電池

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009224141A (ja) * 2008-03-14 2009-10-01 Toyota Central R&D Labs Inc スラリー利用型二次電池
WO2010143634A1 (ja) * 2009-06-09 2010-12-16 シャープ株式会社 レドックスフロー電池
WO2011131959A1 (en) * 2010-04-19 2011-10-27 The Queen's University Of Belfast Redox battery

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
LI, ZHEN ET AL.: "Electrochemical Properties of an All-Organic Redox Flow Battery Using 2,2,6,6-Tetramethyl-1-Piperidinyloxy and N-Methylphthalimide", ELECTROCHEMICAL AND SOLID-STATE LETTERS, vol. 14, no. 1, 2011, pages A171 - 7173, XP055163582 *
WANG, WEI ET AL.: "Anthraquinone with tailored structure for a nonaqueous metal-organic redox flow battery", CHEMICAL COMMUNICATIONS, 2012, vol. 48, no. 5, 28 May 2012 (2012-05-28), pages 6669 - 6671, XP055163586 *

Also Published As

Publication number Publication date
EP2834875A1 (en) 2015-02-11
KR20150003789A (ko) 2015-01-09
CA2867433A1 (en) 2013-10-10
US9130218B2 (en) 2015-09-08
IN2014DN07835A (https=) 2015-04-24
US20130266836A1 (en) 2013-10-10
CN104321924A (zh) 2015-01-28
AU2012376225A1 (en) 2014-10-02

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