WO2013069475A1 - Fibres avec des propriétés d'allongement thermique et tissu non-tissé les utilisant - Google Patents

Fibres avec des propriétés d'allongement thermique et tissu non-tissé les utilisant Download PDF

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Publication number
WO2013069475A1
WO2013069475A1 PCT/JP2012/077707 JP2012077707W WO2013069475A1 WO 2013069475 A1 WO2013069475 A1 WO 2013069475A1 JP 2012077707 W JP2012077707 W JP 2012077707W WO 2013069475 A1 WO2013069475 A1 WO 2013069475A1
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Prior art keywords
heat
resin component
fiber
nonwoven fabric
melting point
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PCT/JP2012/077707
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English (en)
Japanese (ja)
Inventor
啓介 長島
祥一 種市
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花王株式会社
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Priority to CN201280050711.9A priority Critical patent/CN103890250B/zh
Publication of WO2013069475A1 publication Critical patent/WO2013069475A1/fr

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/55—Polyesters
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/32—Side-by-side structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/34—Core-skin structure; Spinnerette packs therefor

Definitions

  • the present invention relates to a heat stretch fiber.
  • the present invention also relates to a nonwoven fabric produced using the thermally stretched fiber.
  • Various heat-extensible fibers made of composite fibers containing a first component and a second component having a melting point lower than that of the first component are known.
  • the combination of the first component and the second component include polypropylene / polyethylene and polyethylene terephthalate / polyethylene.
  • the applicant firstly made of a core-sheath type composite fiber having polypropylene as a core and polyethylene as a sheath, and a heat-extensible fiber formed by setting the orientation index of polypropylene and polyethylene within a specific range. Proposed (see Patent Document 1).
  • Patent Document 2 is known as a heat-extensible fiber made of polyethylene terephthalate / polyethylene.
  • This heat-extensible fiber is obtained by subjecting an undrawn yarn of a composite fiber taken at a spinning speed of 150 m / min to 1800 m / min at a temperature higher than both the glass transition point of polyethylene and the glass transition point of polyethylene terephthalate. , 0.5 to 1.3 times, followed by heat treatment under no tension at a temperature 5 ° C. higher than the constant-length heat treatment temperature.
  • thermoadhesive conjugate fiber composed of a first component made of polylactic acid and a second component made of polyethylene having a melting point of 20 degrees or more lower than the melting point of polylactic acid.
  • This heat-adhesive conjugate fiber is spun by adding inorganic fine particles to the resin of the first component and / or the second component, the draw ratio is set to 75% or more and 90% or less of the break draw ratio of the undrawn fiber, and the heating temperature
  • the heat-extensible fibers known so far including the heat-extensible fibers described in Patent Documents 1 and 2 described above, generally have a length that gradually increases as the temperature rises due to heating. .
  • a nonwoven fabric is produced using such a heat-extensible fiber as a raw material, for example, by thermal bonding, the fiber will be stretched to some extent by the heat of the thermal bond. It is not easy to increase the degree of elongation when heating is performed in the bulk recovery treatment step to further stretch the fiber to give a bulky feeling.
  • the present invention comprises a first resin component and a second resin component having a melting point or softening point lower than the melting point of the first resin component, and the second resin component extends at least part of the fiber surface in the length direction.
  • a heat-extensible fiber that is continuously present and lengthened by heating,
  • the change rate ( ⁇ (BA) / A ⁇ ⁇ 100) of the thermal elongation rate B at the melting point of the second resin component + 10 ° C. with respect to the thermal elongation rate A at the melting point ⁇ 6 ° C. of the second resin component is 130 % Or more of the heat-extensible fiber is provided.
  • the present invention also uses the heat-extensible fiber as a raw material, has a plurality of convex portions and concave portions on one surface side, and the other surface side is flatter than the one surface side.
  • the part is a nonwoven fabric containing the thermally stretchable fiber in a thermally stretched state, Present at a position corresponding to the convex portion on the surface on the other surface side, existing at a position corresponding to the convex portion on the surface on the one surface side, and the thermal elongation rate C of the thermally extensible fiber in a thermally stretched state, Providing a nonwoven fabric in which the ratio (C / D) to the thermal elongation rate D of the thermally stretchable fiber in the thermally stretched state is 3 or more at the melting point of the second resin component constituting the thermally stretchable fiber + 20 ° C. It is.
  • the present invention is a nonwoven fabric using the above heat-extensible fiber as a raw material
  • the non-woven fabric has a plurality of convex portions and concave portions on one surface side, and also has a plurality of convex portions and concave portions on the other surface side, the convex portions and concave portions on one surface side, and the other surface
  • the convex portion and concave portion on the side are located at the same position in the plan view of the nonwoven fabric
  • the convex part contains a heat-extensible fiber in a heat-extended state, Present at a position corresponding to the convex portion on the surface on the other surface side, existing at a position corresponding to the convex portion on the surface on the one surface side, and the thermal elongation rate E of the heat-extensible fiber in a thermally stretched state,
  • the ratio (E / F) with the thermal elongation rate F of the thermally stretchable fiber in the thermally stretched state is 0.1
  • the thickness of the convex part in the other surface side on the basis of the center position of the thickness direction of a nonwoven fabric provides the nonwoven fabric which occupies 20% or more and 40% or less of the thickness of the whole convex part. is there.
  • the spinning temperature of the first component is set in the range of the melting point of the first component plus 20 ° C. to 180 ° C.
  • the spinning temperature of the second resin component is set to the melting point of the second component plus 20 ° C. to 180 ° C.
  • Stretching is performed, crimping is performed, Thereafter, relaxation treatment by heat drying is performed at 100 ° C. or more and 125 ° C. or less.
  • a method for producing a heat-extensible fiber is provided.
  • FIG. 1 is a graph showing the relationship between the heating temperature and the amount of elongation of a heat-extensible fiber.
  • Fig.2 (a) is a perspective view which shows one Embodiment of the nonwoven fabric of this invention
  • FIG.2 (b) is a longitudinal cross-sectional view of the nonwoven fabric shown to Fig.2 (a).
  • FIG. 3 is a perspective view (corresponding to FIG. 2 (a)) showing another embodiment of the nonwoven fabric of the present invention.
  • FIG. 4 is a schematic view showing an apparatus suitably used for producing the nonwoven fabric of the present invention.
