WO2013073090A1 - 薄膜トランジスタ装置とその製造方法、有機el表示素子、および有機el表示装置 - Google Patents
薄膜トランジスタ装置とその製造方法、有機el表示素子、および有機el表示装置 Download PDFInfo
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- WO2013073090A1 WO2013073090A1 PCT/JP2012/006007 JP2012006007W WO2013073090A1 WO 2013073090 A1 WO2013073090 A1 WO 2013073090A1 JP 2012006007 W JP2012006007 W JP 2012006007W WO 2013073090 A1 WO2013073090 A1 WO 2013073090A1
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- opening
- layer
- drain electrode
- source electrode
- lyophilic
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- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/124—Insulating layers formed between TFT elements and OLED elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
- H01L27/1222—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or crystalline structure of the active layer
- H01L27/1225—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or crystalline structure of the active layer with semiconductor materials not belonging to the group IV of the periodic table, e.g. InGaZnO
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
- H01L27/1259—Multistep manufacturing methods
- H01L27/1292—Multistep manufacturing methods using liquid deposition, e.g. printing
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/484—Insulated gate field-effect transistors [IGFETs] characterised by the channel regions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K19/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic element specially adapted for rectifying, amplifying, oscillating or switching, covered by group H10K10/00
- H10K19/10—Integrated devices, or assemblies of multiple devices, comprising at least one organic element specially adapted for rectifying, amplifying, oscillating or switching, covered by group H10K10/00 comprising field-effect transistors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/121—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
- H10K59/1213—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements the pixel elements being TFTs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
- H10K71/13—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
- H10K71/135—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing
Definitions
- the present invention relates to a thin film transistor device and a manufacturing method thereof, an organic EL display element, and an organic EL display device.
- a thin film transistor device in which a thin film transistor (TFT) element is formed for each subpixel is employed in order to control light emission in units of subpixels.
- TFT thin film transistor
- the organic TFT device includes, for example, a gate electrode 9012a and 9012b, an insulating layer 9013, source electrodes 9014a and 9014b, and a drain electrode (not shown) on a substrate 9011.
- Organic semiconductor layers 9017a and 9017b are sequentially stacked.
- the organic semiconductor layers 9017a and 9017b are formed on the insulating layer 9013 by applying and drying an organic semiconductor ink so as to fill the space between the source electrodes 9014a and 9014b and the drain electrode and to cover them. Is formed.
- a partition wall 9016 is provided on the insulating layer 9013 in order to partition adjacent elements.
- a plurality of openings 9016a to 9016c are opened in the partition wall 9016.
- a connection wiring 9015 connected to the drain electrode is exposed at the bottom of the opening 9016a, and an organic semiconductor layer is formed. Absent.
- the connection wiring 9015 is an electrode for connecting an electrode of a light emitting element formed above the TFT element.
- organic semiconductor layers 9017 a and 9017 b partitioned from each other are formed in the openings 9016 b and 9016 c of the partition wall 9016.
- Each thin film transistor element of an organic TFT device used for a liquid crystal display panel or an organic EL display panel performs light emission control of the light emitting element by inputting a signal to the gate electrodes 9012a and 9012b.
- the ink dropped on the opening 9016b and the ink dropped on the adjacent opening 9016c Can be mixed.
- the organic semiconductor inks 90170a and 90170b are dropped into the openings 9016b and 9016c opened in the partition wall 9016, the organic semiconductor inks 90170a and 90170b are indicated by arrows. May mix with each other.
- the organic semiconductor layers 9017a and 9017b have an undesired thickness, and when semiconductor layers having different components are to be formed, mixing of the ink causes a decrease in transistor performance. .
- the present invention has been made to solve the above-described problems, and when semiconductor ink is dropped into adjacent openings, a thin film transistor device having high quality that suppresses mixing of each other's ink and a method for manufacturing the same
- An object of the present invention is to provide an organic EL display element and an organic EL display device.
- the thin film transistor device according to one embodiment of the present invention has the following characteristics.
- a thin film transistor device includes first and second thin film transistor elements arranged adjacent to each other with a space therebetween, and each thin film transistor element is stacked over a gate electrode and the gate electrode.
- a source electrode and a drain electrode arranged in parallel with each other in a direction crossing the stacking direction, an insulating layer interposed between the gate electrode, the source electrode and the drain electrode, and the source electrode and the drain A gap between the electrode and a semiconductor layer formed on the source electrode and the drain electrode and in close contact with the source electrode and the drain electrode; and an insulating layer formed separately from the source electrode and the drain electrode; A lyophilic layer having higher lyophilicity than the insulating layer.
- a partition wall is formed between the semiconductor layer in the first thin film transistor element and the semiconductor layer in the second thin film transistor element.
- the partition separates at least a part of each of the source and drain electrodes and the lyophilic layer in the first thin film transistor element and at least a part of each of the source and drain electrodes and the lyophilic layer in the second thin film transistor element.
- the surface has liquid repellency.
- an opening formed by surrounding at least a part of each of the source electrode, the drain electrode, and the lyophilic layer in the first thin film transistor element is defined as a first opening, and the source electrode in the second thin film transistor element and
- an opening formed by surrounding at least a part of each of the drain electrode and the lyophilic layer is a second opening
- the first opening The center position of the surface area of the lyophilic layer at the bottom is farther away from the side adjacent to the second opening than the center position of the area at the bottom of the first opening, and the bottom of the second opening is In a plan view, the center position of the surface area of the lyophilic layer at the bottom of the second opening is closer to the side where the first opening is adjacent than the center position of the area at the bottom of the second opening.
- Away on the opposite side characterized in that.
- the center position of the surface area of the lyophilic layer at the bottom of the first opening is smaller than the center position at the bottom of the first opening.
- the central position of the surface area of the lyophilic layer at the bottom of the second opening is at the bottom of the second opening.
- the first opening is arranged away from the side opposite to the side adjacent to the center position.
- the semiconductor ink applied (dropped) is undesirably mixed with the first opening and the second opening at the time of manufacture. The situation can be suppressed.
- the thin film transistor device has high quality by suppressing the mixing of the semiconductor inks when the semiconductor ink is applied (dropped) to each of the adjacent openings.
- FIG. 1 is a schematic block diagram showing a schematic configuration of an organic EL display device 1 according to Embodiment 1 of the present invention.
- 3 is a schematic cross-sectional view showing a part of the configuration of the organic EL display panel 10.
- FIG. (A) is a schematic plan view showing a partial configuration of the TFT substrate 101, and (b) is a schematic cross-sectional view thereof.
- (A) is a process flow diagram which shows the outline of the manufacturing method of the organic electroluminescent display panel 10
- (b) is a process flowchart which shows the outline of the formation method of the TFT substrate 101.
- FIG. 10 is a schematic process diagram showing a part of the manufacturing process of the TFT substrate 101.
- FIG. 10 is a schematic process diagram showing a part of the manufacturing process of the TFT substrate 101.
- FIG. 10 is a schematic process diagram showing a part of the manufacturing process of the TFT substrate 101.
- FIG. 10 is a schematic process diagram showing a part of the manufacturing process of the TFT substrate 101.
- A) is a schematic top view which shows a partial structure of a TFT substrate among the structures of the organic electroluminescence display panel which concerns on Embodiment 2 of this invention
- (b) is Embodiment 3 of this invention.
- It is a schematic plan view which shows a part structure of a TFT substrate among the structures of the organic EL display panel which concerns
- (c) is a TFT substrate among the structures of the organic EL display panel which concerns on Embodiment 4 of this invention.
- FIG. 1 It is a schematic plan view which shows a partial structure.
- A is a schematic top view which shows a partial structure of a TFT substrate among the structures of the organic electroluminescence display panel which concerns on Embodiment 5 of this invention
- (b) is Embodiment 6 of this invention.
- (c) is a TFT substrate among the structures of the organic EL display panel which concerns on Embodiment 7 of this invention.
- FIG. (A) is a schematic top view which shows the opening shape of the opening part prescribed
- (b) is prescribed
- FIG. 6C is a schematic plan view showing the opening shape of the opening defined by the partition wall in the TFT substrate according to Modification 3.
- FIG. (A) is sectional drawing which shows a part of structure of the organic TFT apparatus based on a prior art
- (b) is a process which concerns on application
- a thin film transistor device includes first and second thin film transistor elements arranged adjacent to each other with a space therebetween, and each thin film transistor element is stacked over a gate electrode and the gate electrode.
- a source electrode and a drain electrode arranged in parallel with each other in a direction crossing the stacking direction, an insulating layer interposed between the gate electrode, the source electrode and the drain electrode, and the source electrode and the drain A gap between the electrode and a semiconductor layer formed on the source electrode and the drain electrode and in close contact with the source electrode and the drain electrode; and an insulating layer formed separately from the source electrode and the drain electrode; A lyophilic layer having higher lyophilicity than the insulating layer.
- a partition wall is formed between the semiconductor layer in the first thin film transistor element and the semiconductor layer in the second thin film transistor element.
- the partition separates at least a part of each of the source and drain electrodes and the lyophilic layer in the first thin film transistor element and at least a part of each of the source and drain electrodes and the lyophilic layer in the second thin film transistor element.
- the surface has liquid repellency.
- an opening formed by surrounding at least a part of each of the source electrode, the drain electrode, and the lyophilic layer in the first thin film transistor element is defined as a first opening, and the source electrode in the second thin film transistor element and
- an opening formed by surrounding at least a part of each of the drain electrode and the lyophilic layer is a second opening
- the first opening The center position of the surface area of the lyophilic layer at the bottom is farther away from the side adjacent to the second opening than the center position of the area at the bottom of the first opening, and the bottom of the second opening is In a plan view, the center position of the surface area of the lyophilic layer at the bottom of the second opening is closer to the side where the first opening is adjacent than the center position of the area at the bottom of the second opening.
- Away on the opposite side characterized in that.
- the center position of the surface area of the lyophilic layer at the bottom of the first opening is smaller than the center position at the bottom of the first opening.
- the central position of the surface area of the lyophilic layer at the bottom of the second opening is at the bottom of the second opening.
- the first opening is arranged away from the side opposite to the side adjacent to the center position.
- the semiconductor ink applied (dropped) is undesirably mixed with the first opening and the second opening at the time of manufacture. The situation can be suppressed.
- the thin film transistor device has high quality by suppressing the mixing of the semiconductor inks when the semiconductor ink is applied (dropped) to each of the adjacent openings.
- the insulating layer and the semiconductor layer are formed on the side where the second opening at the bottom of the first opening is adjacent, without any of the source electrode, the drain electrode, and the lyophilic layer. And the insulating layer and the semiconductor layer without any source electrode, drain electrode, or lyophilic layer on the side where the first opening at the bottom of the second opening adjoins. There is a place where there is a direct contact. In the case of adopting such a configuration, when the semiconductor ink is applied to the first opening and the second opening, respectively, due to the relative difference in liquid repellency between the insulating layer and the lyophilic layer.
- the portion having the highest height in the surface profile of the semiconductor ink is separated from the side opposite to the side where the second opening is adjacent in the first opening, and similarly, the first opening is adjacent in the second opening. It is possible to more surely realize the state of moving away from the side opposite to the side. For this reason, mixing of the ink dropped into the first opening and the ink dropped into the second opening can be more reliably suppressed.
- a portion where the insulating layer and the semiconductor layer are in direct contact with each other without the source electrode, the drain electrode, and the lyophilic layer is interposed at the bottom of the first opening. 2
- the opening is also present on the side opposite to the adjacent side, and the bottom of the first opening is viewed in plan, the area of the portion where the insulating layer and the semiconductor layer are in direct contact is the bottom of the first opening ,
- the second opening side is larger than the side opposite to the side adjacent to the second opening, and the source electrode, the drain electrode, and the lyophilic liquid are formed at the bottom of the second opening.
