WO2013081055A1 - Composition déodorante - Google Patents

Composition déodorante Download PDF

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Publication number
WO2013081055A1
WO2013081055A1 PCT/JP2012/080941 JP2012080941W WO2013081055A1 WO 2013081055 A1 WO2013081055 A1 WO 2013081055A1 JP 2012080941 W JP2012080941 W JP 2012080941W WO 2013081055 A1 WO2013081055 A1 WO 2013081055A1
Authority
WO
WIPO (PCT)
Prior art keywords
copolymer
component
alkyl acrylate
deodorant composition
alkyl
Prior art date
Application number
PCT/JP2012/080941
Other languages
English (en)
Japanese (ja)
Inventor
長嶋　慎一
百合子 尾本
公樹 友松
昌彦 藤山
Original Assignee
ライオン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ライオン株式会社 filed Critical ライオン株式会社
Priority to JP2013547213A priority Critical patent/JP6070571B2/ja
Publication of WO2013081055A1 publication Critical patent/WO2013081055A1/fr
Priority to PH12014501211A priority patent/PH12014501211A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers

Definitions

  • the present invention relates to a deodorant composition.
  • JP 2005-536477 A Japanese National Patent Publication No. 10-500711 Special table 2004-517093 gazette Japanese Patent Laid-Open No. 8-34718 JP-A-2-290810 JP 2010-70553 A JP 2000-86476 A
  • the present invention has been made in view of the above circumstances, has a sufficient sweat suppression effect and its sustainability, and can suppress stickiness, prevent sweating of clothes, and in addition to these, body odor due to sweating
  • An object of the present invention is to provide a deodorant composition having a long lasting deodorizing effect.
  • the present inventors have improved the antiperspirant effect by using an antiperspirant component and a specific anionic polymer in combination, and the antiperspirant effect has been maintained for a long time. It has been found that it can last long, suppress stickiness, and prevent sweating of clothes. Furthermore, it has been found that by adding powder, a deodorant composition that maintains the deodorizing effect of body odor due to perspiration can be obtained, and the present invention has been made.
  • the present invention provides the following deodorant composition.
  • A an antiperspirant component
  • B-1 styrene / alkyl acrylate copolymer ammonium, alkyl acrylate copolymer ammonium, acrylate acrylate amide / hydroxypropyl acrylate / butyl aminoethyl methacrylate copolymer, (alkyl acrylate / diacetone acrylamide) copolymer ⁇ Amodimethicone, (acrylates / alkyl acrylate (C 1-18 ) / alkyl (C 1-8 ) acrylamide) copolymer or salt thereof, and (alkyl acrylate / diacetone acrylamide) copolymer or salt thereof
  • the salt of the (B-1) component (acrylates / alkyl acrylate (C 1-18 ) / alkyl (C 1-8 ) acrylamide) copolymer is (acrylates / alkyl acrylate (C 1-18 ) / alkyl (C 1-8 ) a salt of 2-amino-2-methyl-1-propanol of an acrylamide) copolymer, wherein the salt of the (alkyl acrylate / diacetone acrylamide) copolymer is 2 of the (alkyl acrylate / diacetone acrylamide) copolymer.
  • the deodorant composition according to [1] which is a salt of amino-2-methyl-1,3-propanediol.
  • the blending amount of the component (A) is 1.5 to 10% by weight of the whole composition, and the blending amount of the component (B-1) is 0.3 to 2% by weight of the whole composition [1] or [ 2]
  • (B-2) The deodorant composition according to [4], wherein the component is a (vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer.
  • the blending amount of the component (A) is 1.5 to 10% by mass of the whole composition, and the blending amount of the component (B-2) is 1 to 4% by mass of the entire composition [4] or [5] A deodorant composition as described.
  • the deodorant composition according to [8], wherein the component (C) is a powder selected from talc and magnesia silica.
  • a deodorant composition that has a high antiperspirant effect, an antiperspirant effect that lasts for a long time, suppresses stickiness, and prevents sweating of clothes.
  • a deodorant composition that is excellent in sustainability of the deodorizing effect of body odor due to sweating.
  • the antiperspirant component is not particularly limited as long as it provides an antiperspirant effect.
  • chlorohydroxyaluminum chlorohydroxyaluminum / propylene glycol complex, and chlorohydroxyaluminum / zirconium / glycine complex are preferable, and chlorohydroxyaluminum is more preferable from the viewpoint of antiperspirant effect.
  • the blending amount of component (A) is preferably from 0.1 to 15% by mass, more preferably from 1.5 to 10% by mass, based on the antiperspirant effect. If it is less than 0.1% by mass, the antiperspirant effect, its persistence, and the sweat-suppressing effect may be insufficient. If it exceeds 15% by mass, there is no stickiness, skin irritation or stability of the preparation (no white turbidity). , The lack of precipitation) may worsen.
