WO2013061406A1 - 機能性空調装置及び機能性空調方法 - Google Patents
機能性空調装置及び機能性空調方法 Download PDFInfo
- Publication number
- WO2013061406A1 WO2013061406A1 PCT/JP2011/074545 JP2011074545W WO2013061406A1 WO 2013061406 A1 WO2013061406 A1 WO 2013061406A1 JP 2011074545 W JP2011074545 W JP 2011074545W WO 2013061406 A1 WO2013061406 A1 WO 2013061406A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- air
- ground
- heat
- functional
- disinfectant
- Prior art date
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
- F24T10/00—Geothermal collectors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F5/00—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater
- F24F5/0046—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater using natural energy, e.g. solar energy, energy from the ground
- F24F5/005—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater using natural energy, e.g. solar energy, energy from the ground using energy from the ground by air circulation, e.g. "Canadian well"
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/117—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering
- F24F8/125—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering using wet filter elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
- F24T10/00—Geothermal collectors
- F24T10/10—Geothermal collectors with circulation of working fluids through underground channels, the working fluids not coming into direct contact with the ground
- F24T10/13—Geothermal collectors with circulation of working fluids through underground channels, the working fluids not coming into direct contact with the ground using tube assemblies suitable for insertion into boreholes in the ground, e.g. geothermal probes
- F24T10/17—Geothermal collectors with circulation of working fluids through underground channels, the working fluids not coming into direct contact with the ground using tube assemblies suitable for insertion into boreholes in the ground, e.g. geothermal probes using tubes closed at one end, i.e. return-type tubes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
- A61L9/145—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes air-liquid contact processes, e.g. scrubbing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/117—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/175—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using biological materials, plants or microorganisms
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
- F24F8/24—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/50—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by odorisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/40—Geothermal heat-pumps
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/54—Free-cooling systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/10—Geothermal energy
Definitions
- the present invention relates to a functional air conditioner and a functional air conditioning method using geothermal heat.
- the present invention is a functional air conditioner that can perform high-level sterilization and purification of air in various facilities such as offices and factories as well as general houses, and can provide a safe, comfortable and healthy living space.
- the purpose is to provide a functional air conditioning method.
- the functional air conditioner of the present invention sucks indoor or outdoor air from the inlet, sends it to the ground, heat exchanges the air in the ground, and performs heat exchange.
- a geothermal heat functional air conditioner provided with a flow pipe that discharges the air from the outlet into the room, wherein the flow pipe includes a forward path section for sending the air from the ground to the ground.
- a heat exchange reciprocating pipe having a return path for returning the air that has been heat-exchanged with the underground heat to the ground, and between the air outlet and the ground exhaust port of the heat exchange reciprocating pipe
- a sterilizing / purifying device in which a disinfectant solution is stored is interposed.
- the sterilizing and purifying device includes a heat-insulating sterilizing and cleaning casing, a liquid storage part for storing the disinfecting liquid, and one end edge side of the disinfecting liquid stored in the liquid storing part so that the disinfecting liquid is capillaryed.
- a filter that sucks up by a phenomenon and the sterilizing and purifying device further includes an inlet guide unit that guides the air that has flowed in between the inlet of the sterilizing and cleaning casing and the filter to the liquid storage unit side. It is what has.
- the filter is an inorganic fiber, the fiber thickness is set to 0.01 to 0.05 mm, and the filter thickness is set to 0.05 to 2.0 mm.
- the antiseptic solution contains a metal ion having antibacterial action, L-cysteine, and L-ascorbic acid as main components, and a surfactant excluding a nonionic system as a main component.
- the sterilizer is provided with a temperature adjusting means for adjusting the temperature of the sterilizing solution, and is configured to adjust the temperature of the air discharged from the sterilizing and cleaning device by adjusting the temperature of the sterilizing solution. It is.
- a housing casing having a connection port through which the air discharged from the sterilizing and purifying apparatus flows and having heat insulation, a housing part for housing a physiologically active substance effective in relieving stress, and the physiologically active substance
- a bioactive device having an ultrasonic wave generating means for volatilizing and mixing in the air is interposed between the air outlet and the sterilizer.
- the air conditioning method of the present invention is a method of using geothermal heat that sends indoor or outdoor air from the ground to the ground, heat-exchanges the air in the ground, and sends the heat-exchanged air to the room.
- This is a functional air conditioning method in which the air is brought into contact with a stored disinfectant solution before the air is sent into the room to sterilize and clean the air.
- the air is guided to the disinfecting solution to be brought into contact therewith, and further, the air is passed through a filter that sucks up the stored disinfecting solution by capillary action. And sterilizing and cleaning the air.
- it is a functional air conditioning method using geothermal heat that sends indoor or outdoor air from the ground to the ground, heat-exchanges the air in the ground, and sends the heat-exchanged air to the room.
- a method of sterilizing and cleaning the air by wetting the inner peripheral surface of the flow pipe through which the air flows with the disinfecting liquid and flowing the air in contact with the disinfecting liquid in the flow pipe. is there.
- a sterilizing and purifying device in which a disinfectant solution is stored is provided in the middle of a flow pipe that discharges air from the air outlet in the room.
- the present invention it is possible to send clean, high quality air that is aseptic and odorless, beautifully clear and high-quality air free of dust, pollen, mite carcasses, pet hair, etc., to obtain a safe and comfortable living space. be able to. Advanced air purification and a healthy life can be obtained not only in ordinary houses but also in offices, factories, and various large facilities.
- the air conditioner and the air conditioning method using the conventional geothermal heat can exhibit more excellent capability, and contribute to the spread of the air heat utilizing air conditioner using the geothermal heat.
- the functional air conditioner according to the present invention has a suction port Pa for sucking in air A in the room R or outdoor S of the building, and the sucked air A in the ground G.
- a heat exchange reciprocating pipe 10 that exchanges heat with the underground heat and sends it to the ground again, and a blowout port Pb that discharges the air A heat-exchanged with the underground heat in the underground G into the room R.
- It is a functional air conditioner using geothermal heat that is provided with a feed pipe P.
- a heat exchange reciprocating pipe 10 (hereinafter also referred to as a reciprocating pipe 10) is connected to a suction port Pa and is connected to a suction port Pa.
- a ground air supply port 10a into which air A flows in via a fan F, and air A from the ground to the ground.
- it is comprised by the double cylinder shape and is embed
- the sterilizing and purifying device 2 has a sterilizing and cleaning casing 21 having heat insulating properties.
- the sterilization / cleaning casing 21 has an upper opening-shaped sterilization / cleaning box member 51 having an inflow port 21a through which air A flows in and an outflow port 21b through which air A flows out, and a sterilization / cleaning box member 51 with a lid. And a sterilizing / cleaning lid member 52.
- the sterilizing and purifying device 2 stores the disinfecting liquid W at the bottom of the sterilizing / cleaning box member 51, and the disinfecting liquid W in the accumulating part 22 is immersed at one end of the sterilizing liquid W by a capillary phenomenon.
- the sterilizing and purifying device 2 supplies the air A that flows between the inlet 21a and the filter 24 on the inlet 21a side (hereinafter also referred to as inlet filter 24A) to the liquid storage unit 22 side (downward).
- An inlet guide portion 26 for guiding is provided.
- the inlet guide portion 26 is formed to be inclined forward and downward in a side view so that the inflowing air A can easily come into contact with the liquid surface of the disinfecting liquid W, and is formed continuously to the inlet partition portion 23 (23A).
- the diameter of the inlet 21a is set to be smaller than the average inner diameter of the connection pipe 91 connecting the ground exhaust port 10b of the reciprocating pipe 10 and the inlet 21a, and is set so as to increase the flow velocity of the inflowing air A. desirable.
- outlet guide portion that guides the air A close to the disinfectant W (lower part) to the outlet 21b between the outlet 21b and the filter 24 on the outlet 21b side (hereinafter also referred to as outlet filter 24B).
- the outlet guide portion 27 is continuous with the outlet partition portion 23 (23B), and is formed in a quarter arc shape (concave curved shape).
- the partition part 23 (23A, 23B), the inlet guide part 26, and the outlet guide part 27 are formed in a plate shape.