  • FIG. 5 is a longitudinal cross-sectional view of the nonwoven fabric of the present invention with the bulk recovered.
  • the heat-extensible fiber of the present invention includes a first resin component made of a high melting point resin and a second resin component made of a low melting point resin having a melting point or softening point lower than the melting point of the first resin component. It is a composite fiber in which the resin component is continuously present in the length direction on at least a part of the fiber surface.
  • fever extensible fiber is a component which expresses the heat
  • a 2nd resin component is a component which expresses heat-fusibility.
  • the heat stretchable fiber of the present invention can be stretched by heat at a temperature lower than the melting point of the first resin component.
  • the temperature range for thermal extension is the range from the melting point of the second resin component to ⁇ 60 ° C. to less than the melting point of the first resin component.
  • the heat-extensible fiber of the present invention can typically be a core-sheath type composite fiber having a first resin component and a second resin component. Alternatively, it may be a side-by-side type composite fiber. When the heat-extensible fiber of the present invention is a core-sheath type, the heat-extensible fiber may be a concentric type or an eccentric type.
  • the heat stretchable fiber of the present invention is characterized by a high rate of change in the heat stretch rate between two specific temperatures. Specifically, when the thermal elongation rate at the melting point of the second resin component at ⁇ 6 ° C. is A and the thermal elongation rate at the melting point of the second resin component + 10 ° C. is B, the thermal elongation rate B with respect to the thermal elongation rate A Change rate (hereinafter referred to as “thermal elongation rate change rate”), that is, ⁇ (BA) / A ⁇ ⁇ 100 is a high value of 130% or more, preferably 135% or more, more preferably 150% or more.
  • the rate of change in thermal expansion rate is preferably 130% or more and 300% or less, for example, and preferably 135% or more and 210% or less.
  • the horizontal axis represents temperature (° C.), and the vertical axis represents fiber elongation (mm).
  • A represents the heat stretchable fiber of the present invention
  • B represents a conventional heat stretchable fiber (core component is polypropylene / sheath component is polyethylene).
  • core component is polypropylene / sheath component is polyethylene.
  • the graph of the temperature-elongation amount is composed of a line L1 having a first slope S1 and a line L2 having a second slope S2.
  • the temperature at the intersection of the line L1 and the line L2 is the temperature T1 described above.
  • the inclinations S1 and S2 have a relationship of S1 ⁇ S2.
  • the conventional heat stretchable fiber B only stretches gradually as the temperature rises, and no temperature at which a rapid change in the slope of the graph is observed.
  • the heat stretchable fiber of the present invention having a large rate of change in heat stretch rate has the advantages described below. Since the thermal elongation rate up to a specific temperature is kept low, after producing a thermal bond nonwoven fabric using the thermally extensible fiber, for example, after further heating in the bulk recovery treatment step of the nonwoven fabric, for example, It is easy to increase the degree of elongation when the thermally stretchable fiber is further stretched to give the nonwoven fabric a bulky feeling. As a result, a bulky nonwoven fabric can be easily obtained.
  • the heat-extensible fiber of the present invention has a thermal elongation ratio A at the melting point of ⁇ 6 ° C. of the second resin component of 3.5% or less, particularly 3.2% or less. In particular, it is preferably 3.0% or less. In addition, it is preferable that the lower limit of the thermal expansion rate A is zero, or it is more preferable that it is a positive value close to zero.
  • the temperature of the melting point of the second resin component of ⁇ 6 ° C. is the temperature at which the fibers start to fuse when the heat-extensible fibers of the present invention are subjected to thermal processing such as thermal bonding.
  • the value of the elongation ratio B is preferably 5% or more, and more preferably 8% or more.
  • the temperature of the melting point of the second resin component + 10 ° C. is a typical temperature when the heat-extensible fiber of the present invention is subjected to thermal processing such as thermal bonding.
  • the heat-extensible fiber of the present invention has the above-described temperature T1 in FIG. 1 at the melting point of the second resin component ⁇ 10 ° C. ⁇ T1 ⁇ the melting point of the second resin component ⁇ 3 ° C.
  • the slope S1 of the line L1 in FIG. 1 is preferably as close to zero as possible, and the slope S2 of the line L2 in FIG. 1 is preferably as large as possible.
  • the thermal elongation rate of the heat-extensible fiber is measured by the following method.
  • a thermomechanical analyzer TMA / SS6000 manufactured by Seiko Instruments Inc. is used.
  • TMA / SS6000 manufactured by Seiko Instruments Inc.
  • the measurement start temperature is 25 ° C.
  • the temperature is increased at a rate of temperature increase of 5 ° C./min with a constant load of 0.73 mN / dtex applied, and the fiber elongation at that time is measured.
  • E T (mm) the thermal elongation rate (%) at the temperature T (° C.) is calculated from (E T / 10) ⁇ 100 [%].
  • the order of crystallization rate of these resins is PE> PP> PET> PLA. Therefore, the first resin component and the second resin component may be selected in consideration of the crystallization speed of these resins and the melting point of the resins.
  • a preferable combination of resins from these viewpoints includes a combination in which the first resin component is polylactic acid and the second resin component is a polyolefin such as polyethylene or polypropylene.
  • a particularly preferable combination of resins is that the first resin component is polylactic acid and the second resin component is polyolefin.
  • a particularly preferable combination of resins is that the first resin component is polylactic acid and the second resin component is polyethylene.
  • the crystallization speed of the resin component is measured using a differential scanning calorimeter (DSC). First, a sample is heated to the melting point or higher (300 ° C.) in the atmosphere to be melted, and then immediately cooled to a predetermined crystallization temperature. When the temperature (crystallization temperature) was maintained, the time (crystallization time) when the exothermic peak top of crystallization observed on the DSC curve from the start of cooling was measured, and the obtained time was used as the crystallization rate. It is defined as The rapid cooling is performed at a cooling rate of 100 ° C./min, for example.
  • Polylactic acid which is a thermoplastic resin preferably used as the first resin component, has a melt index of 2 g / 10 min or more, particularly preferably 5 g / 10 min or more, and 50 g / 10 min or less, particularly 40 g / 10 min or less. Is preferred.
  • polyethylene which is a thermoplastic resin preferably used as the second resin component, preferably has a melt index of 10 g / 10 min or more, preferably 40 g / 10 min or less, particularly preferably 25 g / 10 min or less.