- the area of the portion where the insulating layer and the semiconductor layer are in direct contact with each other at the bottom of the first opening and the bottom of the second opening is defined as described above, it is the highest in the surface profile of the semiconductor ink.
- the second opening portion is separated from the side opposite to the adjacent side, and similarly, in the second opening portion, the first opening portion is separated from the adjacent side. The state can be realized more reliably. For this reason, mixing of the ink dropped into the first opening and the ink dropped into the second opening can be more reliably suppressed.
- the lyophilic layer in each of the first and second thin film transistor elements, is formed of the same material as the source electrode and the drain electrode, It is characterized by being formed in a state of being separated from each other.
- the lyophilic layer is formed of the same material as the source electrode and the drain electrode, so that the lyophilic layer, the source electrode, and the drain are formed in the same process.
- An electrode can be formed and an increase in the manufacturing process can be suppressed. For this reason, an increase in manufacturing cost can be suppressed.
- the performance of the thin film transistor device can be maintained high by separating the lyophilic layer from the source electrode and the drain electrode. it can.
- the center position of the surface area of each of the source electrode and the drain electrode matches the center position of the bottom of the first opening.
- the center position of the surface area of each of the source electrode and the drain electrode matches the center position of the bottom of the first opening.
- the center position of the sum of the surface areas of the source electrode, the drain electrode, and the lyophilic layer is at the bottom of the first opening.
- the sum of the surface areas of the source electrode, the drain electrode, and the lyophilic layer when the second opening is away from the adjacent side from the center position of the area and the bottom of the second opening is viewed in plan.
- the center position of the first opening is away from the center position of the area at the bottom of the first opening on the side opposite to the side where the first opening is adjacent.
- the relative relationship between the lyophilic layer, the source electrode, the drain electrode, and the insulating layer when the semiconductor ink is applied to each of the first opening and the second opening in the manufacturing process Due to the liquid repellency relationship, the ink in the first opening has a surface profile that is biased to the side opposite to the side where the second opening is adjacent, and the ink in the second opening is on the side where the first opening is adjacent. The surface profile is biased to the opposite side.
- the surface area of the source electrode is A S
- the distance from any one point to the center of the area of the source electrode is x S
- D D is the surface area of the drain electrode
- x D is the distance from any one point to the center of the drain electrode area
- a H is the surface area of the lyophilic layer
- the area center of the lyophilic layer is from any one point.
- X H is “the center position of the sum of the surface areas of the source electrode, the drain electrode, and the lyophilic layer” z can be expressed by the following equation.
- the lyophilic layer is in contact with the side surface facing the first opening on the side opposite to the side adjacent to the second opening at the bottom of the first opening. In the bottom of the second opening, the lyophilic layer is in contact with the side surface facing the second opening on the side opposite to the side where the first opening is adjacent. As described above, the above-described effect can be obtained also when the specific arrangement of the lyophilic layer in each of the first opening and the second opening is adopted.
- the liquid repellency on the surface of the partition wall is higher than the contact surface of the insulating layer of each of the first and second thin film transistor elements with the semiconductor layer, and the first and second The liquid repellency of the contact surface between the insulating layer and the semiconductor layer in each of the two thin film transistor elements is higher than that of each surface of the source electrode, the drain electrode, and the lyophilic layer in each of the first and second thin film transistor elements. It is characterized by. By adopting such a configuration, the surface profile of the semiconductor ink in each opening when the semiconductor ink is applied to the inside of each of the first opening and the second opening is more reliably described above. Such a profile can be used. Therefore, mixing of the ink dropped into the first opening and the ink dropped into the second opening can be reliably suppressed.
- the thin film transistor device according to any one of the above aspects of the present invention, a planarization film provided above the thin film transistor device and formed with a contact hole, and the planarization film And a lower electrode formed on the side surface of the planarizing film facing the contact hole and electrically connected to the drain electrode or the source electrode in the first thin film transistor element, and an upper electrode formed above the lower electrode; And an organic light emitting layer interposed between the lower electrode and the upper electrode.
- the effect exerted by the thin film transistor device according to any one aspect of the present invention can be exhibited as it is. Therefore, high display quality is provided.
- An organic EL display device includes the organic EL display element according to an aspect of the present invention. Accordingly, the organic EL display device according to one embodiment of the present invention can have high display quality and can ensure a high yield during manufacturing.
- the method for manufacturing a thin film transistor device according to one embodiment of the present invention includes the following steps.
- the second source electrode and the second drain electrode are juxtaposed in a state of being spaced apart from each other in the direction intersecting the layer thickness direction of the insulating layer.
- a second lyophilic layer having a higher lyophilic property than the insulating layer is formed in a state of being separated from both the second source electrode and the second drain electrode.
- a photosensitive resist material is laminated on the insulating layer so as to cover the first and second source electrodes and the first and second drain electrodes.
- the second The partition wall is such that the center position of the surface area of the second lyophilic layer at the bottom of the opening is away from the side where the first opening is adjacent to the center of the area at the bottom of the second opening. Is formed.
- the first lyophilic layer is disposed on the side opposite to the side adjacent to the second opening at the bottom of the first opening by executing the fifth step.
- the second lyophilic layer is disposed on the side opposite to the side adjacent to the first opening at the bottom of the second opening.
- the source electrode, the drain electrode, and the lyophilic layer are interposed at the bottom of the first opening on the side adjacent to the second opening.
- the insulating layer and the first semiconductor layer are in direct contact with each other, and at the bottom of the second opening, on the side adjacent to the first opening, the source electrode, the drain electrode, and the lyophilic layer
- a partition wall is formed so that there is a portion where the insulating layer and the second semiconductor layer are in direct contact with each other without any interposition.
- the liquid repellency between the insulating layer and the lyophilic layer is determined. Due to the relative difference, the highest point in the surface profile of the semiconductor ink is separated to the side opposite to the side where the second opening is adjacent in the first opening, and similarly, the first opening is the first in the second opening. It is possible to more reliably realize a state in which the opening is separated from the side opposite to the adjacent side. For this reason, mixing of the ink dropped into the first opening and the ink dropped into the second opening can be more reliably suppressed.
- the insulating layer and the first layer are formed without any source electrode, drain electrode, or lyophilic layer interposed at the bottom of the first opening.
- the semiconductor layer is in direct contact with the side where the second opening is adjacent to the side where the second opening is adjacent, the insulating layer and the first semiconductor layer are The area of the directly contacting portion is larger on the side of the second opening than on the side opposite to the side on which the second opening is adjacent, with reference to the center position at the bottom of the first opening.
- the portion where the insulating layer and the second semiconductor layer are in direct contact with each other without the source electrode, the drain electrode, and the lyophilic layer at the bottom of the portion is opposite to the side where the first opening is adjacent
- the insulating layer and the second half The area where the body layer is in direct contact with the area where the first opening is adjacent to the side opposite to the side where the first opening is adjacent is based on the center position at the bottom of the second opening.
- a partition wall is formed to be large.
- the area of the portion in direct contact between the insulating layer and the semiconductor layer at each of the bottom of the first opening and the bottom of the second opening is defined as described above.
- the portion having the highest height in the surface profile of the semiconductor ink is separated from the side opposite to the side where the second opening is adjacent in the first opening, and similarly, the first opening is adjacent in the second opening. It is possible to more surely realize the state of moving away from the side opposite to the side. For this reason, mixing of the ink dropped into the first opening and the ink dropped into the second opening can be more reliably suppressed.
- the third step includes a sub-step of forming a metal film over the insulating layer and a sub-step of etching the metal film.
- Forming a first source electrode, a first drain electrode, and a first lyophilic layer, and a second source electrode, a second drain electrode, and a second lyophilic layer by performing, It is characterized by.
- the lyophilic layer is formed of the same material as the source electrode and the drain electrode, it is possible to suppress an increase in the number of processes, and to obtain the above effect while suppressing an increase in manufacturing cost.
- the liquid repellency on the surface of the partition wall is more than the contact surfaces of the insulating layer with the first and second semiconductor layers.
- the liquid repellency of the contact surface of the insulating layer with the first and second semiconductor layers is increased, and the first and second source electrodes, the first and second drain electrodes, and the first and second It is characterized by being higher than each surface of the lyophilic layer.
- the term “upward” does not indicate the upward direction (vertically upward) in absolute space recognition, but is defined by the relative positional relationship based on the stacking order in the stacking configuration. Further, the term “upward” is applied not only when there is a gap between each other but also when they are in close contact with each other.
- the organic EL display device 1 includes an organic EL display panel 10 and a drive control circuit unit 20 connected thereto.
- the organic EL display panel 10 is a panel using an electroluminescence phenomenon of an organic material, and a plurality of organic EL elements are arranged in a matrix, for example.
- the drive control circuit unit 20 includes four drive circuits 21 to 24 and a control circuit 25.
- the arrangement of the drive control circuit unit 20 with respect to the organic EL display panel 10 is not limited to this.
- the organic EL display panel 10 includes a TFT (thin film transistor) substrate 101.
- the TFT substrate 101 is laminated on a substrate 1011 with gate electrodes 1012a and 1012b spaced from each other, and an insulating layer 1013 is laminated so as to cover the gate electrodes 1012a and 1012b.
- source electrodes 1014a and 1014b are provided corresponding to the gate electrodes 1012a and 1012b, respectively, and as shown in FIG. Drain electrodes 1014c and 1014d are provided at intervals in the axial direction.
- a lyophilic layer 1019a corresponding to the source electrode 1014a and the drain electrode 1014c is formed on the insulating layer 1013, and a lyophilic layer corresponding to the source electrode 1014b and the drain electrode 1014d. 1019b is formed.
- connection wiring 1015 is formed on the insulating layer 1013 with a space leftward in the X-axis direction with respect to the source electrode 1014a. Note that the connection wiring 1015 extends from the source electrode 1014a or the drain electrode 1014c, or is electrically connected to one of them.
- the connection wiring 1015, the source electrode 1014a, the drain electrode 1014c, the lyophilic layer 1019a, the source electrode 1014b, the drain electrode 1014d, and the lyophilic layer 1019b are provided.
- the partition walls 1016 are formed so as to surround each. In other words, as shown in FIG. 3A, of the three openings 1016a, 1016b, and 1016c opened in the partition wall 1016, the opening 1016a on the left side in the X-axis direction where the connection wiring 1015 is exposed at the bottom is a channel. It is a part different from the part and functions as a contact part with the anode.
- an opening 1016b from which the source electrode 1014a, the drain electrode 1014c and the lyophilic layer 1019a are exposed at the bottom, and an opening 1016c from which the source electrode 1014b, the drain electrode 1014d and the lyophilic layer 1019b are exposed at the bottom, respectively, serve as channel portions. It is a functional part.
- the center of each area of the source electrode 1014a and the drain electrode 1014c is the area center (center L 1 ) in the X-axis direction at the bottom of the opening 1016b.
- the center of each area of the source electrode 1014b and the drain electrode 1014d is the center of the area in the X-axis direction (center L) at the bottom of the opening 1016c. 2 ) It is arranged so as to match.
- the area center of the lyophilic layer 1019a in the bottom of the opening 1016b compared X axis direction of the center of area in the bottom of the opening 1016b (center L 1), X on the opposite side to the side where the opening 1016c is adjacent It is spaced apart on the left side in the axial direction.
- Centroid of the lyophilic layer 1019b on the bottom of the opening 1016c compared X axis direction of the center of area in the bottom of the opening 1016c (center L 2), X-axis direction of the side opposite to the side where the opening 1016b is adjacent Disposed on the right side.