- the sterilizer 2 has a first space (chamber) 71 between the inlet 21a and the inlet filter 24A, and a second space (chamber) 72 between the inlet filter 24A and the outlet filter 24B.
- a third space (chamber) 73 is provided between the outlet filter 24B and the outlet 21b. Further, the disinfecting liquid W and the filter 24 can be replaced and replenished by removing the sterilization / cleaning lid member 52.
- the filter 24 is provided so as to be detachable (detachable) in the vertical direction from the sterilization / cleaning box member 51.
- the material is an inorganic fiber, and has the advantages that the thickness, length, shape, and density can be easily set and less deteriorated compared to natural cotton and cellulose. Specifically, glass wool, rock wool, metal wool and the like.
- the fiber thickness is set to 0.01 to 0.05 mm, and the thickness of the filter 24 is set to 0.05 to 2.0 mm.
- the density is set to 20 to 30 g / 1000 cm 3
- the density is set to 15 to 20 g / 1000 cm 3
- the density is set to 40 to 60 g / 1000 cm 3 .
- the sterilizer 2 includes a temperature control means 28 for adjusting the temperature of the air A discharged from the outlet 21b by adjusting the temperature of the disinfectant W in the liquid storage unit 22.
- the temperature control means 28 is a cooling body such as a cooling agent housed in a hermetically sealed container when the temperature of the discharged air A is lower than the air A that has flowed in.
- a heating element such as a heat insulating agent or a hot water bottle stored in a sealed container.
- the temperature of the disinfecting liquid W is set 15 ° C. higher than the temperature of the inflowing air A, and the discharged air A is raised by 1.5 to 2.5 ° C. More preferably, the temperature is increased by 3 ° C. It is desirable to set the temperature of the disinfectant W so that it does not exceed 45 ° C. or the temperature difference with the air A does not exceed 40 ° C.
- the temperature of the disinfecting liquid W is set to 5 ° C. or more lower than the temperature of the air A that flows in, and the discharged air A is 1.5 ° C. to 2.5 ° C. Lower, more preferably 3 ° C. It is desirable to set so that the disinfectant W does not become less than 5 ° C. or the temperature difference from the inflowing air A does not exceed 15 ° C.
- a physiologically active device 3 for mixing the volatilized physiologically active substance 39 in the air A is interposed. Yes.
- the physiological activator 3 contributes to relief of chronic unpleasant symptoms resulting from stress or recovery / improvement of natural healing power by relieving stress.
- the physiologically active device 3 has a housing casing 31 having heat insulation properties.
- the storage casing 31 includes an upper opening storage box member 61 having a connection port 31a through which air A discharged from the sterilizer 2 flows in and an outlet 31b through which the air A flows out, and a storage box member And a storage lid member 62 that covers 61. By removing the lid member 62, the physiologically active substance 39 can be easily replaced and supplemented.
- the physiologically active device 3 includes a storage part 32 in which a physiologically active substance 39 effective for relieving stress is stored in the storage box member 61, and a physiologically active substance (healing substance) disposed at the bottom of the storage box member 61. And 39) ultrasonic generating means 33 for volatilizing 39 components (extract, odor, etc.) and mixing (mixing) them into the air A flowing into the upper part of the housing casing 31.
- the ultrasonic wave generation means 33 may be configured to change (set) the frequency of the ultrasonic wave and induce repellent behavior in unpleasant beasts and pests such as moths, cockroaches, stray cats, and pigeons.
- a plurality of upwardly open storage portions 32 (32A, 32B) divided by a plurality of partition plate members are formed.
- an air cooling / warming amplification means (cooling body, heating element, etc.) made of warmer or colder air than the air A is stored in the storage section 32. May be.
- the physiologically active substance 39 is effective for relieving (relaxing) stress, and includes those in which stress is relieved by a brushbow (placebo) effect caused by a belief or the like.
- it is an essential oil (extract) used for aromatherapy (aroma therapy).
- aromatherapy is a type of alternative medicine that uses the essence extracted from aromatic plants, refreshes the mind and body, and makes it healthy by increasing the natural healing power. produce. It is transmitted to the cerebral system through the skin and nasal cavity, leading to old memory and instinct behavior, and further to the hypothalamus, where physiological reactions occur in the body.
- the hypothalamus is an important organ called the “brain in the brain” and adjusts the autonomic nervous system, endocrine system, and immune system in order to maintain body homeostasis.
- the olfactory sense does not pass through the intelligent cerebral cortex and is directly linked to the physiological response of the body.
- Table 1 below shows an example of an essential oil (extract) effective for stress-related chronic diseases and physiological actions other than stress relief.
- extract an essential oil
- the physiologically active substance 39 the actual effect (scientific effect) is not clear and there are many unclear points, but it may be a so-called drug stone.
- Table 2 below shows an example of medicinal stones (minerals) and substances that are said to be effective in relieving stress, or fine powder thereof and physiological actions other than relieving stress.
- volatilization means dispersion of components of the physiologically active substance 39 such as gasification and dispersion, fine particle dispersion and diffusion of odor components.
- the disinfectant W has extremely high safety mainly composed of amino acids, vitamins and minerals, which are basic substances of life and life activities, and has a wide range of antibacterial properties including general bacteria, acid-fast bacteria, spores, fungi and viruses. It has a spectrum and can be used for a variety of purposes, such as fingers, mucous membranes, and wounds, as well as instruments, equipment, excrement, and the environment, as well as disinfecting fresh foods and agricultural products.
- the disinfectant W is composed of one or more metal ions having an antibacterial action, L-cysteine and L-ascorbic acid as main components, and a surfactant that excludes nonionics from the main components. 1 type or 2 types or more are added.
- metal ions having antibacterial action include trivalent iron ions (Fe 3+ ), divalent iron ions (Fe 2+ ), zinc ions (Zn 2+ ), copper ions (Cu 2+ ), and cobalt ions (Co 2+ ). , Nickel ion (Ni 2+ ) or silver ion (Ag + ).
- the concentration of the metal ions having antibacterial action is 50 to 200 ppm for III-valent iron ions, 110 to 400 ppm for II-valent iron ions, 7.5 to 125 ppm for zinc ions, 15 to 60 ppm for copper ions, It is 180 to 300 ppm for cobalt ions, 85 to 175 ppm for nickel ions, and 1 to 3 ppm for silver ions.
- the concentration of L-cysteine is 100 to 1000 ppm and the concentration of L-ascorbic acid is 100 to 500 ppm.
- non-ionic surfactants are alkyl benzene sulfonate, linear alkyl benzene sulfonate, polyoxyethylene alkyl ether sulfate, higher alcohol sulfate ester, sodium lauryl sulfate, sodium lauroyl sarcosine, stearyl dimethylbenzene ammonium chloride. And at least one selected from the group consisting of benzalkonium chloride, benzethonium chloride, alkyldiaminoethylglycine hydrochloride and alkylpolyaminoethylglycine hydrochloride.
- the concentration of the surfactant excluding the nonionic system is 20 to 100 ppm.
- the antibacterial activity may be further enhanced by adding a small amount of various plant-derived essential oils such as hinoki and mint, antibacterial components, or mineral-derived antibacterial components to the above-described disinfectant W.
- the constituents are Fe 3+ ion 200 ppm, L-cysteine 1000 ppm, L-ascorbic acid 100 ppm, potassium sorbate 50 ppm, sodium lauryl sulfate 100 ppm. Moreover, it is PH3.0. Production Examples 2 to 4 are shown in Table 3 below.
- fungi such as Candida
- Spores such as Bacillus subtilis
- the avian influenza H5N3 type with an envelope lowered its titer (activity) to 1 / 100,000 to 1/1 million after 5 minutes of contact.
- the air A in the room R or the outdoor S is sent from the ground air inlet 10 a of the reciprocating pipe (double tubular pipe for underground heat exchange) 10 to the forward path section (outer cylinder section) 11. .
- the air A that has flowed through the forward path portion 11 is folded back at the bottom portion Pd of the reciprocating pipe 10 and flows through the return path portion (inner cylinder portion) 12, and then flows from the ground exhaust port 10 b to the connection pipe 91.