  • high-density polyethylene, low-density polyethylene, or linear low-density polyethylene can be used, but using high-density polyethylene having a density of 0.941 g / cm 3 or more and 0.965 g / cm 3 or less can be used as a nonwoven fabric. This is preferable in that the tensile strength becomes high.
  • the melt index of the first resin component and the second resin component is measured under the conditions of 190 ° C. and 2.16 kg load according to the method described in JIS K7210.
  • the orientation index is an indicator of the degree of orientation of the polymer chain of the resin component.
  • the orientation index of the first resin component is set to preferably 50% or less, and more preferably 40% or less, the above-described characteristics relating to thermal stretchability can be easily realized.
  • the lower limit value of the orientation index of the first resin component is preferably 3%, and more preferably 10% or more.
  • the orientation index of the second resin component is preferably 5% or more, and more preferably 8% or more.
  • Intrinsic birefringence refers to birefringence in the state where the polymer polymer chains are perfectly oriented.
  • the values are, for example, the first edition of “Plastic Materials in Molding”, Appendix, Typical Plastic Materials Used in Molding (Plastics) Edited by the Japan Society for Molding and Processing, Sigma Publishing, published on February 10, 1998).
  • each resin component in the heat stretchable fiber of the present invention is measured by the following method. That is, a polarizing plate is attached to an interference microscope, and measurement is performed under polarized light parallel and perpendicular to the fiber axis.
  • As the immersion liquid a standard refraction liquid manufactured by Cargille is used.
  • the refractive index of the immersion liquid is measured with an Abbe refractometer. From the interference fringe image of the thermally stretchable fiber obtained by the interference microscope, the refractive index in the direction parallel and perpendicular to the fiber axis is obtained by the calculation method described in the following document, and the birefringence that is the difference between the two is calculated.
  • the spinning conditions of the heat-extensible fiber are appropriately set. Setting is also effective.
  • the heat-extensible fiber of the present invention is preferably produced by a melt spinning method, and it is preferable to appropriately set the conditions at that time.
  • a spinning device equipped with two systems of extrusion devices for each resin component and a spinneret can be used.
  • a plurality of nozzles are formed in the spinneret. From each nozzle, the melted first resin component and second resin component extruded from each extrusion device are discharged so that a core-sheath type or side-by-side type fiber is formed.
  • the molten resin discharged from the nozzle is taken up at a predetermined speed. An example of such a device is described in FIG.
  • the target heat-extensible fibers can be easily obtained by adjusting the spinning temperatures of the first resin component and the second resin component to balance the melt viscosity of each resin component.
  • the spinning temperature of the first resin component varies depending on the resin used, but the melting point of the resin used is preferably in the range of 20 ° C. or higher and 180 ° C. or lower, more preferably in the range of 30 ° C. or higher and 170 ° C. or lower, and 70 ° C. or higher and 170 ° C. or lower. The following ranges are particularly preferred.
  • the spinning temperature with the second resin component varies depending on the resin used, but the melting point of the resin used plus a range of 20 ° C. to 180 ° C.
  • the spinning temperature of the first resin component is preferably set to 230 ° C. or more and 250 ° C. or less, and the spinning of the second resin component It is preferable to set the temperature to 240 ° C. or higher and 280 ° C. or lower.
  • the spinning temperature is the temperature of the resin when discharged from the spinneret. This temperature is the same as the melt kneading temperature of the resin component in the extrusion apparatus.
  • a heat-extensible fiber having satisfactory characteristics can be obtained by setting the spinning speed to preferably 50 m / min to 1500 m / min, and more preferably 100 m / min to 1400 m / min. It turned out to be obtained.
  • the fiber obtained by the melt spinning method is in an unstretched state, it is usually subjected to a stretching process as a post-processing, followed by a crimping process and a relaxation process.
  • a stretching process as a post-processing, followed by a crimping process and a relaxation process.
  • the drawing process is not performed when the heat-extensible fiber of the present invention is produced. Therefore, it is preferable that the heat-extensible fiber of the present invention is substantially unstretched. “Substantially unstretched” is intended to exclude intentional stretching even if the degree is low. Accordingly, in the process of producing a heat-extensible fiber, when unintentionally unavoidably low stretching occurs, it is included in “substantially unstretched”.
  • the crimping process performed on the fiber obtained by the melt spinning method can also be performed when producing the heat-extensible fiber of the present invention.
  • a mechanical crimping process can be performed. There are two-dimensional and three-dimensional aspects of the mechanical crimping process, and any aspect of crimping may be performed in the present invention.
  • the relaxation treatment is generally performed by heating and drying the fiber.
  • the rate of change in the heat stretch rate can be increased by performing the relaxation treatment by heat drying at a temperature higher than usual.
  • the temperature of heat drying is set to a temperature that is about 25 to 60 ° C. lower than the melting point of the second resin component.
  • heat drying is performed at a temperature higher than this. I do.
  • the heat drying temperature is preferably set in the range from the melting point of the second resin component to ⁇ 26 ° C.
  • the relaxation treatment by heat drying is preferably performed at 100 ° C. or higher, particularly 110 ° C. or higher, and is preferably performed at 125 ° C. or lower, particularly 120 ° C. or lower. .
  • the relaxed fiber is cut into a predetermined length to become a staple fiber, which becomes a raw material for various fiber products.
  • This staple fiber is in a crimped state because it has been subjected to the crimping process described above.
  • the degree of crimp is 5% or more and 20% or less, particularly 7% or more and 15% or less, expressed as a crimp rate (%) measured according to JIS L1015. It is preferable from the point that the passability of the card machine in the manufacturing process of the nonwoven fabric becomes good.
  • the number of crimps (pieces) measured according to JIS L1015 is preferably 5 or more and 25 or less, and particularly preferably 10 or more and 20 or less.
  • the ratio (crimp rate (%) / crimp number (pieces)) of the crimp rate (%) and the number of crimps (pieces) is preferably 0.45 or more and 0.75 or less, more preferably 0.00.
  • it is 50 or more and 0.70 or less, in addition to improving the passability of the card machine, it is advantageous because crimps are easily released when the heat-extensible fibers are stretched.
  • the heat-extensible fiber of the present invention obtained by the above-described method becomes a staple fiber, but it may be in the form of a continuous filament depending on the production method.