- the region corresponding to the source electrode 1014 a and the drain electrode 1014 c and the region corresponding to the source electrode 1014 b and the drain electrode 1014 d are respectively organic.
- Semiconductor layers 1017a and 1017b are stacked.
- the organic semiconductor layer 1017a is formed so as to fill the gap between the source electrode 1014a and the drain electrode 1014c and the source electrode 1014a and the drain electrode 1014c, and is in close contact with the electrodes 1014a and 1014c.
- the organic semiconductor layer 1017b is formed in close contact with the electrodes 1014b and 1014d.
- the organic semiconductor layers 1017a and 1017b are partitioned from each other by a partition wall 1016.
- the exposed portions 1013a and 1013b of the insulating layer 1013 shown in FIG. 3B are organic without any intervening source electrodes 1014a and 1014b, drain electrodes 1014c and 1014d, and lyophilic layers 1019a and 1019b.
- the semiconductor layers 1017a and 1017b are in direct contact (see FIG. 2).
- a passivation film 1018 is laminated so as to cover the organic semiconductor layers 1017a and 1017b and the insulating layer 1013. However, the portion corresponding to the connection wiring 1015 is opened.
- the TFT substrate 101 of the organic EL display panel 10 according to the present embodiment has the above-described configuration.
- the TFT substrate 101 is covered with a planarizing film 102.
- a contact hole 102 a is opened on the connection wiring 1015.
- the contact hole 102a communicates with the opening 1016a in the TFT substrate 101.
- an anode 103 On the main surface of the planarizing film 102, an anode 103, a transparent conductive film 104, and a hole injection layer 105 are sequentially stacked.
- the anode 103, the transparent conductive film 104, and the hole injection layer 105 are also formed along the side surface of the planarization film 102 facing the contact hole 102a.
- the anode 103 is in contact with the connection wiring 1015 and is electrically It is connected to the.
- a bank 106 is formed on the hole injection layer 105 so as to surround a portion corresponding to a light emitting portion (subpixel).
- a hole transport layer 107, an organic light emitting layer 108, and an electron transport layer 109 are sequentially stacked.
- a cathode 110 and a sealing layer 111 are sequentially stacked so as to cover the electron transport layer 109 and the exposed surface of the bank 106, and a CF (color filter) substrate 113 is disposed so as to face the sealing layer 111.
- the adhesive layer 112 is filled in between and bonded to each other.
- the CF substrate 113 is configured by forming a color filter 1132 and a black matrix 1133 on the lower main surface in the Z-axis direction of the substrate 1131.
- each part can be formed using the following materials.
- the substrate 1011 is, for example, a glass substrate, a quartz substrate, a silicon substrate, molybdenum sulfide, copper, zinc, aluminum, stainless steel, magnesium, iron, nickel, gold, silver or other metal substrate, a gallium arsenide based semiconductor substrate, A plastic substrate or the like can be used.
- thermoplastic resin such as polyethylene, polypropylene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer (EVA), cyclic polyolefin, modified polyolefin, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyamide, polyimide (PI), Polyamideimide, polycarbonate, poly- (4-methylbenten-1), ionomer, acrylic resin, polymethyl methacrylate, acrylic-styrene copolymer (AS resin), butadiene-styrene copolymer, polio copolymer (EVOH) ), Polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate (PEN), precyclohexane terephthalate (PCT), polyethers, polyether ketones Polyethers
- Gate electrodes 1012a and 1012b are not particularly limited as long as they are conductive materials, for example.
- Specific materials include, for example, chromium, aluminum, tantalum, molybdenum, niobium, copper, silver, gold, platinum, platinum, palladium, indium, nickel, neodymium, or an alloy thereof, or zinc oxide or tin oxide.
- Conductive metal oxides such as indium oxide and gallium oxide or indium tin complex oxide (hereinafter abbreviated as “ITO”), indium zinc complex oxide (hereinafter abbreviated as “IZO”), aluminum zinc complex oxide (AZO), conductive metal composite oxides such as gallium zinc composite oxide (GZO), or conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene, and acids such as hydrochloric acid, sulfuric acid, sulfonic acid, etc.
- ITO indium oxide and gallium oxide or indium tin complex oxide
- IZO indium zinc complex oxide
- AZO aluminum zinc complex oxide
- GZO gallium zinc composite oxide
- conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene, and acids such as hydrochloric acid, sulfuric acid, sulfonic acid, etc.
- Lewis acids such as phosphorus hexafluoride, arsenic pentafluoride, iron chloride, Those obtained by adding a dopant such as a halogen atom, sodium, metal atom such as potassium, such as iodine, or the like dispersed conductive composite material of carbon black or metal particles.
- a dopant such as a halogen atom, sodium, metal atom such as potassium, such as iodine, or the like dispersed conductive composite material of carbon black or metal particles.
- a polymer mixture containing fine metal particles and conductive particles such as graphite may be used. These may be used alone or in combination of two or more.
- Insulating layer 1013 functions as a gate insulating layer and is not particularly limited as long as it is an insulating material, for example, and any known organic material or inorganic material can be used.
- an acrylic resin for example, an acrylic resin, a phenol resin, a fluorine resin, an epoxy resin, an imide resin, a novolac resin, or the like can be used.
- inorganic materials include silicon oxide, aluminum oxide, tantalum oxide, zirconium oxide, cerium oxide, zinc oxide, cobalt oxide and other metal oxides, silicon nitride, aluminum nitride, zirconium nitride, cerium nitride, zinc nitride, Examples thereof include metal nitrides such as cobalt nitride, titanium nitride, and tantalum nitride, and metal composite oxides such as barium strontium titanate and lead zirconium titanate. These can be used in combination of 1 species or 2 species or more.
- ODTS OTS ⁇ HMDS ⁇ PTS surface treatment agent
- Source electrodes 1014a and 1014b and drain electrodes 1014c and 1014d can be formed using the above materials for forming the gate electrodes 1012a and 1012b.
- Organic semiconductor layers 1017a and 1017b are not particularly limited as long as they have, for example, semiconductor characteristics and are soluble in a solvent.
- the passivation film 1018 can be formed using, for example, a water-soluble resin such as polyvinyl alcohol (PVA), a fluorine resin, or the like.
- PVA polyvinyl alcohol
- Planarizing film 102 is formed using an organic compound such as polyimide, polyamide, or acrylic resin material.
- the anode 103 is made of a metal material containing silver (Ag) or aluminum (Al). In the case of the organic EL display panel 10 according to this embodiment of the top emission type, it is preferable that the surface portion has high reflectivity.
- the transparent conductive film 104 is formed using, for example, ITO (Indium Tin Oxide) or IZO (Indium Zinc Oxide).
- the hole injection layer 105 may be formed of, for example, an oxide such as silver (Ag), molybdenum (Mo), chromium (Cr), vanadium (V), tungsten (W), nickel (Ni), iridium (Ir), or PEDOT. It is a layer made of a conductive polymer material such as (mixture of polythiophene and polystyrene sulfonic acid). In the organic EL display panel 10 according to the present embodiment shown in FIG. 2, it is assumed that the hole injection layer 105 made of a metal oxide is formed. In this case, a conductive polymer such as PEDOT is used. Compared to the case where a material is used, the hole has a function of injecting holes into the organic light emitting layer 108 stably or by assisting the generation of holes, and has a large work function.
- an oxide such as silver (Ag), molybdenum (Mo), chromium (Cr), vanadium (V), tungsten (W), nickel
- the hole injection layer 105 is composed of an oxide of a transition metal, a plurality of levels can be obtained by taking a plurality of oxidation numbers. As a result, hole injection is facilitated and the drive voltage is increased. Can be reduced. In particular, it is desirable to use tungsten oxide (WO X ) from the viewpoint of stably injecting holes and assisting the generation of holes.
- WO X tungsten oxide
- the bank 106 is formed using an organic material such as resin and has an insulating property.
- the organic material used for forming the bank 106 include acrylic resin, polyimide resin, and novolac type phenol resin.
- the bank 106 preferably has organic solvent resistance.
- the bank 106 since the bank 106 may be subjected to an etching process, a baking process, or the like during the manufacturing process, the bank 106 should be formed of a highly resistant material that does not excessively deform or alter the process. Is preferred.
- the surface can be treated with fluorine.
- the bank 106 When the bank 106 is formed using a lyophilic material, the difference in lyophilicity / liquid repellency between the surface of the bank 106 and the surface of the light emitting layer 108 is reduced, and the organic light emitting layer 108 is formed. For this reason, it is difficult to selectively hold the ink containing the organic substance in the opening defined by the bank 106.
- the structure of the bank 106 not only a single layer structure as shown in FIG. 2, but also a multilayer structure of two or more layers can be adopted.
- the above materials can be combined for each layer, and an inorganic material and an organic material can be used for each layer.
- the hole transport layer 107 is formed using a polymer compound having no hydrophilic group.
- a polymer compound having no hydrophilic group for example, polyfluorene or a derivative thereof, or a polymer compound such as polyarylamine or a derivative thereof that does not have a hydrophilic group can be used.
- the light-emitting layer 108 has a function of emitting light by generating an excited state when holes and electrons are injected and recombined.
- a material used for forming the organic light emitting layer 108 it is necessary to use a light emitting organic material that can be formed by a wet printing method.
- the oxinoid compound, perylene compound, coumarin compound, azacoumarin compound, oxazole compound, oxadiazole compound, perinone compound, pyrrolopyrrole described in Japanese Patent Publication (JP-A-5-163488) Compound, naphthalene compound, anthracene compound, fluorene compound, fluoranthene compound, tetracene compound, pyrene compound, coronene compound, quinolone compound and azaquinolone compound, pyrazoline derivative and pyrazolone derivative, rhodamine compound, chrysene compound, phenanthrene compound, cyclopentadiene compound, stilbene compound , Diphenylquinone compound, styryl compound, butadiene compound, dicyanomethylenepyran compound, dicyanomethylenethiopyran compound, fluoro Cein compound, pyrylium compound, thiapyrylium compound, seren
- Electron transport layer 109 has a function of transporting electrons injected from the cathode 110 to the light emitting layer 108.
- an oxadiazole derivative (OXD), a triazole derivative (TAZ), a phenanthroline derivative (BCP, Bphen) Etc. are formed.
- the cathode 110 is formed using, for example, ITO (Indium Tin Oxide) or IZO (Indium Zinc Oxide).
- ITO Indium Tin Oxide
- IZO Indium Zinc Oxide
- permeability shall be 80 [%] or more.
- the material used for forming the cathode 110 includes, for example, a layer structure containing an alkali metal, an alkaline earth metal, or a halide thereof, or a layer containing silver in any one of the above layers.
- a structure in which the layers are stacked in this order can also be used.
- the layer containing silver may be formed of silver alone, or may be formed of a silver alloy.
- a highly transparent refractive index adjusting layer can be provided on the silver-containing layer.
- the sealing layer 111 has a function of suppressing exposure of an organic layer such as the light emitting layer 108 to moisture or exposure to air.
- an organic layer such as the light emitting layer 108
- SiN silicon nitride
- SiON silicon oxynitride
- a sealing resin layer made of a resin material such as an acrylic resin or a silicone resin may be provided on a layer formed using a material such as SiN (silicon nitride) or SiON (silicon oxynitride).
- the sealing layer 111 needs to be formed of a light transmissive material.
- the source electrodes 1014a and 1014b and the drain electrodes 1014c and 1014d are arranged in the X-axis direction.
- the centers are arranged so as to coincide with the area centers (centers L 1 and L 2 ) in the X-axis direction of the bottoms of the openings 1016b and 1016c, respectively.
- Each of the source electrodes 1014 a and 1014 b and the drain electrodes 1014 c and 1014 d is in a state where both ends in the X-axis direction are separated from the side surface portion of the partition wall 1016.