- the air A is heat-exchanged while being sent through the underground G, cooled in the summer, and warmed in the winter.
- the heat-exchanged air A flows through the connection pipe 91 and flows into the sterilizer 2.
- the inflowing air A is guided in the first space 71 by the inlet guide 26 in the direction of the level of the disinfecting liquid W, and by direct contact with the liquid level, dust, pollen, fungi, pet hair, etc.
- the foreign matter is removed by adsorption and sterilized. Further, it passes through the inlet filter 24A. At this time, foreign substances are sterilized, cleaned, and adsorbed by the disinfecting liquid W sucked up by the capillary phenomenon, and adsorbed on the fibers of the inlet filter 24A.
- the air A that has passed through the inlet filter 24A passes through the outlet filter 24B through the second space 72, and the remaining foreign matter that has not been removed by the inlet filter 24A is adsorbed and removed by the outlet filter 24B and sterilized and cleaned.
- the sterilized and purified (purified) air A is smoothly guided to the outlet 21b by the outlet guide 27 and is sent to the physiological activator 3. Further, in the sterilizer 2, heat exchange is performed with the disinfecting liquid W whose temperature has been adjusted by the temperature control means 28, so that the air A is cooled in the summer and the air A is warmed in the winter.
- the purified air A discharged from the sterilizing and purifying device 2 is mixed with the physiologically active substance 39 volatilized by the ultrasonic wave generating means 33 in the physiologically active device 3.
- the air A that has been sterilized and washed and that contains the component (stress relieving component) of the physiologically active substance 39 is discharged into the room R, and provides a safe, secure and comfortable healthy life for people.
- the air A in the room R or the outdoor S is sent from the ground to the underground G, and the air A exchanges heat with the underground heat in the underground G.
- This is a functional air-conditioning method using underground heat that sends air to the room R, and before sending the air A to the room R, the liquid was stored on the ground side and the outlet Pb side of the feed pipe P through which the air A flows.
- the air is brought into contact with the disinfecting liquid W so that the air A is brought into contact with the liquid surface.
- the stored disinfecting liquid W is sterilized and cleaned by sequentially passing through the two filters 24 and 24 sucked up by capillary action.
- the temperature of the air A is adjusted by exchanging heat between the disinfecting liquid W and the temperature of the air A adjusted by the temperature control means 28, and then the sterilized and temperature-adjusted air A is converted into the ultrasonic wave generation means 33.
- This is a functional air conditioning method in which the volatilized physiologically active substance 39 (component) is mixed and sent to the room R.
- a sterilizer 2 is installed in the room R.
- bacteria lactic acid bacteria that can easily measure the number of bacteria, non-toxic E. coli and green mold spores), pollen (cedar and straw), dust (Chile) ), Mite carcasses, and malodorous components (stool odor, garbage, ammonia odor, hydrogen sulfate odor, trimethylamine like fish rot odor), and stir and dry with a fan from the four corners of room R
- the room temperature was set to 15 ° C.
- lactic acid bacteria are LBS media
- E. coli is EC media
- fungi are Sabouraud media.
- the room temperature is set to a predetermined temperature
- the temperature of the disinfecting liquid W is changed by the temperature adjusting means 28, and the temperature at each location (room R, second space 72, third space 73) is measured. Is shown in Table 5 below.
- the discharged air A is 1.5 to 3.0. C is surely raised.
- the temperature of the disinfectant W is set to be 5 ° C. or more lower than the temperature of the inflowing air A, the discharged air (air that has passed through the outlet filter 24B) A is 1.5 ° C. to 3.0 ° C. C is surely lowered.
- the air (exhaust air) A that has passed through the outlet filter 24B is lower by 0.8 ° C to 1.5 ° C. Become.
- the temperature of the disinfectant liquid W is lowered from room temperature, the temperature of the air A that has passed through the outlet filter 24B is lowered.
- the liquid temperature is 5 ° C. higher than room temperature, the air A that has passed through the outlet filter 24B is made equal to the room temperature (the difference is within 0.5 ° C.).
- the temperature of the air A that has passed through the outlet filter 24B can be increased as the liquid temperature is increased. Note that, by changing the distance between the inlet filter 24A and the outlet filter 24B, a slight difference occurs in the temperature of the air A that has passed through the outlet filter 24B.
- airborne bacteria sampler (MBS-1000, JIS test collection efficiency 99% or more) is used to inhalate and collect bacteria floating in the air. This was sprayed and cultured on a nutrient agar medium at high speed to measure the number of bacteria (Test Example 2). In the second space 72 and the third space 73, each was operated for 15 seconds to collect 25 L of air A and sprayed on the medium. The results when the number of bacteria in the room R is 100 are shown in Table 6 below.
- the reciprocating tube 10 can exchange heat between the air A in the outdoor S and underground heat having a depth of 5 m from the ground. Further, although not shown, water for adsorbing dust or the like is stored in the bottom portion Pd of the reciprocating tube 10.
- the liquid temperature of the disinfectant W was set to 10 ° C. (8 ° C. lower than the air A flowing into the sterilizing and cleaning device 2). The results are shown in Table 7 below.
- the air A sampling and inspection method is the same as in Test Example 1.
- the air A was clean and odorless and beautiful air A was obtained.
- the air A flowing into the sterilizer 2 is reduced by 69% in the number of viable bacteria, 68% in the number of fungi, 75% in the pollen, 75% in the pollen, due to the water at the bottom Pd of the reciprocating tube 10 and the like.
- the carcass was reduced by 80%, dust and odor were halved, and the temperature of air A was lowered from 25 ° C to 18 ° C by heat exchange with underground heat.
- aseptic and odorless clear air A is obtained, and the temperature control effect is also improved. Also, pet hair could be removed.
- the case where the physiologically active device 3 is interposed is demonstrated.
- the bioactive substance 39 that suits the taste of each of the 20 subjects suffering from stress-related chronic unpleasant symptoms was stored in the bioactive device 3 connected to each room R, volatilized, and spent 4 weeks.
- all the symptoms of chronic disease were alleviated. Some reported that symptoms disappeared completely.
- the face of the subject is considered to be highly effective in combination with air A, which is calm and bright, almost aseptic and highly purified. What characterizes society today is the stress that prevails in society.
- FIG. 3 a flow pipe that sends air A in the room R or outdoor S from the ground to the ground G, heat-exchanges the air A in the ground G, and sends the heat-exchanged air A to the room R
- An air-conditioning method using geothermal heat provided with P wherein the inner peripheral surface Pe of the flow pipe P (reciprocating pipe 10) through which the air A flows is wetted with the disinfectant W, and the air A Is an air conditioning method in which air A is sent while being brought into contact with the disinfectant W to sterilize and clean the air A. Further, a small amount of the disinfectant W is stored in the bottom Pd of the reciprocating tube 10 while ensuring ventilation.
- the air A is brought into contact with the disinfecting liquid W on the inner peripheral surface Pe and the bottom Pd to adsorb foreign matters (objects to be removed) such as bacteria, pollen and dust contained in the air A, and sterilize the air A. ⁇
- This is a cleaning method.
- the disinfecting liquid W at the bottom Pd is pumped up and excreted, the feed pipe P is washed with tap water, and then a new disinfecting liquid W is dropped.
- Table 8 below shows the test results.
- the air A sampling and inspection method is the same as in Test Example 1.
- the disinfecting liquid W is stored in a tank T installed on the ground, and the disinfecting liquid W is supplied from the upper part of each of the forward path part 11 and the return path part 12 of the reciprocating pipe 10 via the pump 90.
- the inner peripheral surface Pe is always wetted by spraying or dripping.
- the physiologically active substance 3 volatilizes the physiologically active substance 39 and mixes it with the air A sent to the room R. Note that this method can be said to be a method in which the sterilizer 2 of the embodiment shown in FIGS. 1 and 2 is integrated with the reciprocating tube 10.
- the design of the present invention can be changed, and the installation location of the fan F, the sterilizer 2, the physiological activator 3, the pump 90, the tank T, and the like is under the floor of the building, the basement, the outdoors, or the building site The machine room inside is free.