  • the fiber diameter of the heat-extensible fiber of the present invention is generally 10 ⁇ m or more and 100 ⁇ m or less, particularly preferably 15 ⁇ m or more and 90 ⁇ m or less, although it depends on the specific application.
  • the heat-extensible fiber of the present invention is suitably used as a raw material for various fiber products.
  • it is suitably used as a raw fiber for nonwoven fabrics.
  • 2A and 2B show an example of a nonwoven fabric using the heat-extensible fiber of the present invention as a raw material.
  • the nonwoven fabric 10 shown in the figure has a single layer structure.
  • the first surface 10a of the nonwoven fabric 10 has an uneven shape having a plurality of convex portions 19 and concave portions 18, and the second surface 10b is flatter than the first surface 10a. That is, it is three-dimensionally shaped.
  • the concave portion 18 includes a joint portion formed by compacting and joining the constituent fibers of the nonwoven fabric 10.
  • the convex part 19 is a non-consolidated joint.
  • the thickness of the concave portion 18 is smaller than the thickness of the convex portion 19.
  • the convex portion 19 has a shape protruding toward the first surface 10 a side of the nonwoven fabric 10.
  • the inside of the convex portion 19 is filled with the constituent fibers of the nonwoven fabric 10.
  • fever extensible fibers which are the constituent fibers of the nonwoven fabric 10 are fuse
  • the concave portion 18 has a first linear portion 18a extending in one direction in parallel with each other. Moreover, the recessed part 18 has the 2nd linear part 18b extended in one direction in parallel so that it may cross
  • a closed rhombus is formed by intersecting the two linear portions 18a and 18b. This rhombus portion is a convex portion 19. That is, the convex portion 19 is formed to be surrounded by a continuous closed concave portion 18.
  • FIG. 3 shows a non-woven fabric 10 having a form different from that shown in FIG.
  • the nonwoven fabric 10 shown in the figure is different from the nonwoven fabric shown in FIG.
  • the cross-sectional structure is the same as in FIG.
  • the concave portion 18 of the nonwoven fabric shown in FIG. 3 includes a pressure bonding portion formed by pressing or bonding the constituent fibers of the nonwoven fabric 10.
  • the convex portion 19 is located between the concave portions 18.
  • a pressure bonding part means the coupling
  • the intersections of the constituent fibers of the non-woven fabric are joined by means other than pressure bonding at a portion other than the pressure bonding portion, specifically, mainly at the convex portion 19.
  • the area ratio between the concave portion 18 and the convex portion 19 in the nonwoven fabric 10 is expressed by an embossing rate (an embossed area ratio, that is, a ratio of the total area of the concave portion 18 to the entire nonwoven fabric 10), and affects the bulkiness and strength of the nonwoven fabric 10.
  • an embossing rate in the nonwoven fabric 10 is preferably 5% or more and 35% or less, particularly preferably 10% or more and 25% or less in the embodiment shown in FIG. In the embodiment shown in FIG. 3, it is preferably 1% or more and 20% or less, particularly preferably 2% or more and 10% or less.
  • the embossing rate is measured by the following method.
  • a magnified surface of the nonwoven fabric 10 is obtained using a KEYENCE microscope VHX-900 and a lens VH-Z20R.
  • the scale is aligned with the magnified surface, and the dimensions of the recess 18 (ie, the embossed portion) are measured and measured.
  • the total area P of the recesses 18 in the entire area Q of the part is calculated.
  • the embossing rate can be calculated by the formula (P / Q) ⁇ 100.
  • the nonwoven fabric 10 shown in FIG. 2 and FIG. 3 contains the heat-extensible fiber of the present invention in a thermally stretched state.
  • the heat-extensible fiber in a thermally stretched state is referred to as “fiber after heat stretching”.
  • the non-woven fabric 10 may be composed only of fibers after heat stretching, or other fibers, for example, two components having different melting points, in addition to the fibers after heat stretching, and a non-heat stretchable core formed by stretching treatment.
  • the sheath-type heat-fusible conjugate fiber may be included.
  • the fiber for example, natural fibers, such as cotton and a pulp, rayon, an acetate fiber, etc. which does not have a heat
  • the proportion of the fibers after thermal extension in the nonwoven fabric 10 is preferably 20% by mass or more, particularly preferably 30% by mass or more, and 80 It is preferably at most 70 mass%, particularly at most 70 mass%.
  • the proportion of other fibers is preferably 20% by mass or more, particularly preferably 30% by mass or more, and is preferably 80% by mass or less, particularly preferably 70% by mass or less.
  • the post-heat-stretched fiber contained in the nonwoven fabric 10 is obtained by stretching the heat-extensible fiber, it goes without saying that the heat-stretchable fiber has a higher degree of heat-stretching when compared with each other.
  • this does not mean that the fiber after heat extension contained in the nonwoven fabric 10 is not heat-extensible, and as will be apparent from the method for manufacturing the nonwoven fabric 10 described later, there is room for further heat extension. It is what you have. That is, the post-heat-stretched fiber is not only a heat-stretchable fiber but also a heat-extensible fiber.
  • the thermal expansion rate differs depending on the position in the thickness direction.
  • the post-heat-stretched fiber located closer to the second surface 10b which is a substantially flat surface, has a higher thermal expansion rate than the post-heat-stretched fiber located near the first surface 10a, which is an uneven surface. It is high.
  • the nonwoven fabric 10 has a different degree of thermal elongation in the thickness direction, and therefore the degree of elongation on the second surface 10b side is large when the fiber after thermal elongation is thermally elongated by heat treatment to be described later.
  • the thermal elongation rate of the post-heat-stretched fiber is gradually increased from the first surface 10a of the nonwoven fabric 10 toward the second surface 10b.
  • hot air blowing conditions for example, hot air temperature and wind speed
  • the reason why the value of C / D can be set in the above range is that the thermal elongation rate and the thermal elongation rate change rate of the thermally extensible fibers used as the raw material of the nonwoven fabric 10 are in the above-described ranges. Therefore, even if the heat-extensible fiber known so far is used as the raw material fiber, the value of C / D cannot be set in the above range.