- the lyophilic layers 1019a and 1019b are separated from the area centers (centers L 1 and L 2 ) in the X-axis direction at the bottoms of the openings 1016b and 1016c, respectively. It is formed in an (offset) state. Specifically, the lyophilic layer 1019a is formed at the bottom of the opening 1016b and is offset to the left in the X-axis direction. The lyophilic layer 1019b is formed at the bottom of the opening 1016c in the X-axis direction. It is formed in a state offset to the right side.
- the lyophilic layer 1019a is separated from both the source electrode 1014a and the drain electrode 1014c, and abuts against the side surface facing the opening 1016b of the partition wall 1016. Yes. Similarly, the lyophilic layer 1019b is separated from both the source electrode 1014b and the drain electrode 1014d and is in contact with a side surface facing the opening 1016c of the partition wall 1016.
- the center of the sum of the surface areas of the source electrode 1014a, the drain electrode 1014c, and the lyophilic layer 1019a is separated to the left in the X-axis direction with respect to the area center (center L 1 ) in the X-axis direction at the bottom of the opening 1016b.
- the center of the sum of the surface areas of the source electrode 1014b, the drain electrode 1014d, and the lyophilic layer 1019b is separated to the right in the X-axis direction with respect to the area center (center L 2 ) in the X-axis direction at the bottom of the opening 1016c. Will be.
- the exposed area of the insulating layer 1013 at the right side in the X-axis direction at the bottom of the opening 1016b is on the right side at the bottom portion of the opening 1016c at the left side in the X-axis direction. It is larger than that.
- a substrate 1011 serving as a base of the TFT substrate 101 is prepared (step S1). Then, TFT (thin film transistor) elements are formed on the substrate 1011 to form the TFT substrate 101 (step S2).
- a planarizing film 102 made of an insulating material is formed on the TFT substrate 101 (step S3).
- a contact hole 102 a is formed in a portion corresponding to the upper side of the connection wiring 1015 in the TFT substrate 101, and the other portion in the Z-axis direction upper surface is substantially planarized.
- the anode 103 is formed on the planarizing film 102 (step S4).
- the anode 103 is divided and formed by light emitting units (subpixels), and a part thereof is connected to the connection wiring 1015 of the TFT substrate 101 along the side wall of the contact hole 102a. .
- the anode 103 can be formed by, for example, forming a metal film by a sputtering method, a vacuum deposition method, or the like, and then etching in units of subpixels.
- a transparent conductive film 104 is formed so as to cover the upper surface of the anode 103 (step S5). As shown in FIG. 2, the transparent conductive film 104 covers not only the upper surface of the anode 103 but also the side end surface, and also covers the upper surface of the anode 103 in the contact hole 102a. Note that, as described above, the transparent conductive film 104 is formed by forming a film using a sputtering method, a vacuum evaporation method, or the like, and then partitioning into sub-pixel units by etching.
- the hole injection layer 105 is formed on the transparent conductive film 104 (step S6). As shown in FIG. 2, the hole injection layer 105 is formed so as to cover the entire surface of the transparent conductive film 104. However, the hole injection layer 105 may be formed in a state of being divided for each subpixel.
- the metal oxide film is formed using, for example, a gas composed of argon gas and oxygen gas as a gas in the chamber of the sputtering apparatus.
- the total pressure of the gas exceeds 2.7 [Pa] and is 7.0 [Pa] or less, and the ratio of the oxygen gas partial pressure to the total pressure is 50 [%] or more and 70 [%] or less.
- the input power density per target unit area is 1 [W / cm 2 ] or more and 2.8 [W / cm 2 ] or less.
- step S7 a bank 106 that defines each subpixel is formed. As shown in FIG. 2, the bank 106 is stacked on the hole injection layer 105.
- the bank 106 is formed by laminating the material layer of the bank 106 on the hole injection layer 105.
- This material layer is formed by a spin coating method or the like using a material including a photosensitive resin component and a fluorine component, such as an acrylic resin, a polyimide resin, and a novolac type phenol resin.
- a photosensitive resin material a negative photosensitive material (product number: ZPN1168) manufactured by Nippon Zeon can be used.
- the material layer is patterned to form openings corresponding to the respective subpixels. The opening can be formed by arranging a mask on the surface of the material layer, performing exposure, and then developing.
- a hole transport layer 107, an organic light emitting layer 108, and an electron transport layer 109 are sequentially stacked in each recess defined by the bank 106 on the hole injection layer 105 (steps S8 to S10).
- the hole transport layer 107 is formed by baking a film made of an organic compound, which is a constituent material, by a printing method.
- the organic light emitting layer 108 is formed by baking after being formed by a printing method.
- the cathode 110 and the sealing layer 111 are sequentially laminated on the electron transport layer 109 (steps S11 and S12). As shown in FIG. 2, the cathode 110 and the sealing layer 111 are formed so as to cover the top surface of the bank 106, and are formed on the entire surface.
- an adhesive resin material is applied on the sealing layer 111, and a previously prepared CF (color filter) panel is joined (step S13).
- the CF panel 113 bonded by the adhesive layer 112 has a color filter 1132 and a black matrix 1133 formed on the lower surface of the substrate 1031 in the Z-axis direction.
- the organic EL display panel 10 as an organic EL display element is completed.
- the organic EL display is subjected to an aging process.
- the display device 1 is completed.
- the aging process is performed, for example, by energizing the hole injectability before the process until the hole mobility becomes 1/10 or less. Specifically, the aging process is more than the luminance in actual use.
- the energization process is executed for a predetermined time so that the luminance is three times or less.
- gate electrodes 1012a and 1012b are formed on the main surface of the substrate 1011 (step S21 in FIG. 4B). Regarding the formation of the gate electrodes 1012a and 1012b, a method similar to the method of forming the anode 103 can be used.
- an insulating layer 1013 is formed so as to cover the gate electrodes 1012a and 1012b and the substrate 1011 (step S22 in FIG. 4B).
- source electrodes 1014a and 1014b and drain electrodes 1014c and 1014d as well as connection wiring 1015 and lyophilic layers 1019a and 1019b are formed on the main surface of the insulating layer 1013 (FIG. 5C).
- Step S23 of 4 (b) the source electrodes 1014a and 1014b are arranged so that the lyophilic layers 1019a and 1019b are arranged as described above (see FIG. 3A) in relation to the partition wall 1016 formed in a later step.
- the positions of the lyophilic layers 1019a and 1019b with respect to the drain electrodes 1014c and 1014d are defined.
- an exposed portion 1013a of the insulating layer 1013 is formed on the right side in the X-axis direction of the source electrode 1014a and the drain electrode 1014c, and an exposed portion of the insulating layer 1013 is on the left side in the X-axis direction of the source electrode 1014b and the drain electrode 1014d. 1013b is formed.
- the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, and the connection wiring 1015 and the lyophilic layers 1019a and 1019b are formed by first a sub-process of forming a metal film over the entire surface of the insulating layer 1013, and etching. Can be executed through a sub-process for dividing each. That is, in this embodiment mode, the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, and the lyophilic layers 1019a and 1019b are formed using the same material.
- the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, the connection wiring 1015, the lyophilic layers 1019a and 1019b, and the exposed portions 1013a and 1013b of the insulating layer 1013 are covered.
- a photosensitive resist material film 10160 for forming the partition wall 1016 is deposited (step S24 in FIG. 4B).
- a mask 501 is placed on the deposited photosensitive resist material film 10160, and mask exposure and patterning are performed (step S25 in FIG. 4B).
- windows 501a, 501b, 501c, and 501d are formed in portions where the partition wall 1016 is to be formed.
- the partition wall 1016 is not formed in the mask 501 except for the region where the window portions 501a, 501b, 501c, and 501d are opened. The part is opened.
- the partition wall 1016 shown in FIG. 6C can be formed (step S26 in FIG. 4B).
- the partition wall 1016 defines a plurality of openings including the openings 1016a, 1016b, and 1016c.
- the opening 1016a surrounds the connection wiring 1015 at the bottom
- the opening 1016b surrounds the source electrode 1014a and the drain electrode 1014c (not shown in FIG. 6C) and the lyophilic layer 1019a at the bottom.
- the opening 1016c surrounds the source electrode 1014b and the drain electrode 1014d (not shown in FIG. 6C) and the lyophilic layer 1019b at the bottom.
- the lyophilic layers 1019a and 1019b are separated from any of the source electrodes 1014a and 1014b and the drain electrodes 1014c and 1014d (not shown in FIG. 6C).
- One end of the lyophilic layers 1019a and 1019b is in contact with the side surface of the partition wall 1016.
- organic semiconductor inks 10170a and 10170b for forming the organic semiconductor layers 1017a and 1017b are applied to the openings 1016b and 1016c defined by the partition wall 1016 (FIG. 7).
- Step S27 of 4 (b) the organic semiconductor ink 10170a applied to the inside of the opening 1016b does not have a symmetrical surface profile in the X-axis direction, but the left side in the X-axis direction (indicated by the arrow F 1 illustrated on the organic semiconductor ink 10170a). (Surface direction) of the surface profile.
- the organic semiconductor ink 10170B applied to the inside of the opening 1016c has a surface profile shape biased (the direction of arrow F 2 illustrated on the organic semiconductor ink 10170b) X-axis direction right.
- the highest portions of the surface profiles of the organic semiconductor inks 10170a and 10170b are located away from each other with respect to the area centers (centers L 1 and L 2 ) of the respective openings 1016b and 1016c. It will be.
- the organic semiconductor inks 10170a and 10170b can be prevented from mixing with each other. The reason for this will be described later.
- step S28 in FIG. 4B After drying the organic semiconductor inks 10170a and 10170b (step S28 in FIG. 4B), as shown in FIG. 8A, the organic semiconductor layers 1017a and 1017b with respect to the openings 1016b and 1016c. Can be formed (step S29 in FIG. 4B).
- a passivation film 1018 is formed so as to cover the whole except for the contact region including the opening 1016a (step S30 in FIG. 4B), and the TFT substrate 101 is formed. Complete.
- the organic EL display panel 10 including the TFT substrate 101, and the organic EL display device 1 including the organic EL display panel 10 in the configuration the quality is high for the following reason. In addition, the production yield is high.
- the TFT substrate 101 according to the present embodiment as shown in FIG. 7, when organic semiconductor inks 10170a and 10170b for forming the organic semiconductor layer 1017 are applied (dropped) inside the openings 1016b and 1016c, respectively,
- the height of the surface profile of the organic semiconductor inks 10170a and 10170b is higher on the opposite side of each opening 1016b and 1016c than on the side of the partition wall 1016 interposed between the opening 1016b and the opening 1016c.
- the TFT substrate 101 according to the present embodiment is mixed with the organic semiconductor ink 10170a dropped into the opening 1016b and the organic semiconductor ink 10170b dropped into the opening 1016c at the time of manufacture. Can be reliably suppressed.
- the organic semiconductor layer 1017a formed inside the opening 1016b and the organic semiconductor layer 1017b formed inside the opening 1016c are formed with high accuracy as designed. be able to.
- the thicknesses of the organic semiconductor layers 1017a and 1017b can be controlled with high accuracy.
- the TFT substrate 101 according to the present embodiment, the organic EL display panel 10 including the TFT substrate 101, and the organic EL display device 1 including the organic EL display panel 10 in the configuration include the organic semiconductor layers 1017a and 1017b in the TFT substrate 101. In the formation, the mixing of the organic semiconductor inks 10170a and 10170b is suppressed, and high quality is provided.