- the temperature control means 28 may be a heater or a cooling device.
- a plurality of through holes are provided in the lower end portions of the partition wall portions of the forward path portion 11 and the return path portion 12 in order to ensure ventilation at the bottom portion Pd of the reciprocating pipe 10. It is good to make a notch.
- sterilization includes inactivation of viruses.
- the existing sterilization purifier 2 and the physiological activator 3 may be provided in the existing geothermal air conditioning feed pipe.
- the present invention also relates to an air conditioner having a function (sterilization, air purification, stress relief, etc.) to be installed (installed) in the delivery pipe P and its method, and in particular, installed in a system using geothermal heat ( It exerts power (high performance) by interposing.
- the sterilizer 2 and the physiologically active device 3 are not limited to being installed in an air conditioning system using geothermal heat, but are also shown in Tables 1 to 7 even if they are interposed in a normal blower pipe (flow pipe P). Safe and beautiful clear air can be obtained.
- the functional air conditioner of the present invention sucks the air A in the room R or the outdoor S from the suction port Pa, sends it to the ground G, heat-exchanges the air A in the ground G, It is a functional air conditioner using geothermal heat provided with a feed pipe P for discharging the exchanged air A into the room R from the outlet Pb, and the feed pipe P sends the air A from the ground to the ground.
- the sterilization cleaner 2 in which the disinfectant W is stored is installed between the ground exhaust port 10b of the tube 10, it is aseptic and odorless, and there is almost no dust, pollen, dead mites, pet hair, etc. Clear high-quality air A can be sent to the room R, and a safe and comfortable living space can be obtained. Advanced air purification and a healthy life can be obtained not only in ordinary houses but also in offices, factories, and various large facilities.
- the air conditioner using the geothermal heat is more excellent than the conventional air conditioner and can contribute to the spread of the air conditioner using the geothermal heat.
- the sterilizing and purifying device 2 includes a sterilizing and cleaning casing 21 having heat insulation properties, a liquid storage portion 22 in which the disinfecting liquid W is stored, and one end side of the disinfecting liquid W in the liquid storing portion 22 is immersed in the disinfecting liquid W. And the sterilizer 2 further guides the air A flowing between the inlet 21a of the sterilizing and cleaning casing 21 and the filter 24 toward the liquid storage unit 22 side. Since the inlet guide portion 26 is provided, the air A can be reliably brought into contact with the disinfecting liquid W, and foreign substances such as bacteria, dust and pollen can be reliably adsorbed. The air A can be brought into contact with the disinfecting liquid W efficiently and efficiently, and a reliable purification action can be stably obtained. Particularly in the summer, the air A is cooled by the heat of vaporization when passing through the filter 24, and a further energy saving effect (cooling effect) can be obtained.
- the filter 24 is an inorganic fiber, and the thickness of the fiber is set to 0.01 to 0.05 mm and the thickness of the filter 24 is set to 0.05 to 2.0 mm. It is possible to stably obtain a bactericidal (virus inactivation) action while maintaining a moist state. Air can be brought into contact with the disinfectant W without impairing the air blowing efficiency (air blowing property). Capillary phenomena can be reliably obtained without being affected by the amount of air blown or wind power. Compared with natural cotton and cellulose, the thickness, length, shape and density can be set easily. There is little deterioration and durability is obtained.
- the disinfectant W has a metal ion having an antibacterial action, L-cysteine and L-ascorbic acid as main components, and contains a surfactant excluding nonionics as a main component.
- a metal ion having an antibacterial action L-cysteine and L-ascorbic acid as main components, and contains a surfactant excluding nonionics as a main component.
- the sterilizer 2 is provided with a temperature adjusting means 28 for adjusting the temperature of the disinfecting liquid W, and is configured to adjust the temperature of the air A discharged from the sterilizing / cleaning apparatus 2 by adjusting the temperature of the disinfecting liquid W. Therefore, it is possible to obtain air A that is cooler in summer and warmer in winter than air A that is heat-exchanged by underground heat.
- the effect of relieving stress and restoring and enhancing natural healing power can be added to the air A. It is possible to relieve or eliminate chronic unpleasant symptoms induced by stress, and to restore and enhance natural healing power.
- the functional air conditioning method of the present invention sends the air A in the room R or the outdoor S from the ground to the ground G, heat-exchanges the air A in the ground G, and heat-exchanged air A into the room R.
- the air A is brought into contact with the stored disinfectant W before the air A is sent to the room R, and the air A is sterilized and cleaned. Odorless, beautiful, clear, high-quality air A with almost no dust, pollen, mite carcasses, pet hair, etc. can be sent to the room R, and a safe and comfortable living space can be obtained. Advanced air purification and a healthy life can be obtained not only in ordinary houses but also in offices, factories, and various large facilities.
- the air conditioning method using the conventional geothermal heat exhibits a superior ability and can contribute to the spread of the geothermal heat-utilizing air conditioner.
- the filter 24 in which the air A is guided and brought into contact with the disinfecting liquid W, and the stored disinfecting liquid W is sucked up by capillary action. Since the air A is sterilized and cleaned, the air A can be reliably brought into contact with the disinfectant W, and foreign substances such as fungi, dust, pollen, pet hair and the like can be reliably adsorbed. Particularly in the summer, the air A is cooled by the heat of vaporization when passing through the filter 24, and a further energy saving effect (cooling effect) can be obtained.
- the inner peripheral surface Pe of the flow pipe P through which the air A flows is wetted with the disinfecting liquid W, and the air A is flowed in contact with the disinfecting liquid W in the flow pipe P, so that the air A Since sterilization / cleaning is performed, the air A can be brought into contact with the disinfecting liquid W for a long time without any trouble, and the air A can be reliably sterilized / cleaned. It is possible to easily cope with the existing feed pipe P for underground heat exchange.