  • the thermal elongation rate of the fiber after thermal elongation contained in the nonwoven fabric 10 is measured by the following method. Five fibers are sampled at each site in the thickness direction of the nonwoven fabric. The length of the fiber to be collected is 1 mm or more and 5 mm or less. The collected fiber is sandwiched between preparations, and the total length of the sandwiched fiber is measured. For the measurement, a microscope VHX-900 and a lens VH-Z20R manufactured by KEYENCE were used. The measurement was performed by observing the fiber at a magnification of 50 times to 100 times, and using a measurement tool incorporated in the apparatus for the observed image. The length obtained by the measurement is defined as “the total length of fibers collected from the nonwoven fabric” Y.
  • the fiber whose total length has been measured is put into a DSC6200 sample container (product name: robot container 52-023P, 15 ⁇ L, aluminum) manufactured by SII Nano Technology.
  • the container containing the fibers is placed in a sample place in a DSC 6200 heating furnace set in advance to a temperature 20 ° C. higher than the melting point of the second resin component.
  • 60 seconds after the temperature (display name in the measurement software: sample temperature) measured by a thermocouple installed directly under the DSC6200 sample storage area is within a range of temperature ⁇ 1 ° C that is 20 ° C higher than the melting point of the second resin component Heat briefly and then remove quickly.
  • the heat-treated fiber is taken out from the DSC sample container and sandwiched between preparations, and the total length of the sandwiched fiber is measured.
  • a microscope VHX-900 and a lens VH-Z20R manufactured by KEYENCE were used for the measurement. The measurement was performed by observing the fiber at a magnification of 50 times to 100 times, and using a measurement tool incorporated in the apparatus for the observed image. The length obtained by the measurement is referred to as “full length of fiber after heat treatment” Z.
  • the basis weight is 10 g / m 2 or more and 80 g / m 2 or less, particularly 15 g / m 2 or more and 60 g / m 2 or less, especially 20 g / m. it is preferably 2 or more 40 g / m 2 or less.
  • the thickness of the nonwoven fabric 10 is preferably 0.5 mm or more and 3 mm or less, particularly 0.7 mm or more and 3 mm or less in the state after the heat treatment described later. The thickness of the nonwoven fabric was measured by the method described later.
  • the apparatus 20 shown in the figure includes a web manufacturing unit 30, an embossing unit 40, and a hot air blowing unit 50.
  • the web 10 a is manufactured using the fibers that are the raw material of the nonwoven fabric 10 (that is, the heat-extensible fibers before being stretched and other fibers as necessary).
  • the web 10a has a first surface 101 and a second surface 102 located on the opposite side.
  • the 2nd surface 102 is a surface which contacts the flat roll 42 in the embossing part 40 mentioned later, and is a surface which opposes the conveyor belt 52 which consists of a breathable net in the hot air spraying part 50 mentioned later.
  • the first surface 101 is a surface that comes into contact with the pattern roll 41 in the embossing portion 40 and is a surface to which hot air is blown in the hot air blowing portion 50.
  • a card machine 31 as shown in the figure can be used.
  • another web manufacturing apparatus such as an airlaid apparatus can be used instead of the card machine 31.
  • the web 10a manufactured by the card machine 31 is in a state where its constituent fibers are loosely intertwined, and has not yet achieved shape retention as a sheet. Therefore, in order to impart shape retention as a sheet to the web 10a, the web 10a is processed in the embossing section 40 to form the embossed web 10b.
  • the embossing part 40 is provided with a pair of rolls 41 and 42 arranged to face each other with the web 10a interposed therebetween.
  • the roll 41 is made of a metal pattern roll having a plurality of irregularities formed on its peripheral surface.
  • the uneven pattern in the pattern roll can be appropriately selected according to the specific use of the nonwoven fabric 10. For example, when forming the rhombus lattice-shaped emboss pattern shown in FIG. 2A, convex portions having a shape corresponding to the rhombus lattice may be formed on the peripheral surface of the roll 41. Further, when it is desired to form the dot-shaped emboss pattern shown in FIG.
  • a convex portion having a shape corresponding to the dot may be formed on the peripheral surface of the roll 41.
  • the roll 42 is a flat roll having a smooth peripheral surface.
  • the roll 42 is made of metal, rubber, paper, or the like.
  • the web 10a is sandwiched between both rolls 41 and 42 to perform embossing.
  • the heat-extensible fibers which are constituent fibers of the web 10a, are consolidated by heat-consolidating to form a plurality of embossed portions on the web 10a to produce the embossed web 10b.
  • the roll 41 and the roll 42 have a heatable structure, and at least the pattern roll 41 is heated to a predetermined temperature when the embossing unit 40 is operated.
  • the flat roll 42 may be heated or may not be heated.
  • the pattern roll 41 which is a roll with which the first surface 101 abuts the surface of the web 10a is heated, and the temperature is equal to or higher than the melting point of the second resin component in the heat-extensible fiber. The temperature is kept below the melting point of the first resin component.
  • the temperature of the flat roll 42 which is the roll with which the second surface 102 of the surface of the web 10a abuts is equal to or higher than the melting point of the second resin component ⁇ 20 ° C. in the heat-extensible fiber, and the melting point of the first resin component. Keep the temperature below.
  • the flat roll 42 may be used in an unheated state, and the temperature may be maintained below the melting point of the second resin component, or heated to the extent that the temperature does not exceed the melting point of the second resin component. You may use in the state. By setting the temperatures of the two rolls 41 and 42 in this way, the embossed web 10b to which shape retention is firmly imparted is obtained.
  • the heating temperature of the pattern roll 41 is Mp or more when the melting point of the second resin component is Mp (° C.). Preferably, it is Mp or more and Mp + 20 ° C. or less.
  • the heating temperature of the flat roll 42 is more preferably Mp ⁇ 20 ° C. or higher and Mp + 20 ° C. or lower, where the melting point of the second resin component is Mp (° C.).
  • the embossed web 10 b to which shape retention is imparted by the processing by the embossing unit 40 is then conveyed to the hot air blowing unit 50.
  • the hot air blowing unit 50 includes a hood 51.
  • the embossed web 10 b passes through the hood 51.
  • the hot air spraying part 50 is provided with the conveyor belt 52 which consists of a breathable net.
  • the conveyor belt 52 circulates in the hood 51.
  • the embossed web 10b is placed on the conveyor belt 52 and conveyed in the hot air blowing unit 50.
  • the conveyor belt 52 is made of a resin such as metal or polyethylene terephthalate.
  • the hot air blowing unit 50 hot air is blown against the first surface 101 of the embossed web 10b by an air-through method. That is, the hot air blowing unit 50 is configured such that hot air heated to a predetermined temperature penetrates the embossed web 10b.