- the above effect is obtained by disposing the lyophilic layers 1019a and 1019b at the bottoms of the openings 1016b and 1016c, and the sum of the surface areas of the lyophilic layers 1019a and 1019b, the source electrodes 1014a and 1014b, and the drain electrodes 1014c and 1014d. Between the center position of each of the openings 1016b and 1016c, and the surface area of the partition 1016, the surface of the insulating layer 1013, and the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, and the lyophilic layer 1019a. , 1019b.
- each of the liquid repellency R W , R I and R E is for the organic semiconductor inks 10170a and 10170b.
- the characteristics of the surface of the partition wall 1016, the surface of the insulating layer 1013, and the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, and the lyophilic layers 1019a and 1019b are viewed from the opposite viewpoint, that is, from the viewpoint of wettability. And satisfy the following relationship.
- W W is the wettability of the surface of the partition wall 1016
- W I is the surface wettability of the insulating layer 1013
- W E is the source electrode 1014a, 1014b and the drain electrode 1014c and 1014d and the wettability of the surface of the lyophilic layers 1019a and 1019b.
- the surface of the insulating layer 1013, the surface of the insulating layer 1013, and the lyophobic relationship between the source electrodes 1014a and 1014b, the drain electrodes 1014c and 1014d, and the lyophilic layers 1019a and 1019b are controlled.
- the organic semiconductor ink 10170a When the organic semiconductor inks 10170a and 10170b are applied, the organic semiconductor ink 10170a has a surface profile as shown in FIG. 7, and the organic semiconductor ink 10170a dropped into the opening 1016b and the organic dropped into the opening 1016c. Semiconductor ink 10170b and Mixing that can be effectively suppressed.
- the organic semiconductor layer 1017a and the organic semiconductor layer 1017b can be individually formed based on the design, and mixing of components and a change in layer thickness between each other can be suppressed. Therefore, the high-quality TFT substrate 101, the organic EL display panel 10, and the organic EL display device 1 can be manufactured with a high yield.
- exposed portions 1013a and 1013b of the insulating layer 1013 are formed at the bottoms of the openings 1016b and 1016c as shown in FIG. 3B, and at the bottoms of the openings 1016b.
- the exposed area of the insulating layer 1013 on the right side in the X-axis direction (the area of the exposed portion 1013a) is larger than that on the left side in the X-axis direction, and the insulating layer 1013 is exposed on the left side in the X-axis direction at the bottom of the opening 1016c.
- the area (the area of the exposed portion 1013b) is larger than that on the right side in the X-axis direction. This relationship is also effective in obtaining the above effect.
- FIG. 9 (a) is a diagram corresponding to FIG. 3 (a) in the first embodiment, and other configurations are the same as those in the first embodiment, and thus illustration and description thereof are omitted. .
- source electrodes 2014a, 2014b and drain electrodes 2014c, 2014d are formed at the bottoms of the openings 2016a, 2016b, 2016c defined by the partition wall 2016.
- the lyophilic layer 2019a is further arranged at the bottom of the opening 2016b, and the lyophilic layer 2019b is further arranged at the bottom of the opening 2016c.
- the lyophilic layers 2019a and 2019b are formed using the same material as the source electrodes 2014a and 2014b and the drain electrodes 2014c and 2014d as in the first embodiment.
- the source electrode 2014a and the drain electrode 2014c at the bottom of the opening 2016b, and the source electrode 2014b and the drain electrode 2014d at the bottom of the opening 2016c have a T-shaped planar shape, respectively, and the source electrodes 2014a and 2014b and the drain electrode The portions extending in the respective X-axis directions are opposed to 2014c and 2014d.
- the center of each surface area of the source electrode 2014a and the drain electrode 2014c matches the area center (center L 3 ) in the X-axis direction at the bottom of the opening 2016b, and the lyophilic layer 2019a has the X-axis. It is arranged in a state of being separated toward the left side of the direction.
- each surface area of the source electrode 2014b and the drain electrode 2014d matches the area center (center L 4 ) in the X-axis direction at the bottom of the opening 2016c, and the lyophilic layer 2019b They are arranged in a state of being separated toward the right side in the axial direction.
- the source electrodes 2014a and 2014b and the drain electrodes 2014c and 2014d are arranged in a state of being separated from the side surface facing the openings 2016b and 2014c of the partition wall 2016 in the X-axis direction.
- the lyophilic layer 2019a is in contact with the side surface portion on the left side in the X-axis direction
- the lyophilic layer 2019b is in contact with the side surface portion on the right side in the X-axis direction.
- the area of the exposed portion 2013a of the insulating layer 2013 at the right portion in the X-axis direction at the bottom of the opening portion 2016b before the formation of the organic semiconductor layer is larger than that at the left side. ing.
- the area of the exposed portion 2013b of the insulating layer 2013 on the left side in the X-axis direction is larger than that on the right.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- FIG. 9B is also a diagram corresponding to FIG. 3A in the first embodiment, and the other configurations are the same as those in the first and second embodiments. Is omitted.
- the source electrode 3014a, the drain electrode 3014c, and the lyophilic layer 3019a are arranged at the bottom of the opening 3016b defined by the partition wall 3016.
- a source electrode 3014b, a drain electrode 3014d, and a lyophilic layer 3019b are provided at the bottom of the opening 3016c.
- the lyophilic layers 3019a and 3019b are formed using the same material as the source electrodes 3014a and 3014b and the drain electrodes 3014c and 3014d.
- the source electrodes 3014a and 3014b and the drain electrodes 3014c and 3014d at the bottoms of the openings 3016b and 3016c have comb-like planar shapes, respectively, and the comb tooth portions face each other.
- the center of the sum of the surface areas of the source electrode 3014a and the drain electrode 3014c matches the area center (center L 5 ) in the X-axis direction at the bottom of the opening 3016b, and the lyophilic layer 3019a They are arranged in a state of being separated toward the left side in the axial direction.
- the center of the sum of the surface areas of the source electrode 3014b and the drain electrode 3014d matches the center of the area (center L 6 ) in the X-axis direction at the bottom of the opening 3016c, and the lyophilic layer 3019b is in the X-axis direction. It is arranged in a state of being separated toward the right side.
- each of the source electrode 3014a and the drain electrode 3014c is separated from both the right side in the X-axis direction and the left side in the X-axis direction with respect to the side surface facing the opening 3016b.
- Each of the source electrode 3014b and the drain electrode 3014d is disposed in a state of being separated from both the right side in the X-axis direction and the left side in the X-axis direction with respect to the side surface facing the opening 3016c.
- the lyophilic layer 3019a is in contact with the side surface facing the opening 3016b of the partition wall 3016 on the left side in the X-axis direction, and the lyophilic layer 3019b is in contact with the side surface facing the opening portion 3016c of the partition wall 3016 in the X-axis direction. It touches on the right side.
- the exposed area of the insulating layer 3013 (the area of the exposed portion 3013a) in the portion on the right side in the X-axis direction is lower than that on the left side at the bottom of the opening 3016b before the organic semiconductor layer is formed. Is getting bigger.
- the exposed area of the insulating layer 3013 (the area of the exposed part 3013b) is larger at the left side in the X-axis direction than at the right side.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- the source electrodes 3014a and 3014b and the drain electrodes 3014c and 3014d have a comb shape, and the comb tooth portions face each other, so that the facing region can be made large. The characteristics as a transistor can be improved.
- FIG. 9C is also a diagram corresponding to FIG. 3A in the first embodiment, and the other configurations are the same as those in the first, second, and third embodiments. The description is omitted.
- the openings 4016a, 4016b, and 4016c defined by the partition wall 4016 are both substantially circular in shape and bottom.
- the outer shape of the source electrode 4014a and the drain electrode 4014c arranged at the bottom of the opening 4016b and the outer side of the source electrode 4014b and the drain electrode 4014d arranged at the bottom of the opening 4016c are circular or arcuate.
- an arc-shaped lyophilic layer 4019a is disposed at the bottom of the opening 4016b
- an arc-shaped lyophilic layer 4019b is disposed at the bottom of the opening 4016c.
- Both the source electrode 4014a and the drain electrode 4014c arranged at the bottom of the opening 4016b have their respective area centers in the X-axis direction aligned with the area center (center L 7 ) of the bottom of the opening 4016b.
- the lyophilic layer 4019a is arranged in a state of being separated to the left in the X-axis direction.
- Both the source electrode 4014b and the drain electrode 4014d arranged at the bottom of the opening 4016c have their respective area centers in the X-axis direction aligned with the area center (center L 8 ) of the bottom of the opening 4016c.
- the lyophilic layer 4019b is arranged in a state of being separated to the right in the X-axis direction.
- the center of the sum of the surface area of the source electrode 4014a and the drain electrode 4014c and the lyophilic layer 4019a is directed in the X axis direction the left
- the center of the sum of the surface areas of the source electrode 4014b, the drain electrode 4014d, and the lyophilic layer 4019b is directed to the right in the X-axis direction with respect to the center of the area (center L 8 ) in the X-axis direction at the bottom of the opening 4016c.
- each of the source electrodes 4014a and 4014b and the drain electrodes 4014c and 4014d has both the right side in the X-axis direction and the left side in the X-axis direction with respect to the side surface facing the openings 4016b and 4016c. It is arranged in a state of being separated from the part.
- the lyophilic layer 4019a is in contact with the side surface facing the opening 4016b of the partition wall 4016 on the left side in the X-axis direction
- the lyophilic layer 4019b is in contact with the side surface facing the opening portion 4016c of the partition wall 4016 in the X-axis direction. It touches on the right side.
- the exposed area (exposed portion 4013a) of the insulating layer 4013 at the right side in the X-axis direction at the bottom of the opening 4016b before the formation of the organic semiconductor layer is compared with that on the left side. Is getting bigger.
- the exposed area (exposed portion 4013b) of the insulating layer 4013 in the left portion in the X-axis direction is larger than that on the right side.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- the TFT substrate according to the present embodiment by using the source electrodes 4014a and 4014b and the drain electrodes 4014c and 4014d having the shapes as shown in FIG. Furthermore, the “sneak current” can be reduced.
- FIG. 10 (a) is also a diagram corresponding to FIG. 3 (a) in the first embodiment, and other configurations are the same as those in the first, second, third, fourth, etc. Therefore, illustration and description are omitted.
- the opening shape and bottom shape of the openings 5016a, 5016b, 5016c defined by the partition wall 5016 are the same as those in the first, second, and second embodiments. Like 3, it is a rectangle.
- the outer sides of the source electrode 5014a and the drain electrode 5014c arranged at the bottom of the opening 5016b are substantially square or rectangular, and the outer sides of the source electrode 5014b and the drain electrode 5014d arranged at the bottom of the opening 5016c.
- the shape is also substantially square or rectangular.
- the source electrodes 5014a and 5014b and the drain electrodes 5014c and 5014d arranged at the bottoms of the openings 5016b and 5016c have respective area centers in the X-axis direction, and the area centers (centers) of the bottoms of the openings 5016b and 5016c. L 9 and L 10 ).
- the lyophilic layer 5019a is provided at the bottom of the opening 5016b, and the lyophilic layer 5019b is provided at the bottom of the opening 5016c.
- the lyophilic layer 5019a is disposed in a state of being separated to the left in the X-axis direction with respect to the area center (center L 9 ) at the bottom of the opening 5016b, and the lyophilic layer 5019b is located at the bottom of the opening 5016c. With respect to the center of the area (center L 10 ), it is arranged in a state of being separated to the right in the X-axis direction.
- the lyophilic layer 5019a is in contact with the side surface facing the opening 5016b of the partition wall 5016 only on the left side in the X-axis direction, and is spaced apart vertically in the Y-axis direction.
- the lyophilic layer 5019b is in contact only with the side surface facing the opening 5016c of the partition wall 5016 on the right side in the X-axis direction, and is spaced apart in the vertical direction in the Y-axis direction.