- the functional air conditioner of the present invention is provided with the sterilization cleaner 2 in which the disinfectant liquid W is stored in the middle of the flow pipe P for discharging the air A from the outlet Pb into the room R, it is aseptic and odorless. Therefore, a beautiful, clear and high-quality air A having almost no dust, pollen, mite carcasses, pet hair, etc. can be sent to the room R, and a safe and comfortable living space can be obtained. Advanced air purification and a healthy life can be obtained not only in ordinary houses but also in offices, factories, and various large facilities. Moreover, the ability superior to the conventional air conditioner can be exhibited.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Central Air Conditioning (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Abstract
Description
また、上記殺菌清浄器は、断熱性を有する殺菌清浄用ケーシングと、上記消毒液が貯液される貯液部と、該貯液部の上記消毒液に一端縁側が浸され上記消毒液を毛細管現象によって吸い上げるフィルタと、を有し、さらに、上記殺菌清浄器は、上記殺菌清浄用ケーシングの流入口と上記フィルタの間に、流入した上記空気を、上記貯液部側へ誘導する入口ガイド部を有するものである。
また、上記消毒液は、抗菌作用を有する金属イオンとL-システイン並びにL-アスコルビン酸を主成分として、この主成分に非イオン系を除く界面活性剤を含有するものである。
また、上記殺菌清浄器は、上記消毒液の温度を調節する温調手段を備え、上記消毒液の温度調整によって、上記殺菌洗浄器から排出される上記空気の温度を調整するように構成したものである。
また、上記殺菌清浄器から排出される上記空気が流入する接続口を有すると共に断熱性を有する収納用ケーシングと、ストレスの解消に有効な生理活性物質が収納される収納部と、上記生理活性物質を揮散させて上記空気に混入させるための超音波発生手段と、を有する生理活性器を、上記吹出口と上記殺菌清浄器の間に介設したものである。
また、上記空気が流れる送流配管の地上側において、上記空気を上記消毒液へ誘導して接触させ、さらに、上記空気を、上記貯液された消毒液を毛細管現象にて吸い上げたフィルタに通過させて、上記空気の殺菌・清浄をおこなう方法である。
または、室内に空気を吹出口から排出する送流配管の途中に消毒液が貯えられた殺菌清浄器を介設したものである。
また、従来の地中熱を利用した空調装置及び空調方法よりも、より一層優れた能力を発揮し、地中熱利用空調装置の普及に貢献できる。なぜならば、外気に比べ、夏は涼しく、冬は暖かい地中熱を熱交換パイプやヒートポンプとの併用で効率良く取り出す技術は基本的に確立されエネルギー効率の工場でランニングコストを30~40%削減し得るにも関わらず、掘削工事を伴う設置時のコスト問題がネックとなって、普及は殆ど進んでいない。この様な現状下で、地中熱利用の空調装置及び空調方法の浸透をはかるには、単に、省エネルギー効果を謳うだけでなく、従来にはない良質かつ高品質な空気の提供以外にない。折しも、社会的には環境問題を含めた再生可能エネルギーの積極的な導入が叫ばれ、安心感と安全性が何よりも優先され、病気の予防や健康長寿また自然回帰に視線が注がれている。日本では超高齢化社会を迎えてこれらの傾向は益々顕著になって来ている現在、高いイニシャルコストを補ってなお余りあるものとして多くの人に賛同を得て迎えられることになるからである。
また、現在は社会全般にわたり「安全性と安心感」が何よりも重要視される時代である。福島原発事故の放射能もれで周辺の広い土地は今後100年間は住めないとも言われている。これからは、環境問題とエコロジー(エコ)問題をはずしては語れない時代へと入った。地下資源には限りがあり石油の枯渇も遠い話しではない。その点、自然エネルギー(太陽熱、光、波、水力等々)は地球が存在する限り永久不滅である。
その一つに地中熱がある。大地は巨大な蓄熱層であり、それから得られる熱源(冬は暖かく夏は涼しい)を取り出し、空調装置及び空調方法として大いに利用することはエコ時代にマッチしており、普及を推進する事は社会的責任でもある。本発明によってエコだけでなく「安心と安全と健康」を得ることが容易となった。
本発明に係る機能性空調装置は、図1及び図2の実施の形態に於て、建物の室内R又は室外Sの空気Aを吸い込むための吸入口Paと、吸い込んだ空気Aを地中Gに送って地中熱と熱交換させて再び地上に送り出す熱交換用往復管10と、地中Gで地中熱と熱交換された空気Aを室内Rに排出する吹出口Pbと、を有する送流配管Pを備えている地中熱利用の機能性空調装置である。
図2に於て、殺菌清浄器2は、断熱性を有する殺菌清浄用ケーシング21を有している。
殺菌清浄用ケーシング21は、空気Aが流入する流入口21aと流入した空気Aを流出させる流出口21bとを有する上方開口状の殺菌清浄用箱部材51と、殺菌清浄用箱部材51を施蓋する殺菌清浄用蓋部材52と、を備えている。
入口ガイド部26は、流入した空気Aが消毒液Wの液面に接触しやすくするために側面視で前方下傾状に形成され入口仕切り部23(23A)に連続状に形成されている。
また、流入口21aの口径は、往復管10の地上排気口10bと流入口21aを接続する接続パイプ91の平均内径よりも小さい内径とし、流入する空気Aの流速を高めるように設定するのが望ましい。
材質は、無機質繊維であって、天然系の綿やセルロースに比べて、太さや長さ、形状、密度を、容易に設定でき、かつ、劣化が少ないという利点がある。
具体的には、グラスウール、ロックウール、金属系ウール等である。繊維の太さを、0.01~0.05mmに設定すると共に、フィルタ24の厚みを0.05~2.0mmに設定している。また、グラスウールの場合は、密度を20~30g/1000cm3、ロックウールの場合は、密度を15~20g/1000cm3、金属系ウールの場合は、密度を40~60g/1000cm3に設定する。
具体的には、温調手段28は、排出される空気Aの温度を、流入した空気Aよりも下げる場合は、密封容器に収納されている保冷剤等の冷却体であり、排出される空気Aの温度を、流入した空気Aよりも上げる場合は、密封容器に収納されている保温剤や湯たんぽ等の発熱体である。
また、流入した空気Aよりも冷たくする場合は、消毒液Wの液温を流入する空気Aの温度よりも5℃以上低く設定し、排出される空気Aを1.5℃~2.5℃降下、より好ましくは3℃降下させる。なお、消毒液Wが5℃未満にならないよう、又は、流入する空気Aとの温度差が15℃を越えないように設定するのが望ましい。
生理活性器3は、ストレス解消によって、ストレスから来る慢性の不快な症状の緩和、又は、自然治癒力の回復・向上に貢献するものである。
収納用ケーシング31は、殺菌清浄器2から排出される空気Aが流入する接続口31aと流入した空気Aを流出させる出口31bとを有する上方開口状の収納用箱部材61と、収納用箱部材61を施蓋する収納用蓋部材62と、を備えている。蓋部材62を外すことで容易に生理活性物質39を交換・補充可能としている。
具体的には、アロマテラピー(芳香療法)に使用される精油(エキス)である。アロマテラピーは芳香植物から抽出されたエッセンスを利用し、心身をリフレッシュして、自然治癒力を高めることで健康にするという代替医療の一種でストレスの型によって使い分け
ることでリラックス(ストレス解消)効果を生み出す。
皮膚や鼻腔を通して大脳辺系に伝わり、古い記憶や本能行動に結びつき、さらに、視床下部へと伝わり身体に生理反応があらわれる。視床下部は「脳の中の脳」と言われる程重要な器官で体の恒常性を保つ為に自律神経や内分泌系、免疫系を調整している。嗅覚は知的な大脳皮質を通さず身体の生理反応に直結している。下記表1に、ストレス性の慢性疾患に有効な精油(エキス)の一例と、ストレス解消以外の生理作用等を示す。
なお、樹木から放出される揮発性物質(森の香り、フィトンチッド)、杉や檜のチップ、松葉等も同じであり、また、単なる匂いである干し草や稲ワラの匂い、幼い時の思い出の匂い、郷愁を感じる匂い、チョコレートの香りなど、好みの匂いもアロマテラピーの一種(エキス)である。
下記表2に、ストレス解消に有効と言われる薬石(鉱物)や物質、或いはその微粉末とストレス解消以外の生理作用等の一例を示す。
また、生理活性物質39は、科学的な根拠がなくとも、特別な塩や、特殊な水等、室内Rの人が自分に良いと信じ込んでいるあらゆる物である。いわゆるブラシボー効果を誘うものであれば良く、意外に有効性を発揮することは広く知られている事実である。また、本発明に於て、揮散とは、気体化して分散、微粒子化して分散、臭気成分の拡散等、生理活性物質39が有する成分を分散させることを意味する。
また、抗菌作用を有する金属イオンが、 III価の鉄イオン(Fe3+)、II価の鉄イオン(Fe2+)、亜鉛イオン(Zn2+)、銅イオン(Cu2+)、コバルトイオン(Co2+)、ニッケルイオン(Ni2+)又は、銀イオン(Ag+)である。
また、抗菌作用を有する金属イオンの濃度が、 III価の鉄イオンでは、50~200ppm、II価の鉄イオンでは110~400ppm、亜鉛イオンでは7.5~125ppm、銅イオンでは、15~60ppm、コバルトイオンでは180~300ppm、ニッケルイオンでは85~175ppm及び銀イオンでは、1~3ppmである。