  • the air-through process is performed at a temperature at which the heat-extensible fibers in the embossed web 10b are elongated by heating. And it is performed at the temperature at which the intersections of the heat-extensible fibers in the free state existing in the portions other than the embossed portion in the embossed web 10b are heat-sealed. By blowing hot air at this temperature, the heat-extensible fibers are stretched.
  • the heat-extensible fiber Since a part of the heat-extensible fiber is fixed by a joint portion composed of an embossed portion, it is a portion between the joint portions that extends. And since a part of the thermally stretchable fiber is fixed by the joint, the stretched fiber loses its place in the plane direction of the embossed web 10b and moves in the thickness direction of the embossed web 10b. To do. As a result, the joints rise to form the convex portions 19 and the nonwoven fabric 10 becomes bulky. Moreover, it comes to have the three-dimensional appearance in which the some convex part 19 was formed. Furthermore, the intersections of the heat-extensible fibers are joined by fusion. Thus, the nonwoven fabric 10 which has several unevenness
  • the blowing of hot air in this production method is preferably terminated before the heat-extensible fibers are completely extended.
  • the blowing of hot air by the air-through method is performed from the first surface 101 side of the two surfaces of the embossed web 10b.
  • the hot air blown to the first surface 101 side passes through the embossed web 10b and is discharged from the second surface 102 side. Since the hot air is deprived of heat while passing through the embossed web 10b and the temperature is lowered, the first surface 101 and the second surface 102 of the embossed web 10b are heated at different temperatures. Specifically, the heating temperature is lower on the second surface 102 side than on the first surface 101 side.
  • the post-heat-stretched fiber positioned closer to the first surface 101 and the post-heat-stretched fiber positioned closer to the second surface 102 are positioned closer to the second surface 102.
  • the post-heat stretched fiber has a lower heating temperature.
  • the post-heat-stretched fiber located closer to the second surface 102 is less stretched than the post-heat-stretched fiber located closer to the first surface 101.
  • the post-heat-stretched fiber located closer to the second surface 102 leaves room for further heat-stretching than the post-heat-stretched fiber located closer to the first surface 101.
  • the second surface 102 of the embossed web 10 b is more than the post-heat-stretched fiber located near the first surface 10 a, which is a surface corresponding to the first surface 101 of the embossed web 10 b.
  • the post-heat-stretched fiber located closer to the second surface 10b, which is a corresponding surface, has a higher thermal stretch rate.
  • the thermal elongation rate C of the post-thermal elongation fiber existing at the position P C see FIG.
  • the temperature of the hot air is preferably a temperature from a temperature 6 ° C. lower than the melting point of the second resin component to a temperature 15 ° C. higher than the melting point of the first resin component.
  • the wind speed is preferably 0.05 m / sec or more and 10 m / sec or less.
  • the hot air blowing time for example, it is preferably 1 second or longer and 10 seconds or shorter.
  • the nonwoven fabric 10 shown in FIG. 2 or FIG. 3 is obtained.
  • This nonwoven fabric 10 is once wound up and stored in the form of a roll, and then fed out from the roll and used. Or the required process is given in the same line as the manufacturing line of the nonwoven fabric 10, and the target product is manufactured.
  • the bulk of the nonwoven fabric 10 in the state of being wound in the form of a roll is often reduced by the winding pressure. Therefore, when the nonwoven fabric 10 is unwound from the roll and used, it is preferable to recover the reduced volume by blowing hot air to the nonwoven fabric 10 by an air-through method.
  • hot air blown to the nonwoven fabric 10 it is 20 to 20 ° C. lower than the melting point of the second resin component in the post-heat-stretched fiber (this fiber has heat-stretchability as described above). It is preferable to use hot air having a temperature up to a temperature higher than 0 ° C. and lower than the melting point of the first resin component.
  • the hot air may be blown from the first surface 10a side of the nonwoven fabric 10 or from the second surface 10b side. From the viewpoint of making the bulk recovery more remarkable, it is preferable to blow hot air from the second surface 10b side.
  • the second surface 10b side which is a substantially flat surface extends.
  • the post-heat stretched fibers also stretch.
  • the nonwoven fabric 10 is different in the thermal expansion rate of the fiber after thermal expansion between the first surface 10a side and the second surface 10b side.
  • the nonwoven fabric 10 after bulk recovery (hereinafter, this nonwoven fabric is referred to as “bulk-recovered nonwoven fabric 100”) has a plurality of convex portions 109a and concave portions 108a on the first surface 100a side as shown in FIG. In addition to having a plurality of protrusions 109b and recesses 108b on the second surface 100b side.
  • the nonwoven fabric 100 after bulk recovery is viewed in plan
  • the convex portion 109a on the first surface 100a side and the convex portion 109b on the second surface 100b side are in the same position.
  • the concave portion 108a on the first surface 100a side and the concave portion 108b on the second surface 100b side are in the same position.
  • the first surface 100a corresponds to the first surface 10a of the nonwoven fabric 10 shown in FIGS.
  • the degree of concavo-convex is higher on the first surface 100a side than on the second surface 100b side.
  • the height difference of the unevenness is large, and the thickness of the convex portion 109a on the first surface 100a side with respect to the center position L in the thickness direction of the nonwoven fabric 100 after bulk recovery is larger than the thickness of the convex portion 109b on the second surface 100b side. Is also getting bigger.
  • the thickness on the second surface 100b side in the nonwoven fabric 100 after bulk recovery is after thermal extension located on the second surface 10b side of the nonwoven fabric 10. It is thought to be due to the thermal elongation of the fiber.
  • the center position L in the thickness direction of the nonwoven fabric 100 after bulk recovery is obtained by using the KEYENCE microscope VHX-900 and the lens VH-Z20R to obtain an enlarged photograph of the nonwoven fabric cross section of the nonwoven fabric 100 after bulk recovery. Determined by tying in.
  • the thickness T b of the convex portion 109b When focusing on the convex portion 109b of the second surface 100b in the bulk recovery after nonwoven fabric 100, the thickness T b of the convex portion 109b, based on the thickness direction center position L of the bulk recovery after nonwoven 100, a bulk recovery after nonwoven fabric 100 It is preferable to occupy 20% or more and 40% or less of the thickness, and more preferably 22% or more and 35% or less.