  • An anionic polymer is mix
  • an anionic polymer (B-1) an acrylic acid polymer or (B-2) a vinyl acetate polymer is preferably used.
  • (B-1) Acrylic acid-based anionic polymer As acrylic acid-based anionic polymer, (styrene / alkyl acrylate) copolymer ammonium (trade name: Yodosol GH41F, manufactured by Akzo Nobel Co., Ltd., 45% by mass), acrylic acid Alkyl copolymer ammonium (trade name: Yodosol GH800F, Akzo Nobel Co., Ltd., 45% by mass), octylamide acrylate / hydroxypropyl acrylate / butylaminoethyl methacrylate copolymer (trade name: AMPHOMER 28-4910, Akzo) Nobel Co., Ltd.), (alkyl acrylate / diacetone acrylamide) copolymer, amodimethicone (compound name: acrylic acid alkyl ester, methacrylic acid alkyl ester, diacetone acrylamide, methacrylic acid co-polymer) Mixtures body and aminoeth
  • (Acrylates / alkyl acrylate (C 1-18 ) / alkyl (C 1-8 ) acrylamide) copolymers or salts thereof include (acrylates / alkyl acrylate (C 1-18 ) / alkyl (C 1-8 ) acrylamide) ) Copolymer AMP (Compound name: 2-Amino-2-methyl-1-propanol salt of acrylic acid / methacrylic acid alkyl ester / alkyl acrylate / acrylamide copolymer, trade name: Plus Size L-9909B; Co., Ltd., 40% by mass) and the like.
  • the (alkyl acrylate / diacetone acrylamide) copolymer AMPD (compound name: acrylic acid alkyl ester / methacrylic acid alkyl ester / diacetone acrylamide / methacrylic acid copolymer) Salt of 2-amino-2-methyl-1,3-propanediol, trade name: Plus Size L-1260, manufactured by Kyoyo Chemical Industry Co., Ltd., 40% by mass), (alkyl acrylate / diacetone acrylamide) copolymer AMP (compound name: 2-amino-2-methyl-1-propanol salt of alkyl acrylate, alkyl methacrylate, diacetone acrylamide, methacrylic acid copolymer, trade name: Plus Size L-53P, Mutual Chemistry Industrial Co., Ltd.
  • (alkyl acrylate / diacetone acrylamide) copolymer compound name: acrylic acid alkyl ester / methacrylic acid alkyl ester / diacetone acrylamide / methacrylic acid copolymer, trade name: plus size L-53, compatible) Chemical Industry Co., Ltd., 50 mass%) and the like.
  • the blending amount of the component (B-1) is preferably 0.1 to 2.5% by mass, more preferably 0.3 to 2% by mass of the whole composition from the viewpoint of antiperspirant effect and prevention of sweating of clothes. is there. If the component (B-1) is less than 0.1% by mass, the antiperspirant effect, the persistence of the antiperspirant effect, and the absence of sweating of the clothes may be insufficient. The feeling of use may decrease, and the stability of the preparation (no separation or precipitation) may decrease.
  • (B-2) Vinyl acetate anionic polymer
  • vinyl acetate anionic polymer (vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer (trade name: RESYN 28-2930, manufactured by Akzo Nobel Co., Ltd.), ( (Vinyl methyl ether / ethyl maleate) copolymer (trade name: Gantrez ES-225, manufactured by ISP Japan), (vinyl methyl ether / butyl maleate) copolymer (Gantrez ES-425, manufactured by ISP Japan), etc.
  • (Vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer is particularly preferable from the viewpoint of antiperspirant effect, its durability and non-sweating, and (vinyl acetate / croton) is particularly preferable from the viewpoint of the stability of the preparation.
  • Acid / vinyl neodecanoate) copolymer and (vinyl methyl ether) Le / butyl maleate) copolymer are preferable.
  • the blending amount of the component (B-2) is preferably 0.1 to 5% by mass, more preferably 1 to 4% by mass from the viewpoint of the antiperspirant effect.
  • the component (B-2) is less than 0.1% by mass, the antiperspirant effect, the persistence of the antiperspirant effect, and the absence of sweating of the clothes may be insufficient. In addition, the stability of the preparation (no cloudiness, no precipitation) may be reduced.
  • an unneutralized commercial product may be converted into a salt using an arbitrary alkaline agent, and a neutralized commercial product may be desalted using an optional acid.
  • Alkaline agents and acids are not particularly limited, but alkali agents such as ammonium, 2-amino-2-methyl-1-propanol (AMP), 2-amino-2-methyl-1,3-propanediol (AMPD), etc. Is preferably used to form a salt, and the acid is preferably desalted using hydrochloric acid, sulfuric acid or the like.
  • AMP 2-amino-2-methyl-1-propanol
  • AMPD 2-amino-2-methyl-1,3-propanediol
  • the optimal blending ratio of the component (A) and the component (B-1) or (B-2) is from the viewpoint of antiperspirant effect, durability of the antiperspirant effect, improvement of prevention of sweating of clothes, and non-stickiness.