また、L-システインの濃度が100~1000ppm及びL-アスコルビン酸の濃度が100~500ppmである。
また、非イオン系を除く界面活性剤がアルキルベンゼンスルホン酸塩、直鎖アルキルベンゼンスルホン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、高級アルコール硫酸エステル塩、ラウリル硫酸ナトリウム、ラウロイルサルコシンナトリウム、塩化ステアリルジメチルベンゼンアンモニウム、塩化ベンザルコニウム、塩化ベンゼントニウム、塩酸アルキルジアミノエチルグリシン及び塩酸アルキルポリアミノエチルグリシンからなる群より選ばれる1種以上である。
また、非イオン系を除く界面活性剤の濃度が20~100ppmである。
また、ソルビン酸、ソルビン酸塩、安息香酸、安息香酸塩並びにパラオキシ安息香酸エステルからなる群より選ばれる少なくとも1種以上をさらに含有したものである。
なお、上述した消毒液Wに、ヒノキ、ミント等の各種の植物由来の精油や抗菌成分又は鉱物由来の抗菌成分を微量加えることによりその抗菌力をさらに高めても良い。
製造例1は、第1溶液として、塩化第二鉄・六水和物0.96gを精製水200mlに溶解する。第2溶液として、L-システイン1g、L-アスコルビン酸0.1g、ソルビン酸カリウム0.05g、ラウリル硫酸ナトリウム0.1gを精製水800mlに溶解する。次に、第1溶液と第2溶液とを混和せしめ、1規定の塩酸1mlを添加して、以下の構成成分から成る消毒液Wを製造した。
構成成分は、Fe3+イオン200ppm、L-システイン1000ppm、L-アスコルビン酸100ppm、ソルビン酸カリウム50ppm、ラウリル硫酸ナトリウム100ppm、である。また、PH3.0である。
製造例2~4を以下表3に示す。
ウイルスの場合、エンベローブを有する鳥インフルエンザH5N3型は5分の接触で1/10万~1/100万に力価(活性力)を低下させた。エンベローブを持たないノロウイルスは、感染しているカキ並びに感染者の便を、その10倍量の消毒液で浸漬させて検証したところ、30分後に崩壊(不活性化)した。
図1に於て、室内R又は室外Sの空気Aは、往復管(地中熱交換用二重筒状パイプ)10の地上給気口10aから往路部(外筒部)11に送流される。往路部11を流れた空気Aは、往復管10の底部Pdで、折り返して復路部(内筒部)12を流れ、地上排気口10bから接続パイプ91に流れる。空気Aは、地中Gを送流する間に熱交換され、夏期は冷やされ、冬期は温められる。
ルタ24Aの繊維に吸着させる。
また、殺菌清浄器2内において、温調手段28によって温度調整された消毒液Wと熱交換して、夏期の場合は空気Aが冷やされ、冬期の場合は空気Aが温められる。
殺菌清浄器2を室内Rに設置し、その室内Rに、細菌類(容易に菌数が測定可能な乳酸菌と無毒な大腸菌並びに青カビの胞子)と、花粉(杉及び檜)と、ホコリ(チリ)と、ダニの死骸と、悪臭成分(便臭、生ゴミ、アンモニア臭、硫酸水素臭、魚の腐敗臭のようなトリメチルアミン)と、を噴霧し、室内Rの四隅から扇風機にて攪拌、乾燥するに従い空気中に浮遊せしめ、室内Rの空気Aと、殺菌清浄器2内(第2空間72と第3空間73)の空気Aの浄化の程度、並びに空気Aの臭いや温度の違いを測定した(試験例1)。なお、殺菌清浄器2の流出口21bから陰圧(吸引仕事率60W)にて吸引することで検証した。室温は15℃に設定した。
花粉及びダニの死骸の場合は、1mmメッシュ格子線入りスライドグラス(26×76mm)にワリセリンを均等に塗り、グローボックス内で捕集した100mlの空気Aを均一に吹き付ける。花粉はゲンチアナバイオレット・グリセリンゼリー剤にて染色し、100~200倍の鏡見下で観察、ダニの死骸は5~10倍で観察した。
ホコリの場合は、清浄なガラス箱に捕集した1Lの空気Aを入れ、黒い紙を背景に光を照射することでチンタル現象しているホコリを肉眼で観察した。
悪臭成分の場合は、500mlのシリンジで採取し、臭い(匂い)袋に入れ、5人の官能テストの平均値とした。
雰囲気)。+印2つで、少ない(通常の室内の状態)。+印1つで、僅少で見た目に澄んで美しい。-印1つで、完全に澄んでいる状態。
また、悪臭の程度は次のように6段階評価した。0は無臭。1は、やっと微かに感じる臭い。2は、楽に(少し)感じる臭い。3は、明らかに感じる臭い。4は、強い臭い。5は、耐えられない程強く感じる臭い。
測定結果を下記表4に示す。
なお、結核菌などの抵酸菌や細菌芽胞、また、インフルエンザB型、鳥インフルエンザH1N1型、ノロ等のウイルスに於ても、別途試験を行なったが、上記の細菌や真菌と同様、ほぼ100%、フィルタ24に吸着され死滅又は失活することが確認された。
また、臭いについては臭いの性質にも影響されるが、生ゴミとか便臭等のいわゆる日常生活で発生する臭いはほぼ無臭化された。ただ、硫化水素の臭いやトリメチルアミン等のように水にやや溶けにくい臭いは僅かに残ったがその残った有臭空気を1~数回、殺菌清浄器2に還流させる事により消失した。即ち、空気Aを循環させれば、殆どの臭いは程なく吸着され、無臭の澄んだ空気Aが得られる。
また、室温より液温が5℃高い場合は、出口フィルタ24Bを通過した空気Aを室温と同等(差が0.5℃以内)にする。そして、液温が室温より5℃を越える熱さの場合、液温を高くするにつれて出口フィルタ24Bを通過した空気Aの温度を高くすることが可能であると言える。
なお、入口フィルタ24Aと出口フィルタ24Bの距離を変化させることで、出口フィルタ24Bを通過した空気Aの温度に多少の差異は発生する。
第2空間72及び第3空間73に於て夫々、15秒間作動させて25Lの空気Aを採取し、培地に吹き付けた。室内Rの細菌数を100とした場合の結果を下記表に6に示す。
試験例1と同様の室内Rで、生菌数、花粉、ホコリの程度、ダニの死骸、生ゴミ臭、温度、を測定(計測)した。なお、消毒液Wの液温を10℃に設定した(殺菌清浄機器2に流入する空気Aより8℃低くした)。結果を下記表7に示す。なお、空気Aの採取及び検査方法は、試験例1と同様である。
ストレス性の慢性な不快な症状に悩む20人の被験者夫々の好みに合った生理活性物質39を、各室内Rと接続された生理活性器3に収納して揮散させ、4週間過ごしてもらった結果、個人差はあるものの、全員が持病の症状が緩和された。中には、症状が完全に消失したとの報告もあった。外見的所見に於ても、被験者の顔は穏やかで明るくなり、ほぼ無菌で、高度に清浄された空気Aと相まって、高い効果が現われたものと考えられる。
現在社会を特徴づけるものは社会に蔓延するストレスである。この裏返しとして「安心・安全・健康指向」が重視され、現代人はストレス社会からの脱却を求めていると言っても過言ではない。厳しい競争社会、情報過多、家庭や職場での孤独感や人間関係の難しさなど解決能力を越えたストレスの大きさは体の不調を招き、当人の体の一番弱い部分が病気となって現れる。例えば、高血圧、低血圧、静脈瘤、蕁麻疹、頭痛、肥満症、月経不順や過多、副鼻腔炎、鼓腸、慢性下痢、便秘、不眠症、円形脱毛症、喘息、肌荒れ等、体の各分野に及んでいる。ストレスは万病の元凶と言われる所以である。
ストレスが原因となっている慢性疾患には特効薬はなく、ストレスから開放され精神の安定と心の癒しが症状の緩和や治療への最大のポイントとなる。何故ならば、心の安定は自然治癒力や免疫力を後押しし得るからである。
図3に示すように、室内R又は室外Sの空気Aを地上から地中Gに送って、地中Gにて空気Aを熱交換させ、熱交換した空気Aを室内Rに送る送流配管Pを備えた地中熱利用の空調方法であって、空気Aが流れる送流配管P(の往復管10)の内周面Peを消毒液Wで濡らし、送流配管P内で、空気Aを消毒液Wに接触させつつ送流させて、空気Aの殺菌・洗浄を行なう空調方法である。また、往復管10の底部Pdに、通風を確保しつつ消毒液Wを少量貯留させている。
そして、内周面Pe及び底部Pdの消毒液Wに、空気Aを接触させ、空気A中に含まれる細菌、花粉、ホコリ、等の異物(被除去物)を吸着すると共に、空気Aの殺菌・洗浄を行なう方法である。
また、所定期間毎に、底部Pdの消毒液Wを汲み上げて排泄し、送流配管Pを水道水で洗浄し、その後、新たな消毒液Wを滴下する。
また、本発明は送流配管Pに設置(介設)する機能性(殺菌・空気浄化・ストレス解消等)を有する空調装置とその方法に関わり、特に、地中熱を利用したシステムに設置(介在)せしめることにより威力(高性能)を発揮する。また、殺菌清浄器2及び生理活性器
3は、地中熱を利用した空調システムに設置するに止まらず、通常の送風管(送流配管P)に介在せしめても表1~表7に示すように安全で美しく澄んだ空気が得られる。
3 生理活性器
10 熱交換用往復管
10b 地上排気口
11 往路部
12 復路部
21 殺菌清浄用ケーシング
21a 流入口
22 貯液部
24 フィルタ
26 入口ガイド部
28 温調手段
31 収納用ケーシング
31a 接続口
32 収納部
33 超音波発生手段
39 生理活性物質
A 空気
G 地中
P 送流配管
Pa 吸入口
Pb 吹出口
Pe 内周面
R 室内
S 室外
W 消毒液
Claims (10)
- 室内(R)又は室外(S)の空気(A)を吸入口(Pa)から吸い込んで、地中(G)に送って、該地中(G)にて上記空気(A)を熱交換させ、熱交換した該空気(A)を上記室内(R)に吹出口(Pb)から排出する送流配管(P)を備えた地中熱利用の機能性空調装置であって、
上記送流配管(P)は、上記空気(A)を地上から地中に送るための往路部(11)と、地中にて地中熱と熱交換された該空気(A)を地上に戻す復路部(12)と、を有する熱交換用往復管(10)を備え、
上記吹出口(Pb)と、上記熱交換用往復管(10)の地上排気口(10b)の間に、消毒液(W)が貯えられた殺菌清浄器(2)を介設したことを特徴とする機能性空調装置。 - 上記殺菌清浄器(2)は、断熱性を有する殺菌清浄用ケーシング(21)と、上記消毒液(W)が貯液される貯液部(22)と、該貯液部(22)の上記消毒液(W)に一端縁側が浸され上記消毒液(W)を毛細管現象によって吸い上げるフィルタ(24)と、を有し、