  • the thickness T a of the convex portion 109a of the first surface 100a of the bulk recovery after nonwoven 100 based on the thickness direction center position L, accounting for 80% or more and 60% or less of the thickness of the bulk recovery after nonwoven fabric 100 It is preferable that it occupies 65% or more and 78% or less.
  • the nonwoven fabric 100 after bulk recovery has a concavo-convex structure in which both surfaces are plump, it has a texture with a high concavo-convex feeling.
  • the post-heat-stretched fibers contained in the nonwoven fabric 100 after bulk recovery are stretched by blowing hot air at the time of bulk recovery. This means that the post-heat-stretched fibers are not stretched at all by the subsequent application of heat. It doesn't mean that. That is, the post-heat-stretched fiber contained in the nonwoven fabric 100 after bulk recovery may be further stretchable by applying heat. However, since the post-heat-stretched fibers contained in the nonwoven fabric 100 after bulk recovery have already been subjected to heat application twice, the degree is not so large although it can be heat-stretched.
  • the thermal elongation E of the thermal post elongation fibers present position P E corresponding to the convex portion 109b in the surface of the second surface 100b side, corresponding to the convex portions 109a on the surface of the first surface 100a side the ratio between the thermal expansion rate F of the thermal post elongation fibers present position P F (E / F) is, in the melting point + 20 ° C. of the second resin component constituting the fiber after heat expansion, preferably less than 0.1 or more 3 More preferably, it is 2.0 or more and 2.8 or less.
  • the thermal elongation rate of the post-thermal elongation fiber contained in the nonwoven fabric 100 after bulk recovery is measured by the same method as the thermal elongation rate of the post-thermal elongation fiber contained in the nonwoven fabric 10.
  • the non-woven fabric 10 and the post-bulk-recovered non-woven fabric 100 that has recovered its bulk are suitably used as components of various absorbent articles such as sanitary napkins and disposable diapers, for example, surface sheets.
  • a second sheet a sheet disposed between the top sheet and the absorber
  • a back sheet a back sheet
  • a leak-proof sheet a personal wipe sheet
  • a skin care sheet a skin care sheet
  • an objective wiper can also be suitably used.
  • the nonwoven fabric 10 and the nonwoven fabric 100 after bulk recovery are used for an absorbent article such as a sanitary napkin, for example, the surface of the nonwoven fabric 10 and the nonwoven fabric 100 after bulk recovery having convex portions and concave portions faces the wearer's skin. It can arrange
  • the present invention further discloses the following heat-extensible fiber, a method for producing the same, and a nonwoven fabric.
  • ⁇ 1> Consists of a first resin component and a second resin component having a melting point or softening point lower than the melting point of the first resin component, and the second resin component continues at least part of the fiber surface in the length direction.
  • a heat-extensible fiber that is present and stretched by heating The change rate ( ⁇ (BA) / A ⁇ ⁇ 100) of the thermal elongation rate B at the melting point of the second resin component + 10 ° C. with respect to the thermal elongation rate A at the melting point ⁇ 6 ° C. of the second resin component is 130 % Heat-extensible fiber.
  • ⁇ 4> The heat-extensible fiber according to any one of the above items ⁇ 1> to ⁇ 3>, wherein the thermal elongation rate A is 3.5% or less.
  • ⁇ 5> The thermally extensible fiber according to ⁇ 4>, wherein the thermal elongation rate A is 0% to 3.5%, particularly 0% to 3.2%, particularly 0% to 3.0%.
  • ⁇ 6> The heat-extensible fiber according to any one of ⁇ 1> to ⁇ 5>, wherein the first resin component is made of polylactic acid and the second resin component is made of polyolefin.
  • the heat-extensible fiber according to any one of the above items ⁇ 1> to ⁇ 6> which is more preferable.
  • the second resin component is made of polyolefin, the polyolefin is made of polyethylene, and the polyethylene has a melt index of 10 g / 10 min to 40 g / 10 min, particularly 10 g / 10 min to 25 g / 10 min.
  • ⁇ 12> Any one of the above ⁇ 1> to ⁇ 11>, wherein the second resin component is made of polyolefin, the polyolefin is made of polyethylene, and the polyethylene has an orientation index of 5% or more, preferably 8% or more.
  • the heat-extensible fiber according to any one of ⁇ 1> to ⁇ 13> is used as a raw material, and has a plurality of convex portions and concave portions on one surface side, and the other surface side is one surface.
  • a nonwoven fabric in which the ratio (C / D) to the thermal elongation rate D of the thermally stretchable fiber in a thermally stretched state is 3 or more at the melting point + 20 ° C. of the second resin component constituting the thermally stretchable fiber.
  • the non-woven fabric has a plurality of convex portions and concave portions on one surface side, and also has a plurality of convex portions and concave portions on the other surface side, the convex portions and concave portions on one surface side, and the other surface
  • the convex portion and concave portion on the side are located at the same position in the plan view of the nonwoven fabric
  • the convex part contains a heat-extensible fiber in a heat-extended state, Present at a position corresponding to the convex portion on the surface on the other surface side, existing at a position corresponding to the convex portion on the surface on the one surface side, and the thermal elongation rate E of the heat-extensible fiber in a thermally stretched state, The ratio (E / F) with the thermal elongation rate F of the thermally stretchable fiber in the thermally stretched
  • the thickness of the convex part in the other surface side on the basis of the center position of the thickness direction of a nonwoven fabric occupies 20% or more and 40% or less of the thickness of the whole convex part.
  • the spinning temperature of the first component is set in the range of the melting point of the first component plus 20 ° C. to 180 ° C.
  • the spinning temperature of the second resin component is in the range of the melting point of the second component plus 20 ° C. to 180 ° C.
  • ⁇ 20> The method for producing a heat-extensible fiber according to any one of ⁇ 17> to ⁇ 19>, wherein melt spinning is performed at a spinning speed of 100 m / min to 1400 m / min.
  • ⁇ 21> The method for producing a heat-extensible fiber according to any one of ⁇ 17> to ⁇ 20>, wherein the relaxation treatment by heat drying is performed at 110 ° C. or more and 120 ° C. or less.
  • Example 1 Production of heat-extensible fibers Heat-extensible fibers made of concentric core-sheath composite fibers were produced by the melt spinning method using the apparatus described in Fig. 1 of Patent Document 1.