- the source electrode 5014a and the drain electrode 5014c are formed at the bottom of the opening 5016b with respect to the area center (center L 9 ) in the X-axis direction at the bottom of the opening 5016b.
- the center of the sum of the surface areas of the lyophilic layer 5019a is separated toward the left side in the X-axis direction.
- the center of the sum of the surface area of the source electrode 5014b and the drain electrode 5014d and the lyophilic layer 5019b is, It is separated toward the right side in the X-axis direction.
- the exposed area of the insulating layer 5013 (the area of the exposed part 5013a) is larger at the right side in the X-axis direction than at the left side. It has become.
- the exposed area of the insulating layer 5013 (the area of the exposed part 5013b) is larger at the left side in the X-axis direction than at the right side.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- the lyophilic layers 5019a and 5019b are formed using the same material as the source electrodes 5014a and 5014b and the drain electrodes 5014c and 5014d.
- FIG. 10B is also a diagram corresponding to FIG. 3A in the first embodiment, and the other configurations are the same as those in the first, second, third, fourth, and fifth embodiments. Therefore, illustration and description are omitted.
- the opening shape and bottom shape of the opening portions 6016a, 6016b, and 6016c defined by the partition wall 6016 are the same as those in the first, second, and second embodiments. Like 3 and 5, it is a rectangle.
- the drain electrodes 6014c and 6014d arranged at the bottoms of the openings 6016b and 6016c are rectangular.
- the source electrodes 6014a and 6014b arranged at the bottoms of the openings 6016b and 6016c have a U-shaped planar shape so as to surround a part of the drain electrodes 6014c and 6014d, respectively.
- the center of the area in the X-axis direction of the source electrode 6014a arranged at the bottom of the opening 6016b is offset to the left in the X-axis direction with respect to the area center (center L 11 ) in the X-axis direction at the bottom of the opening 6016b. Is arranged.
- Source electrode 6014b which is disposed at the bottom of the opening 6016C is, X-axis direction right to offset the center of the area in the X-axis direction relative to the center of area X-axis direction of the bottom portion of the opening 6016C (center L 12) Is arranged.
- drain electrode 6014c is arranged such that the center of the area in the X-axis direction is offset to the right in the X-axis direction with respect to the area center (center L 11 ) in the X-axis direction at the bottom of the opening 6016b.
- Drain electrode 6014d is the center of the area in the X-axis direction is arranged offset in the X axis direction the left of the area center in the X-axis direction of the bottom portion of the opening 6016C (center L 12).
- a lyophilic layer 6019a is provided at the bottom of the opening 6016b, and a lyophilic layer 6019b is provided at the bottom of the opening 6016c.
- the lyophilic layer 6019a is disposed in a state of being separated to the left in the X-axis direction with respect to the area center (center L 11 ) at the bottom of the opening 6016b, and the lyophilic layer 6019b is located at the bottom of the opening 6016c. With respect to the center of the area (center L 12 ), it is arranged in a state of being separated to the right in the X-axis direction.
- the lyophilic layer 6019a is in contact with the side surface facing the opening 6016b of the partition wall 6016 only on the left side in the X-axis direction, and is spaced apart vertically in the Y-axis direction.
- the lyophilic layer 6019b is in contact with the side surface facing the opening 6016c of the partition wall 6016 only on the right side in the X-axis direction, and is spaced apart in the vertical direction in the Y-axis direction.
- the surface areas of the source electrode 6014a, the drain electrode 6014c, and the lyophilic layer 6019a with respect to the area center (center L 11 ) in the X-axis direction at the bottom of the opening 6016b. are separated toward the left side in the X-axis direction.
- the center of the sum of the surface areas of the source electrode 6014b, the drain electrode 6014d, and the lyophilic layer 6019b is located on the right side in the X-axis direction with respect to the area center (center L 12 ) in the X-axis direction at the bottom of the opening 6016c. It is separated toward.
- the source electrode 6014a is in contact with the side surface facing the opening 6016b at each of the upper and lower portions in the Y-axis direction and the left side in the X-axis direction.
- the drain electrode 6014c is in contact with the side surface facing the opening 6016b on the right side in the X-axis direction and is separated on the left side in the X-axis direction.
- the source electrode 6014b is in contact with the side surface facing the opening 6016c on the upper and lower portions in the Y-axis direction and on the right side in the X-axis direction, and is separated on the left side in the X-axis direction.
- the drain electrode 6014d is in contact with the side surface facing the opening 6016c on the left side in the X-axis direction and is separated on the right side in the X-axis direction.
- the exposed area (exposed portion 6013a) of the insulating layer 6013 at the right portion in the X-axis direction at the bottom of the opening 6016b before the formation of the organic semiconductor layer. Area) is larger than the left side.
- the exposed area of the insulating layer 6013 is larger at the left side in the X-axis direction than at the right side.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- the lyophilic layers 6019a and 6019b are formed using the same material as the source electrodes 6014a and 6014b and the drain electrodes 6014c and 6014d.
- FIG. 10C is also a diagram corresponding to FIG. 3A in the first embodiment, and the other configurations are the same as those in the first, second, third, fourth, fifth, and the like. Since it is the same as that, illustration and description are omitted.
- the opening shape and bottom shape of the openings 7016a, 7016b, and 7016c defined by the partition wall 7016 are the same as those in the first, second, and second embodiments. Like 3, 5 and 6, it is square.
- the source electrode 7014a and the drain electrode 7014c disposed on the bottom of the opening 7016b are substantially square or rectangular, and the source electrode 7014b and the drain electrode 7014d disposed on the bottom of the opening 7016c are also approximately square or rectangular. It is a rectangle.
- lyophilic layers 7019a and 7019b are disposed at the bottoms of the openings 7016b and 7016c. These lyophilic layers 7016a and 7016b are formed using the same material as the source electrodes 7014a and 7014b and the drain electrodes 7014c and 7014d as described above.
- the source electrode 7014b disposed at the bottom of the opening 7016c has an area center offset from the center of the area in the X-axis direction (center L 14 ) at the bottom of the opening 7016c on the left side in the X-axis direction.
- the drain electrode 7014d is offset from the center of the area of the bottom of the opening 7016c in the X-axis direction (center L 14 ) on the right side in the X-axis direction.
- the source electrode 7014b and the drain electrode 7014d and it is arranged me than in the X-axis direction across the line of the center L 14 a relationship axisymmetric.
- a lyophilic layer 7019a is provided at the bottom of the opening 7016b, and a lyophilic layer 7019b is provided at the bottom of the opening 7016c.
- the lyophilic layer 7019a is disposed in a state of being spaced apart to the left in the X-axis direction with respect to the area center (center L 13 ) in the X-axis direction at the bottom of the opening 7016b.
- the bottom portion of the portion 7016c is disposed in a state of being separated to the right in the X-axis direction with respect to the center of the area in the X-axis direction (center L 14 ).
- the lyophilic layer 7019a is in contact with the side surface facing the opening 7016b of the partition wall 7016 on the left side in the X-axis direction and vertically in the Y-axis direction.
- the lyophilic layer 7019b is in contact with the side surface facing the opening 7016c of the partition wall 7016 on the right side in the X-axis direction and up and down in the Y-axis direction.
- the center of the sum of the surface areas of the source electrode 7014b, the drain electrode 7014d, and the lyophilic layer 7019b is the X-axis direction with respect to the area center (center L 14 ) in the X-axis direction at the bottom of the opening 7016c. It is separated toward the right side.
- the exposed area (exposed portion) of the insulating layer 7013 in the right portion in the X-axis direction at the bottom of the opening 7016b before the formation of the organic semiconductor layer. 7013a) is larger than the left side.
- the exposed area of the insulating layer 7013 (the area of the exposed portion 7013b) at the left portion in the X-axis direction is larger than that on the right.
- the same effect as in the first embodiment can be obtained. Further, in the organic EL display panel and the organic EL display device including the TFT substrate according to the present embodiment as well, as described above, high quality and high yield in manufacturing can be realized.
- the lyophilic layers 7019a and 7019b are formed using the same material as the source electrodes 7014a and 7014b and the drain electrodes 7014c and 7014d.
- the insulating layer and the organic semiconductor layer are directly connected to each other at the bottom of the opening, on the other side opposite to the one side, without any source electrode or drain electrode.
- the present invention is not limited to this, but the center position of the sum of the surface areas of the source electrode and the drain electrode at the bottom of one of the two adjacent openings is an opening. If the other opening is arranged away from the center position (center position of the surface area) at the bottom of the part, the other opening is the side adjacent to the bottom of the opening.
- the present invention can also be applied to a configuration in which a portion where both the source electrode and the drain electrode are present exists between the insulating layer and the organic semiconductor layer.
- the TFT substrate used in the organic EL display panel 10 is taken as an example, but the application target is not limited to this.
- it can be applied to a liquid crystal display panel, a field emission display panel, or the like.
- the present invention can be applied to electronic paper.
- each constituent material in the above-described first to seventh embodiments is shown as an example, and can be appropriately changed.
- a top emission type configuration is taken as an example, but a bottom emission type may be adopted. In that case, appropriate changes can be made to each material used and layout design.
- FIG. 11 (a) the opening corresponding to the channel portion is square, or as shown in FIG. 11 (b), one side is arcuate and the remaining three sides are straight lines. It can also be set as the opening part of such a shape.
- FIG.9 (c) both a channel part and a non-channel part can also be made circular, The circular opening part as shown in FIG.11 (c) is applied to a non-channel part, An arc-shaped opening that surrounds a part of the periphery can be used as a channel portion.
- the shapes of the openings of the channel portion and the non-channel portion can be interchanged.
- the configuration for suppressing the mixing of the organic semiconductor ink between two adjacent openings is adopted.
- the above-described configuration can be adopted as appropriate.
- a configuration including an organic semiconductor layer formed using an organic semiconductor ink is used as an example.
- a similar configuration is employed for a configuration including an inorganic semiconductor layer formed using a facing semiconductor ink. be able to.
- an amorphous metal oxide semiconductor can be used as the inorganic semiconductor material.
- Such semiconductors are expected to be applied to displays and electronic paper because of their transparency.
- such a semiconductor is a material that can realize 3 to 20 [cm 2 / Vs] required for high performance liquid crystal, organic EL (Electro-Luminescence), and the like.
- an amorphous In—Zn—O oxide semiconductor a-InZnO
- a-InZnO amorphous In—Zn—O oxide semiconductor
- a-InGaZnO amorphous In—Ga—Zn—O oxide semiconductor
- the present invention is used for a display device including a panel such as an organic EL display panel, and is useful for realizing a high-quality TFT device even with high definition.
- Organic EL display device 10. Organic EL display panel 20. Drive control circuit unit 21-24. Drive circuit 25. Control circuit 101. TFT substrate 102. Planarization film 102a. Contact hole 103. Anode 104. Transparent conductive film 105. Hole injection layer 106. Bank 107. Hole transport layer 108. Organic light emitting layer 109. Electron transport layer 110. Cathode 111. Sealing layer 112. Adhesive layer 113. CF substrate 501. Mask 1011, 1131. Substrate 1012a, 1012b. Gate electrode 1013.