  • the ratio of the component (B-1) to the component (A) represented by (B-1) / (A) is 0.02 to 5 by mass ratio, More preferably, it is 0.04 to 0.75.
  • this ratio is less than 0.02, the antiperspirant effect persistence and the sweat sweat inhibiting effect of the clothes are deteriorated, and if it exceeds 5, the antiperspirant effect and its sustainability and the sweat sweat inhibiting effect are deteriorated.
  • the proportions of the components (A) and (B-1) the stability of the preparation over the long term (no cloudiness, no precipitation) is deteriorated. From the viewpoint of stability, 0.02 to 1.0 is preferable, and 0.04 to 0.5 is particularly preferable.
  • the ratio of the component (B-2) to the component (A) represented by (B-2) / (A) is 0.05 to 10 by mass ratio. More preferably, it is 0.1 to 1. If it is less than 0.05, the durability of the antiperspirant effect and the effect of preventing sweating deteriorate, and if it exceeds 10, the antiperspirant effect and its durability, and prevention of sweating of clothes are not sufficient, and the non-stickiness decreases. On the other hand, depending on the proportions of the components (A) and (B-2), the stability of the preparation over the long term (no cloudiness, no precipitation) may deteriorate. From the viewpoint of stability, 0.05 to 1.0 is preferable, and 0.1 to 0.5 is particularly preferable.
  • the antiperspirant effect can be further maintained, and the deodorizing effect of body odor due to perspiration can be obtained over a long period of time.
  • the powder include magnesia silica, silicic anhydride, talc, nylon resin, silicone resin and the like, and these can be used alone or in combination of two or more. Among these, magnesia silica, silicic anhydride, and talc are preferable from the viewpoint of the deodorizing effect and the durability of the antiperspirant effect.
  • the powder preferably has an average particle size of 0.5 to 30 ⁇ m, and more preferably 2 to 25 ⁇ m from the viewpoint of sustaining the deodorizing effect. In the present invention, the average particle size is a value measured with a laser diffraction particle size distribution analyzer (SALD-2200, manufactured by Shimadzu Corporation).
  • the blending amount is preferably 0.1 to 5% by mass, more preferably, from the viewpoint of durability of the antiperspirant effect, durability of the deodorizing effect, particularly durability of the deodorizing effect. 0.5-3 mass%. If the amount is less than 0.1% by mass, the deodorizing effect and the antiperspirant effect may be insufficient. If the amount exceeds 5% by mass, whitening may occur.
  • deodorant composition of the present invention within the range that does not impair the effects of the present invention, in addition to the above-mentioned components, known optional components that are usually blended in the deodorant composition are used alone or in combination of two or more. And it can mix
  • fats and oils for example, fats and oils, waxes, silicone oils, hydrocarbon oils, higher fatty acids, esters, higher alcohols, synthetic ester oils, surfactants, polymer compounds other than the component (B), antioxidants, Pigments, emulsion stabilizers, pH adjusters, astringents other than component (A), preservatives, UV absorbers, chelating agents, moisturizers, thickeners, cooling agents, anti-inflammatory agents, bactericides, amino acids, vitamins And various plant extracts.
  • higher fatty acids examples include stearic acid, linoleic acid, lauric acid, myristic acid, palmitic acid, behenic acid, lanolinic acid, oleic acid, undecylenic acid, and isostearic acid. These may be used alone or in combination of two or more.
  • esters include decyl oleate, butyl stearate, myristyl myristate, hexyl laurate, isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl decyl dimethyloctanoate, diethyl phthalate, glyceryl monostearate, Examples include glyceryl trimyristate and cetyl lactate. These may be used alone or in combination of two or more.
  • nonionic surfactants nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants and the like can be used, and among them, surfactants that do not cause skin diseases are preferable.
  • astringents include zinc sulfate, zinc phenolsulfonate, citric acid, tartaric acid, lactic acid, tannic acid, alum and the like. These may be used alone or in combination of two or more.
  • humectants include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, pentaerythritol, Xylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, sorbitol, xylitol, erythritol, mannitol, maltitol, glucose, fructose, galactose, mannose , Threose, xylose, arabinose, maltose, trehalose, lactose, raffinose, ⁇ -, ⁇ -, ⁇ -cyclodex Phosphorus, pectin