  • the first resin component polylactic acid (PLA) having a melt index of 8 g / 10 min was used.
  • the second resin component high density density polyethylene (HDPE) having a melt index of 22 g / 10 min was used.
  • the first resin component and the second resin component were melt-spun at the spinning temperature and spinning speed shown in Table 1 below.
  • the post-process shown in the same table was performed and the heat
  • Various physical properties of this heat-extensible fiber were measured as described above. The results are shown in Table 1 below.
  • the thickness of the nonwoven fabric 10 was measured by observing the longitudinal section of the nonwoven fabric. First, the nonwoven fabric was cut into a size of MD 120 mm ⁇ CD 60 mm, and a measurement piece was collected. A plate of 12.5 g (diameter 56.4 mm) was placed on the measurement piece, and a load of 49 Pa was applied. Under this condition, the longitudinal section of the nonwoven fabric was observed with a microscope (manufactured by Keyence Corporation, VHX-900, lens VH-Z20R), and the thickness of the convex portion of the nonwoven fabric was measured.
  • the nonwoven fabric 10 was cut into MD120 mm ⁇ CD60 mm to produce a cut piece.
  • the weight of this cut piece was measured using an electronic balance, and the basis weight was calculated.
  • the nonwoven fabric 10 obtained in the previous item (3) was pressurized with a weight or the like so as to be 4.9 kPa, and left in a 50 ° C. environment for 10 days (240 hours). The thickness and bulk were reduced.
  • the nonwoven fabric 10 was blown with hot air by an air-through method under the conditions shown in Table 4 to recover the bulk and obtain a nonwoven fabric 100 after the bulk recovery.
  • the obtained nonwoven fabric 100 after bulk recovery had a structure shown in FIG.
  • Various evaluations were performed on the nonwoven fabric 100 after the bulk recovery by the following methods. The results are shown in Table 4.
  • the thickness of the nonwoven fabric 100 after bulk recovery was measured by the same method as the thickness of the nonwoven fabric 10.
  • the thickness of the convex part in the 2nd surface side in the nonwoven fabric 100 after bulk recovery was measured as follows. First, as described above, an enlarged photograph of the cross section of the nonwoven fabric 100 after bulk recovery was obtained, and the thickness direction center position L was obtained by connecting adjacent concave portions with a straight line. Then, a perpendicular line is drawn from the thickness direction center position L shown as a straight line toward the vertex of the convex portion on the second surface side, and the distance from the thickness direction center position L to the vertex on the perpendicular line is set to the second surface. It was defined as the thickness of the convex portion on the side.
  • the unevenness of the nonwoven fabric 100 was measured by observing the longitudinal section of the nonwoven fabric. First, the nonwoven fabric was cut into a size of MD 120 mm ⁇ CD 60 mm, and a measurement piece was collected. A plate of 12.5 g (diameter 56.4 mm) was placed on the measurement piece, and a load of 49 Pa was applied. Under this condition, the longitudinal section of the nonwoven fabric was observed with a microscope VHX-900 and a lens VH-Z20R manufactured by KEYENCE. For five monitors, the degree of unevenness of the nonwoven fabric was evaluated according to the following four criteria. The results are shown as an average of 5 people. ⁇ Criteria> 4: The unevenness of the nonwoven fabric is sufficient.
  • a non-woven fabric having a length of 2700 m was wound around a paper tube having an outer diameter of 85 mm in a roll shape and stored at room temperature for 2 weeks.
  • the non-woven fabric in a wound state after storage is drawn out at a conveyance speed of 150 m / min in a range where the winding diameter is larger than 500 mm and smaller than 600 mm, hot air temperature 139 ° C., hot air blowing time 0.35 seconds, wind speed
  • the nonwoven fabric thickness was recovered by blowing hot air on the nonwoven fabric under the condition of 3.5 m / sec.
  • the thickness of the convex portion of the nonwoven fabric before winding the nonwoven fabric in a roll shape is G
  • Example 2 and Comparative Examples 1 to 4 Except using the conditions shown in the following Tables 1 to 4, a heat-extensible fiber, a nonwoven fabric 10, and a nonwoven fabric 100 after bulk recovery were obtained in the same manner as in Example 1. The evaluation results are shown in Tables 1, 3 and 4.
  • the heat-extensible fibers obtained in each example have a low thermal elongation rate at the melting point of ⁇ 6 ° C. of the second resin component, and the elongation is suppressed. Furthermore, it turns out that the heat extensible fiber obtained in each Example has a high rate of change of the thermal elongation rate. On the other hand, the fibers obtained in each comparative example have a high thermal elongation rate at the melting point of ⁇ 6 ° C. of the second resin component or heat shrinkage, and the change rate of the thermal elongation rate is low. I understand.
  • the nonwoven fabric 10 obtained in each example has the same basis weight as the nonwoven fabric obtained in each comparative example, but the thickness is obtained in each comparative example. It can be seen that it is larger than the nonwoven fabric.
  • the present invention it is possible to provide a heat-extensible fiber in which elongation is suppressed up to a specific temperature, and the degree of elongation increases rapidly when the temperature exceeds a specific temperature.

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  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Multicomponent Fibers (AREA)

Abstract

L'invention concerne des fibres qui présentent des propriétés d'allongement thermique et qui comportent un premier composant de résine et un second composant de résine ayant un point de fusion ou un point de ramollissement qui est inférieur au point de fusion du premier composant de résine, et au moins une partie de la surface des fibres du second composant de résine est présente sans interruption dans la direction de la longueur, la longueur s'étendant par suite de l'application de chaleur. La vitesse de changement ({(B - A)/A} × 100) de l'allongement thermique B, au niveau du point de fusion du second composant de résine plus 10°C, par rapport à l'allongement thermique A au point de fusion du second composant de résine moins 6°C, est d'au moins 130 %. Le premier composant de résine comporte de préférence de l'acide polylactique, alors que le second composant de résine comporte de préférence une polyoléfine. Le rapport (taux de crêpage (%)/taux de frisures (comptage)) entre le taux de crêpage (%) mesuré conformément à JIS L1015 et le nombre de frisures (comptage) mesuré conformément à JIS L1015 est de préférence entre 0,45 et 0,75.
PCT/JP2012/077707 2011-11-07 2012-10-26 Fibres avec des propriétés d'allongement thermique et tissu non-tissé les utilisant WO2013069475A1 (fr)

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