さらに、上記殺菌清浄器(2)は、上記殺菌清浄用ケーシング(21)の流入口(21a)と上記フィルタ(24)の間に、流入した上記空気(A)を、上記貯液部(22)側へ誘導する入口ガイド部(26)を有する請求項1記載の機能性空調装置。 - 上記フィルタ(24)は、無機質繊維であって、繊維の太さを0.01~0.05mmに設定すると共に、上記フィルタ(24)の厚みを0.05~2.0mmに設定した請求項2記載の機能性空調装置。
- 上記消毒液(W)は、抗菌作用を有する金属イオンとL-システイン並びにL-アスコルビン酸を主成分として、この主成分に非イオン系を除く界面活性剤を含有するものである請求項1,2又は3記載の機能性空調装置。
- 上記殺菌清浄器(2)は、上記消毒液(W)の温度を調節する温調手段(28)を備え、
上記消毒液(W)の温度調整によって、上記殺菌洗浄器(2)から排出される上記空気(A)の温度を調整するように構成した請求項1,2,3又は4記載の機能性空調装置。 - 上記殺菌清浄器(2)から排出される上記空気(A)が流入する接続口(31a)を有すると共に断熱性を有する収納用ケーシング(31)と、ストレスの解消に有効な生理活性物質(39)が収納される収納部(32)と、上記生理活性物質(39)を揮散させて上記空気(A)に混入させるための超音波発生手段(33)と、を有する生理活性器(3)を、上記吹出口(Pb)と上記殺菌清浄器(2)の間に介設した請求項1,2,3,4又は5記載の機能性空調装置。
- 室内(R)又は室外(S)の空気(A)を地上から地中(G)に送って、該地中(G)にて上記空気(A)を熱交換させ、熱交換した該空気(A)を上記室内(R)に送る地中熱利用の機能性空調方法であって、
上記空気(A)を上記室内(R)に送る前に、貯液された消毒液(W)に上記空気(A)を接触させ、該空気(A)の殺菌・清浄をおこなうことを特徴とする機能性空調方法。 - 上記空気(A)が流れる送流配管(P)の地上側において、上記空気(A)を上記消毒液(W)へ誘導して接触させ、さらに、上記空気(A)を、上記貯液された消毒液(W)を毛細管現象にて吸い上げたフィルタ(24)に通過させて、上記空気(A)の殺菌・清浄をおこなう請求項7記載の機能性空調方法。
- 室内(R)又は室外(S)の空気(A)を地上から地中(G)に送って、該地中(G)にて上記空気(A)を熱交換させ、熱交換した該空気(A)を上記室内(R)に送る地中熱利用の機能性空調方法であって、
上記空気(A)が流れる送流配管(P)の内周面(Pe)を上記消毒液(W)で濡らし、
上記送流配管(P)内で上記空気(A)を上記消毒液(W)に接触させつつ送流させて、上記空気(A)の殺菌・清浄をおこなうことを特徴とする機能性空調方法。 - 室内(R)に空気(A)を吹出口(Pb)から排出する送流配管(P)の途中に消毒液(W)が貯えられた殺菌清浄器(2)を介設したことを特徴とする機能性空調装置。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/349,431 US20140246168A1 (en) | 2011-10-25 | 2011-10-25 | Functional air conditioning apparatus and functional air conditioning method |
JP2013540532A JP5800911B2 (ja) | 2011-10-25 | 2011-10-25 | 機能性空調装置及び機能性空調方法 |
EP11874496.0A EP2772698A4 (en) | 2011-10-25 | 2011-10-25 | FUNCTIONAL AIR CONDITIONING DEVICE AND FUNCTIONAL AIR CONDITIONING METHOD |
PCT/JP2011/074545 WO2013061406A1 (ja) | 2011-10-25 | 2011-10-25 | 機能性空調装置及び機能性空調方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2011/074545 WO2013061406A1 (ja) | 2011-10-25 | 2011-10-25 | 機能性空調装置及び機能性空調方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013061406A1 true WO2013061406A1 (ja) | 2013-05-02 |
Family
ID=48167273
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2011/074545 WO2013061406A1 (ja) | 2011-10-25 | 2011-10-25 | 機能性空調装置及び機能性空調方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20140246168A1 (ja) |
EP (1) | EP2772698A4 (ja) |
JP (1) | JP5800911B2 (ja) |
WO (1) | WO2013061406A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018165607A (ja) * | 2017-03-28 | 2018-10-25 | 東新住建株式会社 | 建物の空調装置 |
JP6979143B1 (ja) * | 2021-03-25 | 2021-12-08 | 特定非営利活動法人パッシブ地中熱大地の風 | 地中パイプを利用した建物の冷暖房及びウイルス等除去システム |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105783153B (zh) * | 2016-03-09 | 2018-11-02 | 李传友 | 基于地温结构比杂交风泵多管取温穿水净化的系统 |
JP6260977B1 (ja) * | 2016-10-26 | 2018-01-17 | 株式会社エコ・プランナー | 地中熱交換装置及び地中熱交換装置用の貯液槽の構築方法 |
CN108180664B (zh) * | 2017-12-29 | 2019-10-11 | 东南大学 | 一种中深层地热井的沉管装置 |
CN109114715A (zh) * | 2018-09-25 | 2019-01-01 | 四川建源节能科技有限公司 | 天然电催化液体喷雾清洁空气制造装置 |
JP2020110557A (ja) * | 2019-01-08 | 2020-07-27 | パナソニックIpマネジメント株式会社 | 空気浄化装置 |
DE102020112877A1 (de) | 2020-05-12 | 2021-11-18 | Gebr. Sträb GmbH & Co. KG | Pfosten, Pfahl oder Poller mit Erdkühlung |
TR202011322A2 (tr) * | 2020-07-16 | 2020-12-21 | Hamzaçebi̇ Eda | Kapali ortamlarda sağlikli hava solunmasi i̇çi̇n geli̇şti̇ri̇lmi̇ş si̇stem |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001289518A (ja) * | 2000-04-05 | 2001-10-19 | S X L Corp | 建物の外気導入装置 |
JP2003035443A (ja) * | 2001-07-24 | 2003-02-07 | Sanyo Electric Co Ltd | 加湿機 |
JP2003035455A (ja) | 2001-07-23 | 2003-02-07 | Daiwa House Ind Co Ltd | 地熱利用空調用の地中埋設縦型チューブの設置構造 |
JP2008076015A (ja) * | 2006-09-25 | 2008-04-03 | Sugiyama Shoji Kk | 地熱利用による建築物空調システム |
JP2009072653A (ja) * | 2007-09-19 | 2009-04-09 | Panasonic Corp | 超音波霧化装置 |
JP2009293298A (ja) * | 2008-06-06 | 2009-12-17 | Takashoo:Kk | 建築物の空気循環システム、および空気循環構造を有する建築物。 |
JP2011043294A (ja) * | 2008-05-12 | 2011-03-03 | Tai-Her Yang | 自然の熱エネルギーを利用した給気システム |
JP2011507975A (ja) * | 2007-12-31 | 2011-03-10 | タイコ ヘルスケア グループ リミテッド パートナーシップ | 消毒剤組成物、方法およびシステム |
WO2011086875A1 (ja) * | 2010-01-12 | 2011-07-21 | パナソニック株式会社 | 加湿装置および加湿機能付空気清浄装置 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4369635A (en) * | 1979-06-25 | 1983-01-25 | Ladek Corporation | Subterranean heating and cooling system |
JPS57195030U (ja) * | 1980-12-15 | 1982-12-10 | ||
CA2128612C (en) * | 1992-01-23 | 1999-06-15 | Mamoru Tomita | Antimicrobial agents and method for treating products therewith |