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Abstract
Description
本発明の一態様に係る薄膜トランジスタ装置は、互いに間隔をあけた状態で隣接配置された第1および第2の薄膜トランジスタ素子を備え、各薄膜トランジスタ素子が、ゲート電極と、ゲート電極の上方に積層形成され、積層方向に対して交差する方向に互いに間隔をあけて並設されたソース電極およびドレイン電極と、ゲート電極とソース電極およびドレイン電極との間に介挿された絶縁層と、ソース電極とドレイン電極との間の間隙、およびソース電極およびドレイン電極の上に形成され、ソース電極およびドレイン電極に対して密に接する半導体層と、絶縁層上において、ソース電極およびドレイン電極とは別に形成され、絶縁層よりも高い親液性を有する親液層と、を備える。
本発明の一態様に係る薄膜トランジスタ装置では、第1開口部の底部において、親液層が、第1開口部を臨む側面部に対し、第2開口部が隣接する側とは反対側で接しており、第2開口部の底部において、親液層が、第2開口部を臨む側面部に対し、第1開口部が隣接する側とは反対側で接している、ことを特徴とする。このように、第1開口部および第2開口部の各々における親液層の具体的配置を採用する場合にも、上記効果を得ることができる。
1.有機EL表示装置1の全体構成
以下では、本発明の実施の形態1に係る有機EL表示装置1の構成について図1を用い説明する。
有機EL表示パネル10の構成について、図2の模式断面図および図3を用い説明する。
有機EL表示パネル10では、例えば、各部位を次のような材料を用い形成することができる。
基板1011は、例えば、例えば、ガラス基板、石英基板、シリコン基板、硫化モリブデン、銅、亜鉛、アルミニウム、ステンレス、マグネシウム、鉄、ニッケル、金、銀などの金属基板、ガリウム砒素基などの半導体基板、プラスチック基板等を用いることができる。
ゲート電極1012a,1012bは、例えば、導電性を有する材料であれば特に限定されない。
絶縁層1013は、ゲート絶縁層として機能するものであって、例えば、絶縁性を有する材料であれば特に限定されず、公知の有機材料や無機材料のいずれも用いることができる。
ソース電極1014a,1014b、ドレイン電極1014c,1014dは、ゲート電極1012a,1012bを形成するための上記材料を用い形成することができる。
有機半導体層1017a,1017bは、例えば、半導体特性を有し、溶媒に可溶であれば特に限定されない。例えば、ポリ(3-アルキルチオフェン)、ポリ(3-ヘキシルチオフェン)(P3HT)、ポリ(3-オクチルチオフェン)、ポリ(2,5-チエニレンビニレン) (PTV ) もしくはクォーターチオフェン(4T)、セキシチオフェン(6T)およびオクタチオフェンなどのα-オリゴチオフェン類もしくは2,5-ビス(5'-ビフェニル-2'-チエニル)-チオフェン(BPT3)、2,5-[2,2'-(5,5'-ジフェニル)ジチエニル]-チオフェンなどのチオフェン誘導体、ポリ(パラ-フェニレンビニレン) (PPV) などのフェニレンビニレン誘導体、ポリ(9,9-ジオクチルフルオレン) (PFO) などのフルオレン誘導体、トリアリルアミン系ポリマー、アントラセン、テトラセン、ペンタセンおよびヘキサセン等のアセン化合物、1,3,5-トリス[(3-フェニル-6-トリ-フルオロメチル)キノキサリン-2-イル]ベンゼン(TPQ1) および1,3,5-トリス[{3-(4-t-ブチルフェニル)-6-トリスフルオロメチル}キノキサリン-2-イル]ベンゼン(TPQ2)などのベンゼン誘導体、フタロシアニン、銅フタロシアニン(CuPc)および鉄フタロシアニンのようなフタロシアニン誘導体、トリス(8-ヒドロキシキノリノレート)アルミニウム(Alq3)、およびファクトリス(2-フェニルピリジン)イリジウム(Ir(ppy)3)のような有機金属化合物、C60、オキサジアゾール系高分子、トリアゾール系高分子、カルバゾール系高分子およびフルオレン系高分子のような高分子系化合物ならびにポリ(9,9-ジオクチルフルオレン-コ-ビス-N,N’-(4-メトキシフェニル)-ビス-N,N’-フェニル-1,4-フェニレンジアミン) (PFMO)、ポリ(9,9-ジオクチルフルオレン-コ-ベンゾチアジアゾール) (BT) 、フルオレン-トリアリルアミン共重合体およびポリ(9,9-ジオクチルフルオレン-コ-ジチオフェン) (F8T2)などのフルオレンとの共重合体などが挙げられる。これらは、1種または2種以上組み合わせて用いることができる。
パッシベーション膜1018は、例えば、ポリビニルアルコール(PVA)などの水溶性樹脂や、フッ素系樹脂などを用い形成することができる。
平坦化膜102は、例えば、ポリイミド、ポリアミド、アクリル系樹脂材料などの有機化合物を用い形成されている。
アノード103は、銀(Ag)またはアルミニウム(Al)を含む金属材料から構成されている。トップエミッション型の本実施の形態に係る有機EL表示パネル10の場合には、その表面部が高い反射性を有することが好ましい。
透明導電膜104は、例えば、ITO(Indium Tin Oxide)若しくはIZO(Indium Zinc Oxide)などを用い形成される。
ホール注入層105は、例えば、銀(Ag)、モリブデン(Mo)、クロム(Cr)、バナジウム(V)、タングステン(W)、ニッケル(Ni)、イリジウム(Ir)などの酸化物、あるいは、PEDOT(ポリチオフェンとポリスチレンスルホン酸との混合物)などの導電性ポリマー材料からなる層である。なお、図2に示す本実施の形態に係る有機EL表示パネル10では、金属酸化物からなるホール注入層105を構成することを想定しているが、この場合には、PEDOTなどの導電性ポリマー材料を用いる場合に比べて、ホールを安定的に、またはホールの生成を補助して、有機発光層108に対しホールを注入する機能を有し、大きな仕事関数を有する。
バンク106は、樹脂等の有機材料を用い形成されており絶縁性を有する。バンク106の形成に用いる有機材料の例としては、アクリル系樹脂、ポリイミド系樹脂、ノボラック型フェノール樹脂等があげられる。バンク106は、有機溶剤耐性を有することが好ましい。さらに、バンク106は、製造工程中において、エッチング処理、ベーク処理など施されることがあるので、それらの処理に対して過度に変形、変質などをしないような耐性の高い材料で形成されることが好ましい。また、表面に撥水性をもたせるために、表面をフッ素処理することもできる。
ホール輸送層107は、親水基を備えない高分子化合物を用い形成されている。例えば、ポリフルオレンやその誘導体、あるいはポリアリールアミンやその誘導体などの高分子化合物であって、親水基を備えないものなどを用いることができる。
発光層108は、上述のように、ホールと電子とが注入され再結合されることにより励起状態が生成され発光する機能を有する。有機発光層108の形成に用いる材料は、湿式印刷法を用い製膜できる発光性の有機材料を用いることが必要である。
電子輸送層109は、カソード110から注入された電子を発光層108へ輸送する機能を有し、例えば、オキサジアゾール誘導体(OXD)、トリアゾール誘導体(TAZ)、フェナンスロリン誘導体(BCP、Bphen)などを用い形成されている。
カソード110は、例えば、ITO(Indium Tin Oxide)若しくはIZO(Indium Zinc Oxide)などを用い形成される。本実施の形態のように、トップエミッション型の本実施の形態に係る有機EL表示パネル10の場合においては、光透過性の材料で形成されることが必要となる。光透過性については、透過率が80[%]以上とすることが好ましい。
封止層111は、発光層108などの有機層が水分に晒されたり、空気に晒されたりすることを抑制する機能を有し、例えば、SiN(窒化シリコン)、SiON(酸窒化シリコン)などの材料を用い形成される。また、SiN(窒化シリコン)、SiON(酸窒化シリコン)などの材料を用い形成された層の上に、アクリル樹脂、シリコーン樹脂などの樹脂材料からなる封止樹脂層を設けてもよい。
TFT基板101におけるソース電極1014a,1014bおよびドレイン電極1014c,1014dおよび親液層1019a,1019bの配置について、図3(a)および図3(b)を用い説明する。
(i)有機EL表示パネル10の製造方法の概要
有機EL表示装置1の製造方法、特に、有機EL表示パネル10の製造方法について、図2と図4を用い説明する。
次に、TFT基板101の形成方法について、図4(b)および図5から図8を用い説明する。
本実施の形態に係るTFT基板101およびこれを備える有機EL表示パネル10、さらには、有機EL表示パネル10を構成に含む有機EL表示装置1では、次のような理由から高品質であって、且つ、その生産における歩留まりが高いという効果を有する。
上記において、上記各撥液性RW,RI,REは、有機半導体インク10170a,10170bに対するものである。
なお、上記[数3]において、WWは、隔壁1016の表面の濡れ性であり、WIは、絶縁層1013の表面の濡れ性であり、WEは、ソース電極1014a,1014bとドレイン電極1014c,1014dと親液層1019a,1019bの表面の濡れ性である。
本発明の実施の形態2に係るTFT基板の構成について、図9(a)を用い説明する。なお、図9(a)は、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1と同様であるので、図示および説明を省略する。
本発明の実施の形態3に係るTFT基板の構成について、図9(b)を用い説明する。なお、図9(b)についても、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1,2と同様であるので、図示および説明を省略する。
本発明の実施の形態4に係るTFT基板の構成について、図9(c)を用い説明する。なお、図9(c)についても、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1,2,3と同様であるので、図示および説明を省略する。
本発明の実施の形態5に係るTFT基板の構成について、図10(a)を用い説明する。なお、図10(a)についても、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1,2,3,4などと同様であるので、図示および説明を省略する。
本発明の実施の形態6に係るTFT基板の構成について、図10(b)を用い説明する。なお、図10(b)についても、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1,2,3,4,5などと同様であるので、図示および説明を省略する。
本発明の実施の形態7に係るTFT基板の構成について、図10(c)を用い説明する。なお、図10(c)についても、上記実施の形態1における図3(a)に相当する図であり、他の構成については、上記実施の形態1,2,3,4,5,6などと同様であるので、図示および説明を省略する。
上記実施の形態1~7では、開口部の底部で、一方の側とは反対側の他方の側において、ソース電極およびドレイン電極の何れも介在せずに、絶縁層と有機半導体層とが直に接する箇所が存在する形態を一例として採用したが、これに限らず、隣接する2つの開口部において、一方の開口部の底部で、ソース電極およびドレイン電極の表面積の和の中心位置が、開口部の底部における中心位置(表面積の中心位置)よりも、他方の開口部が隣接する側に離れて配されていれば、当該開口部の底部においては、他方の開口部が隣接する側とは反対側において、絶縁層と有機半導体層との間に、ソース電極およびドレイン電極の何れもが介在する箇所が存在する形態についても適用することができる。
10.有機EL表示パネル
20.駆動制御回路部
21~24.駆動回路
25.制御回路
101.TFT基板
102.平坦化膜
102a.コンタクトホール
103.アノード
104.透明導電膜
105.ホール注入層
106.バンク
107.ホール輸送層
108.有機発光層
109.電子輸送層
110.カソード
111.封止層
112.接着層
113.CF基板
501.マスク
1011,1131.基板
1012a,1012b.ゲート電極
1013.絶縁層
1014a,1014b,2014a,2014b,3014a,3014b,4014a,4014b,5014a,5014b,6014a,6014b,7014a,7014b.ソース電極
1014c,1014d,2014c,2014d,3014c,3014d,4014c,4014d,5014c,5014d,6014c,6014d,7014c,7014d.ドレイン電極
1015,2015,3015,4015,5015,6015,7015.接続配線
1016,2016,3016,4016,5016,6016,7016.隔壁
1016a,1016b,1016c,2016a,2016b,2016c,3016a,3016b,3016c,4016a,4016b,4016c,5016a,5016b,5016c,6016a,6016b,6016c,7016a,7016b,7016c.開口部
1017a,1017b.有機半導体層
1018.パッシベーション膜
1132.カラーフィルタ
1133.ブラックマトリクス
10160.感光性レジスト材料膜
10170a,10170b.有機半導体インク
Claims (15)
- 互いに間隔をあけた状態で隣接配置された第1および第2の薄膜トランジスタ素子を備え、
各薄膜トランジスタ素子が、
ゲート電極と、
前記ゲート電極の上方に積層形成され、積層方向に対して交差する方向に互いに間隔をあけて並設されたソース電極およびドレイン電極と、
前記ゲート電極と前記ソース電極および前記ドレイン電極との間に介挿された絶縁層と、
前記ソース電極と前記ドレイン電極との間の間隙、および前記ソース電極および前記ドレイン電極の上に形成され、前記ソース電極および前記ドレイン電極に対して密に接する半導体層と、
前記絶縁層上において、前記ソース電極および前記ドレイン電極とは別に形成され、前記絶縁層よりも高い親液性を有する親液層と、
を備え、
前記第1の薄膜トランジスタ素子における前記半導体層と、前記第2の薄膜トランジスタ素子における前記半導体層との間には、互いの間を区画する隔壁が形成されており、
前記隔壁は、前記第1の薄膜トランジスタ素子における前記ソース電極および前記ドレイン電極および前記親液層の各々の少なくとも一部と、前記第2の薄膜トランジスタ素子における前記ソース電極および前記ドレイン電極および前記親液層の各々の少なくとも一部とを別々に囲繞し、且つ、表面が撥液性を有しており、
前記第1の薄膜トランジスタ素子における前記ソース電極および前記ドレイン電極および前記親液層の各々の少なくとも一部を囲繞することで構成される開口部を第1開口部とし、前記第2の薄膜トランジスタ素子における前記ソース電極および前記ドレイン電極および前記親液層の各々の少なくとも一部を囲繞することで構成される開口部を第2開口部とするとき、
前記第1開口部の底部を平面視する場合において、当該第1開口部の底部における前記親液層の表面積の中心位置が、前記第1開口部の底部における面積の中心位置よりも、前記第2開口部が隣接する側とは反対側に離れており、
前記第2開口部の底部を平面視する場合において、当該第2開口部の底部における前記親液層の表面積の中心位置が、前記第2開口部の底部における面積の中心位置よりも、前記第1開口部が隣接する側とは反対側に離れている
ことを特徴とする薄膜トランジスタ装置。 - 前記第1開口部の底部では、前記第2開口部が隣接する側において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記半導体層とが直に接する箇所が存在し、
前記第2開口部の底部では、前記第1開口部が隣接する側において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記半導体層とが直に接する箇所が存在する
ことを特徴とする請求項1に記載の薄膜トランジスタ装置。 - 前記第1開口部の底部において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記半導体層とが直に接する箇所は、前記第2開口部が隣接する側とは反対側にも存在し、
前記第1開口部の底部を平面視する場合において、前記絶縁層と前記半導体層とが直に接する箇所の面積は、前記第1開口部の底部における中心位置を基準として、前記第2開口部が隣接する側とは反対側よりも前記第2開口部の側の方が大きく、
前記第2開口部の底部において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記半導体層とが直に接する箇所は、前記第1開口部が隣接する側とは反対側にも存在し、
前記第2開口部の底部を平面視する場合において、前記絶縁層と前記半導体層とが直に接する箇所の面積は、前記第2開口部の底部における中心位置を基準として、前記第1開口部が隣接する側とは反対側よりも前記第1開口部が隣接する側の方が大きい
ことを特徴とする請求項2に記載の薄膜トランジスタ装置。 - 前記第1および前記第2の薄膜トランジスタ素子の各々において、前記親液層は、前記ソース電極および前記ドレイン電極と同一の材料を以って構成され、前記ソース電極および前記ドレイン電極の何れに対しても離間した状態で形成されている
ことを特徴とする請求項1から請求項3の何れかに記載の薄膜トランジスタ装置。 - 前記第1開口部の底部を平面視する場合において、
前記ソース電極および前記ドレイン電極の各々における表面積の中心位置は、前記第1開口部の底部における中心位置に合致しており、
前記第2開口部の底部を平面視する場合において、
前記ソース電極および前記ドレイン電極の各々における表面積の中心位置は、前記第1開口部の底部における中心位置に合致している
ことを特徴とする請求項1から請求項4の何れかに記載の薄膜トランジスタ装置。 - 前記第1開口部の底部を平面視する場合において、
前記ソース電極と前記ドレイン電極と前記親液層との表面積の和の中心位置が、前記第1開口部の底部における面積の中心位置から、前記第2開口部が隣接する側とは反対側に離れており、
前記第2開口部の底部を平面視する場合において、
前記ソース電極と前記ドレイン電極と前記親液層との表面積の和の中心位置が、前記第1開口部の底部における面積の中心位置から、前記第1開口部が隣接する側とは反対側に離れている
ことを特徴とする請求項1から請求項5の何れかに記載の薄膜トランジスタ装置。 - 前記第1開口部の底部において、前記親液層は、前記第1開口部を臨む側面部に対し、前記第2開口部が隣接する側とは反対側で接しており、
前記第2開口部の底部において、前記親液層は、前記第2開口部を臨む側面部に対し、前記第1開口部が隣接する側とは反対側で接している
ことを特徴とする請求項1から請求項6の何れかに記載の薄膜トランジスタ装置。 - 前記隔壁の表面における撥液性は、前記第1および第2の薄膜トランジスタ素子の各々における前記絶縁層の前記半導体層との接触面よりも高く、且つ、前記第1および第2の薄膜トランジスタ素子の各々における前記絶縁層の前記半導体層との接触面の撥液性は、前記第1および第2の薄膜トランジスタ素子の各々における前記ソース電極および前記ドレイン電極および前記親液層の各表面よりも高い
ことを特徴とする請求項1から請求項7の何れかに記載の薄膜トランジスタ装置。 - 請求項1から請求項8の何れかに記載の薄膜トランジスタ装置と、
前記薄膜トランジスタ装置の上方に設けられ、コンタクトホールが形成された平坦化膜と、
前記平坦化膜上、および前記平坦化膜の前記コンタクトホールを臨む側面上に形成され、前記第1の薄膜トランジスタ素子における前記ドレイン電極または前記ソース電極と電気的に接続された下部電極と、
前記下部電極の上方に形成された上部電極と、
前記下部電極と前記上部電極との間に介挿された有機発光層と、
を備える
ことを特徴とする有機EL表示素子。 - 請求項9に記載の有機EL表示素子を備える
ことを特徴とする有機EL表示装置。 - 基板上に互いに間隔をあけた状態で隣接した第1および第2のゲート電極を形成する第1工程と、
前記第1および第2のゲート電極の上方を覆うように、絶縁層を形成する第2工程と、
前記絶縁層上において、前記第1のゲート電極に対応して、前記絶縁層の層厚方向に対して交差する方向に互いに間隔をあけた状態で、第1のソース電極および第1のドレイン電極を並設するとともに、当該第1のソース電極および第1のドレイン電極の何れに対しても離間した状態で、前記絶縁層よりも親液性が高い第1の親液層を形成し、且つ、前記第2のゲート電極に対応して、前記絶縁層の層厚方向に対して交差する方向に互いに間隔をあけた状態で、第2のソース電極および第2のドレイン電極を並設するとともに、当該第2のソース電極および第2のドレイン電極の何れに対しても離間した状態で、前記絶縁層よりも親液性が高い第2の親液層を形成する第3工程と、
前記絶縁層上において、前記第1および第2のソース電極上および前記第1および第2のドレイン電極上を覆う状態で、感光性レジスト材料を積層する第4工程と、
前記積層された感光性レジスト材料をマスク露光してパターニングすることにより、前記第1のソース電極および前記第1のドレイン電極および前記第1の親液層の各々の少なくとも一部と、前記第2のソース電極および前記第2のドレイン電極および前記第2の親液層の各々の少なくとも一部とを、別々に囲繞し、且つ、表面が撥液性を有する隔壁を形成する第5工程と、
前記第1のソース電極および前記第1のドレイン電極および前記第1の親液層の各々の少なくとも一部を囲繞することにより構成される第1開口部の内部と、前記第2のソース電極および前記第2のドレイン電極および前記第2の親液層の各々の少なくとも一部を囲繞することにより構成される第2開口部の内部との各々に対し、半導体材料を塗布して乾燥させ、前記第1のソース電極および前記第1のドレイン電極に対して密に接する第1の半導体層と、前記第2のソース電極および前記第2のドレイン電極に対して密に接する第2の導体層とを形成する第6工程と、
を備え、
前記第5工程では、
前記第1開口部の底部を平面視する場合において、当該第1開口部の底部における前記第1の親液層との表面積の中心位置が、前記第1開口部の底部における面積の中心位置よりも、前記第2開口部が隣接する側とは反対側に離れ、
前記第2開口部の底部を平面視する場合において、当該第2開口部の底部における前記第2の親液層の表面積の中心位置が、前記第2開口部の底部における面積の中心位置よりも、前記第1開口部が隣接する側とは反対側に離れるように、
前記隔壁を形成する
ことを特徴とする薄膜トランジスタ装置の製造方法。 - 前記第5工程では、
前記第1開口部の底部では、前記第2開口部が隣接する側において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記第1の半導体層とが直に接する箇所が存在し、
前記第2開口部の底部では、前記第1開口部が隣接する側において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記第2の半導体層とが直に接する箇所が存在するように、
前記隔壁を形成する
ことを特徴とする請求項11に記載の薄膜トランジスタ装置の製造方法。 - 前記第5工程では、
前記第1開口部の底部において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記第1の半導体層とが直に接する箇所は、前記第2開口部が隣接する側とは反対側にも存在し、
前記第1開口部の底部を平面視する場合において、前記絶縁層と前記第1の半導体層とが直に接する箇所の面積は、前記第1開口部の底部における中心位置を基準として、前記第2開口部が隣接する側とは反対側よりも前記第2開口部の側の方が大きく、
前記第2開口部の底部において、前記ソース電極および前記ドレイン電極および前記親液層の何れも介在せずに、前記絶縁層と前記第2の半導体層とが直に接する箇所は、前記第1開口部が隣接する側とは反対側にも存在し、
前記第2開口部の底部を平面視する場合において、前記絶縁層と前記第2の半導体層とが直に接する箇所の面積は、前記第2開口部の底部における中心位置を基準として、前記第1開口部が隣接する側とは反対側よりも前記第1開口部が隣接する側の方が大きくなるように、
前記隔壁を形成する
ことを特徴とする請求項12に記載の薄膜トランジスタ装置の製造方法。 - 前記第3工程では、前記絶縁層上に金属膜を成膜するサブ工程と、前記金属膜をエッチングするサブ工程と、を経ることにより、前記第1のソース電極および前記第1のドレイン電極および前記第1の親液層と、前記第2のソース電極および前記第2のドレイン電極および前記第2の親液層と、を形成する
ことを特徴とする請求項11から請求項13の何れかに記載の薄膜トランジスタ装置の製造方法。 - 前記第2工程から前記第6工程では、
前記隔壁の表面における撥液性を、前記絶縁層における前記第1および第2の半導体層との各接触面よりも高くし、且つ、前記絶縁層における前記第1および第2の有機半導体層との接触面の撥液性を、前記第1および第2のソース電極と前記第1および第2のドレイン電極と前記第1および第2の親液層の各表面よりも高くする
ことを特徴とする請求項11から請求項14の何れかに記載の薄膜トランジスタ装置の製造方法。
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US9112162B2 (en) | 2013-03-26 | 2015-08-18 | Panasonic Corporation | Electronic device and electronic device manufacturing method |
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US8907344B2 (en) | 2014-12-09 |
CN103370775B (zh) | 2016-03-23 |
CN103370775A (zh) | 2013-10-23 |
US20140034933A1 (en) | 2014-02-06 |
JPWO2013073090A1 (ja) | 2015-04-02 |
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