  • High molecular compounds and thickeners include guar gum, locust bean gum, queens seed, galactan, gum arabic, tara gum, pectin, xanthan gum, pullulan, gellan gum, chitin, chitosan, agar, casein, collagen, gelatin, ethyl cellulose, hydroxy Ethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, soluble starch, methyl hydroxypropyl starch, propylene glycol alginate, polyvinyl alcohol (PVA), polyoxyethylene / polyoxypropylene copolymer, (dimethicone / vinyl dimethicone) crosspolymer, Examples thereof include cationized cellulose. These may be used alone or in combination of two or more.
  • the refreshing agent is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include 1-menthol, 1-menthyl glyceryl ether, 1-menthyl lactate and the like. These may be used alone or in combination of two or more.
  • the form of the deodorant composition of the present invention is not particularly limited, and can be applied to cosmetics, pharmaceuticals, quasi drugs, etc., and can be made into a body deodorant composition such as acupuncture.
  • Examples of the dosage form of the deodorant composition of the present invention include various types such as solid, semi-solid, gel, liquid, and cream, and can be prepared based on the conventional method of the dosage form.
  • each component can be mix
  • roll-on, gel, lotion, mist, stick, cream, sheet, deodorant foundation, and the like are preferable.
  • roll-on, gel, lotion, and mist are more preferable from the viewpoint of the durability of the antiperspirant effect and the durability of the deodorizing effect.
  • the composition of the present invention is effective for expression when applied to the skin in a state of being dissolved in moisture, and as a liquid type roll-on, gel, lotion, mist, etc., especially a roll-on type, Gel-type and lotion-type preparations can be suitably used because they can be applied with high adhesion and can exhibit high effects.
  • the deodorant composition of the present invention comprises a deodorant composition for filling a roll-on container, a deodorant product obtained by filling the roll-on container with the deodorant composition, a deodorant composition, and a roll-on container having a coating ball filled with the composition.
  • it is a liquid sweat deodorant product.
  • the roll-on type preparation is contained in a known roll-on container, and the deodorant composition is attached to a ball held by a holder so that a part of the roll-on preparation is exposed in a rotatable manner. Can be applied to the skin. It is also preferable to use a gel type in which the deodorant composition is filled in a bottle container and applied as it is using the container, or a gel type or lotion type in which the deodorant composition is applied using a fingertip or hand.
  • the production method of the deodorant composition of the present invention is not particularly limited, and can be appropriately selected according to the purpose.
  • the components (A) and (B), and the component (C) and optional components as needed, can be ethanol and It can be obtained by mixing with water (the remainder blended so that the entire deodorant composition is 100% by mass).
  • the amount of each component indicates the blended amount in terms of pure content.
  • Examples 1 to 80, Comparative Examples 1 to 9 A deodorant composition (roll-on) having the composition shown in the following table was prepared by a conventional method, and 40 mL was filled in a roll-on container having the following specifications, and the following evaluation was performed. The results are also shown in the table.
  • Example 81 to 98 Examples 26, 31, 32, 40, 41, 45 to 48, 35, 58, 59, 64 to 68, The following deodorant composition (roll-on) containing the same composition was prepared as in the above examples. . As shown below, the composition of the present invention was excellent in the stability of the preparation over a long period of time.
  • Example 99 Deodorant mist (trigger container)
  • a trigger type spray container (average diameter of spray holes: 0.45 mm, trigger: Z-305, manufactured by Mitani Valve Co., Ltd., polyethylene container: PH-100, manufactured by Kamimura Chemical Co., Ltd.) was filled with 100 mL of the sample, and the above And evaluated in the same manner.
  • Example 100 to 102 Deodorant gel (bottle container) A bottle container (TOM-30, with an inner stopper (TO cap nozzle B), manufactured by Takemoto Container Co., Ltd.) was filled with 20 mL of the sample and evaluated in the same manner as described above.
  • Example 103 Deodorant lotion (bottle container) A bottle container (TOMIII-50, equipped with an inner stopper (TO cap nozzle A), manufactured by Takemoto Container Co., Ltd.) was filled with 40 mL of the sample and evaluated in the same manner as described above.

Abstract

L'invention concerne une composition déodorante comprenant (A) un constituant anti-transpiration et (B-1) un polymère anionique de type acide acrylique choisi parmi un copolymère (styrène/acrylate d'alkyle) d'ammonium, un copolymère acrylate d'alkyle d'ammonium, un copolymère acrylate octylamide-acrylate d'hydroxypropyle-méthacrylate de butylaminoéthyle, un copolymère (acrylate d'alkyle/acrylamide de diacétone)-amidométhicone, un copolymère (acrylates/acrylate d'alkyle en (C1-18)/acrylamide d'alkyle en (C1-8)) ou un sel de celui-ci et un copolymère (acrylate d'alkyle/acrylamide de diacétone) ou un sel de celui-ci, le rapport de la teneur du constituant (B-1) à la teneur du constituant (A) (à savoir, (B-1)/(A)) étant de 0,02 à 5 en masse.
PCT/JP2012/080941 2011-11-29 2012-11-29 Composition déodorante WO2013081055A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013547213A JP6070571B2 (ja) 2011-11-29 2012-11-29 デオドラント組成物
PH12014501211A PH12014501211A1 (en) 2011-11-29 2014-05-29 Deodorant composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-260213 2011-11-29
JP2011260213 2011-11-29

Publications (1)

Publication Number Publication Date
WO2013081055A1 true WO2013081055A1 (fr) 2013-06-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/080941 WO2013081055A1 (fr) 2011-11-29 2012-11-29 Composition déodorante

Country Status (4)

Country Link
JP (1) JP6070571B2 (fr)
MY (1) MY165096A (fr)
PH (1) PH12014501211A1 (fr)
WO (1) WO2013081055A1 (fr)

Cited By (8)

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JP2015117239A (ja) * 2013-11-14 2015-06-25 ライオン株式会社 制汗剤組成物
FR3015269A1 (fr) * 2013-12-20 2015-06-26 Oreal Composition comprenant un copolymere acrylique particulier et un polymere fixant amphotere
WO2015092322A3 (fr) * 2013-12-20 2015-08-27 L'oreal Composition comprenant un copolymère acrylique particulier et un polymere fixant choisi parmi les polymères fixants anioniques comprenant un monomère d'acide crotonique, les polymères fixants non ioniques et non siliconés
JP2017105733A (ja) * 2015-12-11 2017-06-15 ライオン株式会社 制汗剤組成物
JP2017226605A (ja) * 2016-06-20 2017-12-28 ライオン株式会社 制汗剤組成物
JP2019156815A (ja) * 2018-03-16 2019-09-19 株式会社マンダム 制汗剤組成物、及び制汗剤
WO2019176265A1 (fr) * 2018-03-16 2019-09-19 株式会社マンダム Composition anti-transpirante et anti-transpirant
JP7393925B2 (ja) 2019-11-25 2023-12-07 花王株式会社 皮膚外用剤

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Publication number Priority date Publication date Assignee Title
JP2015117239A (ja) * 2013-11-14 2015-06-25 ライオン株式会社 制汗剤組成物
FR3015269A1 (fr) * 2013-12-20 2015-06-26 Oreal Composition comprenant un copolymere acrylique particulier et un polymere fixant amphotere
WO2015092322A3 (fr) * 2013-12-20 2015-08-27 L'oreal Composition comprenant un copolymère acrylique particulier et un polymere fixant choisi parmi les polymères fixants anioniques comprenant un monomère d'acide crotonique, les polymères fixants non ioniques et non siliconés
JP2017105733A (ja) * 2015-12-11 2017-06-15 ライオン株式会社 制汗剤組成物
JP2017226605A (ja) * 2016-06-20 2017-12-28 ライオン株式会社 制汗剤組成物
JP2019156815A (ja) * 2018-03-16 2019-09-19 株式会社マンダム 制汗剤組成物、及び制汗剤
WO2019176265A1 (fr) * 2018-03-16 2019-09-19 株式会社マンダム Composition anti-transpirante et anti-transpirant
JP7393925B2 (ja) 2019-11-25 2023-12-07 花王株式会社 皮膚外用剤

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PH12014501211A1 (en) 2014-09-08

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