US5209286A (en) * | 1992-02-24 | 1993-05-11 | Schmidt James D | Ground open-air heat exchange, open-air conditioning system, and method |
US6054324A (en) * | 1995-09-12 | 2000-04-25 | Sullivan; George D. | Method for detecting the presence of killing and collecting infectious airborne microorganisms |
JP3091195B1 (ja) * | 1999-10-18 | 2000-09-25 | 株式会社東光工業 | 地熱利用空調システム |
US20030098276A1 (en) * | 2001-07-10 | 2003-05-29 | Carlson Robert A. | Filter for removing bacteria and particulates from fluid stream |
JP2004212038A (ja) * | 2002-12-20 | 2004-07-29 | Toko Kogyo:Kk | 建物の空調換気システム |
CN2654124Y (zh) * | 2003-09-25 | 2004-11-10 | 杨乐锡 | 空气净化机 |
JP2006207872A (ja) * | 2005-01-26 | 2006-08-10 | Toko Kogyo:Kk | 除湿空調システム |
DE102005029148B4 (de) * | 2005-06-23 | 2013-10-31 | Eisenmann Ag | Vorrichtung zur Luftaufbereitung sowie Oberflächenbehandlungsanlage mit derselben |
US8047905B2 (en) * | 2005-09-14 | 2011-11-01 | Steve Eugene Everett | Method, arrangement and apparatus for facilitating environmental climate control of a building structure |
KR101152472B1 (ko) * | 2006-05-19 | 2012-07-03 | 엘지전자 주식회사 | 지열을 이용한 공기조화기 |
CN101828079B (zh) * | 2007-10-17 | 2012-10-31 | 地能系统有限公司 | 利用自然能量的空调设备以及使用该设备的建筑物 |
US8201811B2 (en) * | 2009-01-12 | 2012-06-19 | Jason International, Inc. | Microbubble therapy method and generating apparatus |
-
2011
- 2011-10-25 EP EP11874496.0A patent/EP2772698A4/en not_active Withdrawn
- 2011-10-25 US US14/349,431 patent/US20140246168A1/en not_active Abandoned
- 2011-10-25 JP JP2013540532A patent/JP5800911B2/ja not_active Expired - Fee Related
- 2011-10-25 WO PCT/JP2011/074545 patent/WO2013061406A1/ja active Application Filing
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001289518A (ja) * | 2000-04-05 | 2001-10-19 | S X L Corp | 建物の外気導入装置 |
JP2003035455A (ja) | 2001-07-23 | 2003-02-07 | Daiwa House Ind Co Ltd | 地熱利用空調用の地中埋設縦型チューブの設置構造 |
JP2003035443A (ja) * | 2001-07-24 | 2003-02-07 | Sanyo Electric Co Ltd | 加湿機 |
JP2008076015A (ja) * | 2006-09-25 | 2008-04-03 | Sugiyama Shoji Kk | 地熱利用による建築物空調システム |
JP2009072653A (ja) * | 2007-09-19 | 2009-04-09 | Panasonic Corp | 超音波霧化装置 |
JP2011507975A (ja) * | 2007-12-31 | 2011-03-10 | タイコ ヘルスケア グループ リミテッド パートナーシップ | 消毒剤組成物、方法およびシステム |
JP2011043294A (ja) * | 2008-05-12 | 2011-03-03 | Tai-Her Yang | 自然の熱エネルギーを利用した給気システム |
JP2009293298A (ja) * | 2008-06-06 | 2009-12-17 | Takashoo:Kk | 建築物の空気循環システム、および空気循環構造を有する建築物。 |
WO2011086875A1 (ja) * | 2010-01-12 | 2011-07-21 | パナソニック株式会社 | 加湿装置および加湿機能付空気清浄装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2772698A4 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018165607A (ja) * | 2017-03-28 | 2018-10-25 | 東新住建株式会社 | 建物の空調装置 |
JP6979143B1 (ja) * | 2021-03-25 | 2021-12-08 | 特定非営利活動法人パッシブ地中熱大地の風 | 地中パイプを利用した建物の冷暖房及びウイルス等除去システム |
Also Published As
Publication number | Publication date |
---|---|
EP2772698A4 (en) | 2015-11-11 |
US20140246168A1 (en) | 2014-09-04 |
JP5800911B2 (ja) | 2015-10-28 |
JPWO2013061406A1 (ja) | 2015-04-02 |
EP2772698A1 (en) | 2014-09-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5800911B2 (ja) | 機能性空調装置及び機能性空調方法 | |
CN107333813A (zh) | 一种室内空气消毒剂及其制备方法 | |
CN102657245B (zh) | 一种采用植物提取物制成的消毒液及其制备方法 | |
CN104606700A (zh) | 一种固体空气清新剂及其制备方法 | |
CN103322622B (zh) | 一种卫生间空气净化系统 | |
CN111623462B (zh) | 医院用无味消毒换气装置 | |
CN104524613A (zh) | 一种环保空气清新剂及其制备方法 | |
CN105519597A (zh) | 一种含有植物精油的畜舍空气消毒剂及其使用方法 | |
CN102846491A (zh) | 宠物湿巾 | |
CN105135520A (zh) | 一种空气制水、加湿和净化一体化装置及其控制方法 | |
CN210070130U (zh) | 一种等离子体新风系统 | |
CN100525630C (zh) | 空调用抑菌组合物 | |
JP2010167088A (ja) | 殺菌・ウイルス不活性装置 | |
LU500752B1 (en) | Photocatalytic Ultraviolet Air Disinfection and Deodorization Device for Livestock and Poultry Houses | |
KR20220013998A (ko) | 공기 정화용 수직 가든 | |
CN1752643A (zh) | 一种单体/中央空调空气保湿净化的方法及装置 | |
CN106614781A (zh) | 一种家用消毒液及其制备方法 | |
CN103330956A (zh) | 一种抑菌型清新空气的组合物及其制备方法和用途 | |
CN213219589U (zh) | 杀菌消毒一体机 | |
CN213219571U (zh) | 过氧化氢杀菌消毒一体机 | |
CN209004791U (zh) | 室内空气消毒装置 | |
CN207734814U (zh) | 超声波除臭机 | |
JP2000126251A (ja) | クリ―ンベッド | |
CN110410917A (zh) | 一种等离子体新风系统 | |
CN2733218Y (zh) | 一种空调空气保湿净化的装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11874496 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2013540532 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14349431 Country of ref document: US |
|
REEP | Request for entry into the european phase |
Ref document number: 2011874496 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2011874496 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |